KR850006433A - 방사선에 안정한 폴리프로필렌 수지 조성물 - Google Patents
방사선에 안정한 폴리프로필렌 수지 조성물 Download PDFInfo
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- KR850006433A KR850006433A KR1019850001613A KR850001613A KR850006433A KR 850006433 A KR850006433 A KR 850006433A KR 1019850001613 A KR1019850001613 A KR 1019850001613A KR 850001613 A KR850001613 A KR 850001613A KR 850006433 A KR850006433 A KR 850006433A
- Authority
- KR
- South Korea
- Prior art keywords
- polypropylene resin
- resin composition
- phosphite
- weight
- peroxide
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
- C08K5/526—Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/14—Materials characterised by their function or physical properties, e.g. injectable or lubricating compositions, shape-memory materials, surface modified materials
- A61L31/143—Stabilizers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/156—Heterocyclic compounds having oxygen in the ring having two oxygen atoms in the ring
- C08K5/1575—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Vascular Medicine (AREA)
- Surgery (AREA)
- Heart & Thoracic Surgery (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (11)
- 폴리프로필렌 수지 (a), 하기 구조식(I)을 갖는 소르비톨 유도체(b), 하기 구조식(II)를 갖는 포스파이트 화합물(c) 및 하기 구조식(III)을 갖는 폴리아민 화합물(d)로 구성되고 화합물(b), (c) 및 (d)의 함량이 폴리프로필렌 수지(a)의 100중량부에 대해 각각 0.005 내지 8중량부, 0.01 내지 4중량부 및 0.01 내지 4중량부인 우수한 투명성을 갖는 방사선에 안정한 폴리프로필렌 수지 조성물 :상기에서,R은 수소원자 또는 탄소원자 1 내지 18의 알킬기이고;R1은 3차 부틸, 1,1-디메틸프로필, 시클로헥실 또는 페닐기이고;R2는 수소원자 또는 메틸, 3차 부틸, 1,1-디메틸프로필, 시클로헥실 또는 페닐기이고;n은 평균 1 내지 40의 정수이다.
- 제 1 항에 있어서, 유기 과산화물(e)를 더 포함하는 것을 특징으로 하는 방사선에 안정한 폴리프로필렌 수지 조성물.
- 제 1 항에 있어서, 수지 조성물이 유기 과산화물 존재하에 190°내지 270℃에서 열적 저하되는 것을 특징으로 하는 방사선에 안정한 폴리프로필렌 수지 조성물.
- 제 1 항에 있어서, 폴리프로필렌 수지가 폴리프로필렌 단일중합체, 에틸렌 0.1 내지 7중량%를 함유하는 프로필렌-에틸렌 공중함체 또는 α-올레핀 0.1 내지 20중량%를 함유하는 프로필렌-α-올레핀 공중합체인 것을 특징으로 하는 방사선에 안정한 폴리프로필렌 수지 조성물.
- 제 1 항에 있어서, 소르비톨 유도체 (b)가 디벤질리덴 소르비톨, 1.3,2.4-디(메틸벤질리덴)소르비톨 또는 1.3,2.4-디(헥실벤질리덴)소르비톨인 것을 특징으로 하는 방사선에 안정한 폴리프로필렌 수지 조성물.
- 제 1 항에 있어서, 소르비톨 유도체(b)의 함량이 폴리프로필렌 수지 100중량부당 0.05 내지 1중량부인 것을 특징으로 하는 방사선에 안정한 폴리프로필렌 수지 조성물.
- 제 1 항에 있어서, 포스파이트 화합물(c)가 트리스(2,5-디-t-부틸페닐)포스파이트, 트리스(2-t-부틸페닐)포스파이트, 트리스[2-(1,1-디메틸프로필)페닐]포스파이트, 트리스(2-페닐페닐)포스파이트, 트리스(2-시클로헥실페닐)포스파이트, 트리스(2,4-디-t-부틸페닐)포스파이트 또는 트리스(2-t-부틸-4-페닐)포스파이트인 것을 특징으로 하는 방사선에 안정한 폴리프로필렌 수지 조성물.
- 제 1 항에 있어서, 포스파이트 화합물(c)의 함량이 폴리프로필렌 수지(a)의 100중량부당 0.02 내지 2중량부인 것을 특징으로 하는 방사선에 안정한 폴리프로필렌 수지 조성물.
- 제 1 항에 있어서, 폴리아민 화합물(d)의 함량이 폴리프로필렌 수지(a)의 100중량부당 0.02 내지 2중량부인 것을 특징으로 하는 방사선에 안정한 폴리프로필렌 수지 조성물.
- 제 2 항에 있어서, 유기 과산화물(e)의 t-부틸퍼록시피발레이트, 라우로일퍼록사이드, 벤조일퍼록사이드, 시클로헥사논퍼록사이드, t-부틸퍼록시이소프로필카르보네이트, t-부틸퍼록시벤조에이트, 메틸에틸케톤퍼록사이드, 디큐밀퍼록사이드, 2,5-디메틸-2,5-디-(t-부틸퍼록시)헥산, 디-t-부틸퍼록사이드, 또는 2,5-디메틸-2,5-디(t-부틸퍼록시)헥신-3인 것을 특징으로 하는 방사선에 안정한 폴리프로필렌 수지 조성물.
- 제 3 항에 있어서, 유기 과산화물(e)이 t-부틸 퍼록시피발레이트, 라우로일퍼록사이드, 벤조일퍼록사이드, 시클로헥사논퍼록사이드, t-부틸퍼록시이소프로필카보네이트, t-부틸퍼록시벤조에이트, 메틸에틸케톤퍼록사이드, 디큐밀퍼록사이드, 2,5-디메틸-2,5-디-(t-부틸퍼록시)헥산, 디-t-부틸퍼록사이드, 또는 2,5-디메틸-2,5-디(t-부틸퍼록시)헥신-3인 것을 특징으로 하는 방사선에 안정한 폴리프로필렌 수지 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP46522 | 1984-03-13 | ||
JP46522/83 | 1984-03-13 | ||
JP4652284A JPS60190443A (ja) | 1984-03-13 | 1984-03-13 | 放射線に安定なポリプロピレン樹脂組成物 |
JP69197 | 1984-04-09 | ||
JP59069197A JPS60212442A (ja) | 1984-04-09 | 1984-04-09 | 放射線に安定なポリプロピレン樹脂組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR850006433A true KR850006433A (ko) | 1985-10-05 |
KR870002104B1 KR870002104B1 (ko) | 1987-12-08 |
Family
ID=26386616
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019850001613A KR870002104B1 (ko) | 1984-03-13 | 1985-03-13 | 방사선에 안정한 폴리프로필렌 수지 조성물 |
Country Status (9)
Country | Link |
---|---|
KR (1) | KR870002104B1 (ko) |
AU (1) | AU552479B2 (ko) |
CA (1) | CA1254339A (ko) |
DE (1) | DE3508983A1 (ko) |
FR (1) | FR2561247B1 (ko) |
GB (1) | GB2156360B (ko) |
IT (1) | IT1184148B (ko) |
NL (1) | NL8500696A (ko) |
PT (1) | PT80096B (ko) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0243319A3 (de) * | 1986-04-25 | 1989-02-15 | Ciba-Geigy Ag | Gegen Lichteinwirkung stabilisierte Thermoplasten |
EP0303894A3 (en) * | 1987-08-18 | 1991-03-20 | American Cyanamid Company | Radiation sterilizable composition and articles made therefrom |
JPH032239A (ja) * | 1989-05-31 | 1991-01-08 | Mitsubishi Petrochem Co Ltd | 有色食品用成形品 |
US5219600A (en) * | 1989-05-31 | 1993-06-15 | Mitsubishi Petrochemical Co., Ltd. | Molded product for colored food |
US4959402A (en) * | 1989-06-08 | 1990-09-25 | Becton, Dickinson And Company | High clarity radiation stable polymeric compostion and articles therefrom |
GB2261667A (en) * | 1991-11-20 | 1993-05-26 | Sandoz Ltd | Stabilized polymeric compositions |
US5342978A (en) * | 1993-05-24 | 1994-08-30 | General Electric Company | Organic phosphite ester compositions containing hindered piperdinyl light stabilizers |
GB0005629D0 (en) * | 2000-03-10 | 2000-05-03 | Clariant Int Ltd | Light stabilizer composition |
FR2866892B1 (fr) * | 2004-02-27 | 2007-09-21 | Arkema | Composition de peroxyde organique et alcool pour la reticulation des elastomeres |
WO2008024154A1 (en) * | 2006-08-22 | 2008-02-28 | Exxonmobil Chemical Patents Inc. | High clarity polymer compositions, methods and articles made therefrom |
BR112017002362B1 (pt) * | 2014-08-08 | 2021-11-03 | Braskem America, Inc. | Composição, método para preparação e uso de uma composição, e, artigo fabricado |
GB201812145D0 (en) | 2018-07-25 | 2018-09-05 | Addivant Switzerland Gmbh | Composition |
GB2591482A (en) | 2020-01-29 | 2021-08-04 | Si Group Switzerland Chaa Gmbh | Non-dust blend |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5122740A (ko) * | 1974-08-16 | 1976-02-23 | Kenzo Hamada | |
NO146433C (no) * | 1975-03-21 | 1982-09-29 | Montefibre Spa | Stabilisert polyolefinmateriale inneholdende et polyamin som stabilisator |
SE398498B (sv) * | 1976-05-03 | 1977-12-27 | Strabruken Ab | Eldfast massa avsedd for anvendning i metallurgiska ugnar som stamp- eller avlagningsmassa eller efter pressning och/eller vibrering som tegel, vilken massa bestar av en blandning omfattande eldfast material ... |
IT1165130B (it) * | 1979-06-28 | 1987-04-22 | Montedison Spa | Policondensati di piperidine sostituite e loro impiego come stabilizzanti per polimeri |
JPS5630449A (en) * | 1979-08-21 | 1981-03-27 | Mitsui Toatsu Chem Inc | Polypropylene composition |
IT1151035B (it) * | 1980-07-31 | 1986-12-17 | Chimosa Chimica Organica Spa | Piperidil-derivati di copolimeri triazinici,processi per la loro preparazione e composizioni stabilizzate che li comprendono |
JPS5892660A (ja) * | 1981-11-27 | 1983-06-02 | Adeka Argus Chem Co Ltd | ピペリジルアミン化合物 |
JPS58180543A (ja) * | 1982-04-19 | 1983-10-22 | Mitsubishi Petrochem Co Ltd | プロピレン重合体組成物 |
JPS58185632A (ja) * | 1982-04-23 | 1983-10-29 | Iic Kagaku Kogyo Kk | ポリオレフイン樹脂組成物 |
-
1985
- 1985-02-22 CA CA000474969A patent/CA1254339A/en not_active Expired
- 1985-03-04 GB GB08505499A patent/GB2156360B/en not_active Expired
- 1985-03-06 AU AU39571/85A patent/AU552479B2/en not_active Ceased
- 1985-03-11 IT IT19844/85A patent/IT1184148B/it active
- 1985-03-12 FR FR8503614A patent/FR2561247B1/fr not_active Expired
- 1985-03-12 PT PT80096A patent/PT80096B/pt not_active IP Right Cessation
- 1985-03-12 NL NL8500696A patent/NL8500696A/nl not_active Application Discontinuation
- 1985-03-13 KR KR1019850001613A patent/KR870002104B1/ko not_active IP Right Cessation
- 1985-03-13 DE DE19853508983 patent/DE3508983A1/de not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
IT1184148B (it) | 1987-10-22 |
NL8500696A (nl) | 1985-11-01 |
FR2561247B1 (fr) | 1987-12-11 |
IT8519844A0 (it) | 1985-03-11 |
GB8505499D0 (en) | 1985-04-03 |
PT80096A (en) | 1985-04-01 |
AU552479B2 (en) | 1986-06-05 |
AU3957185A (en) | 1985-09-19 |
PT80096B (en) | 1986-11-20 |
GB2156360B (en) | 1987-07-01 |
CA1254339A (en) | 1989-05-16 |
DE3508983A1 (de) | 1985-09-26 |
KR870002104B1 (ko) | 1987-12-08 |
GB2156360A (en) | 1985-10-09 |
FR2561247A1 (fr) | 1985-09-20 |
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