TW200920809A - Double-faced pressure-sensitive adhesive sheet - Google Patents

Double-faced pressure-sensitive adhesive sheet Download PDF

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Publication number
TW200920809A
TW200920809A TW097112563A TW97112563A TW200920809A TW 200920809 A TW200920809 A TW 200920809A TW 097112563 A TW097112563 A TW 097112563A TW 97112563 A TW97112563 A TW 97112563A TW 200920809 A TW200920809 A TW 200920809A
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TW
Taiwan
Prior art keywords
release paper
adhesive layer
paper
layer
adhesive
Prior art date
Application number
TW097112563A
Other languages
Chinese (zh)
Inventor
Keiji Takano
Takuya Okada
Makoto Kohira
Teruhisa Harada
Jyunji Sugino
Original Assignee
Denki Kagaku Kogyo Kk
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Publication of TW200920809A publication Critical patent/TW200920809A/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38Pressure-sensitive adhesives [PSA]
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/40Adhesives in the form of films or foils characterised by release liners
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/326Applications of adhesives in processes or use of adhesives in the form of films or foils for bonding electronic components such as wafers, chips or semiconductors
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/124Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/40Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/416Additional features of adhesives in the form of films or foils characterized by the presence of essential components use of irradiation
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2433/00Presence of (meth)acrylic polymer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00Presence of polyester
    • C09J2467/005Presence of polyester in the release coating

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesive Tapes (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)

Abstract

A double-faced pressure-sensitive adhesive sheet which is produced by a simple production process and has satisfactory applicability at time of use. The double-faced pressure-sensitive adhesive sheet is obtained by superposing a first release paper (1) on one side of a pressure-sensitive adhesive layer (2), superposing a second release paper (3) on the other side, and subjecting the laminate to half-cutting from each side to form tape-shaped pressure-sensitive adhesive layers (2) and to cause only the first release paper (1) to have pickup tabs which protrude from edge parts of the tape-shaped pressure-sensitive adhesive layers (2) in the length direction therefor.

Description

200920809 九、發明說明: 【發明所屬之技術領域】 本發明係關於在黏著層之兩面具 性片材,尤其是關於用於搭載於電子設備中著 ‘之固定用途中的作業性良好之兩 ^熱#位等 【先前技術】 生片材。 近年來,於精密零件、電氣. '被接合材彼此接合之兩面等領域’將 :及:且,該等所需求之兩面黏著性? 性及電磁波吸收性等高性能化。同時,自=有V熱 點而言亦有較多要求,考慮 、附作業性之觀 高作業性。 ’、9 1剝離紙賦予特徵來提 例如,於專利文獻2中, 材(黏著層)之剝離紙之端部較兩::著為片夾, 側突出的兩面接著切割片材。 站者片材之端部向外 專利文獻1 :曰本專利拉pi 1, 【發明内容】 ]特開千10~204387號公報 (务明所欲解決之問題) 然而,專利文獻1所記载之 較兩面黏著片材之端部向 ,由於剝離紙之兩端 各形狀之剝離紙,於—大,因此製造時必須準備 將另一片剝離紙積層於誃二紙j積層兩面黏著片材後, 複雜。又,於2片剝離紙之端::片材上’製造步驟非常 中一片剝離紙時,手於 口致之情況,當欲剝離其 相雞以進行操作。 97112563 200920809 良好之兩面黏著性片=造步驟簡便,且使用時作業性 器中之發熱部位之固=供適合用於搭載於電子機 (解決問題之手段)途中的兩面黏著性片材。 本發明係一種兩面勒菩,祕μ ^ 面上設置第於另片面材:係於帶片狀黏著層之-特徵在於: '氏於另-面上設置第2剝離紙者,其 第2剝離紙之兩端部與黏 第2剝離紙之至少一端部 第1剝離紙之兩端部與該 於上述黏著層之寬度方向上 著層之兩端部一致; 於上述黏著層之長度方向上 較該黏著層之端部向外側突出 黏著層之兩端部一致。 (發明效果) 二由於第2剝離紙之端部較黏著層及第丨剝離 突向外側突出’因此於使用時可將該第2剝離紙之 部作為拾取引條(pickup⑽,容易用手指或 ^夾持該拾取引條,將該第2剝離紙連同黏著層一起 又’由於第2剥離紙之寬度方向之端 ^者層-致’因此將黏著層貼附於被接合構件上並轉 移可,亦容易對準位置,而容易進行貼附作業。 ^本發明之兩面黏著性片材可藉由下述方式而容易地 即,形成包含第1剝離紙、黏著層及第2剝離紙之 曰^體後,進-步藉由半切割除去多餘之部分,因此本發 月之兩面黏著性片材適合量產,可廉價地提供。又,可带 97112563 200920809 成多個之積層體,並將每丨個積層體切斷,然後進行半切 割’因此能夠以更高之效率進行量產。 【實施方式】 圖1係本發明之兩面黏著性片材之一較佳實施形態之 •立體圖。又,圖i之實施形態之剖面示意圖示於圖^ 3。圖2係帶片狀黏著層2之寬度方向之剖面二 3係帶片狀黏著層2之長度方向之剖面示意圖。° Γ材:二二3所示,基本而言’本發明之兩面黏著性片 材係於γ片狀黏著層(以下,稱 第1剝離紙丨,於另一面之—面上設置 層體。 於另自上狄置弟2剥離紙3所形成的積 本’X明中,如圖2所示,於黏著層 2剝離紙3之兩端部與黏著層 1方向上’第 上,第1剝離紙1之端部可如圖一致。於該方向 部不一致,亦可—较,έ '圖2所不般與黏著層2之端 ,之至少-端部較黏著層1佳為如圖2所示’第1剝離紙1 於:當欲將第2剝離紙、連:=侧突出,其原因在 1剝離時,Τ用手指等 層2 一起自第1剝離紙 部分而容易地進行剝離。 4離紙1之突出至外側之 又,本發明中,如圖3 第2剝離紙3之至少—山…於黏著層2之長度方向上, 出。當將第_紙3遠:部較勒著層2之端部向外侧突 剝離時,該第2剝離紙 點者層2—起自第1剝離紙i 之部分成為拾取%條。=著層2之端部向外側突出 97112563 尹,於黏著層2之長度方向 200920809 上第1剝離Λ 1之兩端部與黏 第2剝離紙3之端部相對於2之兩^ 一致。即’ 1 J 層2之端部及第1剝離紙 之兩者向外侧突出,當用手指或小鑷子等夾持(於 ?該向外側突出之部分時,第1剝離紙i之端部不合: 成妨礙,可容易地夾持住鈿卩不曰k 门* # 亥。P刀’因此將第2剝離紙3連 同黏著層2 -起剝離之作業較為容易 刪3連 f f發明中,考慮到加工成特定形狀 苐2剝離紙3之自黏著層2 午及粘取! 生 為3〜25·,更佳為^之^大^的部分之長度較佳 小鎮子不容易夾持住該突出部分H13、職日寺,手指或 25 mm時,有可能會導致製品良率下°降。差。又,當長於 :者’第2剝離紙3之端部較黏著層2之端 出之口ίΜ立可位於黏著層2之長度方向的一 大 兩端部,又,於位於兩端部之情況,突出之長度二二 =不同。於兩端部突出之情況,可將該兩端 二取 。丨條而拉起,在將黏著層2貼附於被接合構件時容 ’故而較佳。尤其是,當黏著層2之長度較長可 猎由拾取兩端部而防止產生扭曲等,使操作 ^ ’可 進而’本發明中’可較佳地使用如下形態: 所示,於1片第!剝離紙!上,沿黏著層2之θ 、圖 配置多條黏著層2與第2剝離紙3之積層體。、广方向 中’可使多條積層體互相接觸而緊密配置,,該構造 層體之間,黏著層2彼此黏著,導致當將每;:相鄰之積 離時’難以進行剝離,或導致相鄰之積層體亦容 ^7112563 200920809 =二此較佳為,如圖丨、圖2所示,於黏著層2之寬 度方向上,伟t。 、 條積層體相互隔開間隙而配置。該間隙之 第9ί為〇.5 _以上且小於製品寬度(即,黏著層2與 則除層體之寬度)。若該間隙小於G.5腿, 至盥 °所花費之勞力將會增加,又,若該間隙增大 隙部時品ί = 則不僅損耗較大,且會導致於除去間 易將I σσ亦一起剝離,因此不佳。 '黏SI二所示,於1片第1剝離紙1上配置有多條 按二:剝離紙3之積層體之情況,藉由用手指等 „ ;J離紙1之已剝離之積層體的配置區域,可更容 易地剝離新的積声# 斑第9 、曰體車又’與每1條黏著層2 =,^ 氏3之積層體使用1片帛1剝離紙1之構造相 之^^廢棄物之第1剝離紙1之片數減少,因此廢棄物 <體積減小,而較佳。 丨Γί發明中’係將第2剝離紙3及黏著層2自第 y件上’缺^離’繼而’將黏著層2貼附於第1被接合構 3之二:i 2剝離紙3自黏著層2剝離,並於黏著層 之路出面上貼附第2被接合構件,從而將 件與第2被接合構件接合。因此,理 ς 著m 著力大於第1剝離紙1與黏著層2之黏 ’,、體而言,較佳為,(第2剝離紙3與黏著層2之 剝離紙1與黏著層2之勘著力)為〜心 將第;3〜5/2。若該黏著力之比未滿3/2,則於 第2剝雜3及黏著層2自第1剝離紙!剥離時,將有 97112563 200920809 =2剝:紙3與黏著層2剝離之虞,若大於ι〇",則 有第1剝離紙i在進行特定作業以外之,自#㈣ 離之虞,導致作業性下降,故而均不佳。作為哕θ : 調整方法,可改變第i剝離紙】及第2剥離紙:二之 之與第1剝離紙1相接觸之側的黏著力高於 與第2剝離紙3相接觸之側。 對本發明之兩面黏著性片材之各構件進行說明。 本發明中’所謂第i剝離紙卜第2剝離紙3,係指剝 離襯墊、隔片、脫模紙等構件。作為剝離紙以3所^用 之剝離紙,可選擇表面經實施聚矽氧系剝離處理、氟系 離處理等之紙系、樹脂系或金屬箱系剝離紙,紙系具體而 言y考慮使用玻璃紙、道林紙、牛皮紙、或利用聚乙稀對 該等進行填充處理後所得者。樹脂系可使用各種合成樹 脂。具體而言,可舉出:聚氯乙烯、聚對苯二曱酸乙二酯 (PET,polyethylene terephthalate)、乙烯-乙酸乙烯酯 共聚合物、乙烯-丙烯酸乙酯共聚合物、聚乙烯、聚丙烯、 乙烯-丙烯酸共聚合物、離聚物樹脂、聚醯亞胺、聚萘二 曱酸乙二醋等。又’可使用該等樹脂之混合物。進而,亦 可較佳地使用該等樹脂之多層薄膜。又,作為金屬箱系剝 離紙,可舉出··銘箔、銅箔、錫箔等。 對剝離紙1、3之厚度並無特別限定,考慮到下述製造 步驟中之切斷或半切割加工,較佳為5〇 "m以上。又,200920809 IX. Description of the Invention: [Technical Field of the Invention] The present invention relates to two mask sheets in an adhesive layer, and particularly to a workability for mounting in an electronic device. Hot #位等 [previous technique] raw sheet. In recent years, in the fields of precision parts, electrical, and the two sides to which the joined materials are joined together, and the like, and the high-performance properties such as the adhesiveness and electromagnetic wave absorption required for these two sides are required. At the same time, there are many requirements for the V hot spot, considering the workability and the high workability. For example, in Patent Document 2, the end portion of the release paper of the material (adhesive layer) is two sheets: the sheet is sandwiched, and the two sides of the side protrusion are then cut. The end of the sheet of the station is disclosed in the patent document 1 : 曰 专利 专利 1, 1, 1, 【 【 【 【 【 【 【 【 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( Since the end of the adhesive sheet on both sides of the sheet is peeled off from the two ends of the paper, it is necessary to prepare another sheet of the release paper to be laminated on both sides of the second layer of the paper. complex. Further, at the end of the two sheets of release paper: on the sheet, when the production step is very high, a piece of the release paper is used, and when it is desired to peel off the chicken, it is operated. 97112563 200920809 Good two-sided adhesive sheet = easy to make, and the solid part of the working device is used for the two-sided adhesive sheet suitable for use in the electronic machine (the means to solve the problem). The present invention is a two-sided Le Bo, which is provided on the surface of the other surface of the surface of the micro-[i] surface, which is attached to the sheet-like adhesive layer, and is characterized in that: the second peeling paper is provided on the other side, and the second peeling is provided. Both end portions of the paper and at least one end portion of the second release paper have the same end portions of the first release paper in the width direction of the adhesive layer; the length of the adhesive layer is longer than The ends of the adhesive layer are aligned to the outer side and the ends of the adhesive layer are aligned. (Effect of the Invention) 2. Since the end portion of the second release paper protrudes outward from the adhesive layer and the second peeling projection, the second peeling paper can be used as a picking strip (pickup (10), which is easy to use with a finger or ^. Holding the pick-up strip, the second release paper together with the adhesive layer is further "attached to the end of the width direction of the second release paper" so that the adhesive layer is attached to the member to be joined and transferred, It is also easy to align the position, and it is easy to carry out the attaching work. The double-sided adhesive sheet of the present invention can be easily formed by forming the first release paper, the adhesive layer and the second release paper by the following means. After the body, the step is to remove the excess by half-cutting. Therefore, the adhesive sheets on both sides of this month are suitable for mass production and can be provided at low cost. In addition, it can be combined with 97112563 200920809, and each layer will be The one-layered body is cut and then subjected to the half-cutting, so that it can be mass-produced with higher efficiency. [Embodiment] Fig. 1 is a perspective view of a preferred embodiment of the double-sided adhesive sheet of the present invention. Section of the embodiment of Figure i The schematic view is shown in Fig. 3. Fig. 2 is a schematic cross-sectional view of the longitudinal direction of the strip-shaped adhesive layer 2 in the width direction of the two-series strip-like adhesive layer 2. ° Coffin: 22:3, basic The double-sided adhesive sheet of the present invention is attached to a γ-sheet adhesive layer (hereinafter, referred to as a first release paper sheet, and a layer body is provided on the other surface). As shown in FIG. 2, in the formed product 'X', as shown in FIG. 2, the end portions of the first release paper 1 in the direction in which the adhesive layer 2 peels the paper 3 and the direction of the adhesive layer 1 are the same. The direction of the direction is inconsistent, but also - έ 'Fig. 2 and the end of the adhesive layer 2, at least - the end of the adhesive layer 1 is preferably as shown in Figure 2 'the first peeling paper 1 When the first release paper is joined to the side of the second release paper, the reason is that the layer 2 is separated from the first release paper portion by the layer 2 such as a finger, and the paper is easily peeled off. In the invention, as shown in Fig. 3, at least the mountain of the second release paper 3 is in the longitudinal direction of the adhesive layer 2. When the paper sheet 3 is farther than the end portion of the layer 2, the end portion is peeled off to the outside. At the time of the second release paper dot layer 2, the portion from the first release paper i becomes a pickup %. = The end of the layer 2 protrudes outward from the 97112563 Yin, and is 1st in the length direction of the adhesive layer 2 200920809. The end portions of the peeling crucible 1 and the end portions of the adhesive second release paper 3 are aligned with respect to the two of the two, that is, both the end portion of the 1 J layer 2 and the first release paper protrude outward, when using a finger or When the small tweezers are held or the like, the end portion of the first release paper i is not in contact with each other: it is an obstacle, and the door can be easily gripped. The peeling operation of the second release paper 3 together with the adhesive layer 2 is relatively easy to delete. In the invention, it is considered that the self-adhesive layer 2 of the release paper 3 is processed into a specific shape 苐2 and the paste is taken! It is better that the length of the part of ^^^^ is better than that of the small part of the town, it is not easy to hold the protruding part H13, the Japanese temple, the finger or 25 mm, which may cause the product yield to drop. difference. Further, when the end of the second release paper 3 is longer than the end of the adhesive layer 2, the end portion of the second release paper 3 may be located at a large end portion of the longitudinal direction of the adhesive layer 2, and at the both end portions. The length of the highlight is two or two = different. In the case where the two ends are protruded, the two ends can be taken. Pulling up the stringer is preferable when attaching the adhesive layer 2 to the member to be joined. In particular, when the length of the adhesive layer 2 is long, it is possible to prevent the occurrence of distortion or the like by picking both end portions, so that the operation can be further used in the present invention. The following form can be preferably used: ! Stripping paper! The laminate of the plurality of adhesive layers 2 and the second release paper 3 is disposed along the θ of the adhesive layer 2. In the wide direction, a plurality of laminated bodies can be brought into contact with each other and closely arranged, and the adhesive layer 2 is adhered to each other between the structural layer bodies, so that when each of the adjacent layers is separated, it is difficult to peel off or cause Adjacent laminated body is also allowed to be 7112563 200920809 = the second is preferably as shown in FIG. 2 and FIG. 2, in the width direction of the adhesive layer 2, Wei t. The strips are arranged with a gap between them. The 9th ί of the gap is 〇.5 _ or more and less than the width of the article (i.e., the thickness of the adhesive layer 2 and the layer except the layer). If the gap is smaller than the G.5 leg, the labor cost to 盥° will increase, and if the gap increases the gap, the product ί = will not only have a large loss, but also cause the I σ σ to be easily removed. Stripped together, so it's not good. 'As shown in the viscosity SI 2, a plurality of layers of the first release paper 1 are disposed on the first layer: the laminate of the release paper 3, by means of a finger or the like; J is separated from the laminated body of the paper 1 The configuration area makes it easier to peel off the new accumulation sound # 斑第9, 曰 Body and 'with each adhesive layer 2 =, ^ 3's laminate using a piece of 帛1 peeling paper 1 structure phase ^ ^The number of pieces of the first release paper 1 of the waste is reduced, so the waste < volume is reduced, and it is preferable. In the invention, the second release paper 3 and the adhesive layer 2 are missing from the first y ^From then, the adhesive layer 2 is attached to the first joined structure 3: the i 2 release paper 3 is peeled off from the adhesive layer 2, and the second joined member is attached to the exit surface of the adhesive layer, thereby The member is joined to the second member to be joined. Therefore, the force of m is greater than the adhesion of the first release paper 1 to the adhesive layer 2, and the body is preferably (the second release paper 3 and the adhesive layer 2) The adhesive force of the release paper 1 and the adhesive layer 2 is ~3~5/2. If the adhesive force ratio is less than 3/2, the second peeling 3 and the adhesive layer 2 are peeled off from the first layer. Paper! When peeling off, there will be 97112563 2 00920809 = 2 peeling: If the paper 3 and the adhesive layer 2 are peeled off, if it is larger than ι〇", the first peeling paper i is outside the specific work, and since #(四) is separated, the workability is lowered, so Poor. As 哕θ: adjustment method, the ith release paper and the second release paper can be changed: the adhesive force on the side in contact with the first release paper 1 is higher than the contact with the second release paper 3. The member of the double-sided adhesive sheet of the present invention will be described. In the present invention, the term "the ii-th release paper" and the second release paper 3 refer to a member such as a release liner, a separator, and a release paper. For the release paper used in three types, paper, resin or metal box release paper whose surface is subjected to polyfluorination stripping treatment or fluorine separation treatment may be selected, and paper is specifically considered to use cellophane and paper. It is obtained by using a forest paper, a kraft paper, or a filling treatment with polyethylene, and various synthetic resins can be used for the resin. Specifically, polyvinyl chloride or polyethylene terephthalate (polyethylene terephthalate) can be used. PET, polyethylene terephthalate), ethylene-vinyl acetate copolymer Ethylene-ethyl acrylate copolymer, polyethylene, polypropylene, ethylene-acrylic acid copolymer, ionomer resin, polyimine, polyethylene naphthalate, etc. Further, a multilayer film of the above resins may be preferably used. Further, as the metal box-based release paper, there may be mentioned, for example, a foil, a copper foil, a tin foil, etc. The thickness of the release papers 1 and 3 is not In particular, in consideration of the cutting or half-cutting processing in the following manufacturing steps, it is preferably 5 〇 " m or more.

於不進行切斷或半切割加工之情況’自價格方面等考慮較 佳為較薄者。 ~ X 97112563 10 200920809 又’猎由使第1剝離紙丨及第2剝離紙3中之 =或互為不同顏色,可容易地區分第 ,紙3,因此較佳。例*,可較佳地使氏印、二2 =?通常可使用之PET薄膜實施特定剝離= 二吏獲得者;或對PET薄膜自身添加顏 離紙1,以聚乙二二;1’Γ紙系剝離紙來構成第1剝 Λ烯糸剝離、我來構成第2剝離紙3,則可利 ,用素材之差異來區分剝離紙1、3。 本發明中,作為黏著層2,可較㈣ 性之樹脂素材、或於基礎薄膜之兩面附 == 之樹脂素材所得者中之任一種。作為具有自 ::康目的進行選擇’例如可使用丙埽 :乳㈣脂、環氧系樹脂。較佳形態為製成如下黏著声2 ^占者層2係藉由塗佈液狀樹脂 液狀感光性樹脂幸妯,、隹—s t 逆仃乾知,或塗佈 於播用^ 曝光而顯示出適度之黏著性。 ;吏用感光性樹脂素材之情況,可將感光性抖&去# 佈於第!剝離紙!及第2剝離紙3中:一=素材塗 制離紙覆蓋後,自_面或兩用另-片In the case where no cutting or half-cutting is performed, it is considered to be a thinner one from the viewpoint of price. ~ X 97112563 10 200920809 In addition, it is preferable that the first and second release papers 3 of the first release paper and the second release paper 3 have different colors, and the paper 3 can be easily distinguished. For example, it is preferable to carry out the special peeling of the PET film which is usually usable, the second film, the second film, or the film of the PET film itself, to add the polyethylene film 2 to the polyethylene film; When the paper-based release paper is used to form the first peeling bismuth, and the second release paper 3 is formed, it is advantageous to distinguish the release papers 1 and 3 by the difference in the materials. In the present invention, the adhesive layer 2 may be one of a resin material of a (four) property or a resin material having a == on both sides of the base film. The selection is made from the following: For example, a propylene:milk (tetra) grease or an epoxy resin can be used. In a preferred embodiment, the adhesive layer 2 is formed by coating a liquid resin-based photosensitive resin, or by using 隹-st, or by applying it to a broadcast. Appropriate adhesion. When using a photosensitive resin material, you can shake the photosensitive light and go to the first! In the peeling paper! and the second peeling paper 3: one = the material is coated after the paper is covered, the self-side or the dual-use another-piece

π $ π士 士尤§曝先側之剝離紙A 光後制吏用另外製作之透明片材來代替剝離紙,曝 ==:材’積層原來之剝離紙。又,在由二 著性不同之情況,係如上所述,, 一第2剝離紙3側之黏著力大於第— 又,作為黏著層2,可藉由使具有自我黏著性之樹脂素 97112563 11 200920809 材中含有導熱性填充料’而對該黏著層2賦予良好之導熱 陡使知本發明可較佳地用於目標之對搭載於電子設備中 2熱π#:之m定用途中。作為該導熱性填充料,具體而 吕可舉出:氧化鋁粉末或氫氧化鋁粉末、各種二氧化矽粉 末、氮化鋁粉末、氮化硼粉末、碳化矽粉末、鋁或銅等之 各種粉末等。 作為本發明之面黏著性片材,首先形成包含第1剝離紙 1黏著層2及第2剝離紙3之積層體。該積層體之形成 f法可舉出塗佈加工法、刮刀成形加工法、擠出加工法 ^視而要可貫施壓製二次加工。對如此獲得之積層體, 刀另】自第2剝離紙3側及第1剝離紙丨侧進行半切割加 工,藉此獲得所需形狀之兩面黏著性片材。 例如,於圖1之實施形態之情況,首先形成包含第1剝 離、、、氏1、黏著層2及第2剝離紙3之積層體,繼而,使第 2剝離紙3朝向下側’於黏著層2之長度方向上,利用打 孔機將&積層體半切割成特定長度,並自第2剝離紙3剝 離除去短侧之第1剝離紙1及黏著層2,獲得第2剝離紙 3之払取引條。接著,使第1剝離紙1朝向下側,利用打 孔機將該積層體半切割成特定寬度’並自第1剝離紙1剝 離除去間隙部分之黏著層2及第2剝離紙3。 再者,本發明中,由於如上所述般,係在形成包含第1 剝離紙1、黏著層2及第2剝離紙3之積層體後進行半切 QJ加工因此藉由形成多個之大面積之積層體作為該積層 ~ :'將母1個積層體切斷’然後進行半切割加工,能夠 97112563 12 200920809 以更高之效率進行製造。 [實施例] 製作圖1所示之形狀之兩面黏著性片材,作為實施例。 - 第1剝離紙:於厚度為50 # m之PET薄膜之單面實施 剝離處理所得者。 第2剝離紙:於厚度為75 # m之PET薄膜之單面實施 剝離處理所得者。 f „ 再者’第1剝離紙、第2剝離紙均為170 mmxl6. 1 mm。 黏著層用樹脂組成物: 於洛解有ίο質量%之丙烯酸橡膠(日本瑞翁(Ze〇n)股份 有限公司製造之「AR-53L」)之丙烯酸2-乙基己酯(東亞 合成股份有限公司製造之「2EHA」)溶液中,混合1〇質量 %之丙烯酸(東亞合成股份有限公司製造之「AA」),然後 添加0.5質量%之光聚合起始劑2,2—二曱氧基—丨,2—二苯 基乙1網(巧巴精化(Ciba Specialty Chemicals)股份 I有限公司製造)、0.2質量%之三乙二醇二硫醇(丸善化學 股伤有限公司製造)、〇2質量%之2-丁基—2-乙基-1,3-丙二醇二丙烯酸酯(共榮社化學股份有限公司製造)並加 以混合’獲得樹脂組成物。於1〇〇質量份之該樹脂組成物 中混s刀政4 0 0質量份之作為導熱性填充料之氧化鋁 (電氣化學工業公司製造之「以^丨〇」),進行真空消泡 (0.08 MPAx60 min)處理,獲得導熱樹脂組成物。 於上述第2剝離紙之經實施剝離處理之面上塗佈上述 導熱知Μ曰、、且成物’使厚度達到1 〇 〇 # m ’於塗佈面被覆相 97112563 13 200920809 ' 同之薄臈’以使空氣不會進入’自表背侧以3〇〇“j/cffl 照射365 nm之紫外線,形成黏著層。 剝離覆蓋上述塗佈面之薄膜,將第!剝離紙之” _ 離處理之側朝向黏著層並進行層壓,獲得包含第1剝離 紙、黏著層、第2剝離紙之積層體。 ' 將上述積層體置於打孔機中,使第2剝離紙朝向下侧, 之長度方向上,利用打孔機半切割成150-4之長度,剝離除去兩側之第!剝離紙及黏著層。萨此 兩側开> 成長度為1 〇 mm之拾取引條。 次,使第1剝離紙朝向下侧,調節打孔機之饋孔距進 I且=’使黏著層之寬度為3·4,間隙為°.5 _, 二使第1剝離紙於寬度方向上自黏著層之端部向外側 :出’剝離除去間隙及兩端之黏著層及第2剝離 、我。猎此’獲得於第i剝離紙上配置有4條寬度為3 4咖 之占著層與第2_紙之積層體,且該4條積層體係隔開 〇.5随^間隙而平行配置著的兩面黏著性片材。 荖二兩面黏者性片材之(第2剝離紙與黏著層之黏 者力)/(第1剝離紙與黏著層之黏著力)為2/1。 f於本實施例之兩面”性片材,可容易 突出之第2剝離紙的拾取引條而自第i剝離紙剝離,= 以握持拾取引條之狀態,高精度地將 附在搭載於牿定φ工% , 部百丨王乃材貼 ,甘么、寺疋電子5又備中之發熱部位之被接合構件 。?後’自第2剝離紙側用手指按壓,使黏著層充分 貝於被接合構件上後’剝離第2剝離紙,藉此將黏著層轉 97112563 200920809 移至被接合構件上,然後,使另一個被接合構件密著於該 黏著層上,由此可良好地實現接合。 於上述實施例之使第2剝離紙朝向下方並進行半切割 -之步驟中,將第2剝離紙亦去除,獲得無拾取引條之兩面 :黏著性片材。將所獲得之片材之第2剝離紙及黏著層自第 1剝離紙剝離時,無法良好地剝離,且無法良好地將該兩 面黏著性片材貼附於接合處。 () 又,於上述實施例中,調整第1剝離紙及第2剥離紙之 彔J離處理,將(第2剝離紙與黏著層之黏著力) 紙與黏著層之黏著力)調整成未滿3/2,結果,(:自^ 剝離紙剝離第2剝離紙及黏著層時,黏著層之一部分自 2剝離紙浮起。 進而,於上述實施例中,言周整第1剝離紙及第2剝離紙 之剝離處理,將(第2剝離紙與黏著層之黏著力^(第1剝 :紙與黏著層之黏著力)調整為超過ι〇/ι,結 黏著層之黏著力過弱,半切割加工時,。剝離紙 自一部分黏著層浮起。 【圖式簡單說明】 體S。1係本發明之兩面黏著性片材之較佳實施形態的立 圖 圖2係圖1之兩面黏著性片材之寬度方向 之剖面示意 圖3係圖〗之兩面黏著 圖。 ’者丨生片材之長度方向之剖面示意 97112563 200920809 【主要元件符號說明】 1 第1剝離紙 2 帶片狀黏著層 3 第2剝離紙 97112563 16π $ π士士士 § Exposure of the first side of the release paper A light after the use of a separate transparent sheet to replace the release paper, exposure ==: material 'layered original release paper. Further, in the case where the two properties are different, as described above, the adhesion force on the side of the second release paper 3 is larger than that of the first, and as the adhesive layer 2, the resin resin 97112563 11 having self-adhesive property can be used. 200920809 The material contains a thermally conductive filler', and the adhesive layer 2 is provided with a good thermal conductivity. The present invention can be preferably used for a target application in an electronic device. Specific examples of the heat conductive filler include alumina powder, aluminum hydroxide powder, various cerium oxide powders, aluminum nitride powder, boron nitride powder, cerium carbide powder, various powders such as aluminum or copper, and the like. As the surface-adhesive sheet of the present invention, first, a laminate including the first release paper 1 adhesive layer 2 and the second release paper 3 is formed. The formation of the laminate is a coating method, a doctor blade forming method, and an extrusion processing method, and it is necessary to apply a press secondary process. The laminated body thus obtained was subjected to half-cut processing from the side of the second release paper 3 and the side of the first release paper, thereby obtaining a double-sided adhesive sheet having a desired shape. For example, in the case of the embodiment of Fig. 1, first, a laminate including the first peeling layer, the first layer 1, the adhesive layer 2, and the second release paper 3 is formed, and then the second release paper 3 is adhered toward the lower side. In the longitudinal direction of the layer 2, the laminated body is half-cut into a specific length by a punching machine, and the first release paper 1 and the adhesive layer 2 on the short side are peeled off from the second release paper 3 to obtain a second release paper 3 Take the lead. Then, the first release paper 1 is directed downward, and the laminated body is half-cut into a specific width by a punching machine, and the adhesive layer 2 and the second release paper 3 of the gap portion are peeled off from the first release paper 1. Further, in the present invention, as described above, after the layered body including the first release paper 1, the adhesive layer 2, and the second release paper 3 is formed, half-cut QJ processing is performed, thereby forming a plurality of large areas. The laminate is used as the laminate ~ : 'cutting one parent laminate' and then performing half-cut processing, which can be manufactured with higher efficiency at 97112563 12 200920809. [Examples] A double-sided adhesive sheet having the shape shown in Fig. 1 was produced as an example. - 1st release paper: obtained by peeling treatment on one side of a PET film having a thickness of 50 #m. The second release paper: one obtained by peeling treatment on one side of a PET film having a thickness of 75 #m. f „ Furthermore, the first peeling paper and the second release paper are both 170 mm×1.61 mm. Resin composition for adhesive layer: Acrylic rubber of ίο% by mass% (Ze〇n) limited stock In the "2EHA" solution of "AR-53L" manufactured by the company, "2EHA" manufactured by Toagosei Co., Ltd., mixed with 1% by mass of acrylic acid ("AA" manufactured by Toagosei Co., Ltd.) Then, 0.5% by mass of a photopolymerization initiator 2,2-dimethoxy-oxime, 2-diphenylethyl 1 mesh (manufactured by Ciba Specialty Chemicals Co., Ltd.), 0.2 was added. 3% by mass of ethylene glycol dithiol (manufactured by Maruzen Chemical Co., Ltd.) and 2% by mass of 2-butyl- 2-ethyl-1,3-propanediol diacrylate (Kyoeisha Chemical Co., Ltd.) Made by the company) and mixed 'to obtain a resin composition. One part by mass of the resin composition was mixed with 750 parts by mass of alumina, which is a thermal conductive filler ("Electric Chemical Industry Co., Ltd."), for vacuum defoaming ( 0.08 MPAx 60 min) treatment to obtain a thermally conductive resin composition. Applying the above-mentioned heat conduction to the surface of the second release paper subjected to the release treatment, and forming the article 'to a thickness of 1 〇〇# m ' on the coated surface of the coated surface 97112563 13 200920809 ' 'In order to prevent the air from entering the 'UV from the back side of the watch with 3 〇〇" j/cffl 365 nm, an adhesive layer is formed. The film covering the coated surface is peeled off, and the "peel release paper" is removed. The side faces the adhesive layer and is laminated, and a laminate including the first release paper, the adhesive layer, and the second release paper is obtained. The above-mentioned laminated body is placed in a punching machine, and the second release paper is directed to the lower side, and the length of the second release paper is half-cut by a puncher to a length of 150-4, and the two sides are peeled off and removed! Strip the paper and the adhesive layer. Say on both sides of the > into a length of 1 〇 mm picking lead. Then, the first release paper is directed to the lower side, the feed hole of the puncher is adjusted to be I and = 'the width of the adhesive layer is 3.4, the gap is °. 5 _, and the first release paper is oriented in the width direction. The upper part of the self-adhesive layer is outwardly: "exfoliation removes the gap and the adhesive layer at both ends and the second peeling, I." The shovel is provided with four layers of the width of the 3-4 coffee and the layer of the second _ paper, and the four laminated systems are arranged in parallel with each other. Adhesive sheets on both sides. The two-sided adhesive sheet (adhesive force of the second release paper and the adhesive layer) / (adhesion of the first release paper to the adhesive layer) was 2/1. f. The two-sided "sheet" of the present embodiment is peeled off from the ith release paper by the pick-up strip of the second release paper which can be easily protruded, and is attached to the high-precision state in the state of holding the pick-up strip.牿定φ工%, Part of the 丨 丨 乃 乃 , 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 After the member is pasted, the second release paper is peeled off, whereby the adhesive layer is transferred to the member to be joined, 97112563 200920809, and then the other joined member is adhered to the adhesive layer, whereby the bonding can be satisfactorily achieved. In the step of causing the second release paper to face downward and half-cutting in the above embodiment, the second release paper is also removed, and both surfaces of the pickupless strip are obtained: an adhesive sheet. The second sheet obtained is obtained. When the release paper and the adhesive layer were peeled off from the first release paper, the double-sided adhesive sheet could not be favorably peeled off, and the double-sided adhesive sheet could not be adhered to the joint. (In addition, in the above embodiment, the first release paper was adjusted. And the second release paper is separated from the treatment, and will be (2nd) The adhesion between the release paper and the adhesive layer) The adhesion between the paper and the adhesive layer is adjusted to less than 3/2. As a result, when the second release paper and the adhesive layer are peeled off from the release paper, one part of the adhesive layer is peeled off from 2 Further, in the above embodiment, the peeling treatment of the first release paper and the second release paper is performed (the adhesion between the second release paper and the adhesive layer) (first peeling: paper and adhesive layer) The adhesion is adjusted to exceed ι〇/ι, and the adhesion of the adhesive layer is too weak. During the half-cut processing, the release paper floats from a part of the adhesive layer. [Simplified illustration] The body S. 1 is the invention Figure 2 is a schematic view of a preferred embodiment of the two-sided adhesive sheet. Figure 2 is a cross-sectional view of the two-sided adhesive sheet in the width direction of the two-sided adhesive sheet. Figure 2 shows the relationship between the two sides of the sheet. Illustrated 97112563 200920809 [Description of main component symbols] 1 1st release paper 2 with sheet-like adhesive layer 3 2nd release paper 97112563 16

Claims (1)

200920809 十、申請專利範園: 1.-種兩面黏著性諸,係於帶片狀料 置第1剝離紙,於另一面上設置第 σ又 於: 又置第2剝離紙者,其特徵在 第2剥離紙之兩端部與黏 第2剝離紙之至少一端部 第1剝離紙之兩端部與該 : 於上述黏著層之寬度方向上 著層之兩端部一致; 於上述黏著層之長度方向上 r較該黏著層之端部向外側突出 黏著層之兩端部一致。 2. 如申請專利範圍第!項之 1片第1剝離紙上,>勒菩展少^ 片材其卜於 知抓 黏者層之寬度方向,平耔抑里士夕 條π片狀黏著層盘筮9幻 丁配置有夕 译考·層興第2剝離紙之積層體。 3. 如申請專利範圍第2項之兩面黏著性片 4 一主1 隙而配置於第1剝離紙上。 .申5月專利範圍第1至3項_任一頊之Λ & 材,I中,鹛灿二 、r任項之兩面黏著性片 思 冑狀兩面黏著層與第2剝 黏者層與第1剝離紙之#以。 ^耆力大於該 5. 如申凊專利範圍第丨至3 材,其中,帶壯$ a* — 項尹任一項之兩面黏著性片 好之導熱性。、’占者層含有導熱性填充料,而具有良 6. 如中請專利範圍第4項之兩 狀兩面勸著層含有導 % #材其中,▼ ”、真充科,而具有良好之導熱性。 97112563 17200920809 X. Applying for the patent garden: 1.- Kind of adhesive on both sides, which is based on the first release paper with a sheet material, and the σ on the other side: and the second release paper, which is characterized by Both end portions of the second release paper and at least one end portion of the second release paper are adhered to both end portions of the first release paper in the width direction of the adhesive layer; and the adhesive layer is In the longitudinal direction, r is aligned with the end portions of the adhesive layer that protrude outward from the end portions of the adhesive layer. 2. If you apply for a patent scope! On the 1st peeling paper of the item, > Le Bo exhibition less ^ The sheet is in the width direction of the sticky layer of the sticky layer, and the flat 耔 耔 夕 夕 π 片 状 状 状 筮 筮 筮 筮 筮 幻 幻 幻 幻Translation of the layered body of the second peeling paper. 3. Place the two-sided adhesive sheet 4 on the first release paper as in the second paragraph of the patent application. The application of the May patent range 1 to 3 _ any 顼 Λ & material, I, 鹛 二 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 The first peeling paper ##. ^ 耆 大于 greater than the 5. If the scope of the application of the patent range 丨 to 3, which, with the strong $ a * - Xiang Yin any one of the two sides of the adhesive film good thermal conductivity. The 'occupant layer contains a thermal conductive filler, and has a good 6. As in the fourth paragraph of the patent scope, the two sides of the two sides are persuaded that the layer contains the conductive material #, among them, ”, true charge, and has good thermal conductivity. Sex. 97112563 17
TW097112563A 2007-04-06 2008-04-03 Double-faced pressure-sensitive adhesive sheet TW200920809A (en)

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JP2007100183A JP5336050B2 (en) 2007-04-06 2007-04-06 Double-sided adhesive sheet

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JP6368507B2 (en) * 2014-03-14 2018-08-01 日東シンコー株式会社 Thermally conductive sheet with release sheet
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