PE20191848A1 - Polimerizacion en solucion en multiples reactores - Google Patents

Polimerizacion en solucion en multiples reactores

Info

Publication number
PE20191848A1
PE20191848A1 PE2019002059A PE2019002059A PE20191848A1 PE 20191848 A1 PE20191848 A1 PE 20191848A1 PE 2019002059 A PE2019002059 A PE 2019002059A PE 2019002059 A PE2019002059 A PE 2019002059A PE 20191848 A1 PE20191848 A1 PE 20191848A1
Authority
PE
Peru
Prior art keywords
reactor
reactors
polymerization
solution
multiple reactors
Prior art date
Application number
PE2019002059A
Other languages
English (en)
Inventor
Niousha Kazemi
Yves Lacombe
Stephen Brown
Stephen Salomons
Xiaochuan Wang
Asseldonk Lawrence Van
Original Assignee
Nova Chem Int Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chem Int Sa filed Critical Nova Chem Int Sa
Publication of PE20191848A1 publication Critical patent/PE20191848A1/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006Controlling or regulating processes
    • B01J19/0013Controlling the temperature of the process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0046Sequential or parallel reactions, e.g. for the synthesis of polypeptides or polynucleotides; Apparatus and devices for combinatorial chemistry or for making molecular arrays
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053Details of the reactor
    • B01J19/0066Stirrers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • B01J19/1862Stationary reactors having moving elements inside placed in series
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/245Stationary reactors without moving elements inside placed in series
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00Feed or outlet devices; Feed or outlet control devices
    • B01J4/008Feed or outlet control devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00Feed or outlet devices; Feed or outlet control devices
    • B01J4/02Feed or outlet devices; Feed or outlet control devices for feeding measured, i.e. prescribed quantities of reagents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00162Controlling or regulating processes controlling the pressure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/08Presence of a deactivator
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/04Cp or analog not bridged to a non-Cp X ancillary anionic donor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/05Bimodal or multimodal molecular weight distribution
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17Viscosity
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Proceso de polimerizacion en solucion continuo en tres reactores. El solvente del proceso, etileno, comonomeros opcionales, hidrogeno opcional y un sistema catalizador de sitio unico se inyectan en un primer y un segundo reactores configurados en paralelo entre si. Un tercer reactor recibe el efluente del primer reactor, del segundo reactor o una combinacion del primer y segundo reactores. Se alimentan monomeros frescos al tercer reactor para continuar con la polimerizacion y para obtener un producto de polietileno final.
PE2019002059A 2017-04-19 2018-03-28 Polimerizacion en solucion en multiples reactores PE20191848A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15/491,135 US9963529B1 (en) 2017-04-19 2017-04-19 Multi reactor solution polymerization
PCT/IB2018/052141 WO2018193327A1 (en) 2017-04-19 2018-03-28 Multi reactor solution polymerization

Publications (1)

Publication Number Publication Date
PE20191848A1 true PE20191848A1 (es) 2019-12-31

Family

ID=62044773

Family Applications (1)

Application Number Title Priority Date Filing Date
PE2019002059A PE20191848A1 (es) 2017-04-19 2018-03-28 Polimerizacion en solucion en multiples reactores

Country Status (12)

Country Link
US (1) US9963529B1 (es)
EP (1) EP3612571B1 (es)
JP (1) JP7090643B2 (es)
KR (1) KR102489928B1 (es)
CN (1) CN110573538B (es)
AR (1) AR111607A1 (es)
AU (1) AU2018255899A1 (es)
CL (1) CL2019002954A1 (es)
ES (1) ES2878289T3 (es)
MX (1) MX2019011843A (es)
PE (1) PE20191848A1 (es)
WO (1) WO2018193327A1 (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10538654B2 (en) * 2017-04-19 2020-01-21 Nova Chemicals (International) S.A. Multi reactor solution polymerization, polyethylene and polyethylene film
CA2978205A1 (en) * 2017-09-01 2019-03-01 Nova Chemicals Corporation Continuous tuning of ci:mg ratio in a solution polymerization
KR102133030B1 (ko) * 2017-12-18 2020-07-10 주식회사 엘지화학 올레핀 중합체, 이의 제조 방법, 그리고 이를 이용한 필름
CA2989212C (en) * 2017-12-18 2024-05-14 Nova Chemicals Corporation Multistage process for the solution polymerization of ethylene
US11680120B2 (en) * 2017-12-26 2023-06-20 Dow Global Technologies Llc Dual reactor solution process for the production of multimodal ethylene-based polymer
ES2953350T3 (es) 2017-12-26 2023-11-10 Dow Global Technologies Llc Composiciones que comprenden polímeros basados en etileno multimodales y polietileno de baja densidad (LDPE)
EP3732216B1 (en) * 2017-12-26 2023-04-19 Dow Global Technologies LLC Process for the production of multimodal ethylene-based polymers
BR112020012842B1 (pt) 2017-12-26 2024-01-02 Dow Global Technologies Llc Método para produzir um polímero trimodal em um processo de polimerização em solução
JP7278286B2 (ja) 2017-12-26 2023-05-19 ダウ グローバル テクノロジーズ エルエルシー 靭性が改善された多峰性エチレン系ポリマー組成物
WO2019246069A1 (en) * 2018-06-19 2019-12-26 Exxonmobil Chemical Patents Inc. Polyethylene compositions and films prepared therefrom
WO2019243348A1 (en) * 2018-06-21 2019-12-26 Sabic Global Technologies B.V. Polyethylene cast films
CA3011031A1 (en) 2018-07-11 2020-01-11 Nova Chemicals Corporation Polyethylene composition and film having outstanding properties
CA3011030A1 (en) * 2018-07-11 2020-01-11 Nova Chemicals Corporation Polyethylene composition and film having retained dart impact
CA3011050A1 (en) * 2018-07-11 2020-01-11 Nova Chemicals Corporation Polyethylene composition and film having high stiffness, outstanding sealability and high permeability
CA3011041A1 (en) * 2018-07-11 2020-01-11 Nova Chemicals Corporation Polyethylene composition and film
CA3011038A1 (en) * 2018-07-11 2020-01-11 Nova Chemicals Corporation Polyethylene composition and film having a good permeability, stiffness and sealability
US10781273B2 (en) 2018-12-27 2020-09-22 Chevron Phillips Chemical Company Lp Multiple reactor and multiple zone polyolefin polymerization
WO2020178010A1 (en) * 2019-03-04 2020-09-10 Borealis Ag Polymerization process
KR102523121B1 (ko) * 2020-01-31 2023-04-19 주식회사 엘지화학 공액디엔계 중합체의 연속 제조 시스템
US11643531B2 (en) * 2020-10-01 2023-05-09 Nova Chemicals (International) S.A. Thermoformable film
KR102395347B1 (ko) * 2020-10-20 2022-05-09 한화토탈에너지스 주식회사 폴리에틸렌 수지 조성물 및 이의 제조방법
CN112279941B (zh) * 2020-10-21 2024-04-30 浙江传化合成材料股份有限公司 三元稀土催化剂的连续陈化装置及其连续陈化工艺
CN116396549A (zh) 2022-01-04 2023-07-07 韩华道达尔能源有限公司 聚乙烯树脂组合物、其制造方法及包含其的模制品
CA3221979A1 (en) 2022-03-22 2023-10-05 Nova Chemicals Corporation Organometallic complex, olefin polymerization catalyst system and polymerization process
CN114716589B (zh) * 2022-04-20 2023-08-11 浙江大学 一种聚烯烃生产装置和方法
CN114957530B (zh) * 2022-06-28 2023-09-29 杭州双安科技有限公司 一种乙烯和α-烯烃的溶液聚合方法

Family Cites Families (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2302305A1 (fr) 1975-02-28 1976-09-24 Charbonnages Ste Chimique Procede perfectionne de polymerisation et de copolyme
JPS5910724B2 (ja) 1979-08-24 1984-03-10 旭化成株式会社 エチレンの連続重合法
JPS5783538A (en) 1980-11-12 1982-05-25 Kyowa Chem Ind Co Ltd Polyolefin composition and agent thereof
GB8610126D0 (en) 1986-04-25 1986-05-29 Du Pont Canada Isopropanolamines
US4731438A (en) 1986-12-30 1988-03-15 Union Carbide Corporation Water treatment method for resin in a purge vessel
US5236998A (en) 1991-03-07 1993-08-17 Occidental Chemical Corporation Process for the manufacture of linear polyethylene containing α-alkene commonomers
JPH06509528A (ja) 1991-07-18 1994-10-27 エクソン・ケミカル・パテンツ・インク ヒートシール製品
ES2161444T3 (es) 1996-03-05 2001-12-01 Dow Chemical Co Poliolefinas con reologia modificada.
CA2227674C (en) 1998-01-21 2007-04-24 Stephen John Brown Catalyst deactivation
US6127484A (en) * 1999-04-29 2000-10-03 Equistar Chemicals, Lp Olefin polymerization process
DE19945980A1 (de) 1999-09-24 2001-03-29 Elenac Gmbh Polyethylen Formmasse mit verbesserter ESCR-Steifigkeitsrelation und Schwellrate, Verfahren zu ihrer Herstellung und daraus hergestellte Hohlkörper
US7288596B2 (en) 2003-12-22 2007-10-30 Univation Technologies, Llc Polyethylene compositions having improved tear properties
US7312279B2 (en) 2005-02-07 2007-12-25 Univation Technologies, Llc Polyethylene blend compositions
DE102005009916A1 (de) 2005-03-01 2006-09-07 Basell Polyolefine Gmbh Polyethylen Formmasse zum Herstellen von Blasfolien mit verbesserten mechanischen Eigenschaften
DE102005009896A1 (de) 2005-03-01 2006-09-07 Basell Polyolefine Gmbh Polyethylen Formmasse zum Herstellen von Blasfolien mit verbesserten mechanischen Eigenschaften
DE102005030941A1 (de) 2005-06-30 2007-01-11 Basell Polyolefine Gmbh Polyethylen Formmasse zur Herstellung von spritzgegossenen Fertigteilen
KR100882314B1 (ko) * 2006-04-04 2009-02-10 주식회사 엘지화학 폴리에틸렌의 제조방법
KR101141494B1 (ko) * 2007-09-05 2012-05-03 에스케이이노베이션 주식회사 다봉 분자량 분포를 갖는 에틸렌 공중합체 및 이의제조방법
US9187627B2 (en) 2008-10-23 2015-11-17 Equistar Chemicals, Lp Polyethylene having faster crystallization rate and improved environmental stress cracking resistance
US20100113715A1 (en) * 2008-11-04 2010-05-06 Lynch Michael W Olefin polymerization process
US8114946B2 (en) * 2008-12-18 2012-02-14 Chevron Phillips Chemical Company Lp Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches
CN102753590B (zh) 2009-11-20 2014-07-09 巴塞尔聚烯烃股份有限公司 用于吹塑的三峰聚乙烯
CA2688217C (en) 2009-12-11 2016-07-12 Nova Chemicals Corporation Multi reactor process
RU2540073C2 (ru) 2010-01-29 2015-01-27 Бореалис Аг Повышение однородности смесей полиэтиленов
WO2012004422A1 (es) 2010-07-06 2012-01-12 Dow Global Technologies Llc Mezclas de polímeros de etileno y artículos orientados con resistencia mejorada a la contracción
BR122019023821B1 (pt) 2010-11-22 2021-03-02 Basell Polyolefine Gmbh artigo moldado por sopro
GB2498936A (en) 2012-01-31 2013-08-07 Norner Innovation As Polyethylene with multi-modal molecular weight distribution
WO2013144324A1 (en) 2012-03-28 2013-10-03 Borealis Ag Multimodal polymer
CA2798855C (en) * 2012-06-21 2021-01-26 Nova Chemicals Corporation Ethylene copolymers having reverse comonomer incorporation
CA2798854C (en) 2012-12-14 2020-02-18 Nova Chemicals Corporation Polyethylene compositions having high dimensional stability and excellent processability for caps and closures
EP2883887A1 (en) 2013-12-13 2015-06-17 Borealis AG Multistage process for producing polyethylene compositions
CA2868640C (en) 2014-10-21 2021-10-26 Nova Chemicals Corporation Solution polymerization process
WO2016063200A1 (en) 2014-10-21 2016-04-28 Nova Chemicals (International) S.A. Continuous solution polymerization process

Also Published As

Publication number Publication date
CL2019002954A1 (es) 2020-05-08
AU2018255899A1 (en) 2019-10-31
KR20190140444A (ko) 2019-12-19
CN110573538B (zh) 2022-09-20
JP7090643B2 (ja) 2022-06-24
US9963529B1 (en) 2018-05-08
KR102489928B1 (ko) 2023-01-19
MX2019011843A (es) 2020-02-07
JP2020517780A (ja) 2020-06-18
EP3612571B1 (en) 2021-05-19
ES2878289T3 (es) 2021-11-18
EP3612571A1 (en) 2020-02-26
BR112019021841A2 (pt) 2020-05-26
CN110573538A (zh) 2019-12-13
AR111607A1 (es) 2019-07-31
WO2018193327A1 (en) 2018-10-25

Similar Documents

Publication Publication Date Title
PE20191848A1 (es) Polimerizacion en solucion en multiples reactores
PE20200228A1 (es) Polimerizacion en solucion en multiples reactores, polietileno y pelicula de polietileno
CL2019002999A1 (es) Medios para aumentar el peso molecular y disminuir la densidad de los interpolímeros de etileno usando formulaciones catalizadoras homogéneas y heterogéneas.
PE20200030A1 (es) Medios para aumentar el peso molecular y disminuir la densidad de los interpolimeros de etileno empleando formulaciones de catalizadores homogeneos
MX2016010309A (es) Produccion de productos de poliolefina.
WO2015200740A3 (en) Ethylene-based polymer composition for films with improved toughness
BR112017008262A2 (pt) processo de polimerização em solução
MX2017008336A (es) Polietileno para tuberias.
AR094325A1 (es) Un proceso de polimerización para producir polímeros a base de etileno
TR201819970T4 (tr) Polietilen ürün hazırlamaya yönelik proses.
AR113190A1 (es) Proceso mejorado para fabricar productos de interpolímeros de etileno
CL2020001204A1 (es) Fabricación de productos de interpolímero de etileno a una mayor tasa de producción.
AR101445A1 (es) Procesos para preparar polímeros basados en etileno que utilizan una distribución de monóxido de carbono
BR112017008723A2 (pt) homopolímero ou copolímero de propileno, composição de polipropileno, artigo, processos para produzir um homopolímero ou copolímero de propileno e para produzir uma composição de polipropileno, processo de transformação de estado de fusão para produzir um artigo, e, uso do homopolímero e/ou copolímero de propileno.
MX2019009111A (es) Composicion de copolimero de etileno-alfa-olefina y fosfato de trialilo.
BR112021006524A2 (pt) método de polimerização de um monômero de olefina para produzir uma primeira composição de poliolefina.
BR112017008724A2 (pt) homopolímero ou copolímero de propileno, composição de polipropileno, artigo, processos para produzir um homopolímero ou copolímero de propileno e para produzir uma composição de polipropileno, processo de transformação de estado de fusão para produzir um artigo, e, uso do homopolímero e/ou copolímero de propileno.
MX2016014070A (es) Proceso para formar poliolefinas.
AR107473A1 (es) Purificación y decoloración de polímeros
BR112018009563A2 (pt) dispositivo injetor de iniciador de polimerização em reator tubular, reator tubular para polimerização contínua de olefinas, e, processo de produção de polímeros e copolímeros de etileno.
WO2019099587A3 (en) Polymerization processes
MX2022000740A (es) Copolimero de poli (etileno-acetato de vinilo) con configuracion espacial no especifica, metodo para su preparacion y uso.
WO2016052982A8 (ko) 섬유 제조용 폴리올레핀 중합체의 제조방법
TH171849B (th) กระบวนการเพื่อก่อรูปเอทิลีน/แอลฟา-โอเลฟินอินเตอร์พอลิเมอร์
TH151208A (es)