RU2003127946A - Способ получения высокочистого диизобутена - Google Patents
Способ получения высокочистого диизобутена Download PDFInfo
- Publication number
- RU2003127946A RU2003127946A RU2003127946/04A RU2003127946A RU2003127946A RU 2003127946 A RU2003127946 A RU 2003127946A RU 2003127946/04 A RU2003127946/04 A RU 2003127946/04A RU 2003127946 A RU2003127946 A RU 2003127946A RU 2003127946 A RU2003127946 A RU 2003127946A
- Authority
- RU
- Russia
- Prior art keywords
- diisobutene
- metal ions
- protons
- isobutene
- conversion
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/28—Catalytic processes with hydrides or organic compounds with ion-exchange resins
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- C07C2531/08—Ion-exchange resins
- C07C2531/10—Ion-exchange resins sulfonated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Claims (11)
1. Способ получения высокочистого диизобутена посредством превращения изобутена или изобутен-содержащих смесей углеводородов на твердой кислой ионообменной смоле, отличающийся тем, что кислая ионообменная смола содержит сульфокислотные группы, протоны которых частично обмениваются на ионы металла.
2. Способ по п.1, отличающийся тем, что от 30 до 90% протонов обмениваются на ионы металла.
3. Способ по п.1 или 2, отличающийся тем, что от 50 до 80% протонов обмениваются на ионы металла.
4. Способ по одному из пп.1-3, отличающийся тем, что ионами металла являются ионы щелочных металлов.
5. Способ по одному из пп.1-4, отличающийся тем, что ионами металла являются ионы натрия.
6. Способ по одному из пп.1-5, отличающийся тем, что превращение проводят при температуре от 20 до 120°С.
7. Способ по п.6, отличающийся тем, что превращение проводят при температуре от 40 до 100°С.
8. Способ по одному из пп.1-7, отличающийся тем, что превращение проводят в жидкой фазе в области давлений от 5 до 40 бар.
9. Применение диизобутена, полученного по пп.1-8, для получения 3,5,5-триметилгексановой кислоты посредством гидроформилирования и последующего окисления.
10. Применение диизобутена, полученного по пп.1-8, для получения 3,5,5-триметилгексанола посредством гидроформилирования и последующего гидрирования.
11. Применение диизобутена, полученного по пп.1-8, в качестве алкилирующего агента для фенолов и ароматических аминов.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10106593.0 | 2001-02-13 | ||
DE10106593 | 2001-02-13 | ||
DE10113381.2 | 2001-03-20 | ||
DE10113381A DE10113381A1 (de) | 2001-02-13 | 2001-03-20 | Verfahren zur Herstellung von hochreinem Diisobuten |
Publications (1)
Publication Number | Publication Date |
---|---|
RU2003127946A true RU2003127946A (ru) | 2005-03-20 |
Family
ID=26008485
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2003127946/04A RU2003127946A (ru) | 2001-02-13 | 2001-12-28 | Способ получения высокочистого диизобутена |
Country Status (15)
Country | Link |
---|---|
US (1) | US7002053B2 (ru) |
EP (1) | EP1360160B1 (ru) |
JP (1) | JP4076442B2 (ru) |
KR (1) | KR100763216B1 (ru) |
CN (1) | CN1213003C (ru) |
AT (1) | ATE425133T1 (ru) |
BR (1) | BR0116884A (ru) |
CA (1) | CA2435590C (ru) |
CZ (1) | CZ20032479A3 (ru) |
DE (2) | DE10113381A1 (ru) |
ES (1) | ES2322693T3 (ru) |
HU (1) | HUP0303274A2 (ru) |
PL (1) | PL362245A1 (ru) |
RU (1) | RU2003127946A (ru) |
WO (1) | WO2002064531A1 (ru) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110452083A (zh) * | 2019-08-05 | 2019-11-15 | 中国石油天然气集团有限公司 | 二异丁烯的生产方法及装置 |
Families Citing this family (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10231051A1 (de) * | 2002-07-10 | 2004-01-22 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von hochreinem Methyl-tert.-butylether |
EP1388528B1 (de) | 2002-08-06 | 2015-04-08 | Evonik Degussa GmbH | Verfahren zur Oligomerisierung von Isobuten in n-Buten-haltigen Kohlenwasserstoffströmen |
DE10302457B3 (de) * | 2003-01-23 | 2004-10-07 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Butenoligomeren und tert.-Butylethern aus Isobuten-haltigen C4-Strömen |
DE10329042A1 (de) * | 2003-06-27 | 2005-01-13 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Octen aus Crack-C4 |
DE102005036040A1 (de) | 2004-08-28 | 2006-03-02 | Oxeno Olefinchemie Gmbh | Verfahren zur Telomerisation von nicht cyclischen Olefinen |
DE102005036038A1 (de) * | 2004-08-28 | 2006-03-02 | Oxeno Olefinchemie Gmbh | Verfahren zur Telomerisation von nicht cyclischen Olefinen |
DE102005036039A1 (de) | 2004-08-28 | 2006-03-02 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 2,7-Octadienylderivaten |
DE102004060520A1 (de) * | 2004-12-16 | 2006-06-22 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von unverzweigten acyclischen Octatrienen |
DE102005062700A1 (de) | 2005-12-28 | 2007-07-05 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Buten aus technischen Mischungen von C4-Kohlenwasserstoffen |
DE102005062722A1 (de) * | 2005-12-28 | 2007-07-12 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Ethyl-tert.-Butylether aus technischen Mischungen von C4-Kohlenwasserstoffen |
DE102005062699A1 (de) * | 2005-12-28 | 2007-09-06 | Oxeno Olefinchemie Gmbh | Verfahren zur Feinreinigung von 1-Buten-haltigen Strömen |
DE102006003492A1 (de) * | 2006-01-25 | 2007-07-26 | Oxeno Olefinchemie Gmbh | Verfahren zur Entwässerung von Ethanol |
US8975047B2 (en) * | 2006-06-16 | 2015-03-10 | E I Du Pont De Nemours And Company | Process for making isooctenes from dry 1-butanol |
US20080015397A1 (en) * | 2006-06-16 | 2008-01-17 | D Amore Michael B | Process for making isooctenes from aqueous 1-butanol |
US20080131948A1 (en) * | 2006-12-01 | 2008-06-05 | Leo Ernest Manzer | Process for making isooctenes from dry 2-butanol |
CN101952398B (zh) | 2007-12-03 | 2014-05-21 | 格沃股份有限公司 | 可再生组合物 |
US8193402B2 (en) * | 2007-12-03 | 2012-06-05 | Gevo, Inc. | Renewable compositions |
EP2070894A1 (en) * | 2007-12-12 | 2009-06-17 | BP p.l.c. | A process for the conversion of n-butanol of n-butanol to di-isobutene and pentene |
EP2105428A1 (en) * | 2007-12-12 | 2009-09-30 | BP p.l.c. | A process for the conversion of n-butanol to di-isobutene |
EP2070896A1 (en) * | 2007-12-12 | 2009-06-17 | BP p.l.c. | A process for the conversion of n-butanol to di-isobutene and propene |
US20100145122A1 (en) * | 2008-12-04 | 2010-06-10 | Zak Thomas S | Diisobutylene process |
WO2010099201A1 (en) * | 2009-02-24 | 2010-09-02 | Gevo, Inc. | Methods of preparing renewable butadiene and renewable isoprene |
WO2011044243A1 (en) * | 2009-10-06 | 2011-04-14 | Gevo, Inc. | Integrated process to selectively convert renewable isobutanol to p-xylene |
BR112012016883A2 (pt) | 2010-01-08 | 2018-06-05 | Gevo Inc | metodos integrados de preparar produsot quimicos renovaveis |
WO2011140560A1 (en) | 2010-05-07 | 2011-11-10 | Gevo, Inc. | Renewable jet fuel blendstock from isobutanol |
US8742187B2 (en) | 2011-04-19 | 2014-06-03 | Gevo, Inc. | Variations on prins-like chemistry to produce 2,5-dimethylhexadiene from isobutanol |
DE102012105877A1 (de) | 2012-07-02 | 2014-01-02 | Oxea Gmbh | Verfahren zur Herstellung von Diisobuten |
DE102012105879A1 (de) | 2012-07-02 | 2014-01-02 | Oxea Gmbh | Verfahren zur Herstellung von Isononylderivaten |
DE102012105874A1 (de) * | 2012-07-02 | 2014-01-02 | Oxea Gmbh | Verfahren zur Herstellung von Isononansäurevinylestern |
DE102012105876A1 (de) | 2012-07-02 | 2014-01-02 | Oxea Gmbh | Verfahren zur Herstellung von Terephthalsäure und ihren Derivaten |
US20140275664A1 (en) * | 2013-03-13 | 2014-09-18 | Chevron Phillips Chemical Company Lp | Processes for Preparing Low Viscosity Lubricants |
CN104557392B (zh) * | 2013-10-11 | 2017-07-21 | 中国石油化工股份有限公司 | 一种戊烷的生产方法 |
US20150148572A1 (en) * | 2013-11-27 | 2015-05-28 | Saudi Arabian Oil Company | Process for the Dimerization/Oligomerization of Mixed Butenes Over an Ion-Exchange Resin Catalyst |
US9447346B2 (en) | 2013-12-11 | 2016-09-20 | Saudi Arabian Oil Company | Two-step process for production of RON-enhanced mixed butanols and diisobutenes |
ES2785564T3 (es) * | 2017-12-21 | 2020-10-07 | Evonik Degussa Gmbh | Procedimiento para la conversión directa de diisobuteno en un ácido carboxílico |
EP3693355B1 (de) | 2019-02-07 | 2021-11-10 | Evonik Operations GmbH | Flexible herstellung von mtbe oder etbe und isononanol |
CN115066429A (zh) | 2020-02-11 | 2022-09-16 | 巴斯夫欧洲公司 | 二异丁烯的低压醛化 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3955938A (en) * | 1973-08-21 | 1976-05-11 | Exxon Research And Engineering Company | Gasoline composition containing a sodium additive |
IT1039740B (it) * | 1975-07-08 | 1979-12-10 | Snam Progetti | Procedimento per l addizione di acidi organici a composti acetile nici contenuti in correnet i idrocar buriche inorganiche do organiche |
DE2706465C3 (de) * | 1977-02-16 | 1980-10-02 | Deutsche Texaco Ag, 2000 Hamburg | Verfahren zur Gewinnung von Butadien bzw. n-Butenen aus diese enthaltenden Kohlenwasserstoffgemischen unter Abtrennung von Isobuten |
DE2709438C3 (de) | 1977-03-04 | 1980-01-17 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von C6. bis C20 Alkylcarbonsäuren |
US4100220A (en) | 1977-06-27 | 1978-07-11 | Petro-Tex Chemical Corporation | Dimerization of isobutene |
DE2757559C2 (de) * | 1977-12-23 | 1986-10-30 | Henkel KGaA, 4000 Düsseldorf | Verwendung der 3,5,5-Trimethylhexansäureester als Riechstoffe sowie diese enthaltende Riechstoffkompositionen |
US4436936A (en) * | 1981-06-19 | 1984-03-13 | Ciba-Geigy Corporation | Alkylation and aralkylation of aromatic amines |
US5004845A (en) | 1981-08-20 | 1991-04-02 | Davy Mckee (London) Limited | Hydrogenation of aldehydes |
-
2001
- 2001-03-20 DE DE10113381A patent/DE10113381A1/de not_active Withdrawn
- 2001-12-28 BR BR0116884-3A patent/BR0116884A/pt not_active IP Right Cessation
- 2001-12-28 WO PCT/EP2001/015365 patent/WO2002064531A1/de active Application Filing
- 2001-12-28 RU RU2003127946/04A patent/RU2003127946A/ru not_active Application Discontinuation
- 2001-12-28 HU HU0303274A patent/HUP0303274A2/hu unknown
- 2001-12-28 EP EP01986943A patent/EP1360160B1/de not_active Expired - Lifetime
- 2001-12-28 US US10/467,844 patent/US7002053B2/en not_active Expired - Lifetime
- 2001-12-28 JP JP2002564468A patent/JP4076442B2/ja not_active Expired - Lifetime
- 2001-12-28 DE DE50114767T patent/DE50114767D1/de not_active Expired - Lifetime
- 2001-12-28 AT AT01986943T patent/ATE425133T1/de not_active IP Right Cessation
- 2001-12-28 ES ES01986943T patent/ES2322693T3/es not_active Expired - Lifetime
- 2001-12-28 CZ CZ20032479A patent/CZ20032479A3/cs unknown
- 2001-12-28 CN CNB01822623XA patent/CN1213003C/zh not_active Expired - Lifetime
- 2001-12-28 CA CA002435590A patent/CA2435590C/en not_active Expired - Lifetime
- 2001-12-28 KR KR1020037010581A patent/KR100763216B1/ko active IP Right Grant
- 2001-12-28 PL PL01362245A patent/PL362245A1/xx not_active Application Discontinuation
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110452083A (zh) * | 2019-08-05 | 2019-11-15 | 中国石油天然气集团有限公司 | 二异丁烯的生产方法及装置 |
CN110452083B (zh) * | 2019-08-05 | 2021-11-30 | 中国石油天然气集团有限公司 | 二异丁烯的生产方法及装置 |
Also Published As
Publication number | Publication date |
---|---|
KR100763216B1 (ko) | 2007-10-08 |
EP1360160B1 (de) | 2009-03-11 |
EP1360160A1 (de) | 2003-11-12 |
CN1213003C (zh) | 2005-08-03 |
CA2435590A1 (en) | 2002-08-22 |
JP2004529876A (ja) | 2004-09-30 |
WO2002064531A1 (de) | 2002-08-22 |
US7002053B2 (en) | 2006-02-21 |
KR20040002865A (ko) | 2004-01-07 |
US20040054246A1 (en) | 2004-03-18 |
JP4076442B2 (ja) | 2008-04-16 |
CN1489565A (zh) | 2004-04-14 |
BR0116884A (pt) | 2004-06-22 |
ES2322693T3 (es) | 2009-06-25 |
CZ20032479A3 (cs) | 2004-08-18 |
HUP0303274A2 (hu) | 2004-01-28 |
DE50114767D1 (de) | 2009-04-23 |
ATE425133T1 (de) | 2009-03-15 |
DE10113381A1 (de) | 2002-08-14 |
PL362245A1 (en) | 2004-10-18 |
CA2435590C (en) | 2009-06-02 |
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Legal Events
Date | Code | Title | Description |
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FA93 | Acknowledgement of application withdrawn (no request for examination) |
Effective date: 20050209 |