KR850004776A - 가교결합 중합체의 제조방법 - Google Patents

가교결합 중합체의 제조방법 Download PDF

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Publication number
KR850004776A
KR850004776A KR1019840007853A KR840007853A KR850004776A KR 850004776 A KR850004776 A KR 850004776A KR 1019840007853 A KR1019840007853 A KR 1019840007853A KR 840007853 A KR840007853 A KR 840007853A KR 850004776 A KR850004776 A KR 850004776A
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vinyl
weight
polymer
dispersion medium
crosslinker
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KR1019840007853A
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KR920006761B1 (ko
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마우즈(외2) 오토
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하인리히벡커, 베른하루트 벡크
훽스트 아크티엔게젤샤프트
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    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/48—Biological material, e.g. blood, urine; Haemocytometers
    • G01N33/50—Chemical analysis of biological material, e.g. blood, urine; Testing involving biospecific ligand binding methods; Immunological testing
    • G01N33/53—Immunoassay; Biospecific binding assay; Materials therefor
    • G01N33/543—Immunoassay; Biospecific binding assay; Materials therefor with an insoluble carrier for immobilising immunochemicals
    • G01N33/54353—Immunoassay; Biospecific binding assay; Materials therefor with an insoluble carrier for immobilising immunochemicals with ligand attached to the carrier via a chemical coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters
    • C08F218/08—Vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/12—Hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N11/00—Carrier-bound or immobilised enzymes; Carrier-bound or immobilised microbial cells; Preparation thereof
    • C12N11/02—Enzymes or microbial cells immobilised on or in an organic carrier
    • C12N11/08—Enzymes or microbial cells immobilised on or in an organic carrier the carrier being a synthetic polymer
    • C12N11/082—Enzymes or microbial cells immobilised on or in an organic carrier the carrier being a synthetic polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently

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  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Immunology (AREA)
  • Biomedical Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Genetics & Genomics (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Microbiology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biotechnology (AREA)
  • Polymers & Plastics (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Urology & Nephrology (AREA)
  • Hematology (AREA)
  • General Engineering & Computer Science (AREA)
  • Pathology (AREA)
  • General Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Food Science & Technology (AREA)
  • Cell Biology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
  • Medicinal Preparation (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Polymerisation Methods In General (AREA)
  • Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Filtering Materials (AREA)

Abstract

내용 없음

Description

가교결합 중합체의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. 분산 매질의 존재하에 비닐 아실레이트를 하기 일반식(Ⅰ) 및/또는 (Ⅱ)를 갖는 가교결합제와 공중합시키고, 필요하다면 생성중합체를 부분적으로 또는 완전히 가수분해 시킴으로서 가교결합 중합체를 제조하는 방법.
    상기식에서, R1및 R2는 동일하거나 다를 수 있으며 각각 비닐, 1-아실옥시비닐, 알릴 또는 2-아실옥시알릴을 나타내며, A는 탄소수 2 내지 8의 2가의 탄화수소 라디칼을 나타내고 B는 탄소수 1내지 8의 2가, 3가 또는 4가의 탄화수소 라디칼을 나타내며, m은 상기 B라디칼의 원자가에 해당되고 X는 아실옥시를 나타낸다.
  2. 제1항에 있어서, 가교결합제 단위의 양이 중합체의 0.1내지 60중량%인 방법.
  3. 제1 또는 2항에 있어서, 비닐아실레이트가 비닐아세테이트인 방법.
  4. 제1,2 또는 3항에 있어서, 일반식(Ⅰ)의 R1및 R2라디칼중의 아실옥시잔기 또는 일반식(Ⅱ)중의 아실옥시 라디칼이 탄소수 2 내지 6을 갖는 방법.
  5. 제1내지 4항중 어느하나에 있어서, 일반식(Ⅰ)중의 라디칼 R1/R2가 각각 비닐을 나타내는 방법.
  6. 제1 내지 5항중 어느 하나에 있어서, 가교결합제단위의 양이 1내지 50중량%인 방법.
  7. 제1 내지 6항중 어느 하나에 있어서, 가교결합제 단위의 양이 1 내지 40중량%인 방법.
  8. 제1 내지 7항중 어느하나에 있어서, 비닐아실레이트 단위중의 아실옥시잔기 적어도 10중량%를 히드록실기로 치환시키는 방법.
  9. 제1 내지 8항중 어느하나에 있어서, 비닐아세테이트와 공중합가능한 추가의 단량체가 또한 존재하는 방법.
  10. 제1 내지 9항중 어느 하나에 있어서, 중합을 비이드(bead) 중합으로서 수행하는 방법.
  11. 제10항에 있어서, 분산 매질이알 칼리성 완충 수용액인 방법.
  12. 제11항에 있어서, 분산 매질이 전해질 0내지 50중량%를 함유하는 방법.
  13. 제10내지 12항중 어느하나에 있어서, 분산 매질이 분산 안정화제로서 비이온성 계면활성제를 함유하는 방법.
  14. 제1 내지 13항중 어느 하나에 있어서, 중합을 불환성 희석제로서 적어도 탄소수 6의 디알킬에테르의 존재하에 수행하는 방법.
  15. 제8항에 있어서, 비닐아실기를 함유하는 중합체를 가수분해 처리하여 아실레이트기의 70%이상을 OH기로 치환시켜 가교결합될 중합체를 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840007853A 1983-12-13 1984-12-12 가교결합 중합체의 제조방법 KR920006761B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19833344912 DE3344912A1 (de) 1983-12-13 1983-12-13 Vernetzte polymerisate, verfahren zu ihrer herstellung und ihre anwendung
DEP3344912.0 1983-12-13

Publications (2)

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KR850004776A true KR850004776A (ko) 1985-07-27
KR920006761B1 KR920006761B1 (ko) 1992-08-17

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Country Link
US (2) US4906715A (ko)
EP (1) EP0150350B1 (ko)
JP (2) JPS60152518A (ko)
KR (1) KR920006761B1 (ko)
AR (1) AR244264A1 (ko)
AT (1) ATE40388T1 (ko)
AU (1) AU569353B2 (ko)
BR (1) BR8406380A (ko)
CA (1) CA1241146A (ko)
DE (2) DE3344912A1 (ko)
DK (1) DK167152B1 (ko)
ES (1) ES538489A0 (ko)
FI (1) FI85028C (ko)
GR (1) GR81231B (ko)
HU (1) HU199519B (ko)
IE (1) IE58209B1 (ko)
IL (1) IL73793A (ko)
NO (1) NO166188C (ko)
NZ (1) NZ210512A (ko)
PH (1) PH21340A (ko)
PT (1) PT79659B (ko)
ZA (1) ZA849660B (ko)

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ES2156307T3 (es) * 1995-12-28 2001-06-16 Eco Solutions Ltd Composicion acuosa para plastificar pintura con anterioridad a su decapado.
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KR102081560B1 (ko) * 2012-02-09 2020-02-25 라이프 테크놀로지스 코포레이션 친수성 중합체성 입자 및 그의 제조 방법
CN107106932B (zh) * 2015-01-15 2021-05-25 戴安公司 具有改进的pH稳定性的色谱材料、其制备方法和其用途
EP3702383B1 (en) 2015-07-02 2023-12-27 Life Technologies Corporation Polymer substrates formed from carboxy functional acrylamide
CN108659428A (zh) * 2018-05-23 2018-10-16 宁波宝亭生物科技有限公司 一种聚乙烯醇水凝胶的制备方法

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Also Published As

Publication number Publication date
JPS60152518A (ja) 1985-08-10
ATE40388T1 (de) 1989-02-15
ES8600776A1 (es) 1985-11-01
DK167152B1 (da) 1993-09-06
JPH05279411A (ja) 1993-10-26
IE58209B1 (en) 1993-08-11
FI85028C (fi) 1992-02-25
FI85028B (fi) 1991-11-15
HUT38374A (en) 1986-05-28
EP0150350A3 (en) 1985-08-21
HU199519B (en) 1990-02-28
AR244264A1 (es) 1993-10-29
DK594884D0 (da) 1984-12-12
DK594884A (da) 1985-06-14
EP0150350B1 (de) 1989-01-25
ZA849660B (en) 1985-07-31
DE3344912A1 (de) 1985-06-20
IL73793A0 (en) 1985-03-31
NZ210512A (en) 1987-11-27
BR8406380A (pt) 1985-10-08
AU3657384A (en) 1985-06-20
ES538489A0 (es) 1985-11-01
JPH0554379B2 (ko) 1993-08-12
PH21340A (en) 1987-10-13
DE3476405D1 (en) 1989-03-02
NO166188B (no) 1991-03-04
AU569353B2 (en) 1988-01-28
US5079156A (en) 1992-01-07
NO844994L (no) 1985-06-14
EP0150350A2 (de) 1985-08-07
IE843192L (en) 1985-06-13
DE3344912C2 (ko) 1989-10-05
JPH0689055B2 (ja) 1994-11-09
PT79659B (de) 1986-11-18
KR920006761B1 (ko) 1992-08-17
FI844889L (fi) 1985-06-14
PT79659A (de) 1985-01-01
IL73793A (en) 1989-09-28
GR81231B (en) 1985-04-17
NO166188C (no) 1991-06-12
US4906715A (en) 1990-03-06
CA1241146A (en) 1988-08-23
FI844889A0 (fi) 1984-12-11

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