KR920012123A - 스티렌계 중합체의 제조방법 및 그 촉매 - Google Patents

스티렌계 중합체의 제조방법 및 그 촉매 Download PDF

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KR920012123A
KR920012123A KR1019910022421A KR910022421A KR920012123A KR 920012123 A KR920012123 A KR 920012123A KR 1019910022421 A KR1019910022421 A KR 1019910022421A KR 910022421 A KR910022421 A KR 910022421A KR 920012123 A KR920012123 A KR 920012123A
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catalyst
metal
compound
styrene polymer
transition metal
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KR0135271B1 (ko
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노리오 도모쓰
미즈도모 다케우찌
마사히코 구라모도
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이데미쓰 쇼소께
이데미쓰 고산 가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602—Component covered by group C08F4/60 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)

Abstract

내용 없음

Description

스티렌계 중합체의 제조방법 및 그 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. (A)금속-수소결합, 금속-탄소 α결합 및 금속-규소 α결합중 어느 것도 포함하지 않는 전이 금속 화합물, (B)양이온과 복수의 기가 금속에 결합한 음이온으로된 배위 착화합물 및 (C)알킬기 함유 화합물로 된 것을 특징으로 하는 촉매.
  2. 제1항에 있어서, (A) 성분에서의 전이 금속이 Ti, Zr 및 Hf으로부터 선택된 적어도 1종 이상인 것을 특징으로 하는 촉매.
  3. 제1항에 있어서, 전이 금속이 Ti인 것을 특징으로 하는 촉매.
  4. 제2항에 있어서, 전이 금속이 Ti인 것을 특징으로 하는 촉매.
  5. 제1항에 있어서, (C)성분에서의 알킬기 함유 화합물이 알킬기 함유 알루미늄 화합물인 것을 특징으로 하는 촉매.
  6. 제1항에 있어서, 촉매가 스티렌계 모노마의 중합용인 것을 특징으로 하는 촉매.
  7. (A) 금속-수소결합, 금속-탄소 α결합 및 금속-규소 α결합중 어느 것도 포함하지 않는 전이 금속 화합물, (B) 양이온과 복수의 기가 금속에 결합한 음이온으로된 배위 착화합물 및 (C) 알킬기 함유 화합물로 된 촉매의 존재하에서 스티렌계 모노마를 중합하는 것을 특징으로 하는 스티렌계 중합체의 제조방법.
  8. 제7항에 있어서, (A) 성분에서의 전이 금속이 Ti, Zr 및 Hf으로부터 선택된 적어도 1종 이상인 것을 특징으로 하는 스티렌계 중합체의 제조방법.
  9. 제7항에 있어서, 전이 금속이 Ti인 것을 특징으로 스티렌계 중합체의 제조방법.
  10. 제8항에 있어서, 전이 금속이 Ti인 것을 특징으로 하는 스티렌계 중합체의 제조방법.
  11. 제7항에 있어서, (C) 성분에서의 알킬기 함유 화합물이 알킬기 함유 알루미늄 화합물인 것을 특징으로 하는 스티렌계 중합체의 제조방법.
    ※ 참고사항: 최초출원 내용에 의하여 공개하는 것임.
KR1019910022421A 1990-12-28 1991-12-09 스티렌계 중합체의 제조방법 및 그 촉매 KR0135271B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP90-415574 1990-12-28
JP2415574A JP2888648B2 (ja) 1990-12-28 1990-12-28 スチレン系重合体の製造方法及びその触媒

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KR920012123A true KR920012123A (ko) 1992-07-25
KR0135271B1 KR0135271B1 (ko) 1998-04-23

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US (2) US5272229A (ko)
EP (1) EP0493678B1 (ko)
JP (1) JP2888648B2 (ko)
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AT (1) ATE155496T1 (ko)
DE (1) DE69126854T2 (ko)
TW (1) TW233302B (ko)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5763549A (en) * 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
US5387568A (en) * 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
JP3194438B2 (ja) * 1992-01-08 2001-07-30 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
US6147184A (en) * 1992-03-23 2000-11-14 Rhone-Poulenc Chimie Onium borates/borates of organometallic complexes and cationic initiation of polymerization therewith
JP3216662B2 (ja) * 1992-10-08 2001-10-09 出光興産株式会社 スチレン系重合体の製造方法
EP0698619B1 (en) * 1993-03-31 2001-11-07 Idemitsu Kosan Company Limited Catalyst for producing vinyl polymer and process for producing vinylaromatic polymer
JPH0733812A (ja) * 1993-07-02 1995-02-03 Idemitsu Kosan Co Ltd スチレン系重合体製造触媒及びそれを用いたスチレン系重合体の製造方法
JP3189175B2 (ja) * 1993-07-02 2001-07-16 出光興産株式会社 芳香族ビニル化合物共重合体の製造方法
JP3216748B2 (ja) * 1993-07-23 2001-10-09 出光興産株式会社 芳香族ビニル化合物重合体組成物の製造触媒及びそれを用いた芳香族ビニル化合物重合体組成物の製造方法
US5453474A (en) * 1993-10-08 1995-09-26 The Dow Chemical Company Process for preparation of syndiotactic vinylidene aromatic polymers using reduced metal cationic catalysts
JP3301455B2 (ja) 1993-11-26 2002-07-15 出光興産株式会社 芳香族ビニル化合物重合体の製造触媒及びそれを用いた芳香族ビニル化合物重合体の製造方法
JPH07188325A (ja) * 1993-12-27 1995-07-25 Idemitsu Kosan Co Ltd スチレン系重合体の製造方法
JP3369294B2 (ja) * 1994-03-11 2003-01-20 出光興産株式会社 遷移金属化合物、それを用いた重合用触媒及び該重合用触媒を用いたスチレン系重合体の製造方法
DE69505293T2 (de) * 1994-03-31 1999-03-11 Idemitsu Kosan Co. Ltd., Tokio/Tokyo Verfahren zur Herstellung eines Styrolpolymers
GB9603226D0 (en) * 1996-02-15 1996-04-17 Pharmacia Spa Heterocyclyl-ergoline derivatives
US6060483A (en) * 1996-06-27 2000-05-09 Pharmacia & Upjohn S.P.A. Antineurodegenerative ergoline derivatives
US6479424B1 (en) 1998-12-14 2002-11-12 Bp Corporation North America Inc. Fluxional catalysts and related ligands containing bulky substituents
US20070106000A1 (en) * 2005-11-10 2007-05-10 Hua Guo Polymer blend and method for its isolation
US20070238831A1 (en) * 2006-03-30 2007-10-11 Steven Klei Poly(arylene ether) composition and method of making the same
US20070238190A1 (en) * 2006-03-30 2007-10-11 Steven Klei Method of authenticating a poly(arylene ether) composition
JP6275961B2 (ja) 2013-06-26 2018-02-07 富士フイルム株式会社 光学フィルム及び表示装置

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5155080A (en) * 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
CA2024830A1 (en) * 1989-09-29 1991-03-30 Richard E. Campbell, Jr. Process for preparation of syndiotactic vinyl aromatic polymers
US5066741A (en) * 1990-03-22 1991-11-19 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers
DE69026679T3 (de) * 1989-10-30 2005-10-06 Fina Technology, Inc., Houston Addition von Alkylaluminium zum Verbessern eines Metallocenkatalysators

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DE69126854T2 (de) 1997-11-20
EP0493678A3 (en) 1992-10-07
KR0135271B1 (ko) 1998-04-23
EP0493678A2 (en) 1992-07-08
US5430001A (en) 1995-07-04
JP2888648B2 (ja) 1999-05-10
DE69126854D1 (de) 1997-08-21
TW233302B (ko) 1994-11-01
US5272229A (en) 1993-12-21
ATE155496T1 (de) 1997-08-15
EP0493678B1 (en) 1997-07-16
JPH04249504A (ja) 1992-09-04

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