KR870011507A - 카르복시 벤조트리아졸을 함유한 감광성 조성물 - Google Patents
카르복시 벤조트리아졸을 함유한 감광성 조성물 Download PDFInfo
- Publication number
- KR870011507A KR870011507A KR870005299A KR870005299A KR870011507A KR 870011507 A KR870011507 A KR 870011507A KR 870005299 A KR870005299 A KR 870005299A KR 870005299 A KR870005299 A KR 870005299A KR 870011507 A KR870011507 A KR 870011507A
- Authority
- KR
- South Korea
- Prior art keywords
- comonomer
- substrate
- acrylic
- actinic radiation
- methacryl
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims 7
- KFJDQPJLANOOOB-UHFFFAOYSA-N 2h-benzotriazole-4-carboxylic acid Chemical compound OC(=O)C1=CC=CC2=NNN=C12 KFJDQPJLANOOOB-UHFFFAOYSA-N 0.000 title claims 4
- 239000000758 substrate Substances 0.000 claims 5
- -1 acryl Chemical group 0.000 claims 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 4
- 238000000034 method Methods 0.000 claims 4
- 239000000178 monomer Substances 0.000 claims 4
- 230000005855 radiation Effects 0.000 claims 4
- MVWQZIKQYNDOLK-UHFFFAOYSA-N 2-methyl-n-prop-2-enoylprop-2-enamide Chemical compound CC(=C)C(=O)NC(=O)C=C MVWQZIKQYNDOLK-UHFFFAOYSA-N 0.000 claims 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 3
- 230000002378 acidificating effect Effects 0.000 claims 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 3
- 238000007334 copolymerization reaction Methods 0.000 claims 3
- 239000003999 initiator Substances 0.000 claims 3
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims 3
- 229920000642 polymer Polymers 0.000 claims 3
- GUOVBFFLXKJFEE-UHFFFAOYSA-N 2h-benzotriazole-5-carboxylic acid Chemical group C1=C(C(=O)O)C=CC2=NNN=C21 GUOVBFFLXKJFEE-UHFFFAOYSA-N 0.000 claims 2
- 238000010030 laminating Methods 0.000 claims 2
- 125000005395 methacrylic acid group Chemical group 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- 238000005530 etching Methods 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 125000005641 methacryl group Chemical group 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/0073—Masks not provided for in groups H05K3/02 - H05K3/46, e.g. for photomechanical production of patterned surfaces
- H05K3/0076—Masks not provided for in groups H05K3/02 - H05K3/46, e.g. for photomechanical production of patterned surfaces characterised by the composition of the mask
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/085—Photosensitive compositions characterised by adhesion-promoting non-macromolecular additives
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/12—Using specific substances
- H05K2203/122—Organic non-polymeric compounds, e.g. oil, wax, thiol
- H05K2203/124—Heterocyclic organic compounds, e.g. azole, furan
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/02—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding
- H05K3/06—Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding the conductive material being removed chemically or electrolytically, e.g. by photo-etch process
- H05K3/061—Etching masks
- H05K3/064—Photoresists
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/38—Improvement of the adhesion between the insulating substrate and the metal
- H05K3/389—Improvement of the adhesion between the insulating substrate and the metal by the use of a coupling agent, e.g. silane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/1053—Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
- Y10S430/1055—Radiation sensitive composition or product or process of making
- Y10S430/106—Binder containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/1053—Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
- Y10S430/1055—Radiation sensitive composition or product or process of making
- Y10S430/106—Binder containing
- Y10S430/111—Polymer of unsaturated acid or ester
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/1053—Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
- Y10S430/1055—Radiation sensitive composition or product or process of making
- Y10S430/114—Initiator containing
- Y10S430/12—Nitrogen compound containing
- Y10S430/121—Nitrogen in heterocyclic ring
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing Of Printed Circuit Boards (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Materials For Photolithography (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (5)
- 하기(a)-(c)로 이루어진 조성물에 있어서, 하기(d)가 첨가됨을 특징으로 하는 감광성 조성물:(a)부가 중합성 에틸렌형 불포화 단량체,(b)화학선으로 활성화될 수 있는 개시계(c) (1) 아크릴 또는 메타크릴 아크릴아미드 또는 메타 크릴아미드, 마미노알킬 아크릴레이트 또는 메타크릴레이트 또는 이들 중 어느 것이라도 함께 합해진 혼합물인 염기성 공단량체 최소한 하나 ;(2) 하나 또는 그 이상의 카르복실기를 함유한 산성 공단량체 최소한 하나 와(3) 아크릴성 또는 메타 크릴성인 공단량체 최소한 하나, 와의 공중합으로 부터 유도된 양쪽성 중합체;(d) 하기 일반식의 카르복시 벤조트리아졸
- 제1항에 있어서,카르복시트리아졸이 5-카르복시 벤조트리아졸인 조성물
- (a)지지된 고체 감광성 필름을 가질에 라미네이팅하고,(b)화학선에 층을 상형성 방식으로 노출하고,(c)내식막 지역을 형성하기 위해 층의 비노출 지역을 제거하고,(d)내식막 지역에 의해서 보호되지 않은 기질 지역을 기질을 에칭시키거나 물질을 기질상에 부착시켜 영구적으로 개질시키는 단계에 의하여(a)부가 중합성 에틸렌형 불포화 단량체,(b)화학선으로 활성화될 수 있는 개시계(c) (1) 아크릴 또는 메타크릴 아크릴아미드 또는 메타크릴아미드, 아미노알킬 아크릴레이트 또는 메타크릴레이트 또는 이들 중 어느 것이라도 함께 합해진 혼합물인 염기성 공 단량체 최소한 하나 ; (2) 하나 또는 그 이상의 카르복실기를 함유한 산성 공단량체 최소한 하나와(3) 아크릴성 또는 메타크릴 성인 공단량체 최소한 하나, 와의 공중합으로부터 유도된 양쪽성 중합체;를 포함하는 감광서 필름을 기질에 라미네이팅하는 방법에 있어서, 감광성 필름에 하기(d)를 첨가함을특징으로 하는 방법;(d)하기 일반식의 카르복시 벤조트리아졸
- 제1항에 있어서,카르복시트리아졸이 5-카르복시 벤조 트리아졸인 방법.
- 하기 (a)-(b)를 혼합하는 것으로 이루어진 향상된 부착성을 갖는 감광성 조성물의 제조방법.(a)부가 중합성 에틸렌형 불포화 단량체,(b)화학선으로 활성화될 수 있는 개시계(c) (1) 아크릴 또는 메타크릴 아크릴아미드 또는 메타크릴아미드, 아미노알킬 아크릴레이트 또는 메타크릴레이트 또는 이들 중 어느 것이라도 함께 합해진 혼합물인 염기성 공단량체 최소한 하나 ; (2) 하나 또는 그 이상의 카르복실기를 함유한 산성 공단량체 최소한 하나와 (3) 아크릴성 또는 메타크릴성인 공단량체 최소한 하나, 와의 공중합으로부터 유도된 양쪽성 중합체;(d) 하기 일반식의 카르복시 벤조트리아졸※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US867431 | 1986-05-28 | ||
US06/867,431 US4680249A (en) | 1986-05-28 | 1986-05-28 | Photopolymerizable composition containing carboxy benzotriazole |
Publications (2)
Publication Number | Publication Date |
---|---|
KR870011507A true KR870011507A (ko) | 1987-12-23 |
KR910001589B1 KR910001589B1 (ko) | 1991-03-16 |
Family
ID=25349761
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019870005299A KR910001589B1 (ko) | 1986-05-28 | 1987-05-27 | 카르복시 벤조트리아졸을 함유한 감광성 조성물 |
Country Status (8)
Country | Link |
---|---|
US (2) | US4680249A (ko) |
EP (1) | EP0247549B1 (ko) |
JP (1) | JPS6324243A (ko) |
KR (1) | KR910001589B1 (ko) |
CN (1) | CN87103854A (ko) |
BR (1) | BR8702714A (ko) |
CA (1) | CA1295166C (ko) |
DE (1) | DE3774763D1 (ko) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0234984A (ja) * | 1988-04-13 | 1990-02-05 | Mitsubishi Electric Corp | プリント回路基板の製造方法 |
JP2733672B2 (ja) * | 1988-10-24 | 1998-03-30 | 東京応化工業株式会社 | 光重合性樹脂組成物 |
US4942248A (en) * | 1988-12-01 | 1990-07-17 | Ppg Industries, Inc. | Tertiary-alkyl esters of 1H-benzotriazole-1-carboxylic acids |
JPH03179356A (ja) * | 1989-05-18 | 1991-08-05 | Hitachi Chem Co Ltd | 感光性樹脂組成物及び感光性樹脂組成物積層体 |
JPH0351853A (ja) * | 1989-07-19 | 1991-03-06 | Hitachi Chem Co Ltd | 感光性樹脂組成物及び感光性積層体 |
DE3926708A1 (de) * | 1989-08-12 | 1991-02-14 | Basf Ag | Photopolymerisierbares schichtuebertragungsmaterial |
US5204390A (en) * | 1989-09-08 | 1993-04-20 | H.B. Fuller Company | Hot melt adhesive resistant to ultraviolet light-induced degradation and to plasticizer migration |
JPH0511439A (ja) * | 1990-09-13 | 1993-01-22 | Fuji Photo Film Co Ltd | 光重合性組成物 |
US5403698A (en) * | 1990-10-16 | 1995-04-04 | Hitachi Chemical Company, Ltd. | Negative type photosensitive electrodepositing resin composition |
US5314789A (en) * | 1991-10-01 | 1994-05-24 | Shipley Company Inc. | Method of forming a relief image comprising amphoteric compositions |
US5240817A (en) * | 1991-12-20 | 1993-08-31 | E. I. Du Pont De Nemours And Company | Lamination of a photopolymerizable solder mask layer to a substate containing holes using an intermediate photopolymerizable liquid layer |
JPH0643644A (ja) * | 1992-04-01 | 1994-02-18 | Dainippon Toryo Co Ltd | ネガ型感光性電着塗料樹脂組成物、これを用いた電着塗装浴及びレジストパターンの製造法 |
US6297294B1 (en) | 1999-10-07 | 2001-10-02 | E. I. Du Pont De Nemours And Company | Method for improving the adhesion of a photopolymerizable composition to copper |
JP2003005359A (ja) * | 2001-06-27 | 2003-01-08 | Hitachi Chem Co Ltd | 高解像・高密着性の感光性樹脂組成物及びその用途 |
JP2003035953A (ja) * | 2001-07-23 | 2003-02-07 | Hitachi Chem Co Ltd | 高密度・高解像度用の感光性樹脂組成物及びその用途 |
EP1279699A1 (en) | 2001-07-27 | 2003-01-29 | Baselltech USA Inc. | Soft polyolefin compositions |
US6822047B2 (en) * | 2003-01-02 | 2004-11-23 | National Starch And Chemical Investment Holding Corporation | Adhesive with carboxyl benzotriazole for improved adhesion to metal substrates |
DE602005009990D1 (de) * | 2004-02-26 | 2008-11-13 | Fujifilm Corp | Polymerisierbare Zusammensetzung und Verfahren zur Herstellung von lithographischen Druckplatten unter Verwendung der polymerisierbaren Zusammensetzung |
US20060027321A1 (en) * | 2004-08-09 | 2006-02-09 | 3M Innovative Properties Company | Adhesive composition |
US20060029784A1 (en) * | 2004-08-09 | 2006-02-09 | 3M Innovative Properties Company | Laminated optical article |
KR100860901B1 (ko) | 2004-08-11 | 2008-09-29 | 히다치 가세고교 가부시끼가이샤 | 감광성 수지 조성물 및 이것을 이용한 감광성 필름 |
TW200619846A (en) * | 2004-08-11 | 2006-06-16 | Hitachi Chemical Co Ltd | Photosensitive resin composition and photosensitive film made with the same |
US20060154180A1 (en) | 2005-01-07 | 2006-07-13 | Kannurpatti Anandkumar R | Imaging element for use as a recording element and process of using the imaging element |
US7579134B2 (en) * | 2005-03-15 | 2009-08-25 | E. I. Dupont De Nemours And Company | Polyimide composite coverlays and methods and compositions relating thereto |
US7618766B2 (en) * | 2005-12-21 | 2009-11-17 | E. I. Du Pont De Nemours And Company | Flame retardant photoimagable coverlay compositions and methods relating thereto |
US20090087774A1 (en) * | 2007-08-27 | 2009-04-02 | E.I. Du Pont De Nemours And Company | Compositions and methods for wet lamination of photopolymerizable dry films onto substrates |
CN101430507A (zh) * | 2007-08-27 | 2009-05-13 | E.I.内穆尔杜邦公司 | 基片上的可光聚合干膜的湿层叠以及与湿层叠有关的组合物 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3622334A (en) * | 1969-12-31 | 1971-11-23 | Du Pont | Photopolymerizable compositions and elements containing heterocyclic nitrogen-containing compounds |
US4054483A (en) * | 1976-12-22 | 1977-10-18 | E. I. Du Pont De Nemours And Company | Additives process for producing plated holes in printed circuit elements |
US4214936A (en) * | 1978-10-24 | 1980-07-29 | E. I. Du Pont De Nemours And Company | Lamination process |
US4293635A (en) * | 1980-05-27 | 1981-10-06 | E. I. Du Pont De Nemours And Company | Photopolymerizable composition with polymeric binder |
US4438190A (en) * | 1981-03-04 | 1984-03-20 | Hitachi Chemical Company, Ltd. | Photosensitive resin composition containing unsaturated monomers and unsaturated phosphates |
JPS589138A (ja) * | 1981-07-10 | 1983-01-19 | Hitachi Chem Co Ltd | 感光性樹脂組成物 |
JPS61166541A (ja) * | 1985-01-19 | 1986-07-28 | Fuotopori Ouka Kk | 光重合性組成物 |
-
1986
- 1986-05-28 US US06/867,431 patent/US4680249A/en not_active Expired - Lifetime
-
1987
- 1987-02-24 US US07/017,891 patent/US4710262A/en not_active Expired - Fee Related
- 1987-05-21 CA CA000537589A patent/CA1295166C/en not_active Expired - Lifetime
- 1987-05-23 DE DE8787107524T patent/DE3774763D1/de not_active Expired - Lifetime
- 1987-05-23 EP EP87107524A patent/EP0247549B1/en not_active Expired - Lifetime
- 1987-05-27 JP JP62128557A patent/JPS6324243A/ja active Pending
- 1987-05-27 KR KR1019870005299A patent/KR910001589B1/ko not_active IP Right Cessation
- 1987-05-27 BR BR8702714A patent/BR8702714A/pt unknown
- 1987-05-28 CN CN198787103854A patent/CN87103854A/zh active Pending
Also Published As
Publication number | Publication date |
---|---|
DE3774763D1 (de) | 1992-01-09 |
US4710262A (en) | 1987-12-01 |
JPS6324243A (ja) | 1988-02-01 |
KR910001589B1 (ko) | 1991-03-16 |
EP0247549A2 (en) | 1987-12-02 |
EP0247549A3 (en) | 1988-01-13 |
EP0247549B1 (en) | 1991-11-27 |
CN87103854A (zh) | 1987-12-23 |
US4680249A (en) | 1987-07-14 |
BR8702714A (pt) | 1988-03-01 |
CA1295166C (en) | 1992-02-04 |
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