WO2008035563A1 - Cosmétique capillaire - Google Patents

Cosmétique capillaire Download PDF

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Publication number
WO2008035563A1
WO2008035563A1 PCT/JP2007/067169 JP2007067169W WO2008035563A1 WO 2008035563 A1 WO2008035563 A1 WO 2008035563A1 JP 2007067169 W JP2007067169 W JP 2007067169W WO 2008035563 A1 WO2008035563 A1 WO 2008035563A1
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WO
WIPO (PCT)
Prior art keywords
acid
hair
gallic acid
chitosan
hair cosmetic
Prior art date
Application number
PCT/JP2007/067169
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English (en)
Japanese (ja)
Inventor
Katsunori Ohnuma
Motohiro Kageyama
Original Assignee
Lion Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lion Corporation filed Critical Lion Corporation
Priority to JP2008535309A priority Critical patent/JPWO2008035563A1/ja
Priority to CN2007800301011A priority patent/CN101500536B/zh
Publication of WO2008035563A1 publication Critical patent/WO2008035563A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/736—Chitin; Chitosan; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87—Polyurethanes

Definitions

  • the present invention relates to a hair cosmetic, and more particularly, to a hair cosmetic that gives firmness and firmness to damaged, thin, soft hair, suppresses stickiness, prevents wrinkling, and finishes it smoothly and smoothly according to the finger. is there.
  • hair cosmetics containing a film-forming resin such as polyacrylic acid or polybule polymer have been proposed for the purpose of giving firmness to thin hair and facilitating styling.
  • a film-forming resin such as polyacrylic acid or polybule polymer
  • these hair cosmetics give a firmness and firmness, they appear stiff and squeezed and the feel is reduced, and the film formed on the hair also has physical strength and strength.
  • the firmness of the skin decreased with time because it was easily disintegrated by moisture.
  • Patent Document 1 Japanese Patent Laid-Open No. 60-243010
  • Patent Document 2 Japanese Patent Laid-Open No. 2-53712
  • Patent Document 3 Japanese Patent Laid-Open No. 59-65008
  • Patent Document 4 Japanese Patent Laid-Open No.
  • Patent Document 5 Special). JP-A-62-29404, Patent Document 6: JP-A-62-221615, Patent Document 7: JP-A-1 009911 1, Patent Document 8: JP-A-4308525, Patent Document 9: JP-A-1 24971 No. 1).
  • Patent Document 1 Japanese Patent Application Laid-Open No. 60-243010
  • Patent Document 2 JP-A-2-53712
  • Patent Document 3 Japanese Patent Laid-Open No. 59-65008
  • Patent Document 4 JP-A 62-36308
  • Patent Document 5 Japanese Patent Publication No. 62 29404
  • Patent Document 6 Japanese Patent Laid-Open No. 62-221615
  • Patent Document 7 Japanese Patent Laid-Open No. 1009911
  • Patent Document 8 Japanese Patent Laid-Open No. 4 308525
  • Patent Document 9 Japanese Patent Laid-Open No. 1 24971 1
  • Patent Document 10 Japanese Unexamined Patent Publication No. 2000-290143
  • the present invention is damaged and weakened by chemical treatments such as coloring and perm, and gives firmness and firmness to thin and soft hair.
  • the purpose of the present invention is to provide a hair cosmetic that can suppress hair and give a good hair feel.
  • the inventors of the present invention used chitosans and polyurethane resin in combination to form a strong and uniform film of chitosans, and the polyurethane resin gives flexibility and elasticity. It has been found that it can give firmness and firmness without squeezing through the fingers, suppress stickiness, and provide a good styling feel.
  • a hair cosmetic containing (A) chitosans and (B) a polyurethane resin,
  • a hair cosmetic composition that gives firmness and firmness to damaged thin and soft hair, and is free of squeaking and squeezing, and has a strong hair and imparts a good hair feel. can do.
  • the hair cosmetic composition of the present invention is a hair cosmetic composition containing (A) chitosans and (B) a polyurethane resin.
  • the chitosans of the present invention include (1) chitosan, partially deacetylated chitin and salts thereof, (2) a water-soluble oligomer obtained by decomposing (1) above, (3) hydrophilic to (1) above And water-soluble chitosan derivatives into which a group has been introduced. These may be used alone or in appropriate combination of two or more.
  • (1) Chitosan and partially deacetylated chitin are chitin (/ 3 1, 4 poly N acetyl darcosamine), the main structural polysaccharide of arthropods, mollusks, anal animals, and fungi. Obtained by deacetylation.
  • Chitosan is a completely deacetylated product of chitin (/ 3 1, 4 polydarcosamine), and a partially deacetylated chitin having a degree of deacetylation of about 45 to 55% is preferably used.
  • Chitosan or partially deacetylated chitin salts include inorganic salts such as hydrochlorides and nitrates, acetates, lactates, glycolates, pyrrolidone carboxylates, kenates, succinates, malic acids.
  • Organic acid salts such as salts can be mentioned.
  • the water-soluble chitosan derivatives having a hydrophilic group introduced in (1) above are hydroxyethyl chitosan, hydroxypropyl chitosan, hydroxyethyl 'hydroxypropyl chitosan, (poly) oxyalkylene chitosan, carboxymethyl chitosan.
  • the (2) water-soluble oligomer and (3) the water-soluble chitosan derivative introduced with a hydrophilic group can be obtained by the methods described in, for example, DE3541305 and JP-A-62-2221615.
  • chitosan hydrolyzes the N-acetyl group of chitin and is itself water-insoluble. Therefore, it can be converted into a water-soluble chitosan derivative by controlling the molecular weight or by inducing chitosan into a water-soluble compound. .
  • the chitosans are preferably water-soluble oligomers, hydroxyethyl chitosan, hydroxypropyl chitosan, hydroxyethyl hydroxypropyl chitosan, quaternized chitosan, and salts thereof.
  • the amount of component (A) is not particularly limited, but is usually 0.00;! To 5 mass%, preferably 0.0;! To 3 mass% with respect to the total amount of the hair cosmetic. By setting this range, it is possible to obtain the desired effect.
  • the polyurethane resin is (1) a resin obtained by polyaddition reaction of a polyisocyanate and an active hydrogen-containing compound. These can be used alone or in combination of two or more.
  • Diisocyanates and trifunctional or higher polyfunctional isocyanates such as aromatic polyisocyanates having 6 to 20 carbon atoms (except for carbon in the NCO group) 6 to 20 carbon atoms; Aliphatic polyisocyanate, C6-C15 alicyclic polyisocyanate, C8-C15 araliphatic polyisocyanate and modified products of these polyisocyanates (urethane groups, carpositimides) Group, alophanate group, burette group, uretdione group, uretoimine group, isocyanurate group, modified product containing oxazolidone group) and a mixture of two or more of these.
  • aromatic polyisocyanates having 6 to 20 carbon atoms (except for carbon in the NCO group) 6 to 20 carbon atoms
  • aromatic polyisocyanate examples include, for example, 1,3 phenylene diisocyanate, 1,4 phenylene diisocyanate, 2,4-tolylene diisocyanate (TDI), 2 , 6 Tolylene diisocyanate (TDI), Crude TDI, 2, 4, 1-diphenylmethane diisocyanate (MDI), 4, 4'-diphenylmethane diisocyanate (MDI), 4, 4'-diisocyanate Anatobiphenyl, 3, 3, 1-dimethyl-4,4'-diisocyanatobiphenyl, 3,3, -dimethyl-4,4, -diisocyanatodiphenylmethane, crude MDI [crude diaminodiphenylmethane [formaldehyde and fragrance condensation products of family Amin (Anirin) or mixtures thereof; phosgene product of diamino diphenyl mixture of trifunctional or higher polyamine enyl methane
  • polyaryl Soshianeto 1, 5-naphthylene diisocyanate iso shea Aneto, 4, 4 ', 4 "triphenylmethane triisostearate Xia sulfonates, m-isocyanatophenyl sulfonyl Ruisoshianeto include p- isocyanatophenyl sulfonyl iso Xia sulfonates.
  • aliphatic polyisocyanate examples include, for example, ethylene diisocyanate. , Tetramethylene diisocyanate, hexamethylene diisocyanate (HDI), dodecamethine diisocyanate, 1,6,11-undecane triisocyanate, 2,2,4-trimethinore force proate) Bis (2-isocyanatoethyl) fumarate, bis (2-isocyanatoethyl) carbonate, 2 isocyanatoethyl-2, 6 diisocyanatohexanoate.
  • ethylene diisocyanate Tetramethylene diisocyanate
  • hexamethylene diisocyanate HDI
  • dodecamethine diisocyanate 1,6,11-undecane triisocyanate
  • 2,2,4-trimethinore force proate bis (2-isocyanatoethyl) fumarate, bis (2-isocyanatoethyl) carbonate, 2 iso
  • alicyclic polyisocyanate examples include, for example, isophorone diisocyanate.
  • IPDI dicyclohexylmethane 4,4'-diisocyanate
  • hydromethyl MDI hydrogenated MDI
  • cyclohexylene diisocyanate methinolecyclohexylene diisocyanate
  • bis (2-isocyanatoethyl) -4-cyclohex examples include xenene 1,2-dicarboxylate, 2,5-norbornane diisocyanate, and 2,6-norbornane diisocyanate.
  • aromatic aliphatic polyisocyanate examples include m-xylylene diisocyanate, p-xylylene diisocyanate, ⁇ , a, ⁇ ', ⁇ , monotetramethylxylylene diisocyanate. Can be mentioned.
  • modified polyisocyanate examples include modified MDI (urethane modified MDI, carpositimide modified MDI, trihydrocarbyl phosphate modified MDI), urethane modified TDI, burette modified HDI, isocyanurate modified HDI, isocyanurate modified IPDI, etc. And polyisocyanate modifications and mixtures of two or more thereof.
  • aliphatic and alicyclic polyisocyanates particularly HDI, IPDI, and hydrogenated MDI because they are less likely to discolor due to aging.
  • the active hydrogen-containing compound includes (2) a low molecular polyfunctional active hydrogen-containing compound and (3) a high molecular polyol.
  • the low molecular weight polyfunctional active hydrogen-containing compound includes a low molecular weight polyol.
  • OH equivalent number average molecular weight per hydroxyl group (according to GPC measurement; the same applies hereinafter)] is less than 300 (preferably 30 to 250) 2 to 10 Or more polyols (preferably divalent to trivalent) can be used.
  • (2-1) include dihydric alcohols such as aliphatic diols [linear diols (ethylene glycol, Diethylene glycol, 1,3-propanediol, 1,4 butanediol, 1,5-pentanediol, 1,6-hexanediol, etc., and branched diols (propylene glycol, neopentyl glycol, 3 methyl-1, 5 pentanediol, 2 methylol 2,4 pentanediol, 2,2 jetyl 1,3 propanediol, 1,2-butanediol, 1,3 butanediol, 2,3 butanediol, etc.), a diol having a carboxyl group A certain dimethylolpropionic acid] and a diol having a cyclic group [for example, those described in JP-B-45-1474; 1,4 bis (hydroxymethyl) cyclohexane,
  • Carbon number 2 10 or more] low molar adducts; and mixtures of two or more of these, preferred! / are aliphatic diols, more preferably 1,3-butanediol. 3-methyl-1,5-pentanediol and dimethylolpropionic acid.
  • (3) includes (3-1) polyester polyol, (3-2) polyether polyol, and mixtures of two or more thereof.
  • polyester polyols include condensed polyester polyols (by polycondensation of polyols and polycarboxylic acids).
  • the polyol in (3-1) is a low molecular weight polyol [for example, one or more selected from the above-mentioned (2-1)] and a polyether polyol [for example, (3-2) described later] Can be used.
  • the polycarboxylic acids in (3-1) include polycarboxylic acids and ester-forming derivatives thereof. Specific examples include aliphatic polycarboxylic acids [functional group number 2-6, carbon number 3 To 30 polycarboxylic acids such as succinic acid, glutaric acid, maleic acid, fumaric acid, adipic acid, azelaic acid, sebacic acid, hexahydrophthalic acid, etc.], aromatic polycarboxylic acids [functional group number 2-6, C8-C30 polycarboxylic acids such as phthalic acid, isophthalic acid, terephthalic acid, tetrabromophthalic acid, tetrachlorophthalic acid, trimellitic acid, pyromellitic acid, etc.]; these ester-forming derivatives [acid anhydride , Lower alkyl (1 to 4 carbon atoms) ester (dimethyl ester, jetyl ester, etc.), acid halide (acid chloride, etc.
  • (3-2) includes a compound in which AO is added to a compound having two or more active hydrogen atoms.
  • Examples of the compound having an active hydrogen atom include a low molecular polyol [for example, (2-1) above];
  • Divalent phenols eg bisphenols (bisphenol A, bisphenol F, bisphenol S, etc.), monocyclic phenols (catechol, hydroquinone, etc.)]; amines [primary monoamines such as alkyl or alkenylamine (carbon number 1 To 20), aniline, alkanolamine (2 to 4 carbon atoms of hydroxylalkyl group)] and the like.
  • AO includes ethylene oxide (hereinafter abbreviated as EO), propylene oxide (hereinafter abbreviated as PO), 1,2-butylene oxide, 1,3-butylene oxide, 1,4-butylene oxide, 2,3-butylene.
  • EO ethylene oxide
  • PO propylene oxide
  • 1,2-butylene oxide 1,3-butylene oxide
  • 1,4-butylene oxide 2,3-butylene.
  • fatty acid diols and divalent phenols with addition of soot and soot.
  • the equivalent weight of (3) is from the viewpoint of hair feel, force, etc., preferably 300 to 10,000, more preferably 500 to 5,000, particularly preferably ⁇ 1,000, 000.
  • the polyurethane resin used in the present invention may be cationic, nonionic, anionic or amphoteric, and commercially available polyurethane resins include Rubyset PUR (manufactured by BASF): DynamX (Japan NSC) ), Heralol UC-4 (manufactured by Sanyo Chemical Co., Ltd.) The power to raise S.
  • a polyurethane resin having a cationic group is preferable from the viewpoint of improving the feel to damaged hair.
  • the cationic group it is preferable to neutralize a polyurethane resin having a tertiary amine group with an acid or to contain a quaternary ammonium base. Furthermore, from the viewpoint of formulation, the cationic polyurethane resin is preferably blended in the form of an emulsion dispersed in water.
  • the polyurethane resin (B) of the present invention include HEAROL UC-4 (trade name: manufactured by Sanyo Kasei Co., Ltd.), which is a cationic polyurethane resin emulsion. The components of the polyurethane resin are shown below.
  • Noreviset P. U. R. IPDI, dimethylolpropionic acid, isophthalic acid, adipic acid, 2-methylolene 2, 4-pentanediol (hexylene glycol), neopentino glycol
  • Hairol UC—4 IPDI, Butylene glycol, Alkylmethyljetanol ammonium methylsulfate (cationic group)
  • the number average molecular weight of the polyurethane resin is usually 10,000 or more, preferably 15,000-1, 000,000. GPC analysis was used as a method for measuring the number average molecular weight.
  • the amount of the component is not particularly limited, 0.1 to ordinary hair cosmetic total amount from 01 to 5 weight 0/0, preferably from 0.05 to 3 mass 0/0. Within this range, a firmer feeling can be obtained, and when it exceeds 5% by mass, it may cause a stiff feeling.
  • the hair cosmetic composition of the present invention preferably contains one or more selected from (C) polyphenols, polyphenol salts, and polyphenol derivatives.
  • Polyphenols include, for example, gallotannic acid, kebulinic acid, hamamelitannin, azeltannin, gallic acid, baronic acid, kebulic acid, hexahydroxydiphenic acid, ellagic acid, caffeic acid, p-tamaric acid, ferulic acid, sinapinic acid And chlorogenic acid.
  • polyphenol salt examples include the sodium salt, potassium salt, ammonium salt, and triethanolamine salt of the above polyphenol.
  • Polyphenol derivatives include erosion Preference is given to, for example, m-digallic acid, dehydrodigallic acid, gallic acid methyl ester 3-dalcoside, gallic acid methyl ester 4 dalcoside, gallic acid propyl ester 3-dalcoside, gallic acid methyl ester 3-maltoside, Gallic acid 3-Dalcoside, Gallic acid 3-Maltoside, Octyl gallate 3-Maltoside, Gallic acid 3-Daluronide, Galate thulonide gallate, Methyl gallate 3,5-Didarcoside, Gallic acid 3, 4-Zydarcoside, Gallic acid Acid 3,5--Didalcoside, 4-galactosamino gallic acid, 4 darcosamino gallic acid, 3-galactosamino gallic acid, 3--darcosamino gallic acid, 3--darcos
  • gallic acid disaccharides such as gallic acid methyl ester 3,5-didarcoside, gallic acid 3,4-didarcoside, gallic acid 3,5-didarcoside, etc. due to the supply of raw gallic acid and ease of production
  • gallic acid disaccharides such as gallic acid methyl ester 3,5-didarcoside, gallic acid 3,4-didarcoside, gallic acid 3,5-didarcoside, etc. due to the supply of raw gallic acid and ease of production
  • a gallic acid derivative containing a sugar residue having an amino group or an amide group such as dalcosamino gallic acid has, for example, a gallic acid ester having a corresponding amino group or amide group. It can be obtained with the force S obtained by hydrolyzing the alkyl group after reacting with the o-alkylated sugar.
  • a gallic acid derivative containing a glyceryl group such as 4-glyceryl gallic acid
  • the dihydroxylation method include a method in which olefin is directly dihydroxylated with osmium oxide, a method in which an epoxy compound is used as an intermediate using a peroxide of an organic acid, and the ring is opened.
  • an organic acid such as formic acid or peracetic acid
  • olefins are oxidized and then reacted with the organic acid to form a mixture of esteno-dihydroxyl compounds.
  • the target compound When these compounds are subjected to hydrolysis without isolation or purification, the target compound can be obtained.
  • An olefin compound as an intermediate can be obtained by reacting a gallic acid ester with allyl bromide in the presence of a base.
  • a method of hydrolysis of gallic acid ester there are a method of treating with basic water and a method of treating with acidic water.
  • the amount of component (C) is not particularly limited, but is usually 0.00;! To 5% by mass, more preferably 0.0;! To 3% by mass, based on the total amount of hair cosmetics. . Within this range, more damage repair effect can be obtained, and in the range exceeding 5% by mass, it may be difficult to control the coloring specific to polyphenols.
  • the hair cosmetic of the present invention includes one or more kinds of various components generally used in cosmetics, quasi-drugs, pharmaceuticals, etc., as long as the effects of the present invention are not impaired. Or two or more kinds can be combined in an appropriate combination.
  • examples of such components include ayuionic surfactants, cationic surfactants, amphoteric surfactants, noionic surfactants, fats and oils, polymer compounds, amino acids, polyhydric alcohols and the like.
  • anionic surfactant examples include sodium ⁇ -olefin sulfonate, potassium a-olefin sulfonate, sodium stearate, sodium palmitate, sodium laurate, sodium coconut oil fatty acid, stearin.
  • Examples of cationic surfactants include stearyl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, behenyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride, dioleyl dimethyl ammonium chloride. , Didecyldimethyl ammonium chloride, amide butyl dandanine acetate laurate, amido butyl dandanidine acetate myristate amide butyl dandanidine acetate, distearyl dimethyl ammonium sulfate, ⁇ coconut oil fatty acid L arginine cetyl DL pyrrolidone carboxylic acid Examples include salts.
  • Amphoteric surfactants include: 2 alkyl ⁇ ⁇ ⁇ ⁇ ⁇ carboxyethyl ⁇ hydroxy ethyl imidazolium betaine, coconut oil fatty acid amide propyl betaine, lauric acid amide propyl betaine, lauryl dimethylamino acetate betaine, hydrogenated Examples include soybean phospholipid, alkyldiaminoethylglycine hydrochloride, ⁇ - [3 alkyloxy-2-hydroxypropyl] -L-arginine hydrochloride, sodium laurylaminopropionate, and the like.
  • Nonionic surfactants include sucrose fatty acid ester, sorbitan fatty acid ester, sorbitol fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene phytosterol ether, polyoxy Ethylene polyoxypropylene alkyl ether, polyoxyethylene polyoxypropylene phytosterol ether, hydrogenated castor oil, hydrogenated castor oil fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyethylene polyoxypropylene hydrogenated castor oil, polyoxyethylene hydrogenated castor Examples include oil fatty acid esters and polyoxyethylene polyoxypropylene hardened castor oil fatty acid esters.
  • Oils and fats include isopropyl myristate, isopropyl palmitate, ethyl oleate, octyldodecyl neopentanoate, butyloctyl salicylate, and styrene stearate.
  • Lesteryl polyoxyethylene, liquid paraffin, liquid isoparaffin, squalene, squall, castor oil, jojoba oil, hazelnut oil, sweet almond oil, grape seed oil, southern power oil, safflower oil, olive oil, meadow home oil, Examples include rosehip oil and avogado oil.
  • polymer compound examples include hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, cationized cellulose, polybutylpyrrolidone, polyvinyl alcohol, acrylic acid / methacrylic acid copolymer, carboxybule polymer, and the like.
  • amino acids include glycine, ornithine, methionine, alanine, arginine, glutamine, cysteine, cysteic acid, cystine, leucine, isoleucine, aspartic acid, lysine, and fualarayun.
  • polyhydric alcohol examples include propylene glycol, dipropylene glycol, glycerin, butylene glycol and the like.
  • preservatives such as paraoxybenzoate and noroxybenzoate, sequestering agents such as edetate, pyrophosphate, kenate, glycolic acid and tartaric acid, liquefied petroleum gas, dimethyl ether, nitrogen, Gases such as carbon dioxide, antioxidants such as dibutylhydroxytoluene, butylhydroxyanisole, erythorbic acid, dilauryl thiodipropionate, sodium sulfate, sodium sulfite, tocopherol, and ascorbyl dipalmitate, p-aminobenzoate Ultraviolet absorbers such as acid derivatives, salicylic acid derivatives, cinnamic acid derivatives, oxybenzone, dioxybenzone, dihydroxydimethoxybenzophenone, pH adjusters, vitamins, dyes, 1 menthol and its derivatives, etc. Add a sticky agent, water, solvent (ethanol etc.) That power S.
  • sequestering agents such as edetate,
  • the fragrance composition used in the hair cosmetic composition of the present invention is a hair cosmetic composition when blended with a fragrance composition according to the fragrance compositions A to E described in JP-A-2003-095895. It is preferable that the fragrance composition is blended so that the amount of the fragrance composition is 0.00001 to 10% by mass, and more preferably 0.000;! To 5% by mass. Moreover, dibutylhydroxytoluene (BHT), which is an antioxidant, can be blended with these fragrance compositions A to E to enhance the stability of the fragrance.
  • BHT dibutylhydroxytoluene
  • the hair cosmetic composition of the present invention is obtained by mixing the above-described components with water and / or ethanol (the remainder is blended so that the total amount of the hair cosmetic composition is 100% by mass) and obtained based on a conventional method.
  • the dosage form is not particularly limited, and can be used as various dosage forms such as a solubilizing system, an emulsifying system, a dispersing system, and an oil-water two-layer system.
  • a liquid, an aerosol, a tick, a genere, a cream can be used in dosage forms such as lotions.
  • the hair cosmetic of the present invention is used as a hair cosmetic for hair milk, hair care jewel, hair foam, hair cream, hair tonic, hair liquid, hair lotion, hair spray, shampoo, rinse, conditioner, treatment, etc. it can.
  • Hair cosmetics such as shampoos, rinses, conditioners, treatments, etc., are used after washing, and hair amino lects, hair care jewels, hair foams, hair creams, hair tonics, hair liquids, hair lotions, hair Examples include sprays and leave-on type hair treatments that are used without being washed away after application (leave-on type). In the present invention, it is suitable for those used without being washed away after application (leave-on type).
  • a container In the case of using a container, there are no particular restrictions on the material and shape of the container. Polypropylene, polyethylene terephthalate, polyethylene, Eval, laminated containers of these, laminated containers with aluminum foil layers, tinplate, etc. Commonly used containers such as a type container, a pump type container, an aerosol container, a tube type container, a swing-out type container, a roll-on container, a jar container, a pillow pack, a portion container and a capsule can be used.
  • the hair cosmetic composition of the present invention is suitable for thin and soft hair damaged and weakened by coloring or permanent chemical treatment from the viewpoint of its effect. It is suitable as.
  • % of the composition indicates mass%, and when the raw material in the table is a diluted product, it indicates the blending amount (%) as the diluted product.
  • hair cosmetics are shown below, all of which are “harshness”, “goodness of fingers”, “softness”, “no squeakiness”, “no stickiness”, The evaluation of “no stickiness” was good.
  • composition% Chitosan solution 1 1.0
  • Polyurethane resin emulsion 1 1.0 0 Gallic acid 3, 5-diglucoside 0.5
  • phytosterol 1.0 benyltrimethyl ammonium chloride 0.2 benzyloxyethanol 0.2 rosemary mono extract 0.2 methyl benzoate 0.1. 0 5 Power thione hydrolyzed soy protein 0.1 Hydroxypropyl guar gum 0.2 Cetyltrimethylmonum chloride 0.2 oxybenzone 0.5 Perfume D 0.2 Dibutyl hydroxytoluene 0 0 0 1 Purified water Remainder a ⁇ 1 0 0 .0 [Example 13]
  • Hydroxyl mouth pill 'chitosan solution 0.5 Polyurethane resin emulsion 1 2 .0 Gallic acid 3,5-didarcoside 0.05 Cholesteryl isostearate 2.0 Hydroxybenzophenone 0.1 Isisostearyl myristate 1.0 Amino-modified silicone emulsion 20.5 Stearyl trimethylammonium chloride 1.0 Steari / Rare / Reco / Re 3.0 Polyoxyethylene (20E. O.) hydrogenated castor oil 1.0 Propylene glycol "5.0 Glycerin 'Furactic acid lactic acid 0.1 Benzenorea / reco-monore 0.1 fragrance D 0.1 Balance of purified water a at 1 00 .0 [Example 14]
  • E'Hydroxyethylene hydrogenated castor oil EMALEX HC series "Day; ⁇ : Emulsy Yon ():” Human Roxy ", Gamma, 7 Emsaw 100 ° 7 ° Kasei Co., Ltd. p sodium phosphate Mouth Sodium Phosphate Taihei Chemical Industry Co., Ltd.
  • ethyl acetate was added to the aqueous layer for re-extraction and combined with the previous ethyl acetate layer.
  • This organic layer was washed sequentially with 20 mL of water, 20 mL of aqueous sodium bicarbonate, and 20 mL of aqueous sodium bisulfite solution, and then this organic layer was washed until the aqueous layer became neutral while adjusting the pH with an aqueous sodium hydroxide solution. .

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Abstract

L'utilisation d'une combinaison (A) d'un composé de chitosan et (B) d'une résine de polyuréthane permet d'obtenir un produit cosmétique capillaire qui peut conférer une tension et une élasticité à des cheveux fins et mous ayant été endommagés et affaiblis par un traitement chimique tel qu'une coloration ou une permanente, qui assure un fini souple avec une sensation de douceur au toucher et aucune sensation de rudesse, qui régule l'aspect gras et la rugosité, et permet ainsi d'obtenir une texture favorable des cheveux.
PCT/JP2007/067169 2006-09-21 2007-09-04 Cosmétique capillaire WO2008035563A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2008535309A JPWO2008035563A1 (ja) 2006-09-21 2007-09-04 毛髪化粧料
CN2007800301011A CN101500536B (zh) 2006-09-21 2007-09-04 毛发化妆品

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Application Number Priority Date Filing Date Title
JP2006255475 2006-09-21
JP2006-255475 2006-09-21

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WO2008035563A1 true WO2008035563A1 (fr) 2008-03-27

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010235470A (ja) * 2009-03-30 2010-10-21 Lion Corp 洗い流さない毛髪化粧料
JP2010275285A (ja) * 2009-05-26 2010-12-09 Sanei Kagaku Kk 洗い流さない毛髪化粧料
JP2010275286A (ja) * 2009-05-26 2010-12-09 Sanei Kagaku Kk 洗い流さない毛髪化粧料
JP2011529938A (ja) * 2008-08-04 2011-12-15 ポリケム・エスエイ 頭髪および頭皮に薬剤を放出するための被膜形成性の液体製剤
JP2014080391A (ja) * 2012-10-17 2014-05-08 Maruzen Pharmaceut Co Ltd 毛髪損傷の予防又は抑制剤
WO2014185461A1 (fr) * 2013-05-15 2014-11-20 ライオン株式会社 Composition d'agents de croissance capillaire
JPWO2014196562A1 (ja) * 2013-06-06 2017-02-23 凸版印刷株式会社 針状体
KR20190140039A (ko) * 2017-04-28 2019-12-18 로레알 폴리우레탄 라텍스 중합체 및 증점제를 포함하는 모발-트리트먼트 조성물
WO2020171002A1 (fr) 2019-02-19 2020-08-27 株式会社Adeka Polyuréthane pour des préparations cosmétiques et procédé pour la production de polyuréthane pour des préparations cosmétiques

Families Citing this family (2)

* Cited by examiner, † Cited by third party
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004285043A (ja) * 2003-03-03 2004-10-14 Pola Chem Ind Inc カチオン化ウレタン樹脂を含有する化粧料。
JP2005206573A (ja) * 2003-12-22 2005-08-04 Nippon Fine Chem Co Ltd ジエステル及び油剤、並びに化粧料及び皮膚外用剤
JP2006515021A (ja) * 2003-02-03 2006-05-18 ロレアル ヒドロゲル化イオン性アミドおよび髪に有益なポリマーを含有する化粧品組成物
JP2006143695A (ja) * 2003-11-18 2006-06-08 L'oreal Sa ゲランガム又はその誘導体、固定ポリマー、１価の塩及びアルコールを含む化粧組成物、該組成物の使用方法及びその使用

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1201067A (zh) * 1997-05-30 1998-12-09 延边五星化工有限公司 黄瓜香皂及其制备方法
FR2815350B1 (fr) * 2000-10-17 2006-12-29 Oreal Polyurethanes cationiques a caractere elastique
JP2004035529A (ja) * 2002-06-28 2004-02-05 Lion Corp ケラチン繊維細胞膜複合体補修剤
FR2863884B1 (fr) * 2003-12-19 2007-06-29 Oreal Composition coiffante comprenant, dans un milieu majoritairement aqueux, un polyurethane cationique elastique, procedes la mettant en oeuvre et utilisations

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006515021A (ja) * 2003-02-03 2006-05-18 ロレアル ヒドロゲル化イオン性アミドおよび髪に有益なポリマーを含有する化粧品組成物
JP2004285043A (ja) * 2003-03-03 2004-10-14 Pola Chem Ind Inc カチオン化ウレタン樹脂を含有する化粧料。
JP2006143695A (ja) * 2003-11-18 2006-06-08 L'oreal Sa ゲランガム又はその誘導体、固定ポリマー、１価の塩及びアルコールを含む化粧組成物、該組成物の使用方法及びその使用
JP2005206573A (ja) * 2003-12-22 2005-08-04 Nippon Fine Chem Co Ltd ジエステル及び油剤、並びに化粧料及び皮膚外用剤

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JP2011529938A (ja) * 2008-08-04 2011-12-15 ポリケム・エスエイ 頭髪および頭皮に薬剤を放出するための被膜形成性の液体製剤
JP2010235470A (ja) * 2009-03-30 2010-10-21 Lion Corp 洗い流さない毛髪化粧料
JP2010275285A (ja) * 2009-05-26 2010-12-09 Sanei Kagaku Kk 洗い流さない毛髪化粧料
JP2010275286A (ja) * 2009-05-26 2010-12-09 Sanei Kagaku Kk 洗い流さない毛髪化粧料
JP2014080391A (ja) * 2012-10-17 2014-05-08 Maruzen Pharmaceut Co Ltd 毛髪損傷の予防又は抑制剤
JPWO2014185461A1 (ja) * 2013-05-15 2017-02-23 ライオン株式会社 育毛剤組成物
KR20160021427A (ko) * 2013-05-15 2016-02-25 라이온 가부시키가이샤 육모제 조성물
WO2014185461A1 (fr) * 2013-05-15 2014-11-20 ライオン株式会社 Composition d'agents de croissance capillaire
KR102164151B1 (ko) 2013-05-15 2020-10-12 라이온 가부시키가이샤 육모제 조성물
JPWO2014196562A1 (ja) * 2013-06-06 2017-02-23 凸版印刷株式会社 針状体
JP2019006798A (ja) * 2013-06-06 2019-01-17 凸版印刷株式会社 針状体
KR20190140039A (ko) * 2017-04-28 2019-12-18 로레알 폴리우레탄 라텍스 중합체 및 증점제를 포함하는 모발-트리트먼트 조성물
JP2020517728A (ja) * 2017-04-28 2020-06-18 ロレアル ポリウレタンラテックスポリマー及び増粘剤を含むヘアトリートメント組成物
KR102339211B1 (ko) 2017-04-28 2021-12-13 로레알 폴리우레탄 라텍스 중합체 및 증점제를 포함하는 모발-트리트먼트 조성물
JP7158411B2 (ja) 2017-04-28 2022-10-21 ロレアル ポリウレタンラテックスポリマー及び増粘剤を含むヘアトリートメント組成物
WO2020171002A1 (fr) 2019-02-19 2020-08-27 株式会社Adeka Polyuréthane pour des préparations cosmétiques et procédé pour la production de polyuréthane pour des préparations cosmétiques
KR20210132063A (ko) 2019-02-19 2021-11-03 가부시키가이샤 아데카 화장료용 폴리우레탄 및 화장료용 폴리우레탄의 제조 방법

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