KR830006148A - 디 올레핀을 선택적으로 수소화하는 방법 - Google Patents

디 올레핀을 선택적으로 수소화하는 방법 Download PDF

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KR830006148A
KR830006148A KR1019810001785A KR810001785A KR830006148A KR 830006148 A KR830006148 A KR 830006148A KR 1019810001785 A KR1019810001785 A KR 1019810001785A KR 810001785 A KR810001785 A KR 810001785A KR 830006148 A KR830006148 A KR 830006148A
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silver
palladium
process according
hydrogen
diolefins
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KR1019810001785A
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KR850001062B1 (ko
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코신스 쟝
두란드 다니엘
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쟝 꼴라스 데스 프랑솨스
인스티투트 프랑솨스 두 페트롤레
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/08—Alkenes with four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/40—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/163—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/48—Silver or gold
    • C07C2523/50—Silver

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

내용 없음

Description

디올레핀을 선택적으로 수소화하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

1-올레핀의 실질적인 이성화 및 수소화가 없이 축매가 팔라듐 농도가 무게비로 0.05에서 0.5%이고 은 농도가 0.05에서 1%이며 수소/디올레핀 몰랄비가 1/1에서 5/1인 팔라듐 혹은 팔라듐 화합물과은 혹은 은 화합물을 동시에 포괄한 지지된 촉매로 되는데에 특징이 있는 최소한 4탄소원자를 지닌 탄화수소 및 디올레핀에 덧붙여서 1-디올레핀으로 구성되는 혼합물을 촉매의 접촉과 더불어서 수소를 접촉시키는 디올레핀을 선택적으로 수소화하는 방법.
수소/디올레핀 몰랄비가 1/1에서 2/1인 청구범위에 따르는 방법.
은/팔라듐비가 무게비로 0.7/1에서 3/1인 청구범위 1혹은 2에 따르는 방법.
은/팔라듐비가 무게비로 1/1에서 2.5/1인 청구범위 1 혹은 2에 따르는 방법.
매개물이 100㎡/g보다 적은 특히 표면적의 알루미나인 청구범위 1에 따르는 방법.
매개물이 10과 200㎡/g사이의 특히 표면적의 실리카인 청구범위 1에 따르는 방법.
탄화수소 혼합물이 부라디엔 및 1-부텐으로 구성되는 C4컬인 청구범위 1에서 6중의 하나에 따르는 방법.
조작이 0-80℃로 액체상태에서 3-20바아로 시간당 축매부피당 2에서 50부피의 약체 원료공급속도로 수행하는 청구범위 1에서 7중의 하나에 따르는 방법.
촉매가 팔라듐과 은 촉매 금속을 매개물에 포괄하고 공기중에서 200-900℃로 경소하여서 얻을 수 있는 청구범위 1에서 8중의 하나에 따르는 방법.
경소가 0-200℃로 수소환원으로 수반되는 청구범위 9에 따르는 방법.
※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019810001785A 1980-05-22 1981-05-22 디올레핀을 선택적으로 수소화하는 방법 KR850001062B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR8011480A FR2482953A1 (fr) 1980-05-22 1980-05-22 Procede d'hydrogenation selective d'une di-olefine dans un melange d'hydrocarbures renfermant au moins 4 atomes de carbone et contenant une olefine -a
FR80/11480 1980-05-22
US06/347,127 US4409410A (en) 1980-05-22 1982-02-09 Process for selectively hydrogenating a di-olefin in a mixture of hydrocarbons having at least 4 carbon atoms and comprising an α-olefin

Publications (2)

Publication Number Publication Date
KR830006148A true KR830006148A (ko) 1983-09-17
KR850001062B1 KR850001062B1 (ko) 1985-07-25

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KR1019810001785A KR850001062B1 (ko) 1980-05-22 1981-05-22 디올레핀을 선택적으로 수소화하는 방법

Country Status (5)

Country Link
US (1) US4409410A (ko)
JP (1) JPS5718785A (ko)
KR (1) KR850001062B1 (ko)
DE (1) DE3119850A1 (ko)
FR (1) FR2482953A1 (ko)

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Also Published As

Publication number Publication date
DE3119850C2 (ko) 1991-04-25
KR850001062B1 (ko) 1985-07-25
FR2482953A1 (fr) 1981-11-27
FR2482953B1 (ko) 1983-11-18
US4409410A (en) 1983-10-11
JPS5718785A (en) 1982-01-30
DE3119850A1 (de) 1982-02-25

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