KR101467603B1 - 이온 교환 수지를 이용한 산화 촉매 회수 방법 - Google Patents

이온 교환 수지를 이용한 산화 촉매 회수 방법 Download PDF

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Publication number
KR101467603B1
KR101467603B1 KR1020097024810A KR20097024810A KR101467603B1 KR 101467603 B1 KR101467603 B1 KR 101467603B1 KR 1020097024810 A KR1020097024810 A KR 1020097024810A KR 20097024810 A KR20097024810 A KR 20097024810A KR 101467603 B1 KR101467603 B1 KR 101467603B1
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South Korea
Prior art keywords
exchange resin
anion exchange
heavy metal
contacting
bromine
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KR1020097024810A
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English (en)
Korean (ko)
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KR20100017447A (ko
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마르지오 모나게듀
루치아노 피라스
지오바니 콕코
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다우 이탈리아 에스.알.엘.
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Publication of KR20100017447A publication Critical patent/KR20100017447A/ko
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/74—Regeneration or reactivation of catalysts, in general utilising ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/04—Processes using organic exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/04—Processes using organic exchangers
    • B01J41/05—Processes using organic exchangers in the strongly basic form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/05—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds
    • B01J49/08—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds containing cationic and anionic exchangers in separate beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
    • B01J49/53—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for cationic exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
    • B01J49/57—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for anionic exchangers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/47—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
KR1020097024810A 2007-05-31 2008-05-16 이온 교환 수지를 이용한 산화 촉매 회수 방법 KR101467603B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US93240007P 2007-05-31 2007-05-31
US60/932,400 2007-05-31

Publications (2)

Publication Number Publication Date
KR20100017447A KR20100017447A (ko) 2010-02-16
KR101467603B1 true KR101467603B1 (ko) 2014-12-01

Family

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Application Number Title Priority Date Filing Date
KR1020097024810A KR101467603B1 (ko) 2007-05-31 2008-05-16 이온 교환 수지를 이용한 산화 촉매 회수 방법

Country Status (7)

Country Link
EP (1) EP2158039A2 (fr)
JP (1) JP5296781B2 (fr)
KR (1) KR101467603B1 (fr)
CN (1) CN101952039B (fr)
BR (1) BRPI0811377A2 (fr)
RU (1) RU2009149338A (fr)
WO (1) WO2009022237A2 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101831738B1 (ko) * 2010-02-19 2018-02-23 미쯔비시 가스 케미칼 컴파니, 인코포레이티드 방향족 카르복실산류　제조 프로세스의 촉매 회수에 사용하는 피리딘환 함유 킬레이트 수지의 전처리 방법
KR101839774B1 (ko) 2010-02-19 2018-03-19 미쯔비시 가스 케미칼 컴파니, 인코포레이티드 테레프탈산 제조 프로세스의 촉매 회수에 사용하는 피리딘환 함유 킬레이트 수지의 전처리 방법
DE102013001972A1 (de) * 2013-02-05 2014-08-07 Thyssenkrupp Industrial Solutions Ag Verfahren zur selektiven Entfernung von Katalysatorbestandteilen aus Abströmen von Oxidationsreaktionen aromatischer Verbindungen, dafür geeignete Anlage und Verwendung
EP2774490B1 (fr) * 2013-03-06 2018-04-25 Cargill, Incorporated Purification de sirop par déionisation capacitive
US10829635B2 (en) 2016-03-11 2020-11-10 Lg Chem, Ltd. Economical method of preparing a resin composition including polyalkylene carbonate with improved thermal stability and processability
CN107555654A (zh) * 2017-09-25 2018-01-09 浙江绿维环境科技有限公司 一种用于金属工业冷却***的中水回用工艺

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5840643A (en) * 1995-01-07 1998-11-24 Yukong Limited Recovery of oxidation catalysts used for the production of trimellitic acid
US5955394A (en) * 1996-08-16 1999-09-21 Mobile Process Technology, Co. Recovery process for oxidation catalyst in the manufacture of aromatic carboxylic acids
US20020016500A1 (en) * 2000-06-27 2002-02-07 Masami Matsumoto Process for recovering catalyst components from a mother liquor of liquid phase oxidation

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JPS5419399B2 (fr) * 1973-04-26 1979-07-14
JPS557300B2 (fr) * 1973-03-30 1980-02-23
JPS53104590A (en) * 1977-02-24 1978-09-11 Asahi Chem Ind Co Ltd Recovery method for liquid-phase oxidation catalyst and solvent
GB1595904A (en) * 1977-04-25 1981-08-19 Ici Ltd Recovery catalyst values
JPH05221655A (ja) * 1992-02-15 1993-08-31 Mitsubishi Heavy Ind Ltd 塩酸水溶液中の塩化鉄の回収方法
GB9305902D0 (en) * 1993-03-22 1993-05-12 Bp Chem Int Ltd Process
JPH10176532A (ja) * 1996-12-16 1998-06-30 Sanshin Seisakusho:Kk エンジン冷却液の再生方法
US5880313A (en) * 1997-09-09 1999-03-09 Mitsubishi Gas Chemical Company, Inc. Process for producing aromatic carboxylic acid
AU5490799A (en) * 1999-08-17 2001-03-13 Mobile Process Technology, Co. Process for the purification of wash water from the production of aromatic acids
KR20020046280A (ko) * 1999-08-17 2002-06-20 추후제출 방향족 카복실산의 제조시 산화 촉매의 회수방법
US6825387B2 (en) * 2002-10-15 2004-11-30 Kellogg Brown & Root, Inc. Low sodium cleavage product
US7527733B2 (en) * 2004-09-30 2009-05-05 The University Of Southern California Chelating agents for heavy metal removal

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5840643A (en) * 1995-01-07 1998-11-24 Yukong Limited Recovery of oxidation catalysts used for the production of trimellitic acid
US5955394A (en) * 1996-08-16 1999-09-21 Mobile Process Technology, Co. Recovery process for oxidation catalyst in the manufacture of aromatic carboxylic acids
US20020016500A1 (en) * 2000-06-27 2002-02-07 Masami Matsumoto Process for recovering catalyst components from a mother liquor of liquid phase oxidation

Also Published As

Publication number Publication date
JP5296781B2 (ja) 2013-09-25
WO2009022237A9 (fr) 2009-08-13
CN101952039B (zh) 2015-05-20
WO2009022237A3 (fr) 2009-10-01
KR20100017447A (ko) 2010-02-16
BRPI0811377A2 (pt) 2014-12-09
CN101952039A (zh) 2011-01-19
RU2009149338A (ru) 2011-07-10
WO2009022237A2 (fr) 2009-02-19
JP2010527785A (ja) 2010-08-19
EP2158039A2 (fr) 2010-03-03

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