WO2006130150A3 - Functionalized single walled carbon nanotubes - Google Patents

Functionalized single walled carbon nanotubes Download PDF

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Publication number
WO2006130150A3
WO2006130150A3 PCT/US2005/022413 US2005022413W WO2006130150A3 WO 2006130150 A3 WO2006130150 A3 WO 2006130150A3 US 2005022413 W US2005022413 W US 2005022413W WO 2006130150 A3 WO2006130150 A3 WO 2006130150A3
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WO
WIPO (PCT)
Prior art keywords
walled carbon
nanotubes
functionalized
single walled
carbon nanotubes
Prior art date
Application number
PCT/US2005/022413
Other languages
French (fr)
Other versions
WO2006130150A2 (en
WO2006130150A9 (en
Inventor
Robert Hoch
Alan Fischer
Howard Tennent
Original Assignee
Hyperion Catalysis Int
Robert Hoch
Alan Fischer
Howard Tennent
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hyperion Catalysis Int, Robert Hoch, Alan Fischer, Howard Tennent filed Critical Hyperion Catalysis Int
Priority to EP05857879A priority Critical patent/EP1776125A4/en
Priority to AU2005332329A priority patent/AU2005332329A1/en
Priority to CA002571575A priority patent/CA2571575A1/en
Priority to JP2007519302A priority patent/JP2008513318A/en
Publication of WO2006130150A2 publication Critical patent/WO2006130150A2/en
Publication of WO2006130150A3 publication Critical patent/WO2006130150A3/en
Publication of WO2006130150A9 publication Critical patent/WO2006130150A9/en

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/168—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/003—Catalysts comprising hydrides, coordination complexes or organic compounds containing enzymes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B01J21/185—Carbon nanotubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B1/00—Nanostructures formed by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B82B1/008—Nanostructures not provided for in groups B82B1/001 - B82B1/007
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B82B3/0061—Methods for manipulating nanostructures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B82B3/0095—Manufacture or treatments or nanostructures not provided for in groups B82B3/0009 - B82B3/009
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/168—After-treatment
    • C01B32/174—Derivatisation; Solubilisation; Dispersion in solvents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/041—Carbon nanotubes
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
    • D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
    • D01F11/12—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with inorganic substances ; Intercalation
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
    • D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
    • D01F11/14—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with organic compounds, e.g. macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/02—Single-walled nanotubes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/20—Nanotubes characterized by their properties
    • C01B2202/36—Diameter
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Abstract

Graphitic nanotubes, which includes tubular fullerenes (commonly called 'buckytubes') and fibrils, which are functionalized by chemical substitution or by adsorption of functional moieties. More specifically the invention relates to single walled carbon nanotubes having diameters than 5 nanometers which are uniformly or non-uniformly substituted with chemical moieties or upon which certain cyclic compounds are adsorbed and to complex structures comprised of such functionalized nanotubes linked to one another. The invention also relates to methods for introducing functional groups onto the surface of such nanotubes. The invention further relates to uses for functionalized single walled carbon nanotubes.
PCT/US2005/022413 2004-06-23 2005-06-23 Functionalized single walled carbon nanotubes WO2006130150A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP05857879A EP1776125A4 (en) 2004-06-23 2005-06-23 Functionalized single walled carbon nanotubes
AU2005332329A AU2005332329A1 (en) 2004-06-23 2005-06-23 Functionalized single walled carbon nanotubes
CA002571575A CA2571575A1 (en) 2004-06-23 2005-06-23 Functionalized single walled carbon nanotubes
JP2007519302A JP2008513318A (en) 2004-06-23 2005-06-23 Functionalized single-walled carbon nanotubes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US87543504A 2004-06-23 2004-06-23
US10/875,435 2004-06-23

Publications (3)

Publication Number Publication Date
WO2006130150A2 WO2006130150A2 (en) 2006-12-07
WO2006130150A3 true WO2006130150A3 (en) 2009-04-16
WO2006130150A9 WO2006130150A9 (en) 2009-06-11

Family

ID=37482092

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/022413 WO2006130150A2 (en) 2004-06-23 2005-06-23 Functionalized single walled carbon nanotubes

Country Status (7)

Country Link
EP (1) EP1776125A4 (en)
JP (1) JP2008513318A (en)
KR (1) KR20070030282A (en)
CN (1) CN101432227A (en)
AU (1) AU2005332329A1 (en)
CA (1) CA2571575A1 (en)
WO (1) WO2006130150A2 (en)

Cited By (4)

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US9090472B2 (en) 2012-04-16 2015-07-28 Seerstone Llc Methods for producing solid carbon by reducing carbon dioxide
US9221685B2 (en) 2012-04-16 2015-12-29 Seerstone Llc Methods of capturing and sequestering carbon
US9556031B2 (en) 2009-04-17 2017-01-31 Seerstone Llc Method for producing solid carbon by reducing carbon oxides
US9598286B2 (en) 2012-07-13 2017-03-21 Seerstone Llc Methods and systems for forming ammonia and solid carbon products

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JP2008534425A (en) 2005-03-29 2008-08-28 ハイピリオン カタリシス インターナショナル インコーポレイテッド Method for producing single-walled carbon nanotubes from a metal layer
US7947247B2 (en) 2005-03-29 2011-05-24 Hyperion Catalysis International, Inc. Method for preparing single walled carbon nanotubes from a metal layer
EP2001795A4 (en) 2006-03-29 2012-06-27 Hyperion Catalysis Int Method for preparing uniform single walled carbon nanotubes
WO2008156021A1 (en) * 2007-06-21 2008-12-24 National University Corporation Nagoya University Method for introducing foreign substance into cell having cell wall
KR100936167B1 (en) * 2009-05-29 2010-01-12 한국과학기술원 Carbon nanotube bulk material and fabricating method thereof
US8435931B2 (en) 2009-07-17 2013-05-07 Exxonmobil Research And Engineering Company Reduced friction lubricating oils containing functionalized carbon nanomaterials
US8841454B2 (en) 2009-07-17 2014-09-23 Exxonmobil Research And Engineering Company Functionalized carbon nanostructures which are soluble in hydrocarbons and method for preparation
CN102741163B (en) * 2010-02-04 2014-06-11 独立行政法人科学技术振兴机构 Process for production of selectively chemically modified carbon nano-tube
CN102335434A (en) * 2010-07-23 2012-02-01 复旦大学 Targeting carbon nanotube drug carrier with specific monoclonal antibody and its preparation method
KR101281733B1 (en) * 2010-11-18 2013-07-04 한국과학기술원 Methods for the preparation of carbon nanotubes covalentely modified by poly(aryleneether)s
JP5429893B2 (en) * 2011-11-02 2014-02-26 独立行政法人物質・材料研究機構 Preparation of bioreactive carbon nanotubes by functionalizing redox proteins by non-covalent bonding
NO2749379T3 (en) 2012-04-16 2018-07-28
CN104284861A (en) 2012-04-16 2015-01-14 赛尔斯通股份有限公司 Methods for treating offgas containing carbon oxides
CN104271498B (en) 2012-04-16 2017-10-24 赛尔斯通股份有限公司 The method and structure of oxycarbide is reduced with non-iron catalyst
US9896341B2 (en) 2012-04-23 2018-02-20 Seerstone Llc Methods of forming carbon nanotubes having a bimodal size distribution
US10815124B2 (en) 2012-07-12 2020-10-27 Seerstone Llc Solid carbon products comprising carbon nanotubes and methods of forming same
US9604848B2 (en) 2012-07-12 2017-03-28 Seerstone Llc Solid carbon products comprising carbon nanotubes and methods of forming same
US9779845B2 (en) 2012-07-18 2017-10-03 Seerstone Llc Primary voltaic sources including nanofiber Schottky barrier arrays and methods of forming same
CN104936893A (en) 2012-11-29 2015-09-23 赛尔斯通股份有限公司 Reactors and methods for producing solid carbon materials
WO2014150944A1 (en) 2013-03-15 2014-09-25 Seerstone Llc Methods of producing hydrogen and solid carbon
WO2014151119A2 (en) 2013-03-15 2014-09-25 Seerstone Llc Electrodes comprising nanostructured carbon
WO2014151898A1 (en) 2013-03-15 2014-09-25 Seerstone Llc Systems for producing solid carbon by reducing carbon oxides
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EP3113880A4 (en) 2013-03-15 2018-05-16 Seerstone LLC Carbon oxide reduction with intermetallic and carbide catalysts
KR102095282B1 (en) * 2015-12-31 2020-04-01 기초과학연구원 Photoluminescent Carbon Nano-structure and Fabrication Method Thereof
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US11752459B2 (en) 2016-07-28 2023-09-12 Seerstone Llc Solid carbon products comprising compressed carbon nanotubes in a container and methods of forming same
CN106809817B (en) * 2017-01-16 2019-01-11 东华大学 A kind of preparation method of porous carbon nanotube
CN106841344B (en) * 2017-04-07 2018-12-11 西北师范大学 The preparation and application of a kind of poroid single-walled carbon nanotube and its modified electrode
US10865502B2 (en) 2018-05-14 2020-12-15 Global Graphene Group, Inc. Continuous graphene fibers from functionalized graphene sheets
US10927478B2 (en) 2018-05-21 2021-02-23 Global Graphene Group, Inc. Fabric of continuous graphene fiber yarns from functionalized graphene sheets
US10934637B2 (en) 2018-05-21 2021-03-02 Global Graphene Group, Inc. Process for producing fabric of continuous graphene fiber yarns from functionalized graphene sheets
CN108636363B (en) * 2018-05-25 2019-12-27 湖南大学 Glutamic acid modified carbon nanotube composite material and preparation method and application thereof
CN110564016B (en) * 2019-08-27 2022-06-14 山东大展纳米材料有限公司 High-reinforcement rubber latex wet mixing composite material and preparation process thereof
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9556031B2 (en) 2009-04-17 2017-01-31 Seerstone Llc Method for producing solid carbon by reducing carbon oxides
US9090472B2 (en) 2012-04-16 2015-07-28 Seerstone Llc Methods for producing solid carbon by reducing carbon dioxide
US9221685B2 (en) 2012-04-16 2015-12-29 Seerstone Llc Methods of capturing and sequestering carbon
US9598286B2 (en) 2012-07-13 2017-03-21 Seerstone Llc Methods and systems for forming ammonia and solid carbon products

Also Published As

Publication number Publication date
EP1776125A4 (en) 2012-01-25
CN101432227A (en) 2009-05-13
WO2006130150A2 (en) 2006-12-07
EP1776125A2 (en) 2007-04-25
JP2008513318A (en) 2008-05-01
AU2005332329A1 (en) 2006-12-07
CA2571575A1 (en) 2006-12-07
WO2006130150A9 (en) 2009-06-11
KR20070030282A (en) 2007-03-15

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