KR950025050A - 폴리우레탄 제조용 히드록시 및 아미노 작용성 피롤리지딘 촉매 조성물 - Google Patents
폴리우레탄 제조용 히드록시 및 아미노 작용성 피롤리지딘 촉매 조성물 Download PDFInfo
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- KR950025050A KR950025050A KR1019950003206A KR19950003206A KR950025050A KR 950025050 A KR950025050 A KR 950025050A KR 1019950003206 A KR1019950003206 A KR 1019950003206A KR 19950003206 A KR19950003206 A KR 19950003206A KR 950025050 A KR950025050 A KR 950025050A
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- cycloalkyl
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1825—Catalysts containing secondary or tertiary amines or salts thereof having hydroxy or primary amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/20—Heterocyclic amines; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/20—Heterocyclic amines; Salts thereof
- C08G18/2045—Heterocyclic amines; Salts thereof containing condensed heterocyclic rings
- C08G18/2054—Heterocyclic amines; Salts thereof containing condensed heterocyclic rings having one nitrogen atom in the condensed ring system
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2101/00—Manufacture of cellular products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2115/00—Oligomerisation
- C08G2115/02—Oligomerisation to isocyanurate groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S521/902—Cellular polymer containing an isocyanurate structure
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
본 발명은 발포제, 기포 안정화제 및 하기 일반식의 피롤리지딘 화합물을 주성분으로 하는 촉매 조성물의 존재하에서, 유기 폴리이소시아네이트와 폴리올을 반응시키는 방법을 포함하는 폴리우레탄 포옴 제조 방법에 관한 것이다 :
상기식에서, R1및 R2는 각각또는 -NR4R5이고, R3은 수소, C1-C12알킬, C5-C6시클로알킬, C6-C10아릴, 또는 C7-C11아릴알킬기이고 : 및 R4및 R5각각은 H, C1-C12알킬기, C5-C10시클로알킬, C6-C10아릴, C7-C11아릴알킬기를 나타내고, 단 R1및 R2중 하나 이상은 수소가 아님을 조건으로 한다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (17)
- 폴리 이소시아네이트의 그 자체 또는 활성 수소-함유 화합물의 반응을 촉매화 하는 반응에 있어서, 촉매적 유효량의 하기 일반식 화합물을 사용하는 것을 특징으로 하는 방법.상기식에서, R1및 R2는 각각또는 -NR4R5이고, R3은 수소, C1-C12알킬, C5-C6시클로알킬, C6-C10아릴, 또는 C7-C11아릴알킬기이고 : 및 R4및 R5각각은 H, C1-C12알킬기, C5-C10시클로알킬, C6-C10아릴, C7-C11아릴알킬기를 나타내고, 단 R1및 R2중 하나 이상은 수소가 아님을 조건으로 한다.
- 제1항에 있어서, R1및 R2중 하나는 -H이고, 나머지 하나는 -OH인 방법.
- 제1항에 있어서, R1및 R2중 하나는 -H이고, 나머지 하나는 -CH2OH인 방법.
- 제1항에 있어서, R1및 R2중 하나는 -H이고, 나머지 하나는 -NH2인 방법.
- 제1항에 있어서, R1및 R2중 하나는 -H이고, 나머지 하나는 -CH2NH2인 방법.
- 제1항에 있어서, R1및 R2중 하나는 -H이고, 나머지 하나는 -CH2NR4R5이고, R4및 R5는 각각 H 및 C1-C4알킬기를 나타내는 방법.
- 발포제, 기포 안정화제 및 촉매 조성물의 존재하에서 유기 폴리 이소시아네이트와 폴리올의 반응을 포함하는 폴리우레탄 포옴 제조 방법에 있어서, 하기 일반식의 화합물을 주성분으로 하는 촉매 조성물을 사용하는 것을 특징으로 하는 방법 :상기식에서, R1및 R2는 각각또는 -NR4R5이고, R3은 수소, C1-C12알킬, C5-C6시클로알킬, C6-C10아릴, 또는 C7-C11아릴알킬기이고 : 및 R4및 R5각각은 H, C1-C12알킬기, C5-C10시클로알킬, C6-C10아릴, C7-C11아릴알킬기를 나타내고, 단 R1및 R2중 하나 이상은 수소가 아님을 조건으로 한다.
- 제7항에 있어서, 화합물이 3-또는 4-히드록시메틸피롤리지딘 또는 이의 혼합물인 방법.
- 제7항에 있어서, 화합물이 3- 또는 4-(N-이소프로필)아미노메틸피롤리지딘 또는 이의 혼합물인 방법.
- 제7항에 있어서, 화합물이 4-히드록시메틸피롤리지딘인 방법.
- 제7항에 있어서, 화합물이 4-히드록시피롤리지딘인 방법.
- 제7항에 있어서 화합물이 3- 또는 4-아미노메틸피롤리지딘 또는 이의 혼합물인 방법.
- 하기 일반식으로 나타낸 화합물을 포함하는 촉매 조성물 :상기식에서, R1및 R2는 각각또는 -NR4R5이고, R3은 수소, C1-C12알킬, C5-C6시클로알킬, C6-C10아릴, 또는 C7-C11아릴알킬기이고 : 및 R4및 R5각각은 H, C1-C12알킬기, C5-C10시클로알킬, C6-C10아릴, C7-C11아릴알킬기를 나타내고, 단 R1및 R2중 하나 이상은 수소가 아님을 조건으로 한다.
- 제13항에 있어서, 화합물이 3- 또는 4-히드록시메틸피롤리지딘 또는 이의 혼합물인 조성물.
- 제13항에 있어서, 화합물이 3- 또는 4-(N-이소프로필)아미노메틸피롤리지딘 또는 이의 혼합물인 조성물.
- 제14항에 있어서, 화합물이 4-히드록시메틸피롤리지딘인 조성물.
- 제14항에 있어서, 혼합물이 4-히드록시피롤리지딘인 조성물※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US8/199,396 | 1994-02-22 | ||
US08/199,396 US5512603A (en) | 1994-02-22 | 1994-02-22 | Hydroxy and amino functional pyrrolizidine catalyst compositions for the production of polyurethanes |
US08/199,396 | 1994-02-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR950025050A true KR950025050A (ko) | 1995-09-15 |
KR0150871B1 KR0150871B1 (ko) | 1998-10-15 |
Family
ID=22737331
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019950003206A KR0150871B1 (ko) | 1994-02-22 | 1995-02-20 | 폴리우레탄 제조용 히드록시 및 아미노 작용성 피롤리지딘 촉매 조성물 |
Country Status (8)
Country | Link |
---|---|
US (1) | US5512603A (ko) |
EP (1) | EP0668303B1 (ko) |
JP (1) | JP2974273B2 (ko) |
KR (1) | KR0150871B1 (ko) |
CN (1) | CN1048736C (ko) |
BR (1) | BR9500675A (ko) |
CA (1) | CA2142584A1 (ko) |
DE (1) | DE69518448T2 (ko) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6534555B1 (en) | 2001-09-10 | 2003-03-18 | Huntsman Petrochemical Corporation | Catalyst systems for polyurethane polyester foams |
US20050059749A1 (en) * | 2003-09-16 | 2005-03-17 | Huntsman Petrochemical Corporation | Catalysts useful in polyurethane foam |
US8258198B2 (en) | 2004-05-28 | 2012-09-04 | Air Products And Chemicals, Inc. | Fast demold/extended cream time polyurethane formulations |
US20050267227A1 (en) * | 2004-05-28 | 2005-12-01 | Andrew Gary D | Fast demold/extended cream time polyurethane formulations |
US10023683B2 (en) * | 2006-06-12 | 2018-07-17 | Evonik Degussa Gmbh | Catalyst compositions for improving polyurethane foam performance |
US20080269365A1 (en) | 2007-04-25 | 2008-10-30 | Gary Dale Andrew | Additives for Improving Surface Cure and Dimensional Stability of Polyurethane Foams |
US8637584B2 (en) | 2007-05-25 | 2014-01-28 | Air Products And Chemicals, Inc. | Polyester polyol-containing polyurethane systems having improved hydrolytic stability |
CN102786562B (zh) * | 2012-08-16 | 2014-10-08 | 西南交通大学 | 一种吡咯里西啶生物碱及其用途 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2058365B1 (ko) * | 1969-08-18 | 1973-01-12 | Nat Chemical Corp | |
DE2403858A1 (de) * | 1974-01-28 | 1975-08-21 | Basf Ag | Stabile, fluessige amid- und/oder acylharnstoffgruppenhaltige isocyanurat-polyisocyanatloesungen |
US4066580A (en) * | 1976-06-07 | 1978-01-03 | Basf Wyandotte Corporation | Process for the manufacture of polyisocyanurate foams |
GB1584153A (en) * | 1976-09-22 | 1981-02-04 | Ici Ltd | Carbodimides |
DE2943550A1 (de) * | 1979-10-27 | 1981-05-14 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von urethanen und ihre verwendung als ausgangsmaterial zur herstellung von isocyanaten |
DE2943551A1 (de) * | 1979-10-27 | 1981-05-07 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von n,o-disubstituierten urethanen, sowie ihre verwendung zur herstellung von isocyanaten |
DE2943480A1 (de) * | 1979-10-27 | 1981-05-07 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von n,o-disubstituierten urethanen, sowie ihre verwendung als ausgangsmaterial zur herstellung von isocyanaten |
DE3110573A1 (de) * | 1981-03-18 | 1982-10-21 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von n- und o-substituierten di- und/oder polyurethanen |
US4957944A (en) * | 1989-06-16 | 1990-09-18 | Union Carbide Chemicals And Plastics Company Inc. | Urethane catalysts |
US5091583A (en) * | 1990-05-07 | 1992-02-25 | Air Products And Chemicals, Inc. | Tertiary amine catalysts for polurethanes |
US5071809A (en) * | 1990-05-07 | 1991-12-10 | Air Products And Chemicals, Inc. | Tertiary amine catalysts for polyurethanes |
DE4104870A1 (de) * | 1991-02-17 | 1992-08-27 | Bayer Ag | Verwendung von 3,(4)-substituierten pyrrolidinen als katalysatoren fuer das polyisocyanatpolyadditionsverfahren, verfahren zu ihrer herstellung sowie verfahren zur herstellung von polyurethan(harnstoff)en |
US5143944A (en) * | 1992-01-30 | 1992-09-01 | Air Products And Chemicals, Inc. | 3-quinuclidinol catalyst compositions for making polyurethane foams |
-
1994
- 1994-02-22 US US08/199,396 patent/US5512603A/en not_active Expired - Fee Related
-
1995
- 1995-02-15 CA CA002142584A patent/CA2142584A1/en not_active Abandoned
- 1995-02-17 BR BR9500675A patent/BR9500675A/pt not_active IP Right Cessation
- 1995-02-20 DE DE69518448T patent/DE69518448T2/de not_active Expired - Fee Related
- 1995-02-20 KR KR1019950003206A patent/KR0150871B1/ko not_active IP Right Cessation
- 1995-02-20 EP EP95102351A patent/EP0668303B1/en not_active Expired - Lifetime
- 1995-02-21 JP JP7031961A patent/JP2974273B2/ja not_active Expired - Fee Related
- 1995-02-21 CN CN95102159A patent/CN1048736C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE69518448D1 (de) | 2000-09-28 |
CN1048736C (zh) | 2000-01-26 |
JPH07258365A (ja) | 1995-10-09 |
EP0668303A1 (en) | 1995-08-23 |
BR9500675A (pt) | 1995-10-31 |
EP0668303B1 (en) | 2000-08-23 |
KR0150871B1 (ko) | 1998-10-15 |
CN1119194A (zh) | 1996-03-27 |
DE69518448T2 (de) | 2001-01-04 |
JP2974273B2 (ja) | 1999-11-10 |
CA2142584A1 (en) | 1995-08-23 |
US5512603A (en) | 1996-04-30 |
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