CA2087384A1 - Reduction de la teneur en benzene dans les essences - Google Patents

Reduction de la teneur en benzene dans les essences

Info

Publication number: CA2087384A1
Authority: CA; Canada
Prior art keywords: isomerization; catalyst; cut; paraffins; charge
Prior art date: 1992-01-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA002087384A

Other languages

English (en)

French (fr)

Inventor

Christine Travers

Patrick Sarrazin

Jean-Marie Deves

Christian Marcilly

Philippe Travers

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

IFP Energies Nouvelles IFPEN

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-01-15

Filing date

1993-01-15

Publication date

1993-07-16

1993-01-15 Application filed by Individual filed Critical Individual

1993-07-16 Publication of CA2087384A1 publication Critical patent/CA2087384A1/fr

Status Abandoned legal-status Critical Current

Links

UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title claims abstract description 60
230000009467 reduction Effects 0.000 title abstract description 6
239000007789 gas Substances 0.000 title 1
238000006317 isomerization reaction Methods 0.000 claims abstract description 32
238000000034 method Methods 0.000 claims abstract description 20
239000003054 catalyst Substances 0.000 claims abstract description 15
238000004821 distillation Methods 0.000 claims abstract description 14
239000000203 mixture Substances 0.000 claims abstract description 13
230000008569 process Effects 0.000 claims abstract description 13
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 11
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
229910052680 mordenite Inorganic materials 0.000 claims description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
239000001257 hydrogen Substances 0.000 claims description 5
229910052739 hydrogen Inorganic materials 0.000 claims description 5
229910052697 platinum Inorganic materials 0.000 claims description 5
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
229910052751 metal Inorganic materials 0.000 claims description 4
239000002184 metal Substances 0.000 claims description 4
229910052759 nickel Inorganic materials 0.000 claims description 3
229910052763 palladium Inorganic materials 0.000 claims description 2
239000000945 filler Substances 0.000 abstract 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 15
229930195733 hydrocarbon Natural products 0.000 description 6
150000002430 hydrocarbons Chemical class 0.000 description 6
239000010457 zeolite Substances 0.000 description 5
229910021536 Zeolite Inorganic materials 0.000 description 4
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
239000000686 essence Substances 0.000 description 4
238000001833 catalytic reforming Methods 0.000 description 3
230000006641 stabilisation Effects 0.000 description 3
238000011105 stabilization Methods 0.000 description 3
239000004215 Carbon black (E152) Substances 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
239000005995 Aluminium silicate Substances 0.000 description 1
208000007514 Herpes zoster Diseases 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
241001474977 Palla Species 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
238000005341 cation exchange Methods 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
238000005984 hydrogenation reaction Methods 0.000 description 1
230000006872 improvement Effects 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
238000005453 pelletization Methods 0.000 description 1
230000008707 rearrangement Effects 0.000 description 1
238000002407 reforming Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical class C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Crystallography & Structural Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

CA002087384A 1992-01-15 1993-01-15 Reduction de la teneur en benzene dans les essences Abandoned CA2087384A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR9200436A FR2686095B1 (fr)	1992-01-15	1992-01-15	Production de base pour carburant exempt de benzene, presentant un indice d'octane eleve.
FR92/00.436		1992-01-15

Publications (1)

Publication Number	Publication Date
CA2087384A1 true CA2087384A1 (fr)	1993-07-16

Family

ID=9425704

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002087384A Abandoned CA2087384A1 (fr)	1992-01-15	1993-01-15	Reduction de la teneur en benzene dans les essences

Country Status (9)

Country	Link
EP (1)	EP0552069B1 (ko)
KR (1)	KR930016525A (ko)
CA (1)	CA2087384A1 (ko)
DE (1)	DE69302287T2 (ko)
ES (1)	ES2089739T3 (ko)
FR (1)	FR2686095B1 (ko)
MY (1)	MY109121A (ko)
RU (1)	RU2091441C1 (ko)
TW (1)	TW238298B (ko)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2714305B1 (fr) *	1993-12-29	1996-02-02	Inst Francais Du Petrole	Catalyseur pour la réduction de la teneur en benzène dans les essences.
FR2743079B1 (fr) *	1995-12-27	1998-02-06	Inst Francais Du Petrole	Procede et dispositif d'hydrogenation selective par distillation catalytique comportant une zone reactionnelle a co-courant ascendant liquide-gaz
FR2743080B1 (fr) *	1995-12-27	1998-02-06	Inst Francais Du Petrole	Procede de reduction selective de la teneur en benzene et en composes insatures legers d'une coupe d'hydrocarbures
US5830345A (en) *	1996-02-28	1998-11-03	Chinese Petroleum Corporation	Process of producing a debenzenated and isomerized gasoline blending stock by using a dual functional catalyst
FR2948380B1 (fr) *	2009-07-21	2011-08-12	Inst Francais Du Petrole	Procede de reduction selective de la teneur en benzene et en composes insatures legers de differentes coupes hydrocarbures
EP2277980B1 (fr) *	2009-07-21	2018-08-08	IFP Energies nouvelles	Procédé de réduction sélective de la teneur en benzène et en composés insatures legers de differentes coupes hydrocarbures
US8808533B2 (en) *	2010-04-23	2014-08-19	IFP Energies Nouvelles	Process for selective reduction of the contents of benzene and light unsaturated compounds of different hydrocarbon fractions
CN103464210B (zh) *	2013-09-27	2015-07-22	凯瑞环保科技股份有限公司	一种轻烃异构化催化剂及其制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA975384A (en) *	1971-04-19	1975-09-30	Graham K. Hilder	Isomerisation of paraffin hydrocarbons
US4457832A (en) *	1983-01-19	1984-07-03	Chevron Research Company	Combination catalytic reforming-isomerization process for upgrading naphtha
FR2579906B1 (ko) *	1985-04-05	1987-05-15	Inst Francais Du Petrole
US5003118A (en) *	1989-12-29	1991-03-26	Uop	Isomerization of benzene-containing feedstocks

1992
- 1992-01-15 FR FR9200436A patent/FR2686095B1/fr not_active Expired - Fee Related
1993
- 1993-01-07 DE DE69302287T patent/DE69302287T2/de not_active Expired - Fee Related
- 1993-01-07 EP EP93400020A patent/EP0552069B1/fr not_active Expired - Lifetime
- 1993-01-07 ES ES93400020T patent/ES2089739T3/es not_active Expired - Lifetime
- 1993-01-14 MY MYPI93000060A patent/MY109121A/en unknown
- 1993-01-14 RU RU9393004431A patent/RU2091441C1/ru active
- 1993-01-14 KR KR1019930000407A patent/KR930016525A/ko active IP Right Grant
- 1993-01-15 CA CA002087384A patent/CA2087384A1/fr not_active Abandoned
- 1993-01-18 TW TW082100291A patent/TW238298B/zh active

Also Published As

Publication number	Publication date
FR2686095B1 (fr)	1994-04-29
RU2091441C1 (ru)	1997-09-27
ES2089739T3 (es)	1996-10-01
DE69302287T2 (de)	1996-09-12
MY109121A (en)	1996-12-31
FR2686095A1 (fr)	1993-07-16
EP0552069B1 (fr)	1996-04-24
DE69302287D1 (de)	1996-05-30
KR930016525A (ko)	1993-08-26
EP0552069A1 (fr)	1993-07-21
TW238298B (ko)	1995-01-11

Legal Events

Date	Code	Title	Description
1999-12-01	EEER	Examination request
2001-01-15	FZDE	Discontinued

Publication	Publication Date	Title
EP1640436B1 (fr)	2007-09-26	Procédé d'isomérisation d'une coupe C7 avec coproduction d'une coupe cycliques riche en méthylcyclohexane
EP0242260B1 (fr)	1989-03-29	Procédé de réformage catalytique
WO1997009397A1 (fr)	1997-03-13	Procede d'hydroisomerisation selective de paraffines longues lineaires et/ou peu ramifiees avec un catalyseur a base de tamis moleculaire
FR2611739A1 (fr)	1988-09-09	Procede d'activation d'un catalyseur d'isomerisation de paraffines normales
EP0863198B1 (fr)	2004-08-04	Catalyseur à base de tamis moléculaire et procédé d'hydroisomérisation sélective de paraffines longues linéaires et/ou peu ramifiées avec ce catalyseur
FR2757533A1 (fr)	1998-06-26	Procede de preparation d'une matiere premiere de melange pour essence exempte de benzene et isomerisee utlisant un catalyseur a double fonction
EP0552070B1 (fr)	1999-08-18	Réduction de la teneur en benzène dans les essences
EP0661095B1 (fr)	1999-06-23	Catalyseur pour la réduction de la teneur en benzène dans les essences
EP0661370B1 (fr)	2000-04-19	Catalyseur pour la réduction de la teneur en benzène dans les essences
EP0552069B1 (fr)	1996-04-24	Réduction de la teneur en benzène dans les essences par un procédé d'isomérisation
FR2548204A1 (fr)	1985-01-04	Procede de transformation d'hydrocarbures
EP0610168B1 (fr)	1999-04-07	Procédé de production d'essences à haut indice d'octane
CA1334980C (fr)	1995-03-28	Procede d'isomerisation du butene-1 en butenes-2 dans une coupe d'hydrocarbures en c _ contenant du butadiene et des composes sulfures
EP0552072B1 (fr)	1998-10-28	Réduction de la teneur en benzène dans les essences
FR2828205A1 (fr)	2003-02-07	Procede d'isomerisation d'une coupe c5-c8 mettant en oeuvre deux reacteurs en parallele
FR2694565A1 (fr)	1994-02-11	Réduction de la teneur en benzène dans les essences.
FR2686094A1 (fr)	1993-07-16	Production de base pour carburant exempt de benzene, presentant un indice d'octane eleve.
FR2568581A1 (fr)	1986-02-07	Procede de reformage catalytique en presence de silicalite
FR2695648A1 (fr)	1994-03-18	Utilisation d'un catalyseur pour la diminution de la teneur en benzène d'une charge hydrocarbonée.
FR2857371A1 (fr)	2005-01-14	Procede ameliore d'isomerisation d'une coupe c7 avec ouverture des cycles naphteniques
FR2738243A1 (fr)	1997-03-07	Procede d'hydroisomerisation de paraffines longues lineaires et/ou peu ramifiees avec un catalyseur a base de zeolithe nu-10
EP0922747B1 (fr)	2003-10-29	Procédé d'isomérisation des coupes paraffiniques C5-C8 riches en paraffines à plus de sept atomes de carbone
FR2597496A1 (fr)	1987-10-23	Procede de reformage catalytique
FR2738244A1 (fr)	1997-03-07	Procede d'hydroisomerisation selective de paraffines longues lineaires et/ou peu ramifiees avec un catalyseur a base de tamis moleculaire