KR20110002297A - A method for manufacuring masato-brick and masato-brick - Google Patents

A method for manufacuring masato-brick and masato-brick Download PDF

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Publication number
KR20110002297A
KR20110002297A KR1020090059815A KR20090059815A KR20110002297A KR 20110002297 A KR20110002297 A KR 20110002297A KR 1020090059815 A KR1020090059815 A KR 1020090059815A KR 20090059815 A KR20090059815 A KR 20090059815A KR 20110002297 A KR20110002297 A KR 20110002297A
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KR
South Korea
Prior art keywords
weight
masato
brick
phytoncide
water
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KR1020090059815A
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Korean (ko)
Inventor
김민철
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주식회사자연과길
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Priority to KR1020090059815A priority Critical patent/KR20110002297A/en
Publication of KR20110002297A publication Critical patent/KR20110002297A/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • B28B11/243Setting, e.g. drying, dehydrating or firing ceramic articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B17/00Details of, or accessories for, apparatus for shaping the material; Auxiliary measures taken in connection with such shaping
    • B28B17/02Conditioning the material prior to shaping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • B28B3/02Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/048Granite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/10Clay

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

PURPOSE: A masato brick manufacturing method, and a masato brick thereof are provided to solve the problem caused by the toxicity of the cement such as new house syndrome and atopy. CONSTITUTION: A masato brick manufacturing method comprises a first step(S10) of manufacturing the phytoncide capsule of diameter of 50nm ~ 3000μm containing the phytoncide solution, and a second step(S20) of mixing the masato of 20 to 80 weight %, the based dust powder of 10 to 70 weight %, water of 5 to 20 weight %, and the phytoncide capsule.

Description

Method for Manufacuring Masato-Brick and Masato-Brick}

The present invention relates to a method for producing environmentally friendly Masato brick containing phytoncide and Masato brick.

Masato is a weathered remnant of granite rocks, and its mother rock is mainly granite, but crystalline psalts (granite and granitic rocks) and gneiss rocks, which have similar properties to those of granite, are generally included. Its components are quartz, feldspar, colored minerals and the like. As it is weathered residue soil, it includes a wide range from close to rock to fine grains such as silt and clay depending on the degree of weathering. The distinction from rock is not necessarily clear, but excavation with general earth-moving machine is included as Masato, and it can be classified into granulation (3mm), neutral (3-1 mm), and fine grain (1 mm). On the other hand, from the point of view of the cause of Masato production, it is divided into Structure Masato and Ordinary Masato. In Structure Masato, weathering is less chemical weathering, low plasticity, and high permeability. Depending on the quality of the granules is remarkable, but slightly harder and less permeable.

Ocher is a yellow mineral mainly composed of 0.05 ~ 0.01mm silt particles, including calcium carbonate, silica, alumina, iron, magnesium, sodium, and kali, and has a viscous force not easily broken by calcium carbonate. When water is added, it turns into clay. Such ocher has a beneficial effect on the human body such as promoting blood circulation and metabolism because it radiates a large amount of far infrared rays, and has the effect of neutralizing the toxicity of cement.

However, cement bricks generally used in sidewalk blocks and bricks have the advantages of high mechanical strength, but they are harmful to humans due to the toxicity of cement and harmful substances such as heavy metals. Bricks have been developed and used.

In addition, the ocher / Masato brick has a lower strength than the cement brick is easy to be broken, cracking / cracking occurs due to the hardening of the ocher / Masato there was a problem that does not look aesthetically. In order to solve the problem of ocher / masato brick, bricks are manufactured by mixing an appropriate amount of cement, but since the coupling between the masato and the cement material is not smooth, the molding of the brick is uneven and the strength is not uniform.

The present invention manufactures bricks with eco-friendly masato and ocher, hardener and phytoncide to solve the problems caused by the toxicity of cement such as sick house syndrome and atopy during building construction. To provide a brick manufacturing method and Masato brick.

Environmentally friendly Masato brick manufacturing method containing a phytoncide according to the present invention for achieving the object of the present invention, the first step (S10) for manufacturing a phytoncide capsule of 50nm ~ 3000μm particle diameter containing a phytoncide solution;

The weight ratio of Masato 20 to 80% by weight, baked ocher powder 10 to 70% by weight, solidifying agent 5 to 50% by weight, water 5 to 20% by weight, and phytoncide solution except the weight of the capsule is 0.001 to 1 A second step (S20) of mixing and stirring the phytoncide capsule to be in weight%;

A third step (S30) of forming a brick by compressing the mixture stirred through the second step into a brick-forming mold;

It consists of a 4th process (S40) to cure the Masato brick shape | molded by the said 3rd process.

The environmentally friendly Masato brick containing phytoncide according to the present invention is manufactured by mixing and stirring the capsule containing Masato, a hardening agent, water, and a phytoncide solution having a particle size of 50 nm to 3000 μm, and then solidifying the entire brick weight. 0.001 to 1% by weight of phytoncide solution is included. Preferably, the baked ocher powder may be further added.

In accordance with the present invention, the problems of the prior art are solved, and by manufacturing bricks with environmentally friendly masato, ocher, hardener and phytoncide, it is extremely possible to solve the problems caused by the toxicity of cement such as sick house syndrome, atopic induction, etc. There is provided an environmentally friendly method of making masato bricks containing environmentally friendly phytoncide and masato bricks.

It reduces formaldehyde, a representative poisonous substance of birdhouses, by more than 80%, inhibits the growth of house dust mites, which are the main causes of atopy, asthma, and allergies, and has a strong antibacterial effect against various species and viruses such as Lazionella and Staphylococcus. Deodorizing function is effective in removing indoor odor from indoors. There is provided an environmentally friendly Masato brick production method and Masato brick containing phytoncide which can provide various forest bathing effects such as stress hormone reduction and comfort.

Hereinafter, a method for manufacturing environmentally friendly Masato brick containing phytoncide according to an embodiment of the present invention according to the present invention will be described in detail according to the embodiment shown in the accompanying drawings. 1 is a flowchart illustrating a method for manufacturing environmentally friendly Masato brick containing phytoncide according to an embodiment of the present invention.

As shown in Figure 1, the phytoncide-containing environmentally friendly Masato brick manufacturing method according to an embodiment of the present invention is mixed with the first step (S10) of manufacturing a phytoncide capsule and a second step of stirring (S20) And a third step (S30) of forming a brick and a fourth step (S40) of curing a molded Masato brick.

First, a phytoncide capsule having a particle size of 50 nm to 3000 μm containing a phytoncide solution is prepared in a first step (S10). In general, microcapsules are used in various fields as recording materials, pharmaceutical capsules, optical materials (light scattering enhancement materials) and the like. The microcapsules include a chemical interfacial polymerization method, a physical core-shell method, an interfacial precipitation method and a liquid drying method. Theoretically, the atomized nucleus material is dispersed in a suitable medium, and the nucleus material is prepared in such a way as to cover the membrane with a polymer or the like. Generally, liquids or solids are used as nuclear materials. Microcapsules are composites consisting of a functional material that is active inside and a wall material that protects it from the outside.The microcapsules are fine particles made to protect the functional material from the external environment and show continuous performance. Can be produced with The method for producing a micro capsule known at the time of filing the present invention is considered to be based on the specification of the present invention.

Phytoncide is a substance that plants exhale or secrete to resist pathogens, pests, and fungi.It reduces stress hormones, has strong antimicrobial antifungal properties, removes formaldehyde, and inhibits the growth of house dust mites. Relieves stress, strengthens bowel and cardiopulmonary function, and sterilizes. In addition, it reduces formaldehyde, a representative poisonous substance of birdhouses, by more than 80%, inhibits the growth of house dust mites, which are the main causes of atopy, asthma, and allergies, and has a strong antimicrobial effect against various bacteria and viruses such as Lazionella and Staphylococcus. With its excellent deodorizing function, it is effective to remove indoor odor from indoors. It is known to have an effect that can provide a variety of forest bathing effects, such as stress hormone reduction, comfort.

Next, in the second step (S20) of mixing and stirring, Masato 20 to 80% by weight, baked ocher powder 10 to 70% by weight, solidifying agent 5 to 50% by weight, water 5 to 20% by weight, and capsules The phytoncide capsules are mixed and stirred so that the weight ratio of only the phytoncide solution excluding the weight is 0.001 to 1% by weight.

If Masato is less than 20% by weight, manufacturing costs increase, Masato is more than 70% by weight, and the strength of the bricks is reduced. The ocher powder is preferably used after being cooled to room temperature after heating to 300 ~ 1200 ℃, if not baked, there is a problem that the phyton cide can be scattered in this process if a separate firing process. If too little ocher powder is contained, the advantages of ocher, such as far-infrared radiation effect, neutralizing the toxicity of the cement is weakened, and if too much ocher powder is contained, the strength of the brick is reduced.

The range of 5 to 50% by weight of the solidifying agent is preferable, and the weight may be changed to obtain the desired strength of the brick depending on the type of solidifying agent. The solidifying agent may be a cement-based hardener or a non-cement-based hardener, but a non-cement-based hardener may be used to increase environmentally friendly properties. Republic of Korea Patent Application No. 2007-0060376 (solidifying agent and non-fired ocher brick using the same and its manufacturing method), Republic of Korea Patent Application 2002-0071381 (Ocher brick and ocher mortar with increased strength and its manufacturing method), Republic of Korea Patent No. Descriptions of organic or inorganic solidifying agents known in the filing of the present invention, including 711115 (clay solidifying agent and clay composition to which the solidifying agent is added), etc., are regarded as being described in the specification of the present invention, The detailed description is omitted for publication.

It is advantageous in terms of kneading and strength that water contains 5 to 20% by weight, and it is preferable that the weight ratio of the phytoncide solution alone excluding the weight of the capsule is 0.001 to 1% by weight. If the amount of phyton chip is too small, the effect of the phyton chip may not be felt, and if the amount of phyton chip is too large, the manufacturing cost may increase and more than necessary phyton chip may be emitted.

In the third step (S30), the mixture stirred through the second step is put into a brick forming mold and compressed to form a brick. In the fourth step S40, the Masato brick molded by the third step is cured. Curing is preferably about 3 to 10 days at room temperature, preferably about 7 days. In the second step, the brick is formed by high-strength compression into a molding mold. In the fourth step (S40) to cure for about 160 to 170 hours to manufacture a brick. At this time, the curing time of the wall stone is a normal brick curing time when the brick is dried and completely hardened, and is usually cured for 7 days.

Environmentally friendly Masato brick manufacturing method containing a phytoncide in accordance with an embodiment of the present invention, before the second step (S20) put the wood and paper in water, steamed and dried by compression molding, 5 ~ 10mm size It may be configured to further include a fifth step of preparing a cone by molding into a spherical pellet form. In this case, 0.01-0.5 weight% of cone shell is further mixed and stirred in a 2nd process (S20). In the second step (S20), the cone may be prepared by mixing 0.1% by weight, adding 0.05 to 0.1% by weight of iron oxide, and mixing 0.5% by weight of AE reducing agent in water.

 If the amount of the cone is more than 0.5% by weight, the appearance of the brick is a lot of exposure to the cone, the surface of the brick is cracked or cracks along the cone may be bent hardness. If the amount of cone is less than 0.01%, the brick is prone to weak pressure or impact. The cone shell is added to prevent the Masato brick from breaking down by maintaining the toughness, and serves as a normal straw. It is prepared by steaming the flour with water, drying it completely, compressing it, and molding it into spherical pellets having a size of 5 to 10 mm. The mixing amount of these cones was found to be the best when 0.1% by weight of the total weight of the bricks.

On the other hand, the present invention is prepared by mixing 0.05 to 0.1% by weight of iron oxide relative to the total weight of the brick, the iron oxide is a material that is added so that the color of the brick red or yellow, when the color is mixed below 0.05% by weight When it is mixed with more than 0.1% by weight, there is a problem that the price of the brick is increased because the amount of iron oxide to be added is large, it is preferable to mix at 0.05 to 0.1% by weight. At this time, the iron oxide is added to the red iron or yellow iron oxide selected or mixed in a certain ratio, if the amount of red iron oxide is a large amount of red brick, if the amount of yellow iron oxide is a yellow brick is produced, the red and yellow iron oxide By mixing it is possible to produce bricks of intermediate color between red and yellow.

In addition, the present invention is added by mixing 0.5% by weight of the AE reducing agent to the total weight of the mixture, the AE reducing agent, by dispersing the particles by the dispersion / wetting action during the surfactant action to improve the workability (Workability), It is a admixture to reduce the amount of water, and by mixing through it, the fluidity of pasting (Paste) of the particles is increased, the amount of heat of hydration is reduced, the resistance to freezing is increased, and the watertightness of the brick is improved.

The use of such an AE water reducing agent, in particular, AE water reducing agent mixed with water to use the AE water reducing agent aqueous solution is generally widely used in the construction of bricks, there are a variety of types, it is specified that the AE water reducing agent is preferred in the present invention, but those skilled in the art In order to facilitate the implementation, it can be changed to various kinds of water reducing agents. Such AE water reducing agents can be used in many of the above-mentioned advantages, resulting in higher production costs, lower compressive strength, masato, ocher, hardener and iron oxide. There is a problem that the adhesion strength between the back and the like, and if used less, the effect of the AE reducing agent is weak.

In addition, a crosslinking agent can be added together with the AE reducing agent. Cross-linking agent is a cross linging agent, a bridge that acts as a bridge between the chains of the chain-like polymer, by using it to increase the firmness, elasticity and mechanical strength between masato, cement, cone and iron oxide It is effective in increasing chemical stability. Such crosslinking agents are mixed at about 0.01% of the total weight of the bricks. If too small, the effect of increasing the firmness and elasticity and mechanical strength between the mixed materials is insignificant, if too much is added to the crosslinking agent than necessary to increase the firmness, elasticity and mechanical strength between the materials no longer increase, the manufacturing cost is increased have.

Although the present invention has been described in connection with the above-mentioned preferred embodiments, the scope of the present invention is not limited to these embodiments, and the scope of the present invention is defined by the following claims, and equivalent scope of the present invention. It will include various modifications and variations belonging to.

The reference numerals set forth in the claims below are merely to aid the understanding of the present invention, not to affect the interpretation of the scope of the claims, and the scope of the claims should not be construed narrowly.

1 is a flow diagram of a method for producing environmentally friendly Masato brick containing phytoncide according to an embodiment of the present invention.

Claims (5)

A first step (S10) of preparing a phytoncide capsule having a particle size of 50 nm to 3000 µm containing a phytoncide solution; The weight ratio of Masato 20 to 80% by weight, baked ocher powder 10 to 70% by weight, solidifying agent 5 to 50% by weight, water 5 to 20% by weight, and phytoncide solution except the weight of the capsule is 0.001 to 1 A second step (S20) of mixing and stirring the phytoncide capsule to be in weight%; A third step (S30) of forming a brick by compressing the mixture stirred through the second step into a brick-forming mold; Method of manufacturing an environmentally friendly Masato brick containing phytoncide, characterized in that the fourth step (S40) for curing the masato brick molded by the third process. The method of claim 1, The second step (S20) before putting the steam and paper in water, steamed and dried by compression molding, and the fifth step of preparing a cone by forming a spherical pellet of 5 ~ 10mm size; Become, Method of manufacturing an environmentally friendly Masato brick containing phytoncide, characterized in that the second step (S20) in which the cone shell 0.01 to 0.5% by weight further mixed and stirred. The method of claim 2, The second step (S20) is The cone cell is mixed 0.1% by weight, Add 0.05 to 0.1% by weight of iron oxide, A method for producing environmentally friendly Masato brick containing phytoncide, characterized by mixing 0.5% by weight of AE reducing agent in water. Environmentally friendly Masato brick containing phytoncide prepared by the method of claim 1 to claim 4. Masato, baked ocher powder, solidifying agent, water, and capsules containing 50 nm to 3000 μm particle size of phytoncide solution are mixed and stirred, and then solidified. Eco-friendly masato brick containing phytoncide, characterized in that the phytoncide solution of 0.001 to 1% by weight based on the total weight of the brick.
KR1020090059815A 2009-07-01 2009-07-01 A method for manufacuring masato-brick and masato-brick KR20110002297A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101133032B1 (en) * 2011-04-22 2012-04-04 (주)아리산업 Manufacturing method for soil panel with main material of natural soils
KR20160134211A (en) * 2015-05-15 2016-11-23 박형준 Method for manufacturing eco-friendly clay bricks or clay floorings using byproducts of steelmaking and eco-friendly clay bricks or clay floorings manufactured by thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101133032B1 (en) * 2011-04-22 2012-04-04 (주)아리산업 Manufacturing method for soil panel with main material of natural soils
KR20160134211A (en) * 2015-05-15 2016-11-23 박형준 Method for manufacturing eco-friendly clay bricks or clay floorings using byproducts of steelmaking and eco-friendly clay bricks or clay floorings manufactured by thereof

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