KR960004433A - 자동차 내장용 폴리프로필렌 수지 조성물 - Google Patents
자동차 내장용 폴리프로필렌 수지 조성물 Download PDFInfo
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- KR960004433A KR960004433A KR1019950019904A KR19950019904A KR960004433A KR 960004433 A KR960004433 A KR 960004433A KR 1019950019904 A KR1019950019904 A KR 1019950019904A KR 19950019904 A KR19950019904 A KR 19950019904A KR 960004433 A KR960004433 A KR 960004433A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/005—Modified block copolymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
(a) 결정성 폴리프로필렌, (b) 특정의 수첨 블록 공중합체, (c) 상기 (b)와는 다른 특정의 수첨 블록 공중합체, (d) 특정의 탈크로 이루어진 자동차 내장용 폴리프로필렌 수지 조성물.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (6)
- (a) 용융 유동 속도(230℃, 2160g)가 7 내지 70g/10분인 결정성 폴리프로필렌 60 내지 89중량%, (b) 일반식, A-(B-A)n 및/또는 A-B(여기서, A는 모노비닐 치환 방향족 탄화수소의 중합 블록, B는 공액 디엔에라스토머성 중합 블록이고, n은 1 내지 5의 정수임)로 나타낸 블록 공중합체의 A부가 22 중량% 이하이며, 용융 유동 속도(200℃, 5kg)가 5g/10분 이상인 블록 공중합체를 90 몰% 이상 수소 첨가한 수첨 블록 공중합체 2 내지 16 중량%, (c) 일반식, A-(B-A)n 및/또는 A-B(여기서, A모노비닐 치환 방향족 탄화수소의 중합블록, B는 공액 디엔 에라스토머성 중합 블록이고, n은 1 내지 5의 정수임)로 나타낸 블록 공중합체의 A부가 27 중량% 이상이며 용융 유동 속도(200℃, 5kg)가 2g/10분 이하인 블록 공중합체를 90 몰% 이상 수소 첨가한 수첨 블록 공중합체 2 내지 16 중량%, (d) 레이저 회절법으로 측정한 평균 입자 직경이 3 내지 5㎛인 탈크 7 내지 25 중량%로 이루어진 자동차 내장용 폴리프로필렌 수지 조성물.
- 제1항에 있어서, 결정성 폴리프로필렌 (a)는 에틸렌 함유량 0.5 내지 8 중량%, 폴리프로필렌 성분의 비등 n-헵탄 불용분 95 중량% 이상, 비등 n-헵탄 불용분의 아이소타틱 펜타도 분율이 0.970 이상인 결정성 에틸렌-프로필렌 블록 공중합체인 조성물.
- 제2항에 있어서, 결정성 에틸렌-프로필렌 블록 공중합체의 상온 p-크실렌 가용분이 4 내지 20 중량%, 상온 p-크실렌 가용분의 에텔렌 함유량이 20 내지 45 중량%, 극한 점도(135℃, 데칼린에서)가 4dl/g 이상인 조성물.
- 제1항에 있어서, 수첨 블록 공중합체 (b) 및 수첨 블록 공중합체 (c)의 비율(중량비)은 (b)/(c)=0.25 내지 4.0인 조성물.
- 제1항에 있어서, 탈크(d)의 BET 비표면적이 5 내지 13㎡/g, 톱-캇 직경이 20㎛ 미만인 조성물.
- 제1항에 있어서, 수첨 블록 공중합체 ((b)+(c))=100 중량부에 대해, (e) 에틸렌 함유량 60 내지 80 중량%, 무니 점도 ML 1+4(100℃) 10 내지 70의 에틸렌-프로필렌 공중합체 고무 및/또는 (f) 에틸렌 함유량 60 내지 80 중량%의 에틸렌-프로필렌-디엔 공중합체 고무 및/또는 (g) 부텐 함유량 10 내지 25 중량%, 무니 점도 ML1+4(11℃) 5 내지 20의 에틸렌-부텐 공중합체 고무 0 내지 200 중량부를 추가로 함유하는 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP94-156161 | 1994-07-07 | ||
JP15616194A JP3213481B2 (ja) | 1994-07-07 | 1994-07-07 | 自動車内装用ポリプロピレン樹脂組成物 |
Publications (2)
Publication Number | Publication Date |
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KR960004433A true KR960004433A (ko) | 1996-02-23 |
KR0175705B1 KR0175705B1 (ko) | 1999-05-15 |
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Application Number | Title | Priority Date | Filing Date |
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KR1019950019904A KR0175705B1 (ko) | 1994-07-07 | 1995-07-07 | 자동차 내장용 폴리프로필렌 수지 조성물 |
Country Status (7)
Country | Link |
---|---|
US (1) | US5750612A (ko) |
EP (1) | EP0697435B1 (ko) |
JP (1) | JP3213481B2 (ko) |
KR (1) | KR0175705B1 (ko) |
AU (1) | AU697439B2 (ko) |
CA (1) | CA2153093A1 (ko) |
DE (1) | DE69501136T2 (ko) |
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JP2843120B2 (ja) | 1990-06-27 | 1999-01-06 | 日産自動車株式会社 | 自動車バンパー用樹脂組成物 |
US5256734A (en) * | 1991-02-15 | 1993-10-26 | Mitsui Toatsu Chemicals, Inc. | Polypropylene resin composition and method for manufacturing coated molded article of the resin composition |
JP2902496B2 (ja) * | 1991-03-28 | 1999-06-07 | 宇部興産株式会社 | 自動車バンパー用樹脂組成物 |
JP3160059B2 (ja) * | 1992-04-16 | 2001-04-23 | 三菱化学株式会社 | プロピレン系樹脂組成物 |
-
1994
- 1994-07-07 JP JP15616194A patent/JP3213481B2/ja not_active Expired - Fee Related
-
1995
- 1995-06-30 CA CA002153093A patent/CA2153093A1/en not_active Abandoned
- 1995-07-06 EP EP95110577A patent/EP0697435B1/en not_active Expired - Lifetime
- 1995-07-06 AU AU24861/95A patent/AU697439B2/en not_active Ceased
- 1995-07-06 DE DE69501136T patent/DE69501136T2/de not_active Expired - Fee Related
- 1995-07-07 KR KR1019950019904A patent/KR0175705B1/ko not_active IP Right Cessation
-
1997
- 1997-02-18 US US08/801,416 patent/US5750612A/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20210128146A (ko) * | 2020-04-16 | 2021-10-26 | 김재곤 | 동 합금판 및 그의 제조방법 |
Also Published As
Publication number | Publication date |
---|---|
EP0697435A1 (en) | 1996-02-21 |
CA2153093A1 (en) | 1996-01-08 |
KR0175705B1 (ko) | 1999-05-15 |
DE69501136D1 (de) | 1998-01-15 |
AU2486195A (en) | 1996-01-18 |
US5750612A (en) | 1998-05-12 |
JP3213481B2 (ja) | 2001-10-02 |
AU697439B2 (en) | 1998-10-08 |
JPH0820684A (ja) | 1996-01-23 |
DE69501136T2 (de) | 1998-03-26 |
EP0697435B1 (en) | 1997-12-03 |
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