WO2003040420A1 - Sintered diamond having high thermal conductivity and method for producing the same and heat sink employing it - Google Patents
Sintered diamond having high thermal conductivity and method for producing the same and heat sink employing it Download PDFInfo
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- WO2003040420A1 WO2003040420A1 PCT/JP2002/010747 JP0210747W WO03040420A1 WO 2003040420 A1 WO2003040420 A1 WO 2003040420A1 JP 0210747 W JP0210747 W JP 0210747W WO 03040420 A1 WO03040420 A1 WO 03040420A1
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Definitions
- the present invention relates to a highly thermally conductive sintered body mainly composed of diamond having excellent characteristics as a heat sink for an electronic device such as a semiconductor laser or a high-performance MPU (microprocessing unit), a method for manufacturing the same, and a method for sintering the same. It relates to a heat sink using a union.
- heat dissipation is very important to prevent malfunctions due to heat generated by the devices themselves.
- a heat radiating substrate heat sink
- solder solder
- A1N sintered body aluminum nitride (A1N) or silicon carbide (SiC) has been mainly used.
- SiC sintered body As the output of semiconductor lasers increases and the integration of MPUs increases, the amount of heat generated from the elements also increases.
- the thermal conductivity of A1N sintered body and SiC sintered body is respectively 250 W / mK and 270 W / mK at best, and these values are insufficient for heat dissipation. Things are happening.
- a material consisting of (cubic boron nitride) is conceivable.
- diamond has recently become industrialized due to the progress of manufacturing technology by the CVD method using hydrocarbon gas such as methane gas as a raw material and the ultra-high pressure method of converting and growing solid carbon materials such as graphite under ultra-high pressure and high temperature. Stable production is also possible.
- c BN can be produced by converting and sintering the allotropic form of hBN (hexagonal boron nitride) under ultra-high pressure and high temperature.
- the metal-diamond composite disclosed in Japanese Unexamined Patent Application Publication No. 2-1745052 is a diamond particle embedded in at least one metal matrix selected from the group consisting of copper, silver, gold and aluminum. It is characterized by having a thermal expansion coefficient substantially the same as that of a semiconductor in a composite body comprising:
- metals such as copper, silver, gold and aluminum and diamond have very poor wettability and do not form carbides, a small amount of pores remain even when a mixture of these metals and diamond is heated and sintered.
- diamond particles on the processed surface fall off.
- the pores of the composite have a negative effect on its own thermal conductivity.
- there is a problem that the diamond particles fall off during processing because the thermal contact at the time of joining the heat sink and the semiconductor is poor and a predetermined heat radiation effect cannot be obtained.
- the metal-diamond composite disclosed in Japanese Unexamined Patent Publication No. 4-259305 is a method in which a powder mixture of a powder of at least one of aluminum, magnesium, copper, and silver and a diamond powder is heated under pressure. And sinter.
- conventional methods such as vacuum hot pressing and powder metallurgy are disclosed in
- the metal-diamond composites disclosed in Japanese Patent Application Laid-Open Nos. 10-22 / 1991 and 11-697991 are disclosed in Japanese Patent Application Laid-Open Nos.
- a metal carbide is formed on the surface of the diamond to improve the adhesion at the interface between the metal and the diamond, thereby improving the properties of the composite.
- a metal carbide as an impurity has an adverse effect on the thermal conductivity, so that a higher thermal conductivity cannot be obtained as compared with a sintered body composed of only copper and diamond.
- the above-mentioned technology discloses melting of metal powder mixed with diamond particles, hot press sintering, ultra-high pressure sintering, and the like.
- the ultra-high pressure / high temperature sintering method is most suitable for obtaining a composite substantially free of pores, which is the object of the present invention.
- the ultra-high pressure and high temperature sintering method has been adopted as a method for producing a sintered body for a tool mainly composed of diamond, and uses a ferrous metal such as C0 as a binder. Iron group metals have the effect of dissolving and precipitating carbon atoms under ultra-high pressure and high temperature.
- the coefficient of thermal expansion of the manufactured sintered body does not become much larger than the coefficient of thermal expansion of diamond.
- the thermal conductivity is about 400 W / m ⁇ K due to the effect of the binder having low thermal conductivity.
- Japanese Patent Publication No. 55-8447, Japanese Patent Publication No. 56-146463, etc. Alternatively, a method is disclosed in which a copper alloy is supplied adjacently into a cubicle.
- This method provides a method of making a Daiyamondo sintered body of a non-magnetic by substituting part of the binder in the copper, however, in processing the capsules under ultra-high pressure and high temperature in this way, Since the capsule is partially torn, the problem of oxidizing copper is inevitable, although it is very small. Therefore, cuprous (C u 2 0) oxidation shown Sutori trace X-ray diffraction results of the sintered body of FIG. 1, cupric oxide (C u O) is present.
- a sintered body having a high thermal conductivity of 500 W / m ⁇ K cannot be obtained due to fine particles due to damage and oxidation of copper.
- the conventional technology combines high thermal conductivity with a thermal expansion coefficient close to that of semiconductor materials, and has a high-power semiconductor laser with high surface quality after processing.
- An object of the present invention is to have a thermal conductivity of 500 W / mK or more, which is higher than the thermal conductivity of A1N or SIC sintered body, and a thermal expansion coefficient of 3.0 to 6.5.
- X 1 0- 5 / K and I eta [rho and G a a s is to provide a material close to the material for semiconductor devices. Disclosure of the invention
- the present inventors sinter diamond with a theoretical thermal conductivity of 2000 W / mK, the highest thermal conductivity among materials, using copper as a binder in the method disclosed in the present invention. it makes found that 5 0 0 3 simultaneously with WXM ⁇ K or more high thermal conductivity. 0 to 6.5 diamond sintered body having a thermal expansion coefficient of X 1 0- 6 / K is obtained.
- the present invention has been achieved based on such findings, and the particulars of the invention include diamond particles having no pores therein and having a particle size distribution peak of 5 ⁇ or more and 100 m or less. It is contained in an amount of 60% by volume or more and 90% by volume or less with respect to the whole sintered body, and the balance is substantially made of copper, and at least a plurality of diamond particles among the diamond particles constituting the sintered body are in direct contact with each other.
- High thermal conductivity characterized in that copper which is bonded to the sintered body is not substantially oxidized and the amount of oxygen in the sintered body is not more than 0.025% by weight. It is in a diamond sintered body.
- L which substantially does not contain pores
- sintered body means those containing pores having a porosity of about 0.5% or less.
- sintering is performed as described later.
- GP is performed at a pressure of at least a.
- the sintered body preferably has a thermal conductivity of 500 W / m ⁇ K or more and 1500 W / m ⁇ K or less.
- Figure 1 shows the results of X-ray diffraction analysis of a sintered body produced by the conventional method using Cu K as a light source.
- FIG. 2 is a conceptual diagram illustrating the wettability of the interface between a solid and a liquid.
- FIG. 3 is a result of observing the sintered body produced by the method of the present invention by TEM.
- FIG. 4 shows the result of analyzing the sintered body produced according to the example of the present invention by X-ray diffraction using Cu K as a light source.
- Fig. 5 shows the relationship between diamond content and coefficient of thermal expansion.
- FIG. 6 shows a capsule configuration diagram used in the first embodiment.
- FIG. 7 is a schematic cross-sectional view showing a semiconductor laser device mounted on a heat sink prepared in Example 5.
- FIG. 6 is a schematic view showing a configuration of a capsule used in Example 1 described later, in which a green compact comprising a mixed powder of diamond powder and copper powder according to the present invention is mounted.
- the container is sealed with a molybdenum lid.
- 1 is a molybdenum lid
- 2 is a molybdenum capsule
- 3 is a filler
- 4 is a titanium plate
- 5 is a niobium plate
- 6 is a green compact.
- ⁇ 1 is a diamond-copper composite sintered body
- 2 is a semiconductor laser element
- 3 is an active layer of a semiconductor laser element
- 4 is a first metal coating layer (nickel)
- 5 is a second metal coating.
- Reference numeral 6 denotes a third metal coating layer (gold-tin alloy)
- 7 denotes a brazing material
- 8 denotes a copper base. '' Best mode for carrying out the invention
- High-purity copper has a thermal conductivity of about 400 W / mK, and a material with a thermal conductivity of 400 W / mK or more can be produced by sintering diamond with copper as a binder. Can be inferred. It is also well known that thermal conductivity decreases as copper purity decreases. However, copper does not form carbides and has poor wettability with diamond, so simply mixing diamond and copper and raising the temperature to above the melting point of copper does not result in a dense sintered body. A sintered body can be obtained by coating a diamond-forming metal (ferrous metal, titanium, niobium, vanadium, etc.) or silicon around the diamond and mixing it with copper to raise the temperature above the melting point of copper. However, a sintered body with high thermal conductivity cannot be obtained because the carbide generated around the diamond impedes heat conduction.
- the interface Under normal pressure, the interface has poor wettability and sinters without enclosing the copper melt around diamond. However, under high pressure, the wettability of the interface is improved and the diamond can be wrapped around with a copper melt. Ultra-high pressure of at least 1 GPa is required to produce a sintered body with substantially no pores. However, if the pressure is as low as 1 GPa and the temperature is maintained at a high temperature of 100 ° C or more for a long time, the conversion of diamond to graphite starts, so if possible, the diamond is held in a thermodynamically stable region. It is desirable to sinter with a device that can.
- a specific pressure level it is preferable to maintain the pressure at a pressure of 4 GPa or more, and sinter at a pressure of 4 GPa to 6 GPa using an industrially used ultra-high pressure generator. It is desirable. By performing sintering under these conditions, it is expected that there will be substantially no pores, and that a sintered body will be obtained in which adjacent diamond particles have been partially contacted and bonded. Thus, sintering under an ultra-high pressure of 1 GPa or more enables sintering without any porosity in the sintered body (porosity: 0%). In other words, since the pores in the sintered body are factors that inhibit heat conduction, high thermal conductivity can be achieved by the absence of pores.
- the diamond particles were bonded together as shown in Fig. 3.
- the measured density of the sintered body is consistent with the approximate theoretical value, according to the composition ratio of the diamond and copper, among 5. 7 g / cm 3 from 4. 0 5 g / cm 3 changed.
- the density of the sintered body is preferably set to 4.55 to 5.15 g / cm 3 because the preferable range of the volume ratio of diamond is 70 to 80%.
- the properties of the high thermal conductive diamond sintered body claimed in claims 4 to 6 described below are the same as those of the high thermal conductive diamond sintered body claimed in any of claims 1 to 3. It shows a preferable characteristic value range provided.
- oxygen (copper oxide) in the sintered body also inhibits heat conduction. This is based on the finding that a high thermal conductivity can be realized with an oxygen content of 0.025% by weight or less.
- a powder composed of diamond particles having a particle size of 5 ⁇ m or more and 100 m or less is arranged so as to be in contact with an oxygen-free copper plate, and one of IVa, Va metal or Sealing a metal capsule containing two or more plates in a vacuum, in an inert gas, or in a reducing gas; and sealing the metal capsule to 1 GPa or more and 6 GPa or less, preferably 4 GPa or more. Pressure below 6 GPa, above 110 ° C and below 150 ° C, preferably above 11.0 ° C and above 120,000.
- a method for producing a highly thermally conductive diamond sintered body comprising:
- Factors that affect the thermal conductivity of the diamond-copper composite sintered body produced at ultra-high pressure, sintering at high temperatures in this way include the ratio of diamond to copper, the purity of diamond particles, Impurities, the size of diamond particles, and the like.
- the volume ratio of diamond to copper the higher the proportion of diamond, the higher the thermal conductivity, but the lower the coefficient of thermal expansion. Since the optimum coefficient of thermal expansion differs depending on the type of semiconductor to be mounted, the optimum volume ratio may be determined from the coefficient of thermal expansion within the range disclosed in the present invention, and the method of mixing powder can be controlled by the mixing ratio. Yes, the impregnation method using a copper plate can be controlled by the following particle size distribution of diamond particles. The content of copper increases when the amount of fine particles increases, and the content of copper increases when the amount of coarse particles increases. Tends to decrease.
- the coefficient of thermal expansion of the sintered body is determined by the volume ratio of diamond to copper.
- thermal expansion coefficient of diamond is 2. 3 X 1 0- ⁇ / ⁇
- thermal expansion coefficient of copper is 1 6. 7 9 X 1 0- 6 / ⁇ greatly ⁇ the proportion of copper in the sintered body It is self-evident that the thermal expansion coefficient increases if it is reduced.
- the present inventors have examined the thermal expansion coefficient (X10-K) of a material in which the volume ratio (%) of diamond to copper was changed, and found that the relationship was as shown in FIG. From this relationship, S i as a target, I n P, G a A s such a range of thermal expansion coefficient close to the semiconductor material 3. 0 ⁇ 6.
- the volume content of diamond and copper can be controlled by the particle size of diamond particles, and when copper powder is used as a starting material, it can be controlled by the mixing ratio of diamond and copper.
- At least one set of two or more surfaces facing each other has at least one metal selected from nickel, chromium, titanium, and tantalum, or an alloy thereof. And at least one or more of its outer surfaces covered with at least one metal selected from molybdenum, platinum, gold, silver, silver, lead, germanium, and indium, or an alloy thereof. It is characterized by being done. It is desirable that the outermost surface of the heat sink used for the semiconductor element is coated with a metal having good solderability with the semiconductor element.
- a metal containing at least one selected from the group consisting of nickel, chromium, titanium, and nanta, which are metals having high affinity for diamond is coated on the surface in contact with the heat sink.
- nickel that does not form a compound with copper is preferable because it does not react with copper and deteriorate even when heated.
- the surface in contact with the semiconductor element should be coated with one or more of the metals of molybdenum, platinum, gold, silver, tin, lead, germanium, and indium, which have good solderability, or in multiple layers. Thus, the bonding between the semiconductor element and the heat sink can be ensured.
- the flatness of the surface on which the semiconductor element is mounted is 30 ⁇ m 0 mm or less, and the surface roughness of the surface on which the semiconductor element is mounted is Ra0. 5 / m or less, chipping of at least one ridge line constituting the side of the surface on which the semiconductor element is mounted, and a radius of curvature of the tip of 30 m or less. L, suitable for exhibiting performance.
- Flat surface on which semiconductors are mounted If the temperature exceeds 30 zm for a length of 1 O mm, there will be a gap between the semiconductor element and the heat sink, or a thick brazing material, Heat conduction is worse.
- the surface roughness of the surface on which the semiconductor is mounted exceeds 0.5 m in the arithmetic mean roughness (R a) specified in JISB 0601, the same as in the case of the poor flatness, A gap is created between the element and the heat sink, or a thicker brazing material is formed, resulting in poor heat conduction.
- R a arithmetic mean roughness
- the heat generated in the active layer will not be dissipated to the heat sink.
- the highly thermally conductive diamond sintered body according to the present invention has a thermal conductivity of 500 W / m-K or more and a thermal expansion coefficient of 3.0 to 6.5 by optimizing the components. It was possible to achieve ideal characteristics as heat one sink for I n P and G a a s semiconductor element of X 1 0 one 8 ZK. It goes without saying that this sintered body can be used as a heat sink for a conventional Si device.
- a sintered body material is processed into a predetermined shape and size, and then a metal for bonding to a semiconductor chip is formed. It is necessary to apply a film coating.
- the sintered body material is cut into the shape and dimensions required for a heat sink.
- the cut material is coated with a metal film and used as a heat sink for mounting semiconductors.
- predetermined It is used to mean “required as a product” or “for the purpose required for a product”.
- the surface oxide film is washed with a weakly acidic solution, followed by electrolytic plating, electroless plating, sputtering, ion plating, and vapor deposition.
- the metal film is coated with a seed or a combination thereof, and the cutting can be performed using either discharge wire machining or laser machining.
- the temperature of the grindstone surface is controlled by water-cooling the back surface of the grindstone in order to suppress oxidation of copper in the sintered body. More than 70% of the area polished by this method has flat diamond particles exposed on the surface. Since the surface with the diamond exposed to a large part of the surface cannot be coated with a film having sufficient adhesion strength by ordinary electrolytic plating, the first metal film is formed by the sputtering method. It is preferred to coat. Any of the second and subsequent metal film plating methods, spattering method, and ion plating method may be used.
- the grinding stones remove the diamond particles in the sintered body, and at the same time, are processed while stretching the copper, so that more than 70% of the surface area is covered with copper. State. In this way, when most of the surface is made of copper, normal electrolytic plating is sufficient for adhesion. Is possible.
- this sintered body was sintered under ultra-high pressure and high temperature, but it could not be achieved by conventional sintered diamond by preventing oxidation of copper as a binder.
- High thermal conductivity can be maintained. In normal pressure sintering, the thermal conductivity does not increase because voids are included in the sintered body.
- a metal film is coated after processing into a predetermined shape and dimensions. Is different, and it is necessary to change the coating method of the first layer.
- a commercially available diamond powder having a predetermined particle size shown in Table 1 and copper powder having a purity of 99.9% and a particle size of under 15 m were mixed at the mixing ratio shown in Table 1, and the mixed powder was mixed with a niobium plate. It was filled into a molybdenum container having an inner diameter of 25 mm and a depth of 5 mm together with the titanium plate in the configuration shown in FIG. 6, and pressed with a load of 2 t / cm 2 to obtain a green compact having a thickness of 2 mm.
- the container equipped with the green compact was covered with a molybdenum lid via a brazing material, and heated in a vacuum to seal and seal the container and the lid.
- Comparative examples 1 to 16 shown in Table 1 were prepared in the same process as those having a diamond particle diameter of less than 5 m, vacuum sealing, and a diamond particle diameter of 5 to 100 without a titanium plate. Shown in
- Table 1 summarizes the results of measuring the thermal conductivity, coefficient of thermal expansion, and density of each diamond particle size.
- both the copper powder compounding ratio and the copper content indicate volume% with respect to the whole sintered body.
- the density can be calculated theoretically by the mixing ratio of copper and diamond. Table 1 illustrates this.
- Table 2 summarizes the results of measuring the thermal conductivity, coefficient of thermal expansion, and density of each diamond particle size. At the same time, a table in which the weight% of copper was analyzed by emission spectroscopy and converted into a volume content is shown.
- Example 2 After the sintered body produced in Example 1 was processed by electric discharge machining to a thickness of 0.5 mm, both surfaces were rubbed with a # 400 diamond grindstone. The rubbed sintered body was cut into a size of 3 mm ⁇ 1 mm using a YAG laser with a power of 3 W. Table 3 shows the results of measurement of the chipping of the cut end after cutting and the surface roughness of the lapping. Similarly, as comparative examples, diamond particle diameters of 110 / zm (comparative sample 14) and 130 zm (comparative sample 15) were sintered in the same manner as in Example 1 and processing tests were performed. I also show it. ⁇ 5 O £ 3 ⁇ 4
- the ⁇ ⁇ 11 sintered body prepared in Example 1 was processed to a thickness of about 0.5 mm by electric discharge machining, and then the upper and lower surfaces were ground to obtain a flat surface having a diameter of 50 mm and a thickness of 0.35 mm.
- a face disk was prepared.
- a diamond grindstone was attached to a polishing device equipped with a mechanism for spraying a coolant on the back side of the grindstone, and the flat disk of the composite sintered body obtained above was coated on both sides while controlling the grindstone temperature at 40 ° C or less. Was polished. By polishing for 20 hours, the surface roughness was Ra 0.08 ⁇ m, the flatness was 50 ⁇ / b 0 mm, and the thickness was 0.3 mm.
- the sintered compact was cut to 10.0 X 2.0 X 0.3 mm using a YAG laser. Chips of this rectangular parallelepiped are not more than 7 zm and flatness was 5 mZl O mm.
- the diamond-copper composite sintered body processed into a rectangular parallelepiped was heated in a hydrogen atmosphere at 800 ° C for 3 hours to remove copper oxide present on the surface.
- This sintered body was multi-layer coated with Ni 1 zm, platinum 0.5 1! 1, and gold 0.1 m using a magnetron sputtering apparatus. Furthermore, using a deposition apparatus, a gold / tin alloy solder was coated at 3 / im to form a heat sink for mounting semiconductors.
- the sintered body of ⁇ 27 prepared in Example 2 was processed to a thickness of about 0.4 mm by electric discharge machining, and then the upper and lower surfaces were ground to obtain a diameter of 50 mm.
- the surface roughness of the polished surface disk after polishing was R a O.08 zm.
- wire A rectangular solid of 1.0 X 2.0 X 0.3 was obtained under electric discharge cutting conditions for finishing a cut cross section under the condition of a tension of 1200 g. Chips in the ridges of this rectangular parallelepiped were up to 8 ⁇ m.
- the diamond-copper composite sintered body processed into a rectangular parallelepiped was heated at 800 ° C. for 2 hours in a hydrogen atmosphere to remove copper oxide present on the surface.
- 1 m of nickel was coated on the entire surface of the sintered body, and platinum was coated on the entire surface with 0.2 using a magnetron sputtering device.
- the surface on which the semiconductor element was mounted was coated 3 m on the surface on which the semiconductor element was mounted using a vapor deposition device to form a heat sink for mounting the semiconductor.
- high thermal conductivity diamond sintered body of the present invention for example, high thermal conductivity is optimal for mounting a semiconductor element having a large size and a high thermal load, such as a high-power semiconductor laser or a high-performance MPU. It is possible to provide a heat sink having both the degree and the matching of thermal expansion. In addition, since the characteristics of the thermal conductivity and the coefficient of thermal expansion can be freely adjusted, an optimal heat sink can be selected according to the characteristics and design of the mounted element.
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Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
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US10/494,947 US7528413B2 (en) | 2001-11-09 | 2002-10-16 | Sintered diamond having high thermal conductivity and method for producing the same and heat sink employing it |
JP2003542664A JP4251986B2 (ja) | 2001-11-09 | 2002-10-16 | 高熱伝導性ダイヤモンド焼結体とその製造方法 |
EP11192688.7A EP2428590B1 (en) | 2001-11-09 | 2002-10-16 | Sintered diamond having high thermal conductivity and method for producing the same and heat sink employing it |
CA002462451A CA2462451C (en) | 2001-11-09 | 2002-10-16 | Sintered diamond having high thermal conductivity and method for producing the same and heat sink employing it |
EP02802700.1A EP1452614B1 (en) | 2001-11-09 | 2002-10-16 | Sintered diamond having high thermal conductivity |
ZA2004/03408A ZA200403408B (en) | 2001-11-09 | 2004-05-05 | Sintered diamond having high thermal conductivity and method for producing the same and heat sink employing it |
Applications Claiming Priority (8)
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JP2001344952 | 2001-11-09 | ||
JP2001-344952 | 2001-11-09 | ||
JP2002030592 | 2002-02-07 | ||
JP2002-30592 | 2002-02-07 | ||
JP2002062294 | 2002-03-07 | ||
JP2002-62294 | 2002-03-07 | ||
JP2002-75283 | 2002-03-19 | ||
JP2002075283 | 2002-03-19 |
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US (1) | US7528413B2 (ja) |
EP (2) | EP2428590B1 (ja) |
JP (1) | JP4251986B2 (ja) |
CA (1) | CA2462451C (ja) |
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- 2002-10-16 EP EP11192688.7A patent/EP2428590B1/en not_active Expired - Lifetime
- 2002-10-16 JP JP2003542664A patent/JP4251986B2/ja not_active Expired - Lifetime
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Cited By (19)
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JPWO2006061937A1 (ja) * | 2004-12-08 | 2008-06-05 | 株式会社アライドマテリアル | ヒートシンク材およびその製造方法ならびに半導体レーザー装置 |
JP2008248324A (ja) * | 2007-03-30 | 2008-10-16 | Sps Syntex Inc | ダイヤモンド粒子分散型金属基複合材料及びその製造方法 |
US7791188B2 (en) | 2007-06-18 | 2010-09-07 | Chien-Min Sung | Heat spreader having single layer of diamond particles and associated methods |
US8575625B2 (en) | 2010-02-08 | 2013-11-05 | A.L.M.T. Corp. | Semiconductor element mounting member, method of producing the same, and semiconductor device |
US9006086B2 (en) | 2010-09-21 | 2015-04-14 | Chien-Min Sung | Stress regulated semiconductor devices and associated methods |
US8531026B2 (en) | 2010-09-21 | 2013-09-10 | Ritedia Corporation | Diamond particle mololayer heat spreaders and associated methods |
US8778784B2 (en) | 2010-09-21 | 2014-07-15 | Ritedia Corporation | Stress regulated semiconductor devices and associated methods |
US8945466B2 (en) | 2011-07-15 | 2015-02-03 | Nippon Light Metal Company, Ltd. | Composite material for heat dissipating plate and method of production of same |
WO2013011668A1 (ja) | 2011-07-15 | 2013-01-24 | 日本軽金属株式会社 | 放熱基板用複合材料、及びその製造方法 |
US10115655B2 (en) | 2014-10-09 | 2018-10-30 | Superufo291 Tec | Heat dissipation substrate and method for producing heat dissipation substrate |
JP6028987B2 (ja) * | 2014-10-09 | 2016-11-24 | 株式会社半導体熱研究所 | 放熱基板及び該放熱基板の製造方法 |
WO2016056637A1 (ja) * | 2014-10-09 | 2016-04-14 | 株式会社半導体熱研究所 | 放熱基板及び該放熱基板の製造方法 |
JP2019102716A (ja) * | 2017-12-06 | 2019-06-24 | セイコーエプソン株式会社 | 発光装置および発光装置の製造方法 |
JP7091640B2 (ja) | 2017-12-06 | 2022-06-28 | セイコーエプソン株式会社 | 発光装置および発光装置の製造方法 |
WO2020090213A1 (ja) * | 2018-10-31 | 2020-05-07 | 住友電気工業株式会社 | 放熱部材 |
JPWO2020090213A1 (ja) * | 2018-10-31 | 2021-10-07 | 住友電気工業株式会社 | 放熱部材 |
JP7196193B2 (ja) | 2018-10-31 | 2022-12-26 | 住友電気工業株式会社 | 放熱部材 |
US11799065B2 (en) | 2020-01-31 | 2023-10-24 | Nichia Corporation | Method of producing heat dissipation substrate and method of producing composite substrate |
WO2021192916A1 (ja) * | 2020-03-24 | 2021-09-30 | 住友電気工業株式会社 | 複合材料、及び放熱部材 |
Also Published As
Publication number | Publication date |
---|---|
EP2428590A3 (en) | 2012-06-20 |
US20050051891A1 (en) | 2005-03-10 |
JPWO2003040420A1 (ja) | 2005-03-03 |
EP2428590B1 (en) | 2018-08-15 |
ZA200403408B (en) | 2005-09-28 |
CA2462451A1 (en) | 2003-05-15 |
EP1452614A4 (en) | 2009-09-23 |
JP4251986B2 (ja) | 2009-04-08 |
US7528413B2 (en) | 2009-05-05 |
CA2462451C (en) | 2009-10-06 |
EP1452614A1 (en) | 2004-09-01 |
EP1452614B1 (en) | 2017-12-27 |
EP2428590A2 (en) | 2012-03-14 |
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