KR890014623A - 내염성을 갖는 폴리아미드 물질의 제조방법 - Google Patents
내염성을 갖는 폴리아미드 물질의 제조방법 Download PDFInfo
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- KR890014623A KR890014623A KR1019890002882A KR890002882A KR890014623A KR 890014623 A KR890014623 A KR 890014623A KR 1019890002882 A KR1019890002882 A KR 1019890002882A KR 890002882 A KR890002882 A KR 890002882A KR 890014623 A KR890014623 A KR 890014623A
- Authority
- KR
- South Korea
- Prior art keywords
- acid
- copolymer
- methacrylic acid
- substrate
- treated
- Prior art date
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- 239000004952 Polyamide Substances 0.000 title claims 7
- 229920002647 polyamide Polymers 0.000 title claims 7
- 238000004519 manufacturing process Methods 0.000 title claims 2
- 239000000463 material Substances 0.000 title 1
- 239000000758 substrate Substances 0.000 claims 14
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 11
- 229920002845 Poly(methacrylic acid) Polymers 0.000 claims 9
- 229920001577 copolymer Polymers 0.000 claims 9
- 229920003986 novolac Polymers 0.000 claims 6
- 229920005989 resin Polymers 0.000 claims 6
- 239000011347 resin Substances 0.000 claims 6
- 239000007864 aqueous solution Substances 0.000 claims 4
- 239000000178 monomer Substances 0.000 claims 4
- 239000004359 castor oil Substances 0.000 claims 3
- 235000019438 castor oil Nutrition 0.000 claims 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims 3
- 229920003145 methacrylic acid copolymer Polymers 0.000 claims 3
- 229920001897 terpolymer Polymers 0.000 claims 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- ZDWZXBJFITXZBL-UHFFFAOYSA-N S(=O)(=O)(O)C=CC1=CC=CC=C1.[Na] Chemical compound S(=O)(=O)(O)C=CC1=CC=CC=C1.[Na] ZDWZXBJFITXZBL-UHFFFAOYSA-N 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- 150000008064 anhydrides Chemical class 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 229920002302 Nylon 6,6 Polymers 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 claims 1
- 125000005250 alkyl acrylate group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 239000003086 colorant Substances 0.000 claims 1
- 239000007859 condensation product Substances 0.000 claims 1
- 238000004043 dyeing Methods 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 claims 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 1
- 125000000623 heterocyclic group Chemical group 0.000 claims 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 claims 1
- 125000005395 methacrylic acid group Chemical class 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 150000005673 monoalkenes Chemical class 0.000 claims 1
- 150000002763 monocarboxylic acids Chemical group 0.000 claims 1
- 150000002825 nitriles Chemical class 0.000 claims 1
- 150000002989 phenols Chemical class 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/41—Phenol-aldehyde or phenol-ketone resins
- D06M15/412—Phenol-aldehyde or phenol-ketone resins sulfonated
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/41—Phenol-aldehyde or phenol-ketone resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/23907—Pile or nap type surface or component
- Y10T428/23986—With coating, impregnation, or bond
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2279—Coating or impregnation improves soil repellency, soil release, or anti- soil redeposition qualities of fabric
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2861—Coated or impregnated synthetic organic fiber fabric
- Y10T442/2893—Coated or impregnated polyamide fiber fabric
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Paints Or Removers (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도 내지 제8도는 내염성을 시험하기 위해 염색정도를 1에서 8까지의 범위로 등급을 매긴 비교평가용 비율 스케일을 나타낸 사진.
Claims (10)
- 섬유상 폴리아미드 기판에 (a) 부분적으로 설폰화된 노보락수지 및 (b) 폴리메타 크릴산, 메타크릴산의 공중합체 또는 상기 폴리메타크릴산 및 상기 메타크릴산의 공중합체로 구성된 조합체가 적용된 산성 착색제에 의한 염색에 내성을 갖는 처리된 섬유상 폴리아미드 기판.
- 제1항에 있어서, 상기 설폰화된 노보락 수지는 최소한 일종의 페놀 화합물 및 알데히드의 설폰화된 축합 생성물을 포함하는 처리된 기판.
- 제 1항에 있어서, 공중합체는 모노카르복실산, 폴리카르복실산, 또는 무수물, 카르복실산 또는 무수물의 치환 또는 비 치환된 에스테르 또는 아미드, 니트릴, 비닐단량체, 비닐리덴 단량체, 모노올레핀 또는 폴리올레핀 단량체, 헤테로시클릭 단량체 또는 그들의 조합체인 공단량체 및 메타크릴산의 공중합체 또는 메타크릴산, 소듐 설포스티렌 및 스티렌으로 구성된 테르 중합체 ; 메타크릴산, 설페이트화된 캐스터유 및 아크릴산으로 구성된 테르중합체 ; 또는 메타크릴산, 아크릴산 및 설페이트화된 캐스터유로 구성된 테르 중합체인 처리된 기판.
- 제3항에 있어서, 상기 공단량체인 1 내지 4개의 알킬 단소원자를 갖는 알킬 아크릴레이트, 이타곤산, 소듐 설포스티렌 또는 설페이트화된 캐스터유인 처리된 기판.
- 제1항에 있어서, 메타크릴산은 약 30 내지 10중량%의 상기 메타크릴산의 공중합체를 포함하는 처리된 기판.
- 제1항에 있어서, 저급의 90중량%의 상기 폴리메타크릴산 및 상기 메타크릴산의 공중합체는 약 2500 내지 250,000범위내의 중량평균 분자량을 갖는 처리된 기판.
- 제1항에 있어서, 상기 기판은 나일론 66이고 상기 설폰화된 노보락 수지는 폴리아미드 섬유상 기판의 중량에 대해 최소 약 0.01중량%의 양으로 존재하며 상기 폴리메타크릴산 또는 상기 메타크릴산의 공중합체는 최소 약 0.06중량%의 양으로 존재하는 처리된 기판.
- 섬유상 폴리아미드 기판을 (a) 부분적으로 설폰화된 노보락 수지 및 (b) 폴리메타프릴산, 메타크릴산의 공중합체 또는 상기 폴리메타크릴산 및 상기 메타크릴산의 공중합체의 조합체로 구성된 처리용 수용액과 접촉시키는 것으로 구성되는 제 1항의 처리된 섬유상 폴리아미드 기판의 제조방법.
- 상기 섬유상 폴리아미드 기판을 부분적으로 설폰화된 노보락 수지의 처리용 수용액 및 폴리메타크릴산, 메타크릴산의 공중합체 또는 그들의 조합체의 처리용 수용액과 접촉시키는 단계로 구성되는 제 1 항의 처리된 섬유상 기판의 제조방법.
- (a) 부분적으로 설폰화된 노보락 수지 및 (b) 폴리메타크릴산, 메타크릴산의 공중합체 또는 상기 폴리메타크릴산 및 상기 메타크릴산의 공중합체의 조합체로 구성된 혼합물을 함유하는 제1항의 처리된 섬유상 기판의 제조에 유용한 수용액.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/167,041 US4822373A (en) | 1988-03-11 | 1988-03-11 | Process for providing polyamide materials with stain resistance with sulfonated novolak resin and polymethacrylic acd |
US167041 | 1988-03-11 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR890014623A true KR890014623A (ko) | 1989-10-25 |
KR0137953B1 KR0137953B1 (ko) | 1998-05-15 |
Family
ID=22605702
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019890002882A KR0137953B1 (ko) | 1988-03-11 | 1989-03-09 | 내오염성을 갖는 폴리아미드 기재 및 이의 제조방법 |
Country Status (9)
Country | Link |
---|---|
US (1) | US4822373A (ko) |
EP (1) | EP0332343B1 (ko) |
JP (1) | JP2744052B2 (ko) |
KR (1) | KR0137953B1 (ko) |
AU (1) | AU614023B2 (ko) |
CA (1) | CA1328716C (ko) |
DE (1) | DE68920172T2 (ko) |
DK (1) | DK117689A (ko) |
ZA (1) | ZA891857B (ko) |
Families Citing this family (88)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5032136A (en) * | 1987-12-21 | 1991-07-16 | E. I. Du Pont De Nemours And Company | Process for importing stain-resistance to textile substrates |
US4937123A (en) * | 1988-03-11 | 1990-06-26 | Minnesota Mining And Manufacturing Company | Process for providing polyamide materials with stain resistance |
US4940757A (en) * | 1989-04-20 | 1990-07-10 | Peach State Labs, Inc. | Stain resistant polymeric composition |
US5061763A (en) * | 1989-04-20 | 1991-10-29 | Peach State Labs, Inc. | Stain resistant treatment for polyamide fibers |
US5223340A (en) * | 1989-04-20 | 1993-06-29 | Peach State Labs, Inc. | Stain resistant polyamide fibers |
US5015259A (en) * | 1989-04-20 | 1991-05-14 | Peach State Labs, Inc. | Stain resistant polymeric composition |
US5310828A (en) * | 1989-04-20 | 1994-05-10 | Peach State Labs, Inc. | Superior stain resistant compositions |
CA2020492A1 (en) * | 1989-07-17 | 1991-01-18 | Matthew B. Hoyt | Polyamide fibers having reduced amino end groups, light-dyed and stain resistant polyamide fibers made therefrom, and method of preparation |
US5340886A (en) * | 1989-07-17 | 1994-08-23 | Basf Corporation | Acid-dye resistant polyamide products and process for preparation |
US5057121A (en) | 1989-08-04 | 1991-10-15 | E. I. Du Pont De Nemours And Company | Process for imparting stain-resist agent |
CA1327856C (en) * | 1989-09-05 | 1994-03-15 | Barry R. Knowlton | Method of enhancing the soil- and stain-resistance characteristics of polyamide and wool fabrics, the fabrics so treated, and treating composition |
US5074883A (en) * | 1989-12-11 | 1991-12-24 | Minnesota Mining And Manufacturing Company | Process for providing polyamide materials with stain resistance |
US5328766A (en) * | 1990-06-26 | 1994-07-12 | West Point Pepperell, Inc. | Stain-resistant, lightfast polyamide textile products and woolen goods and compositions and processes therefor |
US5212272A (en) * | 1990-10-31 | 1993-05-18 | Peach State Labs, Inc. | Polyacrylic acid compositions for textile processing |
US5629376A (en) * | 1990-10-31 | 1997-05-13 | Peach State Labs, Inc. | Polyacrylic acid compositions for textile processing |
US5460887A (en) * | 1990-12-13 | 1995-10-24 | E. I. Du Pont De Nemours And Company | Stain-resistant polyamide substrates |
US5131914A (en) * | 1990-12-13 | 1992-07-21 | Hoechst Celanese Corporation | Process for preparing multi-colored dyed polyamide substrates including the application of a reactive vinyl sulfone dye and a resist agent |
JPH06504097A (ja) * | 1990-12-27 | 1994-05-12 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 無水マレイン酸/ビニルまたはアリルエーテルポリマー耐汚染性材料 |
US5316850A (en) * | 1991-04-12 | 1994-05-31 | Peach State Labs, Inc. | Permanently stain resistant textile fibers |
CA2066876C (en) * | 1991-06-06 | 1999-12-14 | Matthew B. Hoyt | Acid-dye resistant polyamide products and process for preparation |
US5464584A (en) * | 1992-07-15 | 1995-11-07 | Basf Corporation | Process for making soil and stain resistant carpet fiber |
EP0579976B1 (en) * | 1992-07-15 | 1998-05-27 | Basf Corporation | Soil and stain resistant carpet fiber and process for producing the same |
US5516337A (en) * | 1992-09-02 | 1996-05-14 | Minnesota Mining And Manufacturing Company | Chemical system for providing fibrous materials with stain resistance |
US5466529A (en) * | 1992-09-29 | 1995-11-14 | Osi Specialties, Inc. | Polysiloxanes having anionic carboxy, phosphonic or carboxy and sulfonate groups useful as an antistain finish for nylon |
US5358769A (en) * | 1993-02-02 | 1994-10-25 | E. I. Du Pont De Nemours And Company | Process providing durable stain-resistance by use of maleic anhydride polymers |
AU6703994A (en) * | 1993-04-26 | 1994-11-21 | E.I. Du Pont De Nemours And Company | Durable methacrylic acid polymer stain-resists |
US5356689A (en) * | 1993-04-26 | 1994-10-18 | E. I. Du Pont De Nemours And Company | Process providing durable stain-resistance using methacrylic acid polymers |
US5428117A (en) * | 1993-10-18 | 1995-06-27 | Interface, Inc. | Treatment for imparting stain resistance to polyamide substrates and resulting stain resistant materials |
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-
1988
- 1988-03-11 US US07/167,041 patent/US4822373A/en not_active Expired - Lifetime
-
1989
- 1989-02-03 AU AU29622/89A patent/AU614023B2/en not_active Expired
- 1989-02-10 CA CA000590681A patent/CA1328716C/en not_active Expired - Lifetime
- 1989-03-02 DE DE68920172T patent/DE68920172T2/de not_active Expired - Fee Related
- 1989-03-02 EP EP89302086A patent/EP0332343B1/en not_active Expired - Lifetime
- 1989-03-09 KR KR1019890002882A patent/KR0137953B1/ko not_active IP Right Cessation
- 1989-03-10 DK DK117689A patent/DK117689A/da unknown
- 1989-03-10 ZA ZA891857A patent/ZA891857B/xx unknown
- 1989-03-10 JP JP1059507A patent/JP2744052B2/ja not_active Expired - Lifetime
Also Published As
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---|---|
AU2962289A (en) | 1989-09-14 |
AU614023B2 (en) | 1991-08-15 |
EP0332343A3 (en) | 1991-11-13 |
DK117689A (da) | 1989-09-12 |
DE68920172D1 (de) | 1995-02-09 |
CA1328716C (en) | 1994-04-26 |
DK117689D0 (da) | 1989-03-10 |
US4822373A (en) | 1989-04-18 |
JPH0284571A (ja) | 1990-03-26 |
EP0332343A2 (en) | 1989-09-13 |
EP0332343B1 (en) | 1994-12-28 |
KR0137953B1 (ko) | 1998-05-15 |
DE68920172T2 (de) | 1995-06-22 |
ZA891857B (en) | 1990-11-28 |
JP2744052B2 (ja) | 1998-04-28 |
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