TW201023124A - Transparent pressure-sensitive adhesive sheet, image display apparatus comprising the same, and the production methods for making the image display apparatus - Google Patents
Transparent pressure-sensitive adhesive sheet, image display apparatus comprising the same, and the production methods for making the image display apparatus Download PDFInfo
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- TW201023124A TW201023124A TW98131672A TW98131672A TW201023124A TW 201023124 A TW201023124 A TW 201023124A TW 98131672 A TW98131672 A TW 98131672A TW 98131672 A TW98131672 A TW 98131672A TW 201023124 A TW201023124 A TW 201023124A
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J165/00—Adhesives based on macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Adhesives based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2201/00—Constructional arrangements not provided for in groups G02F1/00 - G02F7/00
- G02F2201/50—Protective arrangements
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2202/00—Materials and properties
- G02F2202/28—Adhesive materials or arrangements
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- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Nonlinear Science (AREA)
- Organic Chemistry (AREA)
- Mathematical Physics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Liquid Crystal (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Devices For Indicating Variable Information By Combining Individual Elements (AREA)
- Adhesive Tapes (AREA)
Abstract
Description
201023124 六、發明說明： 【發明所屬之技術領域】 本發明係關於-種透明感壓黏著薄片及—包含其之影像 顯示裝置。 【先前技術】 最近正廣泛利用一種在一影像顯示裝置中，將影像顯示 、螢幕與表面保護層或觸控面板間的間$，或表面保護層與 冑控面板間的間隙用一種透明材料（其折射率比空氣的折 射率更接近於該影像顯示螢幕）替代，藉此提高該影像顯 不裝置之透明度，並防止其亮度或對比度降低之方法。此 透月材料之實例包括透明的聚合物材料，如透明樹脂薄 板、感壓黏著劑及固化黏著劑（如矽酮凝膠 日本未審查專利公開案(公開)第〇9 197387號描述一種製 造-液晶顯示器裝置之方法，其中一液晶顯示面板之可視 侧與一透明保護板係藉由一呈透明聚合物材料之透明樹脂 •冑板而黏結成以下狀態：其中允許—揮發性液體藉由-透 明樹脂薄板(其係由包含可塑劑之聚合物所製造)而存在於 ㈣明樹脂薄板與該液晶顯示面板及該透明保護板中之一 或兩者之間。 日本未審查專利公開案（公開）第G6_59253號描述一種製 晶顯示器裝置之方法’其中反應性-可固化㈣凝 :構成無色且透明的彈性樹脂以作為透明聚合物材料。該 2 =明的彈性樹脂係以液體形式注人再經⑽，藉此 .液日日顯示面板與玻璃板固定。 143310.doc 201023124 曰本未審查專利公開案（公開）第03-204616號描述一種液 晶顯示器，其中一透明聚合物材料係經填充於一液晶顯示 裝置及-保護板之間。藉由將一不飽和聚酯溶於一可聚合 單體中而獲得之物質係用作該透明聚合物材料，且此材料 係被注入至該液晶顯示裝置及該保護板之間，再經固化。 日本未審查專利公開案（公開）第2〇〇7_315〇6號描述—種 用於光學元件之感壓黏著劑組合物，其包含：1〇〇質量份 (曱基）丙稀酸聚合物（A) ’該組分（A)包含：以1〇〇質量份 (甲基）丙烯酸烧酯計，為〇.〇1至5質量份由以下通式表示之 含羥基的（甲基）丙烯酸酯：CHfCR^COOR2(其中R1表示氣 原子或甲基，且R表示至少含有一個經基的經院基） 作為共聚合組分；及0.02至2質量份過氧化物。 【發明内容】 黏著劑、矽酮凝膠、感壓黏著劑等可提及作為透明材 料。但是，該黏著劑涉及處理液體的製程，且因此其問題 為製造方法可能變得很複雜。同樣地，由於該石夕酮凝膠的 膠黏強度較弱’因此長期可靠性就成了問題。相反地，感 壓黏著劑可解決此等問題’且因此在影像顯示裝置與保護 層覆盘物直接相連的結構中係有效的。然而，由於習知的 丙烯酸感壓黏著劑包含丙烯酸烷酯及丙烯酸，因此當該感 壓黏著劑之施用厚度變薄時，顯示器裝置中可能發生不均 勻。且在高溫及高濕條件下，該感壓黏著劑可能具有形成 氣泡並脫離的危險。 當⑴感壓黏著劑的施用厚度為10 μιη或更少，（ii)影像顯 143310.doc 201023124 不裝置之表面保護層具有不平整形狀，（iii)將感壓黏著薄 片施用於不平整形狀之表面，或（W)將感壓黏著薄片施用 於具有不平整形狀之影像顯示單元螢幕（如偏光板）時，需 要可阻止不均勻顯示之解決方法。除阻止不均勻顯示以 .外，亦要求提供一種透明感壓黏著薄片，其即使在被置於 高溫及高濕環境下時，亦可防止該薄片在一影像顯示裝置 (在下文中有時稱為「黏附體」）中，於表面保護層、影像 φ _示單元螢幕或觸控面板的界面處形成氣泡或脫離，且亦 不會造成白化。 根據本發明之一態樣，提供一種製造影像顯示裝置之方 法，其包含： (1) 製備一在1 Hz及80。(：下，儲藏彈性模量為丨〇xl〇4 Pa 或更小及l.〇xl〇3 Pa或更大之透明感壓黏著薄片，其中該 薄片包含（A)脂環烴樹脂，（B)無定形飽和聚烯烴樹脂， 含丙烯酸基團的樹脂，及（D)引發此等樹脂反應的引發 # 劑，且其中以100質量份組分（A)的含量計，組分（B)的含 量為10至200質量份，組分（c)的含量為1〇至2〇〇質量份， 及組分（D)的含量為〇.1至2〇質量份； (2) 將感壓黏著薄片黏貼至表面保護層或觸控面板上； (3) 將黏貼表面保護層或觸控面板的感壓黏著薄片的另 一面黏貼至影像顯示單元螢幕；且 (4) 使感壓黏著劑固化。 根據本發明之另一態樣，提供一種透明感壓黏著薄片， 其係用於在影像顯示裝置中，將表面保護層或觸控面板黏 143310.doc 201023124 貼至影像顯示單元螢幕上，或將表面保護層黏貼至觸控面 板。該透明感壓黏著薄片在1 Hz及8(TC下之儲藏彈性模量 為l.OxlO4 Pa或更小及i.〇xl〇3 Pa或更大。該透明感壓黏著 薄片包含（A)脂環煙樹脂，（B)飽和聚稀烴樹脂，（c)含丙稀 酸基團的樹脂，及（D)引發此等樹脂之反應的引發劑；且 其中，基於100質量份組分（A)的含量計，組分的含量 為10至200質量份，組分（C)的含量為1〇至2〇〇質量份，及 組分（D)的含量為〇.1至2〇質量份。 根據本發明之進一步態樣，提供一影像顯示裝置，其包 含一影像顯示單元、上述透明感壓黏著薄片、及—表面保 護層。 ” 文中，「儲藏彈性模量」意指在_6(rc至2〇〇t：之溫度範 圍（溫度的遞增率為5^/min)及！ Hz的剪切模式下，藉由黏 彈性測量所測得的儲藏彈性模量。在將與表面保護層及/ 或觸控Φ板黏|的感壓黏㈣片之另一面黏貼至影像顯示 單元螢幕的步驟中，應用溫度（通常為4〇至8〇。〇十分重 要。 藉由利用文中所提供的方&，製造出的影像顯示裝置^ 在該顯示螢幕上實質上無不均勻顯示，2)當黏貼至表面保 濩層影像顯示單元螢幕或觸控面板時，在界面中實質上 不形成氣泡’即使在高溫及高濕環境下亦係如此，W亦可 阻止在表面保護層或觸控面板與影像顯示單元榮幕之間黏 貼的感壓黏著薄片脫離。 換。之’利用以本發明另_態樣而提供的透明感壓黏著 143310.doc 201023124 薄片’當其在影像顯示裝置中系 T係用於將表面保護層或觸控 面板黏貼至影像顯示單元瑩篡 平凡愛幕，或將表面保護層黏貼至觸201023124 VI. Description of the Invention: [Technical Field] The present invention relates to a transparent pressure-sensitive adhesive sheet and an image display device comprising the same. [Prior Art] Recently, a transparent display material has been widely used in an image display device, and the gap between the image display, the screen and the surface protective layer or the touch panel, or the gap between the surface protective layer and the control panel is made of a transparent material ( A method in which the refractive index is closer to the image display screen than the refractive index of the air, thereby improving the transparency of the image display device and preventing the brightness or contrast from being lowered. Examples of the moon-permeable material include a transparent polymer material such as a transparent resin sheet, a pressure-sensitive adhesive, and a curing adhesive (for example, an anthraquinone gel, Japanese Unexamined Patent Publication (Kokai) No. Hei. In a method of a liquid crystal display device, a visible side of a liquid crystal display panel and a transparent protective plate are bonded to each other by a transparent resin and a seesaw plate of a transparent polymer material: wherein - the volatile liquid is allowed to be transparent A resin sheet (which is made of a polymer containing a plasticizer) is present between (4) a resin sheet and one or both of the liquid crystal display panel and the transparent protective sheet. Japanese Unexamined Patent Publication (Kokai) No. G6_59253 describes a method of crystallizing display device 'where reactive-curable (four) coagulation: forming a colorless and transparent elastic resin as a transparent polymer material. The 2 = bright elastic resin is injected in liquid form and then (10), whereby the liquid display panel is fixed to the glass plate. 143310.doc 201023124 Unexamined Patent Publication (Kokai) No. 03-204616 A liquid crystal display in which a transparent polymer material is filled between a liquid crystal display device and a protective plate. A substance obtained by dissolving an unsaturated polyester in a polymerizable monomer is used as the transparent material. a polymer material, which is injected between the liquid crystal display device and the protective plate, and then cured. Japanese Unexamined Patent Publication (Kokai) No. Hei No. Hei. A pressure-sensitive adhesive composition comprising: 1 part by mass of (mercapto)acrylic acid polymer (A) 'This component (A) comprises: 1 part by mass of (meth)acrylic acid ester 1 to 5 parts by mass of a hydroxyl group-containing (meth) acrylate represented by the following formula: CHfCR^COOR2 (wherein R1 represents a gas atom or a methyl group, and R represents a scholastic system containing at least one warp group) As a copolymerization component; and 0.02 to 2 parts by mass of a peroxide. [Invention] An adhesive, an anthrone gel, a pressure-sensitive adhesive, or the like can be mentioned as a transparent material. However, the adhesive involves a treatment liquid. Process, and therefore the problem is the manufacturer The method may become complicated. Similarly, the long-term reliability becomes a problem due to the weak adhesive strength of the oxacinone gel. Conversely, pressure-sensitive adhesives can solve such problems' and thus in the image The display device is effective in a structure directly connected to the protective layer covering. However, since the conventional acrylic pressure-sensitive adhesive contains an alkyl acrylate and an acrylic acid, when the application thickness of the pressure sensitive adhesive is thin, the display Non-uniformity may occur in the device, and under high temperature and high humidity conditions, the pressure sensitive adhesive may have the risk of forming bubbles and detaching. (1) The application pressure of the pressure sensitive adhesive is 10 μm or less, (ii) image 143310.doc 201023124 The surface protective layer of the non-device has an uneven shape, (iii) applying the pressure-sensitive adhesive sheet to the surface of the uneven shape, or (W) applying the pressure-sensitive adhesive sheet to the image display having an uneven shape For unit screens (such as polarizers), you need a solution that prevents uneven display. In addition to preventing uneven display, it is also required to provide a transparent pressure-sensitive adhesive sheet which can prevent the sheet from being imaged on an image display device even when placed in a high temperature and high humidity environment (hereinafter sometimes referred to as In the "adhesive body", bubbles or detachment are formed at the interface of the surface protective layer, the image φ_display unit screen or the touch panel, and whitening is not caused. According to an aspect of the present invention, a method of manufacturing an image display apparatus comprising: (1) preparing one at 1 Hz and 80 is provided. (:, a transparent pressure-sensitive adhesive sheet having a storage elastic modulus of 丨〇xl〇4 Pa or less and l.〇xl〇3 Pa or more, wherein the sheet contains (A) an alicyclic hydrocarbon resin, (B) An amorphous saturated polyolefin resin, an acrylic group-containing resin, and (D) an initiator which initiates the reaction of the resins, and wherein the component (B) is contained in an amount of 100 parts by mass of the component (A) The content is 10 to 200 parts by mass, the content of the component (c) is 1 to 2 parts by mass, and the content of the component (D) is 0.1 to 2 parts by mass; (2) the pressure is adhered The sheet is adhered to the surface protection layer or the touch panel; (3) the other side of the pressure-sensitive adhesive sheet adhered to the surface protection layer or the touch panel is adhered to the image display unit screen; and (4) the pressure-sensitive adhesive is cured. According to another aspect of the present invention, a transparent pressure-sensitive adhesive sheet is provided for attaching a surface protection layer or a touch panel to a screen of an image display unit in an image display device, or The surface protective layer is adhered to the touch panel. The transparent pressure-sensitive adhesive sheet is stored at 1 Hz and 8 (TC) The modulus is l.OxlO4 Pa or less and i.〇xl〇3 Pa or more. The transparent pressure-sensitive adhesive sheet comprises (A) alicyclic resin, (B) saturated polyolefin resin, (c) a resin of an acrylic group, and (D) an initiator which initiates a reaction of the resins; and wherein the content of the component is 10 to 200 parts by mass based on 100 parts by mass of the component (A), the group The content of the component (C) is from 1 to 2 parts by mass, and the content of the component (D) is from 0.1 to 2 parts by mass. According to a further aspect of the present invention, there is provided an image display device comprising An image display unit, the above transparent pressure-sensitive adhesive sheet, and a surface protective layer. In the text, "storage elastic modulus" means a temperature range of _6 (rc to 2〇〇t: (the rate of temperature increase is 5) ^/min) and ! Hz shear mode, measured by the viscoelasticity of the measured elastic modulus. In the adhesion with the surface protective layer and / or touch Φ plate | Apply the temperature (usually 4〇 to 8〇) in the step of sticking to the screen of the image display unit. By using the information provided in the text &, the image display device manufactured ^ has substantially no uneven display on the display screen, 2) when pasted to the surface protection layer image display unit screen or touch panel, substantially no bubbles are formed in the interface. Even in high-temperature and high-humidity environments, W can also prevent the pressure-sensitive adhesive sheets that are adhered between the surface protective layer or the touch panel and the image display unit, and the detached pressure-sensitive adhesive sheets. The transparent adhesive pressure provided by the 143310.doc 201023124 sheet is used in the image display device to attach the surface protection layer or the touch panel to the image display unit, or to protect the surface. Layer stick to touch
控面板時，實質上將不會產哇X 个賞座生不均勻顯示。特定而言，即 使當該透明感壓黏著薄片施用 乃她用於具有不規則形狀之表面保 護層，或當其施用於具有不娟刖 /、π个現則形狀之影像顯示單元螢幕 (如偏光板）時，其仍可避免不均勻顯示的產生。When the panel is controlled, it will not produce the W-shaped X-shaped uneven display. In particular, even when the transparent pressure-sensitive adhesive sheet is applied, it is used for a surface protective layer having an irregular shape, or when it is applied to an image display unit screen having a shape of a non-jujube/, π, such as a polarized light. When the board is used, it can still avoid the occurrence of uneven display.
且’當該透明感壓li著薄片被黏貼至影像顯示裝置中的 表面保護層、影像顯示單元螢幕或觸控面板時，其在界面 中實質上不形成氣泡’ J即使在高溫及高濕環境下亦係如 此。此外，其可避免將表面保護層或觸控面板黏貼至影像 顯示單元螢幕後，或將表面保護層黏貼至觸控面板後發生 脫離現象。 另外，由於該透明感壓黏著（PSA)薄片具有低吸水性， 因此其可防止影像顯示裝置中發生白化。 【實施方式】 現轉而描述透明PSA薄片之組分，組分（A)係脂環烴樹 脂。該樹脂具有極佳吸水性且與無定形飽和聚烯烴樹脂 (如聚異丁烯樹脂）相容’且可控制室溫下之預固化組合物 的儲藏彈性模量。特定而言，可提及稱為增黏劑的石油樹 脂、箱烯樹脂、松香樹脂，及其氫化樹脂、及與芳族樹脂 共聚合之經改質的樹脂。 特疋吕之’脂環烴樹脂包括萜稀樹脂（Clearon P、Μ及K 系列等）、松香及松香酯樹脂（Foral AX、Foral 105、Pensel A、Estergum Η、Superester A系列等）、歧化松香及歧化松 143310.doc 201023124 香酯樹脂（Pine Crystal系列等）、基於氫化二環戊二烯之樹 脂（Escorez 5300及5400系列、Eastotac Η系列等），其等係 基於C5石油樹脂的氫化樹脂，且此等C5石油樹脂係藉由 使石腦油熱分解所形成的C5餾分（如戊烯、異戊二烯、胡 椒驗及1,3 -戊一稀）共聚合而獲得、經芳族改質之基於部分 風化一環戊二稀之樹脂（Escorez 5 600系列等）、基於C9石 油樹脂之氫化樹脂（Alcon P或Μ系列），此等C9石油樹脂係 藉由使石腦油熱分解所形成之C9餾分（如茚、乙烯基甲 苯、α-或β-甲基苯乙烯）共聚合而獲得、上述C5&C9餾分 之共聚合石油樹脂的氫化樹脂（I_Marv系列）、及類似物。 在此等聚合物中，就可獲得低吸水性及透明度而言，以氫 化樹脂較佳。 氫化樹脂之實例包括，例如氫化率不同之自部分氫化至 完全氫化之樹脂，且可使用任何其等。然而，從獲得吸水 性、與黏合劑聚合物之相容性及透明度的觀點而言，以完 全氫化者較佳。 脂環烴樹脂具有一軟化點（環球軟化點）。依據感壓黏著 性、操作溫度及組合物製造的難易程度，可使用具有任何 環球軟化點的脂環烴樹脂。通常，可使用環球軟化點在約 50至200°C，或約70至150。(：之間者。 脂環烴樹脂之重量平均分子量通常可在約2〇〇至5〇〇〇之 間，且在約500至3,000之間者可能特別合適。在此等範圍 内，可降低在黏貼溫度下的儲藏彈性模量，且可獲得與無 定形聚缚烴之相容性。 143310.doc 201023124 在本發明之透明感壓黏著薄片中，脂環烴樹脂可以不同 比例與無定形飽和聚烯烴混合。通常，相對於100質量份 脂環烴樹脂，該飽和聚烯烴最佳以10質量份或20質量份之 下限含量及200質量份或1 50質量份之上限含量混合。 第二組分（B)(無定形聚烯烴）係實質上不含碳-碳雙鍵或 三鍵的聚烯烴。在該飽和聚烯烴所包含的碳·碳鍵中，90〇/〇 或更多係單鍵。該飽和聚烯烴之實例包括聚異丁烯、聚α_ 烯烴、乙烯丙烯共聚物、乙烯α-烯烴共聚物、丙烯α_稀烴 共聚物、氫化聚丁二烯、及其與苯乙烯之嵌段共聚物及類 似物。其等可單獨或以兩種或更多種之組合使用。 無疋形聚合物係指結.晶度極低或無法進入結晶態之聚合 物。在無定形聚合物中，其玻璃轉化溫度可經測量，但溶 點無法測量。當使用無定形聚合物時，不會因為結晶作用 而導致透明度降低。 此外’更詳細言之’以具有飽和聚烯烴嵌段及芳族乙烯 φ 基單體嵌段之嵌段共聚物（下文稱為「嵌段共聚物」）作為 無定形飽和聚烯烴較佳。此嵌段共聚物具有包含實質上無 • 碳-碳雙鍵或三鍵之聚烯烴的第一嵌段，及包含芳族乙烯 基單體之第二嵌段。在該飽和聚烯烴嵌段所包含的碳-碳 鍵中，90〇/〇或更多係單鍵。芳族乙烯基單體之實例包括苯 乙烯、對-甲基苯乙烯、α_甲基苯乙烯、節及類似物。此 等可單獨或以兩種或更多種之組合使用。嵌段共聚物之實 例包括，例如：苯乙烯-乙烯_丙烯-苯乙烯嵌段共聚物、笨 乙烯-乙烯-丙烯嵌段共聚物、苯乙烯_乙烯_丁烯-苯乙烯嵌 143310.doc •9· 201023124 段共聚物及類似物。 在該等之中，以飽和聚異丁稀較佳。聚異丁稀係含有聚 異丁烯骨架的樹脂。該聚異丁烯樹脂可藉由在路易斯酸觸 媒（如氯化銘及三氟化蝴）的存在下，僅使異戊二稀、及異 戊二烯與正-丁烯、或異戊二烯或丁二烯聚合而製備。特 疋而& ’已知該聚異丁稀樹脂之商標有：Vistanex (埃克 森化學〇口公司）、Hycar (古德裡奇公司）、〇ppan〇i (巴斯夫 公司）、JSR butyl (日本合成橡膠有限公司）、及類似物。 用於本發明之該無定形飽和聚烯烴係與脂環烴樹脂 而度相容，且因此可形成一透明薄膜。由於飽和聚烯烴具 有低表面能，因此當其作為感麼黏著劑時，其可很容易在 黏附體上塗覆，且在界面中不易產生空隙。此外，由於其 吸水性低，因此其適合作為薄片材料的基質樹脂。 無定形飽和聚烯烴之重量平均分子量（藉由Gpc方法所 獲得的根據聚苯乙烯的分子量）約為1〇〇〇〇或更多及 2,000’0〇〇或更少，尤其約為1〇〇〇〇〇或更多及1，麵，刚或 更少。在此範圍内，可獲得流動性，且可維持足夠的耐熱 性。 第三組分（C)(可固化樹脂）可增加固化前組合物的流動性 及對黏附體的可潤濕性，且亦可依循不規則表面，藉此阻 止液阳顯不器中產生不均勻顯示。此外，固化可增強保持 強度亦有可鯭藉由其添加量及類型來控制固化後之物理 性質，使其達到所需的物理性質。 可固化樹月曰（C)可為任何熱固性樹脂及輻射（光卜可固化 143310.doc 201023124 樹脂。 可固化樹脂（液態單體及/或募聚物）之實例包括在工業中 被稱為可固化丙烯酸化合物的物質者。在一態樣中，其等 可選自丙烯酸化胺基甲酸酯、丙烯酸環氧樹脂、具有 不飽和羰基之胺基樹脂衍生物、乙烯屬不飽和化合物、至 少具有一個丙烯酸酯基團之異氰脲酸酯衍生物'至少具有 一個丙烯酸酯基團之異氰酸酯、及其混合物。 Φ 可固化丙烯酸化合物的分子中通常含有（甲基）丙烯醯 基，且分子量為70至700，且在一實施例中為8〇至6〇〇。其 通常包括丙烯酸酯或甲基丙烯酸酯。光可固化丙烯酸化合 物之實例包括在以下兩段中描述的物質： 單官能丙烯酸單體之實例包括含有直鏈烷基的（甲基）丙 烯酸酯，如：（曱基）丙烯酸月桂酯、（曱基）丙烯酸鯨蠟酯 (n-C16)(其中「η」意指「正（直鏈）」類型，且「ci6」表 不16個碳原子）、（曱基）丙烯酸硬脂酯（n-C18)、（甲基）丙烯 • 酸芳烷酯（n-C20)及（曱基）丙烯酸二十二烷酯（n-C22);及包 含分支鏈烷基的（甲基）丙烯酸酯，如：（甲基）丙烯酸2_乙 . 基己酯、（甲基）丙烯酸異辛醋、（甲基）丙烯酸異壬醋、（曱 基）丙烯酸異癸酯、（曱基）丙烯酸異十二烷醋、（曱基）丙烯 酸異十三烷酯、（甲基）丙烯酸異肉豆蔻酯、（甲基）丙烯酸 異鯨蠟酯（異_C16)、（曱基）丙烯酸異硬脂酯（異_ci8)、（曱 基）丙烯酸2-辛基十二碳烷酯（異_C2〇)。亦可提及脂環族 (甲基）丙烯酸酯，如：（曱基）丙烯酸環己醋、（甲基）丙烯酸 異冰片酯、（曱基）丙烯酸第三_ 丁基環己酯及（甲基）丙烯酸 143310.doc 11 201023124 二環戊酯。亦可提及經取代的丙烯醯胺，如：N，N-二甲基 丙烯醯胺、N，N-二乙基丙烯醯胺、丙烯醯嗎啉、Ν,Ν-二曱 基胺基丙基丙烯醯胺、異丙基丙烯醯胺、第三-丁基丙烯 酿胺及第三-辛基丙稀醢胺。 多官能單體之實例包括己二醇（甲基）丙烯酸酯、二（甲 基）丙烯酸新戊酯、壬二醇二（曱基）丙烯酸酯、癸二醇二 (甲基）丙烯酸酯、十二烷二酵二（曱基）丙烯酸酯、環己烷 二曱醇二（甲基）丙烯酸酯、三環癸烷二甲醇二（甲基）丙烯 酸酯、氫化雙酚Α二（曱基）丙烯酸酯、氫化聚丁二烯二（甲 基）丙烯酸酯、氫化異戊二烯二（甲基）丙烯酸酯、三羥甲基 丙烷三（曱基）丙烯酸酯、及類似物。亦可使用係多元醇的 丙烯酸酯’以在經由胺基曱酸酯鍵寡聚合之丙烯醯單體中 使用。亦可使用其混合物。 在上述可用實施例中，通常以含有長鏈，或9個或更多 個碳之脂環族骨架的（曱基）丙烯酸酯樹脂較佳。通常，含 有（甲基）丙烯醯基或縮水甘油基之光可固化樹脂具有相當 高極性，且因此與極性極低的飽和烯烴極不相容，但此等 化合物可與脂環烴樹脂及飽和聚烯烴之混合物相 容。 在本發明之感壓黏著薄片中，可將（C)可固化樹脂與（A) 脂環烴樹脂及（B)無定形飽和聚烯烴以各種比例混合。通 常，相對於100質量份組分及10至2〇〇質量份組分（B)， 組分（C)的含量可在1 〇至2〇〇質量份之範圍内，且更佳係在 50至150質量份之間。 143310.doc •12· 201023124 藉由使用此等範圍，可獲得足夠的内聚性，且可獲得在 固化期間收縮很小且不會被輕易剝落的組合物。 作為自由基聚合引發劑之輻射（光）聚合引發劑的特定實 例包括：二苯曱酮、2-甲基444-(甲硫基）苯基]·2·嗎啉基 , 丙烷酮、樟腦醌、安息香、安息香曱基醚、安息香-正_ 丙基醚、安息香·正-丁基醚、苄基、對_甲基二苯曱酮、雙 乙醯、曙紅、硫堇、通式為（(ch^nqhaco的米其勒酮 φ (Michler's ketone)、苯乙酮、2_氣噻噸酮、蒽醌、氯蒽 醌、2-曱基蒽醌、α-羥基異丁醯苯、對_異丙基羥基異 丁酿笨α，α _一氯本氧基苯乙酮、1-經基-1-環己基苯 乙酮、2,2-二甲氧基-2-苯基苯乙酮、甲基安息香甲酸酯、 二氯噻噸酮、二異丙基噻噸酮、苯基二硫_2_亞硝基苐、丁 偶姻（butyloine)、菌香偶姻乙基醚、四甲基秋蘭姆二硫化 物、2,2-二甲氧基-1，2-二苯基乙_丨·酮、丨_羥基環己基-苯 基-酮、2-羥基-2-曱基-1-苯基-丙_丨_酮、羥基乙氧 • 基）-笨基]_2-經基-2-甲基―1-丙I酮、2-經基小{4_[4_(2-經 基-2-曱基-丙醯基）_苄基]苯基卜2_甲基_丙_丨·酮、2_甲基小 • (4_甲硫基苯基）-2-嗎啉基丙-1-酮、2-苄基_2-二甲基胺基_ • 1_(4-嗎啉基苯基）· 丁酮-12-(二甲基胺基）_2_[(4_甲基笨基） 甲基]-l-[4-(4-嗎啉基）苯基]_ι_丁酮、2,4,6•三曱基苯曱醯 基-二苯基-氧化膦（phosphoinoxide)、雙（2,4,6_三曱基苯曱 醯基）苯基氧化膦及類似物。 作為自由基聚合引發劑之熱聚合引發劑的特定實例包括 有機過氧化物，如：過氧化異丁酿、過氧化新癸酸異丙苯 143310.doc -13· 201023124 酯、過氧基二碳酸二異丙酯、過氧基二碳酸二正丙酯、過 氧化新己酸異丙苯酯、過氧基二碳酸二（2_乙氧基乙酯）、 過氧基二碳酸二（甲氧基異丙酯）、過氧基二碳酸二（2_乙基 己酯）、過氧化新癸酸第三丁酯、過氧化新己酸第三己 酯、過氧化新己酸第三丁醯酯、過氧化特戊酸第三丁醯 酯、過氧化月桂醯、過氧化辛酸異丙苯酯及過氧化苯甲 醢。亦可提及偶氮化合物，如r 2,2，-偶氮雙（4-甲氧基·2,4_ 一曱基戊腈）、2,2’-偶氮雙（環丙基丙腈）、2,2，偶氮雙（2-甲 基戊腈）、2,2，-偶氮雙異丁腈、2，广偶氮雙（2_甲基丁腈）、 2,2’-偶氮雙（丙酸2-甲酯）及4,4，_偶氮雙（心氰基戊酸）。 所包含之（D)輻射（光）聚合引發劑的含量可係〇」至加質 量份且在某些實施例中係0.5至5質量份。在此範圍内，丙 烯酸單體可經較佳聚合，且可獲得該樹脂組合物之儲藏安 定性。 藉由使用上述組合物中之上述單體組分，所獲得之感壓 黏著薄片可於固化前，在黏貼時獲得足夠的依循性，且在 固化後可具有足夠的保持力。通常，術語「依循性」描述 -種情況，其中該PSA薄片具有足夠高的流動性以使表 面保護層及該PSA薄片之間即使在表面保護層不平整時， 實質上亦不含空隙及分隔。藉由使用具有足夠依循性之透 明感壓黏著薄片，即使當透明感壓黏著薄片施用於—馬像 顯示單元螢幕(其具有形狀不平整的表面保護層或形：不 平整的層體（如偏光板））上時，亦可吸收不均勻性，鈇果將 影像顯示裝置中的不均勻顯示消除…由於該黏；薄片 143310.doc 201023124 具有充足的流動性，因此即使當該黏著薄片本身的厚度有 變化8^其仍可黏貼於黏附體的表面而不產生空隙，且 可阻止在影像顯示裝置中產生不均勻顯示。And when the transparent pressure is applied to the surface protective layer, the image display unit screen or the touch panel in the image display device, substantially no bubbles are formed in the interface. J Even in a high temperature and high humidity environment This is also the case. In addition, it can avoid the phenomenon that the surface protection layer or the touch panel is adhered to the image display unit screen or after the surface protection layer is adhered to the touch panel. In addition, since the transparent pressure-sensitive adhesive (PSA) sheet has low water absorption, it can prevent whitening from occurring in the image display device. [Embodiment] A component of a transparent PSA sheet is described, and component (A) is an alicyclic hydrocarbon resin. The resin has excellent water absorbability and is compatible with an amorphous saturated polyolefin resin such as polyisobutylene resin and can control the storage elastic modulus of the pre-cured composition at room temperature. Specifically, there may be mentioned a petroleum resin called a tackifier, a boxene resin, a rosin resin, a hydrogenated resin thereof, and a modified resin copolymerized with an aromatic resin. Tequila' alicyclic hydrocarbon resins include bismuth resin (Clearon P, Μ and K series, etc.), rosin and rosin ester resins (Foral AX, Foral 105, Pencel A, Estergum Η, Superester A series, etc.), disproportionated rosin And disproportionate 143310.doc 201023124 succinate resin (Pine Crystal series, etc.), hydrogenated dicyclopentadiene-based resin (Escorez 5300 and 5400 series, Eastotac Η series, etc.), which are based on hydrogenated resin of C5 petroleum resin, And these C5 petroleum resins are obtained by copolymerizing C5 fractions formed by thermal decomposition of naphtha (such as pentene, isoprene, pepper and 1,3-penta-diuret). The quality is based on partially weathered pentane resin (Escorez 5 600 series, etc.), hydrogenated resin based on C9 petroleum resin (Alcon P or bismuth series), which are formed by thermal decomposition of naphtha. A hydrogenated resin (I_Marv series) of a copolymerized petroleum resin of the above C5 & C9 fraction obtained by copolymerization of a C9 fraction (e.g., hydrazine, vinyl toluene, α- or β-methylstyrene), and the like. Among these polymers, in order to obtain low water absorption and transparency, it is preferred to hydrogenate the resin. Examples of the hydrogenated resin include, for example, a partially hydrogenated to fully hydrogenated resin having a different hydrogenation rate, and any of them can be used. However, from the viewpoint of obtaining water absorbability, compatibility with a binder polymer, and transparency, it is preferred to use complete hydrogenation. The alicyclic hydrocarbon resin has a softening point (the ring and ball softening point). An alicyclic hydrocarbon resin having any ring and ball softening point can be used depending on the pressure-sensitive adhesiveness, the operating temperature, and the ease of manufacture of the composition. Generally, the ring and ball softening point can be used at about 50 to 200 ° C, or about 70 to 150. (: Between. The weight average molecular weight of the alicyclic hydrocarbon resin may generally be between about 2 Torr and 5 Torr, and may be particularly suitable between about 500 and 3,000. Within these ranges, it may be lowered The storage elastic modulus at the pasting temperature, and the compatibility with the amorphous polyether hydrocarbon can be obtained. 143310.doc 201023124 In the transparent pressure-sensitive adhesive sheet of the present invention, the alicyclic hydrocarbon resin can be saturated in different proportions and amorphous. The polyolefin is mixed. Usually, the saturated polyolefin is preferably mixed at a lower limit content of 10 parts by mass or 20 parts by mass and an upper limit content of 200 parts by mass or 150 parts by mass with respect to 100 parts by mass of the alicyclic hydrocarbon resin. Sub-(B) (amorphous polyolefin) is a polyolefin which does not substantially contain a carbon-carbon double bond or a triple bond. Among the carbon·carbon bonds contained in the saturated polyolefin, 90〇/〇 or more is a single Examples of the saturated polyolefin include polyisobutylene, poly-α-olefin, ethylene propylene copolymer, ethylene α-olefin copolymer, propylene α_dilute hydrocarbon copolymer, hydrogenated polybutadiene, and a block thereof with styrene. Copolymers and the like. They may be used alone or in two Use in combination or more. The non-ruthenium polymer refers to a polymer with a very low crystallinity or inability to enter a crystalline state. In an amorphous polymer, the glass transition temperature can be measured, but the melting point cannot be measured. When an amorphous polymer is used, there is no decrease in transparency due to crystallization. Furthermore, 'more specifically' is a block copolymer having a saturated polyolefin block and an aromatic ethylene φ group monomer block (hereinafter referred to as "Block copolymer" is preferred as the amorphous saturated polyolefin. The block copolymer has a first block comprising a polyolefin substantially free of carbon-carbon double or triple bonds, and comprises an aromatic vinyl group. a second block of monomers. Among the carbon-carbon bonds contained in the saturated polyolefin block, 90 〇/〇 or more are single bonds. Examples of the aromatic vinyl monomer include styrene, p-A. Styrene, α-methylstyrene, rhodium and the like. These may be used singly or in combination of two or more. Examples of the block copolymer include, for example, styrene-ethylene-propylene-benzene Ethylene block copolymer, stupid ethylene-ethylene-propylene Copolymer, styrene_ethylene_butylene-styrene embedded 143310.doc •9·201023124 segment copolymer and the like. Among them, saturated polyisobutylene is preferred. Polyisobutylene contains poly a resin of an isobutylene skeleton. The polyisobutylene resin can be made only by isoprene, isoprene and n-butene in the presence of a Lewis acid catalyst such as chlorinated and trifluoromethane. Or prepared by polymerization of isoprene or butadiene. Specially known & 'The trademarks of the polyisobutylene resin are known as: Vistanex (Exxon Chemical Company), Hycar (Goodrich Company), 〇ppan〇i (BASF Corporation), JSR butyl (Japan Synthetic Rubber Co., Ltd.), and the like. The amorphous saturated polyolefin used in the present invention is compatible with an alicyclic hydrocarbon resin, and thus can form a Transparent film. Since the saturated polyolefin has a low surface energy, it can be easily coated on the adherend when it is used as an adhesive, and voids are not easily generated in the interface. Further, since it has low water absorbency, it is suitable as a matrix resin for a sheet material. The weight average molecular weight of the amorphous saturated polyolefin (molecular weight according to polystyrene obtained by the Gpc method) is about 1 Torr or more and 2,000 Å or less, especially about 1 Torr. 〇〇〇 or more and 1, face, just or less. Within this range, fluidity can be obtained and sufficient heat resistance can be maintained. The third component (C) (curable resin) can increase the fluidity of the composition before curing and the wettability to the adherend, and can also follow the irregular surface, thereby preventing the liquid positive display from being produced. Display evenly. In addition, curing can enhance the strength of retention. It is also possible to control the physical properties after curing by the amount and type of addition to achieve the desired physical properties. The curable tree sap (C) can be any thermosetting resin and radiation (light curing 143310.doc 201023124 resin. Examples of curable resin (liquid monomer and / or merging polymer) include in the industry is called A substance which cures an acrylic compound. In one aspect, the material may be selected from the group consisting of an acrylated urethane, an acrylic epoxy resin, an amine-based resin derivative having an unsaturated carbonyl group, an ethylenically unsaturated compound, and at least An isocyanurate derivative of an acrylate group 'isocyanate having at least one acrylate group, and a mixture thereof. Φ The curable acrylic compound usually contains a (meth) acrylonitrile group and has a molecular weight of 70. Up to 700, and in one embodiment from 8 to 6 Å. It typically comprises an acrylate or methacrylate. Examples of photocurable acrylic compounds include those described in the following two paragraphs: Monofunctional acrylic monomers Examples include (meth) acrylates containing a linear alkyl group such as: lauryl (meth) acrylate, cetyl (meth) acrylate (n-C16) (wherein η" means "positive (straight chain)" type, and "ci6" does not represent 16 carbon atoms), (mercapto) stearyl acrylate (n-C18), (meth) propylene acid aralkyl ester ( n-C20) and (fluorenyl) behenyl acrylate (n-C22); and (meth) acrylate containing a branched alkyl group, such as: (meth)acrylic acid 2-ethyl hexyl hexyl ester, (meth)acrylic acid isooctyl vinegar, (meth)acrylic isophthalic acid vinegar, (mercapto)isodecyl acrylate, (decyl)isododecyl vinegar, (decyl)isotridecyl acrylate, ( Isomyristyl methyl methacrylate, isocetyl (meth) acrylate (iso-C16), isostearyl acrylate (iso-ci8), 2-octyl-12 (fluorenyl) acrylate Carbamate (iso-C2〇). Also mentioned are alicyclic (meth) acrylates such as: (fluorenyl) acrylate hexaacetate, isobornyl (meth) acrylate, (mercapto) acrylate Tri-butylcyclohexyl ester and (meth)acrylic acid 143310.doc 11 201023124 Dicyclopentyl ester. Mention may also be made of substituted acrylamides such as N,N-dimethyl acrylamide, N,N-diethyl acrylamide, propylene morpholine, hydrazine, hydrazine-didecylaminopropyl acrylamide, isopropyl acrylamide, tert-butyl acrylamide and third - Octyl acrylamide. Examples of polyfunctional monomers include hexanediol (meth) acrylate, neopentyl di(meth)acrylate, decanediol di(decyl) acrylate, decanediol II ( Methyl) acrylate, dodecane diyano(indenyl) acrylate, cyclohexanedimethanol di(meth) acrylate, tricyclodecane dimethanol di(meth) acrylate, hydrogenated bisphenol Bis(nonyl) acrylate, hydrogenated polybutadiene di(meth) acrylate, hydrogenated isoprene di(meth) acrylate, trimethylolpropane tris(decyl) acrylate, and the like Things. It is also possible to use a polyhydric alcohol acrylate 'for use in an acrylonitrile monomer which is oligomerically polymerized via an amino phthalate bond. Mixtures can also be used. In the above-mentioned usable examples, a (fluorenyl) acrylate resin usually having an alicyclic skeleton of a long chain or 9 or more carbons is preferred. In general, photocurable resins containing (meth)acrylonyl or glycidyl groups have a relatively high polarity and are therefore extremely incompatible with saturated olefins of extremely low polarity, but these compounds can be saturated with alicyclic hydrocarbon resins. The mixture of polyolefins is compatible. In the pressure-sensitive adhesive sheet of the present invention, the (C) curable resin and (A) alicyclic hydrocarbon resin and (B) amorphous saturated polyolefin may be mixed in various ratios. In general, the content of the component (C) may be in the range of 1 Å to 2 Å by mass, and more preferably 50%, based on 100 parts by mass of the component and 10 to 2 parts by mass of the component (B). Between 150 parts by mass. 143310.doc •12· 201023124 By using these ranges, sufficient cohesiveness can be obtained, and a composition which shrinks little during curing and which is not easily peeled off can be obtained. Specific examples of the radiation (photo) polymerization initiator as the radical polymerization initiator include: benzophenone, 2-methyl 444-(methylthio)phenyl]·2·morpholinyl, propane ketone, camphorquinone , benzoin, benzoin decyl ether, benzoin-n-propyl ether, benzoin·n-butyl ether, benzyl, p-methyldibenzophenone, diacetamidine, ruthenium, thioindigo, (ch^nqhaco's Michler's ketone, acetophenone, 2_ thioxanthone, anthraquinone, chloranil, 2-mercaptopurine, α-hydroxyisobutyl benzene, _ Isopropyl hydroxyisobutyl succinyl α,α _monochlorooxy acetophenone, 1-yl-1-cyclohexylacetophenone, 2,2-dimethoxy-2-phenylacetophenone , methyl benzoic acid ester, dichlorothioxanthone, diisopropyl thioxanthone, phenyl disulfide 2 - nitrosoguanidine, butoin (butyloine), oxalic acid ethyl ether, four Methyl thiuram disulfide, 2,2-dimethoxy-1,2-diphenylethyl ketone, hydrazine-hydroxycyclohexyl-phenyl-one, 2-hydroxy-2-indenyl -1-phenyl-propionyl-p-ketone, hydroxyethoxyxo)-p-phenyl]_2-pyridyl-2-methyl-l-propanone, 2-mercapto {4_[4_(2-Phenyl-2-indenyl-propenyl)-benzyl]phenyl-2-methyl-propionyl- ketone, 2-methylamine • (4-methylthiobenzene) 2-morpholinylpropan-1-one, 2-benzyl-2-dimethylamino} 1 -(4-morpholinylphenyl)butanone-12-(dimethylamino )_2_[(4_methylphenyl)methyl]-l-[4-(4-morpholinyl)phenyl]_ι-butanone, 2,4,6•trimercaptobenzoyl-di Phenyl-phosphooxide, bis(2,4,6-trimercaptophenyl)phenylphosphine oxide, and the like. Specific examples of the thermal polymerization initiator as a radical polymerization initiator include organic Oxide, such as: oxidized isobutylene, peroxy cumene phthalate 143310.doc -13· 201023124 ester, peroxydicarbonate diisopropyl ester, peroxydicarbonate di-n-propyl ester, peroxidation New cumyl hexanoate, bis(2-ethoxyethyl)peroxydicarbonate, bis(methoxyisopropyl)peroxydicarbonate, di(2-ethyl)peroxydicarbonate Hexyl ester), tert-butyl peroxy neodecanoate, trihexyl peroxy neohexanoate, tert-butyl peroxy neohexanoate, tert-butyl peroxypivalate Peroxidic laurel, cumene peroxyoctanoate and benzammonium peroxide. Also mentioned are azo compounds such as r 2,2,-azobis(4-methoxy·2,4_-fluorenyl) Valeronitrile), 2,2'-azobis(cyclopropylpropionitrile), 2,2, azobis(2-methylvaleronitrile), 2,2,-azobisisobutyronitrile, 2, Polyazobis(2-methylbutyronitrile), 2,2'-azobis(2-methylpropionate) and 4,4,-azobis(cardiocyanate). The (D) radiation (photo) polymerization initiator may be included in an amount of from 5% to 5 parts by mass, and in some embodiments from 0.5 to 5 parts by mass. Within this range, the acrylic monomer can be preferably polymerized, and the storage stability of the resin composition can be obtained. By using the above monomer components in the above composition, the pressure-sensitive adhesive sheet obtained can obtain sufficient compliance at the time of curing before curing, and can have sufficient holding force after curing. Generally, the term "dependency" describes a case in which the PSA sheet has a sufficiently high fluidity so that there is substantially no void and separation between the surface protective layer and the PSA sheet even when the surface protective layer is uneven. . By using a transparent pressure-sensitive adhesive sheet having sufficient compliance, even when a transparent pressure-sensitive adhesive sheet is applied to a horse-like display unit screen (which has an uneven surface layer or shape: uneven layer (such as polarized light) When the board)), it can also absorb the unevenness, and the result will eliminate the uneven display in the image display device... Due to the sticking; the sheet 143310.doc 201023124 has sufficient fluidity, so even when the thickness of the adhesive sheet itself There are variations 8 which can still adhere to the surface of the adherent without creating voids, and can prevent uneven display in the image display device.
因此，該感壓黏著薄片之依循性可以樹脂組合物之儲藏 彈性模量來表示。如果該樹脂組合物在8〇t：及i Hz下的儲 藏彈性模#為1.〇><1〇4 pa或更少、，#即使該當感壓黏著薄 片用/、有約10只瓜之形狀不平整表面的黏附體時，仍可 防止不均勻顯示發生。此外，如果該樹脂組合物在80它及 1 Hz下的儲藏彈性模量為〗〇xl〇4 Pa或更少，則即使該當 感壓黏著薄片施用於具有不平整形狀（其具有更大高度差） 或更複雜形狀之黏附體時，仍可減少不均勻顯示。 且，如果該樹脂組合物在8(TC及i Hz下的儲藏彈性模量 為l.〇xl〇3 Pa或更多，則該樹脂組合物在施用時不會外 流，且使用時不會有任何麻煩。可藉由適當地改變組分 A、B、C之種類、分子量及各組分的比例來調節樹脂組合 物之儲藏彈性模量。 口 此外，藉由賦予低吸水性，可防止在影像顯示裝置中產 生白化。防止白化的程度（透明度）可藉由混濁度值表示。 =混濁度值係根據JIS Κ 7136，藉由以下環境測試而測 侍。首先，將透明感壓黏著薄片黏貼至一透明附著體上 (例如影像顯示裝置之表面保護層）以形成層合物，使所得 之層。物在溫度為6〇〇c及相對濕度（RH)為9〇%的條件下靜 置3天，且接著在3天後測量該層合物的混濁度值。如果藉 由將透明感壓黏著薄片黏貼至影像顯示裝置之表面保護層 143310.doc •15· 201023124 上而獲得之層合物的混濁度值小於2%或更少，則可以判 斷未發生白化現象。 另外，該感壓黏著薄片所具有的透明度可使藉由將該黏 著薄片黏貼至一透明黏附體（例如，影像顯示裝置之表面 保護層）上而獲得之層合物，在可見光波長的光譜内，具 有90°/。或更高的總透光率（JIS κ 7361)。 除上述組分以外，該感壓黏著薄片亦可包含其他組分， 如填料、抗氧化劑及矽垸偶合劑。Therefore, the compliance of the pressure-sensitive adhesive sheet can be expressed by the storage elastic modulus of the resin composition. If the storage elastic modulus of the resin composition at 8 〇 t: and i Hz is 1. 〇 >< 1 〇 4 pa or less, # even if the pressure-sensitive adhesive sheet is used, there are about 10 When the shape of the melon is not flat, the unevenness of the surface can be prevented. Further, if the storage elastic modulus of the resin composition at 80 ° C and 1 Hz is 〇 〇 x 〇 4 Pa or less, even if the pressure-sensitive adhesive sheet is applied to have an uneven shape (which has a larger height difference) ) When the adhesive of a more complex shape is used, the uneven display can still be reduced. Moreover, if the resin composition has a storage elastic modulus of 8 (TC and i Hz of 1. 〇xl 〇 3 Pa or more, the resin composition does not flow out during application, and there is no use when it is used. Any trouble. The storage elastic modulus of the resin composition can be adjusted by appropriately changing the kind of the components A, B, C, the molecular weight, and the ratio of each component. Further, by imparting low water absorption, it can be prevented. Whitening occurs in the image display device. The degree of prevention of whitening (transparency) can be expressed by the turbidity value. = The turbidity value is measured by the following environmental test according to JIS Κ 7136. First, the transparent pressure-sensitive adhesive sheet is pasted. To a transparent attachment (for example, a surface protective layer of an image display device) to form a laminate, and the resulting layer is allowed to stand at a temperature of 6 〇〇 c and a relative humidity (RH) of 9 〇 %. The turbidity value of the laminate was measured after 3 days, and then after 3 days, if the laminate was obtained by adhering the transparent pressure-sensitive adhesive sheet to the surface protective layer 143310.doc •15·201023124 of the image display device. The turbidity value of the object is less than 2% or more , it can be judged that no whitening phenomenon occurs. In addition, the transparency of the pressure-sensitive adhesive sheet can be obtained by adhering the adhesive sheet to a transparent adhesive body (for example, a surface protective layer of an image display device). The composition has a total light transmittance (JIS κ 7361) of 90 ° / or higher in the spectrum of visible light wavelength. In addition to the above components, the pressure sensitive adhesive sheet may also contain other components such as a filler, Antioxidant and bismuth coupling agent.
該感壓黏著薄片之厚度並無特定限制，只要其足夠大使 之在黏貼至影像顯示裝置期間（在一影像顯示裝置中，當 將表面保護層或觸控面板層合至影像顯示單元之顯示表 面，或將表面保護層合至觸控面板時）不造成問題即可。 舉例而言，該感壓黏著薄片之厚度可在〇 〇25至1 mm之 間。當該感壓黏著薄片之厚度增加時，其對黏附趙（例如 聚合物薄膜（如PMMA或玻璃板））之黏著力將變高。The thickness of the pressure-sensitive adhesive sheet is not particularly limited as long as it is sufficiently large to be adhered to the image display device (in an image display device, when the surface protection layer or the touch panel is laminated to the display surface of the image display unit) , or when the surface protection layer is laminated to the touch panel, it does not cause a problem. For example, the pressure-sensitive adhesive sheet may have a thickness of between 25 and 1 mm. When the thickness of the pressure-sensitive adhesive sheet is increased, the adhesion to the adhesion (e.g., a polymer film (e.g., PMMA or glass plate)) will become high.
，接著，以下將參照圖！至4描述包含上述感壓二薄片之 影像顯示裝置。該影像顯示裝置包含一像 透明感壓黏著薄片及一表面一該 包含之透明感壓黏著薄片而t，可減輕透明 之内部殘留應力。 該影像顯示單元係未經特定限制，且其實例包括諸 射-或背光-型液晶顯示單元、電漿顯示單元、 (el)‘4不器及電子紙之影像顯示單元。在該影像顯示 之顯示表面上，可提供其他層體（其可係一層或多層、) 143310.doc • 16 - 201023124 偏光板（其有時具有形狀不規則之表面）。且，下述觸控面 板可存在於该影像顯示單元之顯示表面上。 ' 當配置於影像顯示裝置上時，該表面保護層係作為最外 層表面而經配置的層豸。該纟面保護層彳僅由聚合物薄 膜、玻璃板或類似物所組成，或可由與其他層共同形成的 複數層所組成。該表面保護層係未經特定限制，只要為通 常作為影像顯示裴置之保護膜或類似物的薄膜即可，且該 Φ 表面保護層可係例如丙烯酸樹脂薄膜（如聚甲基丙烯酸甲 酯（PMMA))、聚碳酸酯樹脂薄膜或玻璃板。該薄膜或玻璃 板之厚度係未經限制，但通常在〇.1至5〇1111之間。 表面保護層係複數個層所組成之層合物的情況下，賦予 該等功能或性質（如耐磨損性、抗刮性、抗污性、抗反射 性及抗靜電性）之層體可設置於影像顯示裝置之觀看者一 側上。用於賦予耐磨損性及抗刮性之層體可藉由塗佈可形 成硬質塗層之可固化樹脂組合物，且使該塗層固化而形 # 成。舉例而言，一包含由烷基三烷氧基矽烷（其係作為主 要組分）及膠體氧化矽所組成之矽烷混合物的部分縮合反 .應產物之塗料係經塗佈，接著在加熱條件下經固化以形成 固化膜，或者一包含多官能性丙烯酸酯為主要組分之塗料 係經塗佈，且以紫外光照射該塗膜，藉此可形成固化膜。 且，為確保具有抗污性，可形成一包含有機矽化合物或以 氟為主之化合物的樹脂層。此外，為獲得抗靜電性，可形 成一包含界面活性劑或導電性微細顆粒之樹脂層。賦予該 等功能或性質之層體較佳係不會抑制該表面保護層之透明 143310.doc -17- 201023124 度的薄膜’且在可實現此功能之範圍内較佳應儘可能薄。 賦予功能或性質之層體的厚度係未經限制，但通常在〇 〇5 至1 〇 μηι之間。Next, the following will refer to the figure! Up to 4, an image display device including the above-described pressure sensitive two sheets is described. The image display device comprises a transparent pressure-sensitive adhesive sheet and a surface and a transparent pressure-sensitive adhesive sheet contained therein to reduce the internal residual stress of the transparent. The image display unit is not particularly limited, and examples thereof include an image- or backlight-type liquid crystal display unit, a plasma display unit, an (el) '4' device, and an image display unit for electronic paper. On the display surface of the image display, other layers (which may be one or more layers) may be provided. 143310.doc • 16 - 201023124 Polarizer (which sometimes has an irregularly shaped surface). Moreover, the touch panel described below may be present on the display surface of the image display unit. When applied to an image display device, the surface protective layer acts as a layer on the outermost surface. The facet protective layer is composed only of a polymer film, a glass plate or the like, or may be composed of a plurality of layers formed together with other layers. The surface protective layer is not particularly limited as long as it is a film which is generally used as a protective film or the like of an image display device, and the Φ surface protective layer may be, for example, an acrylic resin film (e.g., polymethyl methacrylate ( PMMA)), polycarbonate resin film or glass plate. The thickness of the film or glass sheet is not limited, but is usually between 〇1 and 5〇1111. In the case where the surface protective layer is a laminate composed of a plurality of layers, a layer body imparting such functions or properties such as abrasion resistance, scratch resistance, stain resistance, antireflection and antistatic properties may be used. It is disposed on the viewer side of the image display device. The layer for imparting abrasion resistance and scratch resistance can be formed by coating a curable resin composition which can form a hard coat layer and curing the coating layer. For example, a coating comprising a partial condensation reaction product of a mixture of decane consisting of an alkyltrialkoxysilane (which is a major component) and a colloidal cerium oxide is coated, followed by heating. The cured film is cured to form a cured film, or a coating containing a polyfunctional acrylate as a main component is coated, and the coating film is irradiated with ultraviolet light, whereby a cured film can be formed. Further, in order to secure the stain resistance, a resin layer containing an organic cerium compound or a fluorine-based compound can be formed. Further, in order to obtain antistatic properties, a resin layer containing a surfactant or conductive fine particles can be formed. Preferably, the layer imparting such functions or properties does not inhibit the transparency of the surface protective layer and is preferably as thin as possible within the scope in which this function can be achieved. The thickness of the layer imparted to the function or property is not limited, but is usually between 〇 5 and 1 〇 μηι.
同樣地’表面保護層由複數個層所組成之層合物的情況 下，透明感壓黏著薄片面上可包含其他層，如印刷層、硬 質塗層及氣相沉積層’以覆蓋表面保護層之所有或部分區 域。該其他層在該表面保護層之部分區域中形成的情況 下，該表面保護層將具有形狀不規則的表面^該表面保護 層之厚度（包括該其他層）通常總計為〇1至6爪爪。附帶言 之’當使用該其他層作為下述遮光層之印刷層或氣相沉積 層時’該層之厚度通常係1G μηι或更少。在其他實施例 中，該層之厚度通常係10〇Mm或更少，或5〇μηΐ4更少。 圖1係關於包含上述透明感壓黏著薄片之影像顯示裝置 之一實施例的橫斷面圖。影像顯示裝置1〇具有以下結構： 其中-透明感壓黏著薄片3及一表面保護層4係以此順序堆 叠在-影像顯示單元i之顯示表面上。表面保護層4係由一Similarly, in the case where the surface protective layer is composed of a plurality of layers, the transparent pressure-sensitive adhesive sheet surface may include other layers such as a printed layer, a hard coat layer and a vapor deposited layer to cover the surface protective layer. All or part of the area. Where the other layer is formed in a partial region of the surface protective layer, the surface protective layer will have an irregularly shaped surface. The thickness of the surface protective layer (including the other layers) will generally total 〇1 to 6 claws. . Incidentally, when the other layer is used as a printed layer or a vapor-deposited layer of the light-shielding layer described below, the thickness of the layer is usually 1 G μm or less. In other embodiments, the thickness of the layer is typically 10 〇 Mm or less, or 5 〇 μη ΐ 4 less. BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a cross-sectional view showing an embodiment of an image display apparatus including the above-described transparent pressure-sensitive adhesive sheet. The image display device 1 has the following structure: wherein the transparent pressure-sensitive adhesive sheet 3 and a surface protective layer 4 are stacked in this order on the display surface of the image display unit i. Surface protection layer 4 is composed of one
連續層5及一遮光層6所組成，且具有形狀不平整的表面； 該遮光層6係設置於該連續層5之底表面的部分區域中（在 透明感壓黏著薄片3之兩側上遮光層6係藉由如下方式 形成：藉由適當方法（如網印）將可固化樹脂組合物之塗層 溶液（其中混合有著色劑）塗佈在連續層5之預定區域上，並 藉由適當的固化方法（如Uv照射）使塗層固化。透明感壓黏 者溥片3係經層合至表面保護層4之形狀不平整的表面側 上。透明感壓黏著薄片3具有可撓性，且因此即使表面保 1433l0.doc -18- 201023124The continuous layer 5 and a light shielding layer 6 are formed, and have a surface having an uneven shape; the light shielding layer 6 is disposed in a partial region of the bottom surface of the continuous layer 5 (shading on both sides of the transparent pressure-sensitive adhesive sheet 3) The layer 6 is formed by coating a coating solution of a curable resin composition (in which a coloring agent is mixed) on a predetermined region of the continuous layer 5 by a suitable method (such as screen printing), and by appropriate The curing method (such as Uv irradiation) cures the coating. The transparent pressure-sensitive adhesive sheet 3 is laminated on the uneven surface side of the surface protective layer 4. The transparent pressure-sensitive adhesive sheet 3 has flexibility. And therefore even the surface warranty 1433l0.doc -18- 201023124
護層4的形狀不平整及另外 一具有不平整表面形狀之層 體（如偏光板）設置於該影像顯示單元之顯示表面上該黏 著薄片本身的内部殘留應力亦可有所緩和，從而可防止該 影像顯示裝置出現不均句顯示。同樣地，透明感壓黏著薄 片3具有足夠高的黏著力及親水性，且因此即使在高溫及 高濕環境下 也不會在影像顯示單元丨之顯示表面與透明 感壓黏著薄片3，及透明感壓黏著薄片3與表面保護層4之 間的界面處產生發泡或脫離現象，且亦不會出現白化。影 像顯示裝置10可藉由例如將上述包含表面保護層4及透明 感壓黏著薄片3之層合物2層合至影像顯示單元丨之顯示表 面上而獲得。 圖2係關於包含上述透明感壓黏著薄片《影像顯示裝置 之另一實施例的橫斷面圖。在圖2中，影像顯示裝置2〇具 有以下結構：其中透明感難著薄片3及表面保護層4係以 此順序堆疊在-觸控面板7上（其係、存在於影像顯示單元1 ❹ 之顯示表面上）。層合物2的結構係與圖！所描述者相同， 其中透明感壓黏|薄片3及表面保護層4係以此順序堆疊。 觸控面板7係配置於影像顯示單元丨之顯示表面上，且影像 顯示裝置20所顯示之影像可透過㈣面板而看&。觸控面 板7係透明的且具有如下結構··一透明導電層係位於由玻 璃或聚乙稀對苯三甲酸醋（ΡΕΤ)所製造之兩塊透明板的各 自背面上，且此等透明板之透明導電層係相互面對排列成 八有小空隙的不接觸狀態。當觸控面板的操作者用手指或 筆按壓一透明板表面上的有關位置時，該透明板之背面上 143310.doc •19· 201023124 的導電層則與另一透明板之背面上的導電層接觸，並產生 僅可在有關位置導電的情況。此可導電的位置係經由感測 器進行電性檢測，藉此可確定操作者在觸控面板上所按的 位置。該觸控面板型顯示器係正用於pc(個人電腦）、手機 或移動終端中（如PDAp透明感壓黏著薄片3具有可撓性， 且因此即使表面保護層4的形狀不規則，該黏著薄片本身 的内部殘留應力亦可經緩和’從而可防止該影像顯示裝置 出現不均勻顯示。同樣地，透明感壓黏著薄片3具有足夠 高的黏著力及親水性，且因此即使在高溫及高濕環境下， 也不會在觸控面板7與透明感壓黏著薄片3,及透明感壓黏 著薄片3與表面保護層4之間的界面處產生發泡或脫離現 象，且亦不會出現白化。影像顯示裝置2〇可藉由（例如）將 上述包含表面保護層4及透明感壓黏著薄片3之層合物2層 合至影像顯示單元丨之顯示表面上的觸控面板7上而獲得。 圖3仍係關於包含上述透明感壓黏著薄片之影像顯示裝 置之另一實施例的橫斷面圖。在圖3中，影像顯示裝置3〇 具有以下結構：其中透明感壓黏著薄片3、觸控面板7、透 明感壓黏著薄片3'及表面保護層4係以此順序堆疊在影像顯 示單元1之顯示表面上。该層合物的結構係與圖丨所描述者 相同，其中透明感壓黏著薄片3,及表面保護層4係以此順序 堆疊。透明感壓黏著薄片3及透明感壓黏著薄片3·可包含相 同或不同的共聚物。透明感壓黏著薄片3及3,具有可撓性， 且因此即使表面保護層4的形狀不规则及另外，一具有不 規則表面形狀之層體（如偏光板）設置於影像顯示單元之顯 143310.doc -20· 201023124 ;表：上’每張黏著薄片本身的内部殘留應力亦可有所緩 :’：而可防止該影像顯示裝置出現不均句顯示。同樣 . :透明感壓黏著薄片3及3,具有足夠高的黏著力及親水 像顯且β因此即使在兩溫及高濕環境下’也不會在例如，影 mi之顯不表面與透明感壓黏著薄片3之間，或透 • 2 =著薄片3’與表面保護層4之間的界面處產生發泡或 "象，且亦不會出現白化。影像顯示裝置30可藉由 •(例如）將上述包含表面保護層4、透明感a黏著薄以、觸 二面板7及透明感壓黏著薄片3之層合物2層合至影像顯示 早兀1之顯示表面上而獲得。 要圖4仍係關於包含上述透明感難著薄片之影像顯示裝 之又-實施例的橫斷面圖。在圖4中，影像顯示裝置4〇 具有以下結構：其中透明感壓黏著薄片3、觸控面板7、及 表面保護層4係以此順序堆疊在影像顯示單it 1上。盘圖i 相似’表面保護層4在部分區域中具有遮光層，從而形成 #不平整形狀之表面。透明感壓黏著薄片3係藉由觸控面板7 而存在於表面保護層4之不平整形狀的表面側。透明感壓 #著薄片3具有可撓性’且因此即使—具有不平整表面形 狀之層體（如偏光板）設置於影像顯示單元之顯示表面上， 該黏著薄片本身的内部殘留應力亦可經緩和，從而可防止 該影像顯示震置出現不均句顯示。同樣地，透明感壓黏著 薄片3具有足夠高的黏著力及親水性，且因此即使在高溫 及焉濕環境下’也不會在影像顯示單元！之顯示表面與透 明感壓黏著薄片3 ’及透明感壓黏著薄片3與觸控面板7之 143310.doc 21 · 201023124 間的界面處產生發泡或脫離現象，且亦不會出現白化。影 像顯示裝置40可藉由（例如）將上述包含表面保護層4、觸控 面板7及透明感壓黏著薄片3之層合物2層合至影像顯示單 元1之顯示表面上而獲得。 根據本發明又一態樣，提供一包含上述影像顯示裝置之 電子裝置。該電子裝置係未經特定限制且包括：手機、個 人數位輔助器（PDA) '可攜式電子遊戲機、電子閱讀器終 端、汽車導航系統、可攜式音樂播放器、手錶或時鐘、電 視（TV)、攝像機、視訊播放器、數位照相機、全球定位系 統（GPS)裝置及個人電腦（PC)。 實例 以下將參照實例更詳細描述本發明，但本發明不限於此 等實例。 樣品製備方法 實例1 將100質量份作為脂環烴樹脂之基於氫化DCPD的樹脂 (由埃克森美孚公司製造之Escorez 5340)、17質量份作為 無定形飽和聚烯烴樹脂之飽和聚異丁烯樹脂（由巴斯夫公 司製造之Oppanol B100)、50質量份作為含丙烯酸基團之 樹脂的UV可固化丙烯酸酯樹脂（由曰本新中村化學品公司 製造之DCP)、及0.8重量份作為引發劑之光引發劑（由汽巴 特用化學品控股公司製造的τρο)溶於甲苯中，以製備25重 量％之溶液。將此溶液塗佈在經離型處理之PET薄膜上， 且在I00C烘箱中乾燥30分鐘。將所獲得之黏著感壓黏著 143310.doc -22- 201023124 劑的薄膜與厚度為25 μιη之經離型處理的PET薄膜層合， 以製備一貼有離型襯片的感壓黏著薄片。獲得感壓黏著劑 厚度為25 μιη之透明薄膜。 實例2 除使用100質量份基於氫化DCPD的樹脂（由埃克森美孚 公司製造之Escorez 5340)作為脂環烴樹脂、25質量份之一 種飽和聚異丁烯樹脂（由巴斯夫公司製造之〇ppan〇1 65〇)及 8質量份之另一種飽和聚異丁烯樹脂（由巴斯夫公司製造之 Oppanol B15)作為無定形飽和聚烯烴樹脂、33質量份uV可 固化丙烯酸酯樹脂（由日本新中村化學品公司製造之Dcp) 作為含丙浠酸基團之樹脂、及〇. 8重量份光引發劑（由汽巴 特用化學品控股公司製造的TPO)作為引發劑以外，其他與 操作實例1相同。 實例3 除使用100質量份基於氫化DCPD的樹脂（由埃克森美孚 公司製造之Escorez 5340)作為脂環烴樹脂、40質量份之一 種氫化聚丁二烯（由可樂麗有限公司製造的LIR200)及20質 量份聚α-烯烴共聚物（由住友化學品有限公司製造的 Χ1102Ρ)作為無定形飽和聚浠烴樹脂、40質量份經胺基甲 酸酯改質之氫化聚丁二烯二丙烯酸酯（由曰本曹達公司製 造之ΤΕΑΙ1000)作為含丙烯酸基團之樹脂、及1重量份光引 發劑（由汽巴特用化學品控股公司製造的ΤΡΟ)作為引發劑 以外，其他與操作實例1相同。 實例4 143310.doc • 23· 201023124 除使用100質量份基於氫化DCPD的樹脂（由埃克森美孚 公司製造之Escorez 5340)作為脂環烴樹脂、4〇質量份飽和 聚異丁烯樹脂（由巴斯夫公司製造之0ppan〇1 B5〇)作為無定 形飽和聚烯烴樹脂、60質量份氫化聚丁二烯二丙烯酸酯 (由Osaka Yuki Kogyo公司製造之SPBDA-S30)作為含丙烯 酸基團之樹脂、及1.3重量份光引發劑（由汽巴特用化學品 控股公司製造的τρο)作為引發劑以外，其他與操作實例ι 相同。 實例5 除使用100質量份基於氫化DCPD的樹脂（由埃克森美孚 公司製造之Escorez 5340)作為脂環烴樹脂、1〇〇質量份飽 和5^異丁稀樹脂（由巴斯夫公司製造之〇ppan〇l B3〇)作為無 定形飽和聚烯烴樹脂、50質量份三環癸烷二甲醇二丙烯酸 酯（由曰本新中村化學品公司製造之A_Dcp)作為含丙烯酸 基團之樹脂、及丨重量份光引發劑（由汽巴特用化學品控股 A司製造的TPO)作為引發劑以外，其他與操作實例工相 同。 比較例1 將87.5質量份丙稀酸異辛酯、4質量份丙稀酸、及〇〇4重 量伤作為光聚合引發劑之Irgacure 65 1(2,2-二曱氧基-2-苯 基笨乙綱）在一玻璃容器中充分混合，且在將溶解氧置換 為氮氣後，用一低壓汞燈發出的uv光照射一段時間以使 該混合物發生部分聚合作用，並得到一黏度為約1500 cP 之黏性液體。將8.5質量份丙烯酸2-羥乙酯、oj重量份作 143310.doc 201023124 為交聯劑之HDDA(1，6-己二醇丙烯酸酯）、及0.1重量份其 他聚合引發劑（Irgacure 651)添加至所得之組合物中且充分 混合。該混合物於真空下經消泡後，將其塗覆至一厚度為 50 μηι之經離型處理的聚酯薄膜上，且使其厚底達到5〇 μπι。為去除抑制聚合作用之氧氣，上述薄膜係進一步經 塗佈’且用低壓汞燈自兩側照射4分鐘，以獲得一感壓黏 著薄片。 比較例2 除添加87.5質量份丙烯酸異辛酯、12.5質量份丙烯酸及 不添加丙烯酸2-羥乙酯以外，其他與比較例1相同。 比較例3 除使用100質量份基於氫化DCPD的樹脂（由埃克森美孚 公司製造之Escorez 5340)、33.4質量份飽和聚異丁烯樹脂 (由巴斯夫公司製造之〇ppanol B1〇〇)及、及33 4質量份 可固化丙烯酸酯樹脂（由曰本新中村化學品公司製造之 DCP)外’其他與操作實例丨相同。 評價方法 不均勻性測試 在揭去用於測試之感壓黏著薄片之其中一表面上的離型 膜後’利用-親壓器將該黏著薄片黏貼至—厚度狀7麵 之玻璃板（康寧公司製造的#1737)上，以防止空氣進入界面 中’且利用-切割器將突出部分去除。另外，在去除一市 售手機（由夏普公司製造的9聰)的整個保護蓋後，對其 進行處理，以使液晶模組成為最外層表面。之後，揭去黏 143310.doc -25· 201023124 貼在玻璃板上的感壓黏著薄片的離型膜，並使該感壓黏著 薄片之黏著表面與該液晶模組接觸，再藉由一橡膠輕壓器 輥壓而使其等黏合。將所獲得之玻璃板/感壓黏著薄片/液 晶模組之層合物放置在一高壓蒸汽鍋中，並在〇5 Mpa及 40 C下處理1 5分鐘。對於實例1、實例2、實例3、實例4、 實例5、比較例1、比較例2及比較例3而言，uv光（由 Fusion Κ·Κ·製造之F300S(使用η電子管）；5〇瓜扒加次）係 從玻璃板側照射。此後，將該手機的電源開啟以顯示白色 螢幕，且用眼睛確定不均勻性。結果如表丨所示。在表 示之不均勻性測試的結果中，「3」表示「未發現不均勻顯 示」，「2」表示「發現輕度不均勻顯示」，且Γι」表示 「發現可在實務中引起問題的強烈不均勻顯示」。 可靠性測試（脫離/發泡/白化） 在揭去用於測試之感壓黏著薄片之其中一表面上的離型 膜後，利用一輥壓器將該黏著薄片黏貼至—厚度為〇7 mm 之玻璃板（康寧公司製造的#1737)上，以防止空氣進入界 面，且利用一切割器將突出部分去除。另外，藉由一橡膠 輥壓器，用相同的方法將具有感壓黏著劑之偏光板（由 Sanritz公司製造）層合至一厚度為〇55 之浮法玻璃 (50x80 mm)上。揭去黏貼在玻璃板上的感壓黏著薄片之離 型膜，並使該感壓黏著薄片之黏著表面與該偏光板接觸， 再藉由一橡膠輥壓器輥壓而使其等黏合。將所獲得之玻璃 板/感壓黏著薄片/偏光板/玻璃之層合物放置在一高壓蒸汽 鍋中’並在0.5 MPa及40°C下處理I5分鐘。對於實例i、實 143310.doc -26 - 201023124 例2、實例3、實例4、實例5、比較例1、比較例2及比較例 3而言，UV光（由Fusion K.K.製造之F300S(使用Η電子 管）；50 mJx20次）係從玻璃板側照射。使該層合物於室溫 下靜置12小時，且然後將其放置在一 60°C及90% RH之恒 溫濕器中。3天後，取出該層合物，並且用眼睛確定發泡 或脫離現象存在或不存在。結果如表1所示。 ❹ 143310.doc 27- 201023124 <珑眾茛-1<<垅寒& SI 碟 #- 蹑 •CT IL· ^aL 歌 滅2 黎 ^Ιφΐ tl § 2.3Ε403 3.6E+03 9.8ΕΉ)3 7.2Ε-+Ό3 8.1Ε403 2.9Ε-ΚΜ 5.9E崩 2.1Ε-+Ό4 Π 黎色 i-S p«i 5.4Ε-+04 8.6E+04 2.1Ε-+Ό6 1.7Ε405 2.4Ε+04 1.9Ε405 5.4E+04 1.2E+05 不均勻性測試 1_ cn m m Γ*Ί m CN (Ν IS 想 τ-^ 蹑 -CT 邀 膠帶厚度(μιη) <N ΚΤϊ (Ν (Ν ir> (Ν 混合物(質量份） B100/5340/DCP/TPO =17/100/50/0.8 〇〇 _ 1 1 & § § CQ LIR200/X1102P/5340/TEAI1000/TPO ^0/20/100/40/1 B50/5340/SPBDA-30S/TPO =40/100/60/1.3 | TjjH ο 自 1 m m ffl 1-H ITi p |l 11 i" 1 OR 1 02 1! 2 B100/5340/DCP/TPO =33/100/33/0.8 (Ν 蘧 •CT m % (N ΐΚ 實例3 實例4 ίΚ 比較例1 比較例2 1 jj ±i ίΓ (^鹌阳<<邕杷05。釙^砵^姊书)蘅僉|£伞龄^:11093^11::><0^1 (锄^Π7<<0^0^Π3Α B5JBSO-B)遛镏装«4 紫 Μ 卜龄 qY*w : ocns-vaCQd&o (锄鉍砣<<钾麵-4〇1)错毽敦肊-^教“卜鉍^1^:|,钇遛毽8-砩樊趔：00011¥31 (^1ιΙΪΓ<·ί^{'釙=^^-0-審 4 0-«)错毽衆肊-r-lgrs-M^你:doa-V (^^nr'^og^^^-B-^^B-ffi^s^^^^s--riss-M^^tiwrdoa (帮鉍π<<05。琳^-f+-a-赛4B-ffl) IS 潜翁肊-r 鮏·τη3-9Μ : vaaffi (啭雜阳<<。>.00。^^芸工泛0-®)避10澈-<N毽爱肊：vaffi (嘲踌研<<嘀^商«4«)毽装肊：<< (^^^<<Νεΐι8φ^^^^:νοΙ (辩鉍tm*<<彰趔05^^κ#&3ν-®)ί#:^ιηΓ>φ^^:ορ-ι1 (帮鉍研<<嗟杷^^^^ϋ--Β)^^^^10Μ<Μ&-^^^®ί_«:^^®--λ:(Νος-^®^ (锄鹖研<<嗟杷坤琳^<^姊书)(蘅祺蹩)刼蛑袈：0寸3 (澍鉍冗<<嗟杷咔釙安¥钽书)荽鉍涑趔爱-a鉍：dsllx (帮鉍砣蘇ΙΓ4Β-®)爱 UX 鉍: oofNelH-l (锄鉍ΠΓ<·ί¥ 苌^-®)爱卜蛾鉍：Π9, 0ερ3, OSH, 0019The shape of the protective layer 4 is not flat and another layer having an uneven surface shape (such as a polarizing plate) is disposed on the display surface of the image display unit, and the internal residual stress of the adhesive sheet itself can be moderated, thereby preventing The image display device displays an uneven sentence. Similarly, the transparent pressure-sensitive adhesive sheet 3 has a sufficiently high adhesive force and hydrophilicity, and therefore does not adhere to the display surface of the image display unit and the transparent pressure-sensitive adhesive sheet 3 even in a high-temperature and high-humidity environment, and is transparent. Foaming or detachment occurs at the interface between the pressure-sensitive adhesive sheet 3 and the surface protective layer 4, and whitening does not occur. The image display device 10 can be obtained, for example, by laminating the above-mentioned laminate 2 comprising the surface protective layer 4 and the transparent pressure-sensitive adhesive sheet 3 onto the display surface of the image display unit 丨. Fig. 2 is a cross-sectional view showing another embodiment of the image display device including the above transparent pressure-sensitive adhesive sheet. In FIG. 2, the image display device 2 has a structure in which the transparent film 3 and the surface protection layer 4 are stacked on the touch panel 7 in this order (the system is present in the image display unit 1). On the display surface). The structure and structure of laminate 2! The same is described, in which the transparent adhesive pressure sheet 3 and the surface protective layer 4 are stacked in this order. The touch panel 7 is disposed on the display surface of the image display unit ,, and the image displayed by the image display device 20 can be viewed through the (four) panel. The touch panel 7 is transparent and has the following structure: A transparent conductive layer is located on the respective back faces of two transparent plates made of glass or polyethylene terephthalic acid vinegar, and such transparent plates The transparent conductive layers are arranged to face each other in a non-contact state with eight small gaps. When the operator of the touch panel presses the relevant position on the surface of a transparent plate with a finger or a pen, the conductive layer of 143310.doc •19· 201023124 on the back side of the transparent plate and the conductive layer on the back side of the other transparent plate Contact and produce a condition that can only conduct electricity at the relevant location. This electrically conductive position is electrically detected via the sensor, thereby determining the position of the operator on the touch panel. The touch panel type display is being used in a pc (personal computer), a mobile phone or a mobile terminal (for example, the PDAp transparent pressure-sensitive adhesive sheet 3 has flexibility, and thus even if the shape of the surface protective layer 4 is irregular, the adhesive sheet The internal residual stress can also be moderated to prevent uneven display of the image display device. Similarly, the transparent pressure-sensitive adhesive sheet 3 has sufficiently high adhesion and hydrophilicity, and thus even in a high temperature and high humidity environment. Then, foaming or detachment occurs at the interface between the touch panel 7 and the transparent pressure-sensitive adhesive sheet 3, and between the transparent pressure-sensitive adhesive sheet 3 and the surface protective layer 4, and whitening does not occur. The display device 2 can be obtained, for example, by laminating the laminate 2 including the surface protective layer 4 and the transparent pressure-sensitive adhesive sheet 3 onto the touch panel 7 on the display surface of the image display unit 。. 3 is still a cross-sectional view of another embodiment of an image display apparatus including the above transparent pressure-sensitive adhesive sheet. In FIG. 3, the image display apparatus 3 has the following structure: wherein the transparent pressure is The sheet 3, the touch panel 7, the transparent pressure-sensitive adhesive sheet 3' and the surface protective layer 4 are stacked on the display surface of the image display unit 1 in this order. The structure of the laminate is the same as that described in the figure. The transparent pressure-sensitive adhesive sheet 3 and the surface protective layer 4 are stacked in this order. The transparent pressure-sensitive adhesive sheet 3 and the transparent pressure-sensitive adhesive sheet 3· may comprise the same or different copolymers. The transparent pressure-sensitive adhesive sheet 3 and 3, having flexibility, and thus even if the shape of the surface protection layer 4 is irregular and in addition, a layer body having an irregular surface shape (such as a polarizing plate) is disposed on the image display unit 143310.doc -20· 201023124; Table: The internal residual stress of each adhesive sheet itself can be slowed down: ': It can prevent the uneven display of the image display device. The same.: Transparent pressure-sensitive adhesive sheets 3 and 3, which are high enough The adhesion and hydrophilic image are obvious and β is therefore not between, for example, the surface of the shadow mi and the transparent pressure-sensitive adhesive sheet 3, or the transparent sheet 2 Between the surface protection layer 4 The foaming or "image" is generated at the surface, and whitening does not occur. The image display device 30 can be made, for example, by including the surface protective layer 4, the transparent feeling a, the touch panel 2, and the transparent feeling. The laminate 2 of the pressure-bonded sheet 3 is laminated to the display surface of the image display early 1. Fig. 4 is still a cross section of the image display assembly containing the above-mentioned transparent sensible sheet In Fig. 4, the image display device 4 has the following structure: the transparent pressure-sensitive adhesive sheet 3, the touch panel 7, and the surface protective layer 4 are stacked on the image display unit it 1 in this order. Similarly, the surface protective layer 4 has a light shielding layer in a partial region, thereby forming a surface of an uneven shape. The transparent pressure-sensitive adhesive sheet 3 is present on the surface side of the uneven shape of the surface protective layer 4 by the touch panel 7. . The transparent pressure-sensitive sheet 3 has flexibility [and thus even if a layer body having an uneven surface shape (such as a polarizing plate) is provided on the display surface of the image display unit, the internal residual stress of the adhesive sheet itself can be It is moderated, which prevents the image display from appearing unevenly. Similarly, the transparent pressure-sensitive adhesive sheet 3 has a sufficiently high adhesive force and hydrophilicity, and therefore does not appear in the image display unit even in a high temperature and humidity environment! Foaming or detachment occurs at the interface between the display surface and the transparent pressure-sensitive adhesive sheet 3' and the transparent pressure-sensitive adhesive sheet 3 and the touch panel 7 at 143310.doc 21 · 201023124, and whitening does not occur. The image display device 40 can be obtained, for example, by laminating the laminate 2 including the surface protective layer 4, the touch panel 7, and the transparent pressure-sensitive adhesive sheet 3 onto the display surface of the image display unit 1. According to still another aspect of the present invention, an electronic device including the above image display device is provided. The electronic device is not specifically limited and includes: a mobile phone, a personal digital assistant (PDA), a portable video game console, an e-reader terminal, a car navigation system, a portable music player, a watch or a clock, and a television ( TV), video cameras, video players, digital cameras, global positioning system (GPS) devices, and personal computers (PCs). EXAMPLES Hereinafter, the present invention will be described in more detail with reference to examples, but the invention is not limited thereto. Sample Preparation Method Example 1 100 parts by mass of a hydrogenated DCPD-based resin (Escorez 5340 manufactured by Exxon Mobil Corporation) as an alicyclic hydrocarbon resin, and 17 parts by mass of a saturated polyisobutylene resin as an amorphous saturated polyolefin resin (by 50 parts by mass of UV curable acrylate resin (DCP manufactured by Sakamoto Nakamura Chemical Co., Ltd.) and 0.8 parts by weight of photoinitiator as initiator for acrylate resin (Oppanol B100) (τρο manufactured by Steam Batt Chemicals Holding Co., Ltd.) was dissolved in toluene to prepare a 25% by weight solution. This solution was coated on a release treated PET film and dried in an I00C oven for 30 minutes. The obtained adhesive film of 143310.doc -22-201023124 was laminated with a release-treated PET film having a thickness of 25 μm to prepare a pressure-sensitive adhesive sheet to which a release liner was attached. A pressure sensitive adhesive having a thickness of 25 μm was obtained. Example 2 In addition to using 100 parts by mass of a hydrogenated DCPD-based resin (Escorez 5340 manufactured by ExxonMobil) as an alicyclic hydrocarbon resin, 25 parts by mass of a saturated polyisobutylene resin (〇ppan〇1 65 manufactured by BASF Corporation) 〇) and 8 parts by mass of another saturated polyisobutylene resin (Oppanol B15 manufactured by BASF Corporation) as an amorphous saturated polyolefin resin, 33 parts by mass of uV curable acrylate resin (Dcp manufactured by Japan Nakamura Chemical Co., Ltd.) The same procedure as in the operation example 1 was carried out, except that the resin containing a propionate group and 8 parts by weight of a photoinitiator (TPO manufactured by Kabbat Chemicals Holding Co., Ltd.) were used as an initiator. Example 3 In addition to 100 parts by mass of a hydrogenated DCPD-based resin (Escorez 5340 manufactured by ExxonMobil) as an alicyclic hydrocarbon resin, 40 parts by mass of a hydrogenated polybutadiene (LIR200 manufactured by Kuraray Co., Ltd.) And 20 parts by mass of a poly-α-olefin copolymer (Χ1102Ρ manufactured by Sumitomo Chemical Co., Ltd.) as an amorphous saturated polyfluorene hydrocarbon resin, 40 parts by mass of a urethane-modified hydrogenated polybutadiene diacrylate (The ΤΕΑΙ1000 manufactured by the present Soda Co., Ltd.) The same as Working Example 1 except that the acrylic group-containing resin and 1 part by weight of a photoinitiator (manufactured by Kabbat Chemicals Holding Co., Ltd.) were used as the initiator. Example 4 143310.doc • 23· 201023124 In addition to using 100 parts by mass of hydrogenated DCPD-based resin (Escorez 5340 manufactured by ExxonMobil) as an alicyclic hydrocarbon resin, 4 parts by mass of saturated polyisobutylene resin (manufactured by BASF Corporation) 0ppan〇1 B5〇) as an amorphous saturated polyolefin resin, 60 parts by mass of hydrogenated polybutadiene diacrylate (SPBDA-S30 manufactured by Osaka Yuki Kogyo Co., Ltd.) as an acrylic group-containing resin, and 1.3 parts by weight The photoinitiator (τρο manufactured by Kabbat Chemicals Holding Co., Ltd.) was used as the initiator, and the other operation examples were the same. Example 5 In addition to using 100 parts by mass of a hydrogenated DCPD-based resin (Escorez 5340 manufactured by Exxon Mobil Corporation) as an alicyclic hydrocarbon resin, 1 part by mass of a saturated 5? isobutylene resin (a panppan manufactured by BASF Corporation) 〇l B3〇) as an amorphous saturated polyolefin resin, 50 parts by mass of tricyclodecane dimethanol diacrylate (A_Dcp manufactured by Sakamoto Nakamura Chemical Co., Ltd.) as an acrylic group-containing resin, and yttrium The photoinitiator (TPO manufactured by Gasbat Chemicals Holding Division A) was used as an initiator, and the others were the same as the operation examples. Comparative Example 1 Irgacure 65 1 (2,2-dimethoxyoxy-2-phenyl) having 87.5 parts by mass of isooctyl acrylate, 4 parts by mass of acrylic acid, and ruthenium 4 as a photopolymerization initiator The mixture is thoroughly mixed in a glass container, and after dissolving dissolved oxygen into nitrogen, it is irradiated with uv light emitted from a low-pressure mercury lamp for a period of time to partially polymerize the mixture, and a viscosity of about 1500 is obtained. A viscous liquid of cP. 8.5 parts by mass of 2-hydroxyethyl acrylate, oj parts by weight of 143310.doc 201023124 as crosslinking agent HDDA (1,6-hexanediol acrylate), and 0.1 part by weight of other polymerization initiator (Irgacure 651) To the resulting composition and thoroughly mixed. After the mixture was defoamed under vacuum, it was applied to a release-treated polyester film having a thickness of 50 μm and brought to a thickness of 5 μm. In order to remove oxygen which inhibits polymerization, the above film was further coated and irradiated from both sides with a low pressure mercury lamp for 4 minutes to obtain a pressure sensitive adhesive sheet. Comparative Example 2 The same as Comparative Example 1 except that 87.5 parts by mass of isooctyl acrylate, 12.5 parts by mass of acrylic acid, and 2-hydroxyethyl acrylate were not added. Comparative Example 3 In addition to using 100 parts by mass of a hydrogenated DCPD-based resin (Escorez 5340 manufactured by Exxon Mobil Corporation), 33.4 parts by mass of a saturated polyisobutylene resin (〇ppanol B1® manufactured by BASF Corporation), and 33 4 The mass of the curable acrylate resin (DCP manufactured by Sakamoto Nakamura Chemical Co., Ltd.) is the same as the operation example. Evaluation Method Non-uniformity Test After peeling off the release film on one of the surfaces of the pressure-sensitive adhesive sheet for testing, the adhesive sheet was adhered to a thickness of 7-sided glass plate (Corning Corporation) Manufactured on #1737) to prevent air from entering the interface' and the use of a cutter to remove the protruding portion. In addition, after removing the entire protective cover of a commercially available mobile phone (9 Cong manufactured by Sharp Corporation), it was treated to make the liquid crystal module the outermost surface. After that, the adhesive film of the pressure-sensitive adhesive sheet attached to the glass plate is peeled off, and the adhesive surface of the pressure-sensitive adhesive sheet is brought into contact with the liquid crystal module, and then lightened by a rubber. The press rolls to make it adhere. The obtained laminate of glass plate/pressure-sensitive adhesive sheet/liquid crystal module was placed in a high-pressure steam cooker and treated at 〇5 Mpa and 40 C for 15 minutes. For Example 1, Example 2, Example 3, Example 4, Example 5, Comparative Example 1, Comparative Example 2, and Comparative Example 3, uv light (F300S manufactured by Fusion Κ·Κ (using η electron tube); 5〇 The melon is added to the side of the glass plate. Thereafter, the power of the phone is turned on to display a white screen, and the unevenness is determined by the eyes. The results are shown in the table. In the results of the heterogeneity test indicated, "3" means "no uneven display was found", "2" means "discovery of uneven display", and Γι" means "discovery can cause problems in practice." Not evenly displayed." Reliability test (release/foaming/whitening) After peeling off the release film on one of the surfaces of the pressure-sensitive adhesive sheet for testing, the adhesive sheet was adhered to a thickness of 〇7 mm by a roller presser. The glass plate (#1737 manufactured by Corning Incorporated) was placed to prevent air from entering the interface, and the protrusion was removed using a cutter. Further, a polarizing plate (manufactured by Sanritz Co., Ltd.) having a pressure-sensitive adhesive was laminated to a float glass (50 x 80 mm) having a thickness of 〇55 by a rubber roller in the same manner. The release film of the pressure-sensitive adhesive sheet adhered to the glass plate is removed, and the adhesive surface of the pressure-sensitive adhesive sheet is brought into contact with the polarizing plate, and then pressed by a rubber roller to be bonded. The obtained glass plate/pressure-sensitive adhesive sheet/polarizing plate/glass laminate was placed in a high pressure steamer' and treated at 0.5 MPa and 40 ° C for 1 5 minutes. For Example i, 143310.doc -26 - 201023124 Example 2, Example 3, Example 4, Example 5, Comparative Example 1, Comparative Example 2, and Comparative Example 3, UV light (F300S manufactured by Fusion KK (using Η The tube); 50 mJ x 20 times) was irradiated from the side of the glass plate. The laminate was allowed to stand at room temperature for 12 hours and then placed in a 60 ° C and 90% RH constant temperature humidifier. After 3 days, the laminate was taken out and the presence or absence of foaming or detachment was determined by eyes. The results are shown in Table 1. 143 143310.doc 27- 201023124 <珑众茛-1<<垅寒& SI 碟#- 蹑•CT IL· ^aL 歌灭2 黎^Ιφΐ tl § 2.3Ε403 3.6E+03 9.8ΕΉ)3 7.2Ε-+Ό3 8.1Ε403 2.9Ε-ΚΜ 5.9E collapse 2.1Ε-+Ό4 Π 黎色 iS p«i 5.4Ε-+04 8.6E+04 2.1Ε-+Ό6 1.7Ε405 2.4Ε+04 1.9Ε405 5.4E +04 1.2E+05 Inhomogeneity test 1_ cn mm Γ*Ί m CN (Ν IS want τ-^ 蹑-CT Invite tape thickness (μιη) <N ΚΤϊ (Ν (Ν ir> (Ν Mixture (mass) B100/5340/DCP/TPO =17/100/50/0.8 〇〇_ 1 1 & § § CQ LIR200/X1102P/5340/TEAI1000/TPO ^0/20/100/40/1 B50/5340/SPBDA -30S/TPO =40/100/60/1.3 | TjjH ο from 1 mm ffl 1-H ITi p |l 11 i" 1 OR 1 02 1! 2 B100/5340/DCP/TPO =33/100/33/ 0.8 (Ν 蘧•CT m % (N ΐΚ Example 3 Example 4 ίΚ Comparative Example 1 Comparative Example 2 1 jj ±i ίΓ (^鹌阳<<邕杷05.钋^砵^姊书)蘅佥|£ Umbrella age: 11093^11::><0^1 (锄^Π7<<0^0^Π3Α B5JBSO-B) armored «4 Μ Μ 卜 q qY*w : ocns-vaCQd&o (锄铋砣<<Kana--4〇1) wrong 毽敦肊-^教“卜铋^1^:|,钇遛毽8-砩樊趔:00011¥31 (^1ιΙΪΓ<·ί^{'钋=^^-0-审四 0-«) 毽毽毽肊-r-lgrs-M ^你:doa-V (^^nr'^og^^^-B-^^B-ffi^s^^^^s--riss-M^^tiwrdoa (help 铋π<<05.lin^ -f+-a-赛4B-ffl) IS 潜翁肊-r 鮏·τη3-9Μ : vaaffi (啭阳阳<<.>.00.^^芸工泛0-®) Avoid 10 Che - <N毽爱肊:vaffi (Mocking &<<嘀^商«4«)毽装肊:<<<(^^^<<Νεΐι8φ^^^^:νοΙ (Debate tm *<<彰趔05^^κ#&3ν-®) ί#:^ιηΓ>φ^^:ορ-ι1 (Help 铋研<<嗟杷^^^^ϋ--Β) ^^^^10Μ<Μ&-^^^®ί_«:^^®--λ:(Νος-^®^ (锄鹖研<<嗟杷坤琳^<^姊书) (蘅祺蹩)刼蛑袈:0 inch 3 (澍铋 &&&;;嗟杷咔钋安¥钽书)荽铋涑趔爱-a铋:dsllx (帮铋砣苏ΙΓ4Β-®) Love UX 铋: oofNelH-l (锄铋ΠΓ<·ί¥ 苌^-®) Ai Mo moth:Π9, 0ερ3, OSH, 0019
143310.doc -28- 201023124 黏彈性測量 在剪切模式（1 Hz)下，藉由一動態黏彈性測量裝置（由 TA儀器公司製造的arES)評價該黏彈性。藉由將“張已揭 去離型膜之透明感壓黏著薄片堆疊在一起而獲得之疊合物 係經由一直徑為7.9 mm之沖頭邊緣衝壓且作為測試件。測143310.doc -28- 201023124 Viscoelasticity measurement The viscoelasticity was evaluated in a shear mode (1 Hz) by a dynamic viscoelasticity measuring device (arES manufactured by TA Instruments). The laminate obtained by stacking the sheets of the transparent pressure-sensitive adhesive sheets from which the release film was removed was punched through a punch edge having a diameter of 7.9 mm and used as a test piece.
量步驟係藉由以rC/min之速度將溫度自_6〇t提高至㈣。C 而進行。25°C下的黏彈性值係如表j所示。 【圖式簡單說明】 ^ 圖1係關於包含本發明層合物之繫 〜、夥像顯不裝置之—實施 例的橫斷面圖。 圖2係關於包含本發明層合物之影像顯示裝置之另一實 施例的橫斷面圖。 圖3仍係關於包含本發明層合物之影像顯示裝置之另一 實施例的橫斷面圖。 圖4仍係關^包含本發明層合物之影像顯示裝置之又一 實施例的橫斷面圖。 【主要元件符號說明】 1 影像顯示單元 2 層合物 3 透明感壓黏著薄片 3' 透明感壓黏著薄片 4 表面保護層 5 連續層 6 遮光層 143310.doc -29- 201023124 7 觸控 面 板 10 影像 顯 示 裝 置 20 影像 顯 示 裝 置 30 影像 顯 示 裝 置 40 影像 顯 示 裝 置 143310.doc -30-The quantity step is increased from _6〇t to (d) by a speed of rC/min. C and proceed. The viscoelastic values at 25 ° C are shown in Table j. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a cross-sectional view showing an embodiment of a system comprising a laminate of the present invention. Figure 2 is a cross-sectional view showing another embodiment of an image display apparatus comprising the laminate of the present invention. Figure 3 is still a cross-sectional view of another embodiment of an image display device comprising the laminate of the present invention. Figure 4 is still a cross-sectional view of yet another embodiment of an image display device comprising the laminate of the present invention. [Main component symbol description] 1 Image display unit 2 Laminate 3 Transparent pressure-sensitive adhesive sheet 3' Transparent pressure-sensitive adhesive sheet 4 Surface protective layer 5 Continuous layer 6 Light-shielding layer 143310.doc -29- 201023124 7 Touch panel 10 image Display device 20 image display device 30 image display device 40 image display device 143310.doc -30-
Claims (1)
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| Application Number | Priority Date | Filing Date | Title |
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| JP2008241433A JP2010072471A (en) | 2008-09-19 | 2008-09-19 | Transparent adhesive sheet, image display apparatus comprising the same, and method for producing the image display apparatus |
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| TW201023124A true TW201023124A (en) | 2010-06-16 |
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| TW98131672A TW201023124A (en) | 2008-09-19 | 2009-09-18 | Transparent pressure-sensitive adhesive sheet, image display apparatus comprising the same, and the production methods for making the image display apparatus |
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| Country | Link |
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| JP (1) | JP2010072471A (en) |
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| WO (1) | WO2010033419A2 (en) |
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| CN102760380A (en) * | 2011-04-28 | 2012-10-31 | 藤森工业株式会社 | Hard coating thin film and touch panel using the same |
| TWI501002B (en) * | 2012-05-09 | 2015-09-21 | Dexerials Corp | A method of manufacturing a video display device, and an image display device |
| CN109715753A (en) * | 2016-09-15 | 2019-05-03 | 三菱化学株式会社 | Bond laminate, figuration bonding laminate and its manufacturing method |
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| JP2012237965A (en) * | 2011-04-27 | 2012-12-06 | Nitto Denko Corp | Adhesive layer, optical film and image display device |
| US20140141271A1 (en) * | 2011-06-28 | 2014-05-22 | Lintec Corporation | Adhesive composition and adhesive sheet |
| WO2013046686A1 (en) * | 2011-09-29 | 2013-04-04 | 三井化学株式会社 | Adhesive composition and image display device using same |
| WO2013057957A1 (en) * | 2011-10-21 | 2013-04-25 | 日本化薬株式会社 | Ultraviolet ray cured resin composition, cured product, and article |
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| JP6325984B2 (en) * | 2012-11-30 | 2018-05-16 | リンテック株式会社 | Adhesive composition, adhesive sheet, and electronic device |
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| EP2832780B1 (en) * | 2013-08-01 | 2019-09-25 | 3M Innovative Properties Company | Rubber-Based Pressure Sensitive Adhesive Foam |
| JP6378866B2 (en) * | 2013-08-13 | 2018-08-22 | 富士通コンポーネント株式会社 | Manufacturing method of touch panel |
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| JP5778303B2 (en) | 2014-02-28 | 2015-09-16 | 古河電気工業株式会社 | Resin composition for sealing electronic device and electronic device |
| JP5778304B2 (en) | 2014-02-28 | 2015-09-16 | 古河電気工業株式会社 | Resin composition for sealing electronic device and electronic device |
| KR101917266B1 (en) * | 2014-05-13 | 2018-11-09 | 미쯔비시 케미컬 주식회사 | Method for manufacturing double-sided adhesive sheet for image display device |
| JP2016204406A (en) | 2015-04-15 | 2016-12-08 | 藤森工業株式会社 | Adhesive layer and adhesive film |
| CN108138009B (en) * | 2015-08-27 | 2021-01-05 | 综研化学股份有限公司 | Adhesive water vapor barrier laminate and image display device |
| JP6850601B2 (en) * | 2016-12-21 | 2021-03-31 | 日東電工株式会社 | Image display device |
| JP2017076147A (en) * | 2016-12-27 | 2017-04-20 | 三菱電機株式会社 | Display |
| KR101903888B1 (en) | 2017-05-10 | 2018-10-02 | 동우 화인켐 주식회사 | Optical Laminate and Flexible Display Comprising the Same |
| KR102570517B1 (en) * | 2018-03-29 | 2023-08-24 | 미쯔비시 케미컬 주식회사 | Adhesive sheet, laminated sheet, and image display device using the same |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007197517A (en) * | 2006-01-24 | 2007-08-09 | Three M Innovative Properties Co | Adhesive sealing composition, sealing film and organic el element |
| DE602006019988D1 (en) * | 2006-05-11 | 2011-03-17 | Henkel Ag & Co Kgaa | ACRYLIC MELTING GLUE |
| US8232350B2 (en) * | 2008-06-02 | 2012-07-31 | 3M Innovative Properties Company | Adhesive encapsulating composition and electronic devices made therewith |
-
2008
- 2008-09-19 JP JP2008241433A patent/JP2010072471A/en active Pending
-
2009
- 2009-09-10 WO PCT/US2009/056484 patent/WO2010033419A2/en active Application Filing
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102760380A (en) * | 2011-04-28 | 2012-10-31 | 藤森工业株式会社 | Hard coating thin film and touch panel using the same |
| CN102760380B (en) * | 2011-04-28 | 2014-09-10 | 藤森工业株式会社 | Hard coating thin film and touch panel using the same |
| TWI501002B (en) * | 2012-05-09 | 2015-09-21 | Dexerials Corp | A method of manufacturing a video display device, and an image display device |
| CN109715753A (en) * | 2016-09-15 | 2019-05-03 | 三菱化学株式会社 | Bond laminate, figuration bonding laminate and its manufacturing method |
| CN109715753B (en) * | 2016-09-15 | 2021-12-07 | 三菱化学株式会社 | Adhesive sheet laminate, shaped adhesive sheet laminate, and method for producing same |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2010033419A2 (en) | 2010-03-25 |
| WO2010033419A3 (en) | 2010-05-20 |
| JP2010072471A (en) | 2010-04-02 |
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