SG49573A1 - Aldolisation-dehydration process - Google Patents
Aldolisation-dehydration processInfo
- Publication number
- SG49573A1 SG49573A1 SG1995001941A SG1995001941A SG49573A1 SG 49573 A1 SG49573 A1 SG 49573A1 SG 1995001941 A SG1995001941 A SG 1995001941A SG 1995001941 A SG1995001941 A SG 1995001941A SG 49573 A1 SG49573 A1 SG 49573A1
- Authority
- SG
- Singapore
- Prior art keywords
- aldehyde
- aldolisation
- section
- distillation
- catalyst solution
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
- C07C45/66—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups by dehydration
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
- C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Iron Core Of Rotating Electric Machines (AREA)
- Glass Compositions (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB929207756A GB9207756D0 (en) | 1992-04-07 | 1992-04-07 | Process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SG49573A1 true SG49573A1 (en) | 1998-06-15 |
Family
ID=10713712
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SG1995001941A SG49573A1 (en) | 1992-04-07 | 1993-04-07 | Aldolisation-dehydration process |
Country Status (24)
| Country | Link |
|---|---|
| US (1) | US5434313A (ko) |
| EP (2) | EP0751109A1 (ko) |
| JP (1) | JP3618099B2 (ko) |
| KR (1) | KR100278134B1 (ko) |
| CN (1) | CN1058697C (ko) |
| AT (1) | ATE162169T1 (ko) |
| AU (1) | AU659554B2 (ko) |
| BR (1) | BR9306208A (ko) |
| CA (1) | CA2133764A1 (ko) |
| DE (1) | DE69316349T2 (ko) |
| ES (1) | ES2114045T3 (ko) |
| FI (1) | FI944619A (ko) |
| GB (1) | GB9207756D0 (ko) |
| HU (1) | HUT69744A (ko) |
| IN (1) | IN181962B (ko) |
| MX (1) | MX9302044A (ko) |
| NO (1) | NO943694L (ko) |
| RO (1) | RO117969B1 (ko) |
| RU (1) | RU2113429C1 (ko) |
| SA (1) | SA93130546B1 (ko) |
| SG (1) | SG49573A1 (ko) |
| TW (1) | TW241254B (ko) |
| WO (1) | WO1993020034A1 (ko) |
| ZA (1) | ZA932451B (ko) |
Families Citing this family (64)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5667644A (en) * | 1995-02-13 | 1997-09-16 | Mitsubishi Chemical Corporation | Method for producing a dimerized aldehyde |
| GB9519975D0 (en) * | 1995-09-28 | 1995-11-29 | Davy Process Techn Ltd | Process |
| EP0838435A1 (en) | 1996-10-25 | 1998-04-29 | Kvaerner Process Technology Limited | Process and plant for treating an aqueous waste stream containing alkali metal carboxylates |
| DE19956410A1 (de) * | 1999-11-24 | 2001-05-31 | Oxeno Olefinchemie Gmbh | Verfahren zur Durchführung von Aldolkondensationen |
| ATE493374T1 (de) | 2002-04-26 | 2011-01-15 | Basf Se | Alkoxylatgemische und diese enthaltende waschmittel |
| JP4112500B2 (ja) | 2002-04-26 | 2008-07-02 | ビーエーエスエフ ソシエタス・ヨーロピア | Ｃ１０−アルカノールアルコキシラート類及びその使用 |
| WO2003091192A1 (de) * | 2002-04-26 | 2003-11-06 | Basf Aktiengesellschaft | C10 -alkanolalkoxylat-gemische und ihre verwendung |
| DE10243366A1 (de) | 2002-09-18 | 2004-04-01 | Basf Ag | Herstellung von Alkoxylaten bei optimierten Reaktionsdrücken |
| DE10249912A1 (de) | 2002-10-26 | 2004-05-06 | Oxeno Olefinchemie Gmbh | Benzoesäureisodecyclestergemische, Herstellung und deren Verwendung |
| US6960694B2 (en) * | 2003-07-01 | 2005-11-01 | Eastman Chemical Company | Processes for preparing β-hydroxy-ketones and α,β-unsaturated ketones |
| DE10348420A1 (de) * | 2003-10-14 | 2005-05-25 | Basf Ag | C10-Alkanolalkoxylat-Gemische und ihre Verwendung - Neue schaumarme Netzer |
| US7071361B2 (en) * | 2004-06-25 | 2006-07-04 | Fastman Chemical Company | Processes for the preparation of high molecular weight saturated ketones |
| AR051861A1 (es) * | 2004-12-24 | 2007-02-14 | Basf Ag | Composicion acuosa, procedimiento para extraer metales y utilizacion de agentes tensioactivos no ionicos en la extraccion de metal. |
| US7291748B2 (en) * | 2005-07-28 | 2007-11-06 | Basf Corporation | C10/C7 ester mixtures based on 2-propylheptanol |
| WO2008068307A2 (en) * | 2006-12-07 | 2008-06-12 | Basf Se | Compositions and kits comprising a fungicidal triazole and an alkoxylated alcohol, and their uses |
| WO2008092809A1 (de) * | 2007-01-29 | 2008-08-07 | Basf Se | Verzweigte decylnitrate und ihre verwendung als verbrennungsverbesserer und/oder cetanzahlverbesserer in kraftstoffen |
| TW201031743A (en) | 2008-12-18 | 2010-09-01 | Basf Se | Surfactant mixture comprising branched short-chain and branched long-chain components |
| DE102009001594A1 (de) * | 2009-03-17 | 2010-09-30 | Evonik Oxeno Gmbh | Verfahren zur Herstellung von alpha, beta-ungesättigten C10-Aldehyden |
| DE102009028976A1 (de) | 2009-08-28 | 2011-03-03 | Evonik Oxeno Gmbh | Ester der 2,5-Furandicarbonsäure mit isomeren Decanolen und ihre Verwendung |
| DE102009045139A1 (de) * | 2009-09-30 | 2011-03-31 | Evonik Oxeno Gmbh | Herstellung von alpha,beta-ungesättigten Aldehyden mittels einer Reaktionsmischpumpe |
| WO2011054782A1 (de) | 2009-11-05 | 2011-05-12 | Basf Se | Kleb- und dichtstoffe enthaltend ester auf basis von 2-propylheptanol |
| SG187691A1 (en) | 2010-08-03 | 2013-03-28 | Basf Se | Carrier fluids for abrasives |
| US9365715B2 (en) | 2010-12-23 | 2016-06-14 | Styrolution Europe Gmbh | Thermoplastic elastomer composition and method for the production thereof |
| DE102011121087A1 (de) | 2011-12-14 | 2013-06-20 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur katalytischen Kondensation oder Kopplung |
| US8742177B2 (en) | 2011-12-28 | 2014-06-03 | Rohm And Haas Company | Catalyst and process to produce branched unsaturated aldehydes |
| CN104204161B (zh) | 2012-02-01 | 2017-05-17 | 巴斯夫欧洲公司 | 用于晶片生产的冷却和/或润滑流体 |
| US9006495B2 (en) | 2012-11-30 | 2015-04-14 | Basf Se | Process for the catalytic aldol condensation of aldehydes |
| JP6362612B2 (ja) | 2012-11-30 | 2018-07-25 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 触媒を用いてアルデヒドをアルドール縮合するための方法 |
| TWI654177B (zh) | 2013-10-31 | 2019-03-21 | 德商巴斯夫歐洲公司 | 製備羧酸酯的方法及其作爲塑化劑的用途 |
| ES2675527T3 (es) | 2013-12-06 | 2018-07-11 | Basf Se | Composición plastificante que contiene derivados de tetrahidrofurano y ésteres de ácido 1,2-ciclohexano dicarboxílico |
| RU2016132589A (ru) | 2014-01-09 | 2018-02-12 | Басф Се | Композиция пластификатора, которая содержит производные фурана и сложные эфиры 1,2-циклогександикарбоновой кислоты |
| RU2016145450A (ru) | 2014-04-22 | 2018-05-22 | Басф Се | Способ получения сложных эфиров карбоновых кислот в присутствии ионной жидкости и кислотного катализатора этерификации и их применение в качестве пластификатора |
| DE102015207291A1 (de) | 2014-04-24 | 2016-03-10 | Basf Se | Weichmacher-Zusammensetzung, die Furanderivate und 1,2-Cyclohexandicarbonsäureester enthält |
| FR3021314B1 (fr) * | 2014-05-26 | 2016-05-13 | Rhodia Operations | Procede de preparation de composes p-hydroxymandeliques en reacteurs agites |
| TW201609628A (zh) | 2014-07-08 | 2016-03-16 | 巴斯夫歐洲公司 | 包含脂族二羧酸二酯及對苯二甲酸二烷基酯之塑化劑組成物 |
| TW201605945A (zh) | 2014-07-08 | 2016-02-16 | 巴斯夫歐洲公司 | 包含二羧酸的酯及１，２－環己烷二羧酸的酯之模製化合物 |
| TWI706979B (zh) | 2014-08-19 | 2020-10-11 | 德商巴斯夫歐洲公司 | 包含聚合二羧酸酯的塑化劑組成物 |
| TWI686444B (zh) | 2014-09-04 | 2020-03-01 | 德商巴斯夫歐洲公司 | 包含聚合二羧酸酯的塑化劑組成物 |
| DE202014007140U1 (de) | 2014-09-08 | 2014-10-22 | Basf Se | Öl-basierte Bohrflüssigkeiten mit Copolymeren aus Styrol, (Meth)acrylaten von C10-Alkoholgemischen und (Meth)acrylsäure |
| DE202014007136U1 (de) | 2014-09-08 | 2014-10-16 | Basf Se | Härtbare Zusammensetzung, hergestellt mit einem aus (Meth)acrylaten von C10-Alkoholgemischen aufgebauten Copolymer |
| TW201619119A (zh) | 2014-10-09 | 2016-06-01 | 巴斯夫歐洲公司 | 包含飽和二羧酸之環烷基酯及１，２－環己烷二羧酸酯的塑化劑組成物 |
| TW201619120A (zh) | 2014-10-09 | 2016-06-01 | 巴斯夫歐洲公司 | 包含飽和二羧酸之環烷基酯及對苯二甲酯之塑化劑組成物 |
| CN107001523A (zh) | 2014-11-10 | 2017-08-01 | 巴斯夫欧洲公司 | 乙烯‑(甲基)丙烯酸丙基庚基酯共聚物 |
| RU2706647C2 (ru) | 2015-01-30 | 2019-11-19 | Басф Се | Пластифицирующая композиция, содержащая полимерные сложные эфиры дикарбоновых кислот и диалкиловые сложные эфиры терефталевой кислоты |
| EP3356457B2 (de) | 2015-09-30 | 2022-12-21 | Basf Se | Weichmacher-zusammensetzung, die polymere dicarbonsäureester und 1,2-cyclohexandicarbonsäureester enthält |
| US20180282511A1 (en) | 2015-09-30 | 2018-10-04 | Basf Se | Plasticizer composition containing polymeric dicarboxylic acid esters and terephthalic acid dialkyl esters |
| EP3356459B1 (de) | 2015-09-30 | 2019-11-13 | Basf Se | Weichmacher-zusammensetzung, die polymere dicarbonsäureester und dicarbonsäurediester enthält |
| RU2729055C2 (ru) | 2016-01-20 | 2020-08-04 | Басф Се | Пластифицирующая композиция, которая содержит алифатический сложный эфир дикарбоновой кислоты и сложный диэфир, выбранный из сложных эфиров 1,2-циклогександикарбоновой кислоты и сложных эфиров терефталевой кислоты |
| EP3433309B1 (de) | 2016-03-23 | 2020-05-13 | Basf Se | Polymer-zusammensetzung, enthaltend einen cycloalkyl-alkyl-dicarbonsäurediester als weichmacher |
| WO2018024591A1 (de) | 2016-08-01 | 2018-02-08 | Basf Se | Weichmacher-zusammensetzung |
| WO2018024597A1 (de) | 2016-08-01 | 2018-02-08 | Basf Se | Weichmacher-zusammensetzung |
| EP3491054A1 (de) | 2016-08-01 | 2019-06-05 | Basf Se | Weichmacher-zusammensetzung |
| ES2714899T3 (es) | 2016-09-30 | 2019-05-30 | Oxea Gmbh | Método de producción continuo para 2-metilenos-alcanales |
| GB201617463D0 (en) | 2016-10-14 | 2016-11-30 | Johnson Matthey Davy Technologies Limited | Process |
| JP7000457B2 (ja) * | 2017-05-25 | 2022-02-04 | ローム アンド ハース カンパニー | メタクロレインを調製するためのプロセス |
| US11214533B2 (en) | 2017-06-28 | 2022-01-04 | Dow Global Technologies Llc | Readily biodegradable alkoxylate mixtures |
| WO2019185409A1 (de) | 2018-03-29 | 2019-10-03 | Basf Se | Pvc-zusammensetzung, enthaltend wenigstens einen weichmacher der wenigstens eine carbonsäureestergruppe aufweist und wenigstens eine carbodiimidverbindung |
| CN108658742B (zh) * | 2018-04-27 | 2021-08-17 | 宿迁科思化学有限公司 | 一种铃兰醛关键中间体对叔丁基-α-甲基苯丙烯醛的制备方法 |
| EP3747860B1 (de) | 2019-06-04 | 2023-07-26 | Basf Se | Neue weichmacher auf cyclohexanon-basis |
| EP3786146A1 (de) * | 2019-08-30 | 2021-03-03 | Röhm GmbH | Verfahren zur herstellung von methacrolein aus formaldehyd und propionaldehyd sowie herstellanlage hierfür |
| KR102675020B1 (ko) * | 2019-10-08 | 2024-06-14 | 한화솔루션 주식회사 | 알돌 축합 반응 장치 |
| CN116063167A (zh) * | 2021-11-01 | 2023-05-05 | 中国石油化工股份有限公司 | 一种制备2-丙基-2-庚烯醛的方法及装置和所得2-丙基-2-庚烯醛 |
| GB202213997D0 (en) | 2022-09-26 | 2022-11-09 | Johnson Matthey Davy Technologies Ltd | Parallel zone hydroformylation reaction |
| CN117229132B (zh) * | 2023-11-10 | 2024-02-20 | 济南悟通生物科技有限公司 | 一种反式-2,4-壬二烯醛的合成方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB549006A (en) * | 1940-02-12 | 1942-11-03 | Shell Dev | Condensation of carbonylic compounds |
| FR1036156A (fr) * | 1951-04-25 | 1953-09-04 | Melle Usines Sa | Procédé de préparation d'aldéhydes aliphatiques non saturées |
| US3248428A (en) * | 1961-12-22 | 1966-04-26 | Exxon Research Engineering Co | Aldolization process |
| GB1010695A (en) * | 1961-12-22 | 1965-11-24 | Exxon Research Engineering Co | Process for the production of alpha, beta unsaturated carbonyl compounds |
| DE3106557A1 (de) * | 1981-02-21 | 1982-09-16 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von (alpha)-alkylacroleinen |
| DE3740293A1 (de) * | 1987-11-27 | 1989-06-01 | Hoechst Ag | Verfahren zur herstellung von alpha-alkylacroleinen |
| CA2068489A1 (en) * | 1991-05-16 | 1992-11-17 | Masaru Ishino | Aldol condensation dehydration catalyst, a process for preparing the same and a process for preparing an aldol condensation dehydrate using the process |
-
1992
- 1992-04-07 GB GB929207756A patent/GB9207756D0/en active Pending
-
1993
- 1993-04-05 ZA ZA932451A patent/ZA932451B/xx unknown
- 1993-04-06 IN IN245MA1993 patent/IN181962B/en unknown
- 1993-04-07 BR BR9306208A patent/BR9306208A/pt not_active IP Right Cessation
- 1993-04-07 ES ES93909038T patent/ES2114045T3/es not_active Expired - Lifetime
- 1993-04-07 WO PCT/GB1993/000729 patent/WO1993020034A1/en active IP Right Grant
- 1993-04-07 RO RO94-01620A patent/RO117969B1/ro unknown
- 1993-04-07 HU HU9402893A patent/HUT69744A/hu unknown
- 1993-04-07 RU RU94045865A patent/RU2113429C1/ru active
- 1993-04-07 AU AU39587/93A patent/AU659554B2/en not_active Ceased
- 1993-04-07 SG SG1995001941A patent/SG49573A1/en unknown
- 1993-04-07 EP EP96115200A patent/EP0751109A1/en not_active Withdrawn
- 1993-04-07 DE DE69316349T patent/DE69316349T2/de not_active Expired - Lifetime
- 1993-04-07 KR KR1019940703548A patent/KR100278134B1/ko not_active IP Right Cessation
- 1993-04-07 CA CA002133764A patent/CA2133764A1/en not_active Abandoned
- 1993-04-07 MX MX9302044A patent/MX9302044A/es unknown
- 1993-04-07 CN CN93104066A patent/CN1058697C/zh not_active Expired - Lifetime
- 1993-04-07 AT AT93909038T patent/ATE162169T1/de not_active IP Right Cessation
- 1993-04-07 US US08/313,298 patent/US5434313A/en not_active Expired - Lifetime
- 1993-04-07 JP JP51727493A patent/JP3618099B2/ja not_active Expired - Lifetime
- 1993-04-07 EP EP93909038A patent/EP0634994B1/en not_active Expired - Lifetime
- 1993-04-28 TW TW082103289A patent/TW241254B/zh not_active IP Right Cessation
- 1993-05-19 SA SA93130546A patent/SA93130546B1/ar unknown
-
1994
- 1994-10-04 NO NO943694A patent/NO943694L/no unknown
- 1994-10-04 FI FI944619A patent/FI944619A/fi unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE69316349D1 (de) | 1998-02-19 |
| SA93130546B1 (ar) | 2004-08-29 |
| CN1058697C (zh) | 2000-11-22 |
| RU94045865A (ru) | 1996-08-10 |
| NO943694D0 (no) | 1994-10-04 |
| IN181962B (ko) | 1998-11-21 |
| JPH07505390A (ja) | 1995-06-15 |
| KR100278134B1 (ko) | 2001-02-01 |
| RU2113429C1 (ru) | 1998-06-20 |
| EP0634994A1 (en) | 1995-01-25 |
| EP0634994B1 (en) | 1998-01-14 |
| TW241254B (ko) | 1995-02-21 |
| MX9302044A (es) | 1994-07-29 |
| US5434313A (en) | 1995-07-18 |
| CA2133764A1 (en) | 1993-10-14 |
| AU659554B2 (en) | 1995-05-18 |
| AU3958793A (en) | 1993-11-08 |
| WO1993020034A1 (en) | 1993-10-14 |
| HUT69744A (en) | 1995-09-28 |
| DE69316349T2 (de) | 1998-07-23 |
| ES2114045T3 (es) | 1998-05-16 |
| GB9207756D0 (en) | 1992-05-27 |
| KR950700869A (ko) | 1995-02-20 |
| ZA932451B (en) | 1993-10-20 |
| ATE162169T1 (de) | 1998-01-15 |
| EP0751109A1 (en) | 1997-01-02 |
| NO943694L (no) | 1994-12-06 |
| RO117969B1 (ro) | 2002-11-29 |
| JP3618099B2 (ja) | 2005-02-09 |
| FI944619A0 (fi) | 1994-10-04 |
| BR9306208A (pt) | 1998-06-23 |
| CN1105012A (zh) | 1995-07-12 |
| FI944619A (fi) | 1994-10-04 |
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