US3622283A - Tin-carbon fiber composites - Google Patents
Tin-carbon fiber composites Download PDFInfo
- Publication number
- US3622283A US3622283A US639153A US3622283DA US3622283A US 3622283 A US3622283 A US 3622283A US 639153 A US639153 A US 639153A US 3622283D A US3622283D A US 3622283DA US 3622283 A US3622283 A US 3622283A
- Authority
- US
- United States
- Prior art keywords
- tin
- corrosion resistant
- composite article
- resistant composite
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B64—AIRCRAFT; AVIATION; COSMONAUTICS
- B64C—AEROPLANES; HELICOPTERS
- B64C1/00—Fuselages; Constructional features common to fuselages, wings, stabilising surfaces or the like
- B64C1/06—Frames; Stringers; Longerons ; Fuselage sections
- B64C1/12—Construction or attachment of skin panels
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C49/00—Alloys containing metallic or non-metallic fibres or filaments
- C22C49/14—Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B64—AIRCRAFT; AVIATION; COSMONAUTICS
- B64C—AEROPLANES; HELICOPTERS
- B64C1/00—Fuselages; Constructional features common to fuselages, wings, stabilising surfaces or the like
- B64C2001/0054—Fuselage structures substantially made from particular materials
- B64C2001/0072—Fuselage structures substantially made from particular materials from composite materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B64—AIRCRAFT; AVIATION; COSMONAUTICS
- B64C—AEROPLANES; HELICOPTERS
- B64C1/00—Fuselages; Constructional features common to fuselages, wings, stabilising surfaces or the like
- B64C2001/0054—Fuselage structures substantially made from particular materials
- B64C2001/0081—Fuselage structures substantially made from particular materials from metallic materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T50/00—Aeronautics or air transport
- Y02T50/40—Weight reduction
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/923—Physical dimension
- Y10S428/924—Composite
- Y10S428/926—Thickness of individual layer specified
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12444—Embodying fibers interengaged or between layers [e.g., paper, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12486—Laterally noncoextensive components [e.g., embedded, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12625—Free carbon containing component
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12708—Sn-base component
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12708—Sn-base component
- Y10T428/12722—Next to Group VIII metal-base component
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12778—Alternative base metals from diverse categories
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2918—Rod, strand, filament or fiber including free carbon or carbide or therewith [not as steel]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/294—Coated or with bond, impregnation or core including metal or compound thereof [excluding glass, ceramic and asbestos]
- Y10T428/2942—Plural coatings
- Y10T428/2944—Free metal in coating
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/298—Physical dimension
Definitions
- ABSTRACT Low-density, high-strength tin base composites are provided by coating carbon fibers with a metallic coupling agent and then bonding them together, preferably in a parallel or aligned manner, by means of a tin or tin base alloy matrix. Such composites are characterized by physical properties which are much superior to those evidenced by the matrix material alone and find utility in applications where the chemical properties of tin are desired but its use is prohibited or limited due to its poor physical properties.
- the present invention relates to carbon fiber-tin composites made up of a plurality of carbon fibers coated with a metallic coupling agent and bonded together, preferably in a side-byside or parallel manner, by means of a tin base metal matrix.
- Tin is an element which finds wide useage in industry. One of its most important uses is as a protective coating for stronger materials or substrates. The use of pure tin alone as a material of construction is limited by its inherently poor physical properties, such as low tensile strength and modulus of and/or antimony. However, weak.
- the carbon fiber-tin composite of the invention comprises a plurality of carbon fibers each of which is coated with a thin layer of a coupling metal having a melting a thm but continuous film of a suitable metal, shaping an aggregate of the so-coated fibers into the desired form, infiltrating the voids between the individual fibers with molten tin or tin base alloy and cooling the resultant tin infiltrated aggregate to produce a composite article.
- a graphite fiber-tin composite containing approximately 33.5 volume percent fibers, is characterized by a density a material of construction in apparatus which require strong, corrosion resistant parts or components.
- FIGURE shown in the drawing presented herewith is a diagrammatical illustration of a rectangular section of a carbon fiber-metal matrix composite article produced according to the teachings of the instant invention.
- a rectangular composite article 1 consisting of aligned graphite fibers 2 having disposed on their surface a continuous 2-micron thick coating of nickel 3. These socoated fibers are bonded together by a tin matrix 4.
- the graphite fibers 2 are approximately 1 inch in length and disposed in the tin matrix 4 in a parallel or side-by-side manner.
- length dimension of the fibers 2 is perpendicular to the surface of the drawing.
- Carbon textiles in any form can be employed in the practice of the instant invention. However, it is preferred to employ carbon fibers in yarn or monofilament form. Carbon textiles are available commercially and are generally produced by the techniques described in US. Pat. Nos. 3,107,152 and 3,l 16,975, among others.
- the coupling metal used can be any metal which has a melting point greater than the metal matrix which adheres to the carbon and is readily wetted by the matrix metal without forming low melting point alloys or brittle intermetallic phases.
- Metals which are preferred as coupling agents are nickel, titanium and chromium.
- the selected coupling metal can be deposited on the carbon fibers by a variety of methods. The techniques available for accomplishing this include electrodeposition from a suitable plating bath, thermal decomposition of the appropriate metal halide or sputtering. The exact deposition technique to be employed is dictated by a number of factors. Sputtering can be used on relatively complex shapes and results in a tenacious bond between the coupling metal and the carbon fiber substrate.
- Such a bond is a highly desirable feature in carbon fiber-metal matrix composites.
- Thermal decomposition of the appropriate halide requires a heating of the carbon fiber substrate and, accordingly, somewhat limits the type of shapes which can be coated in this manner.
- Electrodeposition of a metal from a plating solution is an ideal way of coating carbon fibers with a thin metallic film and is the preferred coating technique.
- tin base alloys of low melting point metals such as lead, antimony, and bismuth may also be employed in the practice of the instant invention.
- a single ply of graphite yarn having an average filament diameter of 6.9 microns and consisting of 720 monofilaments per ply was cut into a plurality of 4-inch lengths. These 4 inch sections of graphite yarn were then predipped into acetone to facilitate their subsequent coating with nickel.
- Nickel was so-treated graphite yarn by using a nickel anode and an electroplating plating solution prepared by dissolving 200 grams of NiSO '6H O and 22 grams of H BO in 500 ml. of distilled water. The plating solution temperature was maintained at approximately 52 C. The plating current varied between about 400 to about 1000 milliamperes.
- a metallographic examination of the resultant fibers showed that all monofilaments had a coating of nickel thereon and that the average coating thickness ranged from 1 to 3 microns.
- These nickel clad fibers were then cut in approximately l-inch lengths and placed in an aligned position (all parallel) in a cylindrical capillary tube measuring approximately 1 inch in length and having an internal diameter of about 0.135 inches which was provided with a top and bottom closure.
- the surface of the cylinder was provided with 12 randomly placed holes or openings to facilitate the ingress of tin into the cylinder and hence into the voids between the aligned graphite fibers.
- the cylinder containing the fibers was placed into an airtight chamber which also contained a vessel of tin.
- the chamber was then evacuated to a pressure of approximately ZXlO-mm. of mercury to out gas the graphite fibers.
- the chamber with the tin therein was heated to a temperature of approximately 300 C.
- the cylinder containing the aligned fibers was then submerged below the surface of the molten tin.
- the chamber was subsequently filled with argon gas to a pressure of about latmosphere to insure that molten tin filled essentially all the voids between the aligned graphite fibers.
- the capsule was withdrawn from the molten tin, cooled, and removed from the chamber.
- a metallographic examination of the resultant nickel coated graphite fiber-tin composite showed that the nickel coating was well bonded to the graphite fiber substrate; that the tin matrix material had uniformly and completely wetted the socoated fibers without disturbing the continuity of the nickel coating; and that no undesireable reaction zone was formed at the nickel-tin interface.
- carbon is meant to include both the nongraphitic and graphitic forms of carbon.
- a corrosion resistant composite article comprising a plurality of carbon fibers bonded together by a tin base metal matrix. said carbon fibers having a substantially continuous coating of a coupling metal having a higher melting point than said tin base metal matrix on their outer surface.
- the corrosion resistant composite article of claim 3 wherein said coupling metal is selected from the group consisting of nickel, titanium and chromium.
- the corrosion resistant composite article of claim 15 wherein the thickness of said nickel coupling metal is from I to 3 microns.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US63915367A | 1967-05-17 | 1967-05-17 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3622283A true US3622283A (en) | 1971-11-23 |
Family
ID=24562947
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US639153A Expired - Lifetime US3622283A (en) | 1967-05-17 | 1967-05-17 | Tin-carbon fiber composites |
Country Status (4)
Country | Link |
---|---|
US (1) | US3622283A (fr) |
DE (1) | DE1558690B2 (fr) |
FR (1) | FR1561254A (fr) |
GB (1) | GB1216401A (fr) |
Cited By (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3720257A (en) * | 1970-01-07 | 1973-03-13 | Bbc Brown Boveri & Cie | Method of producing carbon fiber-reinforced metal |
US3807996A (en) * | 1972-07-10 | 1974-04-30 | Union Carbide Corp | Carbon fiber reinforced nickel matrix composite having an intermediate layer of metal carbide |
US3888661A (en) * | 1972-08-04 | 1975-06-10 | Us Army | Production of graphite fiber reinforced metal matrix composites |
US3894677A (en) * | 1971-03-24 | 1975-07-15 | Nasa | Method of preparing graphite reinforced aluminum composite |
US3938579A (en) * | 1970-09-10 | 1976-02-17 | United Kingdom Atomic Energy Authority | Method of producing composite bearing materials |
US4223075A (en) * | 1977-01-21 | 1980-09-16 | The Aerospace Corporation | Graphite fiber, metal matrix composite |
US4341823A (en) * | 1981-01-14 | 1982-07-27 | Material Concepts, Inc. | Method of fabricating a fiber reinforced metal composite |
US4609449A (en) * | 1982-03-16 | 1986-09-02 | American Cyanamid Company | Apparatus for the production of continuous yarns or tows comprising high strength metal coated fibers |
US4624751A (en) * | 1983-06-24 | 1986-11-25 | American Cyanamid Company | Process for fiber plating and apparatus with special tensioning mechanism |
US4648902A (en) * | 1983-09-12 | 1987-03-10 | American Cyanamid Company | Reinforced metal substrate |
US4661403A (en) * | 1982-03-16 | 1987-04-28 | American Cyanamid Company | Yarns and tows comprising high strength metal coated fibers, process for their production, and articles made therefrom |
US4680093A (en) * | 1982-03-16 | 1987-07-14 | American Cyanamid Company | Metal bonded composites and process |
US4680100A (en) * | 1982-03-16 | 1987-07-14 | American Cyanamid Company | Electrochemical cells and electrodes therefor |
US4762603A (en) * | 1983-06-24 | 1988-08-09 | American Cyanamid Company | Process for forming electrodes |
US4831707A (en) * | 1980-11-14 | 1989-05-23 | Fiber Materials, Inc. | Method of preparing metal matrix composite materials using metallo-organic solutions for fiber pre-treatment |
US4837073A (en) * | 1987-03-30 | 1989-06-06 | Allied-Signal Inc. | Barrier coating and penetrant providing oxidation protection for carbon-carbon materials |
US4852453A (en) * | 1982-03-16 | 1989-08-01 | American Cyanamid Company | Chaff comprising metal coated fibers |
WO1989011551A1 (fr) * | 1988-05-23 | 1989-11-30 | Yoon Technology | Fabrication de composites d'alliage a noyau fusible pour le moulage de matieres plastiques |
US4904351A (en) * | 1982-03-16 | 1990-02-27 | American Cyanamid Company | Process for continuously plating fiber |
US4909910A (en) * | 1982-03-16 | 1990-03-20 | American Cyanamid | Yarns and tows comprising high strength metal coated fibers, process for their production, and articles made therefrom |
US4911797A (en) * | 1983-06-24 | 1990-03-27 | American Cyanamid Company | Contact roller mounting assembly and tensioning mechanism for electroplating fiber |
US4942090A (en) * | 1982-03-16 | 1990-07-17 | American Cyanamid | Chaff comprising metal coated fibers |
US4976828A (en) * | 1982-03-16 | 1990-12-11 | American Cyanamid Company | Chaff comprising metal coated fibers |
US5066544A (en) * | 1990-08-27 | 1991-11-19 | U.S. Philips Corporation | Dispersion strengthened lead-tin alloy solder |
US5089356A (en) * | 1990-09-17 | 1992-02-18 | The Research Foundation Of State Univ. Of New York | Carbon fiber reinforced tin-lead alloy as a low thermal expansion solder preform |
US5779872A (en) * | 1992-03-13 | 1998-07-14 | Toyota Jidosha Kabushiki Kaisha | Composite material having anti-wear property and process for producing the same |
EP1096032A2 (fr) * | 1999-11-01 | 2001-05-02 | Ford Global Technologies, Inc. | Matériau composite à matrice métallique renforcée par des fibres |
US20050166386A1 (en) * | 2003-11-20 | 2005-08-04 | Twigg Edwin S. | Method of manufacturing a fibre reinforced metal matrix composite article |
US20050181209A1 (en) * | 1999-08-20 | 2005-08-18 | Karandikar Prashant G. | Nanotube-containing composite bodies, and methods for making same |
US20060062985A1 (en) * | 2004-04-26 | 2006-03-23 | Karandikar Prashant G | Nanotube-containing composite bodies, and methods for making same |
FR2876044A1 (fr) * | 2004-10-05 | 2006-04-07 | Ensmse | Procede d'electrodeposition de nanoparticules de metal sur un filtre en materiau fibreux, materiau ainsi obtenu et son utilisation pour l'elimination de polluants en milieu gazeux |
US20060156662A1 (en) * | 2004-12-01 | 2006-07-20 | Airbus Deutschland Gmbh | Structural element, method for manufacturing a structural element and use of a structural element for an aircraft hull |
US7169465B1 (en) | 1999-08-20 | 2007-01-30 | Karandikar Prashant G | Low expansion metal-ceramic composite bodies, and methods for making same |
US7244034B1 (en) | 1999-08-20 | 2007-07-17 | M Cubed Technologies, Inc. | Low CTE metal-ceramic composite articles, and methods for making same |
EP2208706A1 (fr) * | 2007-09-18 | 2010-07-21 | Shimane Prefectural Government | Matériau de carbone recouvert de métal et matériau composite carbone-métal employant le matériau de carbone recouvert de métal |
US20120009110A1 (en) * | 2010-02-04 | 2012-01-12 | Third Millennium Metals, Llc | Metal-Carbon Compositions |
CN103194698A (zh) * | 2013-04-17 | 2013-07-10 | 中北大学 | 碳纤维增强锡基复合材料及其制备方法 |
US20170307454A1 (en) * | 2014-10-20 | 2017-10-26 | Bae Systems Plc | Strain sensing in composite materials |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2501024C2 (de) * | 1975-01-13 | 1985-09-26 | Fiber Materials, Inc., Biddeford, Me. | Verbundkörper |
SE454519B (sv) * | 1981-09-11 | 1988-05-09 | Inst Mekhaniki Metallopolimern | Sjevsmorjande kompositmaterial |
GB2219006A (en) * | 1988-05-26 | 1989-11-29 | Rolls Royce Plc | Coated fibre for use in a metal matrix |
DE102009015283B4 (de) * | 2009-04-01 | 2015-05-21 | Airbus Defence and Space GmbH | Galvanisierungswerkzeug für Fäden, Verwendung des Galvanisierwerkzeugs und Verfahren zum Galvanisieren von Fäden |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3047383A (en) * | 1955-12-27 | 1962-07-31 | Owens Corning Fiberglass Corp | Polyphase materials |
US3098723A (en) * | 1960-01-18 | 1963-07-23 | Rand Corp | Novel structural composite material |
US3282658A (en) * | 1962-07-20 | 1966-11-01 | Wainer Eugene | Fiber reinforced metals containing bond promoting components |
US3352650A (en) * | 1965-07-19 | 1967-11-14 | Goldstein David | Metallic composites |
-
1967
- 1967-05-17 US US639153A patent/US3622283A/en not_active Expired - Lifetime
- 1967-12-20 DE DE19671558690 patent/DE1558690B2/de not_active Withdrawn
-
1968
- 1968-01-09 GB GB0182/68A patent/GB1216401A/en not_active Expired
- 1968-01-12 FR FR1561254D patent/FR1561254A/fr not_active Expired
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3047383A (en) * | 1955-12-27 | 1962-07-31 | Owens Corning Fiberglass Corp | Polyphase materials |
US3098723A (en) * | 1960-01-18 | 1963-07-23 | Rand Corp | Novel structural composite material |
US3282658A (en) * | 1962-07-20 | 1966-11-01 | Wainer Eugene | Fiber reinforced metals containing bond promoting components |
US3352650A (en) * | 1965-07-19 | 1967-11-14 | Goldstein David | Metallic composites |
Cited By (54)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3720257A (en) * | 1970-01-07 | 1973-03-13 | Bbc Brown Boveri & Cie | Method of producing carbon fiber-reinforced metal |
US3938579A (en) * | 1970-09-10 | 1976-02-17 | United Kingdom Atomic Energy Authority | Method of producing composite bearing materials |
US3894677A (en) * | 1971-03-24 | 1975-07-15 | Nasa | Method of preparing graphite reinforced aluminum composite |
US3807996A (en) * | 1972-07-10 | 1974-04-30 | Union Carbide Corp | Carbon fiber reinforced nickel matrix composite having an intermediate layer of metal carbide |
US3888661A (en) * | 1972-08-04 | 1975-06-10 | Us Army | Production of graphite fiber reinforced metal matrix composites |
US4223075A (en) * | 1977-01-21 | 1980-09-16 | The Aerospace Corporation | Graphite fiber, metal matrix composite |
US4831707A (en) * | 1980-11-14 | 1989-05-23 | Fiber Materials, Inc. | Method of preparing metal matrix composite materials using metallo-organic solutions for fiber pre-treatment |
US4341823A (en) * | 1981-01-14 | 1982-07-27 | Material Concepts, Inc. | Method of fabricating a fiber reinforced metal composite |
US4680100A (en) * | 1982-03-16 | 1987-07-14 | American Cyanamid Company | Electrochemical cells and electrodes therefor |
US4976828A (en) * | 1982-03-16 | 1990-12-11 | American Cyanamid Company | Chaff comprising metal coated fibers |
US4661403A (en) * | 1982-03-16 | 1987-04-28 | American Cyanamid Company | Yarns and tows comprising high strength metal coated fibers, process for their production, and articles made therefrom |
US4680093A (en) * | 1982-03-16 | 1987-07-14 | American Cyanamid Company | Metal bonded composites and process |
US4942090A (en) * | 1982-03-16 | 1990-07-17 | American Cyanamid | Chaff comprising metal coated fibers |
US4909910A (en) * | 1982-03-16 | 1990-03-20 | American Cyanamid | Yarns and tows comprising high strength metal coated fibers, process for their production, and articles made therefrom |
US4609449A (en) * | 1982-03-16 | 1986-09-02 | American Cyanamid Company | Apparatus for the production of continuous yarns or tows comprising high strength metal coated fibers |
US4904351A (en) * | 1982-03-16 | 1990-02-27 | American Cyanamid Company | Process for continuously plating fiber |
US4852453A (en) * | 1982-03-16 | 1989-08-01 | American Cyanamid Company | Chaff comprising metal coated fibers |
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EP2208706A4 (fr) * | 2007-09-18 | 2013-03-27 | Shimane Prefectural Government | Matériau de carbone recouvert de métal et matériau composite carbone-métal employant le matériau de carbone recouvert de métal |
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Also Published As
Publication number | Publication date |
---|---|
FR1561254A (fr) | 1969-03-28 |
DE1558690A1 (fr) | 1971-10-07 |
GB1216401A (en) | 1970-12-23 |
DE1558690B2 (de) | 1971-10-07 |
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Owner name: AMOCO CORPORATION, A CORP. OF INDIANA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:UNION CARBIDE CORPORATION;REEL/FRAME:004634/0001 Effective date: 19860620 |