WO2008081791A1 - 流動性向上剤、芳香族ポリカーボネート系樹脂組成物、及びその成形品 - Google Patents

流動性向上剤、芳香族ポリカーボネート系樹脂組成物、及びその成形品 Download PDF

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Publication number
WO2008081791A1
WO2008081791A1 PCT/JP2007/074876 JP2007074876W WO2008081791A1 WO 2008081791 A1 WO2008081791 A1 WO 2008081791A1 JP 2007074876 W JP2007074876 W JP 2007074876W WO 2008081791 A1 WO2008081791 A1 WO 2008081791A1
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WO
WIPO (PCT)
Prior art keywords
mass
phenyl
meth
acrylate
polymer
Prior art date
Application number
PCT/JP2007/074876
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English (en)
French (fr)
Inventor
Shinji Matsuoka
Yasuhiko Nabeshima
Original Assignee
Mitsubishi Rayon Co., Ltd.
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Publication date
Application filed by Mitsubishi Rayon Co., Ltd. filed Critical Mitsubishi Rayon Co., Ltd.
Priority to AT07860105T priority Critical patent/ATE553155T1/de
Priority to KR1020097013572A priority patent/KR101443407B1/ko
Priority to US12/521,040 priority patent/US8202943B2/en
Priority to JP2008503312A priority patent/JP5269585B2/ja
Priority to EP07860105A priority patent/EP2100918B1/en
Priority to CN200780051750XA priority patent/CN101611096B/zh
Publication of WO2008081791A1 publication Critical patent/WO2008081791A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C08L25/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Optical Record Carriers And Manufacture Thereof (AREA)

Abstract

　芳香族ポリカーボネート樹脂本来の特性（透明性、耐表層剥離性、耐熱性、耐衝撃性、及び耐薬品性）を損なうことなく、成形加工時の流動性を向上させ、大型化、薄肉化、形状複雑化した成形品の成形を実現する。芳香族ビニル単量体（ａ１）０．５～９９質量％、（メタ）アクリル酸フェニル又はフェニル基に置換基を有する（メタ）アクリル酸フェニル（ａ２）０．５～９９質量％、及び官能基（Ｘ）を有するビニル単量体（ａ３）０．５～５質量％を含有する単量体混合物（ａ）を重合して得られる重合体（Ａ）０．５～９９．５質量部と、（メタ）アクリル酸フェニル又はフェニル基に置換基を有する（メタ）アクリル酸フェニル（ｂ１）を含有する単量体混合物（ｂ）と、官能基（Ｘ）と反応し得る官能基（Ｙ）を有する化合物を用いて重合して得られる重合体（Ｂ）０．５～９９．５質量部とを含有する（但し、重合体（Ａ）及び重合体（Ｂ）の合計を１００質量部とする）流動性向上剤。
PCT/JP2007/074876 2006-12-25 2007-12-25 流動性向上剤、芳香族ポリカーボネート系樹脂組成物、及びその成形品 WO2008081791A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
AT07860105T ATE553155T1 (de) 2006-12-25 2007-12-25 Fliessfähigkeitsverbesserer, aromatisches polycarbonatharz enthaltende zusammensetzung und formkörper daraus
KR1020097013572A KR101443407B1 (ko) 2006-12-25 2007-12-25 유동성 향상제, 방향족 폴리카보네이트계 수지 조성물, 및 그 성형품
US12/521,040 US8202943B2 (en) 2006-12-25 2007-12-25 Fluidity-improving agent, aromatic polycarbonate resin composition, and shaped article thereof
JP2008503312A JP5269585B2 (ja) 2006-12-25 2007-12-25 流動性向上剤、芳香族ポリカーボネート系樹脂組成物、及びその成形品
EP07860105A EP2100918B1 (en) 2006-12-25 2007-12-25 Fluidity improving agent, aromatic polycarbonate resin composition, and molded article thereof
CN200780051750XA CN101611096B (zh) 2006-12-25 2007-12-25 流动性改进剂、芳香族聚碳酸酯系树脂组合物及其成型品

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006-347026 2006-12-25
JP2006347026 2006-12-25

Publications (1)

Publication Number Publication Date
WO2008081791A1 true WO2008081791A1 (ja) 2008-07-10

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2007/074876 WO2008081791A1 (ja) 2006-12-25 2007-12-25 流動性向上剤、芳香族ポリカーボネート系樹脂組成物、及びその成形品

Country Status (8)

Country Link
US (1) US8202943B2 (ja)
EP (1) EP2100918B1 (ja)
JP (1) JP5269585B2 (ja)
KR (1) KR101443407B1 (ja)
CN (1) CN101611096B (ja)
AT (1) ATE553155T1 (ja)
TW (1) TWI455950B (ja)
WO (1) WO2008081791A1 (ja)

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WO2009113573A1 (ja) * 2008-03-11 2009-09-17 三菱レイヨン株式会社 芳香族ポリカーボネート樹脂用流動性向上剤及びその製造方法、芳香族ポリカーボネート樹脂組成物、並びに成形体
JP2010116501A (ja) * 2008-11-13 2010-05-27 Mitsubishi Rayon Co Ltd 表面硬度向上剤、熱可塑性樹脂組成物及びその成形体
EP2199336A1 (en) * 2008-12-17 2010-06-23 Cheil Industries Inc. Polycarbonate resin composition with improved transparency and scratch-resistance
JP2011052236A (ja) * 2010-12-17 2011-03-17 Mitsubishi Rayon Co Ltd ハードコート品
JP2011127002A (ja) * 2009-12-18 2011-06-30 Mitsubishi Rayon Co Ltd 熱可塑性樹脂組成物及び成形体
WO2011152486A1 (ja) * 2010-06-02 2011-12-08 三菱レイヨン株式会社 自動車用灯具
JP2012041442A (ja) * 2010-08-19 2012-03-01 Mitsubishi Rayon Co Ltd ポリカーボネート樹脂組成物及び成形品
JP2012057013A (ja) * 2010-09-07 2012-03-22 Kansai Paint Co Ltd 樹脂組成物、該樹脂組成物を含有する水性塗料組成物及び複層塗膜形成方法
US8202943B2 (en) 2006-12-25 2012-06-19 Mitsubishi Rayon Co., Ltd. Fluidity-improving agent, aromatic polycarbonate resin composition, and shaped article thereof
US8304494B2 (en) 2008-12-26 2012-11-06 Cheil Industries Inc. Polycarbonate resin composition with improved scratch resistance and melt flow index
US8318305B2 (en) 2010-05-28 2012-11-27 Sumitomo Chemical Company, Limited Resin composition
US8507594B2 (en) 2008-03-21 2013-08-13 Cheil Industries Inc. Flame retardant thermoplastic resin composition with improved compatibility
US8541506B2 (en) 2009-12-30 2013-09-24 Cheil Industries Inc. Polycarbonate resin composition with excellent scratch resistance and impact strength
US8642693B2 (en) 2007-12-18 2014-02-04 Cheil Industries Inc. Scratch-resistant flameproof thermoplastic resin composition with improved compatibility
US8658720B2 (en) 2008-03-13 2014-02-25 Cheil Industries Inc. Thermoplastic resin composition with improved compatibility
US8664322B2 (en) 2006-09-29 2014-03-04 Cheil Industries Inc. Thermoplastic resin composition and plastic article
JP2014111799A (ja) * 2014-03-27 2014-06-19 Mitsubishi Rayon Co Ltd 表面硬度向上剤、熱可塑性樹脂組成物及びその成形体
US8772401B2 (en) 2008-04-14 2014-07-08 Cheil Industries Inc. Flame-retardant scratch-resistant thermoplastic resin composition with improved compatibility
US8829091B2 (en) 2010-11-23 2014-09-09 Cheil Industries Inc. Polycarbonate resin composition and molded article using the same
JP5597550B2 (ja) * 2008-12-17 2014-10-01 電気化学工業株式会社 光学用成形体及びそれを用いた導光板及び光拡散体
US8901218B2 (en) 2007-12-18 2014-12-02 Cheil Industries Inc. Branched (meth)acrylate copolymer with high refractive index and method for preparing the same
US8907013B2 (en) 2010-05-17 2014-12-09 Cheil Industries Inc. Polycarbonate resin composition and molded product using the same
US8987379B2 (en) 2010-12-30 2015-03-24 Cheil Industries Inc. Polycarbonate resin composition having excellent chemical resistance
US9150725B2 (en) 2010-07-30 2015-10-06 Cheil Industries Inc. Flame retardant polycarbonate resin composition and molded product made using the same
US9150704B2 (en) 2011-06-21 2015-10-06 Cheil Industries Inc. Polyester resin composition
JP2016017153A (ja) * 2014-07-09 2016-02-01 帝人株式会社 熱可塑性樹脂組成物およびその成形品
JP2016040387A (ja) * 2015-12-17 2016-03-24 三菱レイヨン株式会社 表面硬度向上剤、熱可塑性樹脂組成物及びその成形体
JP2016041788A (ja) * 2014-08-19 2016-03-31 三菱レイヨン株式会社 重合体の製造方法、重合体、及び、芳香族ポリカーボネート系樹脂用流動性向上剤
US9359500B2 (en) 2012-12-28 2016-06-07 Cheil Industries Inc. Resin compositions and articles including the same
US9365671B2 (en) 2013-12-04 2016-06-14 Samsung Sdi Co., Ltd. Styrene-based copolymer and thermoplastic resin composition including the same
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JPWO2016031967A1 (ja) * 2014-08-29 2017-06-08 三菱ケミカル株式会社 （メタ）アクリレート樹脂材料、表面硬度向上剤、ポリカーボネート樹脂組成物および成形体
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US10131785B2 (en) 2015-06-30 2018-11-20 Lotte Advanced Materials Co., Ltd. Polyester resin composition with excellent impact resistance and light reliability and molded article using the same
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JP2020122146A (ja) * 2019-01-30 2020-08-13 三菱ケミカル株式会社 流動性向上剤、芳香族ポリカーボネート系樹脂組成物、及びその成形品
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JP6245409B2 (ja) 2015-12-11 2017-12-13 三菱ケミカル株式会社 熱可塑性樹脂用流動改質剤及びそれを含む熱可塑性樹脂組成物
EP3473918B1 (de) * 2017-10-19 2021-12-01 ZKW Group GmbH Beleuchtungsvorrichtung für einen kraftfahrzeugscheinwerfer
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Cited By (59)

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US8664322B2 (en) 2006-09-29 2014-03-04 Cheil Industries Inc. Thermoplastic resin composition and plastic article
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