KR910004540A - N,n'-(1-옥소-1,2-에탄디일)비스(아스파트산), 이의 염 및 이의 세제 조성물에서의 용도 - Google Patents

N,n'-(1-옥소-1,2-에탄디일)비스(아스파트산), 이의 염 및 이의 세제 조성물에서의 용도 Download PDF

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KR910004540A
KR910004540A KR1019900012268A KR900012268A KR910004540A KR 910004540 A KR910004540 A KR 910004540A KR 1019900012268 A KR1019900012268 A KR 1019900012268A KR 900012268 A KR900012268 A KR 900012268A KR 910004540 A KR910004540 A KR 910004540A
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composition
compound
compound according
ethanediyl
oxo
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KR1019900012268A
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윌리엄 글로고우스키 마크
앤토니 하트만 프레드릭
웨인 하인즈만 스테펜
마크 퍼킨스 크리스토퍼
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리차드 찰스 위트
디 프록터 앤드 갬블 캄파니
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Publication of KR910004540A publication Critical patent/KR910004540A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C229/24—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having more than one carboxyl group bound to the carbon skeleton, e.g. aspartic acid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3937—Stabilising agents
    • C11D3/394—Organic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
    • A61Q11/02—Preparations for deodorising, bleaching or disinfecting dentures
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/04—Preparations for permanent waving or straightening the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/08—Preparations for bleaching the hair
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07K—PEPTIDES
    • C07K5/00—Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof
    • C07K5/02—Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof containing at least one abnormal peptide link
    • C07K5/022—Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof containing at least one abnormal peptide link containing the structure -X-C(=O)-(C)n-N-C-C(=O)-Y-; X and Y being heteroatoms; n being 1 or 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07K—PEPTIDES
    • C07K5/00—Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof
    • C07K5/04—Peptides containing up to four amino acids in a fully defined sequence; Derivatives thereof containing only normal peptide links
    • C07K5/06—Dipeptides
    • C07K5/06008—Dipeptides with the first amino acid being neutral
    • C07K5/06017—Dipeptides with the first amino acid being neutral and aliphatic
    • C07K5/06026—Dipeptides with the first amino acid being neutral and aliphatic the side chain containing 0 or 1 carbon atom, i.e. Gly or Ala
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/51—Chelating agents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S210/00—Liquid purification or separation
    • Y10S210/902—Materials removed
    • Y10S210/911—Cumulative poison
    • Y10S210/912—Heavy metal

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  • Chemical & Material Sciences (AREA)
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  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
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  • Proteomics, Peptides & Aminoacids (AREA)
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  • Oral & Maxillofacial Surgery (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음.

Description

N,N′-(1-옥소-1,2-에탄디일)비스(아스파트산), 이의 염 및 이의 세제 조성물에서의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 고수준의 OEDBA 및 소량의 유기오염물을 함유하는 킬레이트화제 조성물에 대한 pH9의 물/산화 중수소중에서의13C NMR 스펙트럼을 도시하고,
제2도는 고수준의 OEDBA 및 고수준의 공지된 화합물을 함유하는 조성물에 대한 pH 9의 물/산화중수소 중에서의13C NMR 스펙트럼을 도시한다.

Claims (17)

  1. 다음 구조식의 N,N′-(1-옥소-1,2-에탄디일)비스(아스파테이트)화합물 또는 이의 입체 이성체 ;
  2. 제1항에 있어서, 다음 일반식의 OEDBA 화합물 ;
    상기식에서, x는 각각 H+, Na+, K+, Li+, RiN(H)4-1+및 이들의 혼합물 중에서 선택되고, 이때 i는 0, 1, 2, 3 또는 4이고 i가 1, 2, 3 또는 4인 경우, R은 양이온 RiN(H)4-1+가 수-해리될 수 있도록 하는 상용성 히드로카빌 잔기이다.
  3. 제2항에 있어서, 다음 일반식의 화합물 ;
    상기식에서, i는 1, 2, 3 또는 4이고 ; R은 메틸, 에틸, 프로필 및 부틸중에서 선택된다.
  4. 제2항에 있어서, 다음 일반식의 화합물 ;
    상기식에서, X는 각각 H+, Na+및 K+중에서 선택된다.
  5. 제4항에 따른 화합물 유효량을 함유하는 킬레이트화제 또는 금속이온 봉쇄제 조성물.
  6. 제4항에 따른 화합물 유효량 및 세정 계면활성제를 함유하는 세제 조성물.
  7. 제6항에 있어서, 세정 계면활성제를 음이온계, 비이온계, 양이온계 및 쯔비터이온계 계면활성제, 및 이들의 혼합물중에서 선택하는 세제 조성물.
  8. 제4항에 따른 화합물 유효량 및 종래의 표백제를 함유하는 표백제 조성물.
  9. 제8항에 있어서, 종래의 표백제를 과붕산염, 과황산염 및 과탄산염중에서 선택하는 표백제 조성물.
  10. 제4항에 따른 화합물 유효량 및 종래의 세제 증강제중 하나 이상을 함유하는 세제 증강제 조성물.
  11. 제10항에 있어서, 종래의 세제 증강제가 모두인(燐)을 함유하지 않는 증강제의 형태인 세제 증강제 조성물.
  12. 제11항에 있어서, 종래의 세제 증강제를 질소부재-폴리카복실레이트 증강제, 제올라이트 증강제 및 이들의 혼합물 중에서 선택하는 조성물.
  13. 반응동안의 pH를 약 8내지 약 9내에서 유지시킨 알카리성 수용액중에서 (i)아스파르산 또는 이의 수용성 염인 아미노산을 (ii)글리옥살 비설파이트, 글리옥살/나트륨 비설파이트 및 글리옥살/이산화황중에서 선택된 글리옥살 반응물과 반응시키는 단계를 특징으로 하여, 제1항에 따른 화합물을 제조하는 방법.
  14. 제13항에 있어서, 수산화나트륨 첨가를 조절하여 pH를 유지시키고, 중등온도에서 반응을 수행하며, 알카리성 수용액을 농축시키는 방법.
  15. N, N′-(1-옥소-1,2-에탄디일)비스(아스파테이트)를 금속양이온 함유-용액에 용해시키는 단계를 특징으로 하여, 금속 양이온을 수용액중에서 금속이온 봉쇄시키는 방법.
  16. 제15항에 있어서, N, N′-(1-옥소-1,2-에탄디일)비스(아스파테이트)의 형태가 테트라프로트산 또는 이의 나트륨 염인 방법.
  17. 수중 알카리성 pH에서 글리실아스파테이트 및 메틸 말레이어트를 반응시킨 다음 생성된 OEDBA 메틸 에스테르의 에스테르 그룹을 가수분해하는 단계를 특징으로 하여, 제1항에 따른 화합물을 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900012268A 1989-08-10 1990-08-10 N,n'-(1-옥소-1,2-에탄디일)비스(아스파트산), 이의 염 및 이의 세제 조성물에서의 용도 KR910004540A (ko)

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Application Number Priority Date Filing Date Title
US392168 1989-08-10
US07/392,168 US4983315A (en) 1989-08-10 1989-08-10 N,N'-(1-oxo-1,2-ethanediyl)-bis(aspartic acid), salts and use in detergent compositions

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KR910004540A true KR910004540A (ko) 1991-03-28

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US (1) US4983315A (ko)
EP (1) EP0412697B1 (ko)
JP (1) JP2749436B2 (ko)
KR (1) KR910004540A (ko)
CN (2) CN1030193C (ko)
AR (1) AR246273A1 (ko)
AU (1) AU648260B2 (ko)
BR (1) BR9003950A (ko)
CA (1) CA2022874C (ko)
CO (1) CO4180529A1 (ko)
DE (1) DE69023074T2 (ko)
ES (1) ES2078313T3 (ko)
IE (1) IE902891A1 (ko)
MY (1) MY107314A (ko)
NZ (1) NZ234834A (ko)
PE (1) PE17351590A1 (ko)
TR (1) TR24799A (ko)

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NZ234834A (en) 1992-05-26
EP0412697A2 (en) 1991-02-13
AU648260B2 (en) 1994-04-21
CA2022874C (en) 1997-02-04
AU6086990A (en) 1991-02-14
CN1101072A (zh) 1995-04-05
US4983315A (en) 1991-01-08
IE902891A1 (en) 1991-02-27
DE69023074D1 (de) 1995-11-23
DE69023074T2 (de) 1996-05-30
CN1030193C (zh) 1995-11-01
MY107314A (en) 1995-11-30
BR9003950A (pt) 1991-09-03
EP0412697A3 (en) 1991-10-30
CA2022874A1 (en) 1991-02-11
PE17351590A1 (es) 1991-01-16
CN1051171A (zh) 1991-05-08
ES2078313T3 (es) 1995-12-16
JPH03173857A (ja) 1991-07-29
TR24799A (tr) 1992-05-01
JP2749436B2 (ja) 1998-05-13
CO4180529A1 (es) 1995-06-07
AR246273A1 (es) 1994-07-29
EP0412697B1 (en) 1995-10-18

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