KR870001282A - 구조 보강처리된 라텍스미립 및 이의 제조방법 - Google Patents
구조 보강처리된 라텍스미립 및 이의 제조방법 Download PDFInfo
- Publication number
- KR870001282A KR870001282A KR1019860006215A KR860006215A KR870001282A KR 870001282 A KR870001282 A KR 870001282A KR 1019860006215 A KR1019860006215 A KR 1019860006215A KR 860006215 A KR860006215 A KR 860006215A KR 870001282 A KR870001282 A KR 870001282A
- Authority
- KR
- South Korea
- Prior art keywords
- mentioned
- monomer
- polymer
- process according
- parts
- Prior art date
Links
- 239000004816 latex Substances 0.000 title claims description 8
- 229920000126 latex Polymers 0.000 title claims description 8
- 239000008187 granular material Substances 0.000 title claims 3
- 238000002360 preparation method Methods 0.000 title 1
- 230000002787 reinforcement Effects 0.000 title 1
- 239000000178 monomer Substances 0.000 claims 11
- 238000000034 method Methods 0.000 claims 8
- 229920000642 polymer Polymers 0.000 claims 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
- 230000000379 polymerizing effect Effects 0.000 claims 2
- 239000002562 thickening agent Substances 0.000 claims 2
- 238000010556 emulsion polymerization method Methods 0.000 claims 1
- 239000010419 fine particle Substances 0.000 claims 1
- 238000009472 formulation Methods 0.000 claims 1
- 230000009477 glass transition Effects 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/902—Core-shell
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Reinforced Plastic Materials (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Abstract
내용 없음.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 구조 보강처리된 라텍스필름 및 대조용 균일질 라텍스 필름의 응력-변형 곡선을 도시한 것이다.
Claims (10)
- (a) 제1단량체 공급물을 중합시켜 코어대역을 형성하고, (b) 라텍스미립중의 단량체 100부당 5 내지 30부의 제2단량체 공급물[여기서, 제2단량체의 중합체는 언급된 (a)보다 높은 유리전이온도(Tg)를 갖는다]을 언급된 (a)의 존재하에 중합시키고, (c) 상기 (a)와 (b)의 존재하에, 제3단량체 공급물[여기서, 제3단량치의 중합체는 언급된 (b)보다 낮은 Tg를 갖는다]을 중합시켜 셀대역을 형성함을 특징으로 하는 유액중합 방법으로 제조된, 개선된 인장 및 신장특성을 갖는 필름으로 제조할 수 있는 구조 보강처리된 라텍스미립의 제조방법.
- 제1항에 있어서, 언급된 (b)로부터 제조된 중합체가 25℃ 이상의 Tg를 갖는 방법.
- 제1항에 있어서, 언급된 단량체 공급물(a) 및 (c)로부터 제조된 중합체가 동일한 Tg를 갖는 방법.
- 제3항에 있어서, 언급된 단량체 공급물(a) 및 (c)가 동일조성인 방법.
- 제1항에 있어서, 언급된 단량체 공급물(a) 및 (C)가 스티렌과 부타디엔과의 혼합물인 방법.
- 제1항에 있어서, 언급된 제2단량체 공급물(b)가 언급된 라텍스미립중의 단량체 100부당 15 내지 25부의 양인 방법.
- 제1항에 있어서, 언급된 단량체 공급물(b)가 이의 중합체가 25℃ 이상의 Tg를 갖는 스티렌 또는 이의 혼합물인 방법.
- 전술된 항들중 어느 하나의 항의 방법으로 제조됨을 특징으로 하는, 개선된 인장 및 신장 특성을 갖는 필름으로 제조할 수 있는 구조 보강처리된 라텍스 미립.
- (i) 제1 내지 7항중 어느 하나의 항의 방법으로 제조된 개선된 인장 및 신장 특성을 갖는 구조 보강 처리된 라텍스미립, 및 (ii) 증점제로 이루어짐을 특징으로 하는 감압성 접착제.
- 제9항에 있어서, 언급된 증점제가 감압성 접착성 제형중의 고체 기준으로 1 내지 90중량%를 구성하는 감압성 접착제.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US759994 | 1985-07-29 | ||
US06/759,994 US4717750A (en) | 1985-07-29 | 1985-07-29 | Structure reinforced latex particles |
US759,994 | 1985-07-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR870001282A true KR870001282A (ko) | 1987-03-12 |
KR920000194B1 KR920000194B1 (ko) | 1992-01-10 |
Family
ID=25057723
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019860006215A KR920000194B1 (ko) | 1985-07-29 | 1986-07-29 | 구조 보강 라텍스 미립자, 이의 제조방법 및 이를 함유하는 감압성 접착제 |
Country Status (13)
Country | Link |
---|---|
US (1) | US4717750A (ko) |
EP (1) | EP0215241B1 (ko) |
JP (1) | JPH075693B2 (ko) |
KR (1) | KR920000194B1 (ko) |
AR (1) | AR242596A1 (ko) |
AT (1) | ATE60614T1 (ko) |
AU (1) | AU595520B2 (ko) |
BR (1) | BR8603557A (ko) |
CA (1) | CA1308835C (ko) |
DE (1) | DE3677298D1 (ko) |
ES (1) | ES2001040A6 (ko) |
FI (1) | FI90245C (ko) |
MX (1) | MX165323B (ko) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4701493A (en) * | 1986-07-14 | 1987-10-20 | Atlantic Richfield Company | Acrylic modified N-arylmaleimide copolymer molding composition |
US4923919A (en) * | 1986-08-22 | 1990-05-08 | S. C. Johnson & Son, Inc. | Pressure sensitive adhesive compositions |
US4806207A (en) * | 1987-02-15 | 1989-02-21 | The Dow Chemical Company | Structured latex particles having reinforcing and opacity characteristics |
US4939190A (en) * | 1987-05-25 | 1990-07-03 | Dainippon Ink And Chemicals, Inc. | Aqueous emulsion-type pressure sensitive adhesives |
US4888395A (en) * | 1987-07-02 | 1989-12-19 | Mobil Oil Corporation | Core/shell polymers and improved sealable articles treated with the same |
GB8718036D0 (en) * | 1987-07-30 | 1987-09-03 | Tioxide Group Plc | Polymeric particles |
GB8729399D0 (en) * | 1987-12-17 | 1988-02-03 | Tioxide Group Plc | Polymeric particles & their preparation |
US5066708A (en) * | 1989-04-11 | 1991-11-19 | Rohm And Haas Company | Novel damping compositions |
US5008324A (en) * | 1989-04-11 | 1991-04-16 | Rohm And Haas Company | Novel damping compositions |
GB9007199D0 (en) * | 1990-03-30 | 1990-05-30 | Tioxide Group Plc | Preparation of polymeric particles |
US5700852A (en) * | 1994-04-06 | 1997-12-23 | Japan Synthetic Rubber Co., Ltd. | Paper coating composition |
US5824748A (en) † | 1996-06-03 | 1998-10-20 | Minnesota Mining And Manufacturing Company | Composite pressure sensitive adhesive microspheres |
DE19632202A1 (de) | 1996-08-09 | 1998-02-12 | Basf Ag | Haftklebstoffe auf Basis mehrstufig aufgebauter Polymerisate |
KR100264512B1 (ko) * | 1998-02-14 | 2000-09-01 | 박찬구 | 스티렌-부타디엔계라텍스 |
US6180307B1 (en) | 1999-11-23 | 2001-01-30 | Xerox Corporation | Layered polymer particles, toner formed therefrom and methods for forming the same |
US6355720B1 (en) | 2000-05-12 | 2002-03-12 | Johnson Polymer, Inc. | Latex formulations with reduced yellowing |
JP4917268B2 (ja) * | 2005-04-13 | 2012-04-18 | 旭化成ケミカルズ株式会社 | 感熱記録紙塗工用組成物 |
EP1911771A1 (en) * | 2006-10-09 | 2008-04-16 | Cytec Surface Specialties, S.A. | Acqueous polymer dispersion and process |
BR102012012742B1 (pt) * | 2012-05-28 | 2022-03-08 | Instituto De Pesquisas Tecnológicas Do Est. S. Paulo S/a Ipt | Método de produção de borracha na forma sólida microparticulada |
CN115947884B (zh) * | 2022-12-20 | 2024-03-05 | 山东万达化工有限公司 | 一种大粒径聚丁二烯胶乳的合成方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2144273C3 (de) * | 1971-09-01 | 1975-09-25 | Japan Synthetic Rubber Co., Ltd., Tokio | Verfahren zur Herstellung eines Pfropfpolymerisates und Verwendung desselben in Formmassen auf Polyvinylchlorid-Basis |
FR2239488B1 (ko) * | 1973-07-11 | 1976-04-30 | Rhone Progil | |
US4289823A (en) * | 1980-09-30 | 1981-09-15 | Rohm And Haas Company | Calenderable acrylic polymers and textiles treated therewith |
IE57758B1 (en) * | 1983-08-31 | 1993-03-24 | Mitsubishi Rayon Co | Impact modifier and thermoplastic resin compositions using the same |
US4537916A (en) * | 1984-06-25 | 1985-08-27 | The Dow Chemical Company | Structured latex particles which are film forming and a process for their preparation |
-
1985
- 1985-07-29 US US06/759,994 patent/US4717750A/en not_active Expired - Fee Related
-
1986
- 1986-07-23 AU AU60458/86A patent/AU595520B2/en not_active Ceased
- 1986-07-25 AT AT86110242T patent/ATE60614T1/de not_active IP Right Cessation
- 1986-07-25 FI FI863060A patent/FI90245C/fi not_active IP Right Cessation
- 1986-07-25 EP EP86110242A patent/EP0215241B1/en not_active Expired - Lifetime
- 1986-07-25 DE DE8686110242T patent/DE3677298D1/de not_active Expired - Fee Related
- 1986-07-28 JP JP61175798A patent/JPH075693B2/ja not_active Expired - Lifetime
- 1986-07-28 BR BR8603557A patent/BR8603557A/pt unknown
- 1986-07-28 AR AR86304677A patent/AR242596A1/es active
- 1986-07-28 CA CA000514750A patent/CA1308835C/en not_active Expired - Fee Related
- 1986-07-28 ES ES8600650A patent/ES2001040A6/es not_active Expired
- 1986-07-29 KR KR1019860006215A patent/KR920000194B1/ko not_active IP Right Cessation
- 1986-07-29 MX MX003294A patent/MX165323B/es unknown
Also Published As
Publication number | Publication date |
---|---|
FI90245B (fi) | 1993-09-30 |
EP0215241A1 (en) | 1987-03-25 |
FI863060A0 (fi) | 1986-07-25 |
MX165323B (es) | 1992-11-05 |
ES2001040A6 (es) | 1988-04-16 |
AU595520B2 (en) | 1990-04-05 |
CA1308835C (en) | 1992-10-13 |
BR8603557A (pt) | 1987-03-04 |
JPS6236413A (ja) | 1987-02-17 |
US4717750A (en) | 1988-01-05 |
FI90245C (fi) | 1994-01-10 |
EP0215241B1 (en) | 1991-01-30 |
ATE60614T1 (de) | 1991-02-15 |
KR920000194B1 (ko) | 1992-01-10 |
DE3677298D1 (de) | 1991-03-07 |
AR242596A1 (es) | 1993-04-30 |
JPH075693B2 (ja) | 1995-01-25 |
FI863060A (fi) | 1987-01-30 |
AU6045886A (en) | 1987-02-05 |
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Free format text: APPEAL AGAINST DECISION TO DECLINE REFUSAL |
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E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
LAPS | Lapse due to unpaid annual fee |