KR970061511A - 적층판 및 그의 제조방법 - Google Patents

적층판 및 그의 제조방법 Download PDF

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KR970061511A
KR970061511A KR1019960041737A KR19960041737A KR970061511A KR 970061511 A KR970061511 A KR 970061511A KR 1019960041737 A KR1019960041737 A KR 1019960041737A KR 19960041737 A KR19960041737 A KR 19960041737A KR 970061511 A KR970061511 A KR 970061511A
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thermosetting resin
inorganic filler
varnish
laminate
fiber support
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KR1019960041737A
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KR100403649B1 (ko
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다까히로 나까따
다까히사 이이다
다까시 야마구찌
도시히데 가나자와
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엔다 나오또
스미또모 베크라이트 가부시끼가이샤
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/02Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising combinations of reinforcements, e.g. non-specified reinforcements, fibrous reinforcing inserts and fillers, e.g. particulate fillers, incorporated in matrix material, forming one or more layers and with or without non-reinforced or non-filled layers
    • B29C70/021Combinations of fibrous reinforcement and non-fibrous material
    • B29C70/025Combinations of fibrous reinforcement and non-fibrous material with particular filler
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/02Layered products comprising a layer of synthetic resin in the form of fibres or filaments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/50Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/02Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
    • B32B17/04Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments bonded with or embedded in a plastic substance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/0038Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding involving application of liquid to the layers prior to lamination, e.g. wet laminating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/08Impregnating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022Non-woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024Woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/28Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer impregnated with or embedded in a plastic substance
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/03Use of materials for the substrate
    • H05K1/0313Organic insulating material
    • H05K1/0353Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
    • H05K1/036Multilayers with layers of different types
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/021Fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04Impregnation, embedding, or binder material
    • B32B2260/046Synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • B32B2305/10Fibres of continuous length
    • B32B2305/20Fibres of continuous length in the form of a non-woven mat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • B32B2305/30Fillers, e.g. particles, powders, beads, flakes, spheres, chips
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00Electrical equipment
    • B32B2457/08PCBs, i.e. printed circuit boards
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/03Use of materials for the substrate
    • H05K1/0313Organic insulating material
    • H05K1/0353Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
    • H05K1/0366Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement reinforced, e.g. by fibres, fabrics
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/02Fillers; Particles; Fibers; Reinforcement materials
    • H05K2201/0203Fillers and particles
    • H05K2201/0206Materials
    • H05K2201/0209Inorganic, non-metallic particles
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/02Fillers; Particles; Fibers; Reinforcement materials
    • H05K2201/0275Fibers and reinforcement materials
    • H05K2201/0284Paper, e.g. as reinforcement
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/02Fillers; Particles; Fibers; Reinforcement materials
    • H05K2201/0275Fibers and reinforcement materials
    • H05K2201/0293Non-woven fibrous reinforcement

Abstract

본 발명은 중간층은 열경화성 수지와 무기 충전제를 함유하는 수지 조성물로 함유된 유리섬유 부직물로 만들어진 중심층 및 열경화성 수지와 무기 충전제를 함유하는 상기의 수지 조성물로 각각 만들어진, 충진층 위에 형성된 상층 및 하층으로 구성되며, 중간층위에 형성된 2개의 표면층은 열경화성 수지-합침된 섬유 지지체로 만들어진 것을 특징으로 하는 중간층과 중간층위에 형성된 2개의 표면층으로 구성된 적층판 및 상기 적층판의 제조방법에 관한 것이다.

Description

적층판 및 그의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 각각 본 발명의 적층판의 제조에서 프리프레그 형성을 위한 단계의 예시를 나타내는 개략도이다.

Claims (19)

  1. 중간층은 열경화성 수지와 무기 충전제를 함유하는 수지 조성물로 함침된 유리섬유 부직물로 만들어진 중심층 및 열경화성 수지와 무기 충전제를 함유하는 상기의 수지 조성물로 각각 만들어진, 중심층 위에 형성된 상층 및 하층으로 구성되며, 중간층위에 형성된 2개의 표면층은 열경화성 수지-합침된 섬유 지지체로 만들어진 것을 특징으로 하는 중간층과 중간층위에 형성된 2개의 표면층으로 구성된 적층판.
  2. 제1항에 있어서, 수지 조성물 중의 무기충전제의 비율을 열경화성 수지에 대해 10-300중량%의 적층판.
  3. 하기의 단계로 구성된 적층판의 제조방법. 무기 충전제를 함유한 열경화성 수지 와니스를 길이가 긴 섬유지지체의 한 면위에 피복하는 단계; 섬유 지지체의 와니스-피복된 면위에 유리섬유 부직물을 적층시켜 라미네이트를 얻는 단계; 라미네이트를 가열-건조시켜 프리프레그를 얻는 단계; 및 상기와 같이 형성된 프리프레그 두장을 적층시켜서 각각의 유리섬유 부직물이 서로 마주보도록 하고, 생성된 라미네이트를 고온 프레싱하는 단계.
  4. 제3항에 있어서, 무기 충전제를 함유한 열경화성 수지 와니스를 길이가 긴 섬유 지지체의 한 면위에 피복하는 단계의 전 단계로서 열경화성 수지만으로 된 와니스를 상기의 한 면위에 피복하는 단계를 추가로 포함하는 방법.
  5. 제3항에 있어서, 와니스 피복된 섬유 지지체의 면위에 유리섬유 부직물을 적층시키는 단계와 다음 단계로서 섬유 지지체의 다른 면위에 열경화성 수지 와니스를 피복하는 단계를 추가로 포함하는 방법.
  6. 제5항에 있어서, 무기충전제를 함유하는 열경화성 수지 와니스에서 무기충전제의 비율은 열경화성 수지에 대해 10-300중량%인 방법.
  7. 하기의 단계로 구성된 적층판의 제조방법. 무기 충전제를 함유한 열경화성 수지 와니스를 길이가 긴 섬유 지지체의 한 면위에 피복하는 단계; 와니스-피복된 섬유 지지체를 가열-건조시키는 단계; 와니스-피복된 섬유 지지체의 면위에 유리섬유 부직물을 적층시켜 라미네이트를 수득하는 단계; 라미네이트를 가열-건조시켜 프리프레그를 얻는 단계; 및 상기와 같이 형성된 프리프레그 두장을 적층시켜서 각각의 유리섬유 부직물이 서로 마주보도록 하고, 생성된 라미네이트를 고온 프레싱하는 단계.
  8. 제7항에 있어서, 무기 충전제를 함유한 열경화성 수지 와니스를 길이가 긴 섬유 지지체의 한 면위에 피복하는 단계의 전 단계로서 열경화성 수지만으로 된 와니스를 상기의 한 면위에 피복하는 단계를 추가로 포함하는 방법.
  9. 제7항에 있어서, 와니스 피복된 섬유 지지체의 면위에 유리섬유 부직물을 적층시키는 단계의 다음 단계로서 섬유 지지체의 다른 면위에 열경화성 수지 와니스를 피복하는 단계를 추가로 포함하는 방법.
  10. 제9항에 있어서, 무기충전제를 함유하는 열경화성 수지 와니스에서 무기충전제의 비율은 열경화성 수지에 대해 10-300중량%인 방법.
  11. 제1항에 있어서, 무기충전제는 수산화알루미늄, 수산화마그네슘, 탄산칼슘, 클레이, 탈크 및 실리카로 구성된 군으로부터 선택된 적층판.
  12. 제1항에 있어서, 열경화성 수지는 에폭시 수지, 폴리이미드 수지, 폴리에스테르 수지, 페놀 수지 및 아크릴 수지로 구성된 군으로부터 선택된 적층판.
  13. 제1항에 있어서, 섬유 지지체는 유리섬유 직물, 유리섬유 부직물, 합성섬유 직물 또는 합성섬유 부직물, 크래프트지 및 린터지로 구성된 군으로부터 선택된 적층판.
  14. 제3항에 있어서, 무기충전제는 수산화알루미늄, 수산화마그네슘, 탄산칼슘, 클레이, 탈크 및 실리카로 구성된 군으로부터 선택된 방법.
  15. 제3항에 있어서, 열경화성 수지는 에폭시 수지, 폴리이미드 수지, 폴리에스테르 수지, 페놀 수지 및 아크릴 수지로 구성된 군으로부터 선택된 열경화성 수지인 방법.
  16. 제3항에 있어서, 섬유 지지체는 유리섬유 직물, 유리섬유 부직물, 합성섬유 직물 또는 합성섬유 부직물, 크래프트지 및 린터지로 구성된 군으로부터 선택된 방법.
  17. 제7항에 있어서, 무기충전제는 수산화알루미늄, 수산화마그네슘, 탄산칼슘, 클레이, 탈크 및 실리카로 구성된 군으로부터 선택된 방법.
  18. 제7항에 있어서, 열경화성 수지는 에폭시 수지, 폴리이미드 수지, 폴리에스테르 수지, 페놀 수지 및 아크릴 수지로 구성된 군으로부터 선택된 방법.
  19. 제7항에 있어서, 섬유 지지체는 유리섬유 직물, 유리섬유 부직물, 합성섬유 직물 또는 합성섬유 부직물, 크래프트지 및 런터지로 구성된 군으로부터 선택된 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960041737A 1996-02-29 1996-09-23 적층판및그의제조방법 KR100403649B1 (ko)

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KR100509161B1 (ko) * 2002-07-11 2005-08-23 주식회사 성진케미칼 도전성 고무패드층 및 폴리이미드층을 구비한 유리섬유 패드
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KR20140063711A (ko) * 2011-09-22 2014-05-27 히타치가세이가부시끼가이샤 적층체, 적층판, 다층 적층판, 프린트 배선판 및 적층판의 제조 방법

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KR100403649B1 (ko) 2004-03-20
EP0792737A2 (en) 1997-09-03
DE69713532D1 (de) 2002-08-01
EP0792737B1 (en) 2002-06-26
CN1080642C (zh) 2002-03-13
DE69713532T2 (de) 2003-02-27
EP0792737A3 (en) 1998-07-22
ID15992A (id) 1997-08-21
CN1162526A (zh) 1997-10-22
JP3119577B2 (ja) 2000-12-25
SG94696A1 (en) 2003-03-18

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