KR870004173A - 방오염성 폴리에스테르섬유 - Google Patents

방오염성 폴리에스테르섬유 Download PDF

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KR870004173A
KR870004173A KR1019860008593A KR860008593A KR870004173A KR 870004173 A KR870004173 A KR 870004173A KR 1019860008593 A KR1019860008593 A KR 1019860008593A KR 860008593 A KR860008593 A KR 860008593A KR 870004173 A KR870004173 A KR 870004173A
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South Korea
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polyester
glycol
group
antifouling
polyester fiber
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KR1019860008593A
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KR910007559B1 (ko
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신지 오와끼
스쯔끼도기
시게노부 고바야시
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나까오 마스로오
데이진 가부시끼가이샤
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Priority claimed from JP60226977A external-priority patent/JPS6290312A/ja
Priority claimed from JP61176566A external-priority patent/JPS6335824A/ja
Application filed by 나까오 마스로오, 데이진 가부시끼가이샤 filed Critical 나까오 마스로오
Publication of KR870004173A publication Critical patent/KR870004173A/ko
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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
    • D01F6/86—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from polyetheresters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0041—Optical brightening agents, organic pigments
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C08K5/42—Sulfonic acids; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Artificial Filaments (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

내용 없음

Description

방오염성 폴리에스테르섬유
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (17)

  1. 골격구조의 폴리에스테르 중합체 : 및 골격구조의 폴리에스테르의 분자중 적어도 몇부분의 말단이 보호되어 있는 한가지 형태 이상의 치환체를 함유하며 또한 치환체가 다음 식(Ⅰ)의 폴리옥시알킬렌글리콜모노에테르 그룹으로 구성되어 있는 것을 포함하는 하나 이상의 섬유형성 폴리에스테르 공중합체로 되어 있는 방오염성 폴리에스테르섬유
    상기 식에서, R1은 활성수소원자가 없는 일가유기기이며 R2는 알킬렌기이며 또한 n은 2 또는 그 이상의 양의정수이다.
  2. 제 1 항에 있어서, 골격구조의 폴리에스테르 중합체가 디카르복실산 성분과 알킬 글리콜성분의 중합 생성물로부터 유도되며 또한 폴리옥시알킬렌글리콜 모노에테르그룹이 디카르복실산 성분의 몰량으로 기준하여 0.01 내지 4.0몰 %의 양인 방오염성 폴리에스테르섬유
  3. 제 1 항에 있어서, 식(Ⅰ) 중 R1로 나타낸 일가유기기가 알킬기, 아릴기 및 활성수소원자가 없는 알킬아릴기로 구성되어 있는 그룹으로부터 선택되는 방오염성 폴리에스테르섬유
  4. 제 1 항에 있어서, 식(Ⅰ) 중 R2로 나타낸 알킬렌기가 2 내지 4개 탄소원자를 갖는 방오염성 폴리에스테르섬유
  5. 제 1 항에 있어서, 식(Ⅰ) 중 n이 20 내지 140의 정수인 방오염성 폴리에스테르섬유
  6. 제 1 항에 있어서, 폴리옥시알킬렌글리콜 모노에테르가 폴리리옥시에틸렌글리콜 모노에틸에테르, 폴리옥시에틸렌글리콜모노페닐에테르, 폴리옥시에틸렌글리콜 모노옥틸페닐에테르, 폴리옥시에틸렌글리콜모노닐페닐에테르, 플로옥시에틸렌글리콜모노세틸에테르, 폴리옥시프로필렌글리콜모노페닐에테르, 폴리옥시프로필렌글리콜모노옥틸페닐에테르, 폴리옥시프로필렌글리콜모노닐페닐에테르, 폴리옥시프로필렌글리콜모노아세틸페닐에테르, 폴리옥시테트라메틸렌글리콜모노메틸에테르, 폴리옥시에틸렌글리콜-폴리옥시프로필글리콜 공중합체의 모노메틸에틸에테르로 구성되어 있는 그룹으로부터 선택되는 방오염성 폴리에스테르섬유
  7. 제 1 항에 있어서, 폴리알킬렌글리콜모노에테르 그룹이 폴리에스테르 공중합체의 중량을 기준으로 하여 0.5내지 10중량%인 방오염성 폴리에스테르섬유
  8. 제 1 항에 있어서, 섬유가(100)평면에 50 내지 100Å의 결정크기와 (010)평면에 65 내지 170Å의 결정크기, 0.15 또는 그 이상의 복굴절도, 40% 또는 그 이하의 최대신도 및 인장강도 4g/l를 갖는 방오염성 폴리에스테르섬유.
  9. 제 1 항에 있어서, 섬유가 섬유형성 폴리에스테르공중합체 이외에 유기폴리실록산, 유기술폰산의 4급 오니움염, 폴리에스테르 공중합체와 반응하지 않는 유기술폰산의 금속염으로 구성되어 있는 그룹으로부터 선택된 한가지 이상의 구성원으로 구성되어 있는 부가물을 함유하는 방오염성 폴리에스테르섬유.
  10. 제 9 항에 있어서, 유기폴리실록산이 폴리에스테르 공중합체의 중량을 기준으로 하여 0.001 중량% 또는 그 이상인 방오염성 폴리에스테르섬유
  11. 제 9 항에 있어서, 유기술폰산의 4급 오니윰염이 폴리에스테르 공중합체의 중량을 기준으로 하여 0.01 내지 2.0 중량% 인 방오염성 폴리에스테르섬유
  12. 제 1 항에 있어서, 유기술폰산의 금속염이 폴리에스테르 공중합체의 중량을 기준으로 하여 0.01 내지 2.0중량%인 방오염성 폴리에스테르섬유
  13. 제 1 항에 있어서, 섬유가 친수성 수지물질로 피복되는 방오염성 폴리에스테르섬유
  14. 제13항에 있어서, 친수성 수지물질이 한가지 이상의 폴리에테르 폴리에스테르블럭 공중합체로 구성되어 있는 방오염성 폴리에스테르섬유
  15. 제 1 항에 있어서, 섬유가 섬유형성 폴리에스테르 공중합체 이외에 한가지 이상의 다음 식(Ⅳ)의 스틸벤화합물로 구성되어 있는 형광백색제를 함유하는 방오염성 폴리에스테르섬유
    상기 식에서, R12및 R13은 각각 수소원자, 할로겐 원자, 알킬기, 알콕시기 및 아릴기로 구성되어 있는 그룹으로 부터 선택된 구성원이며, 또한 c 및 d는 각각 1 내지 2의 정수이다.
  16. 제15항에 있어서, 스틸벤화합물이 4,4′-비스(벤조옥사졸일)스틸벤인 방오염성 폴리에스테르섬유
  17. 제 1 항에 있어서, 골격구조 폴리에스테르 중합체가 주성분으로써 테레프탈산 또는 이의 무수물과 2 내지 6개의 탄소원자를 갖는 하나 이상의 알킬렌글리콜을 함유하는 글리콜 성분과를 포함하는 방향족 디카르복실 성분의 중합생성물인 방오염성 폴리에스테르섬유.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860008593A 1985-10-14 1986-10-14 방오염성 폴리에스테르 섬유 KR910007559B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP60226977A JPS6290312A (ja) 1985-10-14 1985-10-14 改質ポリエステル繊維
JP60-226977 1985-10-14
JP61-176566 1986-07-29
JP61176566A JPS6335824A (ja) 1986-07-29 1986-07-29 防汚性ポリエステル繊維

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KR870004173A true KR870004173A (ko) 1987-05-07
KR910007559B1 KR910007559B1 (ko) 1991-09-27

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US (1) US4745142A (ko)
EP (1) EP0220576B1 (ko)
KR (1) KR910007559B1 (ko)
DE (1) DE3676427D1 (ko)

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JPS5235399B2 (ko) * 1973-07-31 1977-09-08

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DE3676427D1 (de) 1991-02-07
US4745142A (en) 1988-05-17
EP0220576A1 (en) 1987-05-06
EP0220576B1 (en) 1991-01-02
KR910007559B1 (ko) 1991-09-27

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