KR860000096A - 니켈/알루미나촉매, 그 제법 및 용도 - Google Patents
니켈/알루미나촉매, 그 제법 및 용도 Download PDFInfo
- Publication number
- KR860000096A KR860000096A KR1019850004434A KR850004434A KR860000096A KR 860000096 A KR860000096 A KR 860000096A KR 1019850004434 A KR1019850004434 A KR 1019850004434A KR 850004434 A KR850004434 A KR 850004434A KR 860000096 A KR860000096 A KR 860000096A
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- KR
- South Korea
- Prior art keywords
- nickel
- catalyst
- property
- aluminum
- suspension
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims 20
- 229910052759 nickel Inorganic materials 0.000 title claims 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title claims 2
- 238000002360 preparation method Methods 0.000 title 1
- 238000000034 method Methods 0.000 claims 8
- 229910052782 aluminium Inorganic materials 0.000 claims 6
- -1 aluminum compound Chemical class 0.000 claims 4
- 239000011148 porous material Substances 0.000 claims 3
- 239000000725 suspension Substances 0.000 claims 3
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims 2
- 230000032683 aging Effects 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 2
- 229910001453 nickel ion Inorganic materials 0.000 claims 2
- 239000002244 precipitate Substances 0.000 claims 2
- 238000001556 precipitation Methods 0.000 claims 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims 1
- 239000013078 crystal Substances 0.000 claims 1
- 238000005984 hydrogenation reaction Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000013081 microcrystal Substances 0.000 claims 1
- 150000002815 nickel Chemical class 0.000 claims 1
- 150000002816 nickel compounds Chemical class 0.000 claims 1
- 150000002894 organic compounds Chemical class 0.000 claims 1
- 238000005086 pumping Methods 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 238000000635 electron micrograph Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/12—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by hydrogenation
- C11C3/123—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by hydrogenation using catalysts based principally on nickel or derivates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/392—Metal surface area
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/391—Physical properties of the active metal ingredient
- B01J35/393—Metal or metal oxide crystallite size
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/651—50-500 nm
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
- B01J35/69—Pore distribution bimodal
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fats And Perfumes (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 촉매판의 전자현미경사진임.
Claims (16)
- 니켈/알루미늄 촉매는 다음과 같은 특성을 갖는다. 니켈/알루미늄의 원자비율은 10-2니켈의 활성표면적으로 니켈 1g당 70-150㎡이며 평균구멍의 크기는 상기(上記)한 원자비율에 좌우되며 4-20nm가 된다.
- 청구범위 1에 있어서 촉매는 원자비율이 10-4라는 특성을 갖는다.
- 청구범위 1 또는 2에 있어서 촉매는 니켈의 활성표면적이 니켈 1g당 90-150㎡라는 특성을 갖는다.
- 청구범위 1-3중 어느하나라도 만족하는 촉매는 BET의 총표면적이 촉매 1g당 90-450㎡이라는 특성을 갖는다.
- 청구범위 1-4중 어느 하나라도 만족하는 촉매는 니켈의 미소결정의 직경이 1-5nm라는 특성을 갖는다.
- 청구범위 1-5중 어느하나라도 만족시키는 촉매는 100-500nm의 거대동공으로된 다공성의 구조와 평균구경 8-20nm의 중간동공을 갖는 특성이 있다.
- 청구범위 6에 있어서 만족하는 촉매는 거대동공이 상호연결된 촉매결정판에 의해 형성된다는 특성이 있다.
- 청구범위 1-7중 어느 것이든지에 의해 규정된 니켈/알루미나촉매를 제조하는 공정, 그 공정에서 과량의 염기성 침전제를 첨가한 니켈염의 수용액으로부터 불용성의 니켈화합물이 침전의로 석출되고, 이 침전물은 현탄액의 상태로 방치된 후 모아지고, 건조시켜 환원한뒤 특성을 살피게된다. 이때 니켈이온들이 침전이 생성된 후에 가용성의 알루미늄 화합물을 첨가한다는 특성을 갖는다.
- 청구범위 8에 있어서 공정은 니켈이온이 침전된 후 15분이내에 가용성의 알루미늄화합물을 그 현탁액에 첨가하는 특성을 갖는다.
- 청구범위 8 또는 9에 있어서 만족하는 공정은, 가용성의 알루미늄 화합물을 1g 원자의 니켈당 0.1-0.5몰의 알루미늄이온의 비율이 되도록 첨가하는 것을 특징으로 갖는다.
- 청구범위 10에 있어서 공정은 알루미늄화합물의 양이 0.1-0.25라는 것을 특성으로 갖는다.
- 청구범위 8-11중 어느하나라도 따르는 공정은 숙성과정을 20-180분동안에 수행한다는 특성을 갖는다.
- 청구범위 8-12중 어느 하나라도 따르는 공정은 40-100℃에서 숙성과정을 수행한다는 특성을 갖는다.
- 청구범위 8-13에 있어서 불포화유기 화합물의 수소화반응의 공정은 상기한 조건에 따르는 촉매를 사용했다는 점을 특성으로 갖는다.
- 청구범위 8-14중 어느하나라도 만족시키는 공정은 금속염의 수용액과 염기성의 침전제를 격렬하게 교반되는 작은 혼합용기에 넣고, 그 현탁액을 하나 또는 두개의 후반반응기로 펌프질하여 옮김으로써 침전이 계속하여 끊임없이 생성되는 특성을 갖는다.
- 청구범위 15에 있어서 공정은 두 개이상의 후반반응기를 사용하여 두번째 후반반응용기에서와 그 다음에 있을 수 있는 후반반응기의 온도는 첫번째의 후반반응기에서 보다 5-15℃ 낮게 유지한다는 점을 특성으로 갖는다.※ 참고사항 : 최초출원내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL8401965 | 1984-06-21 | ||
NL8401965A NL190750C (nl) | 1984-06-21 | 1984-06-21 | Nikkelaluminaat katalysator, de bereiding daarvan en het hydrogeneren van onverzadigde organische verbindingen daarmee. |
Publications (2)
Publication Number | Publication Date |
---|---|
KR860000096A true KR860000096A (ko) | 1986-01-25 |
KR890002858B1 KR890002858B1 (ko) | 1989-08-05 |
Family
ID=19844110
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019850004433A KR890002859B1 (ko) | 1984-06-21 | 1985-06-21 | 니켈/알루미나/규산염 촉매와 그 제조방법 |
KR1019850004434A KR890002858B1 (ko) | 1984-06-21 | 1985-06-21 | 니켈/알루미나 촉매와 그 제조방법 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019850004433A KR890002859B1 (ko) | 1984-06-21 | 1985-06-21 | 니켈/알루미나/규산염 촉매와 그 제조방법 |
Country Status (16)
Country | Link |
---|---|
US (5) | US4631265A (ko) |
EP (2) | EP0168091B2 (ko) |
JP (2) | JPS6164332A (ko) |
KR (2) | KR890002859B1 (ko) |
AT (2) | ATE33211T1 (ko) |
AU (2) | AU564213B2 (ko) |
BR (2) | BR8502979A (ko) |
CA (2) | CA1246534A (ko) |
DE (2) | DE3561986D1 (ko) |
DK (2) | DK162744C (ko) |
ES (4) | ES8607755A1 (ko) |
IN (4) | IN162417B (ko) |
MX (2) | MX166441B (ko) |
NL (1) | NL190750C (ko) |
NO (2) | NO159700C (ko) |
ZA (2) | ZA854698B (ko) |
Families Citing this family (78)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL190750C (nl) * | 1984-06-21 | 1994-08-01 | Unilever Nv | Nikkelaluminaat katalysator, de bereiding daarvan en het hydrogeneren van onverzadigde organische verbindingen daarmee. |
JPS62175445A (ja) * | 1986-01-27 | 1987-08-01 | Lion Akzo Kk | 長鎖不飽和脂肪族第2級アミンの製造方法 |
CA1304069C (en) * | 1986-08-25 | 1992-06-23 | Johannes C. Oudejans | Hydrogenation catalyst |
ATE87845T1 (de) * | 1987-12-21 | 1993-04-15 | Unilever Nv | Nickel-kieselerde-katalysatoren und ihre bereitung. |
US4992605A (en) * | 1988-02-16 | 1991-02-12 | Craig Wayne K | Production of hydrocarbons with a relatively high cetane rating |
DE3811038A1 (de) * | 1988-03-31 | 1989-10-12 | Ruhrchemie Ag | Verfahren zur herstellung nickel, aluminiumoxid und zirkondioxid enthaltender katalysatorzusammensetzungen |
NL8901049A (nl) * | 1988-08-10 | 1990-03-01 | Unilever Nv | Werkwijze ter bereiding van nikkel/aluminiumoxide-katalysatoren. |
EP0582895B1 (en) * | 1988-12-07 | 1996-11-06 | Kao Corporation | Production of aliphatic primary amines |
DE3906586A1 (de) * | 1989-03-02 | 1990-09-13 | Henkel Kgaa | Verfahren zum herstellen von heterogenen katalysatoren auf der basis nanokristalliner legierungen, verwendung solcher katalysatoren fuer verschiedene reaktionen und entsprechende katalysatoren |
DE69200079T2 (de) * | 1991-01-23 | 1994-07-07 | Unichema Chemie Bv | Herstellung von Hydrogenierungskatalysatoren. |
US5356847A (en) * | 1992-11-10 | 1994-10-18 | Engelhard Corporation | Nickel catalyst |
DE4310971A1 (de) * | 1993-04-03 | 1994-10-06 | Huels Chemische Werke Ag | Nickel/Aluminiumoxid-Katalysator, Verfahren zu seiner Herstellung, seine Verwendung sowie Verfahren zur Hydrierung von aromatischen Kohlenwasserstoffen mit Hilfe des Katalysators |
US5574189A (en) * | 1995-02-02 | 1996-11-12 | Air Products And Chemicals, Inc. | Hydrogenation of nitriles to produce amines |
US6156283A (en) * | 1998-03-23 | 2000-12-05 | Engelhard Corporation | Hydrophobic catalytic materials and method of forming the same |
EP0985448A1 (en) * | 1998-08-28 | 2000-03-15 | Engelhard Corporation | Nickel catalyst |
EP1020223A3 (en) * | 1999-01-12 | 2001-09-12 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Porous material and production process thereof, catalyst comprising the porous material and process for purifying exhaust gas |
DE19909176A1 (de) * | 1999-03-03 | 2000-09-07 | Kataleuna Gmbh Catalysts | Hydrierkatalysator und Verfahren zu seiner Herstellung |
AU2001244705A1 (en) * | 2000-03-31 | 2001-10-08 | Idemitsu Kosan Co. Ltd. | Desulfurizing agent for hydrocarbon derived from petroleum, method for producinghydrogen for use in fuel cell and method for producing nickel-based desulfurizi ng agent |
GB0017839D0 (en) | 2000-07-21 | 2000-09-06 | Ici Plc | Hydrogenation catalysts |
US7433509B1 (en) * | 2001-10-09 | 2008-10-07 | Nanometrics Incorporated | Method for automatic de-skewing of multiple layer wafer for improved pattern recognition |
US20040063576A1 (en) * | 2002-09-30 | 2004-04-01 | Sud-Chemie Inc. | Catalyst adsorbent for removal of sulfur compounds for fuel cells |
EP1551550A1 (en) * | 2002-10-18 | 2005-07-13 | Engelhard Corporation | Nickel catalyst for hydrogenation reactions |
US7408089B2 (en) * | 2004-03-19 | 2008-08-05 | Catalytic Distillation Technologies | Ni catalyst, process for making catalysts and selective hydrogenation process |
US7592290B2 (en) * | 2004-04-08 | 2009-09-22 | Sulzer Metco(Canada) Inc. | Supported catalyst for stream methane reforming and autothermal reforming reactions |
US8022258B2 (en) | 2005-07-05 | 2011-09-20 | Neste Oil Oyj | Process for the manufacture of diesel range hydrocarbons |
AU2006336094B2 (en) * | 2006-01-23 | 2009-12-10 | Shell Internationale Research Maatschappij B.V. | Hydrogenation catalyst and use thereof for hydrogenating Fischer-Tropsch endproducts |
AU2007223922B2 (en) | 2006-03-07 | 2013-05-02 | Wilmar Trading Pte Ltd | Compositions comprising metathesized unsaturated polyol esters |
AU2007305255A1 (en) * | 2006-10-03 | 2008-04-10 | Wyeth | Lyophilization methods and apparatuses |
DE102007012812A1 (de) * | 2007-03-16 | 2008-09-18 | Süd-Chemie AG | Verfahren zur Entschwefelung von Kraftstoffen und dafür geeigneter hochaktiver Nickel-Trägerkatalysator auf der Basis von Aluminiumoxid |
US20080312480A1 (en) * | 2007-06-15 | 2008-12-18 | E. I. Du Pont De Nemours And Company | Catalytic process for converting renewable resources into paraffins for use as diesel blending stocks |
US20080318766A1 (en) * | 2007-06-21 | 2008-12-25 | Quaid-E-Azam University | Novel nanocatalyst for edible oil hydrogenation |
US9284515B2 (en) | 2007-08-09 | 2016-03-15 | Elevance Renewable Sciences, Inc. | Thermal methods for treating a metathesis feedstock |
WO2009050292A2 (en) * | 2007-10-19 | 2009-04-23 | Shell Internationale Research Maatschappij B.V. | Catalyst for the hydrogenation of unsaturated hydrocarbons and process for its preparation |
DE102008004135B4 (de) * | 2008-01-11 | 2014-03-06 | H.C. Starck Gmbh | Katalysatorpulver |
JP5009419B2 (ja) * | 2008-09-24 | 2012-08-22 | 新日本製鐵株式会社 | タール含有ガスの改質用触媒の製造方法、タール改質方法及びタール含有ガスの改質用触媒の再生方法 |
US20130053237A1 (en) * | 2008-10-27 | 2013-02-28 | Wen-Qing Xu | Nickel-based reforming catalyst |
CN101816938B (zh) * | 2009-02-27 | 2012-02-29 | 中国石油化工股份有限公司 | 丙酮氨化制异丙胺的催化剂及其制备方法和应用 |
KR100980591B1 (ko) * | 2009-03-16 | 2010-09-06 | 서울대학교산학협력단 | 중형기공성 니켈-알루미나 공침촉매, 그 제조방법 및 상기 촉매를 이용한 액화천연가스의 수증기 개질반응에 의한 수소 제조방법 |
CN101502802B (zh) * | 2009-03-18 | 2010-11-10 | 山西大学 | 用于顺酐加氢连续生产丁二酸酐的催化剂制备方法 |
US9051519B2 (en) | 2009-10-12 | 2015-06-09 | Elevance Renewable Sciences, Inc. | Diene-selective hydrogenation of metathesis derived olefins and unsaturated esters |
US8735640B2 (en) | 2009-10-12 | 2014-05-27 | Elevance Renewable Sciences, Inc. | Methods of refining and producing fuel and specialty chemicals from natural oil feedstocks |
US9169447B2 (en) | 2009-10-12 | 2015-10-27 | Elevance Renewable Sciences, Inc. | Methods of refining natural oils, and methods of producing fuel compositions |
WO2011046872A2 (en) | 2009-10-12 | 2011-04-21 | Elevance Renewable Sciences, Inc. | Methods of refining and producing fuel from natural oil feedstocks |
US9222056B2 (en) | 2009-10-12 | 2015-12-29 | Elevance Renewable Sciences, Inc. | Methods of refining natural oils, and methods of producing fuel compositions |
US9365487B2 (en) | 2009-10-12 | 2016-06-14 | Elevance Renewable Sciences, Inc. | Methods of refining and producing dibasic esters and acids from natural oil feedstocks |
US9000246B2 (en) | 2009-10-12 | 2015-04-07 | Elevance Renewable Sciences, Inc. | Methods of refining and producing dibasic esters and acids from natural oil feedstocks |
US9382502B2 (en) | 2009-10-12 | 2016-07-05 | Elevance Renewable Sciences, Inc. | Methods of refining and producing isomerized fatty acid esters and fatty acids from natural oil feedstocks |
US9175231B2 (en) | 2009-10-12 | 2015-11-03 | Elevance Renewable Sciences, Inc. | Methods of refining natural oils and methods of producing fuel compositions |
DE102010021792B4 (de) * | 2010-05-27 | 2022-03-31 | Clariant Produkte (Deutschland) Gmbh | Katalysatoren und Verfahren zu deren Herstellung |
JP4918610B2 (ja) * | 2010-07-22 | 2012-04-18 | 有限会社アシスト | 攪拌式融雪装置 |
WO2012128788A1 (en) | 2011-03-24 | 2012-09-27 | Elevance Renewable Sciences, Inc. | Functionalized monomers and polymers |
US9315748B2 (en) | 2011-04-07 | 2016-04-19 | Elevance Renewable Sciences, Inc. | Cold flow additives |
US8796480B2 (en) | 2011-04-28 | 2014-08-05 | Croda International Plc | Process for producing monobranched fatty acids or alkyl esters |
JP2014520207A (ja) * | 2011-06-01 | 2014-08-21 | ターゲット・テクノロジー・インターナショナル・リミテッド | 水素蓄蔵のためのニッケル合金及びそこからのエネルギーの発生 |
MY165147A (en) | 2011-12-22 | 2018-02-28 | Elevance Renewable Sciences | Methods for suppressing isomerization of olefin metathesis products , methods of refining natural oils, and methods of producing fuel compositions |
US9169174B2 (en) | 2011-12-22 | 2015-10-27 | Elevance Renewable Sciences, Inc. | Methods for suppressing isomerization of olefin metathesis products |
US9133416B2 (en) | 2011-12-22 | 2015-09-15 | Elevance Renewable Sciences, Inc. | Methods for suppressing isomerization of olefin metathesis products |
US9139493B2 (en) | 2011-12-22 | 2015-09-22 | Elevance Renewable Sciences, Inc. | Methods for suppressing isomerization of olefin metathesis products |
MX343992B (es) | 2011-12-22 | 2016-11-30 | Elevance Renewable Sciences | Metodos para suprimir la isomerizacion de productos de metátesis de olefina, metodos de refinación de aceites naturales, y metodos de producción de composiciones de combustible. |
US9012385B2 (en) | 2012-02-29 | 2015-04-21 | Elevance Renewable Sciences, Inc. | Terpene derived compounds |
CA2875606A1 (en) | 2012-06-12 | 2013-12-19 | Elevance Renewable Sciences, Inc. | Methods for suppressing dehydrogenation |
WO2013188201A1 (en) | 2012-06-12 | 2013-12-19 | Elevance Renewable Sciences, Inc. | Methods of refining natural oils, and methods of producing fuel compositions |
EA033372B1 (ru) | 2012-06-20 | 2019-10-31 | Elevance Renewable Sciences | Композиция, полученная метатезисом |
MY182542A (en) | 2012-10-09 | 2021-01-25 | Wilmar Trading Pte Ltd | Methods of refining and producing dibasic esters and acids from natural oil feedstocks |
US9388098B2 (en) | 2012-10-09 | 2016-07-12 | Elevance Renewable Sciences, Inc. | Methods of making high-weight esters, acids, and derivatives thereof |
GB201219224D0 (en) | 2012-10-25 | 2012-12-12 | Croda Int Plc | Process |
US20140171677A1 (en) | 2012-11-30 | 2014-06-19 | Elevance Renewable Sciences, Inc. | Methods of Making Functionalized Internal Olefins and Uses Thereof |
US20140256605A1 (en) | 2013-03-08 | 2014-09-11 | Elevance Renewable Sciences, Inc. | Natural oil based grease compositions and processes for making such compositions |
BR112015021070A2 (pt) | 2013-03-14 | 2017-07-18 | Elevance Renewable Sciences | métodos para refinar e produzir ésteres de ácidos graxos isomerizados e ácidos graxos a partir de matérias-primas de petróleo |
DE102013218495A1 (de) | 2013-09-16 | 2015-03-19 | Henkel Ag & Co. Kgaa | Fügeverfahren |
WO2015061032A1 (en) | 2013-10-22 | 2015-04-30 | Elevance Renewable Sciences, Inc. | Polyester polyols and methods of making and using the same |
FR3022162B1 (fr) | 2014-06-13 | 2021-05-07 | Ifp Energies Now | Catalyseur a base de nickel mesoporeux et macroporeux ayant un diametre median macroporeux compris entre 50 nm et 200 nm et son utilisation en hydrogenation |
FR3022163B1 (fr) * | 2014-06-13 | 2021-05-07 | Ifp Energies Now | Catalyseur a base de nickel mesoporeux et macroporeux ayant un diametre median macroporeux superieur a 200 nm et son utilisation en hydrogenation |
FR3022160B1 (fr) * | 2014-06-13 | 2021-05-07 | Ifp Energies Now | Catalyseur a phase active de nickel comalaxee mesoporeux et macroporeux ayant un diametre median macroporeux compris entre 50 et 300 nm et son utilisation en hydrogenation |
FR3022161B1 (fr) * | 2014-06-13 | 2021-05-07 | Ifp Energies Now | Catalyseur a phase active de nickel comalaxee mesoporeux et macroporeux ayant un diametre median macroporeux superieur a 300 nm et son utilisation en hydrogenation |
FR3025728B1 (fr) * | 2014-09-11 | 2018-04-20 | IFP Energies Nouvelles | Catalyseur mesoporeux a base de nickel et son utilisation en hydrogenation. |
JP2016124963A (ja) * | 2014-12-26 | 2016-07-11 | ミヨシ油脂株式会社 | 食用油脂中のクロロプロパノール類を低減する方法 |
KR102436299B1 (ko) * | 2020-09-16 | 2022-08-26 | 울산대학교 산학협력단 | 다공성 알루미나 담체에 담지된 니켈을 포함하는 복합체 및 이의 제조방법 |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE143867C (ko) * | ||||
DE729290C (de) * | 1936-02-26 | 1942-12-15 | Ig Farbenindustrie Ag | Verfahren zur Umsetzung von Kohlenoxyd und Wasserstoff |
GB510698A (en) * | 1937-11-30 | 1939-07-31 | Intermetal Corp | Improvements in or relating to the production of hydrogenated oils and semi-solid fats, and the products thereof |
US2645620A (en) * | 1947-11-01 | 1953-07-14 | Lever Brothers Ltd | Nickel-alumina-silica catalysts and their preparation |
US2566362A (en) * | 1947-11-01 | 1951-09-04 | Lever Brothers Ltd | Hardening and decolorizing glyceride oils with nickel-alumina-silica catalysts |
US2921971A (en) * | 1956-03-14 | 1960-01-19 | Phillips Petroleum Co | Process and catalyst for the poly-merization of olefins |
US2926207A (en) * | 1956-12-31 | 1960-02-23 | Pure Oil Co | Isomerization catalysts and process |
US3320182A (en) * | 1963-10-21 | 1967-05-16 | Exxon Research Engineering Co | High activity nickel-alumina catalyst |
US3421870A (en) * | 1964-02-17 | 1969-01-14 | Exxon Research Engineering Co | Low-temperature catalytic hydrogen-olysis of hydrocarbons to methane |
US4113658A (en) * | 1967-04-14 | 1978-09-12 | Stamicarbon, N.V. | Process for homogeneous deposition precipitation of metal compounds on support or carrier materials |
GB1367088A (en) * | 1970-12-21 | 1974-09-18 | Unilever Ltd | Catalysts |
GB1400719A (en) * | 1971-12-17 | 1975-07-23 | Unilever Ltd | Supported nickel catalysts |
US3793388A (en) * | 1972-05-30 | 1974-02-19 | Phillips Petroleum Co | Selective hydrogenation of acetylene from olefins with a nickel on alumina catalyst |
DE2228332B2 (de) * | 1972-06-10 | 1978-09-28 | Basf Ag, 6700 Ludwigshafen | Verfahren zur selektiven Härtung von Fetten und ölen |
GB1525017A (en) * | 1975-09-29 | 1978-09-20 | British Gas Corp | Steam reforming and methanation catalysts methods of making them and processes for the production of fuel gases |
US4065484A (en) * | 1975-11-12 | 1977-12-27 | Union Oil Company Of California | Methanation process with intermittent reactivation of catalyst |
US4016107A (en) * | 1976-01-05 | 1977-04-05 | Exxon Research And Engineering Company | Preparation of catalysts of predetermined pore size distribution and pore volume |
DD143843B1 (de) * | 1979-05-22 | 1982-12-29 | Heinz Kasten | Schwellwertschalter mit konstanter verzoegerungszeit |
US4273680A (en) * | 1979-11-06 | 1981-06-16 | Exxon Research & Engineering Co. | Supported non-ferrous group VIII aluminate coprecipitated hydrogenation catalysts and process for their preparation |
US4307248A (en) * | 1979-11-06 | 1981-12-22 | Exxon Research & Engineering Co. | Process for hydrogenating organic compounds by use of non-ferrous group VIII aluminum coprecipitated catalysts |
NL8201696A (nl) * | 1982-04-23 | 1983-11-16 | Unilever Nv | Werkwijze ter bereiding van methaneringskatalysatoren. |
IN159334B (ko) * | 1982-06-16 | 1987-05-02 | Exxon Research Engineering Co | |
NL191511C (nl) * | 1983-01-20 | 1995-08-21 | Unilever Nv | Werkwijze voor de bereiding van een nikkel-bevattende katalysator. |
NL190750C (nl) * | 1984-06-21 | 1994-08-01 | Unilever Nv | Nikkelaluminaat katalysator, de bereiding daarvan en het hydrogeneren van onverzadigde organische verbindingen daarmee. |
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