KR960007003A - 탄화수소 전환 촉매 - Google Patents

탄화수소 전환 촉매 Download PDF

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Publication number
KR960007003A
KR960007003A KR1019950026548A KR19950026548A KR960007003A KR 960007003 A KR960007003 A KR 960007003A KR 1019950026548 A KR1019950026548 A KR 1019950026548A KR 19950026548 A KR19950026548 A KR 19950026548A KR 960007003 A KR960007003 A KR 960007003A
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KR
South Korea
Prior art keywords
catalyst
vusy
aluminum
ultrastable zeolite
range
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Application number
KR1019950026548A
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English (en)
Inventor
헨드릭 클라징가 앤
루도비쿠스 마이클 마이슨 디오도루스
안토니우스 로버트 반 벤 요하네스
마리아 반 벡첼 잉그리드
Original Assignee
알베르루스 빌헬무스·요아네스 쩨스트라텐
셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
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Application filed by 알베르루스 빌헬무스·요아네스 쩨스트라텐, 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 filed Critical 알베르루스 빌헬무스·요아네스 쩨스트라텐
Publication of KR960007003A publication Critical patent/KR960007003A/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

본 발명은 존재하는 알루미늄(Al) 총량의 15%미만이 팔면체형 상호-지향된 매우 초안정한 제올라이트 Y(VUSY)를 포함하는 촉매;상기 제올라이트를 제조하는 방법;및 상기 촉매를 사용하는 탄화수소 전환 방법을 제공한다.

Description

탄화수소 전환 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 존재하는 알루미늄(Al) 총량의 15%미만이 팔면체형 상호-지향된 매우 초안정한 제올라이트 Y (VUSY)를 포함하는 탄화수소 전환 방법에 사용하기 위한 촉매.
  2. 제1항에 있어서, 존재하는 알루미늄(Al) 총량의 10%이하가 팔면체형 상호-지향된 촉매.
  3. 제1 또는 제2항에 잇어서, 매우 초안정한 제올라이트 Y (VUSY)가 2.425-2.435nm(24.25-24.35A) 범위내 단위 셀 크기를 갖는 촉매.
  4. 제1-3항 중 임의의 한 항에 있어서, 매우 초안정한 제올라이트 Y (VUSY)가 3-80 범위내 SiO2/Al2O3몰비를 갖는 촉매.
  5. 제1-4항 중 임의의 한 항에 있어서, 결합제를 부가로 포함하는 촉매.
  6. 제1-5항 중 임의의 한 항에 있어서, 하나 이상의 수소첨가 성분을 부가로 포함하는 촉매.
  7. 제6항에 있어서, 하나 이상의 수소 첨가 성분을 6B족 및 8족 금속, 그의 산화물 및 황화물로부터 선택하는 촉매.
  8. 매우 초안정한 제올라이트 Y (VUSY)를 pH 5미만인 알루미늄, 갈륨 및 철 황산염으로부터 선택된 하나이상의 금속 황산염 용액과 접촉시키는 것을 포함하는 매우 초안정한 제올라이트 Y (VUSY)내 존재하는 팔면체형 상호-지향된 알루미늄(Al)의 양을 감소시키는 방법.
  9. 탄화수소 공급 원료를 승온에서 제1-7항 중 임의의 한 항에 청구된 촉매와 접촉시키는 것으로 구성되는 탄화수소 공급원료를 낮은 끓는점을 갖는 물질로 전환시키는 방법.
  10. 제9항에 있어서, 공급원료를 수소첨가 조건하에서 제6 또는 제7항에 청구된 촉매와 접촉시키는 방법.
  11. 제10항에 있어서, 250-500℃ 범위내 온도에서 5×106-3×107Pa 범위내 전체 압력에서 수행되는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950026548A 1994-08-24 1995-08-22 탄화수소 전환 촉매 KR960007003A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP94202422.5 1994-08-24
EP94202422 1994-08-24

Publications (1)

Publication Number Publication Date
KR960007003A true KR960007003A (ko) 1996-03-22

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019950026548A KR960007003A (ko) 1994-08-24 1995-08-22 탄화수소 전환 촉매

Country Status (11)

Country Link
US (1) US5954946A (ko)
EP (1) EP0703003B1 (ko)
JP (1) JPH0866634A (ko)
KR (1) KR960007003A (ko)
CN (1) CN1119668A (ko)
AU (1) AU697549B2 (ko)
CA (1) CA2156681A1 (ko)
DE (1) DE69514599T2 (ko)
ES (1) ES2142448T3 (ko)
SG (1) SG34257A1 (ko)
TW (1) TW358120B (ko)

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EP1779929A1 (en) 2005-10-27 2007-05-02 Süd-Chemie Ag A catalyst composition for hydrocracking and process of mild hydrocracking and ring opening
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US20070199710A1 (en) * 2006-02-27 2007-08-30 Grant Hocking Enhanced hydrocarbon recovery by convective heating of oil sand formations
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US7748458B2 (en) * 2006-02-27 2010-07-06 Geosierra Llc Initiation and propagation control of vertical hydraulic fractures in unconsolidated and weakly cemented sediments
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US7591306B2 (en) * 2006-02-27 2009-09-22 Geosierra Llc Enhanced hydrocarbon recovery by steam injection of oil sand formations
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US7604054B2 (en) * 2006-02-27 2009-10-20 Geosierra Llc Enhanced hydrocarbon recovery by convective heating of oil sand formations
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US20070199699A1 (en) * 2006-02-27 2007-08-30 Grant Hocking Enhanced Hydrocarbon Recovery By Vaporizing Solvents in Oil Sand Formations
FR2900157B1 (fr) * 2006-04-24 2010-09-24 Inst Francais Du Petrole Procede de desulfuration d'essences olefiniques comprenant au moins deux etapes distinctes d'hydrodesulfuration
US7647966B2 (en) * 2007-08-01 2010-01-19 Halliburton Energy Services, Inc. Method for drainage of heavy oil reservoir via horizontal wellbore
US7832477B2 (en) 2007-12-28 2010-11-16 Halliburton Energy Services, Inc. Casing deformation and control for inclusion propagation
FR2970259B1 (fr) 2011-01-07 2014-07-18 IFP Energies Nouvelles Procede d'hydrocraquage utilisant un catalyseur zeolithique contenant deux fonctions hydrogenantes distinctes.
US8955585B2 (en) 2011-09-27 2015-02-17 Halliburton Energy Services, Inc. Forming inclusions in selected azimuthal orientations from a casing section
CN106694025B (zh) * 2017-01-17 2020-04-17 中国石油大学(北京) 劣质柴油超深度加氢脱硫催化剂载体及其制备方法与应用
US20220008908A1 (en) * 2020-07-08 2022-01-13 Saudi Arabian Oil Company Methods of producing hydrocracking catalyst
US11274068B2 (en) 2020-07-23 2022-03-15 Saudi Arabian Oil Company Process for interconversion of olefins with modified beta zeolite
US11332678B2 (en) 2020-07-23 2022-05-17 Saudi Arabian Oil Company Processing of paraffinic naphtha with modified USY zeolite dehydrogenation catalyst
US11420192B2 (en) 2020-07-28 2022-08-23 Saudi Arabian Oil Company Hydrocracking catalysts containing rare earth containing post-modified USY zeolite, method for preparing hydrocracking catalysts, and methods for hydrocracking hydrocarbon oil with hydrocracking catalysts
US11154845B1 (en) 2020-07-28 2021-10-26 Saudi Arabian Oil Company Hydrocracking catalysts containing USY and beta zeolites for hydrocarbon oil and method for hydrocracking hydrocarbon oil with hydrocracking catalysts
US11142703B1 (en) 2020-08-05 2021-10-12 Saudi Arabian Oil Company Fluid catalytic cracking with catalyst system containing modified beta zeolite additive
US11618858B1 (en) 2021-12-06 2023-04-04 Saudi Arabian Oil Company Hydrodearylation catalysts for aromatic bottoms oil, method for producing hydrodearylation catalysts, and method for hydrodearylating aromatic bottoms oil with hydrodearylation catalysts

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Also Published As

Publication number Publication date
AU3018195A (en) 1996-03-07
SG34257A1 (en) 1996-12-06
ES2142448T3 (es) 2000-04-16
TW358120B (en) 1999-05-11
EP0703003B1 (en) 2000-01-19
DE69514599D1 (de) 2000-02-24
CN1119668A (zh) 1996-04-03
US5954946A (en) 1999-09-21
CA2156681A1 (en) 1996-02-25
AU697549B2 (en) 1998-10-08
EP0703003A1 (en) 1996-03-27
DE69514599T2 (de) 2000-07-06
JPH0866634A (ja) 1996-03-12

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