KR960034673A - 질소 산화물 흡수제의 열화 검출장치 - Google Patents

질소 산화물 흡수제의 열화 검출장치 Download PDF

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KR960034673A
KR960034673A KR1019960007161A KR19960007161A KR960034673A KR 960034673 A KR960034673 A KR 960034673A KR 1019960007161 A KR1019960007161 A KR 1019960007161A KR 19960007161 A KR19960007161 A KR 19960007161A KR 960034673 A KR960034673 A KR 960034673A
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absorbent
air
fuel ratio
amount
lean
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다카미츠 아사누마
데츠로 기하라
겐지 가토
사토시 이구치
신이치 다케시마
도시아키 다나카
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와다 아키히로
도요타 지도샤 가부시키가이샤
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0828Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
    • F01N3/0842Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9495Controlling the catalytic process
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N11/00Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity
    • F01N11/007Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity the diagnostic devices measuring oxygen or air concentration downstream of the exhaust apparatus
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D41/00Electrical control of supply of combustible mixture or its constituents
    • F02D41/02Circuit arrangements for generating control signals
    • F02D41/021Introducing corrections for particular conditions exterior to the engine
    • F02D41/0235Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus
    • F02D41/027Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus to purge or regenerate the exhaust gas treating apparatus
    • F02D41/0275Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus to purge or regenerate the exhaust gas treating apparatus the exhaust gas treating apparatus being a NOx trap or adsorbent
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2550/00Monitoring or diagnosing the deterioration of exhaust systems
    • F01N2550/03Monitoring or diagnosing the deterioration of exhaust systems of sorbing activity of adsorbents or absorbents
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2570/00Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/14Nitrogen oxides
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D2200/00Input parameters for engine control
    • F02D2200/02Input parameters for engine control the parameters being related to the engine
    • F02D2200/08Exhaust gas treatment apparatus parameters
    • F02D2200/0806NOx storage amount, i.e. amount of NOx stored on NOx trap
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D2200/00Input parameters for engine control
    • F02D2200/02Input parameters for engine control the parameters being related to the engine
    • F02D2200/08Exhaust gas treatment apparatus parameters
    • F02D2200/0808NOx storage capacity, i.e. maximum amount of NOx that can be stored on NOx trap
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D2200/00Input parameters for engine control
    • F02D2200/02Input parameters for engine control the parameters being related to the engine
    • F02D2200/08Exhaust gas treatment apparatus parameters
    • F02D2200/0814Oxygen storage amount
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D2200/00Input parameters for engine control
    • F02D2200/02Input parameters for engine control the parameters being related to the engine
    • F02D2200/08Exhaust gas treatment apparatus parameters
    • F02D2200/0816Oxygen storage capacity
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02DCONTROLLING COMBUSTION ENGINES
    • F02D41/00Electrical control of supply of combustible mixture or its constituents
    • F02D41/02Circuit arrangements for generating control signals
    • F02D41/14Introducing closed-loop corrections
    • F02D41/1438Introducing closed-loop corrections using means for determining characteristics of the combustion gases; Sensors therefor
    • F02D41/1439Introducing closed-loop corrections using means for determining characteristics of the combustion gases; Sensors therefor characterised by the position of the sensor
    • F02D41/1441Plural sensors
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/40Engine management systems

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Toxicology (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Electrical Control Of Air Or Fuel Supplied To Internal-Combustion Engine (AREA)
  • Combined Controls Of Internal Combustion Engines (AREA)

Abstract

본 발명의 목적은 NOx흡수제의 O2스트레지 기능의 저하 및 NOx흡수 능력의 저하를 검출하는 것으로 기관 배기 통로내에 NOx흡수제(18)를 배치한다. NOx흡수제(18)하류의 기관 배기 통로내에 공연비에 비례한 전류가 발생하는 O2센서(22)를 배치한다. NOx흡수제(18)에 흡수되어 있는 NOx량의 거의 영인 때 혹은 NOx흡수제(18)에 흡수되어 있는 NOx량을 거의 영으로 한 후 혼합기의 공연비를 린에서 리치로 변환하고 이때의 O2센서(22)의 출력 신호에서 NOx흡수제(18)에 저장되어 있던 산소량을 검출한다. 또한 상기 검출된 산소량을 사용하여 NOx흡수 능력을 구한다.

Description

질소 산화물 흡수제의 열화 검출장치
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 내연기관의 전체도, 제12도는 O2스트레지 량을 검출하기 위한 흐름도, 제13도는 공연비를 제어하기 위한 흐름도, 제14도는 공연비를 제어하기 위한 흐름도, 제15도는 공연비를 제어하기 위한 흐름도,제16도는 피드백 제어 Ⅰ를 실행하기 위한 흐름도.

Claims (5)

  1. 유입되는 배기 가스의 공연비가 린(희박)인 때에 NOx를 흡수함과 동시에 산소를 저장하고, 유입되는 배기가스의 공연비가 리치(농후)가 되면 흡수한 NOx및 저장한 산소를 방출하는 NOx흡수제를 기관 배기 통로내에 배치하고, NOx흡수제 하류의 기관 배기 통로내에 공연비에 따른 출력신호를 발생하는 공연비 센서를 배치하고, NOx흡수제에 흡수되어 있는 NOx량이 대부분 영인 때에 NOx흡수제로 유입되는 배기 가스의 공연비를 린에서 리치로 변환하는 공연비 변환 수단과, NOx흡수제로 유입되는 배기가스의 공연비를 린에서 리치로 변환한 후의 공연비 센서의 출력 신호에 의거하여 NOx흡수제에 저장되어 있는 산소량을 검출하는 저장 산소량 검출 수단을 구비한 것을 특징으로 하는 질소 산화물 (NOx)흡수제의 열화 검출장치.
  2. 제1항에 있어서, 상기 공연비 변환 수단은 NOx흡수제에 흡수되어 있는 NOx량을 대부분 영으로 하기 위하여 NOx 흡수제로 유입되는 배기가스의 공연비를 일시적으로 린에서 리치로 변환함과 동시에 , 그후 일시적으로 린으로 유지한 후에 재차 린에서 리치로 변환하고, 상기 저장 산소량 검출 수단은 린에서 리치로 2번째의 변환 후 공연비 센서의 출력 신호에 의거하여 NOx흡수제에 저장되어 있는 산소량을 검출하는 것을 특징으로 하는질소 산화물 (NOx) 흡수제의 열화 검출장치.
  3. 제1항에 있어서, NOx흡수제에 흡수되어 있는 NOx량을 대부분 영인지 아닌지 판단하는 판단 수단을 구비하고, 린 혼합기가 연소되고 있을 때에 상기 판단 수단에 의해 NOx흡수제에 흡수되어 있는 NOx가 대부분 영이라고 판단된 때에는, 공연비 변환 수단에 의해 NOx흡수제에 유입되는 배기 가스의 공연비를 린에서 리치로 변환하고, 저장 산소량 검출 수단은 상기 린에서 리치로의 변환 후의 공연비 센서의 출력 신호에 의거하여 NOx흡수제에 저장되어 있는 것을 특징으로 하는질소 산화물 (NOx)흡수제의 열화 검출장치.
  4. 제1항에 있어서, NOx흡수제에 흡수되어 있는 NOx량이 대부분 영인지 아닌지 판단하는 판단 수단을 구비하고, 대부분 이론 공연비의 혼합기가 연소되고 있을 때에 당해 판단 수단에 의해 NOx흡수제에 흡수되어 있는 NOx가 대부분 영이라고 판단된 때에는, 공연비 변환 수단에 의해 NOx흡수제에 유입되는 배기 가스의 공연비를 대부분 이론 공연비에서 린으로 변환함과 동시에, 그후 일시적으로 린으로 유지한 후에 린에서 리치로 변환하고, 저장 산소량 검출 수단은 상기 린에서 리치로의 변환후의 공연비 센서의 출력 신호에 의거하여 NOx흡수제에 저장되어 있는 것을 특징으로 하는질소 산화물 (NOx) 흡수제의 열화 검출장치.
  5. 제1항에 있어서, 상기 공연비 변환 수단에 의해 NOx흡수제로 유입되는 배기 가스의 공연비가, 린에서 리치로의 변환된 후의 공연비 센서의 출력 신호에 의거하여 NOx흡수제에 저장되어 있는 산소량과 NOx흡수제에 흡수되어 있는 NOx량과의 합을 검출하는 저장 산소량 및 흡수NOx량 검출 수단을 구비하고, 상기 산소량과 NOx량의 합에서 상기 저장 산소량 검출 수단에 의해 검출된 산소량을 감산함으로서, NOx흡수제에 흡수되어 있는 NOx량을 산출하도록 한 것을 특징으로 하는 질소 산화물 흡수제의 열화 검출장치.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960007161A 1995-03-28 1996-03-18 질소 산화물 흡수제의 열화 검출장치 KR0165951B1 (ko)

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Application Number Priority Date Filing Date Title
JP7069703A JP2827954B2 (ja) 1995-03-28 1995-03-28 NOx 吸収剤の劣化検出装置
JP95-69703 1995-03-28

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KR960034673A true KR960034673A (ko) 1996-10-24
KR0165951B1 KR0165951B1 (ko) 1999-01-15

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US (1) US5713199A (ko)
EP (2) EP0735250B1 (ko)
JP (1) JP2827954B2 (ko)
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DE (2) DE69633204T2 (ko)

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US5713199A (en) 1998-02-03
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JPH08260949A (ja) 1996-10-08
DE69633204T2 (de) 2005-09-15
EP1146208A3 (en) 2003-10-15
KR0165951B1 (ko) 1999-01-15
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EP0735250B1 (en) 2002-11-13
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