BR112018009563A2 - dispositivo injetor de iniciador de polimerização em reator tubular, reator tubular para polimerização contínua de olefinas, e, processo de produção de polímeros e copolímeros de etileno. - Google Patents

dispositivo injetor de iniciador de polimerização em reator tubular, reator tubular para polimerização contínua de olefinas, e, processo de produção de polímeros e copolímeros de etileno.

Info

Publication number
BR112018009563A2
BR112018009563A2 BR112018009563-0A BR112018009563A BR112018009563A2 BR 112018009563 A2 BR112018009563 A2 BR 112018009563A2 BR 112018009563 A BR112018009563 A BR 112018009563A BR 112018009563 A2 BR112018009563 A2 BR 112018009563A2
Authority
BR
Brazil
Prior art keywords
tubular reactor
olefins
injector device
production process
ethylene polymer
Prior art date
Application number
BR112018009563-0A
Other languages
English (en)
Other versions
BR112018009563B1 (pt
Inventor
José Dotti Eduardo
Henrique Konat Gandolfi Paulo
Dal Bó Abella Vitor
Original Assignee
Braskem S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Braskem S.A. filed Critical Braskem S.A.
Publication of BR112018009563A2 publication Critical patent/BR112018009563A2/pt
Publication of BR112018009563B1 publication Critical patent/BR112018009563B1/pt

Links

Classifications

    • A—HUMAN NECESSITIES
    • A62—LIFE-SAVING; FIRE-FIGHTING
    • A62C—FIRE-FIGHTING
    • A62C31/00—Delivery of fire-extinguishing material
    • A62C31/02—Nozzles specially adapted for fire-extinguishing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30—Injector mixers
    • B01F25/31—Injector mixers in conduits or tubes through which the main component flows
    • B01F25/313—Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced in the centre of the conduit
    • B01F25/3131—Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced in the centre of the conduit with additional mixing means other than injector mixers, e.g. screens, baffles or rotating elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40—Static mixers
    • B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/433—Mixing tubes wherein the shape of the tube influences the mixing, e.g. mixing tubes with varying cross-section or provided with inwardly extending profiles
    • B01F25/4335—Mixers with a converging-diverging cross-section
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2455—Stationary reactors without moving elements inside provoking a loop type movement of the reactants
    • B01J19/2465—Stationary reactors without moving elements inside provoking a loop type movement of the reactants externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00—Feed or outlet devices; Feed or outlet control devices
    • B01J4/001—Feed or outlet devices as such, e.g. feeding tubes
    • B01J4/002—Nozzle-type elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/26—Processes for applying liquids or other fluent materials performed by applying the liquid or other fluent material from an outlet device in contact with, or almost in contact with, the surface
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/32—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04—Homopolymers or copolymers of ethene
    • C09D123/06—Polyethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2204/00—Aspects relating to feed or outlet devices; Regulating devices for feed or outlet devices
    • B01J2204/002—Aspects relating to feed or outlet devices; Regulating devices for feed or outlet devices the feeding side being of particular interest

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Emergency Management (AREA)
  • Business, Economics & Management (AREA)
  • Public Health (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

a presente invenção refere-se, na sua generalidade a um reator tubular para homo ou copolimerização de olefinas, com um ou mais dispositivos de injeção de iniciador. refere-se também a um dispositivo injetor de iniciador em corrente de fluido de processo em reator tubular de polimerização, e a processo de produção de polímeros e copolímeros de etileno, particularmente polietileno de baixa densidade (pebd), que utilizam o referido dispositivo.
BR112018009563-0A 2015-12-22 2015-12-22 Dispositivo injetor de iniciador de polimerização em reator tubular, reator tubular para polimerização contínua de olefinas, e, processo de produção de polímeros e copolímeros de etileno BR112018009563B1 (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/BR2015/050268 WO2017106940A1 (pt) 2015-12-22 2015-12-22 Dispositivo injetor de iniciador de polimerização em reator tubular, reator tubular para polimerização contínua de olefinas, e processo de produção de polímeros e copolímeros de etileno

Publications (2)

Publication Number Publication Date
BR112018009563A2 true BR112018009563A2 (pt) 2018-11-06
BR112018009563B1 BR112018009563B1 (pt) 2021-10-13

Family

ID=59088703

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018009563-0A BR112018009563B1 (pt) 2015-12-22 2015-12-22 Dispositivo injetor de iniciador de polimerização em reator tubular, reator tubular para polimerização contínua de olefinas, e, processo de produção de polímeros e copolímeros de etileno

Country Status (6)

Country Link
US (1) US10829568B2 (pt)
EP (1) EP3375793B1 (pt)
AR (1) AR107171A1 (pt)
BR (1) BR112018009563B1 (pt)
MX (1) MX2018007698A (pt)
WO (1) WO2017106940A1 (pt)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114939383B (zh) * 2022-06-01 2023-06-06 浙江大学宁波“五位一体”校区教育发展中心 一种在高压管式反应器中的乙烯聚合方法和装置
EP4389775A1 (en) 2022-12-20 2024-06-26 ExxonMobil Chemical Patents Inc. Initiator injection line for high pressure polymerization
EP4389273A1 (en) 2022-12-20 2024-06-26 ExxonMobil Chemical Patents Inc. A tubular reactor comprising a thermocouple device for measuring a temperature within the tubular reactor

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE585741A (pt) * 1958-12-17
GB1038215A (en) * 1962-05-21 1966-08-10 Monsanto Co Production of ethylene polymers and copolymers
GB1090823A (en) * 1963-12-03 1967-11-15 Monsanto Co Copolymerisation of ethylene
US3917577A (en) * 1968-09-20 1975-11-04 Basf Ag Continuous production of ethylene homopolymers
US3691145A (en) 1970-08-06 1972-09-12 Basf Ag Production of polyethylene by the high pressure process using a mixture of tertiary butyl hydroperoxide and oxygen as the initiator
GB1569518A (en) 1978-02-17 1980-06-18 Sumitomo Chemical Co Process for producing ethylene polymers
JPH0725856B2 (ja) * 1986-07-25 1995-03-22 大日本インキ化学工業株式会社 ゴム変性スチレン系樹脂の連続塊状重合法
DE4010271A1 (de) * 1990-03-30 1991-10-02 Basf Ag Verfahren zur herstellung von ethylenpolymerisaten bei druecken oberhalb von 500 bar in einem rohrreaktor mit einspritzfinger
DE19754039A1 (de) * 1997-12-05 1999-06-24 Basf Ag Verfahren zur Herstellung von Ethylencopolymeren in segmentierten Rohrreaktoren und Verwendung der Copolymere als Fließverbesserer
DE19926223A1 (de) 1999-06-10 2000-12-14 Elenac Gmbh Verfahren zur Herstellung von Ethylenhomo- und -copolymeren durch intensives Vermischen einer reaktiven Reaktionskomponente mit einem strömenden Fließmedium
DE10060372A1 (de) 2000-12-05 2002-06-06 Basell Polyolefine Gmbh Vorrichtung zur Initiatoreinspeisung an Reaktoren
DE10351262A1 (de) * 2003-10-31 2005-06-02 Basell Polyolefine Gmbh Verfahren zur kontinuierlichen Herstellung von Ethylenhomo- oder Copolymeren
ATE458548T1 (de) 2004-01-06 2010-03-15 Saudi Basic Ind Corp Polymerisations-rohrreaktor für die herstellung von polyethylen
US7863386B2 (en) * 2005-03-04 2011-01-04 Dow Global Technologies Inc. Low density ethylenic polymer composition and method of making the same
CN102282180B (zh) * 2009-01-16 2013-11-20 巴塞尔聚烯烃股份有限公司 在减少输出量的管式反应器中的乙烯聚合方法
KR101671043B1 (ko) * 2009-02-05 2016-10-31 다우 글로벌 테크놀로지스 엘엘씨 퍼옥시드 개시제 주입용 저밀도 폴리에틸렌(ｌｄｐｅ) 관형 반응기
EP2681250B2 (en) 2011-03-03 2018-11-14 Basell Polyolefine GmbH Process for preparing ethylene homopolymers or copolymers in a tubular reactor with at least two reaction zones having different concentrations of chain transfer agent
CN203227474U (zh) * 2013-05-23 2013-10-09 浙江鑫甬生物化工有限公司 聚合引发剂压力注入装置
CA2837591A1 (en) * 2013-12-19 2015-06-19 Nova Chemicals Corporation Polyethylene composition for extrusion coating

Also Published As

Publication number Publication date
EP3375793A1 (en) 2018-09-19
WO2017106940A1 (pt) 2017-06-29
AR107171A1 (es) 2018-03-28
US10829568B2 (en) 2020-11-10
EP3375793A4 (en) 2019-05-22
EP3375793B1 (en) 2023-09-06
BR112018009563B1 (pt) 2021-10-13
MX2018007698A (es) 2018-11-09
US20190322771A1 (en) 2019-10-24

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Legal Events

Date Code Title Description
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 22/12/2015, OBSERVADAS AS CONDICOES LEGAIS.