RU2019115076A - Композиция концентрата добавок на основе полукристаллического полиолефина - Google Patents

Композиция концентрата добавок на основе полукристаллического полиолефина Download PDF

Info

Publication number
RU2019115076A
RU2019115076A RU2019115076A RU2019115076A RU2019115076A RU 2019115076 A RU2019115076 A RU 2019115076A RU 2019115076 A RU2019115076 A RU 2019115076A RU 2019115076 A RU2019115076 A RU 2019115076A RU 2019115076 A RU2019115076 A RU 2019115076A
Authority
RU
Russia
Prior art keywords
semi
polyolefin
crystalline
iii
moisture
Prior art date
Application number
RU2019115076A
Other languages
English (en)
Other versions
RU2019115076A3 (ru
RU2766574C2 (ru
Inventor
Дачао ЛИ
Раджен М. ПАТЕЛ
Тимоти Дж. ПЁРСОН
Джеффри М. КОГЕН
Бхарат И. ЧАУДХАРИ
Пол Дж. КАРОНИЯ
Original Assignee
Дау Глоубл Текнолоджиз Ллк
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Дау Глоубл Текнолоджиз Ллк filed Critical Дау Глоубл Текнолоджиз Ллк
Publication of RU2019115076A publication Critical patent/RU2019115076A/ru
Publication of RU2019115076A3 publication Critical patent/RU2019115076A3/ru
Application granted granted Critical
Publication of RU2766574C2 publication Critical patent/RU2766574C2/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/241—Preventing premature crosslinking by physical separation of components, e.g. encapsulation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005—Stabilisers against oxidation, heat, light, ozone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
    • C08K5/5333—Esters of phosphonic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/26—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/02—Disposition of insulation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/16—Ethene-propene or ethene-propene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2310/00—Masterbatches
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking
    • C08L2312/08—Crosslinking by silane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Analytical Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)

Claims (11)

1. Композиция концентрата добавок, содержащая полукристаллический полиолефиновый полимер-носитель (А) и пакет добавок, содержащий кислотный катализатор конденсации (В); причем (А) составляет от 50 до 99 массовых процентов (% мас.), а пакет добавок составляет от 1 до 50% мас. от общей массы (100,00% мас.) композиции концентрата добавок; причем кристалличность полукристаллического полиолефинового полимера-носителя (А) составляет от 50 до < 100% мас., и (А) состоит по существу из любого из компонентов от (i) до (vi): (i) полукристаллического полиэтилена средней плотности; (ii) полукристаллического полиэтилена высокой плотности; (iii) полукристаллического полипропилена; (iv) полукристаллического сополимера этилен/пропилен; (v) полукристаллического сополимера поли(этилен-со-альфа-олефин); (vi) комбинации (например, смеси или комбинации) любых двух или более компонентов из (i), (ii) и (v); и при этом полукристаллический полиолефиновый полимер-носитель (A) не содержит никакого полимера-носителя, отличного от полукристаллического полиолефинового полимера-носителя (A).
2. Композиция концентрата добавок по п. 1, отличающаяся тем, что полукристаллический полиолефиновый полимер-носитель (А) имеет (i) плотность по меньшей мере 0,925 г/см3 и представляет собой полиэтилен или плотность от 0,89 до 0,90 г/см3 и представляет собой полипропилен; (ii) кристалличность по меньшей мере 50% мас. и представляет собой полиэтилен; (iii) индекс текучести расплава (MFI) от 0,1 до 20 грамм за 10 минут (г/10 мин) при 190°С/2,16 кг нагрузки и представляет собой полиэтилен или показатель текучести расплава (MFR) от 0,5 до 50 г/10 мин. при 230°С/2,16 кг нагрузки и представляет собой полипропилен; (iv) мономодальное распределение молекулярных масс (MWD); (v) бимодальное MWD; (vi) обе характеристики, и (i), и (ii); (vii) обе характеристики, и (i), и (iii); (viii) обе характеристики, и (ii), и (iii); (ix) обе характеристики, и (iv), и по меньшей мере одну из характеристик от (i) до (iii); или (x) обе характеристики, и (v) и, по меньшей мере, одну из характеристик от (i) до (iii).
3. Композиция концентрата добавок по любому из пп. 1 и 2, отличающаяся тем, что катализатор кислотной конденсации (B) представляет собой (i) органическую сульфоновую кислоту, органическую фосфоновую кислоту или галоидоводород; (ii) органическую сульфоновую кислоту; (iii) алкилзамещенную арилсульфоновую кислоту; (iv) алкилзамещенную арилсульфоновую кислоту, в которой присутствует(ют) 1 или 2 (С5-С20) алкильных заместителя и 1 арильная группа, которая представляет собой фенил или нафтил; (v) (C1-C5)алкилфосфоновую кислоту, в которой (C1-C5) алкил является незамещенным или замещенным одной группой -NH2; (vi) HF, HCl или HBr; (vii) кислоту Льюиса; или (viii) комбинацию любых двух или более кислот из вариантов от (i) до (vii).
4. Композиция концентрата добавок по любому из пп. 1-3, дополнительно содержащая по меньшей мере одну добавку, выбранную из: (C) - вторичного диариламина формулы (I): (R1-Ar)2NH (I), где каждый Ar представляет собой бензол-1,4-диил или оба Ar связаны друг с другом, и вместе с NH из формулы (I) составляют карбазол-3,6-диил; и каждый R1 независимо представляет собой (С1-С20)гидрокарбил; (D) - одного или двух вторых антиоксидантов, каждый из которых имеет структуру, отличную от формулы (I) и друг от друга; (E) - технологической добавки; (F) - красителя; (G) - деактиватора металлов; (Н) - гидролизуемого силана с отсутствующей ненасыщенной углерод-углеродной связью; (I) - ингибитора коррозии; (J) - комбинации любых двух или более добавок от (D) до (I); и (K) - продукта реакции (B) и (C).
5. Композиция концентрата добавок по п. 4, дополнительно содержащая продукт (K) реакции (B) и (C), причем: (i) продукт реакции (B) и (C) включает соль, образованную в результате кислотно-основной реакции (В) и (С); (ii) пакет добавок дополнительно содержит непрореагировавший компонент (B), но не содержит непрореагировавший (C); (iii) пакет добавок дополнительно содержит непрореагировавший компонент (C), но не содержит непрореагировавший (B); или (iv) пакет добавок дополнительно содержит непрореагировавший компонент (B) и непрореагировавший компонент (C).
6. Влагоотверждаемая полиолефиновая композиция, содержащая композицию концентрата добавок по любому из пп. 1-5 и полиолефиновый форполимер, функционализированный гидролизуемой силильной группой; причем в полиолефиновом форполимере, функционализированным гидролизуемой силильной группой: (i) каждая гидролизуемая силильная группа независимо представляет собой одновалентную группу формулы (II): (R2)m(R3)3-mSi- (II); где индекс m обозначает целое число 1, 2 или 3; каждый R2 независимо представляет собой H, HO-, (C1-C6)алкокси, (C2-C6)карбокси, ((C1-C6)алкил)2N-, (C1-C6)алкил (H)C=NO- или ((С1-С6)алкил)2C=NO-; и каждый R3 независимо представляет собой (C1-C6)алкил или фенил; (ii) полиолефин представляет собой полимер на основе полиэтилена, на основе поли(этилен-со-(С3-С40)альфа-олефина) или их комбинации; или (iii) реализованы оба варианта, (i) и (ii).
7. Способ изготовления влагоотверждаемой полиолефиновой композиции, включающий смешивание полиолефинового форполимера, функционализированного гидролизуемой силильной группой, и разделенной твердой формы композиции концентрата добавок по любому из пп. 1-5 для получения смеси; и плавление или экструдирование смеси для получения влагоотверждаемой полиолефиновой композиции.
8. Влагоотвержденная полиолефиновая композиция, которая представляет собой продукт отверждения влагой влагоотверждаемой полиолефиновой композиции по п. 6 или композиции, полученной способом получения влагоотвержденной полиолефиновой композиции по п. 7.
9. Произведенное изделие, включающее сложную форму влагоотвержденной полиолефиновой композиции по п. 8.
10. Проводник с покрытием, содержащий проводящий сердечник и полимерный слой, по меньшей мере частично окружающий проводящий сердечник, причем по меньшей мере часть полимерного слоя содержит влагоотвержденную полиолефиновую композицию по п. 8.
11. Способ пропускания электричества, включающий подачу напряжения на проводящий сердечник проводника с покрытием по п. 10 для генерирования потока электричества через проводящий сердечник.
RU2019115076A 2016-11-02 2017-10-31 Композиция концентрата добавок на основе полукристаллического полиолефина RU2766574C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662416415P 2016-11-02 2016-11-02
US62/416,415 2016-11-02
PCT/US2017/059228 WO2018085241A1 (en) 2016-11-02 2017-10-31 Semi-crystalline polyolefin-based additive masterbatch composition

Publications (3)

Publication Number Publication Date
RU2019115076A true RU2019115076A (ru) 2020-11-16
RU2019115076A3 RU2019115076A3 (ru) 2021-03-05
RU2766574C2 RU2766574C2 (ru) 2022-03-15

Family

ID=60321014

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2019115076A RU2766574C2 (ru) 2016-11-02 2017-10-31 Композиция концентрата добавок на основе полукристаллического полиолефина

Country Status (10)

Country Link
US (1) US11370891B2 (ru)
EP (1) EP3535313B1 (ru)
JP (1) JP7080883B2 (ru)
KR (1) KR102569063B1 (ru)
CN (1) CN109890878B (ru)
BR (1) BR112019008428B1 (ru)
CA (1) CA3042242A1 (ru)
MX (1) MX2019004997A (ru)
RU (1) RU2766574C2 (ru)
WO (1) WO2018085241A1 (ru)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20210137491A (ko) * 2019-03-07 2021-11-17 다우 글로벌 테크놀로지스 엘엘씨 촉매 시스템
CN114302911A (zh) * 2019-08-29 2022-04-08 陶氏环球技术有限责任公司 制备聚烯烃固体和碳固体的均匀混合物的方法
EP4025641A4 (en) * 2019-09-06 2023-05-31 Dow Global Technologies LLC CROSSLINKABLE POLYMER COMPOSITION AND COATED CONDUCTOR

Family Cites Families (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3984940A (en) 1973-05-08 1976-10-12 Murray Reich Degradable plastic
JPS6017353B2 (ja) * 1978-03-03 1985-05-02 古河電気工業株式会社 ポリオレフイン系樹脂の架橋方法
JPS54142255A (en) * 1978-04-28 1979-11-06 Furukawa Electric Co Ltd:The Production of molded article of polyolefin crosslinked by silane
US4255303A (en) 1979-04-25 1981-03-10 Union Carbide Corporation Polyethylene composition containing talc filler for electrical applications
JPS56131631A (en) * 1980-03-21 1981-10-15 Showa Electric Wire & Cable Co Ltd Crosslinked silyl-modified polyolefin film and laminated paper using the same
JPS5757409A (en) * 1980-09-22 1982-04-06 Showa Electric Wire & Cable Co Method of producing electrically insulating film
US4368280A (en) 1980-12-31 1983-01-11 Mitsubishi Petrochemical Company, Ltd. Partially cross-linkable compositions and process for preparing partially cross-linked thermoplastic elastomers
US5202191A (en) 1981-06-19 1993-04-13 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Coated article with metallic finish
JPS60226518A (ja) * 1984-04-25 1985-11-11 Yazaki Corp ポリオレフイン系ゴム組成物
US4681971A (en) * 1984-11-07 1987-07-21 Ciba-Geigy Corporation Phenyl substituted aminodicarboxylate esters
JPS61206113A (ja) * 1985-03-08 1986-09-12 日立電線株式会社 水中モ−トル用絶縁電線
JPH062843B2 (ja) 1988-08-19 1994-01-12 協和化学工業株式会社 難燃剤および難燃性樹脂組成物
US5066752A (en) 1990-06-20 1991-11-19 Great Lakes Chemical Corporation Flame retardant brominated styrene-based polymers
CA2061465A1 (en) 1991-02-25 1992-08-26 Craig C. Meverden Filled hydrolyzable copolymer compositions resistant to premature crosslinking
US5367030A (en) 1993-02-08 1994-11-22 Union Carbide Chemicals & Plastics Technology Corporation Process for crosslinking thermoplastic silane polymers
SE502171C2 (sv) 1993-12-20 1995-09-04 Borealis Holding As Polyetenkompatibla sulfonsyror som silanförnätningskatalysatorer
US5430091A (en) 1994-05-11 1995-07-04 At Plastics Inc. Moisture crosslinkable flame retardant compositions for cable applications
US6384156B1 (en) 1994-08-02 2002-05-07 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization process
US5929129A (en) 1994-09-19 1999-07-27 Sentinel Products Corp. Crosslinked foamable compositions of silane-grafted, essentially linear polyolefins blended with polypropylene
KR0138403B1 (ko) * 1995-02-03 1998-05-01 권문구 전선용 실란가교 폴리올레핀 조성물의 제조방법
JP3322818B2 (ja) * 1997-03-04 2002-09-09 住友ベークライト株式会社 シラン架橋ポリオレフィンの製造方法
WO2000037552A1 (en) 1998-12-22 2000-06-29 Great Lakes Chemical Corporation Additive concentrates for olefinic polymers
US6476132B1 (en) 1999-07-23 2002-11-05 Advanced Elastomer Systems, L.P. Use of a silane grafted polyolefin in EPDM/polyolefin thermoplastic vulcanizates to improve compression set
US6441097B1 (en) 2000-08-03 2002-08-27 King Industries, Inc. Alkylaryl and arylalkyl monosulfonic acid catalysts for crosslinking polyethylene
PT1254923E (pt) 2001-05-02 2007-01-31 Borealis Tech Oy Estabilização de polímero com ligações cruzadas contendo grupos silano
MY136027A (en) 2003-04-02 2008-07-31 Basell Poliolefine Spa Polyolefin masterbatch and composition suitable for injection molding
CN101240102A (zh) 2003-06-25 2008-08-13 联合碳化化学及塑料技术公司 含有特定抗氧化剂的湿可交联聚合组合物
ITMI20031579A1 (it) * 2003-08-01 2005-02-02 Basell Poliolefine Spa Concentrati di additivi, adatti all'impiego nella
US6998443B2 (en) 2003-09-02 2006-02-14 Equistar Chemicals, Lp Flame retardant insulation compositions having improved abrasion resistance
US6936655B2 (en) 2003-09-02 2005-08-30 Equistar Chemicals, Lp Crosslinkable flame retardant wire and cable compositions having improved abrasion resistance
US6936671B2 (en) 2003-10-08 2005-08-30 Equistar Chemicals, Lp Process for copolymerizing ethylene with vinylsilanes
EP1784451A2 (en) 2004-08-05 2007-05-16 Dow Gloval Technologies Inc. Moisture-curable, silane crosslinkable composition
MX2007010671A (es) 2005-03-03 2007-11-08 Union Carbide Chem Plastic Componente/capa retardante a la flama-cable impelente con propiedades de envejecimiento excelentes.
CA2599793C (en) * 2005-03-18 2013-08-13 Dow Global Technologies Inc. Moisture crosslinkable polymeric composition-improved heat aging performance
BRPI0619699A2 (pt) 2005-11-12 2011-10-11 Dow Global Technologies Inc copolìmero bromado termicamente estável, mistura de polìmeros, artigo moldado e processo para preparar um copolìmero bromado
US7514489B2 (en) 2005-11-28 2009-04-07 Martin Marietta Materials, Inc. Flame-retardant magnesium hydroxide compositions and associated methods of manufacture and use
EP1849816B1 (en) 2006-04-26 2008-06-25 Borealis Technology Oy Crosslinkable polyolefin composition comprising high molecular weight silanol condensation catalyst
JP4270237B2 (ja) 2006-07-31 2009-05-27 日立電線株式会社 非ハロゲン難燃性熱可塑性エラストマー組成物及びその製造方法並びにこれを用いた電線・ケーブル
ATE440904T1 (de) * 2007-12-21 2009-09-15 Borealis Tech Oy Polypropylenzusammensetzung mit einer vernetzbaren dispergierten phase mit nanofüllstoffe enthaltenden silanolgruppen
US8962718B2 (en) 2010-04-26 2015-02-24 Momentive Performance Materials Inc. Chlorine-resistant crosslinkable polyolefin compositions and articles made therefrom
EP2632972B1 (en) 2010-10-25 2014-03-19 Applied Minerals Inc. Nucleating agent for polyethylenes
WO2012094395A2 (en) 2011-01-04 2012-07-12 Primex Plastics Corporation Fire retardant and method of use
JP5594185B2 (ja) 2011-02-25 2014-09-24 三菱化学株式会社 成形品及び該成形品で被覆してなる電線
EP2736971A1 (en) * 2011-07-29 2014-06-04 Dow Global Technologies LLC Semi-crystalline polyolefin composition, method of producing the same, and articles made therefrom
WO2013116283A1 (en) 2012-02-01 2013-08-08 Icl-Ip America Inc. Polyolefin flame retardant composition and synergists thereof
JP6078967B2 (ja) 2012-03-29 2017-02-15 大日本印刷株式会社 太陽電池モジュール用封止材シート
WO2014014648A2 (en) 2012-07-18 2014-01-23 Rohm And Haas Company Textiles with brominated polymer flame retardant
EP2889323A1 (en) 2013-12-30 2015-07-01 Abu Dhabi Polymers Company Limited (Borouge) Polymer composition comprising carbon black and a carrier polymer for the carbon black
WO2015149221A1 (en) 2014-03-31 2015-10-08 Dow Global Technologies Llc Crosslinkable polymeric compositions with n,n,n',n',n",n"-hexaallyl-1,3,5-triazine-2,4,6-triamine crosslinking coagent, methods for making the same, and articles made therefrom
BR112016029739B1 (pt) 2014-06-27 2021-08-10 Dow Global Technologies Llc Composição polimérica reticulável por silano, condutor revestido e processo para preparar uma composição polimérica reticulável por silano
KR102396101B1 (ko) 2014-06-27 2022-05-11 다우 글로벌 테크놀로지스 엘엘씨 안정화된 수분-경화성 폴리머성 조성물
CN107428952A (zh) 2015-03-12 2017-12-01 道达尔研究技术弗吕公司 用于制备具有增强的导电性的基于半结晶聚合物的复合材料的母料、工艺和由其制造的复合材料
CA3042237A1 (en) * 2016-11-02 2018-05-11 Dow Global Technologies Llc Semi-crystalline polyolefin-based additive masterbatch composition

Also Published As

Publication number Publication date
EP3535313B1 (en) 2021-06-30
RU2019115076A3 (ru) 2021-03-05
CN109890878A (zh) 2019-06-14
US11370891B2 (en) 2022-06-28
EP3535313A1 (en) 2019-09-11
BR112019008428B1 (pt) 2022-09-27
RU2766574C2 (ru) 2022-03-15
KR20190077395A (ko) 2019-07-03
JP7080883B2 (ja) 2022-06-06
WO2018085241A1 (en) 2018-05-11
MX2019004997A (es) 2019-08-05
US20190248966A1 (en) 2019-08-15
CA3042242A1 (en) 2018-05-11
CN109890878B (zh) 2022-07-08
JP2019535862A (ja) 2019-12-12
BR112019008428A2 (pt) 2019-07-09
KR102569063B1 (ko) 2023-08-23

Similar Documents

Publication Publication Date Title
RU2019115076A (ru) Композиция концентрата добавок на основе полукристаллического полиолефина
KR102414472B1 (ko) 폴리올레핀 조성물
KR101260200B1 (ko) 올레핀계 아이오노머 수지 조성물
RU2012142301A (ru) Полимерная композиция для изготовления проводов и кабелей, обладающая преимущественными электрическими свойствами
RU2012142300A (ru) Полимерная композиция для изготовления проводов и кабелей, обладающая преимущественными электрическими свойствами
RU2012134431A (ru) Полиэтилен с высокой прочностью расплава для использования в пленках
JP2012516385A5 (ru)
KR20200119741A (ko) 저유전 방열필름용 조성물 및 저유전 방열필름
CN103140544A (zh) 聚烯烃类树脂多孔膜
CN103360577A (zh) 热固性树脂组合物、树脂膜、覆铜板及柔性印刷布线板
KR20200077147A (ko) 전력 케이블의 절연층 조성물 및 이로부터 제조된 전력 케이블
RU2019115090A (ru) Полукристаллическая композиция суперконцентрата добавки на основе полиолефина
JP6370999B2 (ja) 金属化プラスチック物品および表面を選択的に金属化する方法
CN103476865A (zh) 阻燃的热塑性模制组合物
EP3535312B1 (en) Semi-crystalline polyolefin-based additive masterbatch composition
KR102541308B1 (ko) 친환경 tpe 단열복합방수시트 및 이의 제조방법
WO2020115522A1 (en) Polyolefins halogen-free flame retardant moulding compositions comprising an inorganic hypophosphorous acid metal salt
JP2015178568A5 (ru)
TWI681994B (zh) 聚烯烴組合物
CN114341247B (zh) 可交联聚合物组合物和涂覆的导体
RU2021124250A (ru) Отверждаемый влагой состав полиолефина
RU2021128723A (ru) Каталитическая система
KR20210126659A (ko) 수분 경화성 폴리올레핀 제형
TW202307117A (zh) 含有克羅托酮（ｃｒｏｔｏｐｈｅｎｏｎｅ）化合物之聚烯烴調配物
RU2021124039A (ru) Способ получения гетерофазных полимерных композиций