TW200835754A

TW200835754A - Ink-jet ink

Info

Publication number: TW200835754A
Application number: TW096143018A
Authority: TW
Inventors: Satoshi Tanioka; Kaori Eguchi; Takashi Kikukawa; Hiroshi Anraku; Shinsuke Hanafusa
Original assignee: Chisso Corp
Priority date: 2006-11-16
Filing date: 2007-11-14
Publication date: 2008-09-01
Also published as: JPWO2008059986A1; WO2008059986A1; KR20090086559A

Abstract

An ink-jet ink for forming a thicker film by inkjetting one time is provided. This invention relates to an ink-jet ink, including at least a nadimide compound replaced by an alkenyl group. The ink-jet ink further includes a polymer. The ink-jet ink further includes a solvent.

Description

200835754200835754

x ^pil.Q〇C 九、發明說明：【發明所屬之技術領域】本每明疋關於一種噴黑累以於電子零件製作中形成：二例如是關於-種含有用x ^pil.Q〇C IX. Description of the invention: [Technical field to which the invention pertains] Each of the alums is formed in the production of electronic parts for the purpose of:

亞胺化合物（A)的噴黑墨、、、^的經烯基取代之耐地醯聚醯亞胺膜、及形成該浐硫水使用該噴墨墨水而形成的膜基板的電子零件。亞胺膜的薄膜基板、具有該薄【先前技術】聚醯亞胺因耐熱性、曰本專利特開曰本專利特開電子通信領域的材料[伤緣異’因此是廣泛用於 2000-039714號公報直參知'日本專利特開 2003- 238683號公報（直^文獻1 ) 2004- 094118 號公報（專獻 2) 使用聚醯亞胺作為I獻3)]。使用纖者感光性以=案膜的情況… 用喷墨形成所期望圖案膜的成圖案，近年來研究有利雖提出有各種噴黑累、 2003-213165號公報[例如，參照日本專利特開 2006·131730號公報（專1，獻4 )、日本專利特開胺系喷墨墨水，咖3)]，但若欲製備聚敏亞因此為了製備最佳黏度的墨高=，溶劑的比例而減少墨水φ 卞马貝墨墨水，而必須增如下問題：丨蝴所得^；^含量。目此，存在如另方面、、二歸基取代之耐地酿亞胺化合物是可籍由 5 200835754“ wpii.doc 加熱進行聚合而成為具有醯亞胺鍵的固體產物（聚醯亞胺）的熱固性化合物[例如，參照日本專利特開昭59_〇8〇661號公報（專利文獻6)、日本專利特開昭6〇_124619號公報（專利文獻7)、日本專利特開昭61_〇18761號公報（專利文獻 8)、日本專利特開平〇5_3〇1948號公報（專利文獻9)]。The black ink of the imine compound (A), the alkenyl-substituted ruthenium-containing polyimide film of the imine compound (A), and the electronic component of the film substrate formed by using the inkjet ink. A film substrate of an imine film, which has the thin [Prior Art] Polyimine, which is widely used in the field of electronic communication, because of its heat resistance, and the patent of the Japanese Patent Laid-Open Patent Publication No. 2000-039714 Japanese Unexamined Patent Publication No. 2003- 238683 (Scheme 1) No. 2004-094118 (Special 2) Polyimine is used as I (3). In the case of using a photosensitive film to form a film, the pattern of a desired pattern film is formed by inkjet. In recent years, research has been conducted in various publications, and various publications have been proposed. [JP-A-2003-213165 [For example, refer to Japanese Patent Laid-Open Publication No. 2006-2006 · 131730 (Special 1, 4), Japanese patented open-amine inkjet ink, coffee 3)], but if you want to prepare poly-sensitization, it is reduced in order to prepare the optimum viscosity of the ink = solvent ratio Ink φ 卞 Ma Bei ink, and must increase the following problem: 所得所得 ^ ^ ^ content. Therefore, there is another aspect, the di-negatively substituted tert-ylidene imide compound can be polymerized by heating according to 5 200835754 "wpii.doc to become a solid product (polyimine) having a quinone bond. For example, Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei.

烯二醯亞胺型、乙炔型、耐地酸型等熱固性聚醯亞胺疋藉由末端具有不飽和基的低分子量、低黏性化合物的立體交聯而獲得，因此與先前的線狀聚醯亞胺相比更容易加工因該熱固性聚醯亞胺表現良好的耐熱性，硬化時空隙或者龜㈣產生少，因此具有作為成形材料或者積層材料的基體樹脂優異的特性。經烯基取代之耐地酿亞胺化合物是熱固性聚酸亞胺的形成材料’是具錢鬆結構的低分子量醯亞胺單體，因此 =於除脂肪族烴外幾乎所有的有機溶劑，即使以溶液狀悲長期保存也不會引起結晶析出或者凝膠化，可穩定使 =ΐ外’對詳細的硬化機制仍不明瞭，藉由加熱，烯丙基^冰片烯骨架中的雙鍵進行烯（Ene)反應或者狄阿 =lels-Alde〇反應，形成立敎騎構。如此表現出對 =用=的溶解性，硬化物表現出良好的耐熱性、機械特性、财化學藥品性，因此研究有對樹脂·改質劑、 u、及各種塗佈材料、耐熱黏接劑等的用途擴展。例如，也提出使用經烯基取代之魏酸亞胺化合物妒成圖案[例如’參照日本補_平爪32湖號公報（專利文獻H))]，但對利时墨形成所期望圖案後，藉由敎 6 200835754 ,Thermosetting polyamidiamines such as enediamine type, acetylene type, and acid-resistant type are obtained by stereo cross-linking of low molecular weight, low-viscosity compounds having an unsaturated group at the end, and thus are combined with the prior linear polycondensation. The bismuth imine is more easily processed because of the heat resistance of the thermosetting polyimide, and the void or the turtle (4) is less likely to be formed during curing, and therefore has excellent properties as a matrix resin as a molding material or a laminate material. The alkenyl-substituted refractory imine compound is a material for forming a thermosetting polyimine, which is a low molecular weight quinone imine monomer having a Qiansong structure, and therefore = almost all organic solvents except aliphatic hydrocarbons, even In the long-term preservation of the solution, it will not cause crystallization or gelation, and it can be stabilized. The detailed hardening mechanism is still unknown. By heating, the double bond in the allyl-bornene skeleton is used to carry out the olefin. The (Ene) reaction or the Dear-lels-Alde〇 reaction forms a stand-up structure. Thus, the solubility of = use = is exhibited, and the cured product exhibits good heat resistance, mechanical properties, and chemical properties. Therefore, there are researches on resins, modifiers, and various coating materials and heat-resistant adhesives. The use of such extensions. For example, it has also been proposed to use an alkenyl-substituted teic acid imine compound to form a pattern [for example, 'refer to Japanese supplement_Ping Chong 32 Lake No. (Patent Document H)), but after forming a desired pattern for the Lishi ink, With 敎6 200835754 ,

i ^piI.ClOC 硬化而聚合时法未餘何_或暗示。、、夫φ另、Uf於合有聚醯胺酸、可溶性聚醯亞胺等的清 :配二、主::二烯基取代之耐地醯亞胺化合物而成的液報（專利文獻11)本專特開2004-341030號公、 ]。y而，該技術中聚酿胺酸、可溶性 =亞胺，胺系高分子化合物是主體，為了二糸配向_機械強度或者耐摩擦性提昇，而添加微量㈣&^為0.6%及〇觀）。觸由輯絲代㈣胺化合物的熱魏㈣絲ϋ懿膜未作任何揭示，對藉由贺墨進行印刷塗佈也未作任何暗示。i ^ piI.ClOC hardens and does not contain any _ or implied. , 夫、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、、 This special open 2004-341030, public. y, in this technology, poly-aracine, soluble = imine, amine-based polymer compound is the main body, in order to improve the mechanical strength or friction resistance of the diterpene alignment, adding a small amount (four) & ^ 0.6% and 〇 )) . The thermal Wei (tetra) silk film of the amine compound was not disclosed, and no suggestion was made for printing by He ink.

[專利文獻1]日本專利特開2〇〇〇_〇39714號公報。 [專利文獻2]日本專利特開2〇〇3_238683號公報。 [專利文獻3]日本專利特開2〇〇4_〇94118號公報。 [專利文獻4]日本專利特開2〇〇3_213165號公報。 [專利文獻5]曰本專利特開2〇〇6_13173〇號公報。 [專利文獻6]日本專利特開昭59_〇8〇661號公報。 [專利文獻7]日本專利特開昭⑽246!9號公報。 [專利文獻8]曰本專利特開昭61_〇18761號公報。 [專利文獻9]日本專利特開平〇5_3〇1948號公 [專利文獻ίο]日本專利特開平〇9-32521〇號公聋 [專利文獻11]日本專利特開2004_341030號公翱 [專利文獻12]日本專利特開平〇7_〇53516鱿八知【發明内容】 7 200835754 X ^pif.doc [發明所欲解決之問題] 本發月毒求種錯由一次喷墨（i) 厚聚醯亞胺膜（女协堃士人，λ」3 I」办成罕乂、、大於專於1 μιη )的噴墨墨水。 [解決問題之手段] 本發明者等人鑒於上述狀況，發現含有至少-種經稀基取代之耐地亞胺化合物⑷㈣墨4水、進而含有南分子化合物⑻的嘴墨墨水、進而含有溶劑（C)的喷墨墨水。 '[Patent Document 1] Japanese Patent Laid-Open Publication No. Hei. No. Hei. [Patent Document 2] Japanese Patent Laid-Open Publication No. Hei. No. 2-238683. [Patent Document 3] Japanese Laid-Open Patent Publication No. Hei. No. Hei. [Patent Document 4] Japanese Laid-Open Patent Publication No. Hei. No. 2-213165. [Patent Document 5] Japanese Patent Laid-Open Publication No. Hei. No. Hei. [Patent Document 6] Japanese Patent Laid-Open Publication No. SHO 59-〇8〇661. [Patent Document 7] Japanese Patent Laid-Open Publication No. (10) 246! [Patent Document 8] Japanese Patent Laid-Open Publication No. SHO 61_〇18761. [Patent Document 9] Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Japanese Patent Special Kaikai 7_〇53516鱿八知[Summary] 7 200835754 X ^pif.doc [The problem to be solved by the invention] This month's poison is wrong by one inkjet (i) thick polyimine Membrane (Women's Association, λ" 3 I" is made into a rare ink, larger than 1 μιη). [Means for Solving the Problem] In view of the above-described circumstances, the inventors of the present invention have found that at least a rare-substituted dysinimide compound (4) (4) ink 4 water, and further contains a south molecular compound (8), and further contains a solvent ( C) Inkjet ink. '

本發明提供一種如以下的喷墨墨水等。 [1] -種喷44水，其含有至少—種經烯基取代之耐地醯亞胺化合物（Α)。 [2] 如上述[1]所述之噴墨墨水，其中上述經烯基取代之财地酸亞胺化合物⑷是使單胺、二胺、三胺或者四胺與下述式（1，）所示之經絲取狀_酸酐反應而成的經烯基取代之耐地醯亞胺化合物。 [化 10]The present invention provides an inkjet ink or the like as follows. [1] - Spray 44 water containing at least one type of alkenyl substituted imide compound (Α). [2] The inkjet ink according to [1] above, wherein the above alkenyl-substituted phthalic acid imine compound (4) is a monoamine, a diamine, a triamine or a tetraamine and the following formula (1,) An alkenyl-substituted ruthenium imine compound obtained by reacting a filament-like anhydride as shown. [化10]

00

式（Γ)中，R1及R2分別獨立為氳、石炭數為1〜之烷基、碳數為3〜6之烯基、碳數為5〜8之環烷基、碳數為6〜12之芳基或者节基中的任一種。 [3]如上述[1]或[2]所述之喷墨墨水，其中上述經婦基取代之耐地醯亞胺化合物（Α)是下述式（！）所示之化人 8 200835754In the formula (Γ), R1 and R2 are each independently an anthracene, an anthracene having an alkyl group of 1 to an alkyl group, an alkenyl group having a carbon number of 3 to 6, a cycloalkyl group having a carbon number of 5 to 8, and a carbon number of 6 to 12; Any of an aryl group or a benzyl group. [3] The inkjet ink according to the above [1] or [2] wherein the above-mentioned base-substituted yttrium imine compound (Α) is a person represented by the following formula (!) 8 200835754

i ^]jif.d〇C 物 [化 11]i ^]jif.d〇C 物 [化11]

H2C=C一CH2C=C-C

式（1)中，以及^ ⑴ 烷基、碳數為3〜6之、j：n 蜀立為氳、碳數為1〜12之為ό〜12之芳基或者苄人歎為5〜8之環烷基、碳數 -時，Α數:t種、琳 12之羥基烷基、碳數為"、、❿12之烷基、奴數為1〜芳基、苄基、以-{(CH彳Ω之環烷基、碳數為6〜12之 S為分別獨立選擇的Uq fj〇)仰说（其中q、r、且…。之整數、者;=者二整數並烧基、以规佩# (直中不之聚氣稀基In the formula (1), and (1) an alkyl group, a carbon number of 3 to 6, j: n is 氲, a carbon number of 1 to 12 is an aryl group of ό~12 or a benzyl group is 5 to 8 Cycloalkyl, carbon number -, number of turns: t species, hydroxyalkyl group of 12, carbon number ", 烷基12 alkyl, slave number 1~ aryl, benzyl, with -{( CH环Ω cycloalkyl, S with a carbon number of 6~12 is independently selected Uq fj〇) (wherein q, r, and... integers, = two integers and burned,规佩# (Straight in the air

表示碳數為卜4之亞狀R4i者1之整數、R 土 R表示虱或者碳數為1〜4之以者烷基）表不之基團、以_C6H4-TC6h5{其中，T為_ch2_、 -C(CH3)2·、-CO·、_S_或者初2]表示之基團或者此等基團的直接鍵結於料環的卜3個氫被羥絲代之基團， n = 2時，R3是碳數為2〜2〇之亞烷基{亞烷基中互相不鄰接的任意亞甲基可被-〇_或者_ch=ch_取代，任意氫可被氟取代}、碳數為5〜8之亞環烷基、碳數為6〜12之亞芳基、以-(RVQHLpR5-(其中，a為〇或者1之整數、R 及R5分別獨立為碳數為1〜4之亞烧基）表示之基團 -C6H4-T-C6H4- 、 -C6H4_T_C6H4-T-C6H4_ 或 9 200835754A group indicating that the carbon number is a sub-form of R4i of R 4i, R R represents a group of 虱 or a carbon number of 1 to 4, and is represented by _C6H4-TC6h5 {where T is _ a group represented by ch2_, -C(CH3)2·, -CO·, _S_ or epoch 2] or a group of such groups directly bonded to the ring of the hydrogen ring by the hydroxy silk, n When 2, R3 is an alkylene group having a carbon number of 2 to 2 {. { Any methylene group in the alkylene group which is not adjacent to each other may be substituted by -〇_ or _ch=ch_, and any hydrogen may be substituted by fluorine} a cycloalkylene group having 5 to 8 carbon atoms, an arylene group having 6 to 12 carbon atoms, and -(RVQHLpR5- (wherein a is an integer of 〇 or 1 and R and R5 are each independently a carbon number of 1) a group represented by a ~4 sub-alkyl group - C6H4-T-C6H4-, -C6H4_T_C6H4-T-C6H4_ or 9 200835754

± j^xI.ClOC -QHi-T’-QH4 其中，T是單鍵、碳數為i 6 之亞烧基七(ch3)2_、c(CF3)2·、_CO-、_〇_、^者 -S〇2-，Γ是^Η2_或者·〇_。}表示之基團、或者此等基團的直接鍵結於芳香環的1〜3個氫被羥基取代之基團、式（7) 所示之基團或者式（8)所示之基團，式（7)中，x獨立為1〜6之整數、y為1〜70之整數， [化 12]± j^xI.ClOC -QHi-T'-QH4 wherein T is a single bond, and the number of carbon atoms is i 6 (ch3)2_, c(CF3)2·, _CO-, _〇_, ^ -S〇2-, Γ is ^Η2_ or ·〇_. a group represented by }, or a group in which one or three hydrogens of the aromatic ring are directly substituted with a hydroxyl group, a group represented by the formula (7), or a group represented by the formula (8). In the formula (7), x is independently an integer of 1 to 6, and y is an integer of 1 to 70, [Chemical 12]

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i>i—Ο—j-Si-^C: Me Mei>i-Ο-j-Si-^C: Me Me

n=3時，R3為下述式（5)或者（5，）所示之基團 [化 13]When n=3, R3 is a group represented by the following formula (5) or (5,) [Chemical 13]

式（5)中，R是氫、氟、氯、_〇h、_〇cf3、-〇CF2H、 -CF3、-CF2H、-CFH2、-OCF2CF2H、·ocf2cfhcf3、或者碳數為1〜10之烷基，式（5)、（5，）中，r4、r5、r6分別獨立，是單鍵、反_1，4_亞環己基、1，3_二噁燒_2,5_二基、n 亞苯基、氫可被氟取代的1，4-亞苯基、或者碳數為ι〜1〇 200835754^In the formula (5), R is hydrogen, fluorine, chlorine, _〇h, _〇cf3, -〇CF2H, -CF3, -CF2H, -CFH2, -OCF2CF2H, ·ocf2cfhcf3, or an alkane having a carbon number of 1 to 10. In the formula, (5), (5,), r4, r5, and r6 are each independently, and are a single bond, a reverse _1, a 4-cyclohexylene group, a 1,3 dioxin 2, a 5-diyl group, n phenylene, hydrogen 1,4-phenylene substituted by fluorine, or carbon number ι~1〇200835754^

l ^piI*Cl〇C 之亞烷基，亞烷基中互相不鄰接的任意亞甲基可被_0_或者 -CH = CH-取代’任意氫可被氟取代，n：=4時，R3為下述式（6)所示之基團。 [化 14] \7 / X \ ⑹ / \ φ 式（6)中，飞4、&5、&6、&7分別獨立，是單鍵、反-1，4- 亞環己基、1，3-二噁烧·2,5·二基、1，4_亞苯基、氫可被氟取代的1，4-亞苯基、或者碳數為1〜1〇之亞烷基，亞炫基中互相不鄰接的任意亞曱基可被·〇_或者-CH=CH-取代，任意氫可被氟取代。 [4] 如上述[3]所述之喷墨墨水，其中2。 [5] 如上述[3]所述之喷墨墨水，其中η為2，R3是碳數為2〜15之亞烷基{亞烷基中互相不鄰接的任意亞甲基可被或者_CH = CH-取代，任意氫可被氟取代}、以 -(R)a-C6H4_R5-(其中，a為〇或者1之整數、r及R5分別獨立為碳數為1〜4之亞烷基）表示之基團、以 -c6h4-t_c6h4- 、 -c6h4_t_c6h4-t-c6h4-或者 C6lVrLC6H4-T-C6H4-T，-C6H4-{其中 T 為單鍵…CH2-、 •C(CH3)2…C(CF3)2…c〇…〇〜s 或者-s〇2，γ為-CH2-或者-Ο-。}表示之基團。尸[6]如上述[3]所述之喷墨墨水，其中R1及R2分別獨立為氫或者碳數為1〜6之烷基，η為2，R3是碳數為2〜15 11 200835754l ^ piI * Cl 〇 C alkylene, any methylene group in the alkylene group not adjacent to each other may be replaced by _0_ or -CH = CH- 'any hydrogen may be substituted by fluorine, n:= 4, R3 is a group represented by the following formula (6). [Chem. 14] \7 / X \ (6) / \ φ In equation (6), fly 4, & 5, & 6, and & 7 are independent, single bond, trans-1,4-cyclohexylene, 1,3-dioxin, 2,5·diyl, 1,4-phenylene, 1,4-phenylene group in which hydrogen can be substituted by fluorine, or alkylene group having a carbon number of 1 to 1 fluorene, Any of the subfluorene groups which are not adjacent to each other may be substituted by 〇_ or -CH=CH-, and any hydrogen may be substituted by fluorine. [4] The inkjet ink according to [3] above, wherein. [5] The inkjet ink according to [3] above, wherein n is 2, and R3 is an alkylene group having 2 to 15 carbon atoms; any methylene group in the alkylene group which is not adjacent to each other may be or -CH = CH-substitution, any hydrogen can be substituted by fluorine}, with -(R)a-C6H4_R5- (where a is an integer of 〇 or 1 and r and R5 are each independently an alkylene group having a carbon number of 1 to 4) The group represented by -c6h4-t_c6h4-, -c6h4_t_c6h4-t-c6h4- or C6lVrLC6H4-T-C6H4-T, -C6H4-{where T is a single bond...CH2-, •C(CH3)2...C( CF3)2...c〇...〇~s or -s〇2, γ is -CH2- or -Ο-. } indicates the group. [6] The inkjet ink according to [3] above, wherein R1 and R2 are each independently hydrogen or an alkyl group having 1 to 6 carbon atoms, η is 2, and R3 is a carbon number of 2 to 15 11 200835754

ζ,υζ. i^pif.doC 之亞烷基{亞烷基中互相不鄰接的任意亞曱基可被或者 •CH=CH-取代，任意氳可被氟取代}、式（2)所示之基團、式（3)所示之基團、式（4)所示之基團、式（7)所示之基團或者式（8)所示之基團。ζ,υζ. i^pif.doC alkylene {any alkylene group in the alkylene group which is not adjacent to each other may be substituted by or CH=CH-, any hydrazine may be substituted by fluorine}, formula (2) a group, a group represented by the formula (3), a group represented by the formula (4), a group represented by the formula (7) or a group represented by the formula (8).

[化 15][化15]

(4)(4)

Me MeMe Me

式（2)及（4)中，R是包括-CH2-、-CH2CH2-、-0·、 C(CH3)2-、-C(CF3)2-、-S02-之有機基，式（4)中，X 是包括-CH2-、-〇-之有機基，式（7)中，x獨立為1〜6之整數、y為1〜之整數。 12In the formulae (2) and (4), R is an organic group including -CH2-, -CH2CH2-, -0, C(CH3)2-, -C(CF3)2-, -S02-, and formula (4) Wherein X is an organic group including -CH2-, -〇-, and in the formula (7), x is independently an integer of 1 to 6, and y is an integer of 1 to 6. 12

200835754 z,uz, i ^pif.d〇C200835754 z,uz, i ^pif.d〇C

[7]如上述[3]所述之喷墨墨水，其中R1及R2分別獨立為氫或者碳數為1〜6之烷基， η為3，R3以式（5_1 )、式（5M )或者式（5^2 )表不。 [化 16][7] The inkjet ink according to the above [3], wherein R1 and R2 are each independently hydrogen or an alkyl group having 1 to 6 carbon atoms, η is 3, and R3 is represented by formula (5_1), formula (5M) or Formula (5^2) does not. [Chemistry 16]

式（5-1)中，R是碳數為1〜10之烷基或者-011，式 (5’-2)中，R4、R5、R6分別獨立為1,2-亞乙基、1，4_亞丁基。 [8]如上述[3]所述之喷墨墨水，其中R1及R2分別獨立為氳或者碳數為1〜6之烷基， η為4，R3以下述式（6-1)表示。 [化 17] 13 200835754In the formula (5-1), R is an alkyl group having a carbon number of 1 to 10 or -011, and in the formula (5'-2), R4, R5 and R6 are each independently 1,2-ethylene and 1, 4_butylene. [8] The inkjet ink according to the above [3], wherein R1 and R2 are each independently 氲 or an alkyl group having 1 to 6 carbon atoms, η is 4, and R3 is represented by the following formula (6-1). [Chem. 17] 13 200835754

厶 v/厶 1 jjjif.d〇C厶 v/厶 1 jjjif.d〇C

"Λ [3]所述之嘴墨墨水，其中含有選自n為1的謇，、_基取代之耐地酿亞胺化合物⑷、η為2的經稀基取代之耐地酿亞胺化合物（Α)、η為3的經烯基取代之耐地酸亞胺化合物（Α)、及η為4的經烯基取代之耐地醯亞胺化合物（Α)的至少2種經烯基取代之耐地醯亞胺化合物 (Α)。 [10]如上述[3]所述之喷墨墨水，其中含有經烯基取代之耐地酿亞胺化合物（Α)之至少2種，該經烯基取代之耐地醯亞胺化合物（Α)中，R1及R2分別獨立為氫或者碳數為1〜6之烷基，R3是碳數為1〜12之烷基（η=1)、破數為 6〜12 之芳基（η= 1)、-(CH2)p_ (η = 2、ρ 為 6〜12 之整數）、式（2-1)所示之基團、式（3)所示之基團、式 (4·1)所示之基團、式（7-1)所示之基團、式所示之基團、式（5-2)所示之基團、式（5-3)所示之基團、式（5’_1)所示之基團、式（5’·3)所示之基團、式（卜1) 所不之基團。 14 200835754 , 上丄i»doc [化 18]< 嘴 [3] The ink ink of the mouth, which contains a ruthenium selected from the group consisting of n, _ group-substituted saponin compound (4), and η of 2, which is substituted with a dilute base. At least two alkenyl groups of a compound (Α), an alkenyl-substituted lysine compound (η) substituted with η, and an alkenyl-substituted quinone imine compound (Α) having a η of 4 Substituted for the ruthenium imine compound (Α). [10] The inkjet ink according to the above [3], which contains at least two kinds of alkenyl-substituted ruthenium imine compounds (Α), the alkenyl-substituted ruthenium imine compound (Α In the above, R1 and R2 are each independently hydrogen or an alkyl group having 1 to 6 carbon atoms, and R3 is an alkyl group having a carbon number of 1 to 12 (η = 1) and an aryl group having a number of 6 to 12 (η = 1), -(CH2)p_ (η = 2, ρ is an integer of 6 to 12), a group represented by the formula (2-1), a group represented by the formula (3), and a formula (4·1) The group shown, the group represented by the formula (7-1), the group represented by the formula, the group represented by the formula (5-2), the group represented by the formula (5-3), and the formula a group represented by (5'_1), a group represented by the formula (5'.3), and a group not represented by the formula (b). 14 200835754 , 上丄i»doc [化 18]

15 200835754^15 200835754^

i ^piI.uOCi ^piI.uOC

進而含有南分子化合物（B)。 [12] 如上述[U]所述之喷墨墨水，其中上述高分子化合物（B)是聚醯胺酸或者聚醯亞胺之至少一種。 [13] 如上述[11]或上述[12]所述之喷墨墨水，其中上述尚分子化合物（B)之重量平均分子量為1，〇〇〇〜5，⑽〇。 [14] 如上述[ι]〜[13]中任一項所述之噴墨墨水，其中進而含有溶劑（C)。 [15] 如上述[14]所述之喷墨墨水，其中溶劑（c)是選 ^由乳酸乙醋、乙醇、乙二醇、丙二醇、甘油、二乙二醇 _甲醚、一乙二醇二***、二乙二醇甲基***、二乙二醇單^醚乙s欠酯、乙二醇單丁醚、乙二醇單***乙酸酯、丙 ^醇^甲醚乙酸酯、3-甲氧基丙酸曱酯、3-乙氧基丙酸乙酉曰娘己酮及γ-丁内酯所組成之族群的大於等於一種。 [16] 如上述[η〜[15]中任一項所述之噴墨墨水，其中目對於100重量份噴墨墨*，含有1重量份〜99重量份上讀烯基取代之耐地酿亞胺化合物（Α)。 [Π]如上述[1]〜[15]中任一項所述之喷墨墨水，其中卜二；重里份實墨墨水，含有10重量份〜80重量份迷經烯基取代之耐地醯亞胺化合物⑷。 16 200835754 opif.doc [18] 如上述[1]〜[15]中任一項所述之噴墨墨水，其中相對於100重量份喷墨墨水，含有22重量份〜7〇重量份上述經細基取代之耐地酿亞胺化合物（A)。 [19] 一種聚酿亞胺膜或者圖案狀聚酿亞胺膜，其是利用喷墨塗佈方法塗佈如上述[。〜[丨幻中任一項所述之喷墨墨水而形成麵’將該塗酿行加祕理形成㈣亞胺膜而獲得。、的步驟 [2〇]種聚醯亞胺膜形成方法，纟包括利用喷墨塗佈如上述Π]〜間中任_項所述之噴墨墨水而形成步驟、及龍麵騎加熱處理㈣成親亞麵胺膜2^薄祕板’其是彻如上述[2_述之聚醯亞、形成方法於基板上形成聚醯亞胺膜。板。[22]—種電子零件，其具有如上述[21]所述之薄膜基 [發明的效果] 墨即較好態樣的噴墨墨水，則藉由一次喷土「j形成具有較厚膜厚的聚醯亞胺膜。之喷墨墨水形成的聚酿亞胺膜耐，由本舍明電子零可靠性、良率提昇。胸紐1絕緣性高，為=本發明之上述和其他目的、特徵 W下文特舉較佳實關，並‘更_ 明如下。己口所附圖式，作詳細說【實施方式】 200835754Further, it contains a south molecular compound (B). [12] The inkjet ink according to [U], wherein the polymer compound (B) is at least one of polyamic acid or polyimine. [13] The inkjet ink according to the above [11], wherein the molecular weight average molecular weight of the above-mentioned molecular compound (B) is 1, 〇〇〇 5, (10) 〇. [14] The inkjet ink according to any one of [1], wherein the solvent (C) is further contained. [15] The inkjet ink according to [14] above, wherein the solvent (c) is selected from the group consisting of ethyl lactate, ethanol, ethylene glycol, propylene glycol, glycerin, diethylene glycol monomethyl ether, and monoethylene glycol. Diethyl ether, diethylene glycol methyl ether, diethylene glycol monoethyl ether ethyl ether, ethylene glycol monobutyl ether, ethylene glycol monoethyl ether acetate, propyl alcohol methyl ether acetate, 3 The group consisting of methoxymethoxypropionate, 3-ethoxypropionate, and γ-butyrolactone is equal to or greater than one. [16] The inkjet ink according to any one of [n1 to [15] wherein, for 100 parts by weight of the inkjet ink*, 1 part by weight to 99 parts by weight of the read alkenyl group is substituted for the ground-resisting Imine compound (Α). The inkjet ink according to any one of the above-mentioned [1] to [15] wherein, in the second embodiment, the heavy ink ink contains 10 parts by weight to 80 parts by weight of the vinyl group substituted by the alkenyl group. Imine compound (4). [18] The inkjet ink according to any one of [1] to [15], wherein the inkjet ink contains 22 parts by weight to 7 parts by weight of the above fine particles with respect to 100 parts by weight of the inkjet ink. The base substituted imine compound (A). [19] A polyimide-based film or a patterned polyimide film which is coated by the inkjet coating method as described above. It is obtained by adding a coating to the inkjet ink according to any one of the above-mentioned items to form a surface. And [2] a method for forming a polyimide film, comprising: forming a step by inkjet coating the inkjet ink according to the above-mentioned item, and the heat treatment of the dragon face (4) The parental amphoteric amine film 2^ thin secret plate' is formed into a polyimine film on the substrate as described above [2]. board. [22] An electronic component having the film base according to the above [21] [Effect of the Invention] Ink, that is, a better inkjet ink, which has a thicker film thickness by one shot "j" The polyimide film formed by the inkjet ink is resistant to the zero-yield film of the present invention, and has zero reliability and good yield. The chest 1 has high insulation, and is the above and other objects and features of the present invention. The following is a better example, and 'more _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

ΔΌΔI jpif.d0C 本發明提供一種含有經烯基取代之耐地醯亞胺化合物 (A)的噴墨墨水、使用該墨水的聚醯亞胺膜形成方法等。該噴墨墨水是含有至少一種經烯基取代之耐地醯亞胺化合物（A)的喷墨墨水、進而含有高分子化合物（B)的喷墨墨水、或者進而含有溶劑（C)的喷墨墨水。 1經烯基取代之耐地醯亞胺化合物（A)ΔΌΔI jpif.d0C The present invention provides an inkjet ink containing an alkenyl-substituted ruthenium imine compound (A), a method for forming a polyimide film using the ink, and the like. The inkjet ink is an inkjet ink containing at least one alkenyl-substituted ruthenium imine compound (A), an inkjet ink containing the polymer compound (B), or an inkjet further containing a solvent (C). ink. 1 alkenyl substituted imide imine compound (A)

本發明之喷墨墨水中所含的經烯基取代之耐地醯亞胺化合物（A)是分子内具有至少一種經烯基取代之耐地醯亞胺結構的化合物，較好的是可列舉下述式（1)所示之經少布基取代之耐地醯亞胺化合物，但並不限定於此。 [化 19]The alkenyl-substituted ruthenium imine compound (A) contained in the inkjet ink of the present invention is a compound having at least one alkenyl-substituted dysinimide structure in the molecule, preferably exemplified The quinone imine compound substituted with a small cloth group represented by the following formula (1) is not limited thereto. [Chem. 19]

⑴ 另外，式（1)中，r、r2分別獨立為氯〜12之烧基、礙數為3〜6之烯基、碳數為5〜8之ς=、礙數為6〜12之芳基或者节基中的任—種、η為丨〜了:整數。正為W2之減絲、•工:二之:t炭數 r,、s為分別獨立延擇的2〜6之整數、t為Q或者亚且II為1〜30之整數、X為氫或者絲）表 = 基烧基、以肌佩^ (其中，a麵G或者 18 200835754 &表示碳數為1〜4之亞燒基、R4表錢或者魏為1〜4 之烧基）表示之基團、ICHC6；^其中，τ為_现… -C(CH3)2_、·〇)_、_s_或者_s〇2_}表示之基團、或者此等基團的直接鍵結於芳香環的丨〜3個氫被羥基取代之基團。另外，n = 2時，R3是碳數為2〜2〇之亞烷基{亞烷基中互相不鄰接的任意亞甲基可被_〇•或者_CH==CH_取代，任意氫可被氟取代}、碳數為5〜8之亞環烷基、碳數為6 〜12之亞芳基、以-Wa-QaTR5·(其中，a為〇或者1之整數、R及R分別獨立為碳數為1〜4之亞烧基）表示之基團、以-C6H4-T-C6H4·、-C6H4_T_C6H4-T-C6H4_ 或者 -C6H4-T’-C6H4-T-C6H4_r_C6H4_{其中，T 是單鍵、碳數為 1 6 之亞烧基、_C(CH3)2-、、-CO·、·0-、或者 -S〇2_，Γ是-CHy或者-0-。}表示之基團、或者此等基團的直接鍵結於芳香環的1〜3個氫被羥基取代之基團、式（7) 所示之基團或者式（8)所示之基團，式（7)中，X獨立為1〜6之整數、y為1〜7〇之整數。 [化 20](1) In the formula (1), r and r2 are each independently a carbonyl group of 12 to 12, an alkenyl group having a hindrance of 3 to 6, an enthalpy having a carbon number of 5 to 8, and a hindrance of 6 to 12 Any one of the base or the base, η is 丨~: an integer. Is the wire reduction of W2, work: two: t carbon number r, s is an integer of 2~6 independently selected, t is Q or sub and II is an integer of 1~30, X is hydrogen or丝) Table = base-based, muscle-penetrating (where a-plane G or 18 200835754 & represents a carbon number of 1 to 4 of the alkylene group, R4 table money or Wei is 1 to 4 of the burning base) a group, ICHC6; ^ where τ is _ now... a group represented by -C(CH3)2_, ·〇)_, _s_ or _s〇2_}, or a direct bond of such groups to an aromatic ring The 丨~3 hydrogen group is replaced by a hydroxy group. Further, when n = 2, R3 is an alkylene group having a carbon number of 2 to 2 Å. Any methylene group which is not adjacent to each other in the alkylene group may be substituted by _〇• or _CH==CH_, and any hydrogen may be used. Substituted by fluorine}, a cycloalkylene group having a carbon number of 5 to 8, an arylene group having a carbon number of 6 to 12, and -Wa-QaTR5· (wherein a is an integer of 〇 or 1 and R and R are each independently a group represented by a sub-alkyl group having a carbon number of 1 to 4, wherein -C6H4-T-C6H4·, -C6H4_T_C6H4-T-C6H4_ or -C6H4-T'-C6H4-T-C6H4_r_C6H4_{where T is a single The bond, the carbon number of 1 6 is a pyridyl group, _C(CH3)2-, -CO·, ·0-, or -S〇2_, and Γ is -CHy or -0-. a group represented by }, or a group in which one or three hydrogens of the aromatic ring are directly substituted with a hydroxyl group, a group represented by the formula (7), or a group represented by the formula (8). In the formula (7), X is independently an integer of 1 to 6, and y is an integer of 1 to 7 Å. [Chem. 20]

19 200835754 4 JL Ujpif.doc 另外，n=3時，R3為下述式（5)或者（5，）所示之基團。 [化 21]19 200835754 4 JL Ujpif.doc Further, when n=3, R3 is a group represented by the following formula (5) or (5,). [Chem. 21]

式（5)中，R是氫、氟、氯、_〇H、-〇Cf3、_〇CF出、 -CF3、-CF2H、-CFH2、〇CF2cF2H、-〇CF2CFHCF3、或者碳數為1〜10之烧基’式（5 )、式（5’）中，r4、分別獨立，是單鍵、反·1，4-亞環己基、ι，3-二噁烧_2,5-二基、 1,4-亞笨基、氫可被氟取代的ι，4-亞苯基、或者碳數為1〜 10之亞烷基，亞烷基中互相不鄰接的任意亞甲基可被_〇_ 或者-CH=CH-取代，任意氫可被氟取代。另外’ n=4時’ R為下述式（6 )所示之基團。 [化 22] \ /In the formula (5), R is hydrogen, fluorine, chlorine, 〇H, -〇Cf3, _〇CF, -CF3, -CF2H, -CFH2, 〇CF2cF2H, -〇CF2CFHCF3, or a carbon number of 1 to 10 In the formula (5) and formula (5'), r4 is independently, and is a single bond, a trans-1,4-cyclohexylene group, an iota, a dioxalate-2,5-diyl group, a 1,4-phenylene group, an iota, a phenylene group in which hydrogen can be substituted by fluorine, or an alkylene group having a carbon number of 1 to 10, and any methylene group in the alkylene group which is not adjacent to each other can be _〇 _ or -CH=CH-substituted, any hydrogen may be substituted by fluorine. Further, when 'n = 4', R is a group represented by the following formula (6). [化22] \ /

式（6)中，化4、尺5、&6、117分別獨立，是單鍵、反-1，4-亞環己基、1，3-二噁烷_2,5-二基、1，4-亞苯基、氫可被氟取代的1,4-亞苯基、或者碳數為1〜1〇之亞烷基，亞烷基中互相不鄰接的任意亞曱基可被或者取代’任意氫可被氟取代。另外，n=3時，R3也可為下述式（5_1)、式（5’-1) 20In the formula (6), the formula 4, the ruler 5, the & 6, and 117 are each independently, and are a single bond, a trans-1,4-cyclohexylene group, a 1,3-dioxane-2,5-diyl group, and 1 a 4-phenylene group, a 1,4-phenylene group in which hydrogen can be substituted by fluorine, or an alkylene group having a carbon number of 1 to 1 Å, and any fluorenylene group in the alkylene group which is not adjacent to each other may be substituted or substituted 'Any hydrogen can be replaced by fluorine. Further, when n=3, R3 may be represented by the following formula (5_1) and formula (5'-1) 20

200835754^ jl ^piI.QOC 或者式（5’-2)所示之基團。 [化 23]200835754^ jl ^piI.QOC or a group represented by the formula (5'-2). [Chem. 23]

着The

式（5-1)中，R是碳數為1〜10之烷基或者-OH，式 (5’-2)中，R4、R5、R6分別獨立為1，2-亞乙基、1，4·亞丁基。另外，n = 4時，R3也可為下述式（6-1)所示之基團。 [化 24]In the formula (5-1), R is an alkyl group having a carbon number of 1 to 10 or -OH, and in the formula (5'-2), R4, R5 and R6 are each independently 1,2-ethylene, 1, 4. Butylene. Further, when n = 4, R3 may be a group represented by the following formula (6-1). [Chem. 24]

經烯基取代之耐地醯亞胺化合物（A)有：η為1的經 21 200835754 a ^ jjif.d〇c 烯基取代之耐地醯亞胺化合物（al :以下僅稱為「經烯基取代之耐地醯亞胺」）、及η為2的經烯基取代之耐地醯亞胺化合物（a2:以下僅稱為「經雙烯基取代之耐地醯亞胺」）、及η為3的經烯基取代之耐地醯亞胺化合物（a3 : 以下僅稱為「經三烯基取代之耐地醯亞胺」）、及η為4的經烯基取代之耐地醯亞胺化合物（a4:以下僅稱為「經四烯基取代之耐地醯亞胺」）。The alkenyl substituted imide imine compound (A) is a ruthenium imine compound substituted by 21 200835754 a ^ jjif.d〇c alkenyl with η of 1 (al: hereinafter only referred to as "olefinic a base-substituted quinone imine "), and an alkenyl-substituted ruthenium imine compound having a η of 2 (a2: hereinafter simply referred to as "diallyl-substituted dysinimide"), and An alkenyl-substituted quinone-imine compound having η of 3 (a3 : hereinafter referred to simply as "trienyl-substituted dysinimide"), and an alkenyl-substituted resistance to η of 4 Imine compound (a4: hereinafter referred to simply as "tetradecyl-substituted dysinimide").

本發明之喷墨墨水可含有選自！！為1的經烯基取代之耐地醯亞胺化合物（A)、n為2的經烯基取代之耐地醯亞胺化合物（Α)、η為3的經烯基取代之耐地醯亞胺化合物 (Α)、及η為4的經浠基取代之耐地醢亞胺化合物（Α) 的至少2種經細基取代之耐地酸亞胺化合物（a)。、另外，上述經烯基取代之耐地醯亞胺化合物（Α)可 $使單胺、二胺、三胺或者四胺與下述式（1，）所示之經稀基取代之耐地酸酐反應而成的經烯絲代之雜醯亞胺化合物。The inkjet ink of the present invention may contain a selected one! ! An alkenyl-substituted quinone-imine compound (A) substituted with 1, an alkenyl-substituted quinone-substituted imine compound (n) having n of 2, and an alkenyl-substituted thiophene substituted with η of 3 The amine compound (Α) and the ruthenium-substituted ruthenium-imide compound (η) having at least two kinds of finely substituted lysine compound (a). Further, the above-mentioned alkenyl-substituted ruthenium imine compound (Α) may be substituted with a monoamine, a diamine, a triamine or a tetraamine and a diluted base represented by the following formula (1). An olefin-substituted heteroquinone imine compound obtained by reacting an acid anhydride.

[化 25][Chem. 25]

、（1.) 浐某式二丨及11分別獨立為氫、碳數為1〜12之 3 之稀基、錢為5〜8之環絲、· 為6〜12之方基或者苄基中的任—種另外，本發明之喷墨墨水可含有分別獨立 22 200835754(1.) 浐A type of diterpene and 11 are independently hydrogen, a dilute group having a carbon number of 1 to 12, a ring of 5 to 8 money, a 6 to 12 square group or a benzyl group. In addition, the inkjet ink of the present invention may contain separate 22 200835754

i ^jJiI.UOC 為氫或者碳數為1〜6之烷基，R3是碳數為1〜12之烷基 (n=l)、碳數為 6〜12 之芳基（n=l)、_(CH2)p- (n = 2、 p為6〜12之整數）、式（2-1)所示之基團、式（3)所示之基團、式（4-1)所示之基團、式（7-1)所示之基團、式（8)所示之基團、式（5-2)所示之基團、式（5-3)所示之基團、式（5’-1)所示之基團、式（5^3)所示之基團、式（6-1)所示之基團的經烯基取代之耐地醯亞胺化合物 (A)之至少2種。 [化 26]i ^jJiI.UOC is hydrogen or an alkyl group having a carbon number of 1 to 6, and R 3 is an alkyl group having 1 to 12 carbon atoms (n = 1) and an aryl group having 6 to 12 carbon atoms (n = 1). _(CH2)p- (n = 2, p is an integer of 6 to 12), a group represented by the formula (2-1), a group represented by the formula (3), and a formula (4-1) a group, a group represented by the formula (7-1), a group represented by the formula (8), a group represented by the formula (5-2), a group represented by the formula (5-3), Alkenyl-substituted ruthenium imine compound (A group represented by formula (5'-1), a group represented by formula (5^3), or a group represented by formula (6-1) (A) At least two of them. [Chem. 26]

(4-1) n=2(4-1) n=2

23 200835754 Δ.\}Ζ. 1 ^/pif.doc23 200835754 Δ.\}Ζ. 1 ^/pif.doc

L1經烯基取代之耐地醯亞胺（al) 本發明中可用的η為1的經烯基取代之耐地醯亞胺化合物之具體例，例如可列舉以下者。可列舉：烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、曱基烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 24 if.doc 200835754 N-羥基-烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-羥基·烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N·羥基曱基烯丙基雙環[2.2.1]庚_5_烯_2,3_二羧基醯亞胺、 N-羥基-曱基烯丙基曱基雙環P.2.1]庚-5-烯-2,3-二羧基醯亞胺、 1 N-曱基-烯丙基雙環P.2.1]庚-5-烯-2,3-二羧基醯亞胺、 * N-曱基-烯丙基甲基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺、 N-甲基·甲基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-曱基-曱基烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-(2-乙基己基)-烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醢亞胺、 • 及此等的寡聚物等。另外，可列舉： N-(2-乙基己基)-烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-烯丙基·烯丙基雙環[2.2.1]庚-5·烯-2,3-二羧基醯亞胺、 N-烯丙基-烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 25 200835754 w jjif.doc N-烯丙基-曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基蕴亞胺、 N-異丙烯基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-異丙烯基-烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-異丙烯基-曱基烯丙基雙環[2.2.1]庚-5-烯·2,3-二羧基醯亞胺、 ® Ν-環己基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 Ν-環己基烯丙基曱基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺、 Ν-環己基_曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 Ν-苯基-烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、及此等的寡聚物等。 • 另外，可列舉： Ν-苯基-烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 Ν-苄基-烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 Ν-苄基烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 Ν-苄基-曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 26 200835754 ζ,υζ ijpif.doc N-(2f-羥基乙基)-烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-(2f-羥基乙基)_烯丙基曱基雙環Ρ.2.1]庚_5·烯-2,3·二羧基醯亞胺、 Ν-(2’-羥基乙基;h甲基烯丙基雙環卩.2.1]庚-5-烯-2,3-二羧基醯亞胺、及此等的寡聚物等。另外，可列舉： N-(2f，2’-二曱基羥基丙基)-烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-(2’，2’-二曱基_3’_羥基丙基)-烯丙基曱基雙環[2.2.1] 庚-5-細-2,3-二竣基酿亞胺、 N-(2’，3’-二羥基丙基)-烯丙基雙環P.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-(2’，3’-二羥基丙基)-烯丙基甲基雙環[2.2.1]庚-5-烯 -2,3-二羧基醯亞胺、 N_(3’羥基_Γ_丙烯基)-烯丙基雙環[2.2.1]庚-5-烯·2,3-二羧基醯亞胺、 Ν-(4’-羥基·環己基)-烯丙基曱基雙環[2.2.1]庚-5-烯 -2,3-二羧基醯亞胺、及此等的寡聚物等。另外，可列舉： Ν_(4’·羥基苯基)-烯丙基雙環[2.2.1]庚-5·烯-2,3·二羧基醯亞胺、 27 200835754 丄 ^ρχΙ·(ΙΟΟ 基乙氧基)乙乳基}乙基]-細丙基曱基雙環P.2.1]庚_5_烯·2,3-二羧基醯亞胺、 Ν-ΡΜ2Η2”-羥基乙氧基）乙氧基}乙基]-甲基烯丙基雙環[2.2.1]庚-5-烯_2,3_二羧基醯亞胺、 Ν-{4’-(4-羥基苯基異亞丙基)苯基}-烯丙基雙環[2.2.1] 庚_5_細-2,3-二叛基酿亞胺、 N_{4’-(4’-羥基苯基異亞丙基)苯基}-烯丙基曱基雙環 [2.2.1] 庚-5-細-2,3-二竣基酿亞胺、 $ N- {4’_(4’-控基苯基異亞丙基）苯基}-曱基炸丙基雙J哀 [2.2.1] 庚-5-却·2,3-二竣基酿亞胺、及此等的寡聚物等。另外，此等經烯基取代之耐地醯亞胺（al)可單獨使用，也可使用此等的混合物。上述經烯基取代之耐地醯亞胺（al)較好的是可列舉： N-甲基-烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺、 N-曱基-烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯 # 亞胺、 N-甲基-曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-曱基-曱基烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-(2-乙基己基)-烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺等。另外，可列舉： 29 200835754L1 Alkenyl Substituted Resinimide (al) Specific examples of the alkenyl-substituted dysinimide compound having η of 1 which can be used in the present invention include, for example, the following. There may be mentioned allyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine, allyl fluorenyl bicyclo [2.2.1] hept-5-ene-2,3-di Carboxylimine, decylallylbiscyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolide, decylallylhydrylbicyclo[2.2.1]hept-5-ene -2,3-dicarboxy quinone imine, 24 if.doc 200835754 N-hydroxy-allyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine, N-hydroxy olefin Propyl fluorenylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, N. hydroxy decylallyl bicyclo [2.2.1] hept-5-ene-2,3_ Dicarboxy quinone imine, N-hydroxy-mercaptopropyl propyl bicyclic P.2.1] hept-5-ene-2,3-dicarboxy quinone imine, 1 N-mercapto-allyl bicyclic P. 2.1]hept-5-ene-2,3-dicarboxy quinone imine, * N-mercapto-allylmethylbicyclo[2·2·1]hept-5-ene-2,3-dicarboxyfluorene Imine, N-methyl·methallylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine, N-fluorenyl-mercaptopropylidenebicyclo[2.2 .1]hept-5-ene-2,3-dicarboxyindenine, N-(2-ethylhexyl)-allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyl醢imine, • and such oligomers. Further, N-(2-ethylhexyl)-allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarminemine, N-allyl·allyl Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine, N-allyl-allylmethylbicyclo[2.2.1]hept-5-ene-2,3- Dicarboxy quinone imine, 25 200835754 w jjif.doc N-allyl-mercaptopropyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxyimide, N-isopropenyl Allyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine, N-isopropenyl-allyl fluorenylbicyclo[2.2.1]hept-5-ene-2, 3-Dicarboxy quinone imine, N-isopropenyl-mercaptopropyl bicyclo [2.2.1] hept-5-ene · 2,3-dicarboxy quinone imine, ® Ν-cyclohexylallyl bicyclo [2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, Ν-cyclohexylallylhydrylbicyclo[2·2·1]hept-5-ene-2,3-dicarboxyl Yttrium imine, Ν-cyclohexyl-mercaptopropyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine, Ν-phenyl-allyl bicyclo [2.2.1] Hg-5-ene-2,3-dicarboxy quinone imine, and oligomers thereof. • In addition, Ν-phenyl-allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, Ν-benzyl-allyl bicyclo[2.2. 1]hept-5-ene-2,3-dicarboxy quinone imine, Ν-benzyl allyl fluorenylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, hydrazine -benzyl-mercaptopropylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenine, 26 200835754 ζ, υζ ijpif.doc N-(2f-hydroxyethyl)-ene Propylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine, N-(2f-hydroxyethyl)-allylhydrazylbicycloindole.2.1]hept-5-ene 2,3·dicarboxy quinone imine, Ν-(2'-hydroxyethyl; h methallyl bicyclopurine .2.1] hept-5-ene-2,3-dicarboxy quinone imine, and the like Oligomers, etc. Further, N-(2f,2'-dimercaptohydroxypropyl)-allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyfluorene is exemplified. Amine, N-(2',2'-dimercapto-3'-hydroxypropyl)-allylhydrazylbicyclo[2.2.1]hept-5- fine-2,3-diindolyl , N-(2',3'-dihydroxypropyl)-allylbicyclic P.2.1]hept-5-ene-2,3-dicarboxy quinone imine, N-(2',3'-di Hydroxypropyl)-allylmethyl bicyclic [2.2.1]hept-5-ene-2,3-dicarboxyindolimine, N_(3'hydroxy-indole-propenyl)-allylbicyclo[2.2.1]hept-5-ene·2, 3-dicarboxy quinone imine, Ν-(4'-hydroxycyclohexyl)-allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, and the like Oligomers, etc. Further, Ν_(4'.hydroxyphenyl)-allylbicyclo[2.2.1]hept-5-ene-2,3.dicarboxyindolimine, 27 200835754 丄^ ρχΙ·(Mercaptoethoxy)ethylidene}ethyl]-fine propyl fluorenyl bicyclophene P.2.1]hept-5-ene·2,3-dicarboxy quinone imine, Ν-ΡΜ2Η2”-hydroxy group B Oxy)ethoxy}ethyl]-methylallylbicyclo[2.2.1]hept-5-ene_2,3-dicarboxyarmine, Ν-{4'-(4-hydroxyphenyl Isopropylidene)phenyl}-allylbicyclo[2.2.1]g _5_fine-2,3-di-rebasic imine, N_{4'-(4'-hydroxyphenyl isopropylene Phenyl}-allylhydrazinobicyclo[2.2.1]hept-5-fine-2,3-diindenyl iodide, $N- {4'_(4'-controlled phenyl phenyl Propylene) phenyl}-fluorenyl propyl propyl sulphate [2.2.1] gh-5-but · 2,3-diindenyl ruthenium, and oligomers thereof, etc. Alkenyl substitution The ruthenium imide (al) can be used alone or in combination. The above alkenyl-substituted quinone imine (al) is preferably exemplified by: N-methyl-allyl bicyclo[2·2·1]hept-5-ene-2,3-dicarboxyfluorene Imine, N-fluorenyl-allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindole#imine, N-methyl-nonylallylbicyclo[2.2. 1]hept-5-ene-2,3-dicarboxy quinone imine, N-mercapto-mercaptopropyl hydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxy fluorene Amine, N-(2-ethylhexyl)-allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarminemine, and the like. In addition, can be cited: 29 200835754

1 ^pil.dOC Ν·(2-乙基己基)·烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-坤丙基-炸丙基雙架[2·2·1]庚-5-細-2,3-二竣基酿亞胺、 N-烯丙基-烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-烯丙基-甲基烯丙基雙環P.2.1]庚-5-烯-2,3-二羧基醯亞胺、 ^ N-異丙烯基-烯丙基雙環[2·2·1]庚-5-烯-2,3·二羧基醯亞胺、 Ν-異丙烯基-烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 Ν-異丙烯基-曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 Ν-環己基-烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 _ Ν-環己基-烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 Ν-環己基-曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 Ν-苯基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺等。另外，可列舉： Ν·苯基-烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯 30 200835754,1 ^ pil.dOC Ν·(2-ethylhexyl)·allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, N-kun propyl-fried Base double frame [2·2·1]hept-5-fine-2,3-diindolyl,imide,N-allyl-allylhydrazylbicyclo[2.2.1]hept-5-ene- 2,3-Dicarboxy quinone imine, N-allyl-methylallyl bicyclol P.2.1]hept-5-ene-2,3-dicarboxy quinone imine, ^ N-isopropenyl-ene Propylbicyclo[2·2·1]hept-5-ene-2,3·dicarboxy quinone imine, Ν-isopropenyl-allylmethylbicyclo[2.2.1]hept-5-ene-2 , 3-dicarboxy quinone imine, Ν-isopropenyl-mercaptopropyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine, Ν-cyclohexyl-allyl Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine, _ Ν-cyclohexyl-allylmethylbicyclo[2.2.1]hept-5-ene-2,3-di Carboxylimine, fluorenyl-cyclohexyl-mercaptopropylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenine, fluorenyl-phenylallylbicyclo[2.2.1] Hg-5-ene-2,3-dicarboxynonimine and the like. Further, Ν·phenyl-allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyfluorene 30 200835754,

-L ^piI*QOC 亞胺、 N-苄基-烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N·苄基-烯丙基曱基雙環[2.2.1]庚-5-烯_2,3_二羧基醯亞胺、 N-苄基-曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺等。經烯基取代之耐地醯亞胺（al)更好的是可列舉： N-曱基-烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-甲基·細丙基曱基雙壤[2.2.1]庚-5-細-2,3-二竣基酿亞胺、 N-甲基·曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-曱基-曱基烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 Ν_(2·乙基己~基)_烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺等。 • 另外，可列舉： Ν·(2-乙基己基)-烯丙基曱基雙環[2.2.1]庚-5_烯-2,3-二羧基醯亞胺、 Ν-烯丙基-烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 Ν-烯丙基烯丙基曱基雙環[2.2.1]庚-5-烯_2,3-二羧基酸亞胺、 Ν-烯丙基-曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基 31 200835754 ζ,υζ, i ^pif.doC 醯亞胺、 Ν·異丙烯基-烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-異丙烯基_烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺、 N-異丙烯基-曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺等。 1.2經雙烯基取代之耐地醯亞胺（a2) ® 另外，本發明中可用的η為2的經烯基取代之耐地醯亞胺化合物之具體例，例如可列舉以下者。可列舉：Ν，Ν’-亞乙基-雙（烯丙基雙環[2·2·1]庚-5-烯 -2,3-二羧基醯亞胺）、 Ν,Ν’-亞乙基-雙(烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）、 Ν，Ν’-亞乙基雙（甲基烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺）、 • 亞丙基-雙(烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）、 N，N’-亞己基雙(烯丙基雙環[2·2·1]庚-5-烯-2,3·二羧基醯亞胺）、 Ν，Ν’-亞己基-雙(烯丙基曱基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺）、 Ν，Ν’-亞十二烷基·雙(烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺）、 32 200835754^ ± ^pii.doc N，N’-亞十二烷基·雙（烯丙基曱基雙環[2·2·1]庚-5-烯 -2,3-二竣基酿亞胺）、 N，Nf亞環己基-雙(烯丙基雙環[2·2·1]庚-5·烯_2,3_二羧基醯亞胺）、 Ν，Ν’-亞環己基-雙(烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）、及此等的寡聚物等。另外，可列舉： * 1，2·雙{3f-(烯丙基雙環[2.2.1]庚-5·烯-2,3_二羧基醯亞胺）丙氧基}乙烷、 1,2-雙{3H烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醢亞胺）丙氧基}乙烧、 1，2·雙{3’-(曱基烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺）丙氧基}乙烧、雙[2’-{3’-(烯丙基雙環Ρ.2.1]庚-5-烯-2,3·二羧基醯亞胺）丙乳基}乙基]鱗、 • 雙[2’-{3’-(烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）丙氧基}乙基]醚、 Μ-雙{3’-(烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺）丙氧基} 丁烷、 M-雙{3’-(烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）丙氧基} 丁烷、及此等的寡聚物等。另外，可列舉： 33 200835754 Ν,Ν’-對亞苯基-雙(烯丙基雙環[2·2·1]庚·5_烯-2,3-二羧基醯亞胺)、 N，N’-對亞苯基-雙(烯丙基甲基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺）、 N，N’-間亞苯基-雙(烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）、 N，N’-間亞苯基-雙(烯丙基曱基雙環[2.2.1]庚_5-烯-2,3-二羧基醯亞胺）、 N,N’-{(1-曱基)-2,4-亞苯基}-雙（烯丙基雙環[2.2.1]庚 -5-卸-2,3-二竣基酿亞胺）、 N，Nf-對苯二曱基-雙(烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）、 N，N’-對苯二曱基-雙（烯丙基曱基雙環[2.2.1]庚-5-烯 -2,3-二叛基酿亞胺）、 N，N’-間苯二曱基·雙(烯丙基雙環[2·2·1]庚-5·烯-2,3-二羧基醯亞胺）、 Ν，Ν’-間苯二曱基-雙(烯丙基甲基雙環[2.2.1]庚-5-烯 -2,3-二叛基酿亞胺）、及此等的寡聚物等。另外，可列舉： 2.2- 雙[4’-{4’_(烯丙基雙環Ρ.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯氧基}苯基]丙烷、 2.2- 雙[4’-{4’_(烯丙基甲基雙環[2.2.1]庚_5_烯-2,3-二羧基醯亞胺)苯氧基}苯基]丙烷、 34 200835754-L ^piI*QOC imine, N-benzyl-allyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine, N · benzyl-allyl fluorenyl bicyclo [2.2.1]hept-5-ene-2,3-dicarboxyarsenine, N-benzyl-mercaptopropylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyfluorene Imine and the like. More preferably, the alkenyl-substituted quinone imine (al) is exemplified by: N-mercapto-allyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine, N-methyl·fine propyl sulfhydryl double soil [2.2.1] hept-5- fine-2,3-diindenyl iodide, N-methyl·mercaptopropyl bicyclo [2.2.1] Hg-5-ene-2,3-dicarboxy quinone imine, N-mercapto-mercaptoallylmethyl bicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, Ν_(2·Ethylhexyl-yl)-allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarminemine. • In addition, Ν·(2-ethylhexyl)-allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, Ν-allyl-ene Propylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, Ν-allyl allyl fluorenylbicyclo[2.2.1]hept-5-ene_2,3- Dicarboxylic acid imine, Ν-allyl-mercaptopropyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxyl 31 200835754 ζ, υζ, i ^pif.doC 醯imine, Ν·Isopropenyl-allyl bicyclo [2.2.1]hept-5-ene-2,3-dicarboxy quinone imine, N-isopropenyl-allyl fluorenylbicyclo[2.2.1]g- 5-ene-2,3-dicarboxy quinone imine, N-isopropenyl-mercaptopropyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine, and the like. 1.2 Dienyl substituted imide imine (a2) ® Further, specific examples of the alkenyl-substituted quinone-substituted imine compound having η of 2 which can be used in the present invention include the following. For example, Ν, Ν '-ethylene-bis(allylbicyclo[2·2·1]hept-5-ene-2,3-dicarboxy quinone imine), ruthenium, Ν'-ethylene - bis (allylmethyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine), hydrazine, Ν '-ethylene bis (methylallyl bicyclo [2· 2·1]hept-5-ene-2,3-dicarboxyindenine), • propylene-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyfluorene Imine), N,N'-hexylene bis(allylbicyclo[2·2·1]hept-5-ene-2,3·dicarboxyindolide), hydrazine, Ν'-hexylene-double (Allyl fluorenylbicyclo[2·2·1]hept-5-ene-2,3-dicarboxy quinone imine), hydrazine, Ν'-dodecylene bis(allyl bicyclo[2 ·2·1]hept-5-ene-2,3-dicarboxy quinone imine), 32 200835754^ ± ^pii.doc N,N'-dododecyl·bis(allylhydrazinobicyclo[ 2·2·1]hept-5-ene-2,3-diindenyl imino), N,Nf cyclohexylene-bis(allylbicyclo[2·2·1]hept-5·ene_ 2,3_dicarboxy quinone imine), hydrazine, Ν'-cyclohexylene-bis(allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinazoline), And such oligomers and the like. Further, it is exemplified by: * 1,2·bis{3f-(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarmine)propoxy}ethane, 1,2 - bis{3H allyl fluorenylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine)propoxy} ethene, 1,2·double {3'-(fluorenyl) Allyl bicyclo [2·2·1]hept-5-ene-2,3-dicarboxy quinone imine) propoxy} ethene, bis[2'-{3'-(allylbicycloindole. 2.1]hept-5-ene-2,3.dicarboxyarsenazo)propyl acrylate}ethyl]scale, • bis[2'-{3'-(allylmethylbicyclo[2.2.1]g -5-ene-2,3-dicarboxyindolimine)propoxy}ethyl]ether, Μ-bis{3'-(allylbicyclo[2·2·1]hept-5-ene-2 , 3-dicarboxy quinone imine) propoxy}butane, M-double {3'-(allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine ) propoxy}butane, and oligomers thereof and the like. In addition, it can be exemplified: 33 200835754 Ν, Ν '-p-phenylene-bis(allylbicyclo[2·2·1]hept-5-ene-2,3-dicarboxy quinone imine), N, N '-p-phenylene-bis(allylmethylbicyclo[2·2·1]hept-5-ene-2,3-dicarboxyindolide), N,N'-m-phenylene-double (allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenine), N,N'-m-phenylene-bis(allylhydrazinobicyclo[2.2.1] Hg-5-ene-2,3-dicarboxyindolimine), N,N'-{(1-indolyl)-2,4-phenylene}-bis(allylbicyclo[2.2.1] G--5-Unloaded-2,3-diindenyl imino), N,Nf-p-phenylenediyl-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-di Carboxylimine), N,N'-p-phenylenediyl-bis(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-di-rebasic imine), N, N'-m-phenylenedifluoryl bis(allylbicyclo[2·2·1]hept-5-ene-2,3-dicarboxy quinone imine), hydrazine, Ν'-m-benzodiazepine- Bis(allylmethylbicyclo[2.2.1]hept-5-ene-2,3-di-rebasic imine), and oligomers thereof. Further, 2.2-bis[4'-{4'-(allylbicyclopurine.2.1]hept-5-ene-2,3-dicarboxyarminemine)phenoxy}phenyl]propane, 2.2-bis[4'-{4'_(allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)phenoxy}phenyl]propane, 34 200835754

二V/A JL JJJli.dOC 2,2-雙[4444曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯氧基}苯基]丙烷、雙{4-(烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺)苯基}曱烷、雙{4-(烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}曱烷、及此等的寡聚物等。另外，可列舉： ® 雙{4-(曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}甲烷、雙{4-(曱基烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}曱烷、雙{4-(烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}鍵、雙{4-(烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}醚、 • 雙{4-(曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}醚、雙{4-(烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}石風、雙{4-(烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}砜、及此等的寡聚物等。另外，可列舉： 35 200835754 ΔΌΑΙ jpif.doc 雙{4-(甲基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}砜、 1，6_雙（烯丙基雙環[2·2· 1]庚-5-烯_2,3-二羧基醯亞胺)-3-經基-己炫、 1，12·雙（曱基烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺)-3,6-二起基-十二烧、 1，3_雙（烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)-5-輕基-¾己烧、 ® 1，5-雙{3’-(烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）丙乳基經基-戊烧、 1，4_雙（烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺)-2-無基-苯、及此等的寡聚物等。另外，可列舉： — 雙(烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)-2,5-二經基苯、 • Ν,Ν’-對(2-羥基)苯二甲基-雙(烯丙基雙環[2.2.1]庚-5- 烯-2,3-二羧基醯亞胺)、 Ν，Ν’-對(2-羥基）苯二甲基-雙(烯丙基曱基環[2·2·1]庚 5-細-2,3-二竣基龜亞胺）、 N，Nf_間(2-羥基）苯二甲基-雙(烯丙基雙環[2·2·1]庚·5· 烯-2,3-二羧基醯亞胺）、 Ν，Ν’-間(2-羥基)苯二曱基-雙（甲基烯丙基雙環[2·2·1] 庚-5_烯_2,3-二羧基醯亞胺）、 36 200835754Two V/A JL JJJli.dOC 2,2-bis[4444] allyl allybicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine)phenoxy}phenyl]propane , double {4-(allylbicyclo[2·2·1]hept-5-ene-2,3-dicarboxyindolide)phenyl}decane, double {4-(allylhydrazinobicyclo) [2.2.1] Hept-5-ene-2,3-dicarboxy quinazoline)phenyl}decane, and oligomers thereof. In addition, it can be exemplified: ® double {4-(mercaptopropyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine) phenyl} methane, double {4-(fluorenyl) Allyl fluorenylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine)phenyl}decane, bis{4-(allylbicyclo[2.2.1]hept-5 -ene-2,3-dicarboxy quinone imine)phenyl} bond, bis{4-(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine) Phenyl}ether, • bis{4-(mercaptopropylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenimido)phenyl}ether, double {4-(allyl Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)phenyl}stone, double {4-(allylhydrazinobicyclo[2.2.1]hept-5-ene -2,3-dicarboxy quinone imine) phenyl sulfone, and oligomers thereof. In addition, it can be exemplified: 35 200835754 ΔΌΑΙ jpif.doc Double {4-(methylallyl bicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenine)phenyl}sulfone, 1, 6_bis(allylbicyclo[2·2·1]hept-5-ene-2,3-dicarboxyindolimide)-3-carbyl-hexyl, 1,12·bis(decylallyl Bicyclo[2·2·1]hept-5-ene-2,3-dicarboxyindolimine)-3,6-dioctyl-dodecyl, 1,3_bis(allylbicyclo[2.2 .1]hept-5-ene-2,3-dicarboxy quinoid imine)-5-light-based hexane, ® 1,5-bis{3'-(allylbicyclo[2.2.1]g -5-ene-2,3-dicarboxy quinone imine) propyl lactyl perylene-pentane, 1,4 bis (allyl bicyclo[2·2·1]hept-5-ene-2,3 -Dicarboxyimine)-2-nonyl-benzene, and oligomers thereof. In addition, exemplified by: — bis(allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenine)-2,5-di-based benzene, • Ν, Ν' -p-(2-hydroxy)benzenedimethyl-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolide), hydrazine, Ν'-pair (2-hydroxyl) Benzyl-bis(allyl-decyl ring [2·2·1]hept-5-fine-2,3-diindolino), N,Nf_m-(2-hydroxy)benzene Methyl-bis(allylbicyclo[2·2·1]hept-5·ene-2,3-dicarboxyindolide), fluorene, Ν'-m-(2-hydroxy)benzodiazepine-double (Methylallylbicyclo[2·2·1]hept-5-ene-2,3-dicarboxyindenine), 36 200835754

1 ^pif.d〇C N，N’·對(2,3_二羥基)苯二曱基-雙(烯丙基雙環[2·2.1]庚 -5-烯-2,3-二羧基醯亞胺）、及此等的寡聚物等。另外，可列舉： 2,2-雙[4’·{4’_(烯丙基雙環[2.2.1]庚·5·烯-2,3·二羧基醯亞胺)-2’-海基-苯乳基}苯基]丙烧、雙{4-(烯丙基曱基雙環[2·2.1]庚-5-烯-2,3-二羧基醯亞胺基-苯基}曱烧、雙{3-(烯丙基雙環[2.2.1]庚-5-烯-2,3_二羧基醯亞胺)-4-經基-苯基}鍵、雙{3_(甲基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)-5-經基-苯基}礙、 1，1，1-三{4’-(烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)}苯氧基曱基丙烷、 Ν,Ν’,Ν”-三（亞乙基曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)異氰尿酸酯、及此等的寡聚物等。進而，可為含有不對稱亞烷基·亞苯基的如下化合物。 37 200835754 ζ,υζ, ι jpif.doc [化 27]1 ^pif.d〇CN, N'·p-(2,3-dihydroxy)benzodiazepine-bis(allylbicyclo[2·2.1]hept-5-ene-2,3-dicarboxyfluorene Amine), and such oligomers and the like. In addition, 2,2-bis[4'·{4'_(allylbicyclo[2.2.1]hepta-5-ene-2,3·dicarboxyindolide)-2'-sea base -Benzyl aryl}phenyl]propane, bis{4-(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenido-phenyl} oxime, Double {3-(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)-4-trans-phenyl} bond, double {3_(methallyl) Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)-5-trans-phenyl-phenyl}, 1,1,1-tris{4'-(allylmethyl Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimide)}phenoxymercaptopropane, hydrazine, Ν', Ν"-tris(ethylene decylallylbicyclo[ 2.2.1] hept-5-ene-2,3-dicarboxy quinone imine) isocyanurate, and oligomers thereof, etc. Further, may contain an asymmetric alkylene phenylene group. The following compounds are available. 37 200835754 ζ,υζ, ι jpif.doc [化27]

另外，此等經雙烯基取代之财地醯亞胺（a2)可單獨使用，也可使用此等的混合物。上述經雙烯基取代之耐地蕴亞胺（a2)較好的是可列舉： N，N’-亞乙基雙(烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺）、 N，Nf-亞乙基·雙(烯丙基甲基雙環[2.2.1]庚-5-烯·2,3-二叛基醢亞胺）、 Ν，Ν’-亞乙基-雙（曱基烯丙基雙環[2.2.1]庚-5-烯-2,3·二 38Further, these dienyl substituted methanides (a2) may be used singly or as such a mixture. The above dienyl substituted substituted iminemine (a2) is preferably exemplified by: N,N'-ethylenebis(allylbicyclo[2·2·1]hept-5-ene-2 , 3-dicarboxy quinone imine), N, Nf-ethylidene bis (allylmethylbicyclo[2.2.1]hept-5-ene·2,3-di-redecyl imine), Ν ,Ν'-Ethylene-bis(mercaptopropylbicyclo[2.2.1]hept-5-ene-2,3·238

200835754 ΔΌΔ UpiLdOO 羧基醯亞胺）、 N，N’-亞丙基雙(烯丙基雙環[2.2.1]庚-5-烯·2,3-二羧基酸亞胺）、 Ν，Ν’-亞己基雙(烯丙基雙環[2·2·1]庚-5·烯_2,3·二羧基醯亞胺）、 Ν,Ν’-亞己基雙(烯丙基曱基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺)、 Ν，Ν’-亞十二烷基-雙(烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺）、 Ν，Ν’-亞十二烷基·雙（烯丙基甲基雙環[2·2·1]庚-5-烯 -2,3-二竣基酿亞胺）、 N，Nf-亞環己基-雙(烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺）、 Ν，Ν’-亞環己基雙(烯丙基甲基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺)等。另外，可列舉： N,Nf-對亞苯基-雙(烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺）、 Ν,ΝΤ-對亞苯基-雙(烯丙基曱基雙環[2.2.1]庚_5_烯-2,3-二羧基醯亞胺）、 Ν，Ν’-間亞苯基-雙(烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）、 Ν，Ν’-間亞苯基-雙(烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）、 39 200835754, 丄 ^|/χΣ·0·00 Ν，Ν’·{(1-曱基)·2,4·亞苯基卜雙（烯丙基雙環[2.2.1]庚 -5-歸-2,3-二竣基酿亞胺）、 Ν，Ν’·對苯二曱基-雙(烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）、 Ν，Ν’-對苯二曱基-雙（烯丙基曱基雙環[2.2.1]庚-5-烯 -2,3-二羧基醯亞胺)、 N，Nf-間苯二曱基-雙(烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)、 ® Ν，Ν’-間苯二甲基-雙（烯丙基甲基雙環[2.2.1]庚-5-烯 -2,3-二竣基酿亞胺）、 2.2- 雙[4’·{4Η烯丙基雙環[2.2.1]庚-5-烯-2,3·二羧基醯亞胺)苯氧基}苯基]丙烷、 2,2_雙[心{4’_(烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯氧基}苯基]丙烷、 2.2- 雙[4’-{4’_(曱基烯丙基雙環[2.2.1]庚-5-烯-2,3_二羧基醯亞胺)苯氧基}苯基]丙烷、 _ 雙{4-(烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}曱烷、雙{4-(烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}曱烷等。另外，可列舉：雙{4-(曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}曱烷、雙{4-(曱基烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基 200835754 醯亞胺)苯基}甲烷、雙{4-(烯丙基雙環ρ·2·1]庚-5-烯-2,3-二羧基醯亞胺)苯基}鍵、雙{4-(烯丙基甲基雙環ρ·2·1]庚-5-烯-2,3-二羧基醯亞胺)苯基}醚、雙{4-(曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}醚、雙{4-(烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}石風、雙{4-(烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}颯等。另外，可列舉：雙{4-(曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}礙等。經雙烯基取代之耐地醯亞胺（a2)更好的是可列舉： N，Nf-亞乙基·雙(烯丙基雙環[2·2·1]庚-5-烯-2,3_二羧基醯亞胺）、 N，Nf-亞乙基-雙(烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)、 N，Nf-亞乙基·雙（曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）、 Ν，Ν’-亞丙基雙(烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺）、 Ν，Ν’-亞己基-雙(烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧基 41 200835754 ijpii.doc 酸亞胺）、 Ν,Ν’-亞己基-雙(烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）、 Ν，Ν’-亞十二烷基·雙(烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）、 Ν,Ν’-亞十二烷基-雙（烯丙基曱基雙環[2·2·1]庚-5-烯 -2,3-二羧基醯亞胺）、 Ν，Ν’·亞環己基-雙(烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧 0基醯亞胺）、 Ν，Ν’-亞環己基雙(烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）等。另外，可列舉： Ν，Ν’-對亞苯基-雙(烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）、 Ν，Ν’-對亞苯基-雙(烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)、 • Ν，Ν’-間亞苯基雙(烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺）、 N，Nf-間亞苯基-雙(烯丙基甲基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺）、 N，N’-{(1-曱基)-2,4-亞苯基卜雙（烯丙基雙環[2·2·1]庚 -5-烯-2,3-二羧基醯亞胺）、 Ν，Ν’-對苯二曱基-雙(烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)、 42 200835754 zozi^pit.doc ]^，1^’-對苯二甲基-雙（烯丙基甲基雙環[2·2·1]庚-5-烯 -2,3-二羧基醯亞胺）、 Ν，Ν’-間苯二甲基_雙(稀丙基雙環[m]庚·5_烯-2,3_二羧基醯亞胺）、 Ν，Ν’-間苯二甲基-雙（烯丙基甲基雙環[2又1]庚_5_烯 -2,3_二羧基醯亞胺）等。另外，可列舉： 2.2- 雙[4f_{4’_(烯丙基雙環[2.2.1]庚-5-浠·2,3_二竣基醯亞胺)苯氧基}苯基]丙烧、 2.2- 雙[4’-{4匕(烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯氧基}苯基]丙烷、 2.2- 雙[4’_{4’_(曱基烯丙基雙環[2·2·1]庚-5_烯_2,3_二叛基醯亞胺)苯氧基}苯基]丙烷、雙{4_(烯丙基雙環[2·2·1]庚-5-烯-2,3-二羧基醯亞胺)苯基}曱烷、雙{4-(烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二綾基醯亞 • 胺)苯基}甲烷等。另外，可列舉·· 雙{4-(曱基烯丙基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}甲烷、雙{4-(曱基烯丙基曱基雙環[2.2.1]庚-5-烯-2,3-二羧基醯亞胺)苯基}甲烷等。 1.3經三稀基取代之紂地醯亞胺（a3) 本發明中可用的η為3的經三烯基取代之耐地醯亞胺 43 200835754 ζ,υ^, upif.doc 化合物之合成可由如下方式進行:相對於1〇莫耳三胺，而混合3.0莫耳〜5·〇莫耳經烯基取代之耐地酸酐，於常溫下，溶解於例如苯、曱苯、二甲苯、均三甲苯、甲基萘、萘滿（tetralin)、氯仿、三氯乙烯、四氯乙烯、氯笨::噪烷、四氫呋喃、六亞曱醚(hexamethylene ether)、笨甲醚、丙酮、曱基乙基酮、曱基異丁基酮、苯乙酮、N，N_二甲美甲酿胺、二曱亞石風等任意溶劑，或者溶解將上述溶劑的2 種或2種以上混合而成的溶劑中，製成溶液，攪拌保^寺〇 $ 小時〜30小時使其反應。於20t〜8(rc下減壓乾燥除^上述溶劑，獲韻胺酸。可於上述溶射於溶躺沸點附近使上述醯胺酸回流0.5小時〜3〇小時，或者使化合物本 1 160°C〜2G〇°C下加熱0.5小時〜3〇小時，進行脫水閉裱’然後使溶劑減壓乾燥而獲得目標化合物。可利用NMR、IR進行確認。 ” t 口 ^ 斗人ί發明中可用的η為3的經三烯基取代之耐地醯亞胺化&物之具體例，例如可列舉以下者。乙基^猶丙基魏Μ·1]庚_冰2,3_二縣酸亞胺)三苯基Γ5(㈣基魏[2.2.1]庚傳2,3_:絲醯亞胺)三三（4_(烯丙基雙環[2.2.1]庚_5_烯_23_ 基}羥基甲烷聽I亞胺)本 Γ其2,丙基雙環[2.2.1]庚_5.2,3_二鲮絲亞胺)三乙細（Τη遍1ΤΑΕΑ)⑽及1Η侧R光譜（·ΜΗζ) 44200835754 ΔΌΔ UpiLdOO Carboxylimine), N,N'-propylene bis(allylbicyclo[2.2.1]hept-5-ene·2,3-dicarboxyacidimide), Ν,Ν'- Hexahexyl bis(allylbicyclo[2·2·1]hept-5·ene_2,3·dicarboxyarsenine), Ν,Ν'-hexylene bis(allylhydrazinobicyclo[2· 2·1]hept-5-ene-2,3-dicarboxy quinazoline), hydrazine, Ν'-dodecylene-bis(allylbiscyclo[2·2·1]hept-5-ene -2,3-dicarboxy quinone imine), hydrazine, Ν'-dodecylene bis(allylmethylbicyclo[2·2·1]hept-5-ene-2,3-diindole Alkyl imine), N, Nf-cyclohexylene-bis(allylbicyclo[2·2·1]hept-5-ene-2,3-dicarboxyindenine), Ν,Ν'- Cyclohexyl bis(allylmethylbicyclo[2·2·1]hept-5-ene-2,3-dicarboxy quinone imine) and the like. In addition, N, Nf-p-phenylene-bis(allylbicyclo[2·2·1]hept-5-ene-2,3-dicarboxyindenine), hydrazine, hydrazine-pair Phenyl-bis(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenine), hydrazine, Ν'-m-phenylene-bis(allylbicyclo[ 2.2.1] hept-5-ene-2,3-dicarboxy quinone imine), hydrazine, Ν'-m-phenylene-bis(allylhydrazinobicyclo[2.2.1]hept-5-ene- 2,3-dicarboxy quinone imine), 39 200835754, 丄^|/χΣ·0·00 Ν, Ν'·{(1-mercapto)·2,4· phenylene b bis (allyl bicyclol) [2.2.1]Hept-5-retributed-2,3-diindenyl iodide), hydrazine, Ν'·p-phenylenediyl-bis(allylbicyclo[2.2.1]hept-5-ene -2,3-dicarboxy quinone imine), hydrazine, Ν'-p-phenylenediyl-bis(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyfluorene Amine, N, Nf-m-phenylenediyl-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyarmineimine), ® Ν, Ν'-m-phenylene Methyl-bis(allylmethylbicyclo[2.2.1]hept-5-ene-2,3-diindenyl imino), 2.2-bis[4'·{4 decallylbicyclo[2.2. 1]hept-5-ene-2,3·dicarboxy quinone imine)phenoxy} Propane, 2,2_double [heart {4'_(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)phenoxy}phenyl] Propane, 2.2-bis[4'-{4'_(decylallylbiscyclo[2.2.1]hept-5-ene-2,3-dicarboxyarenimine)phenoxy}phenyl]propane, _ Double {4-(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimide)phenyl}decane, bis{4-(allylmethylbicyclo[2.2 .1] hept-5-ene-2,3-dicarboxy quinolinimine)phenyl}decane. Further, exemplified by: bis{4-(decylallylbiscyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine)phenyl}decane, double {4-(fluorenyl) Allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyl 200835754 quinone imine)phenyl}methane, double {4-(allylbicyclo ρ·2·1]g- 5-ene-2,3-dicarboxy quinone imine)phenyl} bond, bis{4-(allylmethylbicyclo ρ·2·1]hept-5-ene-2,3-dicarboxy fluorene Amine)phenyl}ether, bis{4-(mercaptopropylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenimido)phenyl}ether, bis{4-(ene Propylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)phenyl}stone, double {4-(allylhydrazinobicyclo[2.2.1]hept-5- Alkene-2,3-dicarboxy quinone imine) phenyl} hydrazine and the like. Further, examples thereof include: bis{4-(decylallylbiscyclo[2.2.1]hept-5-ene-2,3-dicarboxyarmine)phenyl}. More preferably, the dienyl substituted substituted quinone imine (a2) is: N, Nf-ethylidene bis(allylbicyclo[2·2·1]hept-5-ene-2, 3_dicarboxy quinone imine), N,Nf-ethylidene-bis(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine), N, Nf - ethylene bis(mercaptopropyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine), hydrazine, Ν'-propylene bis (allyl bicyclo [ 2·2·1]hept-5-ene-2,3-dicarboxy quinone imine), hydrazine, Ν'-hexylene-bis(allylbiscyclo[2·2·1]hept-5-ene- 2,3-dicarboxyl 41 200835754 ijpii.doc acid imine), hydrazine, Ν'-hexylene-bis(allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyfluorene Imine), hydrazine, Ν'-dodecylene bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine), hydrazine, Ν'- Dialkyl-bis(allylhydrazinobicyclo[2·2·1]hept-5-ene-2,3-dicarboxyindenine), hydrazine, Ν'·cyclohexylene-bis(allyl) Bicyclo[2·2·1]hept-5-ene-2,3-dicarboxymethyl quinone imine), hydrazine, Ν'-cyclohexylene bis(allylhydrazinobicyclo[2.2.1]heptane- 5-ene-2,3-dicarboxy quinone imine Wait. In addition, Ν, Ν'-p-phenylene-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine), Ν, Ν'- Phenyl-bis(allylmethylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindenine), • Ν, Ν'-m-phenylene bis(allylbicyclo[ 2·2·1]hept-5-ene-2,3-dicarboxyindolimine), N,Nf-m-phenylene-bis(allylmethylbicyclo[2.2.1]hept-5-ene -2,3-dicarboxy quinone imine), N,N'-{(1-indenyl)-2,4-phenylene bis(allylbicyclo[2·2·1]hept-5- Alkene-2,3-dicarboxy quinone imine), hydrazine, Ν'-p-phenylenediyl-bis(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxy quinone imine ), 42 200835754 zozi^pit.doc ]^,1^'-p-Oxime-bis(allylmethylbicyclo[2·2·1]hept-5-ene-2,3-dicarboxyfluorene Imine), hydrazine, Ν'-m-xylylene _ bis (dilyl biscyclo[m]hept-5-ene-2,3-dicarboxy quinone imine), hydrazine, Ν'-m-xylylene Base-bis(allylmethylbicyclo[2,1]hept-5-ene-2,3-dicarboxyarenimine) and the like. In addition, it can be exemplified: 2.2-bis[4f_{4'_(allylbicyclo[2.2.1]hept-5-oxime-2,3-didecylimine)phenoxy}phenyl]propane , 2.2-bis[4'-{4匕(allylhydrazinobicyclo[2.2.1]hept-5-ene-2,3-dicarboxyindolimine)phenoxy}phenyl]propane, 2.2- Bis[4'_{4'_(decylallylbiscyclo[2·2·1]hept-5-ene-2,3_di-resinimide)phenoxy}phenyl]propane, double {4_(allylbicyclo[2·2·1]hept-5-ene-2,3-dicarboxyindolimide)phenyl}decane, bis{4-(allylhydrylbicyclo[2.2. 1] hept-5-ene-2,3-dimercaptoquinone•amine)phenyl}methane. In addition, bis(4-(mercaptopropyl bicyclo [2.2.1] hept-5-ene-2,3-dicarboxy quinone imine) phenyl} methane, double {4-(fluorenyl) Allyl indenylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxyinlimine)phenyl}methane or the like. 1.3 Tris-substituted indole quinone imine (a3) The trienyl substituted terpene imine 43 having η of 3 usable in the present invention 200835754 ζ, υ^, upif.doc The synthesis of the compound may be as follows The method is carried out: mixing with 3.0 moles of 5% to 5 〇 molars by the alkenyl group substituted with an alkenic anhydride, and dissolved at, for example, benzene, toluene, xylene, and mesitylene at normal temperature. , methyl naphthalene, tetralin, chloroform, trichloroethylene, tetrachloroethylene, chloroform:: noise, tetrahydrofuran, hexamethylene ether, methyl ether, acetone, mercapto ethyl ketone Any solvent such as decyl isobutyl ketone, acetophenone, N, N-dimethyl methamine, bismuth sulphate, or a solvent obtained by mixing two or more of the above solvents. Make a solution and stir it to make it react for $hour to 30 hours. The above solvent is dried under reduced pressure at 20t~8 (rc under rc to obtain syllabic acid. The above proline can be refluxed for 0.5 hour to 3 hours at the vicinity of the boiling point of the dissolved solution, or the compound is 1160 ° C. Heating at ~2 G 〇 ° C for 0.5 hr to 3 hrs, and performing dehydration and hydration, and then drying the solvent under reduced pressure to obtain the target compound. It can be confirmed by NMR or IR. ” t 口 ^ 斗人 η η available in the invention Specific examples of the trienyl substituted-resistant quinone imidization/amplifier of 3 may be exemplified by the following: Ethyl^ Amine) triphenylphosphonium 5 ((tetra)-based Wei [2.2.1] G-transport 2,3_: silky imine) tris(4_(allylbicyclo[2.2.1]hept-5-ene_23_yl}hydroxyl Methane I. Imine) This is 2, propyl bicyclo [2.2.1] g _5.2, 3 dioxin imine) triethyl fine (Τη遍1ΤΑΕΑ) (10) and 1 Η side R spectrum (·ΜΗζ) 44

200835754 χ ^piI*C10C 分別示於圖1及圖2。 IR光譜中歸屬如下：烯烴C-H伸縮：3070、2966 cm-1 ; 芳香族C-H伸縮：2966 cm·1 ;烷烴C-H伸縮：2938 cm]; 隨亞胺 C = 0 伸縮·· 1762、1690 cnf1 ; C = C 伸縮·· 1640 cnT1 ; _CH2_N-亞曱基剪式振動：1448 cm-i ;醯亞胺c_n伸縮：1382 cnT1 等。 [化 28]200835754 χ ^piI*C10C are shown in Figure 1 and Figure 2, respectively. The IR spectra are classified as follows: olefin CH stretching: 3070, 2966 cm-1; aromatic CH stretching: 2966 cm·1; alkane CH stretching: 2938 cm]; with imine C = 0 stretching · 1762, 1690 cnf1; C = C telescopic · 1640 cnT1 ; _CH2_N- ytterbium scissor vibration: 1448 cm-i; yttrium imine c_n expansion: 1382 cnT1 and so on. [化 28]

譜(烯丙基雙環[训从稀处^基醯亞账，基甲炫（Tris娜risAM)的IR及㈣嫩光譜（4〇〇 MHz)分別示於圖3及圖4。 *瓜光譜中歸屬如下：烯烴C_H伸縮：3〇56、297〇 ^ ; 方香族C-H伸縮：2970cm-1;垸煙站伸縮：2936 ^1; 45 200835754 zoziopn.doc 醯亞胺 C二0 伸縮：1772、1706 cm·1 ; c = C 伸縮：1638 cm 1 ;酸亞胺CXK伸縮：1402 cm·1等。 [化 29]The spectrum (allyl bicyclol [trained from the dilute ^ base 醯账 ,, 甲炫 ( (Tris Na risAM) IR and (four) tender spectrum (4 〇〇 MHz) are shown in Figure 3 and Figure 4, respectively. The affiliation is as follows: olefin C_H stretching: 3〇56, 297〇^; Fangxiang CH stretching: 2970cm-1; smog station stretching: 2936 ^1; 45 200835754 zoziopn.doc 醯 imine C 2 0 telescopic: 1772, 1706 Cm·1 ; c = C expansion and contraction: 1638 cm 1 ; acid imine CXK expansion and contraction: 1402 cm·1, etc. [Chem. 29]

〜7.591>1)111的峰值；6、卜8、卜1質子（1811):2.25卩卩111 〜3.73卯111的峰值；11質子（611):125卯111〜181卯111的峰值；j、k、m、n 質子（12H) : 5.01 ρρηι〜5·14 ppm、5 74 ppm〜6·34 ppm 的峰值；0 質子（1H) : 5 3〇 ppm〜5 6〇 ppm 的峰值等。三{4·(烯丙基雙環[2·2·1]庚烯_2,3二羧基醯亞胺)苯基}經基曱烧（TrisANIPARARO )的 IR 及1H-NMR 光譜（400 MHz)分別示於圖5及圖6。 IR光譜中歸屬如下··烯烴C-H伸縮：3056、2972 cm-1 ; 芳香族C-H伸縮：2972 cnT1 ;烷烴C-H伸縮：2936 cm·1 ; 醯亞胺 C = 0 伸縮：1776、1706 cnf1 ; C = C 伸縮：1636 cm—1 ;醯亞胺 C-N 伸縮·· 1402 cnT1 等。 [化 30] 46 200835754 zoznpif.doc~7.591>1) peak of 111; 6, b, 1 proton (1811): peak of 2.25卩卩111~3.73卯111; 11 proton (611): peak of 125卯111~181卯111; j , k, m, n proton (12H): 5.01 ρρηι~5·14 ppm, 5 74 ppm~6·34 ppm peak; 0 proton (1H): 5 3〇ppm~5 6〇ppm peak. TrisANIPARARO IR and 1H-NMR Spectroscopy (400 MHz) Shown in Figures 5 and 6. The IR spectrum is classified as follows: olefin CH stretching: 3056, 2972 cm-1; aromatic CH stretching: 2972 cnT1; alkane CH stretching: 2936 cm·1; sulfhydryl C = 0 stretching: 1776, 1706 cnf1; C = C Stretching: 1636 cm -1 ; 醯 imine CN stretching · 1402 cnT1 and so on. [化 30] 46 200835754 zoznpif.doc

Wnmr光谱中歸屬如下：a〜d 〜7.53PPm的峰值；e、f 所；（2H).6.98Ppm 〜3.60ppm 的料 f ( : 2.27Ppm 峰值；j、h、n 質子5017PPM 值等。 · ppm〜6.24 ppm的峰耐地醯亞本發明中可用的η 化合物之合成可由如下方式進行：地醯亞胺下，溶解於例如笨、甲n基取代之耐地酸酐，於常溫不滿氟仿、三氯乙埽、四氯乙烯、碧*界不吱喃、六亞甲~財、二°惡烧、四氫基_、苯乙酮、ΝΝ;^丙嗣、甲基乙基闕、甲基異丁或者溶解於將上、卜—甲基、二甲亞颯等任意溶劑，中，製成溶液，種或2種以上混合而成的溶劑 2代〜8(TCT減屋#H.5小時:30小時使其反應。於中於_的缔點附近使上述醯胺酸回流0.5小時 47 200835754The Wnmr spectrum belongs to the following: peak value of a~d~7.53PPm; e, f; (2H).6.98Ppm~3.60ppm material f (: 2.27Ppm peak; j, h, n proton 5017PPM value, etc. · ppm ~ 6.24 ppm of peak resistance 合成 The synthesis of the η compound usable in the present invention can be carried out by dissolving, for example, a stupid, indenyl substituted terephthalic acid anhydride under the guanidine imine, at room temperature less than fluoroform, three Chloroacetam, tetrachloroethylene, bismuth, hexamethylene, hexanone, acetophenone, acetophenone, acetophenone, acetophenone, methyl hydrazine, methyl hydrazine Ding or dissolved in any solvent such as b, methyl or dimethyl hydrazine, prepared as a solution, a mixture of two or more kinds of solvents, 2 to 8 (TCT reduced house #H. 5 hours: The reaction was allowed to proceed for 30 hours. The above proline was refluxed for 0.5 hour in the vicinity of the ? point of the _ 47 200835754

1 ^]Jlf.d〇C 小日士」者使!合物本身於i6G°c〜2GG°c下加熱〇·5 彳胃€入^，進行脫水閉環，然後使溶劑減壓乾燥而獲付目3 目標化合物可利用腿、職行確認。 /μ人/x月中可用的n為4的經四烯基取代之财地醯亞胺化合物之具體例，例如可列舉以下者。四{4-(#两基雙環[2.21]庚_5•烯_2,3_二羧基醯亞胺苯基}甲烷1 ^]Jlf.d〇C 小日士"! The compound itself is heated at i6G °c~2GG °c, 55 彳 stomach into the ^, dehydration ring closure, and then the solvent is dried under reduced pressure Item 3 The target compound can be confirmed by the leg and the job. Specific examples of the tetradecyl-substituted quinone imine compound in which n is 4 in /μ person/x month include, for example, the following. Four {4-(#二基双环[2.21]hept-5•ene_2,3_dicarboxy quinone imine phenyl}methane

^四{心(稀丙基雙環Ρ·2·1]庚-5-烯-2,3_二羧基醢亞胺）四苯基}甲烷(TetrakisANITAM)的 IR 及1H-NMR 光譜（400 MHz)分別示於圖7及圖8。汉光譜中歸屬如下：烯烴C-H伸縮：3060、2972 cnT1 ; 芳香族C-H伸縮：2972 cm·1 ;烷烴C-H伸縮：2936 cnT1 ; 醯亞胺 C = 0 伸縮：1776、1706 cm·1 ; C = C 伸縮：1638 cnT1 ;醯亞胺C-Ν伸縮：1404 cm·1等。 [化 31]IR and 1H-NMR spectra of tetra{{heart (dipropylbicycloindole·2·1]hept-5-ene-2,3-dicarboxyindolimine)tetraphenyl}methane (Tetrakis ANITAM) (400 MHz) They are shown in Figures 7 and 8, respectively. The spectra in the Han spectrum are as follows: olefin CH stretching: 3060, 2972 cnT1; aromatic CH stretching: 2972 cm·1; alkane CH stretching: 2936 cnT1; sulfhydryl C = 0 stretching: 1776, 1706 cm·1; C = C Expansion and contraction: 1638 cnT1; 醯imine C-Ν expansion: 1404 cm·1, etc. [化31]

48 20083575448 200835754

x ^/j^iI.ClOC 〜7.59ppm 的峰值；e、f、g、i、i 質子（24H) : 225ppm 〜3.60??!11的峰值；』、]^、111、11質子（1611):5.04??111〜 6.50Ppm 的峰值；h 質子（8H): 1.25ppm〜1.75ppm 的峰值等。本發明之較好的經烯基取代之耐地醯亞胺化合物（A) 是具有蓬鬆結構的低分子量醯亞胺單體，因此可溶於幾乎所有的有機溶劑中，即使以溶液狀態長期保存也不會引起結晶析=者凝膠化，可穩定使用。另外，藉由加熱而形成立體交聯結構的聚麵胺，該聚輕胺硬化物表現出良好的耐熱性、機械特性、電特性、耐化學藥品性。 (B) a 之噴墨墨水中可進而含有的高分子化合物（B) 聚醯亞胺、聚軸、聚醯胺酿亞胺、 2嫌二聚醋、丙烯酸聚合物、丙烯酸酯聚合物、聚幸六好的日乙烯等高分子化合物，但並不限定於此等。二匕合胺酸或者可溶性聚醯亞胺等聚醯亞胺系高分號所^示@二2好地列舉日本專利特願2編35336 定於此等。-知騃、或者其醯亞胺化聚合物，但並不限該聚醯胺酿η 化合物（bi) _疋可至乂使用具有大於等於2個酸酐基的基的化合物（、br；胺（b2)、單胺（b3)以及具有1個酸酐的聚醯胺酸。❿獲得’但並不限定独該製法所獲得兒月可用以獲得高分子化合物（B) Μ 下’說明 w m ·、·#,«>、_ 的，具有 49 200835754 1 ^ pit. doc 大於等於2個酸酐基的化合物（bl)、二胺（b2)、單胺（53) 以及具有一個酸酐基的化合物（b4)。 2.1具有大於等於2個酸酐基的化合物（bl) 本發明中可用的具有大於等於2個酸酐基的化合物 (M)之具體例，可列舉：苯乙烯-順丁烯二酸酐共聚物、曱基丙烯酸曱酯-順丁烯二酸酐共聚物等具有酐基的自由基聚合性單體與其他自由基聚合性單體的共聚物或者四羧酸二酐等。四羧酸二酐例如可列舉：2,2’，3,3’·二苯曱酮四曱酸二酐、2,3,3’，4’·二苯曱酮四甲酸二酐、2,2’，3,3f_二苯颯四曱酸二酐、2,3,3f，4f-二苯砜四甲酸二酐、2,2’，3,3f二苯基醚四曱酸二酐、2,3,3’，4’-二苯基醚四曱酸二酐、乙二醇雙(偏苯三曱酸酐酯）、乙烷四曱酸二酐、4-(2,5-二氧四氫呋喃-3-基)-1，2,3,4-四氫萘-1，2-二甲酸酐、5-(2,5-二氧四氫呋喃基)-3-曱基-3-環己烯-1，2-二甲酸酐、下述式bl-Ι〜式M-73 所示之化合物等四羧酸二酐。x ^/j^iI.ClOC ~ 7.59ppm peak; e, f, g, i, i proton (24H): 225ppm ~ 3.60??! 11 peak; 』,]^, 111, 11 proton (1611) : 5.04?? 111~ 6.50Ppm peak; h proton (8H): peak of 1.25ppm~1.75ppm, etc. The preferred alkenyl substituted quinone imine compound (A) of the present invention is a low molecular weight quinone imine monomer having a bulky structure, and thus is soluble in almost all organic solvents, even in a solution state for long-term storage. It also does not cause crystallization and gelation, and it can be used stably. Further, a polyamine which forms a bulk crosslinked structure by heating exhibits good heat resistance, mechanical properties, electrical properties, and chemical resistance. (B) A polymer compound (B) which can be further contained in the inkjet ink of a. Polyimine, polyaxial, polyamidiamine, 2, dimerized vinegar, acrylic polymer, acrylate polymer, poly Fortunately, it is a polymer compound such as ethylene, but it is not limited thereto. A poly-imide-based high-grade number such as bis-amino acid or soluble polyimine is shown in the following paragraphs. - a stilbene, or a ruthenium imidized polymer thereof, but not limited to the polyamine amine η compound (bi) _ 疋 can be used to a compound having a group having 2 or more acid anhydride groups (, br; amine ( B2), monoamine (b3) and polyamic acid with one anhydride. ❿ obtained 'but not limited to the one obtained by the method of obtaining the polymer compound (B) Μ 下 ' description wm ·, · #,«>, _, with 49 200835754 1 ^ pit. doc Compounds (bl), diamines (b2), monoamines (53) and compounds having an anhydride group (b4) of 2 or more acid anhydride groups 2.1 Compound having (2) or more of acid anhydride groups (b) Specific examples of the compound (M) having two or more acid anhydride groups usable in the invention include styrene-maleic anhydride copolymer and ruthenium. A copolymer of a radical polymerizable monomer having an anhydride group such as an alkyl acrylate-maleic anhydride copolymer and another radical polymerizable monomer, or a tetracarboxylic dianhydride, etc. Examples of the tetracarboxylic dianhydride include :2,2',3,3'·dibenzophenone tetradecanoic acid dianhydride, 2,3,3',4'·dibenzophenone Acid dianhydride, 2,2',3,3f_diphenylfluorene tetraphthalic acid dianhydride, 2,3,3f,4f-diphenyl sulfone tetracarboxylic dianhydride, 2,2',3,3f diphenyl ether Tetraphthalic acid dianhydride, 2,3,3',4'-diphenyl ether tetradecanoic acid dianhydride, ethylene glycol bis(trimellitic anhydride), ethane tetraphthalic acid dianhydride, 4-( 2,5-Dioxytetrahydrofuran-3-yl)-1,2,3,4-tetrahydronaphthalene-1,2-dicarboxylic anhydride, 5-(2,5-dioxotetrahydrofuranyl)-3-indenyl 4-cyclohexene-1,2-dicarboxylic anhydride, tetracarboxylic dianhydride such as a compound represented by the following formula bl-Ι~formula M-73.

50 20083575450 200835754

ΔΌΔ1 jpiX.doCΔΌΔ1 jpiX.doC

[化 32] b1-1 Ο Ο[化32] b1-1 Ο Ο

b1-2B1-2

b1-4 b1-6B1-4 b1-6

b1-13 o o 200835754 ZDZIDpiI.doc [化 33] b1-15 b1-14 b1-16 b1-18B1-13 o o 200835754 ZDZIDpiI.doc [Chem. 33] b1-15 b1-14 b1-16 b1-18

b1-20 b1-22B1-20 b1-22

o o b1-17 o o o o b1-19o o b1-17 o o o o b1-19

b1-24B1-24

b1_21 b1-23 b1-25 200835754 zoz i^pii.doc [化 34] b1-27 b1-28 b1-29B1_21 b1-23 b1-25 200835754 zoz i^pii.doc [34] b1-27 b1-28 b1-29

b1-32 b1-33B1-32 b1-33

53 200835754 a w/pii.doc53 200835754 a w/pii.doc

Hb 35] b1-35 〇 b1-36 〇Hb 35] b1-35 〇 b1-36 〇

〇 b1-45〇 b1-45

b1-44 〇B1-44 〇

54 200835754 26215pit.doc [化 36] b1-51 b1-52 b1-5354 200835754 26215pit.doc [化36] b1-51 b1-52 b1-53

b1-56B1-56

b1-54 b1-55B1-54 b1-55

〇〇

55 200835754.^ 1 ^ρΐΙ·(100 [化 37]55 200835754.^ 1 ^ρΐΙ·(100 [化37]

b1-66 b1-67B1-66 b1-67

b1-68 Ο κ b1-70 b1-71 CH3 CH3 〇B1-68 Ο κ b1-70 b1-71 CH3 CH3 〇

〇 Ο〇 Ο

b1-72 V 〇B1-72 V 〇

〇〇

-(CH2)10^ 〇/ Λ 厂\'〇 CH3 h3c-(CH2)10^ 〇/ Λ Factory\'〇 CH3 h3c

具有大於等於2個酸酐的化合物的上述具體例中，苯乙烯-順丁烯二酸酐共聚物以及式bl-Ι、式M-5、式bl-6、式 bl_7、式 bl-8、式 bl-9、式 bl_14、式 Μ·18、式 bl-20 所示之化合物對溶劑的溶解性高，可製備高濃度的墨水，因此較好。另外，根據喷墨墨水的用途而要求高透明性，此種情況下，尤其好的是使用苯乙烯-順丁烯二酸酐共聚物 56 200835754 zozi^pu.doc ΐ ((:))12為偶或者以谓CH3)2表示之有機基; t”)〜式㈤中，A1是單鍵、一、〇2…C〇-、-C0NH-、-NHCO-、_C(CH3)2_、 "°"(CH2)m'°~' 's'(CH2)m-s·? *t m 為1 6之正數，A2是單鍵、_〇、_s_、_c〇_、 -C(CF3)2_或者石炭數為1〜a之$ p m 馮1 3之亞圪基，鍵結於環苯環的氫可被取代為-F、-CH3。仏me考通式（n)所示之二胺，例如可列舉 (Π-7)所示之二嚴。、 J 式 [化 39]In the above specific examples of the compound having two or more acid anhydrides, the styrene-maleic anhydride copolymer and the formula bl-Ι, the formula M-5, the formula bl-6, the formula bl_7, the formula bl-8, the formula bl -9. The compound represented by the formula bl_14, the formula 1818, and the formula bl-20 has high solubility in a solvent, and a high concentration of ink can be prepared, which is preferable. Further, high transparency is required depending on the use of the inkjet ink, and in this case, it is particularly preferable to use a styrene-maleic anhydride copolymer 56 200835754 zozi^pu.doc ΐ ((:)) 12 as an even Or an organic group represented by CH3)2; t")~ (5), A1 is a single bond, a 〇2...C〇-, -C0NH-, -NHCO-, _C(CH3)2_, "° "(CH2)m'°~' 's'(CH2)ms·? *tm is a positive number of 16 and A2 is a single bond, _〇, _s_, _c〇_, -C(CF3)2_ or charcoal The number of 1 pm to $ pm von 1 3 fluorenyl, the hydrogen bonded to the benzene ring can be substituted with -F, -CH3. 仏me can be represented by the diamine of formula (n), for example List the two strictness shown in (Π-7). J Formula [39]

IH h2n ^\/NH2 H2 N N H2IH h2n ^\/NH2 H2 N N H2

11-5 h2ist .0 11-6 h2n nh2 11-7 H2 N H2 通式（Π)所示之二胺，例 (皿-3)所示之二胺。 "列舉式 Μ-1 式 58 200835754 x ^j^xf.doc III-1 [化 40]11-5 h2ist .0 11-6 h2n nh2 11-7 H2 N H2 The diamine represented by the formula (Π), the diamine represented by the formula (dish-3). " enumeration Μ-1 type 58 200835754 x ^j^xf.doc III-1 [化40]

III*2H2N- ~^>NH2 H^NH2 通式（IV)所示之二胺 h2n …·z (IV-3)所示之二胺。列如可列舉式（IV-1)〜式 h2n III-3III*2H2N-~^>NH2H^NH2 The diamine represented by the diamine h2n ...·z (IV-3) represented by the formula (IV). The column can be enumerated as formula (IV-1) ~ formula h2n III-3

Ut 41] IV-1Ut 41] IV-1

IV-2IV-2

’例如可通式（V )所示之, (V_5 )所示之二胺。 [化 42] V-1 h2n 胺 IV-3For example, the diamine represented by the formula (V), (V_5) can be used. V-1 h2n amine IV-3

列舉式（v-i)〜式Enumeration formula (v-i)~

V_2H2NV_2H2N

Tf^pNH2 V-3 Η2Ν 谷Η, W V^5Tf^pNH2 V-3 Η2Ν 谷Η, W V^5

通式（VI)所示之二胺，γ (^Μο)所示之二胺。河如可列舉式（VI-1)〜式 59a diamine represented by the formula (VI), a diamine represented by γ (^Μο). River can be enumerated (VI-1) ~ type 59

200835754 ΔΌΔΙ jpil.d〇C200835754 ΔΌΔΙ jpil.d〇C

[化 43][化43]

60 20U835754 zozi jpn.doc [化 46]60 20U835754 zozi jpn.doc [Chem. 46]

VI〜23VI~23

VI-2 2 VI-2 4VI-2 2 VI-2 4

通式（珊）所示之二胺fYNH2 (W-6)所示之二胺。 j如可列舉式（W-l) [化 47] VII-1A diamine represented by the diamine fYNH2 (W-6) represented by the formula (San). j can be enumerated as a formula (W-l) [Chem. 47] VII-1

VII-3VII-3

VII-5VII-5

通式（Μ)所示之二胺，所示之二胺。A diamine of the formula (Μ), shown as a diamine.

200835754 zozopii.doc [化 48] VIII-l200835754 zozopii.doc [Chem. 48] VIII-l

VIII-2 -(CH2)3- /~nh2 VIII-4VIII-2 -(CH2)3- /~nh2 VIII-4

VIII-8 >nh2 h2n分 VIII-7VIII-8 >nh2 h2n points VIII-7

VIII-9 viii-io F3Cv cf3VIII-9 viii-io F3Cv cf3

*2 H2N VIII-U*2 H2N VIII-U

通式（n)〜通式（vm)所示之二胺（b2)的上述具體例中，更好的是可列舉式（v])〜式（v_5)、式（心、) 〜式（VI-12)、式（νμ26)、式（νι·27)、式（n) ::-2)、式(.6)、式(职)〜式(.5)所示之二胺，是可列舉式（ν_6)4(ν·7)、式（叫）〜式（VI-12)所示之二胺。發月中可用的二胺（b2)，進而可列舉通式（幻所 62 200835754 zozi^pif.doc 示之二胺。 [化 49] R6In the above specific examples of the diamine (b2) represented by the general formulae (n) to (vm), the formula (v]) to the formula (v_5) and the formula (heart,) to the formula (b) are more preferable. VI-12), formula (νμ26), formula (νι·27), formula (n)::-2), formula (.6), formula (care)~ (.5) The diamine represented by the formula (ν_6) 4 (ν·7) and the formula (called) to the formula (VI-12) can be cited. The diamine (b2) which can be used in the month of the month can be further exemplified by the diamine of the formula (Zhisui 62 200835754 zozi^pif.doc).

H2N"v^nh2 式（IX)中， A3 是單鍵、-0·、-COO、-〇CO·、者-(CH2)m-(式中，m為1〜6之整數），H2N"v^nh2 In the formula (IX), A3 is a single bond, -0·, -COO, -〇CO·, -(CH2)m- (where m is an integer of 1 to 6),

R6是具有類固醇骨架之基團、下述式（X)所示之其團、或者鍵結於苯環的2個胺基的位置關係為對饮時碳^ 為1〜30之烷基、或者該位置關係為間位時唆數為丨二如之烷基或者苯基，該烷基中，任意-CH2·可被-CF2_、_CHF_、-0_、_CH = CH-或者<三0取代，_CH3可被-CHf、_CHF2或者_Cf3取代，鍵結於該苯環之後的氫可被取代為_F、-CH3、_〇CH3、 -OCH2F、-OCHF2 或者-0CF3。 [化 50]R6 is a group having a steroid skeleton, a group represented by the following formula (X), or a positional relationship of two amine groups bonded to a benzene ring, which is an alkyl group having a carbon number of from 1 to 30 at the time of drinking, or The positional relationship is an alkyl group or a phenyl group having a number of turns, wherein any -CH2. _CH3 may be substituted by -CHf, _CHF2 or _Cf3, and the hydrogen bonded to the benzene ring may be substituted with _F, -CH3, _〇CH3, -OCH2F, -OCHF2 or -0CF3. [化 50]

式（X)中， A及A分別獨立為單鍵、…_c〇〇_、七 -CONH-、-CH=CH-或者碳數為之亞烷基， R及R分別獨立為-j?或者_0迅，環S是1，4-亞苯基、认亞環己基、以二。惡燒乂$ 63 200835754 ,In the formula (X), A and A are each independently a single bond, ..._c〇〇_, seven-CONH-, -CH=CH- or an alkylene group having a carbon number, and R and R are each independently -j? _0 fast, ring S is 1,4-phenylene, phenylene cyclylene, and two.恶烧乂$ 63 200835754 ,

x ^jyil.dOC 基”密咬-2,5-二基H2,5_二基、萘_i，5_二基、萘_2,7· 二基或者蒽-9，10-二基， ’ R9是-Η、-F、碳數為1〜3〇之烷基、碳數為i〜3〇之經氟取代之烧基、礙數為1〜3〇之烷氧基、_(^、_〇(：11217、 -OCHF2 或者-〇CF3， ...... 飞數,x ^jyil.dOC based "Bite-2,5-diyl H2,5_diyl, naphthalene_i,5_diyl, naphthalene_2,7.diyl or -9,10-diyl, 'R9 is -Η, -F, an alkyl group having a carbon number of 1 to 3 fluorene, a fluorine-substituted alkyl group having a carbon number of i to 3 Å, an alkoxy group having a hindrance of 1 to 3 Å, _(^ , _〇 (:11217, -OCHF2 or -〇CF3, ...... fly number,

c、d&e分別獨立表示0〜3之整數，e為2或者3日士多個環S可為相同之基團亦可為不同之基團， ^ f及g分別獨立表示〇〜2之整數，且 c+d+eg1〇通式（K)巾，2個胺基鍵結於苯，基的鍵結位置關係為間位或者二〜式所：之二;胺’例如可列舉下述式⑷) 64 200835754c, d & e respectively represent an integer of 0 to 3, e is 2 or 3, a plurality of rings S may be the same group may also be a different group, ^ f and g respectively represent 〇 ~ 2 An integer, and c+d+eg1 is a general-purpose (K) towel, two amine groups are bonded to benzene, and the bond positional relationship of the group is a meta position or a two-form: two; the amine 'for example, the following Formula (4)) 64 200835754

ΔΌΔ i jpif.dOCΔΌΔ i jpif.dOC

I X - 2I X - 2

>19 I X-5>19 I X-5

I X-6I X-6

[化 52][化52]

H2N H〇N V I Χ-7 h2n I X-8 }"V〇~R18 \ >V h2n h2n ΗΛ I Χ-9 I x-l 0 > Hr19 > > > η2ν h2n η2ν I x-l 1 \_[ )19 上述式（IX-1)、式（ΙΧ·2)、式（IX-7)及式（ΙΧ·8) 中，R18是碳數為2〜30之有機基，此等中較好的是碳數為 65 200835754 ζοζι jpii.docH2N H〇NVI Χ-7 h2n I X-8 }"V〇~R18 \ >V h2n h2n ΗΛ I Χ-9 I xl 0 > Hr19 >>> η2ν h2n η2ν I xl 1 \_ [19] In the above formula (IX-1), formula (ΙΧ·2), formula (IX-7) and formula (ΙΧ·8), R18 is an organic group having a carbon number of 2 to 30, and preferably The carbon number is 65 200835754 ζοζι jpii.doc

j〜之炕丞或者碳數A Q ^ 人数為3〜12之烷氧基，更好的县石山叙為5〜12之烷基或者碳蠢主〇疋厌數式〜式（K-6)H2找祿。另外，上述 r19暑-η ？式⑽）〜式（㈣）中，川厌為〜30之有機基，此等中較好的數為1〜10之烷基或者硭H ^ 了 τ平乂野的疋石反碳數為3〜H)之絲t1G找氧基，更好的是 ii -U DCW : 數為3〜1〇之垸氧基。〜式㈤7)Si^蝴何縣下述式（㈣ 0: [化 53] I X- 1 2 R20 C=0j~ 炕丞 or carbon number AQ ^ The number of people is 3~12 alkoxy, the better county Shishan is 5~12 alkyl or carbon stupid main 〇疋数 type ~ K-6) H2 Looking for a locust. In addition, the above r19 heat-η? In the formula (10)) to the formula ((4)), the anthracene is an organic group of ～30, and the preferred number of these is an alkyl group of 1 to 10 or 硭H ^ ~H) filament t1G to find an oxy group, more preferably ii-U DCW: a number of 3 to 1 fluorene oxy group. ~ (5) 7) Si ^ Butterfly He County following formula ((4) 0: [Chem. 53] I X- 1 2 R20 C=0

1 1 3 /R201 1 3 /R20

20 I X— 1 420 I X— 1 4

NH2NH2

、上逑式（IX-12)〜式（K_l5)中，r2。 * 為1〜30之有機基，較好的疋·或者碳數的是碳數為ό〜16之徐其。# γ馮4〜16之烷基，更好 R21是-Η或者碳數為丨二/之有H6)與式（Κ-Π)中，〜20之絲，更好的是碳數為的是碳數為6 通式（IX)所示之二胺，進二基。〜式（Κ-38)所示之二胺。 Τ列舉下述式（ΙΧ-18) 66 200835754 252npif.doc [化 54], 逑逑 (IX-12) ~ (K_l5), r2. * is an organic group of 1 to 30, preferably 疋 or carbon number is a carbon number of ό~16. # 冯冯4~16的 alkyl, preferably R21 is -Η or the carbon number is 丨2/there is H6) and the formula (Κ-Π), ~20 filament, more preferably the carbon number is The diamine represented by the formula (IX) having a carbon number of 6 is a dibasic group. a diamine of the formula (Κ-38). Τ List the following formula (ΙΧ-18) 66 200835754 252npif.doc [Chem. 54]

67 200835754 upif.doc [化 56]67 200835754 upif.doc [Chem. 56]

I Χ-3 2 H2NI Χ-3 2 H2N

I Χ-3 3 H2NI Χ-3 3 H2N

I X- 3 6I X- 3 6

H3BH3B

h2n h2n 1 X- 3 7H2n h2n 1 X- 3 7

»22 I X-3 8»22 I X-3 8

上述式 OX-18)、式（IX-19)、式（K_22)、式（K_24)、式(IX-25)、式⑽8)、式(仅_3〇)、式(K_3i)、式(關) ^ (Κ·37)中HH或者碳數為u之有機基， ^好的是碳數為1〜12之絲、碳數為1〜12之燒氧基，碳數為3〜12之烷基或者碳數為3〜12之烷氧 Ϊ 上述式（K-2〇)、式（仅-21)、式（K_23)、输27)、式(Μ”、式(Κ_32)〜式之炫基、中’斤是^碳數為1〜12 或者-〇CF3，更杯二2之燒氧基、·CN、_〇卿、七咖2 〜12之烷氧# 疋碳數為3〜12之烷基或者碳數為3 平土0上述式（JX-33)以及式（IX-34)中，A9 68 200835754 是碳數為1〜12之亞烧基。通式（IX)所示之二胺，進而例如可列舉下述式（IX-39) 〜式（IX-48)所示之二胺。 [化 57]The above formula OX-18), formula (IX-19), formula (K_22), formula (K_24), formula (IX-25), formula (10) 8), formula (only _3 〇), formula (K_3i), formula ( Off) ^ (Κ·37) HH or an organic group having a carbon number of u, ^good is a carbon having a carbon number of 1 to 12, a carbon number of 1 to 12, and a carbon number of 3 to 12 An alkyl group or an alkoxy group having a carbon number of 3 to 12. The above formula (K-2〇), formula (only-21), formula (K_23), and 27), formula (Μ), formula (Κ_32)~ Hyun base, medium 'jin is ^ carbon number is 1~12 or -〇CF3, more cups 2 and 2 alkoxy, ·CN, _ 〇、, seven coffee 2 ~ 12 alkoxy # 疋 carbon number is 3~ 12 alkyl or carbon number 3 flat soil 0 In the above formula (JX-33) and formula (IX-34), A9 68 200835754 is a calcined group having a carbon number of 1 to 12. Formula (IX) Further, for example, a diamine represented by the following formula (IX-39) to formula (IX-48) can be mentioned.

69 200835754 Δ,ΧΙΔ, 1 ^pif.doc [化 58]69 200835754 Δ,ΧΙΔ, 1 ^pif.doc [化58]

通式（IX)所示之二胺（b2)中，較好的是式（IX-1) 〜式（1X-11)所示之二胺，更好的是式（IX-2)、式（IX-4)、式（ΙΧ·5)、式（IX-6)所示之二胺。本發明中可用的二胺（b2)，進而可列舉下述通式（XI) 及通式（ΧΠ)所示之化合物。 [化 59] P11R11In the diamine (b2) represented by the formula (IX), a diamine represented by the formula (IX-1) to the formula (1X-11) is preferred, and a formula (IX-2) and a formula are more preferred. (IX-4), a diamine represented by the formula (ΙΧ5) and the formula (IX-6). The diamine (b2) usable in the present invention may, for example, be a compound represented by the following formula (XI) and formula (ΧΠ). [化59] P11R11

70 200835754 zozupif.doc 式（XI)以及（XII)中， R1()是-H 或者-CH3， R11分別獨立為-Η或者碳數為1〜20之烷基或者烯基， Α6分別獨立為單鍵、-C( = 0>或者-CH2-， R13及R14分別獨立為-Η、碳數為1〜20之烷基或者苯基。70 200835754 zozupif.doc In formula (XI) and (XII), R1() is -H or -CH3, and R11 is independently -Η or an alkyl or alkenyl group having a carbon number of 1 to 20, and Α6 is independently a single The bond, -C(=0&0&; or -CH2-, R13 and R14 are each independently -Η, an alkyl group having 1 to 20 carbon atoms or a phenyl group.

上述通式（XI)中，較好的是2個「NH2_Ph-A6-0-」之一個鍵結於類固醇核的3位上，另一個鍵結於6位上。另外，更好的是2個胺基分別鍵結於苯環碳上，且相對於 A6的鍵結位置，而鍵結於間位或者對位。通式（XI)所示之二胺，例如可列舉式（XI-1)〜式 (XI-4)所示之二胺。In the above formula (XI), it is preferred that one of the two "NH2_Ph-A6-0-" is bonded to the 3-position of the steroid core and the other is bonded to the 6-position. Further, it is more preferable that the two amine groups are bonded to the benzene ring carbon, respectively, and bonded to the meta or para position with respect to the bonding position of A6. The diamine represented by the formula (XI) may, for example, be a diamine represented by the formula (XI-1) to the formula (XI-4).

[化 60][60]

71 20083575471 200835754

ζ,υζ, i jpif.d〇C 通式（XII)中，2個「NH2-(R14-)Ph_A6-0-」分別鍵結於苯環碳上，較好的是相對於類固醇核鍵結的碳而鍵結於間位或者對位的碳上。另外，2個胺基分別鍵結於苯環碳上，較好的是相對於A6而鍵結於間位或者對位。通式（ΧΠ)所示之二胺，例如可列舉式（XII-1)〜式（XII-8)所不之二胺。ζ,υζ, i jpif.d〇C In the formula (XII), two "NH2-(R14-)Ph_A6-0-" are bonded to the benzene ring carbon, respectively, preferably with respect to the steroid core bond. The carbon is bonded to the meta or para carbon. Further, the two amine groups are bonded to the benzene ring carbon, respectively, and it is preferably bonded to the meta or para position with respect to A6. The diamine represented by the formula (ΧΠ) may, for example, be a diamine of the formula (XII-1) to the formula (XII-8).

[化 61][化61]

72 200835754 Z0Z13pif.doc72 200835754 Z0Z13pif.doc

[化 62][化 62]

本發明中可用的二胺（b2)，進而可列舉通式（XIII)、通式（XIV)所示之化合物。The diamine (b2) usable in the present invention may, for example, be a compound represented by the formula (XIII) or the formula (XIV).

式（XIII)中， R15是-H或者碳數為1〜20之烷基，該烷基中碳數為 2〜20之烷基的任意-CH2-可被-0、-CH=CH·或者-CeC-取代， A7分別獨立為-0-或者碳數為1〜6之亞烷基， A8是單鍵或者碳數為1〜3之亞烷基， 73 200835754 ^u^i^pif.doc 環T是1，4-亞苯基或者1，4-亞環己基， h是0或者1。 [化 64]In the formula (XIII), R15 is -H or an alkyl group having a carbon number of 1 to 20, and any -CH2- of the alkyl group having a carbon number of 2 to 20 may be -0, -CH=CH· or -CeC-substituted, A7 is independently -0- or an alkylene group having a carbon number of 1 to 6, and A8 is a single bond or an alkylene group having a carbon number of 1 to 3, 73 200835754 ^u^i^pif.doc Ring T is 1,4-phenylene or 1,4-cyclohexylene, and h is 0 or 1. [化 64]

式（XIV)中， R16是碳數為6〜22之烷基，In the formula (XIV), R16 is an alkyl group having a carbon number of 6 to 22,

R17是-H或者碳數為1〜22之烷基， A7分別獨立為·0-或者碳數為1〜6之亞烷基。上述通式（XIII)中，2個胺基分別鍵結於苯環碳上，較好的是相對於A7而鍵結於間位或者對位。通式（XIII)所示之二胺，例如可列舉式（XIII-1)〜式（XIII-9)所示之二胺。 [化 65]R17 is -H or an alkyl group having 1 to 22 carbon atoms, and each of A7 is independently -0- or an alkylene group having 1 to 6 carbon atoms. In the above formula (XIII), the two amine groups are bonded to the benzene ring carbon, respectively, and it is preferably bonded to the meta or para position with respect to A7. The diamine represented by the formula (XIII) may, for example, be a diamine represented by the formula (XIII-1) to the formula (XIII-9). [Chem. 65]

74 200835754 zozupii.doc74 200835754 zozupii.doc

[化 66][化66]

上述式（XIII-1)〜式（XIII-3)中，R24較好的是-Η、碳數為1〜20之烷基，式（ΧΙΙΙ-4)〜式（ΧΙΙΙ-9)中，R25 更好的是-Η、碳數為1〜1〇之烧基。 ^上述通式（XIV)中，2個胺基分別鍵結於苯環碳上，較好的是相對於A7而鍵結於間位或者對位。 75 200835754 upif.docIn the above formula (XIII-1) to formula (XIII-3), R24 is preferably -Η, an alkyl group having 1 to 20 carbon atoms, and a formula (ΧΙΙΙ-4)~(ΧΙΙΙ-9), R25 More preferably, it is a ruthenium having a carbon number of 1 to 1 Torr. In the above formula (XIV), the two amine groups are bonded to the benzene ring carbon, respectively, and it is preferably bonded to the meta or para position with respect to A7. 75 200835754 upif.doc

[化 67] X I v- 1 R26 R27[Chem. 67] X I v- 1 R26 R27

nh2 Χϊν—2 R26 R27Nh2 Χϊν—2 R26 R27

H2NH2N

nh2 式（XIV_1)〜式（XIV_3)中夕古她Iy τ ’ K是石炭數為2〜30 =基〇此:中較好的是碳數為6〜2〇之燒基，r27是碳〜基等中更好的是·Η或者碳數為卜 ^上述，本發财可用的二胺（b2)，例如可使用通式 ^〜通以XIV)所示之二胺，也可使用此等二胺以Nh2 Formula (XIV_1)~Formula (XIV_3) 中夕古 I I τ 'K is a charcoal number of 2~30 = 〇〇: This is preferably a carbon number of 6~2〇, and r27 is carbon~ It is more preferable that the base or the like is Η or the carbon number is the above. The diamine (b2) which can be used for the present invention, for example, the diamine represented by the formula (XIV) can be used, and these can also be used. Diamine

I —胺。/列如可單獨使用具有萘結構的萘系二胺、具有構的第系二胺、或者具有矽氧烷鍵的矽氧烷系二胺等’ ^者將此等二胺與其他二胺混合使用。石夕氧燒系二胺並無特別限定，本發明中可較好地使用下述式（XV)所示者。 [化 68] ψ R3 H2fsMR5V(予卜〇Y+-(r5}^nh2 (XV) 3 R4 R4 式中’ R3及R4獨立是碳數為1〜3之烷基或者苯基， 76 200835754 ζ,υζ, i ^pif.doc R5獨立是亞甲基、立為1〜6之整數、苯基，x獨 1〜15之整數。之I數。其中，y更好的是 [化 69] 式（18)所示之二胺 13I - amine. / Columns such as a naphthalene type diamine having a naphthalene structure, a t-type diamine having a structure, or a decane-based diamine having a decane bond, etc. may be mixed with other diamines. use. The diarrhea-based diamine is not particularly limited, and those represented by the following formula (XV) can be preferably used in the present invention.化 R3 H2fsMR5V ( 予〇 Y+-(r5}^nh2 (XV) 3 R4 R4 where R3 and R4 are independently alkyl or phenyl having a carbon number of 1 to 3, 76 200835754 ζ,υζ , i ^pif.doc R5 is independently a methylene group, an integer of 1 to 6, an phenyl group, and an integer of x 1 to 15. The number of I. Among them, y is more preferably [Chem. 69] ) the diamine 13 shown

述式ΐ:的ί本發明中可用的二胺⑽可使用下ΐ: ί The diamine (10) usable in the present invention can be used

書的二胺I，於本發明的二胺㈤）並不蚊於本說明種形態的二Z現本發明之目的之範_也可使用其他各或者用於本發明的二胺（b2)可單獨使用-種， :可蔣卜:專於2種組合使用。即，大於等於2種的电人疋字t胺彼此組合使用，將上述二胺與其等以外二 77 200835754 ζ,υζ, l ^pif.doc 二胺組合使用，或者將上述二胺以外的二胺彼此組合使用。另外，根據噴墨墨水的用途而要求高透明性，此種情況下，尤其好的是使用3,3’_二胺基二苯砜及通式（XV)中 y=l〜15之整數的二胺。The diamine I of the book, the diamine (5) of the present invention is not a mosquito of the present invention. The purpose of the present invention is also to use other diamines (b2) for use in the present invention. Used alone - can be used in two combinations. That is, two or more kinds of electroacoustic t-amines are used in combination with each other, and the above-mentioned diamine is used in combination with the other two or more of the above-mentioned diamines, or a diamine other than the above diamines. Use in combination with each other. Further, high transparency is required depending on the use of the inkjet ink. In this case, it is particularly preferable to use 3,3'-diaminodiphenyl sulfone and an integer of y = 1 to 15 in the formula (XV). Diamine.

本發明中可用的單胺（b3)並無特別限定，具體例可列舉：3-胺丙基三曱氧基矽烷、3-胺丙基三乙氧基矽烷、 3-胺丙基甲基二甲氧基矽烷、3_胺丙基曱基二乙氧基矽烧、4-胺丁基三曱氧基矽烷、4_胺丁基三乙氧基矽烷、4_ 胺丁基曱基二乙氧基矽烷、對胺基苯基三曱氧基矽烷、對胺基苯基三乙氧基矽烷、對胺基苯基甲基二曱氧基矽烷、對胺基苯基甲基二乙氧基矽烷、間胺基苯基三甲氧基矽烷 f間胺基苯基曱基二乙氧基矽烷、2_胺基苯曱酸、3_胺基苯曱酸、‘胺基苯曱酸、單乙醇胺、正丁胺、苯胺等。曰就所得的膜的耐久性優異之方面而言，此等中較好的是^胺丙基三曱氧基矽烷、3·胺丙基三乙氧基矽烷、對胺基苯基二^氧基矽烷，尤其好的是3_胺丙基三乙氧基矽烷。此等單胺也可單獨使用一種或者將大於等於二種組合使用。酐基的化合物. 本發财可㈣具有—個酸酐基的化合物（⑷並益二限可列舉：對(三甲氧基魏基)苯基_ t 絲)苯基琥_酐、間(三甲氧基石夕基)本基_酸酐、間(三乙氧基魏基)苯基_ 78The monoamine (b3) usable in the present invention is not particularly limited, and specific examples thereof include 3-aminopropyltrimethoxy decane, 3-aminopropyltriethoxydecane, and 3-aminopropylmethyldi Methoxy decane, 3-aminopropyl decyl diethoxy oxime, 4-aminobutyl trimethoxy decane, 4-aminobutyl triethoxy decane, 4-aminobutyl decyl diethoxy Base decane, p-aminophenyl trimethoxy decane, p-aminophenyl triethoxy decane, p-aminophenyl methyl decyl decane, p-aminophenyl methyl diethoxy decane , m-aminophenyltrimethoxydecane f-aminophenyl fluorenyl diethoxy decane, 2-aminobenzoic acid, 3-aminobenzoic acid, 'aminobenzoic acid, monoethanolamine, N-butylamine, aniline, etc.曰 In terms of excellent durability of the obtained film, preferred among these are ethinyl tridecyloxydecane, 3·aminopropyltriethoxydecane, and p-aminophenyloxyxo Particularly preferred is quinoxanes, which are 3-aminopropyltriethoxydecane. These monoamines may also be used singly or in combination of two or more. Anhydride-based compound. The present invention can be used as a compound having an acid anhydride group ((4) and the second is limited to: p-(trimethoxyweiyl)phenyl-t-filament) phenylsuccinic anhydride, m-trimethoxy Base group 本 base acid anhydride, m-(triethoxyweiyl)phenyl _ 78

200835754 z,uz,i^pif.d〇C 二甲氧基魏基丙基琥_酐、三乙氧基械基丙基號雖酸酐等。一，墨水的保存穩定性之方面而言，此等中尤其好的是二曱氧基魏基丙総_酐、三乙氧基雜基丙基坡轴酸酐。此等具有一個酸酐基的化合物也可單獨使用一種或者將大於等於二種組合使用。胺酸的反應倐件可用於本發明的聚醯胺酸，例如可使選自由單胺（b3) 與具有一個酸酐基的化合物（b4)所構成的化合物之族群的大於等於一種化合物、與具有大於等於2個酸酐基的化合物（M)、以及二胺（b2)進行反應而合成。使用單胺（b3)之情況下，較好的是相對於丨莫耳具有大於等於2個酸酐基的化合物（bl)，而使用〇〇1'莫& 〜0·8莫耳二胺（b2)及0.4莫耳〜ι·98莫耳單胺（b3、），更好的是相對於1莫耳具有大於等於2個酸酐基的化合物 (M)，而使用〇·15莫耳〜〇·25莫耳二胺（b2)及^莫耳〜1.7莫耳單胺（b3)。 ·吴使用具有一個酸酐基的化合物（b4)之情況下，較好的是相對於1莫耳二胺（b2)，而使用0.01莫耳〜〇·8莫耳具有大於等於2個酸酐基的化合物（bl)及〇·4莫耳〜丨、％莫耳具有一個酸酐基的化合物（b4)，更好的是相對於一耳二胺（b2)，而使用0·15莫耳〜0.25莫耳具有大於等於 2個酸酐基的化合物（bl)及1.5莫耳〜1/7莫耳具有_個 79 200835754 二 wjji_f.doc 酸酐基的化合物（b4)。 2·5·1反應溶劑至少使用具有大於等於2個酸酐基的化合物（bl )、二胺（b2)、單胺（b3)以及具有一個酸酐基的化合物（b4) 而獲得聚酿胺酸’為此可用的溶劑若可合成該化合物，則並無特別限定，例如可列舉：二乙二醇二甲醚、二乙二醇一***、二乙二醇甲基***、二乙二醇單***乙酸酯、乙 -醇單乙_乙酸I旨、丙二醇單㈣乙酸酯、3甲氧基丙酸曱§曰'3_乙氧基丙酸乙酿、環己嗣、^丁内醋、Nm 吡咯，酮、及N，N-二甲基乙醯胺等。匕右2用此等中的丙二醇單曱醚乙酸酯、3_甲氧基丙酸甲酉曰、、％己酮、二乙二醇甲基***及二乙二醇二甲鍵，則叮‘成對墨頭的損；^較少的墨水，因此較好。此等反應料何單獨㈣，也可作為大於等於2種的 ❹。另外’除上述反應溶劑以外，也可混合他溶劑而使用。 r」目對^具妓於等於2個酸酐基的化合物（b3 )、二胺簡_綱（Μ)的合 :，因此較好。反應較好的是於叱〜靴下進订0.2小時〜2〇小時。順序定。即，可料的反應系的添加順序並無特別限使用如下任—種方法：同時向反應溶劑添加具 200835754 jjif.doc 有大於等於2個酸酐基的化合物（bl)、二胺（b〕）、單胺 (b3)以及具有一個酸酐基的化合物（b4);使二胺（匕2) 與單胺（b3)溶解於反應溶劑中後，添加具有大於等於2 個酸酐基的化合物（M)或者添加具有大於等於2個酸酐基的化合物（bi)與具有一個酸酐基的化合物（b4);使具有大於等於2個酸酐基的化合物（bl)與具有一個酸酐基的化合物（b4)溶解於反應溶劑中後，使單胺（b3)預先反應後，添加二胺（b2);使具有大於等於2個酸酐基的化合物（bl)與二胺（b2)預先反應合成共聚物後，向該丘聚物添加單胺（b3)等。 /' 分子化合物（B)的會量平均公子景、重量平均分子量為1，000〜20,000的高分子化合物（B) 尤其對溶劑的溶解性優異，因此作為噴墨墨水而較好。本發明中，為了進一步提昇高分子化合物（B)對溶劑的「溶解性」’其重量平均分子量較好的是1，000〜10,000,更好的是 1,000〜5,000。馨、並且尤其好的是高分子化合物（B)的重量平均分子 f為1，000〜2,〇〇〇。原因在於：具有大於等於_〇之重，平均分子量的高分子化合物⑻，藉由加熱處理而不會洛發，化學性、機械性穩定；具有2，⑻〇以下之重量平均分子量的高分子化合物（B)，可提昇對於溶劑的溶解性，因此2大所獲得的塗膜之膜厚，可較好地用作喷墨墨水。、、同刀子化合物（B)的重量平均分子量可利用凝膠滲透層析（gd-permeation chr〇mat〇gmphy，Gpc )法而測定。 81 200835754 ± ^pif.doc 具體而言可藉由如下方式而求得，以四氫吱喃（TH 將所獲得的高分子化合物⑻稀釋成濃度約達到i wt%寺使用東曹（Tosoh)股份有限公司製造之管柱G4〇〇〇Hx G3000HXL、G2500HXL 及 G2〇〇〇hxl，以 Thf 、利用凝膠滲透層析（CTO法進行測定，並進行料2 換算。邱 3溶劑（C)200835754 z, uz, i^pif.d〇C Dimethoxyweipropylpropyl succinic anhydride, triethoxyoctyl propyl number, etc. First, in terms of storage stability of the ink, particularly preferred among these are dimethoxy-propionyl-propanoid anhydride and triethoxyheteropropyl-based anhydride. These compounds having an acid anhydride group may also be used singly or in combination of two or more. A reaction reagent of an amine acid can be used for the poly-proline acid of the present invention, for example, a compound selected from the group consisting of a compound composed of a monoamine (b3) and a compound (b4) having an acid anhydride group, or more The compound (M) having two acid anhydride groups or more and the diamine (b2) are reacted and synthesized. In the case of using a monoamine (b3), it is preferred to use a compound (b1) having 2 or more acid anhydride groups with respect to the oxime, and to use 〇〇1'Mo & 0.8 montane diamine ( B2) and 0.4 moles to ι·98 mole monoamine (b3,), more preferably compound (M) having 2 or more acid anhydride groups per mole, and 〇15 moles to 〇 25 moles of diamine (b2) and ^ moles to 1.7 moles of monoamine (b3). In the case where a compound (b4) having an acid anhydride group is used, it is preferred to use 0.01 mol/〇8 mol with or less than 2 acid anhydride groups with respect to 1 mol of diamine (b2). Compound (bl) and 〇·4 Moer~丨, % More has an anhydride group-based compound (b4), more preferably relative to the mono-diamine (b2), but uses 0.15 mol to 0.25 mo The ear has a compound (b1) of 2 or more acid anhydride groups and 1.5 mol% to 1/7 mol of a compound (b4) having an acid anhydride group of 79 200835754 and 2 wjji_f. 2.5.1 Reaction solvent At least a compound (b1) having two or more acid anhydride groups, a diamine (b2), a monoamine (b3), and a compound (b4) having an acid anhydride group are used to obtain a poly-branched acid. The solvent which can be used for the synthesis of the compound is not particularly limited, and examples thereof include diethylene glycol dimethyl ether, diethylene glycol monoethyl ether, diethylene glycol methyl ether, and diethylene glycol monoethyl ether. Acetate, ethyl alcohol monoethyl-acetic acid I, propylene glycol mono (tetra) acetate, 3 methoxypropionic acid 曱曰曰 '3 _ ethoxy propionic acid ethyl, cyclohexyl, ^ butyl vinegar, Nm pyrrole, ketone, and N,N-dimethylacetamide.匕Right 2 uses propylene glycol monoterpene ether acetate, 3-methoxypropionate formazan, % ketone, diethylene glycol methyl ether and diethylene glycol dimethyl bond. 'The loss of the pair of ink heads; ^ less ink, so better. These reactions can be used alone (4) or as two or more types. Further, in addition to the above reaction solvent, a solvent may be mixed and used. It is preferable that r" is a combination of a compound (b3) having two acid anhydride groups and a diamine group. The better reaction is to order under 叱~boots for 0.2 hours to 2 hours. The order is fixed. That is, the order of addition of the reactive reaction system is not particularly limited to the use of any of the following methods: simultaneously adding a compound (b1) or a diamine (b) having two or more acid anhydride groups of 200835754 jjif.doc to the reaction solvent. a monoamine (b3) and a compound (b4) having an acid anhydride group; and after dissolving the diamine (匕2) and the monoamine (b3) in a reaction solvent, adding a compound (M) having two or more acid anhydride groups Or a compound (bi) having 2 or more acid anhydride groups or more and a compound (b4) having an acid anhydride group; and a compound (b) having 2 or more acid anhydride groups and a compound (b4) having an acid anhydride group are dissolved in After reacting the solvent, the monoamine (b3) is preliminarily reacted, then the diamine (b2) is added; and the compound (b1) having two acid anhydride groups or more and the diamine (b2) are reacted in advance to form a copolymer, and then The monolayer is added with a monoamine (b3) or the like. The polymer compound (B) having a weight average molecular weight of the molecular compound (B) and a weight average molecular weight of 1,000 to 20,000 is particularly excellent in solubility in a solvent, and therefore is preferable as an inkjet ink. In the present invention, the weight average molecular weight of the polymer compound (B) to the solvent is preferably from 1,000 to 10,000, more preferably from 1,000 to 5,000. It is particularly preferred that the polymer compound (B) has a weight average molecular weight f of 1,000 to 2, 〇〇〇. The reason is that the polymer compound (8) having an average molecular weight of ≥ 〇 or more is not chemically and mechanically stable by heat treatment; and a polymer compound having a weight average molecular weight of 2, (8) 〇 or less (B), since the solubility in a solvent can be improved, the film thickness of the coating film obtained in two is excellent as an inkjet ink. The weight average molecular weight of the same knife compound (B) can be measured by a gel permeation chromatography (gd-permeation chr〇mat〇gmphy, Gpc) method. 81 200835754 ± ^pif.doc Specifically, it can be obtained by diluting the obtained polymer compound (8) into a concentration of approximately about i wt% by using tetrahydrofuran (TH) to use Tosoh shares. The column G4〇〇〇Hx G3000HXL, G2500HXL and G2〇〇〇hxl manufactured by the company are measured by gel permeation chromatography (CTO method and converted to material 2) by Thf. Qiu 3 solvent (C)

本發明之喷墨墨水例如可將經烯基取代之耐地醯亞胺化合物（A)、視需要的高分子化合物（B)溶解於溶劑（〇而獲得。因此，本發明之噴墨墨水中所含的溶劑，若為可溶解經烯基取代之耐地醯亞胺化合物（A)、視需要的高分子化合物（B)的溶劑，則並無特別限定。另外，即使單獨不溶解經烯基取代之耐地醯亞胺化合物（A)、視需要的高分子化合物（B)的溶劑，也可與其他溶劑混合，籍此用作喷墨墨水中所含的溶劑（C)。喷墨墨水中所含的溶劑（C)之具體例，可列舉曱基·2·吼咯烷酮、二曱基咪唑啉酮（dimethyl imidazolidinone )、N-甲基己内醢胺、N-甲基丙醯胺、n，N- 二甲基乙醯胺、二甲亞石風、N，N-二甲基甲醢胺、n，N-二乙基甲醯胺、二乙基乙醯胺、γ-丁内酯、乳酸乙酯、3_甲基_3_ 甲氧基丁醇、萘滿、異佛酮（isophorone)、乙二醇單丁醚、二乙二醇單***、二乙二醇單***乙酸酯、二乙二醇二甲醚、二乙二醇甲基***、三乙二醇單***、丙二醇單丁醚、丙二醇單甲醚乙酸酯、二丙二醇單甲醚、3_甲氧基丙酸甲 82 ^jjif.doc 200835754 乙醇、2_丙醇酉曰、3-乙氣基丙酸乙一 s ^ 乙酉曰、丙二酸二乙酯 -一％燒、乙二醇等。有時喷墨雖合部件或者内=ead)的規格不同，劑的種類不_發過濾、器材料因所使用的溶 = 因此溶劑(C)的選擇非常重要。昇或者嘴頭堵塞、墨於=的耐久性提酉旨、乙二醇單丁峻、面’尤其好的是乳酸乙一 —乙一知早***乙酸酯、二乙二醇二一乙二醉甲基***、丙二醇單甲醚乙_旨、3-甲氧基丙酸曱酯、γ-丁内酯作為溶劑（c)。墨水的表面張力對噴墨墨水的塗佈性造成較大衫曰，因此將墨水的表面張力調整為20〜45 mN/m、較好的是27〜42mN/m、更好的是3〇〜4〇mN/m。若表面張力纽45 mN/m ’則墨水喷出口的墨水彎液面（meniscus ) 不穩定而無法喷ϋΜ水DHN/m，職佈的液滴擴散而使塗佈圖案的形狀較大惡化。為了將表面張力調整為2〇〜45 mN/m的範圍，溶劑選擇較重要。可使用表面張力處於2〇mN/m〜45mN/m的範圍的一種溶劑，若將表面張力較大的溶劑（例如，丁内酯· 43 mN/m)及表面張力較小的溶劑（例如，二乙二醇曱基***：24 mN/m、或者乙二醇單丁醚·· 32 mN/m)混合使用，則可藉由溶劑組合來微調表面張力，因此較好。 83 200835754The inkjet ink of the present invention can be obtained, for example, by dissolving an alkenyl-substituted ruthenium imine compound (A) and an optional polymer compound (B) in a solvent. Thus, in the inkjet ink of the present invention The solvent to be contained is not particularly limited as long as it is a solvent capable of dissolving the alkenyl substituted imide imine compound (A) and, if necessary, the polymer compound (B). The base-substituted quinone imine compound (A) and the solvent of the polymer compound (B) as needed may be mixed with other solvents, and used as a solvent (C) contained in the inkjet ink. Specific examples of the solvent (C) contained in the ink include mercapto·2·pyrrolidone, dimethyl imidazolidinone, N-methylcaprolactam, and N-methylpropyl. Indoleamine, n,N-dimethylacetamide, dimethyl sulphate, N,N-dimethylformamide, n,N-diethylformamide, diethylacetamide, γ - Butyrolactone, ethyl lactate, 3-methyl_3_methoxybutanol, tetralin, isophorone, ethylene glycol monobutyl ether, diethylene glycol monoethyl , diethylene glycol monoethyl ether acetate, diethylene glycol dimethyl ether, diethylene glycol methyl ether, triethylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol monomethyl ether acetate, dipropylene glycol single Methyl ether, 3-methoxypropionic acid A 82 ^jjif.doc 200835754 Ethanol, 2-propanol oxime, 3-ethyl propyl propionate ethyl s ^ acetamidine, diethyl malonate - one% burning, Ethylene glycol, etc. In some cases, the type of the ink is different depending on the type of the ink jet or the inner part = ead. The type of the agent is not filtered, and the material used is the solution. Therefore, the choice of the solvent (C) is very important. Lit or mouth clogging, ink in the durability of the purpose of the purpose, ethylene glycol single Ding Jun, the surface 'especially good lactic acid E-B Yizhi early ether acetate, diethylene glycol di-Ethylene dilute Ethyl ether, propylene glycol monomethyl ether, methoxy 3-methoxypropionate, γ-butyrolactone as solvent (c). The surface tension of the ink causes a large coat on the coatability of the inkjet ink, so the surface tension of the ink is adjusted to 20 to 45 mN/m, preferably 27 to 42 mN/m, more preferably 3 〇. 4〇mN/m. If the surface tension is 45 mN/m ', the ink meniscus of the ink discharge port is unstable and the water DHN/m cannot be squirted, and the droplets of the service cloth are diffused to deteriorate the shape of the coating pattern. In order to adjust the surface tension to a range of 2 〇 to 45 mN/m, solvent selection is more important. A solvent having a surface tension in the range of 2 〇 mN/m to 45 mN/m can be used, if a solvent having a large surface tension (for example, butyrolactone 43 mN/m) and a solvent having a small surface tension (for example, When diethylene glycol decyl diethyl ether: 24 mN/m or ethylene glycol monobutyl ether · 32 mN/m is used in combination, it is preferable to finely adjust the surface tension by a solvent combination. 83 200835754

1 ^pi£d〇C 另外，Ν-甲基曱醯胺、风队二甲基甲醯胺、Ν，Ν-二乙基甲醯胺、乙醯胺、Ν-甲基乙醒胺、Ν，Ν_:甲基乙酿胺、二乙基乙《、队甲基丙醯胺、Ν，Ν，Ν、Ν，_四甲基脲、2_ 吡咯燒酮、Ν-甲基-2-吡咯烷酮、ε_己内醯胺、N—曱基己内 «、胺甲酸轉_系溶劑，是經烯基取代之耐地醯亞胺化合物（Α)或者冑分子化合物⑻的良賴，因此可較好地使用，另—方面，需要注意喷墨頭難以耐久。1 ^pi£d〇C In addition, Ν-methyl decylamine, wind dimethylformamide, hydrazine, hydrazine-diethylformamide, acetamidine, hydrazine-methyl amide, hydrazine , Ν_: methyl ethylamine, diethyl b, "methyl propyl amide, hydrazine, hydrazine, hydrazine, hydrazine, _ tetramethyl urea, 2 - pyrrolidone, hydrazine - methyl-2-pyrrolidone, ε_Caprolactam, N-mercaptohexyl«, aminic acid conversion solvent, which is a good resistance to an alkenyl substituted imide compound (Α) or a hydrazine molecular compound (8), so it is better Ground use, on the other hand, it is necessary to pay attention to the difficulty of the inkjet head.

較好的是於本發明之喷墨墨水中所含的溶劑（c)中，完全不含有醯㈣溶劑，或者即使含有較㈣胺系溶劑但其相對於溶劑（c)的總重量為2Gwt%或2Qwt%以下。此等溶劑可僅使用一種，另外，也可將大於等於二種混合使用。夂物CA) 匕合物（B)的5詹疫本發財噴墨墨水巾的經烯基取代之耐祕亞胺化合物（A)❺濃度並無特別限定，較好的是1 wt%〜99 wt%， ^Tr80 wt%22 wt%^7°wt% ° 〜^。/。。若為^ ^ ΓΓ 更好的是0 wt% 性，因此較好。4 緣膜可獲得良好的特用作喷墨墨水之情況下，經稀基取代之耐地醯亞胺化 84 200835754 及高分子化合物⑻的濃辆高，朗獲得的也t=:膜厚越厚？此較好’另-方面，存在黏度題。本發因此料產生㈣印刷機無法喷出的問、農人努力研究之結果發現：若尤其是上述的的;=水可較好地用作可形成膜厚較大的《亞胺膜墨水It is preferred that the solvent (c) contained in the inkjet ink of the present invention contains no ruthenium (iv) solvent at all, or even if it contains a (four) amine solvent, it is 2 Gwt% based on the total weight of the solvent (c). Or 2Qwt% or less. These solvents may be used alone or in combination of two or more. The concentration of the alkenyl substituted anti-imine compound (A) of the sputum compound (B) is not particularly limited, and is preferably 1 wt% to 99. Wt%, ^Tr80 wt% 22 wt%^7°wt% ° ~^. /. . If ^ ^ 更好 is better than 0 wt%, it is better. 4 When the edge film is good, it can be used as a good inkjet ink. The rare earth-substituted yttrium imidization 84 200835754 and the high molecular weight of the polymer compound (8) are also obtained by t: the film thickness is higher. thick? This is better. In other respects, there is a viscosity problem. The present invention therefore produces (4) the inability of the printing machine to spray out, and the results of the research conducted by the farmers have found that: especially the above; = water can be preferably used as an imine film ink which can form a large film thickness.

物墨墨水疋㈣烯基取代之耐地㈣胺化合要的高分子化合物⑻、視需要的溶劑⑹ 方式：，之噴墨面活性劑、擇添加環氧翻旨、丙烯酸編旨、界 Ξί^-Γ ^ 聚合物等添加劑=二父2進劑、螯合劑、水溶性 ⑴環均勻並溶解。本發明之噴墨墨水進而墨墨水中所含的環氧 =_脂。本發明之噴限定，較好的有料乙烧，則並無特別本發明=$有大於雜2個魏乙誠化合物。定，較好的是G1’、3中=環^m的濃度並無特別限 wt%。若為該潭二 wt%，更好的是1謂>〜1〇性、财化轉柄彡成驗膜的耐熱 85 200835754 ^u^i^pif.doc 壤氧樹腊例如可列舉：雙酚A刑酯型環氧翻旨、鱗式環氧樹脂、==脂、縮水甘油具有乙燒的單體與其他單體之共聚物等。縮水甘油(甲基）丙烯酸酸甲基縮^；由酉f丙沐輝環氧環己酉旨、及(甲基)丙浠之具n Hi 3m單f進行共聚合的其他單體基)丙烯酸乙酿、V:二：巧：甲基)丙浠酸甲醋、(甲醋、(甲基炳烯酸:; 丙嬌醅瑗p狀，、（曱基）丙烯酉夂弟三丁酯、（甲基）酉旨、（甲A) @曰、（Λ甲基)丙烯酸¥酯、（甲基)丙烯酸2-經基乙甲m 錄義、苯㈣、甲基苯乙浠、氯 N_$己其ίΒ 7基）丙烯酸(3_乙基氺氧雜環丁基）甲酯、 "且二;ί—、丁烯二醯亞胺'苯基順丁烯二醯亞胺等。 =::=:==== 物n Γ基丙烯酸甲§旨_甲基丙稀酸縮水甘油酯共聚 / 土丙烯酸苄酯·甲基丙烯酸縮水甘油酯共聚物、甲美 2丙稀，正丁醋_甲基丙烯酸縮水甘油醋共聚物、曱基丙烯酸 =土乙醋-甲基丙烯酸縮水甘油醋共聚物、甲基丙烯酸(3_ 雜環了基)甲酯_ψ基丙烯酸縮水甘㈣共聚物及 ^由甲基丙烯酸縮水甘油酯共聚物。若本發明之喷墨墨 ^含有轉縣樹脂，難噴墨墨水形成的塗膜的耐熱性達到良好，因此較好。 86Ink ink 疋 (4) Alkenyl substituted for resistance to ground (IV) Amine compounding polymer compound (8), if necessary solvent (6) Method:, inkjet surfactant, optional epoxy, acrylic, and Ξ -Γ ^ Additives such as polymers = secondary parent 2, chelating agent, water-soluble (1) ring is homogeneous and soluble. The inkjet ink of the present invention, in turn, contains epoxy =_lips contained in the ink. The spray limit of the present invention, preferably B-burning, is not particularly the present invention = $ has more than 2 Wei Yicheng compounds. Preferably, the concentration of G1' and 3 = ring ^m is not particularly limited to wt%. If it is the wt% of the pool, it is better that the 1 is >~1〇, the heat of the chemical processing is reduced to the heat resistance of the membrane 85 200835754 ^u^i^pif.doc Phenol A phenolic epoxy, scale epoxy resin, == grease, glycidol, copolymer of ethylenic monomer and other monomers. Glycidyl (meth) acrylate acid methyl condensate; other monomeric group which is copolymerized by 酉f propyl oxime epoxy ring and (meth) propyl oxime with n Hi 3m single f) B, V: 2: Qiao: methyl) methyl acetal, (methyl vinegar, (methyl aceenoic acid:; chlorpyrifos p-like, bismuth-based) propylene triterpene, (methyl) 酉, (A A) @曰, (Λ methyl) acrylate, ester, (meth)acrylic acid 2- via benzyl group m, benzene (tetra), methyl phenyl hydrazine, chlorine N_$ It has 7 bases) (3_ethyloxa oxetanyl) methyl acrylate, "and 2; ί-, butenylene diimide 'phenyl cis-butenylene imine, etc. =: :=:==== 物 Γ Γ 丙烯酸丙烯酸 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Glycidyl methacrylate copolymer, thioglycol=ethethacetate-glycidyl methacrylate copolymer, methacrylic acid (3_heterocyclyl)methyl ester-mercapto-acrylic acid glycidyl (tetra) copolymer and Glycidyl methacrylate copolymer. Ming ink jet ink containing genetically ^ County resin, the heat resistance of the coating film is difficult to achieve good ink-jet ink is formed, so this is preferred. 86

200835754“ 1 ^piI.QOC 本發明之喷墨墨水中可含的環氧樹脂之具體例，可列舉：商品名「Epikote807」、「Epikote815」、「Epikote825」、「Epikote827」、「Epikote828」、「Epikotei90P」、「Epikote 19IP」（以上由油化殼牌環氧股份有限公司（Yuka200835754" 1 ^ piI. QOC Specific examples of the epoxy resin which can be contained in the inkjet ink of the present invention include "Epikote 807", "Epikote 815", "Epikote 825", "Epikote 827", "Epikote 828", and " Epikotei90P", "Epikote 19IP" (above by Oiled Shell Epoxy Co., Ltd. (Yuka

Shell Epoxy Co”Ltd·)製造），商品名「Epikotel004」、「Epikotel256」（以上由日本環氧樹脂股份有限公司（JapanShell Epoxy Co" Ltd.), trade name "Epikotel004", "Epikotel256" (above by Japan Epoxy Resin Co., Ltd. (Japan)

Epoxy Resins Co”Ltd)製造），商品名「AralditeCYl77」、商品名「AralditeCY184」（日本汽巴嘉基股份有限公司 (Ciba-geigy Corporation )製造），商品名「Celloxide2〇21P」、「Celloxide3000」、「EHPE-3150」（大賽路化學工業股份有限公司（Diacel Chemical Industries) 製造），商品名「TechmoreVG3101L」（三井化學股份有限公司製造），Ν,Ν,Ν’,Ν’-四縮水甘油基-間二曱苯二胺、L3-雙(Ν，Ν·二縮水甘油基胺基曱基)環己烧、ν，Ν，Ν，，Ν’_四縮水甘油基-4,4’_二胺基二苯基甲烷等。因所獲得的聚醯亞胺膜的平坦性尤其好，因此此等中’較好的是商品名「AralditeCY184」、商品名「Celloxide2021P」、商品名「TechmoreVG3101L」、商品名「Epikote828」。環氧樹脂可僅使用一種，另外，也可將大於等於二種混合使用。 (2)丙烯酸系樹脂本發明之喷墨墨水進而可含有丙烯酸系樹脂。噴墨墨水中所含的丙烯酸系樹脂若具有丙烯基或者曱基丙烯基， 87 200835754^Epoxy Resins Co" Ltd.), trade name "AralditeCYl77", trade name "AralditeCY184" (manufactured by Ciba-geigy Corporation), trade name "Celloxide2〇21P", "Celloxide3000", "EHPE-3150" (manufactured by Diacel Chemical Industries), trade name "TechmoreVG3101L" (manufactured by Mitsui Chemicals, Inc.), Ν, Ν, Ν', Ν'-tetraglycidyl- Di-p-phenylenediamine, L3-bis(indole, Ν·diglycidylamino)cyclohexane, ν,Ν,Ν,,Ν'_tetraglycidyl-4,4'-diamine Diphenylmethane and the like. Since the flatness of the obtained polyimide film is particularly good, the product name "Araldite CY184", the trade name "Celloxide 2021P", the trade name "Techmore VG3101L", and the trade name "Epikote 828" are preferable. Epoxy resins may be used alone or in combination of two or more. (2) Acrylic resin The inkjet ink of the present invention may further contain an acrylic resin. In the inkjet ink, if the acrylic resin contained in the water has a propenyl group or a mercaptopropenyl group, 87 200835754^

i ^pil. OOC 則並無特別限定。㈣了fft/中的，丙烯酸系樹脂的濃度並無特別限定，較，1 wt〇/^10 wt% ° ^ 丙列舉:具有的單官能聚合性 - /、歹工土的單g能聚合性單體、二官能 •職能的多官能（甲基㈣酸醋ί。基)丙婦酸S基具體例，可列舉：（甲丙烯酸4他醋、4甲酸醋等。就所形成的膜羊軟之：己院二甲醇單(甲基)丙稀丙浠酸4德丁而言，其中尤其好的是不具有絲的單官能甲基氧雜環丁烧、3-乙基_3 ^甲基^(甲基)丙稀酸氧基丁院、3-甲基-3·(甲基)丙‘氧釀氧基甲基氧雜環基:·㈣㈣_基乙基氧雜射=二丁 =乙基氧雜環丁烧、2-三氣甲\ T甲基其_(甲基)丙烯醮氧基甲 -、_丙烯酸、(甲基 (甲基)丙騎異丙酷、(甲基)㈣酸丁 = 二乙:異 88 200835754 二\/厶 upUoc 其二二三丁醋、（甲基）丙婦酸環己酿、（甲i ^pil. OOC is not specifically limited. (4) In the fft/, the concentration of the acrylic resin is not particularly limited, and is 1 wt〇/^10 wt% ° ^. C. Listed: monofunctional polymerizability - /, single g polymerizable property of the masonry soil Specific examples of the monomeric, difunctional and functional polyfunctional (methyl (tetra) acid vinegar ketone) propyl acetoate S group can be exemplified by: (methacrylic acid 4 vinegar, 4 formic vinegar, etc. In the case of hexamethylene dimethicone mono(methyl)propionate 4 debutin, especially preferred is monofunctional methyloxetane, 3-ethyl-3-3 methyl group without silk ^(Methyl)acrylic acid oxybutyl, 3-methyl-3.(methyl)propyl'oxy-oxymethyloxycarbonyl: (IV) (IV) _ yl ethyl oxazepine = dibutyl = Ethyloxetane, 2-trisole, T-methyl, _(methyl)propenyloxymethyl-, _acrylic acid, (methyl(methyl)propene, isopropyl, (methyl) (4) Acid Ding = Diethyl: Different 88 200835754 Two \/厶upUoc Its 222 butyl vinegar, (methyl) propyl benzoic acid ring, (A

苯乙烯、甲基苯乙烯、氯甲基苯乙埽、J 基_3_氧雜環丁基）fg旨、Ν_環己基順丁 J 亞胺、Ν-本基順丁烯二酿亞胺、乙稀基 =(Λ基)丙稀酸三環[，Styrene, methylstyrene, chloromethylacetophenone, J-based _3_oxetanyl)fg, Ν_cyclohexyl cis-butanimide, fluorene-benzyl butylene iminoimine , ethylene group = (fluorenyl) acrylic acid tricyclic [,

-曰’由早（甲基）丙烯酸酯、聚苯乙烯巨單體、聚甲其 :烯酸：酯巨單體、Ν_丙烯醯嗎啉、(曱基)丙烯酸5_四2 °喃甲氧基m基戊醋、月桂醇之環氧乙烧加成物的（甲^ 丙物旨、(甲基)丙烯酸、丁烯酸、α·氯丙烯酸、肉桂酸' 順丁烯二酸、反丁埽二酸、衣康酸（ita_ie add)、檸康酸、(Citraconic acid)、甲基反丁烯二酸（_丁 ω緩基聚己内酯單（甲基）丙烯酸酯、琥珀酸單[2_(甲基）丙 =醯氧基乙基]酯、順丁烯二酸單[2_(曱基)丙烯醯氧基乙基] 酉曰、或者環己烯-3,4-二甲酸單[2-(甲基)丙烯醯氧基乙基]酯等。一官能（曱基)丙埽酸酯之具體例，可列舉：雙盼F環氧乙烷改質二丙烯酸酯、雙酚Α環氧乙烷改質二丙烯酸酉曰、兴二聚氣酸j辰氣乙炫改質二丙烯酸酯、聚乙二醇二丙烯酸酯、聚丙二醇二丙烯酸酯、季戊四醇二丙烯酸酯、季戊四醇二丙烯酸酯單硬脂酸酯、1，4_ 丁二醇二丙稀酸酯、 1，6-己二醇二丙烯酸酯、ι，9-壬二醇二丙浠酸酯、丨，4•環己燒一甲醇二丙烯酸1旨、2-正丁基乙基-ΐ，3·丙二醇二丙埽酸酯、三經甲基丙燒二丙烯酸酯、或者二季戊四醇二丙烯 89 200835754 av/l i 々Af.d〇c 酸酯等。《，於—g此的多官能（甲基）丙烯酸酯之具體例， ·二羥甲基丙烷三（甲基）丙烯酸酯、環氧乙烷改質一爹工:基丙燒二（甲基)丙稀酸酯、環氧丙烧改質三經甲基丙^一（曱基)丙烯酸酯、表氯醇改質三羥曱基丙烷三（曱基) 丙烯酸酯、二(三經曱基丙烧)四（曱基)丙烯酸酯、甘油三（甲基)丙烯酸酯、表氯醇改質甘油三（曱基)丙稀酸醋、二甘油 φ 四（曱基)丙烯酸酯、季戊四醇三（甲基)丙烯酸酯、季戊四醇 =(曱基)丙烯酸酯、二季戊四醇五（曱基)丙烯酸酯、烷基改貝一季戊四醇五（曱基）丙烯酸酯、烷基改質二季戊四醇四 (甲基)、丙烯酸酯、烷基改質二季戊四醇三（甲基)丙烯酸酯、一季戊四醇六（曱基）丙烯酸酯、己内酯改質二季戊四醇六 (曱基)丙烯酸酯、環氧乙烷改質磷酸三（甲基)丙烯酸酯、三 [(曱基)丙烯醯氧基乙基]異氰尿酸酯、己内酯改質三[(甲基) 丙烯醯氧基乙基]異氰尿酸酯、或者（甲基)丙烯酸胺基曱酸酯等。馨此等丙烯酸系樹脂可僅使用一種，另外也可將大於等於二種混合使用。 (3)界面活性劑期望提昇喷墨墨水的塗佈性時，可添加實現該目的之界面活性劑。本發明之噴墨墨水所添加的界面活性劑之具體例，可列舉：商品名「Byk_300」、「Byk-3〇6」、「Byk_335」、「Byk-310」、「Byk-341」、「Byk-344」、「Byk-370」 (BYK-Chemie股份有限公司製造）等矽系界面活性劑； 200835754-曰' from early (meth) acrylate, polystyrene macromonomer, polymethyl ketone: enoic acid: ester macromonomer, Ν _ propylene morpholine, (mercapto) acrylic 5 4 4 2 Ethyl m-pentyl vinegar, lauryl alcohol, ethylene oxide addition product (meth), (meth)acrylic acid, crotonic acid, α·chloroacrylic acid, cinnamic acid, maleic acid, anti Butyric acid, itaconic acid (ita_ie add), citraconic acid, (Citraconic acid), methyl fumaric acid (_ butyl succinyl polycaprolactone mono (meth) acrylate, succinic acid single [2_(Methyl)propane=decyloxyethyl]ester, maleic acid mono[2_(indenyl)propenyloxyethyl]anthracene, or cyclohexene-3,4-dicarboxylic acid single [2-(Methyl)propenyloxyethyl]ester, etc. Specific examples of the monofunctional (fluorenyl)propionate include di-f-ethylene oxide modified diacrylate and bisphenolphthalein. Ethylene oxide modified bismuth diacrylate, dimethyl dimer acid j chen qi yi modified diacrylate, polyethylene glycol diacrylate, polypropylene glycol diacrylate, pentaerythritol diacrylate, pentaerythritol diacrylate Monostearate, 1,4_ Diol diacrylate, 1,6-hexanediol diacrylate, iota, 9-decanediol dipropionate, hydrazine, 4•cyclohexane-methanol diacrylate, 2-n-butyl Ethyl ethyl-hydrazine, 3·propylene glycol dipropionate, tri-methyl propylene diacrylate, or dipentaerythritol dipropylene 89 200835754 av/li 々Af.d〇c acid ester, etc. Specific examples of such a polyfunctional (meth) acrylate, dimethylolpropane tri(meth) acrylate, ethylene oxide upgrading: propylene bis(methyl) acrylate , propylene-acrylic acid modified three-molecular methyl propyl sulfonate, epichlorohydrin modified trihydroxy hydrazinopropane tris(fluorenyl) acrylate, two (three sulfhydryl propylene) four ( Mercapto) acrylate, tris(meth)acrylate, epichlorohydrin-modified glycerol tris(mercapto)acrylic acid vinegar, diglycerin φ tetra(decyl) acrylate, pentaerythritol tri(meth) acrylate , pentaerythritol = (mercapto) acrylate, dipentaerythritol penta (indenyl) acrylate, alkyl modified pentaerythritol penta (indenyl) acrylate, alkyl modified dipentaerythritol (Methyl), acrylate, alkyl modified dipentaerythritol tri(meth) acrylate, pentaerythritol hexakisyl acrylate, caprolactone modified dipentaerythritol hexa(meth) acrylate, epoxy B Alkyl modified tris(meth)acrylate, tris[(indolyl)propenyloxyethyl]isocyanurate, caprolactone modified tris[(methyl)propenyloxyethyl]iso Cyanuric acid ester, or (meth)acrylic acid amino phthalic acid ester, etc. The acrylic resin may be used alone or in combination of two or more. (3) The surfactant is desired to enhance ink jetting. In the case of the coating property of the ink, a surfactant which achieves the object can be added. Specific examples of the surfactant to be added to the inkjet ink of the present invention include the trade names "Byk_300" and "Byk-3〇6".矽-type surfactants such as "Byk_335", "Byk-310", "Byk-341", "Byk-344", "Byk-370" (manufactured by BYK-Chemie Co., Ltd.); 200835754

i ^pif.d〇C 商品名「Byk-354」、「ByK-358」、「Byk-361」（BYK.Chemie 股份有限公司製造）等丙烯酸系界面活性劑·，商$名「DFX-18」、「Ftergent250」、「Ftergent251」（Ne〇s 股份有限公司製造）等氟系界面活性劑。等於此等界面活性劑可僅使用一種，另外也可將大於二種混合使用。、 ” /彳劑是為了提昇對基礎基板的濕潤性、均化i ^pif.d〇C Acrylic surfactants such as "Byk-354", "ByK-358", "Byk-361" (made by BYK.Chemie Co., Ltd.), and the trade name "DFX-18" A fluorine-based surfactant such as "Ftergent 250" or "Ftergent 251" (manufactured by Ne〇s Co., Ltd.). Equivalent to the use of these surfactants alone or in combination of more than two. , " / Tanning agent is to improve the wettability and homogenization of the base substrate

CleVelingagent)、或者塗佈性而使用的，相刚重量份噴墨墨水而添加錢_重量份 (4)抗靜電劑里知定，'水中所添加的抗靜電劑並無特別 ^親〜的w電劑。具體可列舉：二氧化錫、氧化錫二氧化二銻複合氧化、-〜氧化物f金騎化物或者四級賴—等錫.氧化銦錫複種混靜電劑可僅使用—種，另外也可將大於等於. 抗#龟制是為了防止 _量份噴墨墨水而添加使用^二饼的是相奶 (5)偶合劑重里知〜1重量份。 y使用公知的以水:::加的偶合劑並無特別限定，劑，具體可列舉二其^ ϋ的偶合劑較好的是矽烷偶Λ 合物等。較好的;化合物或者，残競，乙歸•基三乙氧^乙稀基丙基·^氧基石夕乙减傾、r•丙婦酸基丙㈣基^ 91 200835754 二 u厶 wjjif.doc 甲氧基魏、γ_丙烯醯基丙基三甲氧基魏、γ_丙稀酿基丙基甲基二乙氧基石夕燒、γ_丙烯酸基丙基三乙氧基石夕烷、丫_ 甲基丙稀酿基丙基甲基二曱氧基魏、γ_ψ基丙稀酿基丙基二甲氧基矽烷、γ_甲基丙烯醯基丙基甲基二乙氧基矽烷、γ-甲基丙烯醯基丙基三乙氧基矽烷、尸縮水甘油1基丙基曱基—Ψ氧基;、卜縮水甘油氧基丙基三甲氧基石夕，、γ'縮水甘油氧基丙基曱基二乙氧基^、丫_縮水甘油，基丙基二乙氧基梦院、γ_胺丙基甲基二甲氧基發烧、丫_ 胺丙基三:氧基魏、γ_胺丙基曱基二曱氧基魏、γ胺丙基三乙氧基矽烷、Ν_胺乙基_γ_胺丙基曱基二甲氧基矽烷、胺乙基胺丙基三曱氧基矽烷、Ν_胺乙基胺丙基三乙氧基矽烷、Ν•苯基-γ-胺丙基三曱氧基矽烷、]Si-苯基-γ-胺丙基^乙氧基矽烷、Ν_苯基_γ_胺丙基甲基二甲氧基矽烧2本基-γ-胺丙基曱基二乙氧基石夕院、γ_疏基丙基曱基二甲氧基矽烷、γ-胺丙基三曱氧基矽烷、γ-巯基丙基曱基二乙氧基矽烷、γ-巯基丙基三乙氧基矽烷、γ-異氰酸酯基 f基'基二乙氧基石夕院、γ-異氰酸醋基丙基三乙氧基石夕烧等。此等中較好的是可列舉：γ_乙烯基丙基三甲氧基矽烧、丙烯醯基喊三f氧基魏、卜甲基丙刺基丙基三甲乳基夕炫γ-兴氰酸醋基丙基三乙氧基梦炫等。此等偶合劑可僅使用一種，另外也可將大於二種混合使用。偶合劑較好的是相對於1〇〇重量份喷墨墨水而添加使用0.01重量份〜3重量份。 92 200835754 ^pif.doc (6)環氧硬化劑本發明之噴墨墨水所添加的環氧硬定，可使用公知的環氧硬化劑。具體別限肼（dihydmzide)化合物、咪：·有機酸-醯胺、若香族脸、夕-,卞及具何生物、二氰基二醯叙方曰無版、多碰酸、多元幾酸可列舉··二氛基二酿胺等二氛基更酸體：二雙(，乙基)·5-異丙基乙内酿CleVelingagent), or the coating property used, add the weight of the inkjet ink to add _ parts by weight (4) antistatic agent, the 'antistatic agent added in the water is not special ^ pro ~ Electric agent. Specific examples thereof include: tin dioxide, tin oxide ruthenium dioxide composite oxidation, -~ oxide f gold rider or fourth-grade lysine-like tin. Indium tin oxide double-mixing electrostatic agent can be used only, or It is greater than or equal to. The anti-chicken system is used to prevent the use of the two-cakes in order to prevent the _ parts of the inkjet ink, and the phase milk (5) coupling agent is weighed to 1 part by weight. y The known coupling agent to be added with water::: is not particularly limited, and specific examples thereof include a coupling agent of ruthenium oxime or the like. Preferably, the compound or the compound is catastrophic, and the compound is exemplified by ethyl ethoxylate, ethyl propyl propyl ethoxylate, ethoxylate, and ethyl phenate. Methoxy Wei, γ-propylene propyl propyl trimethoxy wei, γ propylene propyl propyl methyl diethoxy oxysulfan, γ acryl propyl triethoxy oxalate, 丫 _ A Propylene propyl methyl dimethoxy wei, γ ψ propyl propyl propyl methoxy decane, γ methacryl propyl propyl propyl dimethyl methoxy decane, γ-methyl Propylene decyl propyl triethoxy decane, cadaveric glycidyl 1 propyl propyl fluorenyl hydrazinyl group; bromo glyceryloxy propyl trimethoxy oxalate, γ 'glycidoxy propyl fluorenyl Ethoxyl, hydrazine-glycidol, propyl propyl diethoxy dream, γ-aminopropyl methyldimethoxy fever, 丫_aminopropyl three: oxy-wei, γ-aminopropyl Mercaptodimethoxy, gamma-aminopropyltriethoxydecane, hydrazine-amine ethyl _γ-aminopropyl decyl dimethoxy decane, amine ethylamine propyl trimethoxy decane, hydrazine _Aminoethylamine propyl triethoxy decane, Ν•phenyl- γ-Aminopropyltrimethoxy decane,]Si-phenyl-γ-aminopropyl ethoxy decane, Ν_phenyl_γ-aminopropylmethyldimethoxy oxime 2 base- Γ-aminopropyl decyl diethoxy sylvestre, γ-benzyl decyl dimethoxy decane, γ-aminopropyl trimethoxy decane, γ-mercaptopropyl decyl diethoxy矽、, γ-mercaptopropyltriethoxy decane, γ-isocyanate group f-yl-diethoxy oxime, γ-isocyanate propyl triethoxy sulphur, etc. Preferred among these are γ-vinylpropyltrimethoxysulfonium, propylene fluorenyl-tri-f-oxygen, and propyl-propyl-propylpropyltrimethyl succinyl γ-cyanate vinegar. Propyl triethoxy dreams and so on. These coupling agents may be used alone or in combination of more than two. The coupling agent is preferably added in an amount of 0.01 part by weight to 3 parts by weight based on 1 part by weight of the inkjet ink. 92 200835754 ^pif.doc (6) Epoxy curing agent A known epoxy curing agent can be used as the epoxy resin to be added to the inkjet ink of the present invention. Specifically, it is limited to dihydmzide compounds, imiline: organic acid-decylamine, fragrant face, eve-, 卞 and what organism, dicyandi- 醯醯曰曰、, multi-touch acid, polybasic acid For example, a di-aryl acyl acid such as a di-aryl acetaminophen: a di-double (, ethyl)·5-isopropyl B

二?甲^ 2-本基_4·甲基咪唾、2_苯基_4_甲基-5__美甲其妹L t 衍生物，鄰苯二甲_、鍾^二工基甲基味哇㈣唾 T夂酐偏本二甲酸酐、1，2,4_環己炫二甲酸-u-酐等酸酐等。其中尤其好的是透甲酸酐、u，4-環己烷三甲酸_u_酐。的偏本- 此等環氧硬化劑可僅使用一種，另外也可將大於等於二種混合使用。 ' 環氧硬化劑較好的是相對於100重量份噴墨墨水而添加使用0.2重量份〜5重量份。 (7)胺基梦化合物可於本發明之噴墨墨水中添加胺基矽化合物。胺基矽化合物可列舉：對胺基苯基三曱氧基矽烷、對胺基苯基三乙氧基矽烷、間胺基苯基三曱氧基矽烷、間胺基苯基三乙氧基矽烷、胺丙基三甲氧基矽烷、胺丙基三乙氧基矽烷等。此等胺基矽化合物可僅使用一種，另外也可將大於等於二種混合使用。胺基矽化合物是為了使對基板的密著性達到良好而使 93 200835754二?甲^2-本基_4·Methyl iodide, 2_phenyl_4_methyl-5__Nail, its sister L t derivative, o-phthalene _, 钟^二基基methyl Wow (4) Salicyl T-anhydride is an acid anhydride such as a dicarboxylic anhydride, 1,2,4-cyclohexyl dicarboxylic acid-u-anhydride or the like. Of these, particularly preferred are permeate anhydride, u, 4-cyclohexanetricarboxylic acid _u-anhydride. The partial hardness - these epoxy hardeners may be used alone or in combination of two or more. The epoxy hardener is preferably added in an amount of 0.2 part by weight to 5 parts by weight based on 100 parts by weight of the inkjet ink. (7) Amine-based dream compound An amine-based ruthenium compound can be added to the inkjet ink of the present invention. The amine ruthenium compound may, for example, be p-aminophenyl trimethoxy decane, p-aminophenyl triethoxy decane, m-aminophenyl trimethoxy decane or m-aminophenyl triethoxy decane. , aminopropyltrimethoxydecane, amine propyl triethoxy decane, and the like. These amine sulfonium compounds may be used alone or in combination of two or more. The amine ruthenium compound is used to make the adhesion to the substrate good. 93 200835754

i ^piI.QOC 用的，較好的是相對於100重量份噴墨墨水而添加橡碣 0·05重量份〜2重量份。 6嘴墨墨;dc的黏度For the use of i ^ piI.QOC, it is preferred to add 0.05 parts by weight to 2 parts by weight based on 100 parts by weight of the inkjet ink. 6 mouth ink; dc viscosity

本發明中喷墨墨水的黏度並無特別限定，於常溫卞進行贺墨之情況下，就提昇利用喷墨塗佈方法的喷墨精度么方面而§ ’黏度較好的是1 mPa.s〜50 mPa.s ( 25〇C )，更好的是5mPa.s〜30mpa.s (25。〇,尤其好的是8mpa.s〆 20 mPa-s (25〇C ) ° 、加熱喷墨頭進行喷墨之情況下，於加熱溫度（經烯基取代之耐地醯亞胺化合物不硬化的溫度，較好的是4〇。〇〜 120 C )下，黏度為1 mPa.s〜50 mPa.s、較好的是5 mPa.s 〜30mPa.s、更好的是8mPa.s〜2〇mPa.s即可。 7 ♦ fe亞胺膜可藉由噴墨將本發明之喷墨墨水塗佈於基板表面，利用加熱板、或者洪箱等進行加熱處理而形成整面或者特定圖案狀（線狀等）聚醯亞胺膜。 ’於形成圖錄聚醯亞胺膜之情況下，使用光微需光阻劑、顯影液、蝕刻液、剝離液等多種用日予，°口液，並且需要繁雜的步驟。相對於此，使下ίρΠ'1墨水所形成的圖案狀聚酿亞胺膜，具有如 ffi it貝墨印刷僅描繪至必需的部分，因此材料使 ==少，並因不使用光罩而可多品種大量生產且製造中所需的步驟數少。水的涂佈 94 200835754 貝^佈方法根據墨水的喷出方法而有各種類型。例型^喷^i^_KbUbWejet)(註冊商標）二=墨水中所含的各成分，_各種方法進行噴墨，可將贺墨墨水塗饰成預先確定的圖案狀。 -2用本發明之4錢行㈣的更好时^法是壓電 =1 °該Μ電70件型的喷頭魏選（⑽_ 其具有多個噴嘴的嘴嘴形成基板、。二鳴對向配置的I電材料以及導電材料以及於該壓力產生元件周圍充滿Ρ —丄玍兀仵以㈣產生元件位移，使墨水的小二自;嘴=電磨而使噴軍於塗佈頭與墨水容納部位不同的 :一體的噴:===位二分離水容，部位對塗佈頭可分離或者不可分離地一:=搭= 於托架上，此外，設置於裝置的固定部位， ^The viscosity of the inkjet ink in the present invention is not particularly limited, and in the case where the ink is applied at room temperature, the ink jet precision by the inkjet coating method is improved. § 'The viscosity is preferably 1 mPa.s~ 50 mPa.s (25〇C), more preferably 5mPa.s~30mpa.s (25. Hey, especially good is 8mpa.s〆20 mPa-s (25〇C) °, heating the inkjet head In the case of ink jetting, the viscosity is 1 mPa.s to 50 mPa at a heating temperature (temperature at which the alkenyl substituted imine compound is not hardened by an alkenyl group, preferably 4 Å to 120 C). s, preferably 5 mPa.s to 30 mPa.s, more preferably 8 mPa.s to 2 〇 mPa.s. 7 ♦ feimine film can be coated with inkjet ink of the present invention by inkjet The surface of the substrate is placed on the surface of the substrate and heated by a hot plate or a flood box to form a full-surface or a specific pattern (linear or the like). The polyimide film is formed in the case of forming a polyimine film. The light micro-requires a photoresist, a developing solution, an etching solution, a stripping liquid, etc., and a liquid-filled liquid, and requires complicated steps. In contrast, the pattern formed by the lower ink is made. The polyimine film has a portion such as ffi it, which is drawn to the necessary portion, so that the material has a small amount of ==, and can be mass-produced in many varieties without using a photomask, and the number of steps required in the production is small. Coating of water 94 200835754 There are various types of methods for ejecting ink according to the method of ejecting ink. Example: Ejection ^i^_KbUbWejet) (registered trademark) Two = various components contained in the ink, _ various methods for inkjet The ink ink can be painted into a predetermined pattern. -2 The better method of using the 4th line (4) of the present invention is piezoelectric = 1 °. The 70-piece type of nozzle is selected ((10)_ its nozzle has a plurality of nozzles to form a substrate. To the configured I electrical material and the conductive material and around the pressure generating element are filled with Ρ-丄玍兀仵 to (4) produce component displacement, so that the ink is small; the mouth = electric grind to spray the coating head and the ink Different accommodation parts: one-piece spray: === position two separate water capacity, the part can be separated or inseparable from the coating head: = lap = on the bracket, in addition, set at the fixed part of the device, ^

部件、例如管而將墨水供給至塗佈頭。、、工由墨水i、A 另外’將用以對塗佈頭作用較好墨水箱之情況下，可採用如下形態 === 箱的墨水容納部位的形態，或者ft 及對可撓性墨水容納袋於擴h 70 土、水合納衣以方式的細置’此外’也可為採用於與;== 相對應的範圍内排列塗佈元件而成的缓印刷== 95 200835754 二 υ二 1 jjjif.doc 佈裝置。The component, such as a tube, supplies ink to the coating head. In the case where the ink i, A is used to apply a better ink tank to the coating head, the following form === the form of the ink containing portion of the box, or the ft and the flexible ink can be accommodated. The bag can be used to form the coated component in a range corresponding to the range of === in the case of expanding the h 70 soil and hydrating the nano-coating. In addition, it can be used for the printing of the coated components in the range corresponding to ;==== 95 200835754 二υ二1 jjjif .doc cloth device.

LIMMMA 佈於iC佈方法，藉由噴墨將本發明之噴墨墨水塗氣化等而除去，即乾 .、、、便冷亞脸彳卜人你rA、了猎此形成經烯基取代之耐地醯 (B) ° 。m水進而含有高分子化合物LIMMMA is disposed in the iC cloth method, and the inkjet ink of the present invention is removed by gas-jetting or the like by inkjet, that is, dry, and, and then, the cold-faced face is replaced by an alkenyl group. Resistance to ground (B) °. m water further contains a polymer compound

’可形成輯絲代之耐地ϋ亞胺化合物 ()〃鬲为子化合物（6)的複合膜。曰加熱條件根據各成分賴誠賊比湘不同，較好取奴耐祕細仏物⑷不硬化的溫度， ^吊G C〜12(rc下’使用烘箱時以5分鐘〜丨5分鐘形成膜，使用加熱板時以1分鐘〜5分鐘形成膜。一 X於經烯基取代之耐地醯亞胺化合物（Α)的膜、或者，、」希基取代之耐地輕胺化合物（A)與冑分子化合物⑻ 的複合膜形成後’為了使經烯基取代之耐地酿亞胺化合物硬化車乂好的是於15〇。〇〜35〇〇c、更好的是於細。C〜 300=下進行加熱處理，可藉此獲得聚臨亞胺膜（使用供箱月況下為30分鐘〜9〇分鐘，使用力口熱板之情況下為$ 刀鐘〜3〇分鐘）。另外，高分子化合物（B)為聚醯胺酸或者聚醯胺酸酿等之情況下，利用加熱處理而引起的醯亞胺化反應也可同時進行。 +膜=成為圖案狀之情況下，則形成有圖案狀聚醯亞胺膜。本說明書中，只要無特別提及，聚酸亞胺膜包括圖案 96 200835754 i jpif.doc 狀聚醯亞胺膜。如此而獲得的聚酸亞賴是耐熱性、電絕緣絕緣膜。另外，原料噴墨墨水含有環氧樹脂之情況^兴^ 為較強韌，且耐化學藥品性、平坦性、成優異的絕緣膜，較好。 Μ性及耐機鑛性 8薄膜某&A composite film in which the ruthenium imine compound () is a sub-compound (6) can be formed.曰 heating conditions according to the different components of the thief thief than Hunan, it is better to take the slave to the secret sputum (4) does not harden the temperature, ^ hang GC ~ 12 (rc under the use of the oven to form a film for 5 minutes ~ 丨 5 minutes, The film is formed in a period of from 1 minute to 5 minutes using a hot plate. A film of X-resistant alkenyl substituted imide compound (Α), or, Hilki-substituted light amine compound (A) and After the formation of the composite film of the fluorene molecular compound (8), in order to harden the olefin-substituted imine-substituted imine compound, the ruthenium is preferably 15 〇. 〇 35 〇〇 c, more preferably fine. C 〜 300 = Heat treatment is carried out to obtain a polylin film (used for 30 minutes to 9 minutes for the case of a box, and $5 to 3 minutes for a hot plate). When the polymer compound (B) is polylysine or polylysine, the oxime imidization reaction by heat treatment may be simultaneously performed. When the film is in a pattern, it is formed. There is a patterned polyimide film. In this specification, the polyimide film includes a figure unless otherwise specified. 96 200835754 i jpif.doc Polyimine film. The polyamic acid obtained in this way is a heat-resistant and electrically insulating insulating film. In addition, the case where the raw inkjet ink contains epoxy resin is strong and tough. And it is chemically resistant, flat, and excellent in insulating film. It is excellent in sturdy and mechanically resistant 8 film &

發明之_基板藉由如下方式而獲得：例如於嘴墨等方法而形成有配線的聚醯亞胺薄膜 ' J Ξί=箄將本發明之喷墨墨水塗佈成整二 g電子g 上，形成有配線的聚酸亞胺薄膜等薄臈基板薄膜塗佈本發明之喷墨墨水，其後將該 ^ ίΐ 進而進行加熱，藉此可獲得以具有絕緣性々承&亞胺膜包覆的可撓性電子零件。 [實施例] 恭Μ 1下藉由Λ ^例及比較例對本發明加以說明，但本鲞月亚不限定於此等實施例。寫符號表示實施例及比較例中所用的經烯基取代、kgf經烯基取代之耐地酿亞胺（a】）、經雙稀基取 ^地醯亞胺（a2)、具有大於等於2個酸酐基的化合物以下!、+二胺㈤）、單胺（b3)及溶劑（C)的名稱。於以下敍述中使用該縮寫符號。 97 200835754 Ζ.ΌΖ, I jpif.doc 經烯基取代之耐地酸酐 ANA :烯丙基耐地酸酐經烯基取代之耐地醯亞胺二綾基 ANIM : N_甲基-稀丙基雙環[2β2 ι]υ 醯亞胺經雙烯基取代之耐地醯亞胺^2^ _烯-2,3_二鲮基 ΒΑΝΙΜ :雙{4_(稀丙基雙環[2.2.ηυ 醯亞胺)苯基}曱烧The substrate of the invention is obtained by, for example, a polyimide film formed with a wiring by a method such as a nozzle ink, and the inkjet ink of the present invention is applied to a whole g of electron g to form The thin-film substrate film such as a printed polyimide film is coated with the inkjet ink of the present invention, and then heated and further heated to obtain an insulating tape-bearing & imine film. Flexible electronic parts. [Examples] The present invention will be described by way of example and comparative examples, but this invention is not limited to the examples. The symbols indicate that the alkenyl group substituted in the examples and the comparative examples, the kgf-substituted alkenylamine (a) substituted by alkenyl group, and the diazide-substituted imide (a2) have a ratio of 2 or more. The acid anhydride group compound has the following names: + diamine (5)), monoamine (b3) and solvent (C). This abbreviation is used in the following description. 97 200835754 Ζ.ΌΖ, I jpif.doc Alkenyl substituted by the alkenyl group ANA: allylic acid anhydride resistant to alkenyl substituted quinone imine diindenyl ANIM : N-methyl-dilyl bicyclo [ 2β2 ι]υ 醯 imine substituted by dienyl group of yttrium imine^2^ _ene-2,3_dimercaptopurine: double {4_(dilyl biscyclo[2.2.ηυ 醯imino)benzene Base

經三烯基取代之耐地醯亞胺Tertiary substituted imide

TrisANITAEA ··三{4·(烯丙基雙環似巧庚-二羧基醯亞胺)三乙基}胺坏，3TrisANITAEA ··3{4·(allylbicyclo-p-heptyl-dicarboxy quinhoimine) triethyl}amine bad, 3

TrisANITrisAM :三{4-(烯丙基雙環[2 21]庚_ 二羧基醯亞胺)三苯基}曱烷 ’ _5-烯TrisANITrisAM: tris{4-(allylbicyclo[2 21]heptyl-dicarboxyarenimine)triphenyl}decane ‘5-ene

TrisANIPARARO :三{4-(烯丙基雙環[2 2】]庚 -2,3-二羧基醯亞胺)苯基}羥基曱烷 ·. 經四烯基取代之耐地醯亞胺（a4) -稀TrisANIPARARO: tris{4-(allylbicyclo[2 2]]heptane-2,3-dicarboxyindolimide)phenyl}hydroxydecane. Tetraphenylene substituted terpene imine (a4) -dilute

TetrakisANITAM :四{4·(烯丙基雙璟 r? ? c -2,3-二羧基醯亞胺)四苯基}曱烷县有大於等於2個酸酐基的化合物> ODPA : 3,3’，4,4’_二苯基醚四甲酸二酐二胺（b2) DDS · 3,3f-二胺基二苯石風 HFBAPP : 4,4f_[[2,2,2-三氟·1·(三氟甲基）亞乙基]雙亞苯氧基]雙苯胺 98 200835754TetrakisANITAM: tetra{4·(allyl bis-r-r-? c-2,3-dicarboxy quinone imine) tetraphenyl}decane county having two or more acid anhydride groups> ODPA : 3,3 ',4,4'_Diphenyl ether tetracarboxylic acid dianhydride diamine (b2) DDS · 3,3f-diaminobiphenyl stone wind HFBAPP: 4,4f_[[2,2,2-trifluoro·1 ·(Trifluoromethyl)ethylidene]bis-phenoxy]diphenylamine 98 200835754

i ^pif.d〇C HMDA :己二胺 12DA : 1，12-十二烷二胺 BAEE: 1，2·雙(3·胺基乙氧基)乙烷 ΒΑΡΒ : 1,4-雙(3-胺基丙氧基)丁烷 ΒΑΡΕΕ :雙[2-(3·胺基丙氧基)***] DDET : 4,4’·(1，2-乙炔二基)雙苯胺 DDP : 4,4’-(1，5-戊烷二基)雙苯胺 IPD :異佛酮二胺 ® APDS :雙胺丙基四甲基矽氧烷 FM3311 :上述式（XV)中，R3、R4均為曱基，R5為亞曱基，X為3、y為10〜15左右的混合物，即平均分子量為1，000的化合物（商品名「FM3311」（Chisso股份有限公司製造））單胺（b3) S330 : 3_胺丙基三乙氧基矽烷三胺（b4) • TAEA :三胺基乙胺i ^pif.d〇C HMDA : hexamethylenediamine 12DA : 1,12-dodecanediamine BAEE: 1,2·bis(3·aminoethoxy)ethaneΒΑΡΒ : 1,4-double (3 -Aminopropoxy)butane oxime: bis[2-(3.Aminopropoxy)ethyl ether] DDET : 4,4'·(1,2-acetylenediyl)diphenylamine DDP : 4,4' -(1,5-pentanediyl)diphenylamine IPD: Isophoronediamine® APDS: bisaminopropyltetramethyloxane FM3311: In the above formula (XV), R3 and R4 are sulfhydryl groups, R5 is a fluorenylene group, X is a mixture of 3 and y of about 10 to 15, that is, a compound having an average molecular weight of 1,000 (trade name "FM3311" (manufactured by Chisso Co., Ltd.)) monoamine (b3) S330 : 3 _Aminopropyltriethoxydecanetriamine (b4) • TAEA: Triaminoethylamine

TrisAM :三胺基苯基甲烷 PARAR0 :副玫瑰色素（Pararosaniline) 四胺（b5) ΤΑΜ :四胺基苯基甲烷溶劑（C) EDM :二乙二醇曱基*** GBL : γ-丁内酯 99 200835754 NMP : N-甲基-2-吡咯烷酮 [實施例1]喷墨墨水（1) 於具備攪拌機及原料投入口的200 ml三口燒瓶中，以如下所示之方式投入原料，攪拌至固體成分完全溶解，獲得黃色透明的BANIM為40 wt%的溶液。該溶液的黏度為 15.2 mPa^s (25°C )，表面張力（25°C )為 33 mN/m。可將TrisAM: Triaminophenylmethane PARR0: Pararosaniline Tetraamine (b5) ΤΑΜ: Tetraaminophenylmethane Solvent (C) EDM: Diethylene glycol decyl ether GBL: γ-butyrolactone 99 200835754 NMP : N-methyl-2-pyrrolidone [Example 1] Inkjet ink (1) In a 200 ml three-necked flask equipped with a stirrer and a raw material inlet, the raw materials were put in the following manner, and stirred until the solid content was complete. Dissolved to obtain a yellow transparent BANIM solution of 40 wt%. The viscosity of the solution was 15.2 mPa^s (25 °C) and the surface tension (25 °C) was 33 mN/m. Can

該溶液直接用作喷墨墨水（1)。溶液的黏度可利用E型黏度計（TOKYO KEIKI製造之VISCONIC ELD )進行測定。表面張力可利用自動動態表面張力計（協和界面化學股份有限公司製造之BP-D4)進行測定。 BANIM 40.0 g GBL 30.0 g EDM 30.0 g [實施例2]噴墨墨水（2) 於實施例1中所用的三口燒瓶中，以如下所示之方式投入原料，攪拌至固體成分完全溶解，獲得BANIM為％ wt%的溶液。該溶液的黏度為42 7mpa.s(25ct)、15.4mpas (50°C)，表面張力（25。〇)為 34mN/m。 50.0 g 25.0 g 25.0 gThis solution was directly used as an inkjet ink (1). The viscosity of the solution can be measured using an E-type viscometer (VISCONIC ELD manufactured by TOKYO KEIKI). The surface tension can be measured by an automatic dynamic surface tension meter (BP-D4 manufactured by Kyowa Interface Chemical Co., Ltd.). BANIM 40.0 g GBL 30.0 g EDM 30.0 g [Example 2] Inkjet ink (2) In the three-necked flask used in Example 1, the raw materials were placed in the following manner, and stirred until the solid content was completely dissolved to obtain BANIM. % wt% solution. The viscosity of the solution was 42 7 mPa.s (25 ct), 15.4 mpas (50 ° C), and the surface tension (25 〇) was 34 mN/m. 50.0 g 25.0 g 25.0 g

BANIMBANIM

GBLGBL

EDMEDM

[實施例3]噴墨墨水於貫施例1所用的三口燒瓶中，以如下所示之方式投入原料，攪拌至固體成分完全溶解，獲得anim/Banim 100 200835754[Example 3] Inkjet ink In a three-necked flask used in Example 1, the raw materials were placed in the following manner, and stirred until the solid content was completely dissolved to obtain anim/Banim 100 200835754.

z,uz,i^pif.d〇C 為60wt%的溶液。該溶液的黏度為l〇8mPa.s(25°C )、184 mPa.s ( 60°C )，表面張力（25°C )為 33 mN/m。 ANIM 10.0 g BANIM 50.0 g GBL 20.0 g EDM 20.0 g [實施例4]噴墨墨水（4) 於具備溫度計、攪拌機、原料投入口及氮氣導入u的、 500 ml四口燒瓶中，以如下所示之方式投入原料，於乾燥氮氣流、40X：下攪拌5 hr，結果獲得淡黃色透明的聚醯胺酸（B)為30 wt%的溶液。該溶液的黏度為15·5 mpa.s。藉由GPC測定的重量平均分子量為2，1〇〇。聚醯胺酸的重量平均分子量藉由如下方式求得：以四氫呋喃（THF)將所獲得的聚醯胺酸稀釋成聚醯胺酸濃度約Iwt%，使用GPC裝置：日本分光股份有限公司製造^ JASCO GULLIVER 1500 (智能折射率檢測器 RI_153〇)， • 以上述稀釋液為展開劑利用GPC法進行測定，並進行聚苯乙烯換算。管柱是依序連接4支東曹股份有限公司製造之管柱 G4000HXL、G3000HXL、G2500HXL 及 G2〇〇〇ffia 使用，於管柱溫度為4(Tt、流速為L0 ml/min的條件下進行測定。 ODPA 55.0 g DDS Π.0 g S330 59.0 g 101 200835754z, uz, i^pif.d〇C is a 60 wt% solution. The viscosity of the solution was 10 〇 8 mPa.s (25 ° C), 184 mPa·s (60 ° C), and the surface tension (25 ° C) was 33 mN/m. ANIM 10.0 g BANIM 50.0 g GBL 20.0 g EDM 20.0 g [Example 4] Inkjet ink (4) was placed in a 500 ml four-necked flask equipped with a thermometer, a stirrer, a raw material inlet, and a nitrogen gas, as shown below. The raw materials were charged in a dry nitrogen stream at 40X: for 5 hr, and as a result, a pale yellow transparent polyamine (B) solution of 30 wt% was obtained. The viscosity of the solution was 15·5 mpa.s. The weight average molecular weight measured by GPC was 2,1 Torr. The weight average molecular weight of the polylysine was determined by diluting the obtained polyaminic acid into a polyglycine concentration of about 1 wt% in tetrahydrofuran (THF), using a GPC apparatus: manufactured by JASCO Corporation JASCO GULLIVER 1500 (Intelligent Refractive Index Detector RI_153〇), • The above dilution is used as a developing solvent by GPC method and converted to polystyrene. The pipe string is connected in sequence to four pipe cylinders G4000HXL, G3000HXL, G2500HXL and G2〇〇〇ffia manufactured by Tosoh Corporation, and is measured at a column temperature of 4 (Tt, flow rate of L0 ml/min). ODPA 55.0 g DDS Π.0 g S330 59.0 g 101 200835754

i j piI*d〇Ci j piI*d〇C

EDM 以如下所示之方式投入該聚醯胺酸（B) BAMM，鑛錢誠妓全轉，獲職. wt%的溶液。該溶液的黏度為75.6ιηΡ&·<250(：々一0 (60。〇，表面張力（25。〇為27111獅。' .51111^ 聚醯胺酸（Β)溶液30.0 g BANIM 12.0 gEDM was put into the polyamic acid (B) BAMM in the manner shown below, and the mine was fully transferred to obtain a wt% solution. The viscosity of the solution was 75.6 ηηΡ &·<250(: 々0 (60. 〇, surface tension (25. 〇 is 27111 lion. '. 51111^ poly phthalic acid (Β) solution 30.0 g BANIM 12.0 g

[實施例5] 使用實施例1所製備的噴墨墨水⑴作為噴藉由FUJIFILM Dimadx公司製造之噴墨塗m DMP-2831，於1.5 mm厚的玻璃環氧樹脂雙面 1置以1點寬度設定成點距20微米，進行長度為5邮冷佈。將喷墨頭的加熱器設定為3(rc，壓電電壓設為驅動頻率設為5 kHz。將基板置於8G。⑽加熱板上乾β ，鐘後，置於23(TC的烘箱中加熱3G分鐘，獲得形成為線狀的聚醯亞胺絕緣膜。藉由光學顯微鏡觀察所獲得的聚醯亞胺膜之線寬度、 $見度均勻性，並測定膜厚。膜厚是使用KLA_Tenc〇r 股份有限公司製造之觸針式膜厚計a_Step2〇〇，以3個部位的測定值之平均值作為膜厚。其結果示於表〗。線具有充分的厚度。 [實施例6] 使用實施例2中所製備的噴墨墨水（2)作為喷墨墨水，將噴頭加熱器設定為5〇r ,除此之外，以與實施例5 102 200835754 ^υζ,ι jpif.doc 序目冋的條件，獲付聚亞胺絕緣膜。以與實施例5相同的條件對曰評價。〜其結果示於表〗。線財充厚度恤亞胺膜進行 [實施例7] 使用實施例3中所製備的噴墨墨水⑶作為喷 =將噴頭加熱，設定為6(rc，除此之外，以與實施ς! 5 相同的條件，獲得聚酿亞胺絕緣膜。[Example 5] The inkjet ink (1) prepared in Example 1 was used as the inkjet coating m DMP-2831 manufactured by FUJIFILM Dimadx Co., Ltd., and the 1 mm width was set on the double-sided 1 of the 1.5 mm thick glass epoxy resin. Set to a dot pitch of 20 microns and a length of 5 postal tarps. Set the heater of the inkjet head to 3 (rc, the piezoelectric voltage is set to drive frequency set to 5 kHz. Place the substrate on 8G. (10) Dry the plate on the heating plate, after the clock, place it in 23 (TC oven heating) A polyimine insulating film formed into a linear shape was obtained in 3 G minutes. The line width and visibility of the obtained polyimide film were observed by an optical microscope, and the film thickness was measured. The film thickness was KLA_Tenc〇. The stylus type film thickness meter a_Step2〇〇 manufactured by r Co., Ltd. has the average value of the measured values of the three parts as the film thickness. The results are shown in the table. The line has a sufficient thickness. [Example 6] The inkjet ink (2) prepared in Example 2 was set as the inkjet ink, and the head heater was set to 5 〇r, in addition to the example 5 102 200835754 υζ, ι jpif.doc Under the conditions, a polyimide insulating film was obtained. The evaluation was carried out under the same conditions as in Example 5. The results are shown in Table 1. The line was filled with an imine film [Example 7] Using Example 3 The prepared inkjet ink (3) was sprayed as a spray = heated to a head, set to 6 (rc, in addition to, and implemented ς! 5 Under the same conditions, a polyimide-based insulating film is obtained.

贊以ΪΓΓ1Ϊ同的條件對所獲得的聚醯亞胺膜進行抑。其結果示於表1。線具有充分的厚度。丁 [實施例8] 水ί用實施例4中所製備的喷墨墨水⑷作為喷墨墨 =1頭定為6〇t，除此之外，以與實‘ 相同的條件，獲得聚醯亞胺絕緣膜。坪/ί!施例5相同的條件對所獲得的聚醯亞胺膜進行科。其結果示於表卜線具有充分的厚度。的時=用整仪”之情況下，是指約12小時〜18小時 ^間，使用術語“室溫，，之情況下，是指約2(TC〜2穴的 [ό成例1]經烤基取代之耐地酿亞胺的合成（！） r抹5人獅子、蓋有麵栓的2GG ml #魏瓶預備於】^ ’以如下所示之方式投人原料’室溫下整夜擾拌 (真空計壓力為Μ⑻下，使溶劑蒸發，又件，胺敲。將該醯胺酸移至培養皿，放入加熱至18(rc 的供相中放置30分鐘，進行脫水職喊得41纟固體醯 103 200835754The obtained polyimine film was inhibited by the same conditions. The results are shown in Table 1. The wire has a sufficient thickness. [ [Example 8] Water 用 The inkjet ink (4) prepared in Example 4 was used as the inkjet ink=1 head was set to 6 〇t, and otherwise, the same conditions as those of the real one were obtained. Amine insulating film. Ping / ί! Example 5 The same conditions were applied to the obtained polyimide film. The result is shown in the watch line having a sufficient thickness. When using the whole instrument, it means about 12 hours to 18 hours^, using the term "room temperature, in the case of, it means about 2 (TC~2 hole [ό成例1] Bake-based replacement of the resistance to the synthesis of imine (!) r wipe 5 people lion, covered with a face plug 2GG ml #魏瓶前于】^ 'Inject the raw materials in the way shown below' at room temperature overnight Scrambled (the vacuum gauge pressure is Μ(8), the solvent is evaporated, and the piece is knocked. The valine acid is transferred to the culture dish and placed in the supply phase for 30 minutes. 41纟solid醯103 200835754

X ^pif.d〇C 亞胺化物BANIHFBAPP。醯亞胺化物的鑑定使甩FWR藉由紅外吸收光譜（醯亞胺環羰基的伸縮振動為171〇cm_/、 1778 cm·1)進行確認。 ANA 1.85 g HFBAPP 2.35 g THF 10.0 g [合成例2]經烯基取代之耐地醯亞胺的合成（2) 將放入攪拌子的300 ml茄型燒瓶預備於攪拌器上，烘箱的加熱溫度為160°C，除此之外，經與合成例丨相同的方法，獲得5.97 g黏稠液體醯亞胺化物BANIH。醯亞胺化物的鑑定使用FT-IR藉由紅外吸收光譜（醯亞胺環羰基的伸細振動為1690 cm-1、1766 cmf1)進行確認。 ANA 4.67 g HMDA 1.33 g THF 200.0 ml [合成例3]經烯基取代之耐地醯亞胺的合成（3) 將放入攪拌子的300 ml茄型燒瓶預備於攪拌器上，烘箱的加熱溫度為16(TC，除此之外，經與合成例1相同的方法’獲得5·93 g黏稠液體醯亞胺化物BANI12DA。另外，酿亞胺化物的鑑定使用FT-IR藉由紅外吸收光譜（醯亞胺環羰基的伸縮振動為 1692 cm_]、1766 cm·1)進行確認。 ANA 4.03 g I2DA 1.97 g THF 200.0 ml 104 200835754 1 ^ pif.doc [合成例4]經烯基取代之耐地醯亞胺的合成（4) 將放入攪拌子的300 ml茄型燒瓶預備於攪拌器上，經與合成例1相_方法，獲得277 §細的顧醯亞脸化物 BANIBAEE 〇X ^pif.d〇C imimidate BANIHFBAPP. The ruthenium imide was identified by the infrared absorption spectrum (the stretching vibration of the quinone imine carbonyl group was 171 〇cm_/, 1778 cm·1). ANA 1.85 g HFBAPP 2.35 g THF 10.0 g [Synthesis Example 2] Synthesis of an alkenyl-substituted ruthenium imine (2) A 300 ml eggplant flask placed in a stirrer was prepared on a stirrer, and the heating temperature of the oven was In the same manner as in the synthesis example, 5.97 g of a viscous liquid yttrium imide BANIH was obtained, except for 160 °C. The identification of the ruthenium imide was confirmed by FT-IR by an infrared absorption spectrum (extension vibration of the quinone ring carbonyl group of 1690 cm-1 and 1766 cmf1). ANA 4.67 g HMDA 1.33 g THF 200.0 ml [Synthesis Example 3] Synthesis of alkenyl substituted imidinium imine (3) A 300 ml eggplant flask placed in a stir bar was prepared on a stirrer, and the heating temperature of the oven was For the same procedure as in Synthesis Example 1, a 5·93 g viscous liquid hydrazide BANI12DA was obtained as 16 (TC, in addition to the same method as in Synthesis Example 1. In addition, the identification of the brewed imide was carried out by infrared absorption spectroscopy using FT-IR ( The stretching vibration of the quinone imine ring carbonyl group was determined to be 1692 cm _], 1766 cm·1). ANA 4.03 g I2DA 1.97 g THF 200.0 ml 104 200835754 1 ^ pif.doc [Synthesis Example 4] Alkenyl substituted by the alkenyl group Synthesis of imine (4) A 300 ml eggplant type flask placed in a stir bar was prepared on a stirrer, and the method of Synthesis Example 1 was used to obtain 277 § fine 醯醯醯 B B B B B B B B B B B

ANA BAEE THF 22.01 g 7·99 g 70·〇 gANA BAEE THF 22.01 g 7·99 g 70·〇 g

[合成例5]經烯基取代之耐地醯亞胺的合成（5) 將放入攪拌子的3〇〇mUs型燒瓶預備於授掉器上，經與口成例1相同的方法，獲得28 0 g黏稠的液體酿亞胺化物BANIBAPB。醯亞胺化物的鑑定使用叩汉藉由紅外吸收光譜（醯亞胺環羰基的伸縮振動為169〇 cm_〗、i766 進行確認。[Synthesis Example 5] Synthesis of an alkenyl substituted imide imine (5) A 3 〇〇mUs type flask placed in a stir bar was prepared on a transferer, and obtained in the same manner as in the mouth example 1. 28 0 g of viscous liquid brewed imide, BANIBAPB. The identification of ruthenium imide was confirmed by using an infrared absorption spectrum (the stretching vibration of the quinone imine ring carbonyl group was 169 〇 cm_) and i766.

ANA BAPB 20.00 g 10.00 g THF 70.0 g [合成例6]經烯基取代之耐地醯亞胺的合成將放入攪拌子的 ml &型燒瓶職於攪拌器上，經與合成例1相同的方法，獲得28.1 g黏躺液體醢亞胺化物BAMBAPEE。醯亞胺化物的鑑定使用FWr藉由红外吸收光譜（醯亞胺環羰基的伸縮振動為1692 em:、1766 crrf1)進行樓認。 ANA 19.49 g BAPEE 10.50 g 105 200835754 1 ^pif.doc THF 70.0 g [合成例7]經烯基取代之耐地醯亞胺的合成（7) 將放入攪拌子的300 ml茄型燒瓶預備於攪拌器上，經與合成例1相同的方法，獲得8.26 g固體醯亞“胺化ς BANIDDET。醯亞胺化物的鑑定使用FT_IR藉由紅外吸收光譜（酸亞胺環幾基的伸縮振動為i^cnT1、ANA BAPB 20.00 g 10.00 g THF 70.0 g [Synthesis Example 6] Synthesis of alkenyl substituted imidinium imine The ml & type flask placed in a stirrer was placed on a stirrer, and was the same as in Synthesis Example 1. By way of this, 28.1 g of the adhesive liquid bismuth imide BAMBAPEE was obtained. The identification of ruthenium imide was carried out by FWr using an infrared absorption spectrum (the stretching vibration of the quinone imine carbonyl group was 1692 em:, 1766 crrf1). ANA 19.49 g BAPEE 10.50 g 105 200835754 1 ^pif.doc THF 70.0 g [Synthesis Example 7] Synthesis of an alkenyl-substituted ruthenium imine (7) A 300 ml eggplant flask placed in a stir bar was prepared for stirring. On the apparatus, in the same manner as in Synthesis Example 1, 8.26 g of a solid yttrium "an amidated lanthanum BANIDDET was obtained. The yttrium imide was identified by infrared absorption spectroscopy (the stretching vibration of the acid imine ring group was i^) cnT1

進行確認。 ANA 5·92 g DDET 3.08 g THF 40.0 g [合成例8]經細基取代之耐地醯亞胺的合成（8) 將放入攪拌子的300 ml茄型燒瓶預備於攪拌器上，麫與合成例1相同的方法 BANIDDP 〇 ’獲得8·58 g固體酿亞胺化物 ANA 5,29 g DDP 3.70 g THF 20.0 g [合成例9]經_基取代之耐地酿亞胺的合成（9) 將放入攪拌子的1〇〇 ml茄型燒瓶預備於攪拌器上，烘箱的加熱溫度為16〇。〇，除此之外，經與合成例1相同的方法，獲得2.70g固體醯亞胺化物BANnpD。醯亞胺化物的鑑定使用FT4R藉由紅外吸收光譜（醯亞胺環羰基的伸縮振動為1698 cm·1、1766 cm-1)進行確認。 ANA 2.11 g 106 200835754 ZOZIjpif.doc IPD 0.88 g THF 7.0 g [合成例10]經烯基取代之耐地醯亞胺的合赤（川、將放入攪拌子的100ml茄型燒瓶預備於攪拌哭上，烘箱的加熱，度為WC，除此之外，經與合成例9ro相同的方法’獲得6.73 g黏稠液體醯亞胺化物BANlApDS。醯亞胺化物的較細FT_IR#由紅外讀絲（醯亞胺環幾基的伸縮振動為1692 cm·1、1766 cm·1)進行確認。 ANA 4.47 g APDS 2.72 g THF 16.8 g [合成例11]經烯基取代之耐地醯亞胺的合成（11) ^將放入攪拌子的i〇0ml茄型燒瓶預備於攪拌器上，烘箱的加熱·度為16〇t，除此之外，經與合成例9相同的 =去’獲得7·85 g黏稠的液體酸亞胺化物BANIFM3311。酉胺化物的鑑定使用FT-IR藉由紅外吸收光譜（醯亞胺裱羰基的伸縮振動為Π00 cm·1、1766 cm·1)進行確認。 ANA 2.40 g FM3311 5.76 g THF 20.0 g [合成例12]經烯基取代之耐地醯亞胺的合成（12) _將放入攪拌子的300 ml茄型燒瓶預備於攪拌器上，烘相的加熱溫度為16〇〇c，除此之外，經與合成例9相同的 ’套’獲得4·45 g非常黏稠的液體醯亞胺化物 107 200835754^Undergo verification. ANA 5·92 g DDET 3.08 g THF 40.0 g [Synthesis Example 8] Synthesis of succinimide substituted with a fine base (8) A 300 ml eggplant flask placed in a stirrer was prepared on a stirrer, and The same method as in Synthesis Example 1 BANIDDP 〇 'obtained 8.58 g of solid brewed imine ANA 5, 29 g of DDP 3.70 g of THF 20.0 g [Synthesis Example 9] Synthesis of ruthenium substituted imine (9) A 1 ml ml eggplant flask placed in a stir bar was prepared on a stirrer, and the oven was heated at a temperature of 16 Torr. Further, in the same manner as in Synthesis Example 1, 2.70 g of a solid oxime imide BANnpD was obtained. The identification of ruthenium imide was confirmed by infrared absorption spectroscopy (extension vibration of quinone imine ring carbonyl of 1698 cm·1, 1766 cm-1) using FT4R. ANA 2.11 g 106 200835754 ZOZIjpif.doc IPD 0.88 g THF 7.0 g [Synthesis Example 10] An alkenyl-substituted sulphate-containing succinimide (Chuan, a 100 ml eggplant type flask placed in a stirrer was prepared for stirring and crying In the same manner as in Synthesis Example 9ro, 6.73 g of a viscous liquid bismuth imide BAN1ApDS was obtained in the same manner as in Synthesis Example 9ro. The finer FT_IR# of yttrium imide was obtained by infrared reading. The stretching vibration of the amine ring group was 1692 cm·1, 1766 cm·1). ANA 4.47 g APDS 2.72 g THF 16.8 g [Synthesis Example 11] Synthesis of an alkenyl-substituted ruthenium imine (11) ^ The i〇0ml eggplant type flask placed in a stirrer was prepared on a stirrer, and the heating degree of the oven was 16 〇t, except that the same ==' was obtained as the synthesis example 9 to obtain a 7.85 g thick layer. The liquid acid imide BANIFM3311. The identification of the hydrazine compound was confirmed by FT-IR by infrared absorption spectroscopy (the stretching vibration of the quinone imine carbonyl group was Π00 cm·1, 1766 cm·1). ANA 2.40 g FM3311 5.76 g THF 20.0 g [Synthesis Example 12] Synthesis of alkyne substituted by alkenyl group (12) _ 3 placed in a stir bar The 00 ml eggplant flask was prepared on a stirrer, and the heating temperature of the baking phase was 16 〇〇c. In addition, the same 'sleeve' as in Synthesis Example 9 was obtained to obtain a very viscous liquid hydrazine imide of 4.45 g. 107 200835754^

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TrisANITAEA。醯亞胺化物的鑑定使用FT4R藉由紅外吸收光譜（醢亞胺環幾基的伸縮振動為1692 cm-1、1766 cnT1) 進行確認。 ANA 3.63 g TAEA 0·87 g THF 200.0 mlTrisANITAEA. The identification of ruthenium imide was confirmed by FT4R by an infrared absorption spectrum (the stretching vibration of the quinone ring group was 1692 cm-1, 1766 cnT1). ANA 3.63 g TAEA 0·87 g THF 200.0 ml

[合成例13]經烯基取代之耐地醯亞胺的合成（13) 將放入攪拌子的100ml茄型燒瓶預備於攪拌器上，烘箱的加熱溫度為16(TC，除此之外，經與合成例9相同的方法，獲得2.98 g固體醯亞胺化物TrisANITrisAM。醯亞胺化物的鑑定使用FT_IR藉由紅外吸收光譜（醯亞胺環羰基的伸縮振動為17〇6cm-1、1774 (^1-1)進行確認。 ANA 2.04 g[Synthesis Example 13] Synthesis of alkenyl substituted imidinium imine (13) A 100 ml eggplant type flask placed in a stir bar was prepared on a stirrer, and the oven was heated at a temperature of 16 (TC, in addition, In the same manner as in Synthesis Example 9, 2.98 g of a solid quinone imine TrisANI TrisAM was obtained. The ruthenium imide was identified by FT_IR by infrared absorption spectroscopy (the stretching vibration of the quinone ring carbonyl group was 17 〇 6 cm -1 , 1774 ( ^1-1) Confirmation. ANA 2.04 g

TrisAM 0.97 g THF 7.0 g [合成例14]經烯基取代之耐地醯亞胺的合成（14)TrisAM 0.97 g THF 7.0 g [Synthesis Example 14] Synthesis of an alkenyl substituted imide imine (14)

ANA PARARO THF ^將放入攪拌子的100 ml茄型燒瓶預備於攪拌器上，烘箱的加熱’皿度為16(rc，除此之外，經與合成例9相同的方法，獲知2·97 g固體醯亞胺化物TrisANIPARARO。醯，胺化物的鐘定使用FT_IR藉由紅外吸收_ (醢亞胺環祕的伸縮振動為1706 cm·1、1778 enfi)進行確認。 2.00 g LOO g 7.0 g 108 200835754 upif.doc [合成例15]經烯基取代之耐地醯亞胺的合成（15) 將放入攪拌子的1〇〇 ml茄型燒瓶預備於攪拌器上，烘箱的加熱溫度為16〇它，除此之外，經與合成例9相同的方法’獲彳于2.97 g固體醢亞胺化物TetrakisANITAM。酿亞胺化物的鑑定使用FT_IR藉由紅外吸收光譜（醯亞胺環羰基的伸縮振動為1706 cm·1、1776 cm·1)進行確認。 ANA 2.04 gANA PARARO THF ^ A 100 ml eggplant type flask placed in a stir bar was prepared on a stirrer, and the heating degree of the oven was 16 (rc, except that the same method as in Synthesis Example 9 was used to obtain 2.97. g solid yttrium imide TrisANIPARARO. 醯, the amination of the amide is confirmed by FT_IR by infrared absorption _ (the stretching vibration of the yttrium ring is 1706 cm·1, 1778 enfi) 2.00 g LOO g 7.0 g 108 200835754 upif.doc [Synthesis Example 15] Synthesis of alkenyl substituted imide with an alkenyl group (15) A 1 ml ml eggplant flask placed in a stir bar was prepared on a stirrer, and the oven was heated at a temperature of 16 Torr. In addition, it was obtained in the same manner as in Synthesis Example 9 to obtain 2.97 g of solid hydrazide Tetrakis ANITAM. The identification of the brewed imine was carried out by infrared absorption spectroscopy (FT-IR stretching vibration of quinone imine ring carbonyl). Confirmed for 1706 cm·1, 1776 cm·1) ANA 2.04 g

ΤΑΜ 0.96 g THF 7.0 g [實施例9]喷墨墨水（6) 將放入攪拌子的Asone股份有限公司製造之 LABORAN PACK SCREW管瓶6 cc預備於攪拌器1，以如下所示之方式投入原料，攪拌至BANIM固體成分完全溶解，獲得黃色透明的BANIM為30wt%的溶液。該溶液的黏度為 7·1 mPa.s (25°C )。 BANIM 3.00 g EDM 4.00 g GBL 4.00 g [實施例10]噴墨墨水（7) 以與實施例9相同的方式預備瓶，以如下所示之方式投入原料，攪拌至BANIM固體成分完全溶解，獲得普色透明的BANIM為40 wt%的溶液。該溶液的黏度為ι5 2 mPa-s (25〇C ) 0 又 · BANIM 4.00 g 109 200835754 zoz 丄 Dpif.doc EDM 3.00 g GBL 3.00 g [實施例11]噴墨墨水（8) 以與實施例9相同的方式預備瓶，以如下所示之方投入原料，攪拌至BANIM固體成分完全溶解，獲得普^ 透明的BANIM為60 wt%的溶液。該溶液的黏度為18、 mPa-s (25〇C) ° 、 . ·ΤΑΜ 0.96 g THF 7.0 g [Example 9] Inkjet ink (6) 6 cc of LABORAN PACK SCREW vial manufactured by Asone Co., Ltd., which was placed in a stirrer, was prepared in agitator 1, and the raw material was put in the following manner. The mixture was stirred until the BANIM solid component was completely dissolved, and a yellow transparent BANIM solution of 30% by weight was obtained. The viscosity of this solution was 7·1 mPa.s (25 ° C). BANIM 3.00 g EDM 4.00 g GBL 4.00 g [Example 10] Inkjet ink (7) A bottle was prepared in the same manner as in Example 9, and the raw material was put in the following manner, and stirred until the BANIM solid component was completely dissolved, and the obtained The color transparent BANIM is a 40 wt% solution. The viscosity of this solution was ι 5 2 mPa-s (25〇C) 0 again · BANIM 4.00 g 109 200835754 zoz 丄Dpif.doc EDM 3.00 g GBL 3.00 g [Example 11] Inkjet ink (8) and Example 9 The bottle was prepared in the same manner, and the raw materials were placed as shown below, and stirred until the BANIM solid content was completely dissolved, and a solution of 60 wt% of BANIM was obtained. The viscosity of this solution is 18, mPa-s (25〇C) ° , .

BANIM 6.00 g EDM 2.00 g GBL 2.00 g [實施例12]喷墨墨水（9) 以與實施例9相同的方式預備瓶，以如下所示之方式投入原料，攪拌BANIDDET固體成分，但於室溫下不溶解。 ’ BANIDDET L20 g EDM 1.40 g GBL 1.40 g [實施例13]喷墨墨水（10) 以與實施例9相同的方式預備瓶，以如下所示之方式投入原料，攪拌至BANIDDP固體成分完全溶解，獲得褐. 色透明的BANIDDP為30 wt%的溶液。該溶液的黏度為7.2 时a.s (25〇C)。 BANIDDP 1.20 g EDM 1.40 g 110 200835754 ^0^1 jpif.doc GBL 1.40g [實施例14]喷墨墨水（11) ee以外除使用 LABORAN PACK SCREW 管瓶 13 5 以與實施例9相同的方式預備瓶。以如下所示之方人原料，攪拌至BANIHFBAPP固體成分完全溶解，二色透明的BANIHFBAPP為30 wt%的溶液。該溶液二為 7·5 mPa.s ( 25〇C )。BANIM 6.00 g EDM 2.00 g GBL 2.00 g [Example 12] Inkjet ink (9) A bottle was prepared in the same manner as in Example 9, and the raw material was put in the following manner, and the BANIDDET solid content was stirred, but at room temperature. insoluble. 'BANIDDET L20 g EDM 1.40 g GBL 1.40 g [Example 13] Inkjet ink (10) A bottle was prepared in the same manner as in Example 9, and the raw material was put in the following manner, and stirred until the solid component of BANIDDP was completely dissolved. Brown. The color transparent BANIDDP is a 30 wt% solution. The viscosity of the solution was 7.2 a.s (25 〇C). BANIDDP 1.20 g EDM 1.40 g 110 200835754 ^0^1 jpif.doc GBL 1.40g [Example 14] Inkjet ink (11) Except for using LABORAN PACK SCREW vial 13 5 Prepare the bottle in the same manner as in Example 9. . The raw material shown below was stirred until the solid component of BANIHFBAPP was completely dissolved, and the two-color transparent BANIHFBAPP was a 30 wt% solution. The solution 2 was 7·5 mPa.s (25〇C).

BANIHFBAPP 3.60 g EDM 4.20 g GBL 4.20 g [實施例15]喷墨墨水（12) 除使用 LABORAN PACK SCREW 管瓶 13·5 cc 以外，以與實施例9相同的方式預備瓶。以如下所示之方式投入原料，攪拌至BANIIPD固體成分完全溶解，獲得黃色透明的BANIIPD為40 wt%的溶液。該溶液的黏度為146 mPa.s (25。。）。 BANIIPD 2.40 g EDM 1.80 g GBL 1.80 g [實施例16]喷墨墨水（13) 使用LABORAN PACK SCREW管瓶20 cc，除此之外，以與實施例9相同的方式預備瓶。以如下所示之方式投入原料，攪拌至BANIAPDS固體成分完全混合，獲得褐色透明的BANIAPDS為55 wt%的溶液。該溶液的黏度為 111 200835754 zozi^pif.doc 14.6mPa.s (25。〇。 BANIAPDS 6.60 g EDM 2.70 g GBL 2.70 g [實施例17]喷墨墨水（14) 以與實施例9相同的方式預備瓶。以如下所示之方式投入原料，攪拌至BANIAPDS固體成分完全混合，獲得揭 • 色透明的BANIAPDS為70 wt%的溶液。該溶液的黏度為以.5 mPa.s (70。。）。 BANIAPDS 1.40 g GBL 0.60 g [實施例18]喷墨墨水（15) 使用LABORAN PACK SCREW管瓶20 cc，除此之外，以與實施例9相同的方式預備瓶。以如下所示之方式投入原料，攪拌至BANIFM3311固體成分完全混合，獲得鲁褐色透明的BANIFM3311為60 wt%的溶液。該溶液的黏度為 14.7mPa.s (25°C )。 BANIFM3311 7.20 g EDM 2.40 g GBL 2.40 g [實施例19]喷墨墨水（16) 使用LABORAN PACK SCREW管瓶20 cc，除此之外’以與實施例9相同的方式預備瓶。以如下所示之方式投入原料，攪拌至BANIH固體成分完全混合，獲得褐色 112 200835754 upif.doc 3 透明的ΒΑΝΙΗ為50 wt%的溶液。該溶液的黏度為14· mPa-s (25°C ) ° ΒΑΝΙΗ 6.00 g EDM 3.00 g GBL 3.00 g [實施例20]噴墨墨水（17) 使用LABORAN PACK SCREW管瓶20 cc，除此之外，以與實施例9相同的方式預備瓶。以如下所示之方式投入原料，攪拌至BANI12DA固體成分完全混合，獲得^ 色透明的BANI12DA為50 wt%的溶液。該溶液的黏度為 15·8 mPa.s (25。。）。 … BANI12DA 6.00 g EDM 3.00 g GBL 3.00 g [實施例21]喷墨墨水（18) 以與實施例9相同的方式預備瓶。以如下所示之方式投入原料，授拌至BANIBAEE固體成分完全混合，'獲得^ 色透明的BANIBAEE為50 wt%的溶液。該溶液的黏度為 17·3 mPa.s ( 25〇C )。 BANIBAEE 2.00 g EDM 1.00 g GBL LOO g [實施例22]喷墨墨水（19) 以與實施例9相同的方式預備瓶。以如下所示之方式 113 200835754 Ζ,ΌΖ xjpif.doc 投入原料，攪拌至ΒΑΝΙΒAPB固體成分完全混合，獲得褐色透明的BANIBAPB為50 wt%的溶液。該溶液的黏度為 18.4inPa.s (25艽）。 BANIBAPB 2.00 g EDM 1.00 g GBL 1.00 g [實施例23]喷墨墨水（20)BANIHFBAPP 3.60 g EDM 4.20 g GBL 4.20 g [Example 15] Inkjet ink (12) A bottle was prepared in the same manner as in Example 9 except that LABORAN PACK SCREW vial was used at 13·5 cc. The raw materials were charged in the following manner, and stirred until the BANIIPD solid content was completely dissolved to obtain a yellow transparent BANIIPD solution of 40 wt%. The viscosity of this solution was 146 mPa.s (25%). BANIIPD 2.40 g EDM 1.80 g GBL 1.80 g [Example 16] Inkjet ink (13) A bottle was prepared in the same manner as in Example 9 except that a LABORAN PACK SCREW vial of 20 cc was used. The raw materials were charged in the following manner, and stirred until the BANIAPDS solid content was completely mixed to obtain a brown transparent BANIAPDS solution of 55 wt%. The viscosity of this solution was 111 200835754 zozi^pif.doc 14.6mPa.s (25. B. BANIAPDS 6.60 g EDM 2.70 g GBL 2.70 g [Example 17] Inkjet ink (14) Prepared in the same manner as in Example 9. The bottle was placed in the following manner and stirred until the BANIAPDS solid content was completely mixed to obtain a 70 wt% solution of BANIAPDS which was transparent and transparent. The viscosity of the solution was .5 mPa.s (70%). BANIAPDS 1.40 g GBL 0.60 g [Example 18] Inkjet ink (15) A bottle was prepared in the same manner as in Example 9 except that a LABORAN PACK SCREW vial of 20 cc was used. Stir until the solid component of BANIFM3311 is completely mixed to obtain a solution of BANIFM3311 as a 60 wt% solution. The viscosity of the solution is 14.7 mPa.s (25 ° C). BANIFM3311 7.20 g EDM 2.40 g GBL 2.40 g [Example 19 ] Inkjet ink (16) A bottle was prepared in the same manner as in Example 9 except that a LABORAN PACK SCREW vial of 20 cc was used. The raw materials were put in the following manner, and stirred until the BANIH solid content was completely mixed. Brown 112 200835754 upif. Doc 3 The transparent crucible is a 50 wt% solution. The viscosity of this solution is 14 mPa-s (25 ° C) ° 6.00 6.00 g EDM 3.00 g GBL 3.00 g [Example 20] Inkjet ink (17) Using LABORAN A bottle was prepared in the same manner as in Example 9 except that a PACK SCREW vial of 20 cc was used. The raw materials were charged in the following manner, and stirred until the solid component of BANI12DA was completely mixed to obtain a transparent BANI12DA of 50 wt%. The solution has a viscosity of 15.8 mPa.s (25%). BANI12DA 6.00 g EDM 3.00 g GBL 3.00 g [Example 21] Inkjet ink (18) Prepared in the same manner as in Example 9. The bottle was placed in the following manner, and the mixture was mixed until the BANIBAEE solid content was completely mixed, and the obtained transparent BANIBAEE solution was 50 wt%. The viscosity of the solution was 17·3 mPa.s (25〇C). BANIBAEE 2.00 g EDM 1.00 g GBL LOO g [Example 22] Inkjet ink (19) A bottle was prepared in the same manner as in Example 9. In the manner shown below, 113 200835754 Ζ, ΌΖ xjpif.doc The raw materials were put into the mixture and stirred until the solid component of ΒΑΝΙΒAPB was completely mixed to obtain a 50 wt% solution of brown transparent BANIBAPB. The viscosity of the solution was 18.4 inPa.s (25 Å). BANIBAPB 2.00 g EDM 1.00 g GBL 1.00 g [Example 23] Inkjet ink (20)

以與實施例9相同的方式預備瓶。以如下所示之方式投入原料，攪拌至BANIBAPEE固體成分完全混合，獲得褐色透明的BANIBAPEE為50 wt%的溶液。該溶液的黏度為 17·7 mPa.s (25°C )。 BANIBAPEE 2.00 g EDM 1.00 g GBL 1.00 g [實施例24]喷墨墨水（21) 以與實施例9相同的方式預備瓶。以如下所示之方式投入原料，攪拌至TrisANITAEA固體成分完全混合，獲得褐色透明的TrisANITAEA為50 wt%的溶液。該溶液的参占度為 16.1 mPa.s (25°C )。The bottle was prepared in the same manner as in Example 9. The raw materials were charged in the following manner, and stirred until the BANIBAPEE solid content was completely mixed to obtain a 50 wt% solution of brown transparent BANIBAPEE. The viscosity of this solution was 17·7 mPa.s (25 ° C). BANIBAPEE 2.00 g EDM 1.00 g GBL 1.00 g [Example 24] Inkjet ink (21) A bottle was prepared in the same manner as in Example 9. The raw materials were charged in the following manner, and stirred until the solid components of TrisANITAEA were completely mixed to obtain a 50 wt% solution of brown transparent TrisANITAEA. The solution had a partition of 16.1 mPa.s (25 ° C).

TrisANITAEA 2.40 g EDM L20g GBL 1.20 g [實施例25]喷墨墨水（22) 使用LABORAN PACK SCREW管瓶20 cc，除此之 114 200835754 ZOZJLjpif.doc 外，以與實施例9相同的方式預備瓶。以如下所示之方式投入原料，攪拌至TrisANITrisAM固體成分完全溶解，獲得紅褐色透明的TrisANITrisAM為30 wt%的溶液。該溶液的黏度為 8.9 mPa.s (25。〇 )。TrisANITAEA 2.40 g EDM L20g GBL 1.20 g [Example 25] Inkjet ink (22) A bottle was prepared in the same manner as in Example 9 except that LABORAN PACK SCREW vial 20 cc was used, except for 114 200835754 ZOZJLjpif.doc. The raw materials were charged in the following manner, and stirred until the solid content of TrisANI TrisAM was completely dissolved, and a red-brown transparent TrisANI TrisAM was obtained as a 30 wt% solution. The viscosity of this solution was 8.9 mPa.s (25. 〇).

TrisANITrisAM 3.60 g EDM 4.20 g GBL 4.20 gTrisANITrisAM 3.60 g EDM 4.20 g GBL 4.20 g

[實施例26]喷墨墨水（23) 使用LABORAN PACK SCREW管瓶20 cc，除此之外，以與實施例9相同的方式預備瓶。以如下所示之方式投入原料，攪拌至TrisANIPARARO固體成分完全溶解，獲得紅紫透明的TrisANIPARARO為30 wt%的溶液。該溶液的黏度為 13.8 mPa.s (25°C )。[Example 26] Inkjet ink (23) A bottle was prepared in the same manner as in Example 9 except that a LABORAN PACK SCREW vial of 20 cc was used. The raw materials were charged in the following manner, and stirred until the solid content of TrisANIPARARO was completely dissolved, and a red-violet transparent TrisANIPARARO solution of 30 wt% was obtained. The viscosity of the solution was 13.8 mPa.s (25 ° C).

TrisANIPARARO 3.60 g EDM 4.20 g GBL 4.20 g [實施例27]喷墨墨水（24) 使用LABORAN PACK SCREW管瓶20 cc，除此之外，以與實施例9相同的方式預備瓶。以如下所示之方式投入原料，攪拌至TetmkisANITAM固體成分完全溶解，獲得褐色透明的TetrakisANITAM為30 wt%的溶液。該溶液的黏度為 13.8mPa.s (25°C)。TrisANIPARARO 3.60 g EDM 4.20 g GBL 4.20 g [Example 27] Inkjet ink (24) A bottle was prepared in the same manner as in Example 9 except that a LABORAN PACK SCREW vial of 20 cc was used. The raw materials were charged in the following manner, and stirred until the solid content of Tetmkis ANITAM was completely dissolved, and a brown transparent Tetrakis ANITAM was obtained as a 30 wt% solution. The viscosity of the solution was 13.8 mPa.s (25 ° C).

TetrakisANITAM 3.60 g EDM 4.20 g 115 200835754TetrakisANITAM 3.60 g EDM 4.20 g 115 200835754

ZDZi^pif.doC GBL 4.20 g [比較例1]喷墨墨水（5)ZDZi^pif.doC GBL 4.20 g [Comparative Example 1] Inkjet ink (5)

於實施例1所用的三口燒瓶中，以如下所示之方式於入原料，於乾燥氮氣流、40°C下攪拌1〇 hr後，升溫至7〇。$ 攪拌8 hr進行減黏，獲得黃色透明的聚醯胺酸為8_%的溶液。該溶液的黏度為9.1 mPa.s(25t：)，表面張力（25¾ ) 為43 mN/m。本合成例中，若使用EDM作為溶劑，則反應產物析出，因此使用NMP。藉由GPC測定分子量為25，_。可將該溶液直接作為喷墨〇DPA 5.0 g 4.0 g 1〇3·5 gIn the three-necked flask used in Example 1, the raw materials were placed in the following manner, and the mixture was stirred at 40 ° C for 1 hr in a dry nitrogen stream, and then heated to 7 Torr. The viscosity is reduced by stirring for 8 hr to obtain a solution of yellow transparent polyamine acid in an 8% solution. The viscosity of the solution was 9.1 mPa.s (25t:) and the surface tension (253⁄4) was 43 mN/m. In the present synthesis example, when EDM is used as a solvent, the reaction product is precipitated, and therefore NMP is used. The molecular weight was determined by GPC to be 25, _. This solution can be directly used as an inkjet 〇DPA 5.0 g 4.0 g 1〇3·5 g

DDSDDS

NMPNMP

[比較例2] 使用比較例1所製備的嗔：除此之外，以與實施例5相间土 $水（5 )作為喷墨墨水，膜。的條件，獲得聚醯亞胺絕緣以與實施例5相同的條評價。其結果示於表1。2办對所獲得的聚醯亞胺膜進行線邊緣的直線性也不充分，乂度大幅寬於塗佈時的寬度，另夕卜’線不具有充分的厚度。 200835754 upif.doc [表1] 線寬度（μηι) 線寬度均勻性膜厚（um) 實施例5 70 良好 2.5 實施例6 75 良好 3.0 實施例7 75 良好 3.4 實施例8 130 良好 1.5 比較例2 350 有鋸齒狀 L__0.3 --—------1 [實施例28]耐熱性試驗對實施例9〜27中所獲得的噴墨墨水中除實施例1〇、 11、12、17外的墨水進行耐熱性試驗。將2 ml噴墨墨水 ^至坡璃基板上，進行旋塗。以8(rc的加熱板將基板乾燥分鐘後，於23(TC的烘箱中加熱30分鐘，獲得聚醯 =膜。進而於加熱至赋的烘箱中加熱3〇分鐘出2後、230t：的加熱後、25〇t的加熱後測定膜厚，算其^少率。另外’同時也調查加熱時有無膜的流動（回流^ /、、、、。果示於表2。魯 117 200835754[Comparative Example 2] The ruthenium prepared in Comparative Example 1 was used: In addition, the water (5) was used as the inkjet ink and film in the same manner as in Example 5. The conditions were obtained, and polyimine insulation was obtained and evaluated in the same manner as in Example 5. The results are shown in Table 1. In the obtained polyimide film, the linearity of the edge of the line was also insufficient, and the twist was significantly wider than the width at the time of coating, and the wire did not have a sufficient thickness. 200835754 upif.doc [Table 1] Line width (μηι) Line width uniformity Film thickness (um) Example 5 70 Good 2.5 Example 6 75 Good 3.0 Example 7 75 Good 3.4 Example 8 130 Good 1.5 Comparative Example 2 350 Jagged L__0.3 ---------1 [Example 28] Heat resistance test For the inkjet inks obtained in Examples 9 to 27, except for Examples 1, 11, 12, and 17 The ink was tested for heat resistance. 2 ml of inkjet ink ^ was applied to the glass substrate for spin coating. The substrate was dried for 8 minutes on a heating plate of 8 (rc), and then heated in an oven of 23 (TC for 30 minutes to obtain a polyfluorene = film. Further heating in a given oven was heated for 3 minutes, 2 hours, and 230 t: heating. After the heating of 25 〇t, the thickness of the film was measured, and the film thickness was measured. In addition, the flow of the film at the time of heating was also investigated (reflow ^ /, , , , and . The results are shown in Table 2. Lu 117 200835754

ΔΌΔI ^pii.dOCΔΌΔI ^pii.dOC

[表2][Table 2]

[實施例29]保存穩定性試驗對實施例9、實施例1〇中所獲得的喷墨墨水穩定性試驗。將墨水放人至樣品瓶中，測定製造度及室溫保存140天後的黏度。其結果示於表3。、+ [比較例3]噴墨墨水（25) 預備具備攪拌機及原料投入口的5〇〇 ml可八瓶，以如下所示之方式投人補，攪拌至目體解’獲㈣明的3G wt%的紐。該溶賴黏度為17 (25 C)° s[Example 29] Storage stability test The inkjet ink stability test obtained in Example 9 and Example 1A was carried out. The ink was placed in a vial, and the degree of manufacture and the viscosity after storage for 140 days at room temperature were measured. The results are shown in Table 3. + [Comparative Example 3] Inkjet ink (25) Prepare 8 bottles of 5 〇〇ml with a blender and a raw material input port, and fill it in the following manner. Stir to the target to obtain the 3G of (4) Wt% of New Zealand. The solubility viscosity is 17 (25 C) ° s

0DPA DDS 26.45 g 5.3 g 118 200835754 upif.doc S330 28.25 g EDM !4〇g [比較例4]保存穩定性試驗對比較例3中所獲得的喷墨墨水進行保存穩定性試驗。將墨水放入至樣品航中，測定製造當天的黏度及室溫保存140天後的黏度。其結果示於表3。 [表3] 墨水製造當天的黏度 (mPa.s ) 室溫下保存140天後的黏度 (mPa.s) 實施例9 7.1 __ 7.2 實施例10 15.2 15.3 比較例4 17.6 _— 硬化_ [實施例30] 使用實施例10中所製備的噴墨墨水（7)作為喷墨墨水，藉由FUJIFILM Dimatix公司製造之喷墨塗佈裝置0 DPA DDS 26.45 g 5.3 g 118 200835754 upif.doc S330 28.25 g EDM !4〇g [Comparative Example 4] Storage stability test The inkjet ink obtained in Comparative Example 3 was subjected to a storage stability test. The ink was placed in the sample airway, and the viscosity on the day of manufacture and the viscosity after 140 days of storage at room temperature were measured. The results are shown in Table 3. [Table 3] Viscosity at the time of ink production (mPa.s) Viscosity after storage for 140 days at room temperature (mPa.s) Example 9 7.1 __ 7.2 Example 10 15.2 15.3 Comparative Example 4 17.6 _- Hardening _ [Example 30] The inkjet ink (7) prepared in Example 10 was used as an inkjet ink by an inkjet coating apparatus manufactured by FUJIFILM Dimatix Co., Ltd.

DMP-2831於0.7μιη厚的玻璃基板上，以i點寬度設定成點距20微米，進行長度為5cm的線塗佈。將喷墨頭的加熱器設定為抓，壓電電壓私％ v、驅動頻率設為5 kH二。以8〇。的加熱板將基板乾燥$分鐘後，於a。。。的丈、相:加熱30 ^ ’獲得形成為線狀的雜亞胺絕緣膜。綠-ΐΪί學顯微Ϊ觀察所獲得的聚酿亞胺膜的線寬度、 =二：：& ’測疋膜厚。膜厚是使用KLA-Tencor Japar 股份有限公司製造之觸針式的測定值之平均值作為二分的厚度。，、、、、口果不於表4。線具有充 119 200835754 zozi^pif.doc [實施例31] 使用實施例16所製備的 + 水，將壓電電壓^為16V、頭/^、水（）作為赁墨墨外，以與實施例30相同的侔^鳴器、設定為贼，除此之以與實施例30相同的得聚酸亞胺絕緣膜。行評價。其絲示錄4。賴㈣輕胺膜進 [實施例32] 、緣具有充分的厚度。使用實施例19所製備的略· 水，將壓電電壓設為18 V H墨墨水（、16)/為喷墨墨同的條件，獲得輯亞胺絕緣膜之外’以與’、〜例30相行別同的條件對所獲得的聚醯亞胺膜進 H 線具有充分的厚度。DMP-2831 was coated on a 0.7 μm thick glass substrate with a dot pitch of 20 μm and a line length of 5 cm. The heater of the ink jet head was set to grip, the piezoelectric voltage was private, and the driving frequency was set to 5 kH. Take 8 〇. The heating plate dries the substrate for $ minutes after a. . . The phase of the film: heating 30 ^ ' to obtain a hybrid imine film formed into a linear shape. Green-ΐΪ 学 Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ 聚聚聚聚聚聚聚聚聚聚聚聚聚聚聚聚聚聚聚聚聚聚The film thickness is the average of the measured values of the stylus type manufactured by KLA-Tencor Japar Co., Ltd. as a thickness of two. , , , , , and the fruit is not in Table 4. The line has a charge 119 200835754 zozi^pif.doc [Example 31] Using the + water prepared in Example 16, the piezoelectric voltage is 16V, the head / ^, water () as the ink ink, and the embodiment 30, the same squeaking device was set as a thief, and the same polyimine insulating film as in Example 30 was used. Evaluation. Its silk shows 4. Lai (iv) light amine film [Example 32], the edge has a sufficient thickness. Using the water prepared in Example 19, the piezoelectric voltage was set to 18 VH ink (16) / inkjet ink, and the imine insulating film was obtained. Different conditions are obtained for the polyimine film obtained into the H line to have a sufficient thickness.

[產業上的可利用性] 膜、===例如可列舉可撓性配線基板用絕緣限定本發揭露如上，然其並非用以和範圍内，當可作些許不脫離本發明之精神範圍當視後附之申請專利飾’因此本發明之保護【圖式簡單_】專__界定者為準。 120 200835754 ZOZJL3piI.doc 圖1是合成例12中所獲得的TrisANITAEA的IR光譜。圖2是合成例12中所獲得的TrisANITAEA的iH-NMR 光譜。圖3是合成例13中所獲得的TrisANITrisAM的IR光譜。圖4是合成例13中所獲得的TrisANITrisAM的 iH-NMR 光譜。[Industrial Applicability] Membrane, === For example, the flexible wiring board is exemplified by the above-described insulation, and it is not intended to be within the scope of the invention. </ RTI> </ RTI> <RTIgt; </ RTI> <RTIgt; 120 200835754 ZOZJL3piI.doc Fig. 1 is an IR spectrum of TrisANITAEA obtained in Synthesis Example 12. 2 is an iH-NMR spectrum of TrisANITAEA obtained in Synthesis Example 12. Fig. 3 is an IR spectrum of TrisANI TrisAM obtained in Synthesis Example 13. 4 is an iH-NMR spectrum of TrisANITrisAM obtained in Synthesis Example 13.

圖5疋合成例14中所獲得的TrisANipARAR〇的汉光譜。圖6疋合成例14中所獲得的TrisANIPARARO的 ^-NMR光譜。圖7是合成例15中所獾〜Fig. 5 is a Han spectrum of TrisANipARAR〇 obtained in Synthesis Example 14. Fig. 6 is a ^-NMR spectrum of TrisANIPARARO obtained in Synthesis Example 14. Figure 7 is a summary of the synthesis example 15

得的 TetrakisANITAM 的 IR 光譜。圖8是合成例15中张從 , ^所獲得的 TetrakisANITAM 的 ^-NMR光譜。【主要元件符號說明】 iit 〇 4 121The IR spectrum of TetrakisANITAM. Fig. 8 is a ^-NMR spectrum of Tetrakis ANITAM obtained in Synthesis Example 15 from . [Main component symbol description] iit 〇 4 121

Claims

200835754 zozi3pif.doc 十、申請專利範圍： 1. 一種喷墨墨水，其含有至少一種經烯基取代之耐地醢亞胺(nadimide)化合物（A)。 2. 如申請專利範圍第1項所述之噴墨墨水，其中上述經烯基取代之耐地醯亞胺化合物（A)是使單胺、二胺、三胺或者四胺與下述式（Γ)所示之經烯基取代之耐地酸酐反應而成的經烯基取代之耐地醯亞胺化合物，200835754 zozi3pif.doc X. Patent Application Range: 1. An inkjet ink containing at least one alkenyl substituted nadimide compound (A). 2. The inkjet ink according to claim 1, wherein the above alkenyl-substituted ruthenium imine compound (A) is a monoamine, a diamine, a triamine or a tetraamine and the following formula ( An alkenyl-substituted ruthenium imine compound formed by reacting an alkenyl-substituted ceric acid anhydride as shown in Γ)

[化1] 〇[Chemical 1] 〇

式（1’）中，R1及R2分別獨立為氫、碳數為1〜12之烧基石反數為3〜6之烯基、竣數為5〜8之環&基、碳數為ό〜12之芳基或者节基中的任一種。 3·如申請專利範圍第1項或第2項所述之喷墨墨水，其中上述經烯基取代之耐地醯亞胺化合物（Α)是下述式 (1)所示之化合物， L化2]In the formula (1'), R1 and R2 are each independently hydrogen, a carbon number of 1 to 12, an alkyl group having an inverse number of 3 to 6 and a ring number of 5 to 8 and a carbon number of ό. Any of aryl or decyl groups of ~12. 3. The inkjet ink according to claim 1 or 2, wherein the alkenyl-substituted ruthenium imine compound (Α) is a compound represented by the following formula (1), 2]

⑴ r芙式=)、中，Rl*R、別獨立為氫、碳數為1〜u 凡土厌數為3〜6之烯基、碳數為5〜8之為6〜12夕：| 说暴、今 2之方基或者苄基中的任一種，n.丨〜4之整』 122 200835754 ZOZI3pif.doc n= ”，ms碳數為1〜12之烷基、碳數為1〜之經基说基、石反數為5〜8之環炫基、石炭數〜^ 芳基、絲、以-{(CqH2q)〇t(CrH2r〇)uCsH2sX}(其中 q、= s為分別獨立選擇的2〜6之整數、t為且u為1〜30之整數、又為氫戋数立 &美、U C： H R4 ί +次者基）表不之聚氧烯基絲以-(RVQH4-R (其中，a表示〇或者i之整數、r 表示碳㈣1〜4之线基、R4表示氫或者碳數為卜4之(1) r 芙 ==, middle, Rl*R, independently hydrogen, carbon number 1~u, the number of bases is 3 to 6 alkenyl, carbon number is 5~8, 6~12 eve:| Said violent, any of the square or benzyl of the present 2, n. 丨 ~ 4 of the whole 』 122 200835754 ZOZI3pif.doc n = ”, ms carbon number is 1~12 alkyl, carbon number is 1~ According to the base, the inverse number of the stone is 5~8, the carboniferous number ~^ aryl, the silk, and -{(CqH2q)〇t(CrH2r〇)uCsH2sX} (where q, = s are independently selected An integer of 2 to 6 and t is an integer of 1 to 30, and is also a hydrogen hydrazine. The UC: H R4 ί + the second base) is a polyoxyalkylene wire-(RVQH4) -R (where a represents an integer of 〇 or i, r represents a carbon (4) 1 to 4, a radical R4 represents hydrogen or a carbon number is 4

烷基）表示之基團、以，dC6H5{其中，τ為偶… c(CH3)2_“ro_、_s_或者·s〇2妨示之基團、或者團的直接鍵絲芳香環的1〜3個氫被織取代之基團， n=2時，R3是碳數為2〜2〇之亞烧基（亞烧基中互相不鄰接的任意亞曱基可被或者-CH=CH_取代，任意氣可被氟取代}、碳數為5〜8之亞環烷基、碳數為6〜12之亞芳基、以_(R)a_C6H4_R5-(其中，a為〇或者丄之整數、R 及R分別獨立為碳數為1〜4之亞烧基）表示之基團、以 -C6H4-T-C6H4- 、 -C6H4-T-C6H4-T.C6H4-或者 -C^T’-QIVl^IVr-QHH其巾，T是單鍵、碳數為i 〜6 之亞烧基、_C(CH3)2-、-C(CF3)2-、_C0_、〇_、各或者 S〇2_，Γ是_CHr或者_〇_}表示之基團、或者此等基團的直接鍵結於芳香環的1〜3個氫被經基取代之基團、式（？）所示之基團或者式（8)所示之基團，式（7)中，x獨立為1〜6之整數、y為1〜70之整數， 123 200835754 za^:>pif.doca group represented by an alkyl group, wherein dC6H5 {where τ is an even... c(CH3)2_"ro_, _s_ or ·s〇2 may be a group, or a direct bond of a group of aromatic rings 1~ 3 hydrogen-substituted groups, when n=2, R3 is a sub-alkyl group having a carbon number of 2 to 2 ( (any sulfhydryl group which is not adjacent to each other in the alkylene group may be substituted by -CH=CH_ Any gas may be substituted by fluorine}, a cycloalkylene group having a carbon number of 5 to 8, an arylene group having a carbon number of 6 to 12, and _(R)a_C6H4_R5- (wherein a is an integer of ruthenium or osmium, R and R are each independently a group represented by a sub-alkyl group having a carbon number of 1 to 4, and -C6H4-T-C6H4-, -C6H4-T-C6H4-T.C6H4- or -C^T'-QIVl ^IVr-QHH towel, T is a single bond, a sub-alkyl group with a carbon number of i~6, _C(CH3)2-, -C(CF3)2-, _C0_, 〇_, each or S〇2_, Γ a group represented by _CHr or _〇_}, or a group or a formula represented by the formula (?) in which one to three hydrogens of the aromatic ring are directly bonded to the aromatic ring. (8) The group shown, in the formula (7), x is independently an integer of 1 to 6, and y is an integer of 1 to 70, 123 200835754 za^:>pif.doc

[化3][Chemical 3]

Me Me Si—OMe Me Si-O

⑺ X Me Me(7) X Me Me

(8) n= 3時，R3為下述式（5 )或者（51)所示之基團， [化4](8) When n=3, R3 is a group represented by the following formula (5) or (51), [Chemical 4]

式（5 )中，R 是氫、氟、氯、-OH、-OCF3、-OCF2H、 -CF3、-CF2H、_CFH2、-OCF2CF2H、-OCF2CFHCF3、或者碳數為1〜10之烷基，式（5)、（5’）中，R4、R5、R6分別獨立，是單鍵、反 -1，4-亞ί哀己基、1，3-二σ惡烧-2,5-二基、1，4-亞苯基、鼠可被氟取代的1，4-亞苯基、或者碳數為1〜10之亞烷基，亞烷基中互相不鄰接的任意亞曱基可被-0-或者-CH=CH-取代，任意氫可被氟取代，n = 4時，R3為下述式（6 )所示之基團， 124 200835754 zozopif.docIn the formula (5), R is hydrogen, fluorine, chlorine, -OH, -OCF3, -OCF2H, -CF3, -CF2H, _CFH2, -OCF2CF2H, -OCF2CFHCF3, or an alkyl group having a carbon number of 1 to 10, 5), (5'), R4, R5, and R6 are each independently, which is a single bond, a trans-1,4-a lysyl group, a 1,3-di-sigma-calcin-2,5-diyl group, a 4-phenylene group, a 1,4-phenylene group in which a mouse may be substituted by fluorine, or an alkylene group having a carbon number of 1 to 10, and any anthracene group in the alkylene group which is not adjacent to each other may be -0- or -CH=CH-substitution, any hydrogen may be substituted by fluorine, and when n=4, R3 is a group represented by the following formula (6), 124 200835754 zozopif.doc

[化5] \ χ\ ⑹ / \ 式（6)中，114、;^、]^、；^分別獨立，是單鍵、反-1，4_ 亞環己基、1，3-二噁烷-2,5-二基、1，4-亞苯基、氫可被氟取代的1，4-亞苯基、或者碳數為1〜1〇之亞烧基，亞燒基中互相不鄰接的任意亞曱基可被-〇-或者-CH=CH-取代，任意氫可被氟取代。 4·如申請專利範圍第3項所述之喷墨墨水，其中η為 5·如申請專利範圍第3項所述之喷墨墨水，其中η為 2， R3是碳數為2〜15之亞烷基{亞烷基中互相不鄰接的任意亞曱基可被-0-或者_CH=CH-取代，任意氫可被氟取代}、以_(R)a_C6H4-R5-(其中，a為〇或者1之整數、R及 R5分別獨立為碳數為1〜4之亞烷基）表示之基團、以 -C6H4-T-C6H4- 、 -C6H4-T-C6H4-T-C6H4-或者 -C6H4-Tf-C6H4-T-C6H4-T’-C6H4-{其中 T 為單鍵、、CH2-、 -C(CH3)2-、-C(CF3)2-、-CO-、-〇、-S-或者-S〇2-，Γ為-CH2- 或者-0-}表示之基團。 6·如申請專利範圍第3項所述之喷墨墨水，其中R1及 R2分別獨立為氫或者碳數為1〜6之烷基， η為2， 125 200835754 zozi^pii.doc R3是碳數為2〜15之亞烷基{亞烷基中互相不鄰接的任意亞曱基可被-0-或者-CH=CH-取代，任意氫可被氟取代}、式（2)所示之基團、式（3)所示之基團、式（4) 所示之基團、式（7)所示之基團或者式（8)所示之基團， [化6][ 5 5] \ χ \ (6) / \ In the formula (6), 114, ; ^, ] ^, ; ^ are independent, are single bond, anti-1,4_ cyclohexylene, 1,3-dioxane - a 2,5-diyl group, a 1,4-phenylene group, a 1,4-phenylene group in which hydrogen can be substituted by fluorine, or a pyridylene group having a carbon number of 1 to 1 fluorene, and the sub-alkyl groups are not adjacent to each other. Any fluorenylene group may be substituted by -〇- or -CH=CH-, and any hydrogen may be substituted by fluorine. 4. The inkjet ink according to claim 3, wherein n is 5. The inkjet ink according to claim 3, wherein η is 2 and R3 is a carbon number of 2 to 15 Any of the alkylidene groups in the alkylene group which are not adjacent to each other may be substituted by -0 or _CH=CH-, and any hydrogen may be substituted by fluorine}, with _(R)a_C6H4-R5- (where a is A group represented by 〇 or an integer of 1 and R and R5 are each independently an alkylene group having 1 to 4 carbon atoms, and is -C6H4-T-C6H4-, -C6H4-T-C6H4-T-C6H4- or - C6H4-Tf-C6H4-T-C6H4-T'-C6H4-{where T is a single bond, CH2-, -C(CH3)2-, -C(CF3)2-, -CO-, -〇, - S- or -S〇2-, Γ is a group represented by -CH2- or -0-}. 6. The inkjet ink according to claim 3, wherein R1 and R2 are each independently hydrogen or an alkyl group having a carbon number of 1 to 6, and η is 2, 125 200835754 zozi^pii.doc R3 is a carbon number An alkylene group of 2 to 15 {any alkylene group which is not adjacent to each other in the alkylene group may be substituted by -0- or -CH=CH-, and any hydrogen may be substituted by fluorine}, a group represented by the formula (2) a group represented by the formula (3), a group represented by the formula (4), a group represented by the formula (7) or a group represented by the formula (8), [Chem. 6]

Me MeMe Me

式（2)及（4)中，R是包括-CH2-、-CH2CH2-、-0·、 C(CH3)2_、_C(CF3)2_、-S02·之有機基，式（4)中，X 是包括_CH2·、0之有機基，式（7)中，X獨立為1〜6之整數、y為1〜70之整數。 126 200835754 ZOZJLOpif.doc 7.如申請專利範圍第3項所述之喷墨墨水，其中R1及 R2分別獨立為氫或者碳數為1〜6之烷基， η為3，R3以式（5-1)、式（5’-1)或者式（5!-2)表示， [化7]In the formulae (2) and (4), R is an organic group including -CH2-, -CH2CH2-, -0, C(CH3)2_, _C(CF3)2_, -S02·, in the formula (4), X is an organic group including _CH2·, 0, and in the formula (7), X is independently an integer of 1 to 6, and y is an integer of 1 to 70. 126. The inkjet ink according to claim 3, wherein R1 and R2 are each independently hydrogen or an alkyl group having a carbon number of 1 to 6, η is 3, and R3 is a formula (5- 1), formula (5'-1) or formula (5!-2) means, [Chem. 7]

式（5·1)中，11是碳數為1〜10之烷基或者-〇11，式（5’-2)中，114、115、116.分別獨立為1，2-亞乙基、 Μ-亞丁基。 8.如申請專利範圍第3項所述之喷墨墨水，其中R1及 R2分別獨立為氫或者碳數為1〜6之烷基， η為4，R3以下述式（6-1)表示， [化8] 127 200835754 ZDZI3piI.docIn the formula (5·1), 11 is an alkyl group having a carbon number of 1 to 10 or -〇11, and in the formula (5'-2), 114, 115, and 116 are each independently 1,2-ethylene group. Μ-butylene. 8. The inkjet ink according to claim 3, wherein R1 and R2 are each independently hydrogen or an alkyl group having 1 to 6 carbon atoms, η is 4, and R3 is represented by the following formula (6-1). [化8] 127 200835754 ZDZI3piI.doc

9.如申請專利範圍第3項所述之噴墨墨水，其中含有選自η為1的經烯基取代之财地醯亞胺化合物（A)、η為 2的經稀基取代之耐地醯亞胺化合物（Α)、η為3的經烯基取代之耐地醯亞胺化合物（Α)、及η為4的經烯基取代之耐地醯亞胺化合物（Α)的至少2種經烯基取代之耐地酸亞胺化合物（Α)。 10·如申請專利範圍第3項所述之噴墨墨水，其中含有經烯基取代之耐地醯亞胺化合物（Α)之至少2種，該經稀，取代之耐地醯亞胺化合物（Α)中，R1及R2分別獨立為氫或者碳數為1〜ό之烷基，朴R3是碳數為1〜12之烷基（η=1)、碳數為6〜12之芳，（η〜為 6〜12 之整數）、式（2-1) 所不之基團、式（3)所示之基團、式（4-1)所示之基團、式（H)所示之基團、式（8)所示之基團、式（5-2)所不之基團、式（5-3)所示之基團、式（5，-1)所示之基團、气（5 所示之基團、式（6-1)所示之基團， 128 200835754 ZDZIDplf.doc [化9]9. The inkjet ink according to claim 3, which comprises an alkali-substituted quinone imine compound (A) selected from η of 1, and a dilute base substituted with η of 2 At least two kinds of quinone imine compounds (Α), an alkenyl-substituted quinone-imine compound (Α) having a η of 3, and an alkenyl-substituted quinone imine compound (Α) having a η of 4 An alkenyl substituted imide compound (Α). 10. The inkjet ink according to claim 3, which comprises at least two of the alkenyl-substituted ruthenium imine compounds (Α), the diluted, substituted ruthenium imine compound ( Α), R1 and R2 are each independently hydrogen or an alkyl group having a carbon number of 1 to fluorene, and R3 is an alkyl group having a carbon number of 1 to 12 (η = 1) and a carbon number of 6 to 12 ( Η〜 is an integer of 6 to 12), a group of the formula (2-1), a group represented by the formula (3), a group represented by the formula (4-1), and a formula (H). a group, a group represented by the formula (8), a group not represented by the formula (5-2), a group represented by the formula (5-3), and a group represented by the formula (5, -1) , gas (group shown by 5, group represented by formula (6-1), 128 200835754 ZDZIDplf.doc [Chemical 9]

(4-1)(4-1)

η 二 2 Me Me H2 \ /H2 \ C—j-Si—O-Si--j- (7-1) Me Me 11=2η 2 2 Me Me H2 \ /H2 \ C—j-Si—O-Si--j- (7-1) Me Me 11=2

(8)(8)

129 200835754 upif.doc129 200835754 upif.doc

η•如申請專利範圍第1項至第2項中任一項所述之噴墨墨水，其巾進而含有高分子化合物⑻。The inkjet ink according to any one of the items 1 to 2, wherein the towel further contains a polymer compound (8).

>12·如申請專利範圍第η項所述之噴墨墨水，其中上述南分子化合物（Β)是聚醯胺酸或者聚醯亞胺之至少工種0 13·如申明專利範圍第η項所述之噴墨墨水，其中上述南分子化合物（Β)之重量平均分子量為丨，_〜5,_。 ,14.如申請專利範圍第1項至第2項中任-項所述之嘖墨墨水’其中進而含有溶劑(C)。、 15. 如申請專利範圍第14項所述之喷墨墨水，劑（C)是選自由乳酸乙醋、乙醇、乙二醇、丙二醇、甘油、二乙二醇二甲鱗、二乙二醇二***、二乙二醚、二乙二醇單乙喊乙_、乙二醇單丁醚、乙 ^ 醚乙酸醋、丙二醇單曱醚乙酸醋、3-曱氧基丙酸曱酽 =基=酸乙酿、環己酮及γ·丁内醋所組成之族群的曰大於 16. 如申請專利範圍第丨項至第2項中任一項所、求+ 墨墨水，其中相對於100重量份喷墨墨水，含有1重曰= 〜99重量份上述經烯基取代之耐地醯亞胺化合物（八^。份 130 200835754 ZDZ13pif.doc 17·如申凊專利範圍第1項至第2項中任一項所述之喷墨墨水^其中相對於100重量份喷墨墨水，含有10重量份〜80重量份上述經烯基取代之耐地醯亞胺化合物（Α)。 18·如申請專利範圍第1項至第2項中任一項所述之噴墨墨水，其中相對於1〇〇重量份喷墨墨水，含有22重量份〜70重置份上述經烯基取代之耐地醯亞胺化合物（Α)。 + I9·一種聚醯亞胺膜或者圖案狀聚醯亞胺膜，其是利用藝贺墨塗佈方法塗佈如申請專利範圍第1項所述之喷墨墨水而形成塗膜，將該塗膜進行加熱處理形成聚醯亞胺膜而庐得。、又 20·—種聚醯亞胺膜形成方法，其包括利用噴墨塗佈方法塗佈如申請專利範圍第i項所述之噴墨墨水而形成塗膜的步驟、及將該塗膜進行加熱處理而形成聚應亞麵的步驟。 21·—種薄膜基板，其是利用如申請專利範圍第2〇項所述之聚醯亞胺膜形成方法於基板上形成聚醯亞胺膜。 22·-種電子零件，其具有如申請專職圍第21項所述之薄膜基板。 131<12. The inkjet ink according to claim n, wherein the above-mentioned southern molecular compound (Β) is at least a working species of polyaminic acid or polyimine. In the inkjet ink, the weight average molecular weight of the above-mentioned southern molecular compound (Β) is 丨, _〜5, _. 14. The inkjet ink according to any one of items 1 to 2 of the patent application, which further contains a solvent (C). 15. The inkjet ink according to claim 14, wherein the agent (C) is selected from the group consisting of ethyl lactate, ethanol, ethylene glycol, propylene glycol, glycerin, diethylene glycol, dimethyl scale, diethylene glycol. Diethyl ether, diethylene ether, diethylene glycol, single ethyl ketone B, ethylene glycol monobutyl ether, ethyl ether acetate vinegar, propylene glycol monoterpene ether acetate vinegar, 3-methoxy oxypropionate 基 = base = The hydrazine of the group consisting of acid ethene, cyclohexanone and γ·butyrol vinegar is greater than 16. According to any one of the claims 2 to 2, the ink is obtained, wherein the ink is relative to 100 parts by weight. Inkjet ink, containing 1 weight 曰 = ～99 parts by weight of the above alkenyl-substituted ruthenium imine compound (eight ^. part 130 200835754 ZDZ13pif.doc 17 · as claimed in the scope of patents 1 to 2 Any one of the inkjet inks according to any one of the invention comprising 10 parts by weight to 80 parts by weight of the above-mentioned alkenyl-substituted ruthenium imine compound (Α) with respect to 100 parts by weight of the inkjet ink. The inkjet ink according to any one of the items 1 to 2, wherein the inkjet ink contains 22 parts by weight with respect to 1 part by weight of the inkjet ink. 〜70 restoring the above alkenyl-substituted ruthenium imine compound (Α). + I9·a polyimide film or a patterned polyimide film coated by an arthroic coating method A coating film is formed by applying the inkjet ink according to the first aspect of the patent, and the coating film is heat-treated to form a polyimide film, and a method for forming a polyimide film is disclosed. A step of forming a coating film by applying an inkjet ink according to the item i of the patent application of the inkjet coating method, and a step of heat-treating the coating film to form a polyhedral surface. A film substrate obtained by forming a polyimide film on a substrate by the method for forming a polyimide film according to the second aspect of the patent application. 22--Electronic parts having the 21st item as the application full-time The film substrate. 131