SE456426B - Stabiliserad enzyminnehallande detergentberedning - Google Patents

Stabiliserad enzyminnehallande detergentberedning

Info

Publication number: SE456426B
Authority: SE; Sweden
Prior art keywords: weight; formulation; acid; soap; carbon atoms
Prior art date: 1982-08-30

Application number

SE8304663A

Other languages

English (en)

Swedish (sv)

Other versions

SE8304663D0 (sv

SE8304663L (sv

Inventor

M Dormal

J Noiret

Original Assignee

Colgate Palmolive Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-08-30

Filing date

1983-08-29

Publication date

1988-10-03

1983-08-29 Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co

1983-08-29 Publication of SE8304663D0 publication Critical patent/SE8304663D0/xx

1984-03-01 Publication of SE8304663L publication Critical patent/SE8304663L/

1988-10-03 Publication of SE456426B publication Critical patent/SE456426B/sv

Links

239000003599 detergent Substances 0.000 title claims description 47
238000002360 preparation method Methods 0.000 title claims description 34
239000000203 mixture Substances 0.000 claims description 56
238000009472 formulation Methods 0.000 claims description 36
125000004432 carbon atom Chemical group C* 0.000 claims description 31
125000000217 alkyl group Chemical group 0.000 claims description 23
-1 nonionic Chemical group 0.000 claims description 21
102000004190 Enzymes Human genes 0.000 claims description 19
108090000790 Enzymes Proteins 0.000 claims description 19
229940088598 enzyme Drugs 0.000 claims description 19
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 15
239000000344 soap Substances 0.000 claims description 15
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
150000001875 compounds Chemical class 0.000 claims description 13
150000003839 salts Chemical class 0.000 claims description 12
239000003381 stabilizer Substances 0.000 claims description 12
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 10
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 9
229910001424 calcium ion Inorganic materials 0.000 claims description 9
239000007788 liquid Substances 0.000 claims description 9
KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 9
108091005804 Peptidases Proteins 0.000 claims description 7
102000035195 Peptidases Human genes 0.000 claims description 7
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 7
239000002904 solvent Substances 0.000 claims description 7
125000000129 anionic group Chemical group 0.000 claims description 6
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 5
102000013142 Amylases Human genes 0.000 claims description 5
108010065511 Amylases Proteins 0.000 claims description 5
239000001361 adipic acid Substances 0.000 claims description 5
235000011037 adipic acid Nutrition 0.000 claims description 5
150000004671 saturated fatty acids Chemical class 0.000 claims description 5
239000003352 sequestering agent Substances 0.000 claims description 5
235000019418 amylase Nutrition 0.000 claims description 4
239000001384 succinic acid Substances 0.000 claims description 4
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 3
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 3
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 3
239000005639 Lauric acid Substances 0.000 claims description 3
239000005642 Oleic acid Substances 0.000 claims description 3
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 3
229940025131 amylases Drugs 0.000 claims description 3
125000002091 cationic group Chemical group 0.000 claims description 3
239000003795 chemical substances by application Substances 0.000 claims description 3
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 3
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 3
229920005862 polyol Polymers 0.000 claims description 3
150000003077 polyols Chemical class 0.000 claims description 3
150000004670 unsaturated fatty acids Chemical class 0.000 claims description 3
235000021122 unsaturated fatty acids Nutrition 0.000 claims description 3
239000004365 Protease Substances 0.000 claims description 2
159000000007 calcium salts Chemical class 0.000 claims description 2
239000013543 active substance Substances 0.000 claims 1
230000000087 stabilizing effect Effects 0.000 claims 1
239000011734 sodium Substances 0.000 description 26
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 12
229910052708 sodium Inorganic materials 0.000 description 11
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 10
125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 8
239000002253 acid Substances 0.000 description 7
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
150000002191 fatty alcohols Chemical class 0.000 description 6
229910052700 potassium Inorganic materials 0.000 description 6
239000011591 potassium Substances 0.000 description 6
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 5
150000007513 acids Chemical class 0.000 description 5
239000007859 condensation product Substances 0.000 description 5
230000002209 hydrophobic effect Effects 0.000 description 5
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
229910052791 calcium Inorganic materials 0.000 description 4
239000011575 calcium Substances 0.000 description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
239000012188 paraffin wax Substances 0.000 description 4
239000004094 surface-active agent Substances 0.000 description 4
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 3
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
239000000654 additive Substances 0.000 description 3
150000001298 alcohols Chemical class 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
150000003863 ammonium salts Chemical class 0.000 description 3
150000001450 anions Chemical group 0.000 description 3
239000001110 calcium chloride Substances 0.000 description 3
229910001628 calcium chloride Inorganic materials 0.000 description 3
235000014113 dietary fatty acids Nutrition 0.000 description 3
239000000194 fatty acid Substances 0.000 description 3
229930195729 fatty acid Natural products 0.000 description 3
125000001165 hydrophobic group Chemical group 0.000 description 3
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 3
159000000000 sodium salts Chemical class 0.000 description 3
239000003760 tallow Substances 0.000 description 3
XINQFOMFQFGGCQ-UHFFFAOYSA-L (2-dodecoxy-2-oxoethyl)-[6-[(2-dodecoxy-2-oxoethyl)-dimethylazaniumyl]hexyl]-dimethylazanium;dichloride Chemical compound [Cl-].[Cl-].CCCCCCCCCCCCOC(=O)C[N+](C)(C)CCCCCC[N+](C)(C)CC(=O)OCCCCCCCCCCCC XINQFOMFQFGGCQ-UHFFFAOYSA-L 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
235000013162 Cocos nucifera Nutrition 0.000 description 2
244000060011 Cocos nucifera Species 0.000 description 2
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
OFOBLEOULBTSOW-UHFFFAOYSA-L Malonate Chemical compound [O-]C(=O)CC([O-])=O OFOBLEOULBTSOW-UHFFFAOYSA-L 0.000 description 2
229920002125 Sokalan® Polymers 0.000 description 2
108010056079 Subtilisins Proteins 0.000 description 2
102000005158 Subtilisins Human genes 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
150000004996 alkyl benzenes Chemical class 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
125000003368 amide group Chemical group 0.000 description 2
150000001408 amides Chemical class 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
150000008107 benzenesulfonic acids Chemical class 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000003093 cationic surfactant Substances 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 description 2
DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical class OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
ATJCASULPHYKHT-UHFFFAOYSA-N hexadecane-1,16-diamine Chemical compound NCCCCCCCCCCCCCCCCN ATJCASULPHYKHT-UHFFFAOYSA-N 0.000 description 2
IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
VMPHSYLJUKZBJJ-UHFFFAOYSA-N lauric acid triglyceride Natural products CCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCC)COC(=O)CCCCCCCCCCC VMPHSYLJUKZBJJ-UHFFFAOYSA-N 0.000 description 2
108010003855 mesentericopeptidase Proteins 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
125000004433 nitrogen atom Chemical group N* 0.000 description 2
239000002736 nonionic surfactant Substances 0.000 description 2
239000003921 oil Substances 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
239000000047 product Substances 0.000 description 2
150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
125000001424 substituent group Chemical group 0.000 description 2
KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 2
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
125000001174 sulfone group Chemical group 0.000 description 2
229940095064 tartrate Drugs 0.000 description 2
QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
JKTAIYGNOFSMCE-UHFFFAOYSA-N 2,3-di(nonyl)phenol Chemical compound CCCCCCCCCC1=CC=CC(O)=C1CCCCCCCCC JKTAIYGNOFSMCE-UHFFFAOYSA-N 0.000 description 1
TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
AEDQNOLIADXSBB-UHFFFAOYSA-N 3-(dodecylazaniumyl)propanoate Chemical compound CCCCCCCCCCCCNCCC(O)=O AEDQNOLIADXSBB-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
239000004382 Amylase Substances 0.000 description 1
KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
FVIGODVHAVLZOO-UHFFFAOYSA-N Dixanthogen Chemical compound CCOC(=S)SSC(=S)OCC FVIGODVHAVLZOO-UHFFFAOYSA-N 0.000 description 1
229940120146 EDTMP Drugs 0.000 description 1
DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
235000021360 Myristic acid Nutrition 0.000 description 1
TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
235000021314 Palmitic acid Nutrition 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
239000002202 Polyethylene glycol Substances 0.000 description 1
239000004721 Polyphenylene oxide Chemical class 0.000 description 1
229920000388 Polyphosphate Polymers 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
239000004480 active ingredient Substances 0.000 description 1
125000002015 acyclic group Chemical group 0.000 description 1
125000002252 acyl group Chemical group 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
239000002671 adjuvant Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
150000008051 alkyl sulfates Chemical class 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
150000003868 ammonium compounds Chemical class 0.000 description 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical class N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
229960003237 betaine Drugs 0.000 description 1
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
150000001669 calcium Chemical class 0.000 description 1
VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
239000001639 calcium acetate Substances 0.000 description 1
235000011092 calcium acetate Nutrition 0.000 description 1
229960005147 calcium acetate Drugs 0.000 description 1
229960002713 calcium chloride Drugs 0.000 description 1
235000011148 calcium chloride Nutrition 0.000 description 1
FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 1
239000001354 calcium citrate Substances 0.000 description 1
229960004256 calcium citrate Drugs 0.000 description 1
239000004281 calcium formate Substances 0.000 description 1
229940044172 calcium formate Drugs 0.000 description 1
235000019255 calcium formate Nutrition 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
150000001734 carboxylic acid salts Chemical class 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
150000004985 diamines Chemical class 0.000 description 1
150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
239000000975 dye Substances 0.000 description 1
NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical class OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
YZSJUQIFYHUSKU-UHFFFAOYSA-N ethanol;propane-1,2-diol Chemical compound CCO.CC(O)CO YZSJUQIFYHUSKU-UHFFFAOYSA-N 0.000 description 1
150000002169 ethanolamines Chemical class 0.000 description 1
VOTNXLNTNMCSTJ-UHFFFAOYSA-N ethyl hydrogen sulfite Chemical compound CCOS(O)=O VOTNXLNTNMCSTJ-UHFFFAOYSA-N 0.000 description 1
ZAPUWVBRCYPPQT-UHFFFAOYSA-N ethyl(18-methylnonadecyl)azanium;chloride Chemical compound [Cl-].CC[NH2+]CCCCCCCCCCCCCCCCCC(C)C ZAPUWVBRCYPPQT-UHFFFAOYSA-N 0.000 description 1
239000004744 fabric Substances 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
239000001530 fumaric acid Substances 0.000 description 1
239000003752 hydrotrope Substances 0.000 description 1
230000003165 hydrotropic effect Effects 0.000 description 1
POIZGMCHYSVWDU-UHFFFAOYSA-N icosane-1,20-diamine Chemical compound NCCCCCCCCCCCCCCCCCCCCN POIZGMCHYSVWDU-UHFFFAOYSA-N 0.000 description 1
150000002460 imidazoles Chemical class 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229940079865 intestinal antiinfectives imidazole derivative Drugs 0.000 description 1
YECIFGHRMFEPJK-UHFFFAOYSA-N lidocaine hydrochloride monohydrate Chemical compound O.[Cl-].CC[NH+](CC)CC(=O)NC1=C(C)C=CC=C1C YECIFGHRMFEPJK-UHFFFAOYSA-N 0.000 description 1
125000005647 linker group Chemical group 0.000 description 1
239000012263 liquid product Substances 0.000 description 1
150000004668 long chain fatty acids Chemical class 0.000 description 1
150000002680 magnesium Chemical class 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
125000000896 monocarboxylic acid group Chemical group 0.000 description 1
LMTSQIZQTFBYRL-UHFFFAOYSA-N n'-octadecylethane-1,2-diamine Chemical compound CCCCCCCCCCCCCCCCCCNCCN LMTSQIZQTFBYRL-UHFFFAOYSA-N 0.000 description 1
SPTAJTRODSJRMF-UHFFFAOYSA-N n,n-dimethylheptadecan-1-amine;hydrochloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCC[NH+](C)C SPTAJTRODSJRMF-UHFFFAOYSA-N 0.000 description 1
WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 1
125000006353 oxyethylene group Chemical group 0.000 description 1
239000006174 pH buffer Substances 0.000 description 1
239000002304 perfume Substances 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
229920000570 polyether Chemical class 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical class [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
235000011151 potassium sulphates Nutrition 0.000 description 1
150000003138 primary alcohols Chemical class 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
235000003441 saturated fatty acids Nutrition 0.000 description 1
235000019333 sodium laurylsulphate Nutrition 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000000243 solution Substances 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
235000013337 tricalcium citrate Nutrition 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)
Cosmetics (AREA)

SE8304663A 1982-08-30 1983-08-29 Stabiliserad enzyminnehallande detergentberedning SE456426B (sv)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US06/412,690 US4529525A (en)	1982-08-30	1982-08-30	Stabilized enzyme-containing detergent compositions

Publications (3)

Publication Number	Publication Date
SE8304663D0 SE8304663D0 (sv)	1983-08-29
SE8304663L SE8304663L (sv)	1984-03-01
SE456426B true SE456426B (sv)	1988-10-03

Family

ID=23634046

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SE8304663A SE456426B (sv)	1982-08-30	1983-08-29	Stabiliserad enzyminnehallande detergentberedning

Country Status (22)

Country	Link
US (1)	US4529525A (el)
AT (1)	AT394205B (el)
AU (1)	AU552398B2 (el)
BE (1)	BE897610A (el)
BR (1)	BR8304644A (el)
CA (1)	CA1207256A (el)
CH (1)	CH657372A5 (el)
DE (1)	DE3330323A1 (el)
DK (1)	DK159554C (el)
ES (1)	ES8600380A1 (el)
FR (1)	FR2532324B1 (el)
GB (3)	GB2126242B (el)
GR (1)	GR78984B (el)
IT (1)	IT1168886B (el)
MX (1)	MX158409A (el)
NL (1)	NL8302942A (el)
NO (1)	NO157460C (el)
NZ (1)	NZ205257A (el)
PH (1)	PH19070A (el)
PT (1)	PT77260B (el)
SE (1)	SE456426B (el)
ZA (1)	ZA836073B (el)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ATE34767T1 (de) *	1983-02-14	1988-06-15	Procter & Gamble	Stabilisierte waessrige enzymzusammensetzung.
GB8311314D0 (en) *	1983-04-26	1983-06-02	Unilever Plc	Aqueous enzyme-containing compositions
FR2556364B1 (fr) *	1983-12-10	1989-10-27	Sandoz Sa	Compositions detergentes liquides exemptes de phosphate
US4537707A (en) *	1984-05-14	1985-08-27	The Procter & Gamble Company	Liquid detergents containing boric acid and formate to stabilize enzymes
US4537706A (en) *	1984-05-14	1985-08-27	The Procter & Gamble Company	Liquid detergents containing boric acid to stabilize enzymes
EP0162033B1 (en) *	1984-05-14	1989-12-13	The Procter & Gamble Company	Liquid detergents containing boric acid to stabilize enzymes
CA1263944A (en) *	1984-09-12	1989-12-19	Barbara H. Munk	Pre-wash compositions containing enzymes
GB8424812D0 (en) *	1984-10-02	1984-11-07	Unilever Plc	Enzymatic detergent composition
EP0199405B1 (en) *	1985-04-15	1992-06-24	The Procter & Gamble Company	Liquid detergents containing surfactant, proteolytic enzyme and boric acid
SE468518B (sv) *	1985-07-26	1993-02-01	Colgate Palmolive Co	Stabiliserad textilmjukgoerande enzyminnehaallande foerstaerkt flytande detergentkomposition och dess anvaendning vid tvaett av textilier
US4900475A (en) *	1985-07-26	1990-02-13	Colgate-Palmolive Co.	Stabilized built liquid detergent composition containing enzyme
NZ216791A (en) *	1985-07-26	1988-07-28	Colgate Palmolive Co	Stabilised, built, enzyme-containing liquid detergents
US4842769A (en) *	1985-07-26	1989-06-27	Colgate-Palmolive Co.	Stabilized fabric softening built detergent composition containing enzymes
US4771003A (en) *	1985-10-22	1988-09-13	Genex Corporation	Heat stable alkaline proteases produced by a bacillus
US4764470A (en) *	1986-02-05	1988-08-16	Genex Corporation	Alkaline protease produced by a bacillus
US4842758A (en) *	1986-10-31	1989-06-27	Colgate-Palmolive Company	Stabilized enzyme system for use in aqueous liquid built detergent compositions
DE3704465C2 (de) *	1987-02-13	1995-11-02	Roehm Gmbh	Flüssig-Formulierungen von Enzymen
AU3667189A (en) *	1988-06-23	1990-01-04	Unilever Plc	Enzyme-containing liquid detergents
GB8900496D0 (en) *	1989-01-10	1989-03-08	Procter & Gamble	Liquid detergent composition containing enzyme and enzyme stabilization system
DE3918761C1 (el) *	1989-06-08	1990-06-28	Henkel Kgaa, 4000 Duesseldorf, De
US5030378A (en) *	1990-01-02	1991-07-09	The Procter & Gamble Company	Liquid detergents containing anionic surfactant, builder and proteolytic enzyme
US5221495A (en) *	1990-04-13	1993-06-22	Colgate-Palmolive Company	Enzyme stabilizing composition and stabilized enzyme containing built detergent compositions
US5364553A (en) *	1990-04-13	1994-11-15	Colgate-Palmolive Company	Stabilized built aqueous liquid softergent compositions
US5275945A (en) *	1991-10-08	1994-01-04	Vista Chemical Company	Alkaline proteases stable in heavy-duty detergent liquids
US5527487A (en) *	1991-11-27	1996-06-18	Novo Nordisk A/S	Enzymatic detergent composition and method for enzyme stabilization
CA2143330C (en) *	1992-09-01	1999-02-23	Julie Anne Dyet	Liquid or gel detergent compositions containing calcium and stabilizing agent thereof
US5580849A (en) *	1992-09-01	1996-12-03	The Procter & Gamble Company	Liquid or gel detergent compositions containing calcium and stabilizing agent thereof
DE69427911T2 (de) *	1993-06-21	2002-04-04	Roche Diagnostics Corp	Stabilisator für diagnostische reagentien
ES2148479T3 (es) *	1993-12-03	2000-10-16	Buckman Labor Inc	Estabilizacion de enzimas por medio de secuencias de copolimeros.
CA2266497C (en) *	1996-09-24	2002-12-31	John Mcmillan Mciver	Liquid detergents containing proteolytic enzyme and protease inhibitors
US6165966A (en) *	1996-09-24	2000-12-26	The Procter & Gamble Company	Liquid detergents containing proteolytic enzyme and protease inhibitors
CN1238003A (zh)	1996-09-24	1999-12-08	普罗格特-甘布尔公司	含有蛋白酶和蛋白酶抑制剂的液体洗衣洗涤剂组合物
US8933131B2 (en)	2010-01-12	2015-01-13	The Procter & Gamble Company	Intermediates and surfactants useful in household cleaning and personal care compositions, and methods of making the same
DE102010038501A1 (de)	2010-07-27	2012-02-02	Henkel Ag & Co. Kgaa	Stabilisierte flüssige enzymhaltige Tensidzubereitung
DE102010038498A1 (de) *	2010-07-27	2012-02-02	Henkel Ag & Co. Kgaa	Stabilisierte flüssige enzymhaltige Tensidzubereitung
CN103380107B (zh)	2011-02-17	2015-06-10	宝洁公司	生物基直链烷基苯基磺酸盐
MX340089B (es)	2011-02-17	2016-06-23	Procter & Gamble	Composiciones que comprenden mezclas de alquil fenil sulfonatos de c10-c13.
US9133424B2 (en)	2011-12-16	2015-09-15	Ecolab Usa Inc.	Stabilization and activation of protease for use at high temperature
JP2015530424A (ja) *	2012-07-26	2015-10-15	ザプロクターアンドギャンブルカンパニー	酵素を有する低ｐＨ液体洗浄組成物
BR112015028853A2 (pt)	2013-05-24	2017-08-29	Procter & Gamble	Composição detergente com ph baixo
WO2014190130A1 (en)	2013-05-24	2014-11-27	The Procter & Gamble Company	Concentrated surfactant composition
EP3004307A1 (en)	2013-05-24	2016-04-13	The Procter & Gamble Company	Low ph detergent composition comprising nonionic surfactants
CN105369638A (zh) *	2014-08-25	2016-03-02	江苏欣隆羽绒有限公司	一种羽绒脱脂剂

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1204123A (en) *	1966-11-29	1970-09-03	Unilever Ltd	Detergent composition
DK130417A (el) *	1968-08-08
NL131892C (el) *	1969-03-21
US3634266A (en) *	1969-07-23	1972-01-11	Procter & Gamble	Liquid detergent compositions containing amylolytic enzymes
US3682842A (en) *	1970-05-04	1972-08-08	Irving Innerfield	Stabilized enzymic compositions containing protease and alpha amylase of bacterial origin and method of stabilizing such compositions
GB1368599A (en) *	1970-09-29	1974-10-02	Unilever Ltd	Softening compositions
GB1349650A (en) *	1970-11-27	1974-04-10	Pegg S & Son Ltd	Textile processing
US4092273A (en) *	1974-10-03	1978-05-30	Colgate-Palmolive Company	Liquid detergent of controlled viscosity
GB1572605A (en) *	1976-03-08	1980-07-30	Procter & Gamble	Liqid enzyme containing detergent composition
IT1106254B (it) *	1976-03-08	1985-11-11	Procter & Gamble Europ	Composizione detergente liquida contenente enzimi
GB1590445A (en) *	1976-11-01	1981-06-03	Unilever Ltd	Enzymatic liquid composition
GB2041394B (en) *	1977-09-26	1982-11-17	Procter & Gamble	Low phosphate detergent composition for fabric washing
DE2833991A1 (de) *	1978-08-03	1980-02-21	Basf Ag	Verfahren zum mechanischen spuelen von geschirr unter einsatz mehrwertiger alkohole, carbonsaeuren und/oder estern daraus als klarspuelmittel
US4243546A (en) *	1979-03-23	1981-01-06	The Drackett Company	Stable aqueous compositions containing enzymes
EP0019315B1 (en) *	1979-05-16	1983-05-25	Procter & Gamble European Technical Center	Highly concentrated fatty acid containing liquid detergent compositions
IT1129814B (it) *	1980-07-02	1986-06-11	Unilever Nv	Composizione detergente enzimatica liquida
US4287082A (en) *	1980-02-22	1981-09-01	The Procter & Gamble Company	Homogeneous enzyme-containing liquid detergent compositions containing saturated acids
EP0028866B1 (en) *	1979-11-09	1984-07-11	THE PROCTER & GAMBLE COMPANY	Stabilised aqueous enzyme composition containing formate and calcium ions
US4305837A (en) *	1980-10-30	1981-12-15	The Procter & Gamble Company	Stabilized aqueous enzyme composition
US4318818A (en) *	1979-11-09	1982-03-09	The Procter & Gamble Company	Stabilized aqueous enzyme composition
GB2094826B (en) *	1981-03-05	1985-06-12	Kao Corp	Cellulase enzyme detergent composition
US4462922A (en) *	1981-11-19	1984-07-31	Lever Brothers Company	Enzymatic liquid detergent composition
GB8311314D0 (en) *	1983-04-26	1983-06-02	Unilever Plc	Aqueous enzyme-containing compositions

1982
- 1982-08-30 US US06/412,690 patent/US4529525A/en not_active Expired - Fee Related
1983
- 1983-08-12 NZ NZ205257A patent/NZ205257A/en unknown
- 1983-08-17 ZA ZA836073A patent/ZA836073B/xx unknown
- 1983-08-17 MX MX198420A patent/MX158409A/es unknown
- 1983-08-18 DK DK378283A patent/DK159554C/da not_active IP Right Cessation
- 1983-08-22 NL NL8302942A patent/NL8302942A/nl not_active Application Discontinuation
- 1983-08-23 DE DE19833330323 patent/DE3330323A1/de not_active Ceased
- 1983-08-24 AT AT0301783A patent/AT394205B/de not_active IP Right Cessation
- 1983-08-25 PH PH29444A patent/PH19070A/en unknown
- 1983-08-25 AU AU18410/83A patent/AU552398B2/en not_active Ceased
- 1983-08-26 CH CH4685/83A patent/CH657372A5/de not_active IP Right Cessation
- 1983-08-26 BR BR8304644A patent/BR8304644A/pt not_active IP Right Cessation
- 1983-08-26 FR FR8313806A patent/FR2532324B1/fr not_active Expired
- 1983-08-29 BE BE211413A patent/BE897610A/fr unknown
- 1983-08-29 NO NO833102A patent/NO157460C/no unknown
- 1983-08-29 PT PT77260A patent/PT77260B/pt not_active IP Right Cessation
- 1983-08-29 ES ES525214A patent/ES8600380A1/es not_active Expired
- 1983-08-29 CA CA000435530A patent/CA1207256A/en not_active Expired
- 1983-08-29 SE SE8304663A patent/SE456426B/sv not_active IP Right Cessation
- 1983-08-30 GB GB08323182A patent/GB2126242B/en not_active Expired
- 1983-08-30 IT IT48896/83A patent/IT1168886B/it active
- 1983-08-30 GR GR72337A patent/GR78984B/el unknown
1985
- 1985-12-02 GB GB08529667A patent/GB2168375B/en not_active Expired
- 1985-12-02 GB GB08529668A patent/GB2168376B/en not_active Expired

Also Published As

Publication number	Publication date
SE8304663D0 (sv)	1983-08-29
IT1168886B (it)	1987-05-20
IT8348896A0 (it)	1983-08-30
AT394205B (de)	1992-02-25
PT77260A (en)	1983-09-01
NO833102L (no)	1984-03-01
GB2126242A (en)	1984-03-21
AU552398B2 (en)	1986-05-29
NO157460B (no)	1987-12-14
GB2168375A (en)	1986-06-18
DK159554C (da)	1991-04-02
GB2168376B (en)	1987-03-18
ES525214A0 (es)	1985-10-01
CA1207256A (en)	1986-07-08
BR8304644A (pt)	1984-04-10
MX158409A (es)	1989-01-30
DE3330323A1 (de)	1984-03-01
ATA301783A (de)	1991-08-15
CH657372A5 (de)	1986-08-29
DK159554B (da)	1990-10-29
GR78984B (el)	1984-10-02
BE897610A (fr)	1984-02-29
GB2168376A (en)	1986-06-18
ES8600380A1 (es)	1985-10-01
DK378283A (da)	1984-03-01
NL8302942A (nl)	1984-03-16
PT77260B (en)	1986-02-04
GB8529668D0 (en)	1986-01-08
AU1841083A (en)	1984-03-08
FR2532324A1 (fr)	1984-03-02
SE8304663L (sv)	1984-03-01
GB2126242B (en)	1987-03-25
DK378283D0 (da)	1983-08-18
GB2168375B (en)	1987-04-01
US4529525A (en)	1985-07-16
GB8323182D0 (en)	1983-09-28
GB8529667D0 (en)	1986-01-08
FR2532324B1 (fr)	1987-09-18
NZ205257A (en)	1985-11-08
ZA836073B (en)	1985-03-27
PH19070A (en)	1985-12-17
NO157460C (no)	1988-03-23

Legal Events

Date

Code

Title

Description

1995-01-31

NAL

Patent in force

Ref document number: 8304663-1

Format of ref document f/p: F

1995-05-08

NUG

Patent has lapsed