KR840001185A - 양이온 교환수지의 제조방법 - Google Patents
양이온 교환수지의 제조방법 Download PDFInfo
- Publication number
- KR840001185A KR840001185A KR1019820003757A KR820003757A KR840001185A KR 840001185 A KR840001185 A KR 840001185A KR 1019820003757 A KR1019820003757 A KR 1019820003757A KR 820003757 A KR820003757 A KR 820003757A KR 840001185 A KR840001185 A KR 840001185A
- Authority
- KR
- South Korea
- Prior art keywords
- styrene
- exchange resin
- cation exchange
- sulfonation reaction
- divinylbenzene
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 7
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 title claims 4
- 239000003729 cation exchange resin Substances 0.000 title claims 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 10
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims 8
- 238000006277 sulfonation reaction Methods 0.000 claims 5
- 239000000178 monomer Substances 0.000 claims 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 3
- 125000005907 alkyl ester group Chemical group 0.000 claims 3
- 239000003795 chemical substances by application Substances 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- 238000004519 manufacturing process Methods 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- 239000002245 particle Substances 0.000 claims 3
- 230000008961 swelling Effects 0.000 claims 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- -1 aromatic halogenated hydrocarbons Chemical class 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 2
- 239000003960 organic solvent Substances 0.000 claims 2
- 238000010557 suspension polymerization reaction Methods 0.000 claims 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/16—Organic material
- B01J39/18—Macromolecular compounds
- B01J39/20—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/34—Introducing sulfur atoms or sulfur-containing groups
- C08F8/36—Sulfonation; Sulfation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/20—Manufacture of shaped structures of ion-exchange resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (9)
- (1( 스티렌, (2) 디비닐벤젠 및 (3) 아크릴산, 메타크릴산 및 이들의 저급알킬 에스테르의 군으로부터 선택된 1개이상의 화합물로 이루어진 단량체 혼합물을 현탁중합시키고, 또 수득된 공중합체 입자를 설폰화반응시킴을 특징으로 하여, 양이온 교환수지를 제조하는 방법.
- 제1항에 있어서, 단량체(3)의 양이 스티렌 1몰당 2내지 20몰%인 방법.
- 제1항에 있어서, 디비닐벤젠의 양이 스티렌 1몰당 0.8 내지 55몰%인 방법.
- 제1항에 있어서, 공중합체 입자가 0.1 내지 1.Omm의 입자직경을 갖는 방법.
- 제1항에 있어서, 95 내지 100% 황산을 사용하여 설폰화반응을 진행시키는 방법.
- (1) 스티렌, (2) 디비닐벤젠 및 (3) 아크릴산, 메타크릴산 및 이들의저급알킬에스테르의 군으로부터 선택된 1개이상의 화합물로 이루어진 단량체 혼합물을 현탁중합 시키고 또 수득된 공중합체 입자를, 유기용매로 구성된 팽윤제가 없는 상태에서 설폰화반응 시킴을 특징으로 하여, 양이온교환 수지를 제조하는 방법.
- 제6항에 있어서, 설폰화반응 온도가 50 내지 150℃인 방법.
- (1) 스티렌, (2) 디비닐벤젠 및 (3) 아크릴산, 메타크릴산 및 이들의 저급알킬에스테르 군으로부터 선택된 1개이상의 화합물로 이루어진 단량체 혼합물을 현탁 중합시키고, 또 수득된 공중합체 입자를 유기용매로 구성된 팽윤제 존제하에서 약 50 내지 100℃로 설폰화반응시킴을 특징으로 하여 양이온 교환수지를 제조하는 방법.
- 제8항에 있어서, 팽윤제가 방향족 탄화수소, 방향족 할로겐화 탄화수소와 지방족 할로겐화 탄화수소의 군에서 선택된 1개이상의 유기용매인 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP131356/81 | 1981-08-21 | ||
JP13156 | 1981-08-21 | ||
JP56131356A JPS6050361B2 (ja) | 1981-08-21 | 1981-08-21 | 陽イオン交換樹脂の製造法 |
JP57070652A JPS58187405A (ja) | 1982-04-27 | 1982-04-27 | 強酸性陽イオン交換樹脂の製造法 |
JP70652 | 1982-04-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR840001185A true KR840001185A (ko) | 1984-03-28 |
KR890001758B1 KR890001758B1 (ko) | 1989-05-19 |
Family
ID=26411786
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR8203757A KR890001758B1 (ko) | 1981-08-21 | 1982-08-21 | 양이온 교환수지의 제조방법 |
Country Status (5)
Country | Link |
---|---|
KR (1) | KR890001758B1 (ko) |
DE (1) | DE3230559A1 (ko) |
FR (1) | FR2511614B1 (ko) |
GB (1) | GB2105346B (ko) |
NL (1) | NL8203274A (ko) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2587708B1 (fr) * | 1985-09-20 | 1988-03-18 | Ceca Sa | Copolymeres d'acides styrene sulfoniques a stabilite thermique amelioree. application, notamment aux fluides forage |
CA2061250A1 (en) * | 1991-02-20 | 1992-08-21 | Nobuyuki Higosaki | Process of removing suspended metal corrosion products insoluble or sparingly soluble in water and condensate treating equipment |
US6784213B2 (en) * | 2001-06-22 | 2004-08-31 | Rohm And Haas Company | Method for preparation of strong acid cation exchange resins |
DE10353534A1 (de) * | 2003-11-14 | 2005-06-16 | Bayer Chemicals Ag | Chelataustauscher |
DE102007060790A1 (de) | 2007-12-18 | 2009-06-25 | Lanxess Deutschland Gmbh | Verfahren zur Herstellung von Kationenaustauschern |
KR101294632B1 (ko) * | 2011-04-28 | 2013-08-09 | 충남대학교산학협력단 | 팽윤성이 우수한 코발트 이온 회수용 이온교환수지 및 이를 제조하는 방법 |
KR101294631B1 (ko) * | 2011-04-28 | 2013-08-09 | 충남대학교산학협력단 | 팽윤성과 흡착성이 우수한 인듐회수용 이온교환수지 및 이를 제조하는 방법 |
CN108623733A (zh) * | 2017-03-24 | 2018-10-09 | 鹤壁市山城区牟山大道大唐离子交换树脂应用研究所 | 含有第三单体的树脂中间体 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1068153A (fr) * | 1951-11-28 | 1954-06-23 | Rohm & Haas | Perfectionnements relatifs à une résine insoluble échangeuse de cations et à sonprocédé de préparation |
DE1155603B (de) * | 1961-10-26 | 1963-10-10 | Wolfen Filmfab Veb | Verfahren zur Herstellung von sulfonsaeuregruppenhaltigen Kationenaustauscherharzen |
-
1982
- 1982-08-17 GB GB08223643A patent/GB2105346B/en not_active Expired
- 1982-08-17 DE DE19823230559 patent/DE3230559A1/de not_active Withdrawn
- 1982-08-20 FR FR8214418A patent/FR2511614B1/fr not_active Expired
- 1982-08-20 NL NL8203274A patent/NL8203274A/nl not_active Application Discontinuation
- 1982-08-21 KR KR8203757A patent/KR890001758B1/ko active
Also Published As
Publication number | Publication date |
---|---|
KR890001758B1 (ko) | 1989-05-19 |
GB2105346B (en) | 1985-01-03 |
NL8203274A (nl) | 1983-03-16 |
DE3230559A1 (de) | 1983-03-03 |
FR2511614A1 (fr) | 1983-02-25 |
GB2105346A (en) | 1983-03-23 |
FR2511614B1 (fr) | 1987-05-07 |
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