JPS6369625A - Manufacture of laminated sheet - Google Patents

Manufacture of laminated sheet

Info

Publication number
JPS6369625A
JPS6369625A JP61214673A JP21467386A JPS6369625A JP S6369625 A JPS6369625 A JP S6369625A JP 61214673 A JP61214673 A JP 61214673A JP 21467386 A JP21467386 A JP 21467386A JP S6369625 A JPS6369625 A JP S6369625A
Authority
JP
Japan
Prior art keywords
laminated
laminate
laminated sheet
resin
thereafter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP61214673A
Other languages
Japanese (ja)
Other versions
JP2550956B2 (en
Inventor
Kikuo Kimura
木村 規久男
Isao Yamaji
山地 勲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Electric Works Co Ltd
Original Assignee
Matsushita Electric Works Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Works Ltd filed Critical Matsushita Electric Works Ltd
Priority to JP61214673A priority Critical patent/JP2550956B2/en
Publication of JPS6369625A publication Critical patent/JPS6369625A/en
Application granted granted Critical
Publication of JP2550956B2 publication Critical patent/JP2550956B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/02Apparatus or processes for manufacturing printed circuits in which the conductive material is applied to the surface of the insulating support and is thereafter removed from such areas of the surface which are not intended for current conducting or shielding
    • H05K3/022Processes for manufacturing precursors of printed circuits, i.e. copper-clad substrates

Landscapes

  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Laminated Bodies (AREA)

Abstract

PURPOSE:To manufacture a flat and smooth laminated sheet without any distorsion or twist, by a method wherein base plates, impregnated with resin, are laminated and formed, thereafter, after-cure and rapid cooling are applied thereon. CONSTITUTION:Eight sheets of continuous belt-type glass fabric base materials are impregnated respectively with epoxy resin varnish containing curing agent, thereafter, eight sheets of them are laminated to obtain one set of laminated sheet. Continuous copper foils are laminated on the upper and lower surfaces of the obtained laminated sheet and, subsequently, this laminated body is introduced into a heating furnace under no pressure. The laminated body is cut after heating, and after-cure is applied thereon finally, thereafter, it is introduced into a water tank immediately to be cooled rapidly, then, the laminated body is taken out of the tank and moisture on the surface thereof is removed, whereby the objective laminated sheet may be obtained.

Description

【発明の詳細な説明】 〔技術分野〕 本発明は′(気機器、電子機器、]算鏡器%通偵81器
用等に用すられる積層板の製造方法に関す゛るものであ
る。
DETAILED DESCRIPTION OF THE INVENTION [Technical Field] The present invention relates to a method for manufacturing a laminate plate used for mechanical equipment, electronic equipment, arithmetic instruments, etc.

〔背景技術〕[Background technology]

従来、1気用等に用1八られる積層板は漬74嘆必後、
所要寸法に切断し、自然放冷して製品と−’3−8もの
が殆んどで、特に寸法安定性が要求されるI′バ層板1
でつhては所要寸法に切断後、史jz(アフメ〜キュア
ーし、自然放冷しで製品としてbるが、叶今のファ、イ
ンパターン化におりては更に高i′Fの寸法安定性と表
面平滑性が要求されてIAだ。
Conventionally, the laminated boards used for one purpose, etc. have been soaked for 74 years.
The product is cut to the required size and left to cool naturally.Most of the products are 3-8, and particularly require dimensional stability.
After cutting to the required size, it is cured and left to cool naturally to become a product, but in today's F, in-patterning process, the dimensional stability of even higher i'F is achieved. IA is required because of its flexibility and surface smoothness.

〔発明の目的〕[Purpose of the invention]

本発明の目的とするところは寸法安定tl: 、、春面
平渭性(て優れた積層板の製造方法を提供することにあ
る。
An object of the present invention is to provide a method for manufacturing a laminate with excellent dimensional stability, tl, and flatness.

〔発明の開示〕[Disclosure of the invention]

本発明は撞I−板用基材に樹脂を含′lトした樹脂含浸
基材を所要枚数重ね、更に必要に応じてその上面及び又
は下面に金属箔を配役した穆11体を積層成形後、所要
寸法に切断し、更にアフターキュア−後、急冷すること
を特徴とする積層板の製造方法のため、アフターキエア
ーにより樹脂の完全硬化及び積層成形時に発生する歪が
除去され、更に急冷によって反り、ねじれを発生するこ
となく表面平滑性に優れた積I−板を得ることができた
もので、以下本発明の詳細な説明する。
In the present invention, a required number of resin-impregnated base materials containing resin are stacked on the base material for the I-board, and then 11 pieces are laminated and molded, with metal foil placed on the upper and/or lower surfaces as necessary. The manufacturing method of laminates is characterized by cutting to the required size, followed by after-curing, and then rapidly cooling.The after-curing process completely cures the resin and removes the distortion that occurs during lamination molding, and the laminates are then cut to the required size, followed by after-curing, and then rapidly cooled. A laminated I-plate with excellent surface smoothness was obtained without warping or twisting, and the present invention will be described in detail below.

本発明に用いる積層板用基材としてはガラス、アスベス
ト等の無機繊維やポリエステル、ポリアミド、ポリビニ
ルアルコール、アクリル等の有機合成繊維や木綿等の天
然禮維からなる織布、不織布、マット或は紙又はこれら
の組合せ基材等である。樹脂としてはフェノール樹脂、
クレゾール樹脂、エポキシ樹脂、不飽和ポリエステル樹
脂、メラミン樹脂、ポリイミド、ポリブタジェン、ポリ
アミド、ポリアミドイミF1ポリスルフォン、ポリフェ
ニレンサルファイド、ポリフェニレンオキサイド、ポリ
ブチレンテレツメレート、ポリエーテルエーテルケトン
、弗化樹脂等の単独、変性物、混合物等が用いられ必要
に応じて粘度調整に水、メチルアルコール、アセトン、
シクロヘキサノy1 スチレンモノマー等の溶媒を添加
したものである。樹脂は必要て応じて一次含浸用、二次
含浸用、三次含浸用等のようく複数回に分けて同−樹脂
又は異種樹脂を含浸させることもできる。金属層として
は銅、鉄、ニッケル、亜鉛、アルミニウム等の単独、合
金を用Aることかでき、必要に応じて金属層の片面に接
着剤層を設は接−資性を同上させることもできる。積層
成形は多段プレス機、マルチロール機、ドラム成形機、
ダブルベルト成形機等による加熱加圧成形でもよく又、
エンドレスベルト成形機、連続加熱炉方式等だよる加熱
無圧成形でもよく特に限定するものではな−、切断後の
アブターキエアーは連続加熱炉方式、加熱炉方式等のよ
うにパンチ式、連続式の各れでもよく特に限定するもの
ではないがアフターキュアー後は急冷することが必要で
ある。急冷方式は特に限定するものではなく、冷却した
電気、炭酸ガス。
The base materials for the laminate used in the present invention include woven fabrics, non-woven fabrics, mats, and paper made of inorganic fibers such as glass and asbestos, organic synthetic fibers such as polyester, polyamide, polyvinyl alcohol, and acrylic, and natural fibers such as cotton. Or a combination base material etc. of these. The resin is phenolic resin,
Cresol resin, epoxy resin, unsaturated polyester resin, melamine resin, polyimide, polybutadiene, polyamide, polyamideimide F1 polysulfone, polyphenylene sulfide, polyphenylene oxide, polybutylene teletumerate, polyether ether ketone, fluorinated resin, etc. alone, Modified products, mixtures, etc. are used, and water, methyl alcohol, acetone, etc. are used to adjust the viscosity as necessary.
Cyclohexano y1 A solvent such as styrene monomer is added. If necessary, the resin can be impregnated with the same resin or different resins in multiple steps, such as for primary impregnation, secondary impregnation, and tertiary impregnation. The metal layer can be made of copper, iron, nickel, zinc, aluminum, etc. alone or in an alloy, and if necessary, an adhesive layer can be provided on one side of the metal layer to improve the bondability. can. Laminate molding is done using multi-stage press machines, multi-roll machines, drum molding machines,
Heat and pressure molding using a double belt molding machine etc. may also be used.
It is not particularly limited to heating and pressureless forming using an endless belt forming machine, a continuous heating furnace method, etc., but the abutment air after cutting may be a punch type or continuous method such as a continuous heating furnace method, a heating furnace method, etc. Any of these may be used, but there is no particular limitation, but rapid cooling is required after after-curing. The rapid cooling method is not particularly limited, and can be cooled electricity or carbon dioxide gas.

tA素ガス、ツウ素ガス等の低温気体の充満した檜を通
過させたり、低温気体を吹き付けたりする低温気体によ
る冷却や、冷却した水、液化ガス液等の低温液体の充満
した槽を通過させたり、低温液体を吹付けたりする低温
液体による冷却や、冷却したロール、プレス等の低温金
属との接触による冷却等が用いられ任意である。更に上
記急冷方式を複数組み合わせて用することもできる。積
層成形、了フターキエアー、急冷条件については使用す
る基材、樹脂により異なるが、積層成形については80
〜250℃、アフターキニアーにっbでは80〜250
℃、急冷については積層板表面温度で一10〜60℃迄
急冷することが好ましい。以下本発明を実施例にもとづ
bて説明する。
Cooling with low-temperature gas such as passing through a hinoki cypress filled with low-temperature gas such as tA gas or fluorine gas, or blowing low-temperature gas, or passing through a tank filled with low-temperature liquid such as chilled water or liquefied gas liquid. Cooling with a low-temperature liquid such as spraying a low-temperature liquid, cooling by contact with a low-temperature metal such as a chilled roll or press, etc., may be used as desired. Furthermore, it is also possible to use a combination of a plurality of the above quenching methods. Laminate molding, cooling air, and quenching conditions vary depending on the base material and resin used, but for laminated molding, 80%
~250℃, 80~250 at after-kinear b
As for the rapid cooling, it is preferable to rapidly cool the laminate to a surface temperature of -10 to 60°C. The present invention will be explained below based on examples.

実施例 厚さ0.2flの長尺帯状ガラス布基材8枚に夫々硬化
剤含有エポキシ樹脂フェスを含浸させ、スクイズロール
で樹脂量が50℃ml(以下単に憾と記す)になるよう
に調整すると共に8枚を1組くラミネートした後、上下
面に厚さ0.035fr11の長尺銅箔を夫々配設した
積層体を無圧状態で加熱温度150℃のトンネル炉に連
続して導入し20分間加熱してから1m毎に切断し、更
に160 ’Cの加熱炉で15分間アフターキュアー後
、直ちに20℃の水槽中に導入しF7tJfJ板表面温
度が30℃になる迄10分間急冷してから取出し、表面
水分を除去して積層板を得た。
Example: Eight long strip-shaped glass cloth substrates each having a thickness of 0.2 fl were impregnated with an epoxy resin face containing a curing agent, and adjusted with a squeeze roll so that the resin amount was 50°C ml (hereinafter simply referred to as "regret"). At the same time, after laminating a set of 8 sheets, the laminate, in which long copper foils with a thickness of 0.035 fr11 were arranged on the upper and lower surfaces, was continuously introduced into a tunnel furnace at a heating temperature of 150° C. under no pressure. After heating for 20 minutes, it was cut into 1m sections, and then after-cured for 15 minutes in a 160'C heating furnace, it was immediately introduced into a 20℃ water tank and rapidly cooled for 10 minutes until the surface temperature of the F7tJfJ plate reached 30℃. A laminate was obtained by removing surface water from the laminate.

実施例2 アフターキ二アー′Vt1直ちに20℃の水によるシャ
ーワー室を通過させ、積、1板表面温度が40’Cにな
るIO分間迄急冷した以外は実施例1と同様に処理して
積層板を得た。
Example 2 A laminate was processed in the same manner as in Example 1, except that the after-tinier Vt1 was immediately passed through a shower room with 20°C water and rapidly cooled for 10 minutes to reach a surface temperature of 40°C. I got it.

′44施例3 アフターキュツー後、直ちに25℃のプレス成形機で接
触圧にて20分間急冷し、積層板表面温度が50℃にな
る迄急冷した以外は実施例1と同様に処理してa1層板
を得た。
'44 Example 3 The same process as in Example 1 was carried out, except that after the aftercut, the laminate was immediately quenched for 20 minutes under contact pressure in a press molding machine at 25°C until the surface temperature of the laminate reached 50°C. An a1-layer board was obtained.

実施!/II 4 アフターキュアー後、石ちに25℃のマルチ冷却ロール
を通過させ、積層板表面温度が55℃になる迄5分間急
冷した以外は実施例1と同様に処理して積層板を得た。
implementation! /II 4 After curing, a laminate was obtained in the same manner as in Example 1, except that the stone was passed through a multi-chilling roll at 25°C and rapidly cooled for 5 minutes until the surface temperature of the laminate reached 55°C. .

実施例5 アフターキュアー後、直ちに0〜5℃の低温室を通過さ
せ、積層板表面温度が60℃になる迄20分間急冷した
以外は実施例1と同様に処理して積層板を得た。
Example 5 A laminate was obtained in the same manner as in Example 1, except that after the after-cure, it was immediately passed through a cold room at 0 to 5°C and rapidly cooled for 20 minutes until the surface temperature of the laminate reached 60°C.

比較例 アフターキュアー後、自然放冷したところ積層板表面温
度が25℃になるのに要した時間は8時間であった。
Comparative Example When the laminate was allowed to cool naturally after after-curing, it took 8 hours for the surface temperature of the laminate to reach 25°C.

〔発明の効果〕〔Effect of the invention〕

実施例1乃至5及び比較例のm層板の表面平滑性及び寸
法安定性は第1表で明白なように本発明のものの性能は
よく、本発明の積層板の製造方法の優れてbることを確
認した。
As is clear from Table 1, the surface smoothness and dimensional stability of the m-layer plates of Examples 1 to 5 and the comparative example are good, and the performance of the laminated plates of the present invention is excellent. It was confirmed.

Claims (4)

【特許請求の範囲】[Claims] (1)積層板用基材に樹脂を含浸した樹脂含浸基材を所
要枚数重ね、更に必要に応じてその上面及び又は下面に
金属箔を配設した積層体を積層成形後、所要寸法に切断
し、更にアフターキュアー後、急冷することを特徴とす
る積層板の製造方法。
(1) Layer the required number of resin-impregnated base materials made by impregnating the base material for a laminate with resin, and if necessary, arrange metal foil on the top and/or bottom surfaces of the laminate. After lamination molding, cut into the required dimensions. A method for producing a laminate, which further comprises rapidly cooling after after-curing.
(2)急冷が低温気体によるものであることを特徴とす
る特許請求の範囲第1項記載の積層板の製造方法。
(2) The method for manufacturing a laminate according to claim 1, wherein the quenching is performed using low-temperature gas.
(3)急冷が低温液体によるものであることを特徴とす
る特許請求の範囲第1項記載の積層板の製造方法。
(3) The method for manufacturing a laminate according to claim 1, wherein the quenching is performed using a low-temperature liquid.
(4)急冷が低温金属によるものであることを特徴とす
る特許請求の範囲第1項記載の積層板の製造方法。
(4) The method for manufacturing a laminate according to claim 1, wherein the quenching is performed using a low-temperature metal.
JP61214673A 1986-09-11 1986-09-11 Laminated board manufacturing method Expired - Fee Related JP2550956B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61214673A JP2550956B2 (en) 1986-09-11 1986-09-11 Laminated board manufacturing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61214673A JP2550956B2 (en) 1986-09-11 1986-09-11 Laminated board manufacturing method

Publications (2)

Publication Number Publication Date
JPS6369625A true JPS6369625A (en) 1988-03-29
JP2550956B2 JP2550956B2 (en) 1996-11-06

Family

ID=16659679

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61214673A Expired - Fee Related JP2550956B2 (en) 1986-09-11 1986-09-11 Laminated board manufacturing method

Country Status (1)

Country Link
JP (1) JP2550956B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0371837A (en) * 1989-08-11 1991-03-27 Matsushita Electric Works Ltd Preparation of laminated sheet

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0371837A (en) * 1989-08-11 1991-03-27 Matsushita Electric Works Ltd Preparation of laminated sheet

Also Published As

Publication number Publication date
JP2550956B2 (en) 1996-11-06

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