RU2007121413A - PIGMENT COMPOSITION IN THE FORM OF AQUATIC DISPERSION - Google Patents

PIGMENT COMPOSITION IN THE FORM OF AQUATIC DISPERSION Download PDF

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RU2007121413A
RU2007121413A RU2007121413/04A RU2007121413A RU2007121413A RU 2007121413 A RU2007121413 A RU 2007121413A RU 2007121413/04 A RU2007121413/04 A RU 2007121413/04A RU 2007121413 A RU2007121413 A RU 2007121413A RU 2007121413 A RU2007121413 A RU 2007121413A
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porous aggregates
composition according
particles
filler particles
aluminosilicate
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RU2007121413/04A
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Russian (ru)
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RU2375397C2 (en
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Челль Руне АНДЕРССОН (SE)
Челль Руне АНДЕРССОН
Хоаким КАРЛЕН (SE)
Хоаким КАРЛЕН
Эрик ЛИНДГРЕН (SE)
Эрик ЛИНДГРЕН
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Акцо Нобель Н.В. (NL)
Акцо Нобель Н.В.
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Paper (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Paints Or Removers (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

1. Состав пигмента в форме водной дисперсии, включающий:(a) пористые агрегаты, образованные агрегацией коллоидных первичных частиц диоксида кремния, алюмосиликата или их смеси в водном золе, причем указанные пористые агрегаты имеют средний диаметр от приблизительно 0,03 до приблизительно 25 мкм, иб) частицы наполнителя, где средний размер по меньшей мере одного измерения больше, чем средний диаметр пористых агрегатов,в котором массовое отношение пористых агрегатов к частицам наполнителя составляет от приблизительно 0,01:1 до приблизительно 3:1.2. Состав по п.1, в котором коллоидные первичные частицы диоксида кремния или алюмосиликата образуются из водного раствора силиката щелочного металла, из которого ионы щелочного металла удалены методом ионного обмена, или где силикат щелочного металла был нейтрализован прибавлением кислоты.3. Состав по любому из пп.1 и 2, в котором по меньшей мере некоторые из пористых агрегатов присоединены к частицам наполнителя.4. Состав по любому из пп.1 и 2, в котором пористые агрегаты и частицы наполнителя имеют противоположные чистые заряды.5. Состав по любому из пп.1 и 2, в котором частицы наполнителя являются материалом, выбранным из группы, состоящей из каолинитов, смектитов, талькитов, минералов карбоната кальция, осажденного диоксида кремния, гелеобразного диоксида кремния, тонкоизмельченного диоксида кремния, осажденного карбоната кальция, и их смеси.6. Состав по любому из пп.1 и 2, в котором общее содержание пористых агрегатов и частиц наполнителя в составе составляет от приблизительно 1 до приблизительно 60 мас.%.7. Состав по любому из пп.1 и 2, в котором средний диаметр частиц коллоидных п�1. A pigment composition in the form of an aqueous dispersion, comprising: (a) porous aggregates formed by the aggregation of colloidal primary particles of silica, aluminosilicate or a mixture thereof in an aqueous ash, said porous aggregates having an average diameter of from about 0.03 to about 25 μm, and b) filler particles, where the average size of at least one dimension is greater than the average diameter of the porous aggregates, in which the weight ratio of porous aggregates to filler particles is from about 0.01: 1 to about 3: 1.2. The composition of claim 1, wherein the colloidal primary particles of silica or aluminosilicate are formed from an aqueous solution of an alkali metal silicate from which alkali metal ions have been removed by ion exchange, or wherein the alkali metal silicate has been neutralized by the addition of an acid. Composition according to any one of claims 1 and 2, in which at least some of the porous aggregates are attached to the filler particles. Composition according to any one of claims 1 and 2, in which the porous aggregates and filler particles have opposite net charges. The composition according to any one of claims 1 and 2, in which the filler particles are a material selected from the group consisting of kaolinite, smectite, talcite, calcium carbonate minerals, precipitated silica, gelled silica, micronized silica, precipitated calcium carbonate, and mixtures thereof 6. The composition according to any one of claims 1 and 2, in which the total content of porous aggregates and filler particles in the composition is from about 1 to about 60 wt.%. The composition according to any one of claims 1 and 2, in which the average particle diameter of the colloidal particles

Claims (16)

1. Состав пигмента в форме водной дисперсии, включающий:1. The composition of the pigment in the form of an aqueous dispersion, including: (a) пористые агрегаты, образованные агрегацией коллоидных первичных частиц диоксида кремния, алюмосиликата или их смеси в водном золе, причем указанные пористые агрегаты имеют средний диаметр от приблизительно 0,03 до приблизительно 25 мкм, и(a) porous aggregates formed by aggregation of colloidal primary particles of silicon dioxide, aluminosilicate or mixtures thereof in aqueous ash, said porous aggregates having an average diameter of from about 0.03 to about 25 μm, and б) частицы наполнителя, где средний размер по меньшей мере одного измерения больше, чем средний диаметр пористых агрегатов,b) filler particles, where the average size of at least one dimension is larger than the average diameter of the porous aggregates, в котором массовое отношение пористых агрегатов к частицам наполнителя составляет от приблизительно 0,01:1 до приблизительно 3:1.in which the mass ratio of porous aggregates to filler particles is from about 0.01: 1 to about 3: 1. 2. Состав по п.1, в котором коллоидные первичные частицы диоксида кремния или алюмосиликата образуются из водного раствора силиката щелочного металла, из которого ионы щелочного металла удалены методом ионного обмена, или где силикат щелочного металла был нейтрализован прибавлением кислоты.2. The composition according to claim 1, in which the colloidal primary particles of silicon dioxide or aluminosilicate are formed from an aqueous solution of alkali metal silicate, from which the alkali metal ions are removed by ion exchange, or where the alkali metal silicate has been neutralized by the addition of acid. 3. Состав по любому из пп.1 и 2, в котором по меньшей мере некоторые из пористых агрегатов присоединены к частицам наполнителя.3. The composition according to any one of claims 1 and 2, in which at least some of the porous aggregates are attached to the filler particles. 4. Состав по любому из пп.1 и 2, в котором пористые агрегаты и частицы наполнителя имеют противоположные чистые заряды.4. The composition according to any one of claims 1 and 2, in which the porous aggregates and particles of the filler have opposite net charges. 5. Состав по любому из пп.1 и 2, в котором частицы наполнителя являются материалом, выбранным из группы, состоящей из каолинитов, смектитов, талькитов, минералов карбоната кальция, осажденного диоксида кремния, гелеобразного диоксида кремния, тонкоизмельченного диоксида кремния, осажденного карбоната кальция, и их смеси.5. The composition according to any one of claims 1 and 2, in which the filler particles are a material selected from the group consisting of kaolinites, smectites, talcites, calcium carbonate minerals, precipitated silica, gelled silica, finely divided silica, precipitated calcium carbonate , and mixtures thereof. 6. Состав по любому из пп.1 и 2, в котором общее содержание пористых агрегатов и частиц наполнителя в составе составляет от приблизительно 1 до приблизительно 60 мас.%.6. The composition according to any one of claims 1 and 2, in which the total content of porous aggregates and filler particles in the composition is from about 1 to about 60 wt.%. 7. Состав по любому из пп.1 и 2, в котором средний диаметр частиц коллоидных первичных частиц диоксида кремния, алюмосиликата или их смеси составляет от приблизительно 2 до приблизительно 75 нм.7. The composition according to any one of claims 1 and 2, in which the average particle diameter of the colloidal primary particles of silicon dioxide, aluminosilicate or a mixture thereof is from about 2 to about 75 nm. 8. Способ получения состава пигмента по любому из пп.1-7, включающий стадию смешивания:8. A method of obtaining a pigment composition according to any one of claims 1 to 7, comprising a mixing step: а) водной дисперсии пористых агрегатов, полученных агрегацией коллоидных первичных частиц диоксида кремния, алюмосиликата или их смеси в водном золе, причем указанные пористые агрегаты имеют средний диаметр от приблизительно 0,03 до приблизительно 25 мкм, и,a) an aqueous dispersion of porous aggregates obtained by aggregation of colloidal primary particles of silicon dioxide, aluminosilicate or a mixture thereof in aqueous ash, said porous aggregates having an average diameter of from about 0.03 to about 25 μm, and, б) частиц наполнителя, где средний размер по меньшей мере одного измерения больше, чем средний диаметр пористых агрегатов,b) filler particles, where the average size of at least one dimension is larger than the average diameter of the porous aggregates, в котором массовое отношение пористых агрегатов к частицам наполнителя составляет от приблизительно 0,01:1 до приблизительно 3:1.in which the mass ratio of porous aggregates to filler particles is from about 0.01: 1 to about 3: 1. 9. Способ получения состава пигмента согласно любому из пп.1-7, включающий стадии:9. A method of obtaining a pigment composition according to any one of claims 1 to 7, comprising the steps of: (a) смешивания водного золя, включающего коллоидные первичные частицы диоксида кремния или алюмосиликата и частицы наполнителя в массовом отношении первичные частицы диоксида кремния или алюмосиликата к частицам наполнителя от приблизительно 0,01:1 до приблизительно 3:1; и(a) mixing an aqueous sol comprising colloidal primary silica or aluminosilicate particles and filler particles in a weight ratio of primary silica or aluminosilicate particles to filler particles from about 0.01: 1 to about 3: 1; and (б) агрегации коллоидных первичных частиц диоксида кремния или алюмосиликата с образованием пористых агрегатов, имеющих средний диаметр от приблизительно 0,03 до приблизительно 25 мкм, но не превышая средний размер наибольшего измерения частиц наполнителя.(b) aggregation of colloidal primary particles of silicon dioxide or aluminosilicate with the formation of porous aggregates having an average diameter of from about 0.03 to about 25 microns, but not exceeding the average size of the largest dimension of the filler particles. 10. Состав пигмента, полученный способом по любому из пп.8-9.10. The composition of the pigment obtained by the method according to any one of claims 8 to 9. 11. Состав покрытия, пригодный для покрытия бумаги или картона, включающий связующий компонент и состав пигмента согласно любому из пп.1-7 или 10.11. A coating composition suitable for coating paper or paperboard, comprising a binder component and a pigment composition according to any one of claims 1 to 7 or 10. 12. Состав покрытия по п.11, в котором связующий компонент выбран из группы, состоящей из поливиниловых спиртов, необязательно модифицированных крахмалов, смол, белковых связующих, латексов и их смесей.12. The coating composition of claim 11, wherein the binder component is selected from the group consisting of polyvinyl alcohols, optionally modified starches, resins, protein binders, latexes, and mixtures thereof. 13. Способ получения состава покрытия, включающий стадию смешивания связующего компонента с составом пигмента согласно любому из пп.1-7 или 10.13. A method of obtaining a coating composition, comprising the step of mixing a binder component with a pigment composition according to any one of claims 1 to 7 or 10. 14. Способ получения покрытой бумаги или картона, включающий стадию нанесения состава покрытия по любому из пп.11 и 12 на по меньшей мере одну сторону полотна бумаги или картона.14. A method for producing coated paper or paperboard, comprising the step of applying a coating composition according to any one of claims 11 and 12 to at least one side of the paper or paperboard web. 15. Способ по п.14, в котором покрытие наносят в количестве достаточном, чтобы получить от приблизительно 0,4 до приблизительно 40 г/м2 пористых агрегатов и частиц наполнителя из состава пигмента на покрытую сторону бумаги или картона.15. The method according to 14, in which the coating is applied in an amount sufficient to obtain from about 0.4 to about 40 g / m 2 porous aggregates and filler particles from the pigment composition on the coated side of the paper or cardboard. 16. Бумага или картон, полученные способом по любому из пп.14 и 15.16. Paper or cardboard obtained by the method according to any one of paragraphs.14 and 15.
RU2007121413/04A 2004-11-08 2005-10-13 Composition of pigment in the form of aqueous dispersion RU2375397C2 (en)

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KR (3) KR100948121B1 (en)
CN (3) CN101056956B (en)
AR (3) AR051756A1 (en)
AU (3) AU2005301350B2 (en)
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MX (3) MX2007004959A (en)
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