KR100630056B1 - 퍼플루오로알킬플루오로포스포란의 전기화학적 합성방법 - Google Patents
퍼플루오로알킬플루오로포스포란의 전기화학적 합성방법 Download PDFInfo
- Publication number
- KR100630056B1 KR100630056B1 KR1020007006235A KR20007006235A KR100630056B1 KR 100630056 B1 KR100630056 B1 KR 100630056B1 KR 1020007006235 A KR1020007006235 A KR 1020007006235A KR 20007006235 A KR20007006235 A KR 20007006235A KR 100630056 B1 KR100630056 B1 KR 100630056B1
- Authority
- KR
- South Korea
- Prior art keywords
- cell
- electrolysis
- fluorination
- hydrogen fluoride
- tris
- Prior art date
Links
- 230000015572 biosynthetic process Effects 0.000 title description 5
- 238000003786 synthesis reaction Methods 0.000 title description 4
- 238000000034 method Methods 0.000 claims abstract description 25
- 239000003446 ligand Substances 0.000 claims abstract description 4
- 238000002360 preparation method Methods 0.000 claims abstract description 3
- 238000003682 fluorination reaction Methods 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 125000004122 cyclic group Chemical group 0.000 claims description 3
- 125000004437 phosphorous atom Chemical group 0.000 claims description 2
- 239000003792 electrolyte Substances 0.000 abstract description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052744 lithium Inorganic materials 0.000 abstract description 2
- 239000002243 precursor Substances 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- 229910052731 fluorine Inorganic materials 0.000 description 29
- 238000005868 electrolysis reaction Methods 0.000 description 25
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 22
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 22
- 229910052698 phosphorus Inorganic materials 0.000 description 18
- 239000007788 liquid Substances 0.000 description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- 239000000047 product Substances 0.000 description 11
- 239000007795 chemical reaction product Substances 0.000 description 10
- 239000007858 starting material Substances 0.000 description 9
- SRGQEZQRKDZRHA-UHFFFAOYSA-N F[PH3]F Chemical compound F[PH3]F SRGQEZQRKDZRHA-UHFFFAOYSA-N 0.000 description 8
- 239000007983 Tris buffer Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 229910052759 nickel Inorganic materials 0.000 description 7
- 238000010992 reflux Methods 0.000 description 7
- 239000006227 byproduct Substances 0.000 description 6
- -1 perfluoroalkyl iodine Chemical compound 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- HEJQMLUVXZXFRS-UHFFFAOYSA-N difluoro-tris(1,1,2,2,2-pentafluoroethyl)-$l^{5}-phosphane Chemical compound FC(F)(F)C(F)(F)P(F)(F)(C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)F HEJQMLUVXZXFRS-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- 239000002360 explosive Substances 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- RXJKFRMDXUJTEX-UHFFFAOYSA-N triethylphosphine Chemical compound CCP(CC)CC RXJKFRMDXUJTEX-UHFFFAOYSA-N 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- CTACDZGWOCCHGB-UHFFFAOYSA-N difluoro-tris(1,1,2,2,3,3,3-heptafluoropropyl)-$l^{5}-phosphane Chemical compound FC(F)(F)C(F)(F)C(F)(F)P(F)(F)(C(F)(F)C(F)(F)C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)F CTACDZGWOCCHGB-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- OZVBWWXYCICGEU-UHFFFAOYSA-N tetrafluoro(1,1,2,2,2-pentafluoroethyl)-$l^{5}-phosphane Chemical compound FC(F)(F)C(F)(F)P(F)(F)(F)F OZVBWWXYCICGEU-UHFFFAOYSA-N 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 3
- KCTAHLRCZMOTKM-UHFFFAOYSA-N tripropylphosphane Chemical compound CCCP(CCC)CCC KCTAHLRCZMOTKM-UHFFFAOYSA-N 0.000 description 3
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- CGZWWDMKJVOACI-UHFFFAOYSA-N dichloro ethyl phosphate Chemical compound CCOP(=O)(OCl)OCl CGZWWDMKJVOACI-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000000806 fluorine-19 nuclear magnetic resonance spectrum Methods 0.000 description 2
- GWLJTAJEHRYMCA-UHFFFAOYSA-N phospholane Chemical compound C1CCPC1 GWLJTAJEHRYMCA-UHFFFAOYSA-N 0.000 description 2
- 238000001394 phosphorus-31 nuclear magnetic resonance spectrum Methods 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- YWWDBCBWQNCYNR-UHFFFAOYSA-N trimethylphosphine Chemical compound CP(C)C YWWDBCBWQNCYNR-UHFFFAOYSA-N 0.000 description 2
- DAGQYUCAQQEEJD-UHFFFAOYSA-N tris(2-methylpropyl)phosphane Chemical compound CC(C)CP(CC(C)C)CC(C)C DAGQYUCAQQEEJD-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- IKOHZYDNUZVQHA-UHFFFAOYSA-N FC(C(F)(F)F)(C(F)(F)F)C(F)(F)P(C(C(C(F)(F)F)(C(F)(F)F)F)(F)F)(F)F Chemical compound FC(C(F)(F)F)(C(F)(F)F)C(F)(F)P(C(C(C(F)(F)F)(C(F)(F)F)F)(F)F)(F)F IKOHZYDNUZVQHA-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000005922 Phosphane Substances 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- HRKAMJBPFPHCSD-UHFFFAOYSA-N Tri-isobutylphosphate Chemical compound CC(C)COP(=O)(OCC(C)C)OCC(C)C HRKAMJBPFPHCSD-UHFFFAOYSA-N 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- FXBGQPXZUWMUSD-UHFFFAOYSA-N difluoro-tris(2,2,3,3,3-pentafluoropropyl)-lambda5-phosphane Chemical compound FC(CP(F)(F)(CC(C(F)(F)F)(F)F)CC(C(F)(F)F)(F)F)(C(F)(F)F)F FXBGQPXZUWMUSD-UHFFFAOYSA-N 0.000 description 1
- WITWABDXPDGLJI-UHFFFAOYSA-N difluoro-tris[1,1,2,3,3,3-hexafluoro-2-(trifluoromethyl)propyl]-$l^{5}-phosphane Chemical compound FC(F)(F)C(F)(C(F)(F)F)C(F)(F)P(F)(F)(C(F)(F)C(F)(C(F)(F)F)C(F)(F)F)C(F)(F)C(F)(C(F)(F)F)C(F)(F)F WITWABDXPDGLJI-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- UJMWVICAENGCRF-UHFFFAOYSA-N oxygen difluoride Chemical compound FOF UJMWVICAENGCRF-UHFFFAOYSA-N 0.000 description 1
- 229910000127 oxygen difluoride Inorganic materials 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229910000064 phosphane Inorganic materials 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000004714 phosphonium salts Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- OBCUTHMOOONNBS-UHFFFAOYSA-N phosphorus pentafluoride Chemical compound FP(F)(F)(F)F OBCUTHMOOONNBS-UHFFFAOYSA-N 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/535—Organo-phosphoranes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/27—Halogenation
- C25B3/28—Fluorination
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Secondary Cells (AREA)
Abstract
Description
트리에틸포스판 용액의 함량(g) | 전기분해의 지속시간(Ah) |
27.8 | 0 |
30.4 | 81.8 |
31.9 | 168.0 |
31.1 | 256.4 |
37.0 | 371.3 |
트리부틸포스핀의 함량(g) | 전기분해 지속시간(Ah) |
41.8 | 0 |
38.0 | 291.3 |
38.0 | 623.8 |
35.1 | 930.6 |
41.8 | 1430.0 |
35.8 | 1939.0 |
37.5 | 2414.9 |
디클로로에틸포스판 용액의 함량(g) | 전기분해 지속시간(Ah) |
31.0 | 0 |
34.0 | 33.2 |
23.0 | 54.3 |
24.0 | 84.6 |
트리프로필포스판 용액의 함량(g) | 전기분해 지속시간(Ah) |
33.0 | 0 |
31.0 | 91.8 |
32.0 | 189.8 |
37.0 | 282.3 |
트리(이소부틸)포스판의 함량(g) | 전기분해 지속시간(Ah) |
104.0 | 0 |
96.0 | 315.2 |
102.0 | 699.9 |
99.0 | 983.6 |
98.0 | 1373.4 |
Claims (7)
- -15 내지 40℃의 전지 온도, 1 내지 3bar의 압력, 4.0 내지 6.5V의 전지 전압 및 0.1 내지 3.5A/dm2의 전류 밀도에서 무수 HF중에서 인 원자상에 동일하거나 상이한 선형, 분지형 또는 환식 알킬 치환체를 갖는 알킬포스판의 전기화학적 불소화를 수행하는 것을 특징으로 하는, 하기 화학식 1의 퍼플루오로알킬플루오로포스포란의 제조방법:화학식 1(CnF2n+m)yPF5-y상기식에서,n은 1 내지 8의 정수이고,m은 +1 또는 -1이고,y는 1 내지 3의 정수이고,리간드(CnF2n+m)는 동일하거나 상이할 수 있다.
- 제 1 항에 있어서,불소화를 -10 내지 10℃에서 수행하는 방법.
- 제 1 항에 있어서,불소화를 0℃에서 수행하는 방법.
- 제 1 항에 있어서,불소화를 1 내지 0.5bar의 압력에서 수행하는 방법.
- 제 1 항에 있어서,불소화를 대기압에서 수행하는 방법.
- 제 1 항에 있어서,반응을 0.2 내지 3.5A/dm2의 전류 밀도에서 수행하는 방법.
- 제 1 항에 있어서,반응을 0.22 내지 0.55A/dm2의 전류 밀도에서 수행하는 방법.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19846636A DE19846636A1 (de) | 1998-10-09 | 1998-10-09 | Elektrochemische Synthese von Perfluoralkylfluorophosphoranen |
DE19846636.6 | 1998-10-09 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20010032901A KR20010032901A (ko) | 2001-04-25 |
KR100630056B1 true KR100630056B1 (ko) | 2006-09-27 |
Family
ID=7883977
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020007006235A KR100630056B1 (ko) | 1998-10-09 | 1999-09-29 | 퍼플루오로알킬플루오로포스포란의 전기화학적 합성방법 |
Country Status (12)
Country | Link |
---|---|
US (1) | US6264818B1 (ko) |
EP (1) | EP1037896B1 (ko) |
JP (1) | JP3387059B2 (ko) |
KR (1) | KR100630056B1 (ko) |
CN (1) | CN1177853C (ko) |
AU (1) | AU6330199A (ko) |
BR (1) | BR9906864A (ko) |
CA (1) | CA2313319C (ko) |
DE (2) | DE19846636A1 (ko) |
MX (1) | MXPA00005317A (ko) |
TW (1) | TW577892B (ko) |
WO (1) | WO2000021969A1 (ko) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10031563B4 (de) * | 2000-06-28 | 2009-01-29 | Lanxess Deutschland Gmbh | Verfahren zur Herstellung von perfluororganischen Verbindungen durch elektrochemische Fluorierung |
DE10109756A1 (de) * | 2001-02-28 | 2002-09-05 | Merck Patent Gmbh | Fluora-a,omega-bis [fluoralkyl)fluorphosphorano)]fluoralkane und Verfahren zu ihrer Herstellung |
DE10130940A1 (de) * | 2001-06-27 | 2003-01-16 | Merck Patent Gmbh | Supersäuren, Herstellverfahren und Verwendungen |
DE10216996A1 (de) * | 2002-04-16 | 2003-10-30 | Merck Patent Gmbh | Verfahren zur Perfluoralkylierung mittels Tris(perfluoralkyl)phosphinoxiden |
DE10216998A1 (de) | 2002-04-18 | 2003-11-13 | Merck Patent Gmbh | Verfahren zur Herstellung von Perfluoralkylphosphinen und deren Verwendung als Perfluoralkylierungsreagenzien |
DE102006005103A1 (de) | 2006-02-04 | 2007-08-09 | Merck Patent Gmbh | Oxonium- und Sulfoniumsalze |
DE102007004698A1 (de) * | 2007-01-31 | 2008-08-07 | Merck Patent Gmbh | Verbindungen enthaltend Organofluorochlorophosphatanionen |
DE102008035174A1 (de) * | 2008-07-28 | 2010-02-11 | Merck Patent Gmbh | Verfahren zur Herstellung von Bis(fluoralkyl)-phosphinsäure oder Fluoralkylphosphonsäure |
WO2011051275A1 (en) | 2009-10-27 | 2011-05-05 | Solvay Fluor Gmbh | Lithium sulfur battery |
DE102009058969A1 (de) * | 2009-12-18 | 2011-06-22 | Merck Patent GmbH, 64293 | Verbindung mit (Perfluoralkyl)fluorohydrogenphosphat - Anionen |
EP2531513A1 (en) | 2010-02-02 | 2012-12-12 | Merck Patent GmbH | Phosphinyl hydrazides |
DE102010011034A1 (de) | 2010-03-11 | 2011-09-15 | Merck Patent Gmbh | Verfahren zur Herstellung von Tris (perfluoralkyl)phosphinoxiden |
US8829188B2 (en) | 2010-09-27 | 2014-09-09 | Merck Patent Gmbh | Fluoroalkylfluorophosphorane adducts |
US8846922B2 (en) * | 2010-09-27 | 2014-09-30 | Merck Patent Gmbh | Functionalized fluoroalkyl fluorophosphate salts |
DE102011111490A1 (de) | 2010-09-27 | 2012-03-29 | Merck Patent Gmbh | Verfahren zur Herstellung eines Schaumes |
WO2012146525A1 (en) | 2011-04-26 | 2012-11-01 | Solvay Sa | Lithium air battery cell |
DE102012004068A1 (de) | 2012-03-02 | 2013-09-05 | Merck Patent Gmbh | Verfahren zur Herstellung von Phosphinsäureestern |
DE102012013071A1 (de) | 2012-07-02 | 2014-01-02 | Merck Patent Gmbh | Verfahren zur Herstellung von Tris(perfluoralkyl)phosphinoxiden und Bis(perfluoralkyl)phosphinsäuren |
WO2016074757A1 (de) | 2014-11-11 | 2016-05-19 | Merck Patent Gmbh | Verfahren zur herstellung von mono- und bis(perfluoralkyl)fluorophosphatsalzen und deren säuren |
DE102015006283A1 (de) | 2014-12-17 | 2016-06-23 | Merck Patent Gmbh | Verbindungen mit Fluoralkyl(cyanomethyl)fluorophosphat-Anionen |
JP6603127B2 (ja) | 2015-12-29 | 2019-11-06 | サンアプロ株式会社 | 感光性組成物 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998015562A1 (de) * | 1996-10-05 | 1998-04-16 | Merck Patent Gmbh | Lithiumfluorphosphate sowie deren verwendung als leitsalze |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2620086C3 (de) * | 1976-05-06 | 1980-02-14 | Institut Organitscheskoj Chimii Akademii Nauk Ukrainskoj Ssr, Kiew (Sowjetunion) | Tris-(perfluoralkyl)-phosphinox'ide und Verfahren zu deren Herstellung |
FR2606217B1 (fr) | 1986-10-30 | 1990-12-14 | Elf Aquitaine | Nouveau materiau a conduction ionique constitue par un sel en solution dans un electrolyte liquide |
US4900854A (en) | 1987-03-23 | 1990-02-13 | The Dow Chemical Company | Process for the preparation of asymmetrical alkaline earth metal organoborates, organoaluminates, organoarsenates, and organophosphates |
DE4316104A1 (de) | 1993-05-13 | 1994-11-17 | Manfred Wuehr | Elektrolyt zur Anwendung in einer galvanischen Zelle |
-
1998
- 1998-10-09 DE DE19846636A patent/DE19846636A1/de not_active Withdrawn
-
1999
- 1999-09-29 US US09/509,013 patent/US6264818B1/en not_active Expired - Lifetime
- 1999-09-29 DE DE59902179T patent/DE59902179D1/de not_active Expired - Lifetime
- 1999-09-29 AU AU63301/99A patent/AU6330199A/en not_active Abandoned
- 1999-09-29 CA CA002313319A patent/CA2313319C/en not_active Expired - Fee Related
- 1999-09-29 BR BR9906864-8A patent/BR9906864A/pt not_active IP Right Cessation
- 1999-09-29 CN CNB998017841A patent/CN1177853C/zh not_active Expired - Lifetime
- 1999-09-29 KR KR1020007006235A patent/KR100630056B1/ko active IP Right Grant
- 1999-09-29 WO PCT/EP1999/007214 patent/WO2000021969A1/de active IP Right Grant
- 1999-09-29 EP EP99950566A patent/EP1037896B1/de not_active Expired - Lifetime
- 1999-09-29 JP JP2000575875A patent/JP3387059B2/ja not_active Expired - Lifetime
- 1999-10-05 TW TW088117168A patent/TW577892B/zh not_active IP Right Cessation
-
2000
- 2000-06-08 MX MXPA00005317 patent/MXPA00005317A/es unknown
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998015562A1 (de) * | 1996-10-05 | 1998-04-16 | Merck Patent Gmbh | Lithiumfluorphosphate sowie deren verwendung als leitsalze |
Also Published As
Publication number | Publication date |
---|---|
EP1037896A1 (de) | 2000-09-27 |
CA2313319C (en) | 2008-01-22 |
TW577892B (en) | 2004-03-01 |
JP3387059B2 (ja) | 2003-03-17 |
BR9906864A (pt) | 2000-10-17 |
CN1177853C (zh) | 2004-12-01 |
KR20010032901A (ko) | 2001-04-25 |
CN1287557A (zh) | 2001-03-14 |
CA2313319A1 (en) | 2000-04-20 |
DE59902179D1 (de) | 2002-09-05 |
EP1037896B1 (de) | 2002-07-31 |
AU6330199A (en) | 2000-05-01 |
US6264818B1 (en) | 2001-07-24 |
DE19846636A1 (de) | 2000-04-13 |
JP2002527615A (ja) | 2002-08-27 |
WO2000021969A1 (de) | 2000-04-20 |
MXPA00005317A (es) | 2001-02-01 |
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