US3473900A - Aluminum-carbon fiber composites - Google Patents
Aluminum-carbon fiber composites Download PDFInfo
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- US3473900A US3473900A US617662A US3473900DA US3473900A US 3473900 A US3473900 A US 3473900A US 617662 A US617662 A US 617662A US 3473900D A US3473900D A US 3473900DA US 3473900 A US3473900 A US 3473900A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B64—AIRCRAFT; AVIATION; COSMONAUTICS
- B64C—AEROPLANES; HELICOPTERS
- B64C1/00—Fuselages; Constructional features common to fuselages, wings, stabilising surfaces or the like
- B64C1/06—Frames; Stringers; Longerons ; Fuselage sections
- B64C1/12—Construction or attachment of skin panels
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C47/00—Making alloys containing metallic or non-metallic fibres or filaments
- C22C47/02—Pretreatment of the fibres or filaments
- C22C47/04—Pretreatment of the fibres or filaments by coating, e.g. with a protective or activated covering
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C49/00—Alloys containing metallic or non-metallic fibres or filaments
- C22C49/14—Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B64—AIRCRAFT; AVIATION; COSMONAUTICS
- B64C—AEROPLANES; HELICOPTERS
- B64C1/00—Fuselages; Constructional features common to fuselages, wings, stabilising surfaces or the like
- B64C2001/0054—Fuselage structures substantially made from particular materials
- B64C2001/0072—Fuselage structures substantially made from particular materials from composite materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B64—AIRCRAFT; AVIATION; COSMONAUTICS
- B64C—AEROPLANES; HELICOPTERS
- B64C1/00—Fuselages; Constructional features common to fuselages, wings, stabilising surfaces or the like
- B64C2001/0054—Fuselage structures substantially made from particular materials
- B64C2001/0081—Fuselage structures substantially made from particular materials from metallic materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T50/00—Aeronautics or air transport
- Y02T50/40—Weight reduction
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/923—Physical dimension
- Y10S428/924—Composite
- Y10S428/926—Thickness of individual layer specified
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12444—Embodying fibers interengaged or between layers [e.g., paper, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12486—Laterally noncoextensive components [e.g., embedded, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
- Y10T428/12625—Free carbon containing component
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12736—Al-base component
- Y10T428/12743—Next to refractory [Group IVB, VB, or VIB] metal-base component
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12806—Refractory [Group IVB, VB, or VIB] metal-base component
- Y10T428/12819—Group VB metal-base component
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2918—Rod, strand, filament or fiber including free carbon or carbide or therewith [not as steel]
Definitions
- the present invention relates to a composite refractory article which is made up of a plurality of high modulus, high strength carbon fibers which are completely coated with a thin layer of tantalum and bonded together by an aluminum matrix.
- Aluminum has been suggested as the matrix media for carbon fiber-metal composites which are intended for use in aerospace applications, in the main, due to its low density.
- aluminum does not wet pure graphite for all practical purposes unless aluminum carbide is formed at the interface. Such an aluminum carbide phase cannot be tolerated due to its thermochemical instability.
- the carbon fiber-aluminum composite article of the invention comprises a plurality of carbon iibers each of which is coated with a thin layer ofi tantalum and bonded together, preferably in a side-by-side or parallel manner, with an aluminum binder or matrix.
- this composite article may be provided by a process which comprises coating carbon fibers with a thin but continuous film of tantalum, compacting the socalled fibers into the desired form, infiltrating the voids between the compacted fibers with molten aluminum and cooling the resultant aluminum infiltrated tantalum coated carbon fibers to produce a composite article.
- This article can then be formed into any desired shape by known techniques which will readily suggest themselves to those skilled in the art.
- a rectangular composite article 1 consisting of aligned graphite fibers 2 having disposed on their surface a continuous one to two micron thick coating of tantalum 3. These so-coated fibers are bonded together by an aluminum matrix 4.
- the graphite fibers 2 are approximately two inches in length and disposed in the aluminum matrix 4 in a parallel or side-by-side manner. The length dimension of the fibers 2 is perpendicular to surface of the drawing.
- Carbon textiles in any form can be employed in the practice of the instant invention. However, it is preferred to employ carbon fibers in yarn or mono-filament form. Carbon textiles are available commercially and are generally produced by the techniques described in U.S. Patents 3,107,152 and 3,116,975, among others.
- Tantalum can be deposited on the carbon fibers by a variety of methods.
- the techniques available for accomplishing this include electrodeposition from a fused salt bath, thermal decomposition of the appropriate metal halide or sputtering.
- the exact deposition technique to be employed is dictated by a number of factors.
- Sputtering can be used on relatively complex shapes and results in a tenacious bond between the thin tantalum coating and the carbon fiber substrate. Such a bond is a highly desirable feature in carbon fiber-metal matrix composites.
- Thermal decomposition of the appropriate halide requires a heating of the carbon fiber substrate and, accordingly, somewhat limits the type of shapes which can be coated with tantalum in this manner.
- Electrodeposition of tantalum from a fused salt bath is an ideal way of coating carbon fibers with a thin film of tantalum but this technique is limited to rather simple carbon fiber configurations.
- a carbon yarn material which had been heated to graphitizing temperatures was cut into 2 inch lengths.
- a tantalum coating averaging from 0.2 to 2.0 microns was electrodeposited on these fibers by a technique similar to that described in co-pending US. patent application Ser. No. 609,683 which has been assigned to the same assignee as the instant application.
- These tantalum clad fibers were then placed in an aligned position (all parallel) in a cylindrical capillary tube which was provided with a top and bottom closure.
- the surface of the cylinder was provided with randomly placed holes or openings to facilitate the ingress of aluminum into the cylinder and hence into the voids between the aligned carbon fibers.
- the cylinder containing the carbon fibers in a preselected form was placed into an air tight chamber which also contained a vessel of aluminum.
- The. chamber was then evacuated to a pressure of approximately 2X10" mm. of mercury to out gas the carbon fibers.
- the aluminum was heated to a temperature of approximately 700 C.
- the cylinder containing the aligned fibers was submerged below the surface of the molten aluminum.
- the chamber was then filled with argon gas to a pressure of about one atmosphere to insure that molten aluminum filled essentially all the voids between the aligned carbon fibers. After about thirty seconds of pressurizing the specimen, the capsule was withdrawn from the molten aluminum, cooled and removed from the chamber.
- a metallographic examination of the resultant composite showed that aluminum readily wet the tantalum clad fibers and incorporated them into the matrix without disturbing the tantalum coating and, more importantly, without the formation of a reaction zone at the aluminum-tantalum interface.
- Composite so-produced are extremely useful as materials of construction for subsonic and supersonic aricraft, space system components and various propulsion devices.
- the carbon fibers may be randomly orientated in the aluminum matrix if more isotropic physical properties are desired without losing the benefits of the instant invention.
- the thickness of the tantalum can be varied as desired. All that is required is that it be thick enough to prevent the aluminum matrix metal from coming into contact with the reinforcing carbon fibers.
- graphite fibers and fabrics are preferred in the practice of the instant invention, nongraphitic carbon fibers and fabrics may also be employed.
- other methods of infiltrating the tantalum clad carbon fibers with aluminum will readily suggest themselves to the skilled artisan.
- carbon as used herein and in the appended claims is meant to include both the non-graphitic and graphitic forms of carbon.
- a refractory composite article comprising a plurality of carbon fibers bonded together by an essentially aluminum matrix, said carbon fibers having a continuous coating consisting essentially of tantalum on their outer surface so as to prevent said aluminum matrix from being in direct contact with said carbon fibers.
Abstract
1,185,349. Composite metal articles. UNION CARBIDE CORP. 8 Nov., 1967 [21 Feb., 1967], No. 50695/67. Heading B3F. [Also in Division C7] A composite metal article is made by providing a tantalum covering 3 to carbon fibres 2 and filling the voids between the fibres with an aluminium matrix 4. The tantalum covering 3 facilitates the wetting of the fibres by the molten metal. The article is produced by placing the fibres 2 in a cylinder having a number of holes in its sides, heating them in a partial vacuum, submerging the fibres and cylinder in molten aluminium whilst in the partial vacuum and then pressurizing the molten metal to force it into the voids. The fibres may be in yarn or mono-filament form or in fabric or textile form and the carbon may be in a graphitic or non- graphitic form. The tantalum is formed on the carbon fibres by electro-deposition from a fused salt bath, thermal decomposition of the appropriate metal halide, or by sputtering.
Description
6L 9 R. v. SARA 3,473,900
ALUMINUM-CARBON FIBER COMPOSITES Filed Feb. 21, 1967 INVENTOR RAYMOND V. SARA ATTORNEY 3 473 900 ALrJMmrJrvr-cAneoNrrnnn coMrosrrEs Raymond V. Sara, North Olmsted, Ohio, assignor to Union Carbide Corporation, a corporation of New York Filed Feb. 21, 1967, Ser. No. 617,662 Int. Cl. B23 11/00; B2111 39/00 US. Cl. 29195 8 Claims ABSTRACT OF THE DISCLOSURE BACKGROUND OF INVENTION Field of the invention The present invention relates to a composite refractory article which is made up of a plurality of high modulus, high strength carbon fibers which are completely coated with a thin layer of tantalum and bonded together by an aluminum matrix.
Description of the prior art Recently, in the space and missile industries, there has developed a need for materials of construction which exhibit exceptional physical properties, for example, low density coupled with high strength and stiffness. Attempts to produce such materials have centered around the fabrication of composite articles.
One of the most promising materials available today for use in composite form is carbon textiles since they are available commercially in all known textile forms. Today, it is well known to form composites of carbon textiles and resins.
Recently, efiforts have been directed to forming composites of carbon textiles and metals. The object of forming such composites is to increase the strength of the metal matrix by the inclusion therein of the high strength carbon fibers.
Aluminum has been suggested as the matrix media for carbon fiber-metal composites which are intended for use in aerospace applications, in the main, due to its low density. However, aluminum does not wet pure graphite for all practical purposes unless aluminum carbide is formed at the interface. Such an aluminum carbide phase cannot be tolerated due to its thermochemical instability.
In order to overcome the inherent lack of wettability of carbon fibers with aluminum, it was decided to try and coat carbon fibers with a thin metallic coating which then would be wetted by aluminum. However, most metals react extensively with aluminum above its melting temperature and form one or more brittle intermetallic phases. The intermetallic constituents or phases either degrade certain mechanical properties of the composite or result in dewetting of the aluminum from around the coated fibers. An extensive study was made of the interfacial zone formed between titanium, chromium, nickel, copper, columbium, silver, molybdenum, tungsten and tantalum respectively, and aluminum to determine which metals are most compatible with aluminum and therefore most useful as intermediate phase-free coupling or wetting agents. Of all the metals tried only tantalum was found to be entirely satisfactory.
hired States Patent M 3,473,900 Patented Oct. 21, 1969 SUMMARY Broadly stated, the carbon fiber-aluminum composite article of the invention comprises a plurality of carbon iibers each of which is coated with a thin layer ofi tantalum and bonded together, preferably in a side-by-side or parallel manner, with an aluminum binder or matrix. Generally, this composite article may be provided by a process which comprises coating carbon fibers with a thin but continuous film of tantalum, compacting the socalled fibers into the desired form, infiltrating the voids between the compacted fibers with molten aluminum and cooling the resultant aluminum infiltrated tantalum coated carbon fibers to produce a composite article. This article can then be formed into any desired shape by known techniques which will readily suggest themselves to those skilled in the art.
DESCRIPTION OF THE DRAWING The sole figure shown in the drawing presented herewith is a diagrammatical illustration of a rectangular carbon fiber-metal matrix composite article produced according to the teachings of the instant invention.
Referring now in detail to the drawing, there is shown in cross section a rectangular composite article 1 consisting of aligned graphite fibers 2 having disposed on their surface a continuous one to two micron thick coating of tantalum 3. These so-coated fibers are bonded together by an aluminum matrix 4. The graphite fibers 2 are approximately two inches in length and disposed in the aluminum matrix 4 in a parallel or side-by-side manner. The length dimension of the fibers 2 is perpendicular to surface of the drawing.
DESCRIPTION OF THE PREFERRED EMBODI- MENT OF THE INVENTION Carbon textiles in any form can be employed in the practice of the instant invention. However, it is preferred to employ carbon fibers in yarn or mono-filament form. Carbon textiles are available commercially and are generally produced by the techniques described in U.S. Patents 3,107,152 and 3,116,975, among others.
Tantalum can be deposited on the carbon fibers by a variety of methods. The techniques available for accomplishing this include electrodeposition from a fused salt bath, thermal decomposition of the appropriate metal halide or sputtering. The exact deposition technique to be employed is dictated by a number of factors. Sputtering can be used on relatively complex shapes and results in a tenacious bond between the thin tantalum coating and the carbon fiber substrate. Such a bond is a highly desirable feature in carbon fiber-metal matrix composites. Thermal decomposition of the appropriate halide requires a heating of the carbon fiber substrate and, accordingly, somewhat limits the type of shapes which can be coated with tantalum in this manner. Electrodeposition of tantalum from a fused salt bath is an ideal way of coating carbon fibers with a thin film of tantalum but this technique is limited to rather simple carbon fiber configurations.
The following example illustrates in detail the preferred practice of the instant invention.
A carbon yarn material which had been heated to graphitizing temperatures was cut into 2 inch lengths. A tantalum coating averaging from 0.2 to 2.0 microns was electrodeposited on these fibers by a technique similar to that described in co-pending US. patent application Ser. No. 609,683 which has been assigned to the same assignee as the instant application. These tantalum clad fibers were then placed in an aligned position (all parallel) in a cylindrical capillary tube which was provided with a top and bottom closure. The surface of the cylinder was provided with randomly placed holes or openings to facilitate the ingress of aluminum into the cylinder and hence into the voids between the aligned carbon fibers. The cylinder containing the carbon fibers in a preselected form was placed into an air tight chamber which also contained a vessel of aluminum. The. chamber was then evacuated to a pressure of approximately 2X10" mm. of mercury to out gas the carbon fibers. The aluminum was heated to a temperature of approximately 700 C. The cylinder containing the aligned fibers was submerged below the surface of the molten aluminum. The chamber was then filled with argon gas to a pressure of about one atmosphere to insure that molten aluminum filled essentially all the voids between the aligned carbon fibers. After about thirty seconds of pressurizing the specimen, the capsule was withdrawn from the molten aluminum, cooled and removed from the chamber.
A metallographic examination of the resultant composite showed that aluminum readily wet the tantalum clad fibers and incorporated them into the matrix without disturbing the tantalum coating and, more importantly, without the formation of a reaction zone at the aluminum-tantalum interface.
Composite so-produced are extremely useful as materials of construction for subsonic and supersonic aricraft, space system components and various propulsion devices.
While the foregoing example concerns a composite where the fibers are positioned in a side-by-side relationship, it is readily apparent to those skilled in the art that the carbon fibers may be randomly orientated in the aluminum matrix if more isotropic physical properties are desired without losing the benefits of the instant invention. In addition, it is obvious that the thickness of the tantalum can be varied as desired. All that is required is that it be thick enough to prevent the aluminum matrix metal from coming into contact with the reinforcing carbon fibers. Likewise, it will be appreciated by those versed in the art that although graphite fibers and fabrics are preferred in the practice of the instant invention, nongraphitic carbon fibers and fabrics may also be employed. Also, other methods of infiltrating the tantalum clad carbon fibers with aluminum will readily suggest themselves to the skilled artisan.
The term carbon as used herein and in the appended claims is meant to include both the non-graphitic and graphitic forms of carbon.
The foregoing example is presented for illustrative purposes only and is not intended to unduly limit the reasonable scope of the instant invention. The limitations or applicants invention are defined by the following claims.
What is claimed is:
1. A refractory composite article comprising a plurality of carbon fibers bonded together by an essentially aluminum matrix, said carbon fibers having a continuous coating consisting essentially of tantalum on their outer surface so as to prevent said aluminum matrix from being in direct contact with said carbon fibers.
2. The composite refractory article of claim 1 wherein said fibers are graphite.
3. The composite refractory article of claim 1 wherein said carbon fibers are in yarn form.
4. The refractory composite article of claim 1 wherein said carbon fibers are arranged in a side-by-side, parallel relationship.
5. The refractroy composite of claim 1 wherein said essentially tantalum coating on said carbon fibers is in the range of from about 0.2 to about 2.0 microns thick.
6. The composite refractory article of claim 2 wherein said graphite fibers are in yarn form.
7. The refractory composite article of claim 2 wherein said graphite fibers are arranged in a side-by-side, parallel relationship.
8. The refractory composite of claim 2 wherein said essentially tantalum coating on said graphite fibers is in the range of from about 0.2 to about 2.0 microns thick.
References Cited UNITED STATES PATENTS 2,683,671 7/1954 Findlay et al 29l95 X 2,699,415 1/1955 Nachtman 29-195 K 2,920,385 l/l960 Fike et al. 29-195 X 3,098,723 7/1963 Micks 29-l83.5 3,085,317 4/1963 Stackhouse 29-l94 X 3,384,463 5/1968 Olstowski et al. 29191 X L. DEWAYNE RUTLEDGE, Primary Examiner E. L. WEISE, Assistant Examiner US. Cl. X.R. 29197, 198
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US61766267A | 1967-02-21 | 1967-02-21 |
Publications (1)
Publication Number | Publication Date |
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US3473900A true US3473900A (en) | 1969-10-21 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US617662A Expired - Lifetime US3473900A (en) | 1967-02-21 | 1967-02-21 | Aluminum-carbon fiber composites |
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US (1) | US3473900A (en) |
DE (1) | DE1621379B2 (en) |
FR (1) | FR1559658A (en) |
GB (1) | GB1185349A (en) |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3623981A (en) * | 1967-05-04 | 1971-11-30 | Nat Res Dev | Composite bearing materials |
US3674689A (en) * | 1969-06-25 | 1972-07-04 | Nat Res Dev | Carbon fiber filled composite materials |
US3720257A (en) * | 1970-01-07 | 1973-03-13 | Bbc Brown Boveri & Cie | Method of producing carbon fiber-reinforced metal |
US3871834A (en) * | 1970-12-25 | 1975-03-18 | Hitachi Ltd | Carbon-fiber-reinforced aluminum composite material |
US3894677A (en) * | 1971-03-24 | 1975-07-15 | Nasa | Method of preparing graphite reinforced aluminum composite |
US3936277A (en) * | 1970-04-09 | 1976-02-03 | Mcdonnell Douglas Corporation | Aluminum alloy-boron fiber composite |
US3949804A (en) * | 1973-03-26 | 1976-04-13 | Toyota Jidosha Kogyo Kabushiki Kaisha | Method of manufacturing a metal-impregnated body |
JPS5138643B1 (en) * | 1970-09-30 | 1976-10-22 | ||
US4058052A (en) * | 1971-08-30 | 1977-11-15 | Hart Mark M | Cooking grill and briquettes therefor |
US4364300A (en) * | 1978-06-26 | 1982-12-21 | The United States Of America As Represented By The Secretary Of The Army | Composite cored combat vehicle armor |
US4534400A (en) * | 1981-09-16 | 1985-08-13 | Honda Giken Kogyo Kabushiki Kaisha | Method for making a reinforced article for an internal combustion engine |
US4578287A (en) * | 1984-10-09 | 1986-03-25 | The United States Of America As Represented By The Secretary Of The Navy | Process for producing graphite fiber/aluminum-magnesium matrix composites |
US4609449A (en) * | 1982-03-16 | 1986-09-02 | American Cyanamid Company | Apparatus for the production of continuous yarns or tows comprising high strength metal coated fibers |
US4661403A (en) * | 1982-03-16 | 1987-04-28 | American Cyanamid Company | Yarns and tows comprising high strength metal coated fibers, process for their production, and articles made therefrom |
US4892130A (en) * | 1981-09-16 | 1990-01-09 | Honda Giken Kogyo Kabushiki Kaisha | Method for making a reinforced article for an internal combustion engine |
US4909910A (en) * | 1982-03-16 | 1990-03-20 | American Cyanamid | Yarns and tows comprising high strength metal coated fibers, process for their production, and articles made therefrom |
US6466414B1 (en) * | 2000-08-29 | 2002-10-15 | International Business Machines Corporation | Continuously wound fiber-reinforced disk drive actuator assembly |
EP2208706A1 (en) * | 2007-09-18 | 2010-07-21 | Shimane Prefectural Government | Metal covered carbon material and carbon-metal composite material using the metal covered carbon material |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5260222A (en) * | 1975-09-30 | 1977-05-18 | Honda Motor Co Ltd | Method of manufacturing fibre reinforced composite |
JPS5292827A (en) * | 1976-01-16 | 1977-08-04 | Honda Motor Co Ltd | Method of manufacturing structures with fiber reinforced composite parts |
DE3100950C2 (en) * | 1981-01-14 | 1985-03-28 | Respublikanskij gosudarstvennyj institut po proektirovaniju ob"ektov proizvodstvennoj bazy vodochozjajstvennych organizacij "Rosgiprovodprom", Rostov-na-Donu | Device for internal enamelling of hollow vessels |
GB2219006A (en) * | 1988-05-26 | 1989-11-29 | Rolls Royce Plc | Coated fibre for use in a metal matrix |
GB2222793A (en) * | 1988-09-16 | 1990-03-21 | British Aerospace | "Method of forming a fibre reinforced material" |
US5017438A (en) * | 1989-12-22 | 1991-05-21 | General Electric Company | Silicon carbide filament reinforced titanium aluminide matrix with reduced cracking tendency |
CA2060520A1 (en) * | 1991-03-11 | 1994-12-09 | Jonathan G. Storer | Metal matrix composites |
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US2683671A (en) * | 1952-07-17 | 1954-07-13 | Westinghouse Electric Corp | Low primary and secondary electron emission surface |
US2699415A (en) * | 1953-02-25 | 1955-01-11 | Owens Corning Fiberglass Corp | Method of producing refractory fiber laminate |
US2920385A (en) * | 1956-02-08 | 1960-01-12 | Borg Warner | Process of bonding carbon to aluminum |
US3085317A (en) * | 1959-12-31 | 1963-04-16 | Union Carbide Corp | Coated graphite bodies |
US3098723A (en) * | 1960-01-18 | 1963-07-23 | Rand Corp | Novel structural composite material |
US3384463A (en) * | 1965-03-22 | 1968-05-21 | Dow Chemical Co | Graphite metal body composite |
-
1967
- 1967-02-21 US US617662A patent/US3473900A/en not_active Expired - Lifetime
- 1967-10-26 DE DE19671621379 patent/DE1621379B2/en not_active Withdrawn
- 1967-11-08 GB GB50695/67A patent/GB1185349A/en not_active Expired
- 1967-11-21 FR FR1559658D patent/FR1559658A/fr not_active Expired
Patent Citations (6)
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---|---|---|---|---|
US2683671A (en) * | 1952-07-17 | 1954-07-13 | Westinghouse Electric Corp | Low primary and secondary electron emission surface |
US2699415A (en) * | 1953-02-25 | 1955-01-11 | Owens Corning Fiberglass Corp | Method of producing refractory fiber laminate |
US2920385A (en) * | 1956-02-08 | 1960-01-12 | Borg Warner | Process of bonding carbon to aluminum |
US3085317A (en) * | 1959-12-31 | 1963-04-16 | Union Carbide Corp | Coated graphite bodies |
US3098723A (en) * | 1960-01-18 | 1963-07-23 | Rand Corp | Novel structural composite material |
US3384463A (en) * | 1965-03-22 | 1968-05-21 | Dow Chemical Co | Graphite metal body composite |
Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3623981A (en) * | 1967-05-04 | 1971-11-30 | Nat Res Dev | Composite bearing materials |
US3674689A (en) * | 1969-06-25 | 1972-07-04 | Nat Res Dev | Carbon fiber filled composite materials |
US3720257A (en) * | 1970-01-07 | 1973-03-13 | Bbc Brown Boveri & Cie | Method of producing carbon fiber-reinforced metal |
US3936277A (en) * | 1970-04-09 | 1976-02-03 | Mcdonnell Douglas Corporation | Aluminum alloy-boron fiber composite |
JPS5138643B1 (en) * | 1970-09-30 | 1976-10-22 | ||
US3871834A (en) * | 1970-12-25 | 1975-03-18 | Hitachi Ltd | Carbon-fiber-reinforced aluminum composite material |
US3894677A (en) * | 1971-03-24 | 1975-07-15 | Nasa | Method of preparing graphite reinforced aluminum composite |
US4058052A (en) * | 1971-08-30 | 1977-11-15 | Hart Mark M | Cooking grill and briquettes therefor |
US3949804A (en) * | 1973-03-26 | 1976-04-13 | Toyota Jidosha Kogyo Kabushiki Kaisha | Method of manufacturing a metal-impregnated body |
US4364300A (en) * | 1978-06-26 | 1982-12-21 | The United States Of America As Represented By The Secretary Of The Army | Composite cored combat vehicle armor |
US4534400A (en) * | 1981-09-16 | 1985-08-13 | Honda Giken Kogyo Kabushiki Kaisha | Method for making a reinforced article for an internal combustion engine |
US4892130A (en) * | 1981-09-16 | 1990-01-09 | Honda Giken Kogyo Kabushiki Kaisha | Method for making a reinforced article for an internal combustion engine |
US4609449A (en) * | 1982-03-16 | 1986-09-02 | American Cyanamid Company | Apparatus for the production of continuous yarns or tows comprising high strength metal coated fibers |
US4661403A (en) * | 1982-03-16 | 1987-04-28 | American Cyanamid Company | Yarns and tows comprising high strength metal coated fibers, process for their production, and articles made therefrom |
US4909910A (en) * | 1982-03-16 | 1990-03-20 | American Cyanamid | Yarns and tows comprising high strength metal coated fibers, process for their production, and articles made therefrom |
US4578287A (en) * | 1984-10-09 | 1986-03-25 | The United States Of America As Represented By The Secretary Of The Navy | Process for producing graphite fiber/aluminum-magnesium matrix composites |
US6466414B1 (en) * | 2000-08-29 | 2002-10-15 | International Business Machines Corporation | Continuously wound fiber-reinforced disk drive actuator assembly |
EP2208706A1 (en) * | 2007-09-18 | 2010-07-21 | Shimane Prefectural Government | Metal covered carbon material and carbon-metal composite material using the metal covered carbon material |
EP2208706A4 (en) * | 2007-09-18 | 2013-03-27 | Shimane Prefectural Government | Metal covered carbon material and carbon-metal composite material using the metal covered carbon material |
Also Published As
Publication number | Publication date |
---|---|
FR1559658A (en) | 1969-03-14 |
DE1621379B2 (en) | 1972-05-04 |
GB1185349A (en) | 1970-03-25 |
DE1621379A1 (en) | 1972-05-04 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: AMOCO CORPORATION, A CORP. OF INDIANA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:UNION CARBIDE CORPORATION;REEL/FRAME:004634/0001 Effective date: 19860620 |