NO119490B - - Google Patents

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Publication number: NO119490B
Authority: NO; Norway
Prior art keywords: catalyst; arsenic; component; amount; platinum
Prior art date: 1966-02-14

Application number

NO166826A

Other languages

English (en)

Norwegian (no)

Inventor

V Haensel

J Hoeckstra

Original Assignee

Universal Oil Prod Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1966-02-14

Filing date

1967-02-13

Publication date

1970-05-25

1966-02-14 Priority claimed from US527051A external-priority patent/US3291755A/en

1967-02-13 Application filed by Universal Oil Prod Co filed Critical Universal Oil Prod Co

1970-05-25 Publication of NO119490B publication Critical patent/NO119490B/no

Links

239000003054 catalyst Substances 0.000 claims description 84
239000000463 material Substances 0.000 claims description 35
229910052785 arsenic Inorganic materials 0.000 claims description 31
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 31
238000006356 dehydrogenation reaction Methods 0.000 claims description 29
238000000034 method Methods 0.000 claims description 26
229910052751 metal Inorganic materials 0.000 claims description 23
239000002184 metal Substances 0.000 claims description 23
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 20
229930195733 hydrocarbon Natural products 0.000 claims description 19
150000002430 hydrocarbons Chemical class 0.000 claims description 19
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 16
239000001257 hydrogen Substances 0.000 claims description 16
229910052739 hydrogen Inorganic materials 0.000 claims description 16
229910052783 alkali metal Inorganic materials 0.000 claims description 9
150000001340 alkali metals Chemical class 0.000 claims description 9
229910052787 antimony Inorganic materials 0.000 claims description 8
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 8
229910052797 bismuth Inorganic materials 0.000 claims description 8
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 8
150000001875 compounds Chemical class 0.000 claims description 8
229930195734 saturated hydrocarbon Natural products 0.000 claims description 6
230000000737 periodic effect Effects 0.000 claims description 5
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 69
238000006243 chemical reaction Methods 0.000 description 53
229910052697 platinum Inorganic materials 0.000 description 35
238000005336 cracking Methods 0.000 description 22
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 18
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 15
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 15
229910052744 lithium Inorganic materials 0.000 description 15
230000000694 effects Effects 0.000 description 13
GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 12
239000007858 starting material Substances 0.000 description 12
239000004215 Carbon black (E152) Substances 0.000 description 11
238000006317 isomerization reaction Methods 0.000 description 11
239000007788 liquid Substances 0.000 description 10
239000001282 iso-butane Substances 0.000 description 9
238000007086 side reaction Methods 0.000 description 9
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 8
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
150000001336 alkenes Chemical class 0.000 description 7
125000004429 atom Chemical group 0.000 description 7
230000002378 acidificating effect Effects 0.000 description 6
SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 6
238000004519 manufacturing process Methods 0.000 description 6
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical compound CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
229910052799 carbon Inorganic materials 0.000 description 5
125000004432 carbon atom Chemical group C* 0.000 description 5
239000012876 carrier material Substances 0.000 description 5
229910052809 inorganic oxide Inorganic materials 0.000 description 5
239000000047 product Substances 0.000 description 5
238000012360 testing method Methods 0.000 description 5
ATQUFXWBVZUTKO-UHFFFAOYSA-N 1-methylcyclopentene Chemical compound CC1=CCCC1 ATQUFXWBVZUTKO-UHFFFAOYSA-N 0.000 description 4
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
230000003247 decreasing effect Effects 0.000 description 4
IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 4
150000005673 monoalkenes Chemical class 0.000 description 4
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 4
239000001294 propane Substances 0.000 description 4
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 3
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 3
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
238000002844 melting Methods 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
239000000203 mixture Substances 0.000 description 3
229910000510 noble metal Inorganic materials 0.000 description 3
238000007142 ring opening reaction Methods 0.000 description 3
238000003786 synthesis reaction Methods 0.000 description 3
RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
230000003213 activating effect Effects 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
150000001342 alkaline earth metals Chemical class 0.000 description 2
OTIJDYHLLCTUJA-UHFFFAOYSA-N aluminum oxygen(2-) platinum(2+) Chemical compound [Pt+2].[O-2].[Al+3] OTIJDYHLLCTUJA-UHFFFAOYSA-N 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
238000001354 calcination Methods 0.000 description 2
230000003197 catalytic effect Effects 0.000 description 2
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
150000001925 cycloalkenes Chemical class 0.000 description 2
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
150000001993 dienes Chemical class 0.000 description 2
230000008034 disappearance Effects 0.000 description 2
239000007789 gas Substances 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
238000005470 impregnation Methods 0.000 description 2
229910052741 iridium Inorganic materials 0.000 description 2
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
239000012263 liquid product Substances 0.000 description 2
229910052762 osmium Inorganic materials 0.000 description 2
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 2
229910052763 palladium Inorganic materials 0.000 description 2
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
-1 polypropylene Polymers 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
238000004064 recycling Methods 0.000 description 2
229910052703 rhodium Inorganic materials 0.000 description 2
239000010948 rhodium Substances 0.000 description 2
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
229910052707 ruthenium Inorganic materials 0.000 description 2
239000000243 solution Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
229930195735 unsaturated hydrocarbon Natural products 0.000 description 2
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
229920002367 Polyisobutene Polymers 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
229910002065 alloy metal Inorganic materials 0.000 description 1
239000000538 analytical sample Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
239000002585 base Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
229910052810 boron oxide Inorganic materials 0.000 description 1
239000001273 butane Substances 0.000 description 1
229920005549 butyl rubber Polymers 0.000 description 1
229910052792 caesium Inorganic materials 0.000 description 1
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
238000004517 catalytic hydrocracking Methods 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
229920006026 co-polymeric resin Polymers 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
239000002131 composite material Substances 0.000 description 1
239000003431 cross linking reagent Substances 0.000 description 1
230000009089 cytolysis Effects 0.000 description 1
230000007547 defect Effects 0.000 description 1
230000008021 deposition Effects 0.000 description 1
239000003599 detergent Substances 0.000 description 1
JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000000446 fuel Substances 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
229910000449 hafnium oxide Inorganic materials 0.000 description 1
WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
230000009931 harmful effect Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000003350 kerosene Substances 0.000 description 1
230000002045 lasting effect Effects 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
238000012261 overproduction Methods 0.000 description 1
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
150000003058 platinum compounds Chemical class 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
230000000607 poisoning effect Effects 0.000 description 1
229920001083 polybutene Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
WHFQAROQMWLMEY-UHFFFAOYSA-N propylene dimer Chemical compound CC=C.CC=C WHFQAROQMWLMEY-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
238000000197 pyrolysis Methods 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
238000012552 review Methods 0.000 description 1
229910052701 rubidium Inorganic materials 0.000 description 1
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
230000001629 suppression Effects 0.000 description 1
NBRKLOOSMBRFMH-UHFFFAOYSA-N tert-butyl chloride Chemical compound CC(C)(C)Cl NBRKLOOSMBRFMH-UHFFFAOYSA-N 0.000 description 1
ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
229910003452 thorium oxide Inorganic materials 0.000 description 1
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
239000013638 trimer Substances 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
229910001928 zirconium oxide Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/321—Catalytic processes
- C07C5/324—Catalytic processes with metals
- C07C5/325—Catalytic processes with metals of the platinum group
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/644—Arsenic, antimony or bismuth
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3335—Catalytic processes with metals
- C07C5/3337—Catalytic processes with metals of the platinum group
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/949—Miscellaneous considerations
- Y10S585/952—Reaction stopping or retarding

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Catalysts (AREA)

NO166826A 1966-02-14 1967-02-13 NO119490B (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US527051A US3291755A (en)	1966-02-14	1966-02-14	Catalytic dehydrogenation catalyst for paraffinic hydrocarbons
US541066A US3293319A (en)	1966-02-14	1966-04-08	Catalytic dehydrogenation of paraffinic hydrocarbons

Publications (1)

Publication Number	Publication Date
NO119490B true NO119490B (fr)	1970-05-25

Family

ID=27062296

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO166826A NO119490B (fr)	1966-02-14	1967-02-13

Country Status (18)

Country	Link
US (1)	US3293319A (fr)
AT (2)	AT291951B (fr)
BE (1)	BE693975A (fr)
CH (1)	CH490121A (fr)
CS (1)	CS168494B2 (fr)
DE (2)	DE1643152C3 (fr)
DK (1)	DK136935B (fr)
ES (1)	ES336765A1 (fr)
FI (1)	FI45832C (fr)
FR (1)	FR1511209A (fr)
GB (1)	GB1168342A (fr)
GR (1)	GR33491B (fr)
IL (1)	IL27400A (fr)
NL (1)	NL6702164A (fr)
NO (1)	NO119490B (fr)
OA (1)	OA02319A (fr)
SE (1)	SE332803B (fr)
YU (1)	YU31343B (fr)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3379786A (en) *	1966-05-11	1968-04-23	Universal Oil Prod Co	Catalytic dehydrogenation of alkylaromatic hydrocarbons
US3448165A (en) *	1966-07-26	1969-06-03	Universal Oil Prod Co	Catalytic dehydrogenation of paraffinic hydrocarbons at high space velocity
US3433852A (en) *	1966-11-07	1969-03-18	Ethyl Corp	Process for c6-c24 alkenes by pretreatment of phosphate catalysts
US3433851A (en) *	1966-11-07	1969-03-18	Ethyl Corp	Dehydrogenation process with catalyst pretreating for c6-c24 alkenes
GB1200651A (en) *	1967-05-02	1970-07-29	British Petroleum Co	Dehydrogenation process
US3479416A (en) *	1967-05-19	1969-11-18	Petro Tex Chem Corp	Production of isobutylene from isobutane
US3461183A (en) *	1967-11-08	1969-08-12	Phillips Petroleum Co	Catalytic dehydrogenation process
US3458592A (en) *	1967-12-12	1969-07-29	Texaco Inc	Manufacture of n-mono-olefins from n-paraffins
US3458593A (en) *	1967-12-12	1969-07-29	Texaco Inc	Manufacture of n-alkene from n-alkane
US3448166A (en) *	1967-12-22	1969-06-03	Universal Oil Prod Co	Process for the preparation of normal mono-olefins
US3461177A (en) *	1967-12-26	1969-08-12	Phillips Petroleum Co	Process to convert normal-hexane to naphthenes
US3429944A (en) *	1967-12-27	1969-02-25	Universal Oil Prod Co	Preparation of normal mono-olefins
US3417157A (en) *	1967-12-28	1968-12-17	Universal Oil Prod Co	Transalkylation of toluene and catalyst therefor
US3474156A (en) *	1968-04-03	1969-10-21	Universal Oil Prod Co	Selective catalyst dehydrogenation of a mixture of normal paraffin hydrocarbons
US3527824A (en) *	1968-07-01	1970-09-08	Universal Oil Prod Co	Transalkylation process
US3527825A (en) *	1968-07-03	1970-09-08	Universal Oil Prod Co	Transalkylation process
US3456031A (en) *	1968-07-05	1969-07-15	Universal Oil Prod Co	Selective catalytic dehydrogenation of a mixture of normal paraffin hydrocarbons
US3527837A (en) *	1969-08-13	1970-09-08	Petro Tex Chem Corp	Production of isobutylene
US4133842A (en) *	1977-10-25	1979-01-09	Uop Inc.	Production and recovery of linear mono-olefins
ES2032371T3 (es) *	1990-06-05	1996-03-16	Huntsman Spec Chem Corp	Procedimiento para deshidrogenacion de parafina.
US6417135B1 (en)	1999-08-27	2002-07-09	Huntsman Petrochemical Corporation	Advances in dehydrogenation catalysis
US6676606B2 (en) *	2002-06-11	2004-01-13	Koninklijke Philips Electronics N.V.	Ultrasonic diagnostic micro-vascular imaging

1966
- 1966-04-08 US US541066A patent/US3293319A/en not_active Expired - Lifetime
1967
- 1967-02-07 IL IL27400A patent/IL27400A/xx unknown
- 1967-02-07 GB GB5789/67A patent/GB1168342A/en not_active Expired
- 1967-02-09 FR FR94264A patent/FR1511209A/fr not_active Expired
- 1967-02-10 OA OA52754A patent/OA02319A/fr unknown
- 1967-02-10 AT AT1135168A patent/AT291951B/de not_active IP Right Cessation
- 1967-02-10 AT AT132767A patent/AT289726B/de not_active IP Right Cessation
- 1967-02-11 DE DE1643152A patent/DE1643152C3/de not_active Expired
- 1967-02-11 DE DE19671792719 patent/DE1792719A1/de active Pending
- 1967-02-13 NL NL6702164A patent/NL6702164A/xx unknown
- 1967-02-13 DK DK77967AA patent/DK136935B/da unknown
- 1967-02-13 NO NO166826A patent/NO119490B/no unknown
- 1967-02-13 ES ES336765A patent/ES336765A1/es not_active Expired
- 1967-02-13 BE BE693975D patent/BE693975A/xx unknown
- 1967-02-14 GR GR670133491A patent/GR33491B/el unknown
- 1967-02-14 FI FI670429A patent/FI45832C/fi active
- 1967-02-14 YU YU0281/67A patent/YU31343B/xx unknown
- 1967-02-14 CH CH213667A patent/CH490121A/de not_active IP Right Cessation
- 1967-02-14 CS CS1077A patent/CS168494B2/cs unknown
- 1967-02-14 SE SE02069/67A patent/SE332803B/xx unknown

Also Published As

Publication number	Publication date
SE332803B (fr)	1971-02-22
FI45832B (fr)	1972-06-30
GR33491B (el)	1967-12-09
US3293319A (en)	1966-12-20
CH490121A (de)	1970-05-15
AT291951B (de)	1971-08-10
GB1168342A (en)	1969-10-22
DK136935C (fr)	1978-05-29
IL27400A (en)	1970-07-19
DE1643152B2 (de)	1973-05-30
DK136935B (da)	1977-12-19
AT289726B (de)	1971-05-10
DE1643152C3 (de)	1974-01-10
CS168494B2 (fr)	1976-06-29
NL6702164A (fr)	1967-08-15
BE693975A (fr)	1967-07-17
DE1643152A1 (de)	1972-04-13
FI45832C (fi)	1972-10-10
OA02319A (fr)	1970-05-05
FR1511209A (fr)	1968-01-26
ES336765A1 (es)	1968-01-01
DE1792719A1 (de)	1972-07-06
YU31343B (en)	1973-04-30

Publication	Publication Date	Title
NO119490B (fr)	1970-05-25
JP6563457B2 (ja)	2019-08-21	パラフィンをオレフィンに転化するためのプロセス及びそこで使用するための触媒
Hettinger et al.	1955	Hydroforming Reactions-Effect of Certain Catalyst Properties and Poisons
Csicsery	1970	Dehydrocyclodimerization: I. Dehydrocyclodimerization of butanes over supported platinum catalysts
JP3854650B2 (ja)	2006-12-06	オレフィン複分解
US3116345A (en)	1963-12-31	Process for production of branch chain hydrocarbons from propene
US3679773A (en)	1972-07-25	Dehydrogenation-type reactions with group viii catalysts
US3775505A (en)	1973-11-27	Saturated hydrocarbon disproportionation at low temperatures
US4202996A (en)	1980-05-13	Hydrocarbon isomerization process
US2257082A (en)	1941-09-23	Treatment of hydrocarbons
US3291855A (en)	1966-12-13	Catalytic dehydrogenation of paraffinic hydrocarbons
US3864417A (en)	1975-02-04	Saturated hydrocarbon disproportionation at low temperatures
US2395876A (en)	1946-03-05	Chemical process
US2626286A (en)	1953-01-20	Production of aromatics and saturated aliphatics
US2148129A (en)	1939-02-21	Dehydrogenation of hydrocarbons
US3267170A (en)	1966-08-16	Process for forming olefins by hydrogen transfer
US3391218A (en)	1968-07-02	Catalytic dehydrogenation of paraffinic hydrocarbons enhanced by benzene
US3766292A (en)	1973-10-16	Process for obtaining isopentane from butane hexane or mixtures thereof
US3248451A (en)	1966-04-26	Catalytic dehydrogenation of hydrocarbons
US2355868A (en)	1944-08-15	Catalytic hydrocarbon reactions and catalysts therefor
US2775638A (en)	1956-12-25	Catalytic polymerization of olefins
US3299156A (en)	1967-01-17	Dehydrocyclization catalyst and process
US2401846A (en)	1946-06-11	Procedure for olefin dehydrogenation
US2635123A (en)	1953-04-14	Reforming of hydrocarbons
US2216274A (en)	1940-10-01	Hydrocarbon reactions