KR930000155A - 붕소함유촉매 및 그 제조방법 - Google Patents

붕소함유촉매 및 그 제조방법 Download PDF

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Publication number
KR930000155A
KR930000155A KR1019920009241A KR920009241A KR930000155A KR 930000155 A KR930000155 A KR 930000155A KR 1019920009241 A KR1019920009241 A KR 1019920009241A KR 920009241 A KR920009241 A KR 920009241A KR 930000155 A KR930000155 A KR 930000155A
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South Korea
Prior art keywords
catalyst
boron
alumina
silica
catalyst according
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KR1019920009241A
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KR100213406B1 (ko
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얀 나트 피터
루시우스 데 부이즈 자콥
빌헤르무스 프레드릭 마리아 스쿤호벤 요하네스
Original Assignee
피터 코르넬리스 샬크비즈크; 권터 페트
아크조 엔. 브이.
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Publication of KR930000155A publication Critical patent/KR930000155A/ko
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

내용 없음

Description

붕소함유촉매 및 그 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 알루미나와 실리카알루미나, VlB족금속성분. VII족금속성분으로 구싱된 수용체 금속을 함유하는 촉매조성에 있어서, 촉매적으로 활성인양의 붕소를 함유하는 것을 특징으로 하는 촉매.
  2. 제1항에 있어서, 붕소의 함량이 1∼20wt%인 것을 특징으로 하는 촉매.
  3. 제1항 또는 제2항에 있어서, 수용체물질이60~90wt%의 실리카를 함유하는 비정질 실리카-알루미나와 알루미나로 구성되는 것을 특징으로 하는 촉매.
  4. 제2항 또는 제3항에 있어서, 금속산화물로 계산한 몰리브덴이 5~20wt%, 니켈 및 코발트중 하나 이상이 2~6wt%, 실리카1O~40wt%를 함유하고, 나머지는 알루미나로 구성되는 것을 특징으로 하는 촉매.
  5. 제1항 내기 제4항중 어느 한항에 있어서, 촉매의 활성표면적은 150∼350㎡/g이고, 평균 포어직경은 50~150A인 것을 특징으로 하는 촉매.
  6. 제1항 내지 제5항중 어느 한항에 따른 촉매를 제조하는 방법에 있어서, 혼합, 성형, 하소단계로 이루어지며, VII족 금속성분보다 먼저 촉매적으로 활성인 양의 붕소가 첨가되고, 붕소첨가와 VII족 금속성분 첨가사이에 적어도 한번의 하소단계를 실시하는 것을 특징으로 하는 촉매의 제조방법.
  7. 제1항 내지 제5항중 어느 한항에 따른 촉매를 진공가스오일 공급재료에서 중간유출물로 변환시키는데 사용하는 촉매의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920009241A 1991-06-03 1992-05-29 보륨 함유 촉매 및 그 제조방법 KR100213406B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL9100950 1991-06-03
NL9100950 1991-06-03

Publications (2)

Publication Number Publication Date
KR930000155A true KR930000155A (ko) 1993-01-15
KR100213406B1 KR100213406B1 (ko) 1999-08-02

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Country Status (7)

Country Link
US (1) US5609750A (ko)
EP (1) EP0517300B1 (ko)
JP (1) JP3326198B2 (ko)
KR (1) KR100213406B1 (ko)
CA (1) CA2070249C (ko)
DK (1) DK0517300T3 (ko)
TW (1) TW233307B (ko)

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US5851378A (en) * 1994-06-03 1998-12-22 Akzo Nobel Nv Hydrocracking catalyst comprising coated cracking component particles
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FR2778583B1 (fr) * 1998-05-13 2000-06-16 Inst Francais Du Petrole Catalyseur comprenant un phyllosilicate contenant du bore et/ou du silicium et procede d'hydrocraquage
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Publication number Publication date
DK0517300T3 (da) 1995-10-16
EP0517300B1 (en) 1995-06-21
KR100213406B1 (ko) 1999-08-02
JPH05192573A (ja) 1993-08-03
CA2070249A1 (en) 1992-12-04
CA2070249C (en) 2003-01-14
EP0517300A1 (en) 1992-12-09
US5609750A (en) 1997-03-11
JP3326198B2 (ja) 2002-09-17
TW233307B (ko) 1994-11-01

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