JPS6360794A - Thermal transfer recording medium - Google Patents
Thermal transfer recording mediumInfo
- Publication number
- JPS6360794A JPS6360794A JP61205549A JP20554986A JPS6360794A JP S6360794 A JPS6360794 A JP S6360794A JP 61205549 A JP61205549 A JP 61205549A JP 20554986 A JP20554986 A JP 20554986A JP S6360794 A JPS6360794 A JP S6360794A
- Authority
- JP
- Japan
- Prior art keywords
- thermal transfer
- layer
- anchor layer
- anchor
- recording material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 claims abstract description 32
- 239000002985 plastic film Substances 0.000 claims abstract description 4
- 229920006255 plastic film Polymers 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 239000001993 wax Substances 0.000 claims description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 5
- 229920001971 elastomer Polymers 0.000 claims description 4
- 239000005060 rubber Substances 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 2
- -1 acrylic polyols Chemical class 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 2
- 229920005906 polyester polyol Polymers 0.000 claims description 2
- 229920001225 polyester resin Polymers 0.000 claims description 2
- 239000004645 polyester resin Substances 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 2
- 239000010410 layer Substances 0.000 claims 18
- 239000011256 inorganic filler Substances 0.000 claims 1
- 229910003475 inorganic filler Inorganic materials 0.000 claims 1
- 229920006122 polyamide resin Polymers 0.000 claims 1
- 239000011241 protective layer Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 8
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 238000000034 method Methods 0.000 description 16
- 239000006224 matting agent Substances 0.000 description 7
- 238000007639 printing Methods 0.000 description 6
- 238000007788 roughening Methods 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000020 Nitrocellulose Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004695 Polyether sulfone Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 239000013040 bath agent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、サーマルヘッドやサーマルペンを用いて転写
方式により文字や画［象を記録する熱転写記録法に用い
る感熱転写記録体に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a thermal transfer recording medium used in a thermal transfer recording method for recording characters and images by a transfer method using a thermal head or a thermal pen.
（従来の技術）
近年、サーマルヘッドを用いた感熱転写記録方式は、記
録装置が比較的低価格であること、印字時の騒音が少な
いこと、記録装置の保守が容易なこと、カラー記録が容
易なこと、などの利点により急速に普及ｂ；進んでいる
。(Prior art) In recent years, thermal transfer recording methods using thermal heads have been developed with the following advantages: the recording device is relatively inexpensive, there is little noise during printing, the recording device is easy to maintain, and color recording is easy. It is rapidly becoming popular due to its advantages such as:
この記録方式に用いられる記録媒体、すなわち感熱転写
記録材においては、基材の一方の面に少なくとも熱溶融
性の組成物からなる感熱転写層を設けたものが用いられ
るが、従来の感熱転写記録材では、印字物の表面光沢が
他の方式に比べて大きく、印字物の表面の艶消しの可能
な記録材が求められていた。The recording medium used in this recording method, that is, the heat-sensitive transfer recording material, is one in which a heat-sensitive transfer layer made of a heat-melting composition is provided on one side of the base material. The surface gloss of printed matter is higher than that of other methods, and there has been a demand for a recording material that can make the surface of printed matter matte.
感熱転写記録材の構成上、印字物の表面の艶消し７行な
う方法としては、たとえば特公昭６０−１０１０８４号
に開示されているように、基材の表面？粗面化する方法
、特公昭６０−１０１０８５号に開示されているように
、転写インキ中にマット剤を混入する方法、あるいは特
公昭６０−１０１０８６号に開示されているように、基
材表面に粗面化１■を設ける方法などが提案されている
。Due to the structure of the thermal transfer recording material, methods for matting the surface of the printed matter include, for example, the surface of the base material as disclosed in Japanese Patent Publication No. 101084/1984. As disclosed in Japanese Patent Publication No. 60-101085, a matting agent is mixed into the transfer ink. A method of providing surface roughening 1■ has been proposed.
しかしながら、これらの方法、すなわち基材の表面を粗
面化し、その粗面乞転写された転写層の表面に形成しよ
うとする方法と、転写層自体にマット剤？混入し、その
表面での粗面化効果に期待する方法はいずれも充分かつ
安定した粗面化効果？上げる上で難点があった。前者の
方法は一般的に転写により表面形状？も同時に転写する
技術の転用であるが、この技術は、熱転写時に用いる場
合には、転写層り一基材との剥離時に表面形状が以後変
化しない程度に固化し７ていることが必要であり、サー
マルヘッドによる転写の如く、高温転写。However, these methods, that is, the method of roughening the surface of the base material and forming the roughened surface on the surface of the transferred transfer layer, and the method of using a matting agent on the transfer layer itself? Do any of the methods in which the mixture is mixed and expected to have a roughening effect on the surface produce a sufficient and stable surface roughening effect? There were some difficulties in raising it. Is the former method generally based on the surface shape by transfer? This technology is a reuse of the simultaneous transfer technology, but when used during thermal transfer, it is necessary that the transfer layer is solidified to the extent that the surface shape does not change after peeling from the base material. , high-temperature transfer, such as transfer using a thermal head.
高速剥離の場合に、この条件？安定して満たすのはきわ
めて困難である。後者の方法は一般に塗装の艶消しに用
いられる方法の転用であるが、上と同じ理由でサーマル
ヘッドによる転写の場合には。Is this condition necessary for high-speed peeling? It is extremely difficult to satisfy this requirement stably. The latter method is a repurposing of the method generally used for matting paint, but for the same reasons as above when transferring with a thermal head.
マット剤が表面に分布する時間的間隔が小さく。The time interval during which the matting agent is distributed on the surface is short.
マット剤表面への熱溶融成分のぬれもあり、粗面化効果
を上げるためのマット剤の添加量が多く必要である割に
は安定した粗面を形成するのが困難である。The surface of the matting agent may be wetted by the heat-melting component, and it is difficult to form a stable roughened surface even though a large amount of the matting agent is required to increase the surface roughening effect.
（発明の目的）
本発明は以上のような事情に鑑みなされたものであり、
印字物の表面艶消しの可能な熱転写リボン、感熱転写シ
ート等の感熱転写記録体の提供を目的とする。(Object of the invention) The present invention has been made in view of the above circumstances,
The purpose of the present invention is to provide a thermal transfer recording material such as a thermal transfer ribbon or a thermal transfer sheet that can make the surface of printed matter matte.
（目的を達成するための手段） 上記の目的を達成するために１本発明者等は。(Means to achieve the purpose) In order to achieve the above object, the present inventors.
サーマルヘッドによる転写時の熱的状況の覗察テ基づき
、印字物表面の粗面化方法を鋭意検討した結果、従来の
方法とは全く異なる原理に基き、転写剥離時の剥離界面
近傍の組成物層の凝集破壊乞利用して２印字物表面の艶
消し２行なうことが可能であることを見出し１本発明を
完成するに至った。Based on observations of the thermal conditions during transfer using a thermal head, we conducted a thorough study on a method for roughening the surface of printed matter. Based on a completely different principle from conventional methods, we developed a composition near the peeling interface during transfer peeling. The present inventors discovered that it is possible to make the surface of a printed matter matte by utilizing the cohesive failure of the layer, thereby completing the present invention.
本発明の感熱転写記録材（５）の構成としては、基本的
には、第１図に示すようにプラスチックフィルム等の基
材（１）、アンカー層（２）、感熱転写層（３）とから
なる、アンカー層と感熱転写層の界面近傍で剥離時に凝
集破壊？起こし、その結果、被転写物の表面に転移した
感熱転写層の表面が粗面化されるようにアンカー層の材
料が設定されている。The structure of the thermal transfer recording material (5) of the present invention basically includes a base material (1) such as a plastic film, an anchor layer (2), and a thermal transfer layer (3) as shown in FIG. Cohesive failure occurs near the interface between the anchor layer and the thermal transfer layer when peeled off? The material of the anchor layer is set so that the surface of the heat-sensitive transfer layer transferred to the surface of the transfer object is roughened.
基材（１）としては、ポリエステルフィルム等の耐熱性
プラスチックフィルム、コンデンサー紙等ノ紙のいずれ
でもよく、また、スティッキング防止のだめの背面処理
、後述するアンカー層（２）との接Ｍ￥強化するための
表面処理があってもよい。The base material (1) may be a heat-resistant plastic film such as a polyester film or a paper such as a capacitor paper, and may also be treated with a back surface to prevent sticking and strengthen the contact with the anchor layer (2) described later. There may be surface treatment for this purpose.
感熱転写層（３）としては、ワックス、熱可塑性樹脂等
のバインダーに着色剤？混入したものを基礎とし、必要
な添加剤を入れたものにより形成したもの６”−使用で
きる。The thermal transfer layer (3) uses a binder such as wax or thermoplastic resin, and a coloring agent. 6" - can be used based on mixed materials and with necessary additives.
アンカー層（２）としては、まず基材（１）との接着性
が強く、かつ全体として転写時の熱変形に耐える程度の
耐熱性を有することｂ′−必要である。The anchor layer (2) must have strong adhesion to the base material (1) and have heat resistance as a whole to withstand thermal deformation during transfer.
また、このアンカー層（２）は、前記構成の感熱転写層
（３）と基材（１）との間に、感熱転写１＊ （３）と
アンカーｌ１ｌＪ ｔ２）の凝集力が基材（１）とアン
カー層（２）の結合力とアンカー層（２）２感熱転写層
（３）の結合力並びに感熱転写時における感熱転写層（
３）と受像体の結合力より小さくなるように設ける。ア
ンカー瑠（２）と感熱転写層（３）？このようにすると
、感熱転写時にアンカー層（２）と感熱転写層（３）と
の界面近傍で両層のいずれかの層で凝集破壊を起こすよ
うになり、受像体（被転写体）上の印字面において十分
な艶消し効果が得られることになる、
この条件？満たすアンカー層（２）の組成としては耐熱
性成分と接着性成分の以下の様な組合せがあげられる。In addition, this anchor layer (2) has a structure in which the cohesive force of the thermal transfer 1* (3) and the anchor l1lJ t2) is applied to the base material (1 ) and the anchor layer (2), the bonding force between the anchor layer (2) and the thermal transfer layer (3), and the thermal transfer layer (3) during thermal transfer.
3) and the image receptor so that the bonding force is smaller than that of the image receptor. Anchor Ru (2) and thermal transfer layer (3)? If this is done, cohesive failure will occur in one of the layers near the interface between the anchor layer (2) and the heat-sensitive transfer layer (3) during thermal transfer, resulting in Are these conditions enough to obtain a sufficient matte effect on the printed surface? The composition of the anchor layer (2) that satisfies this requirement includes the following combinations of heat-resistant components and adhesive components.
耐熱性成分としては、ニトロセルロース等のセルロース
誘導体、ポリイミド樹脂、ポリサルホン（！し１旨、ポ
リエーテルサルホン樹脂、シリコーン樹ｑ’＆、ｘ−ホ
キシａｌＩ旨、メラミン樹月旨、フェノール樹脂、弗素
樹脂等の熱可塑性及び熱硬化性樹脂、接着性成分として
は、ポリアミド（ｉｔ Ｂ＆、ポリエステル樹脂、アク
リル樹脂、−１−チレンー酢酸ビニル共重合捧、４化ゴ
ム、塩化ゴム、スチレン−ブタジェン共重合体、スチレ
ン−ブタジェン−スチレン共重合体、ロジン誘導体、ケ
トン樹脂、スチレン樹脂、ポリエステルポリオール、ア
クリルポリオール、天然ワックス、合成ワックス、ポリ
オレフィンワックス等のポリマー？それぞれ挙げること
ができる。Heat-resistant components include cellulose derivatives such as nitrocellulose, polyimide resin, polysulfone (!), polyethersulfone resin, silicone q'&, x-phoxy alI, melamine resin, phenolic resin, fluorine Thermoplastic and thermosetting resins such as resins, adhesive components include polyamide (IT B&, polyester resin, acrylic resin, -1-tyrene-vinyl acetate copolymer, tetrachloride rubber, chloride rubber, styrene-butadiene copolymer) polymers such as styrene-butadiene-styrene copolymers, rosin derivatives, ketone resins, styrene resins, polyester polyols, acrylic polyols, natural waxes, synthetic waxes, and polyolefin waxes.
以上の成分の組合せ方法及び比率は先に述べた条件を満
たすように基材、感熱転写層およびプリンターの印字条
件？考（ばして決定されるｂ″−１代表的な構成例を実
施例に示す。Is the method and ratio of the combination of the above components so as to satisfy the conditions mentioned above, the base material, the thermal transfer layer, and the printing conditions of the printer? A representative configuration example of b''-1 determined by consideration is shown in Examples.
（発明の効果） 本発明の感熱転写記録体を用いることにより。(Effect of the invention) By using the thermal transfer recording material of the present invention.
サーマルヘッド？用いた熱転写記録の印字表面の艶を消
すことができるが、さらに次のような諸効果を奏する。Thermal head? The gloss of the printed surface of the thermal transfer recording used can be erased, and the following effects are also produced.
（１）マット剤を用いる従来の方法に比べて１表面形状
がより微細に粗面化されるρで自然でかつ艶消しの程度
の高い印字面が得られる。(1) Compared to the conventional method using a matting agent, a printed surface that is natural and has a high degree of matteness can be obtained with ρ, in which the surface shape is more finely roughened.
（２）印字条件、エネルギーの広い範囲での艶消効果ｂ
′−得られる。(2) Matting effect b over a wide range of printing conditions and energy
′-obtained.
（３）マット剤ヲ使用しないので、アンカー層の塗工が
容易であり、かつ薄膜化ｈ；できるため、低エネルギー
での印字性？阻害しない。(3) Since no matting agent is used, it is easy to apply the anchor layer, and it is possible to form a thin film, so it is possible to print with low energy. Does not interfere.
（実施例）
厚さ５，７μのポリエステル延伸フィルムニ、表１に示
すアンカー剤を塗布し、浴剤を揮散させて厚み１．０μ
のアンカー層を形成した。次に表２に示す熱転写性イン
キシアンカー層上に３．５μ厚に塗布して感熱転写層？
設け、転写リボンを作成した。(Example) A polyester stretched film with a thickness of 5.7 μm was coated with the anchoring agent shown in Table 1, and the bath agent was evaporated to give a thickness of 1.0 μm.
An anchor layer was formed. Next, coat the thermal transferable ink anchor layer shown in Table 2 to a thickness of 3.5μ to form a thermal transfer layer.
A transfer ribbon was created.
別に比較例として、厚さ５．７μのポリニスチル延伸フ
ィルムに表２に示す熱転写性インキ乞３．５μ厚に塗布
して感熱転写層を設け、転写リボンを作成した。Separately, as a comparative example, a heat-sensitive transfer layer was provided by applying the heat-transferable ink shown in Table 2 to a thickness of 3.5 μm on a stretched polynystil film having a thickness of 5.7 μm to prepare a transfer ribbon.
上記２種類の熱転写リボン？使用して、ラインタイプの
サーマルヘッドを備えたプリンターでベック平滑度５０
０秒坪量５０９ ／ ｍの被転写紙に印字を行なった。The above two types of thermal transfer ribbons? Use a printer with a line type thermal head to achieve Beck smoothness of 50.
Printing was performed on transfer paper having a basis weight of 509/m.
〔表１〕 アンカー剤組成
ニトロセルロースｍＢｆｉ １７ ｉｆｆ量部ポ
リアミド餌月旨 ６ 〃トルエン
５０重量部イソプロピルアルコール
２０ 〃酢酸エチル ７ 〃
〔表２〕インキ組成
カルナバワックス ５０重量部ライスワック
ス ３０ 〃エチレン酢酸ビニル共重合体
６ 〃ノニオン界面活性剤 ２ 〃カー
ボンブラック １２ 〃この印字物の印字表
面を目視及び６０°光沢計で光沢度を測定した、
目視による比較では１本発明の実施例の熱転写リボン？
用いた印字物はほとんど完全に艶カー消えており、比較
例の熱転写リボンを用いた印字物の表面が著しく光沢が
あるのと対照的であった、光沢度を比較したところ１本
発明の熱転写リボンを用いた印字物の印字表面は１０％
±６．２％であり、比較例の熱転写リボン？用いた印字
物の印字表面は７５％±５．６％であったー[Table 1] Anchor agent composition Nitrocellulose mBfi 17 if part polyamide bait 6 toluene
50 parts by weight Isopropyl alcohol 20 Ethyl acetate 7
[Table 2] Ink composition Carnauba wax 50 parts by weight Rice wax 30 Ethylene-vinyl acetate copolymer 6 Nonionic surfactant 2 Carbon black 12 Glossiness of the printed surface was measured visually and with a 60° gloss meter. In the measured and visual comparison, 1 thermal transfer ribbon of the embodiment of the present invention?
The gloss of the printed matter almost completely disappeared, which was in contrast to the extremely glossy surface of the printed matter obtained using the thermal transfer ribbon of the comparative example.A comparison of the glossiness showed that the thermal transfer ribbon of the present invention The printing surface of printed items using ribbon is 10%
±6.2%, and the thermal transfer ribbon of the comparative example? The printing surface of the printed material used was 75% ± 5.6%.
第１図：ｉ本発明の詳細な説明口である。 FIG. 1 is a detailed explanation of the present invention.
Claims (5)
る感熱転写層を少なくとも設けてなる感熱転写記録材に
おいて、該感熱転写層と該基材との間にアンカー層を、
該感熱転写層と該アンカー層の凝集力が該基材と該アン
カー層の結合力と該アンカー層と該感熱転写層の結合力
並びに感熱転写時における該感熱転写層と受像体の結合
力より小さくなるように設定してあり、感熱転写時に該
アンカー層と該感熱転写層との界面近傍で両層のいずれ
かの層で凝集破壊を起こすようにしてあることを特徴と
する感熱転写記録材。(1) In a thermal transfer recording material comprising at least a heat-sensitive transfer layer containing a heat-melting composition as a main component on one side of a base material, an anchor layer is provided between the heat-sensitive transfer layer and the base material. ,
The cohesive force between the thermal transfer layer and the anchor layer is determined by the bonding force between the base material and the anchor layer, the bonding force between the anchor layer and the thermal transfer layer, and the bonding force between the thermal transfer layer and the image receptor during thermal transfer. A thermal transfer recording material, characterized in that the size is set to be smaller, and cohesive failure occurs in either layer of the anchor layer and the thermal transfer layer near the interface between the anchor layer and the thermal transfer layer during thermal transfer. .
リアミド樹脂、ポリエステル樹脂、アクリル樹脂、エチ
レン−酢酸ビニル共重合体、環化ゴム、塩化ゴム、スチ
レンブタジエン共重合体、スチレン−ブタジエン−スチ
レン共重合体、ロジン誘導体、ケトン樹脂、スチレン樹
脂、ポリエステルポリオール、アクリルポリオール、天
然ワックス、合成ワックス、ポリオレフィンワックスの
いずれかより選ばれた材料とからなる組成物より成るこ
とを特徴とする特許請求の範囲第１項記載の感熱転写記
録材。(2) The anchor layer is made of resin with a softening point of 100°C or higher, polyamide resin, polyester resin, acrylic resin, ethylene-vinyl acetate copolymer, cyclized rubber, chlorinated rubber, styrene-butadiene copolymer, styrene-butadiene- A patent claim characterized in that the composition comprises a material selected from any one of styrene copolymers, rosin derivatives, ketone resins, styrene resins, polyester polyols, acrylic polyols, natural waxes, synthetic waxes, and polyolefin waxes. The thermal transfer recording material according to item 1.
とする特許請求の範囲第１項又は第２項記載の感熱転写
記録材。(3) The thermal transfer recording material according to claim 1 or 2, wherein the anchor layer does not contain an inorganic filler.
許請求の範囲第１項〜第３項のいずれかに記載の感熱転
写記録材。(4) The thermal transfer recording material according to any one of claims 1 to 3, wherein the anchor layer contains a colorant.
層が、形成されていない他方の面にはスティックング防
止のための保護層が形成してあることを特徴とする特許
請求の範囲第１項〜第４項のいずれかに記載の感熱転写
記録体。(5) The base material is made of a plastic film, and a protective layer for preventing sticking is formed on the other surface on which the heat-sensitive transfer layer is not formed. The thermal transfer recording material according to any one of items 1 to 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61205549A JPS6360794A (en) | 1986-09-01 | 1986-09-01 | Thermal transfer recording medium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61205549A JPS6360794A (en) | 1986-09-01 | 1986-09-01 | Thermal transfer recording medium |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6360794A true JPS6360794A (en) | 1988-03-16 |
| JPH0455600B2 JPH0455600B2 (en) | 1992-09-03 |
Family
ID=16508729
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61205549A Granted JPS6360794A (en) | 1986-09-01 | 1986-09-01 | Thermal transfer recording medium |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6360794A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS641585A (en) * | 1987-03-17 | 1989-01-05 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
| EP0316674A2 (en) * | 1987-11-17 | 1989-05-24 | Pelikan GmbH | Thermally sensitive dye ribbon |
| JPH01263083A (en) * | 1988-04-15 | 1989-10-19 | Mitsubishi Paper Mills Ltd | Thermal transfer recording sheet |
| JPH01262190A (en) * | 1988-04-13 | 1989-10-19 | Mitsubishi Paper Mills Ltd | Thermal transfer recording sheet |
| JPH01290493A (en) * | 1988-05-18 | 1989-11-22 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
| JPH0281681A (en) * | 1988-09-20 | 1990-03-22 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
| JPH0334894A (en) * | 1989-06-30 | 1991-02-14 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
| JPH0334893A (en) * | 1989-06-30 | 1991-02-14 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
| JPH0338383A (en) * | 1989-07-05 | 1991-02-19 | Dainichiseika Color & Chem Mfg Co Ltd | Thermal transfer recording sheet |
| JPH0372352A (en) * | 1989-08-11 | 1991-03-27 | Toyo Ink Mfg Co Ltd | Opaque material |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55169449U (en) * | 1979-05-23 | 1980-12-05 | ||
| JPS58114987A (en) * | 1981-12-28 | 1983-07-08 | Toppan Printing Co Ltd | Transfer sheet |
| JPS58208088A (en) * | 1982-05-28 | 1983-12-03 | Oike Kogyo Kk | Transfer foil for hot stamping |
| JPS6040294A (en) * | 1983-08-12 | 1985-03-02 | Hitachi Chem Co Ltd | Thermal transfer film |
| JPS6049998A (en) * | 1983-08-30 | 1985-03-19 | Fujitsu Ltd | Ink sheet for thermal transfer recording |
| JPS60101083A (en) * | 1983-11-08 | 1985-06-05 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS60109897A (en) * | 1983-11-18 | 1985-06-15 | Toshiba Corp | Ink carrier for thermal transfer recording |
| JPS60127191A (en) * | 1983-12-14 | 1985-07-06 | Konishiroku Photo Ind Co Ltd | Thermal transfer recording medium |
-
1986
- 1986-09-01 JP JP61205549A patent/JPS6360794A/en active Granted
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55169449U (en) * | 1979-05-23 | 1980-12-05 | ||
| JPS58114987A (en) * | 1981-12-28 | 1983-07-08 | Toppan Printing Co Ltd | Transfer sheet |
| JPS58208088A (en) * | 1982-05-28 | 1983-12-03 | Oike Kogyo Kk | Transfer foil for hot stamping |
| JPS6040294A (en) * | 1983-08-12 | 1985-03-02 | Hitachi Chem Co Ltd | Thermal transfer film |
| JPS6049998A (en) * | 1983-08-30 | 1985-03-19 | Fujitsu Ltd | Ink sheet for thermal transfer recording |
| JPS60101083A (en) * | 1983-11-08 | 1985-06-05 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS60109897A (en) * | 1983-11-18 | 1985-06-15 | Toshiba Corp | Ink carrier for thermal transfer recording |
| JPS60127191A (en) * | 1983-12-14 | 1985-07-06 | Konishiroku Photo Ind Co Ltd | Thermal transfer recording medium |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS641585A (en) * | 1987-03-17 | 1989-01-05 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
| EP0316674A2 (en) * | 1987-11-17 | 1989-05-24 | Pelikan GmbH | Thermally sensitive dye ribbon |
| US4995741A (en) * | 1987-11-17 | 1991-02-26 | Pelikan Aktiengesellschaft | Thermal print-transfer ribbon |
| JPH01262190A (en) * | 1988-04-13 | 1989-10-19 | Mitsubishi Paper Mills Ltd | Thermal transfer recording sheet |
| JPH01263083A (en) * | 1988-04-15 | 1989-10-19 | Mitsubishi Paper Mills Ltd | Thermal transfer recording sheet |
| JPH01290493A (en) * | 1988-05-18 | 1989-11-22 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
| JPH0281681A (en) * | 1988-09-20 | 1990-03-22 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
| JPH0334894A (en) * | 1989-06-30 | 1991-02-14 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
| JPH0334893A (en) * | 1989-06-30 | 1991-02-14 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
| JPH0338383A (en) * | 1989-07-05 | 1991-02-19 | Dainichiseika Color & Chem Mfg Co Ltd | Thermal transfer recording sheet |
| JPH0372352A (en) * | 1989-08-11 | 1991-03-27 | Toyo Ink Mfg Co Ltd | Opaque material |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0455600B2 (en) | 1992-09-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS61206693A (en) | Thermal transfer recording medium | |
| JPH04220380A (en) | Ink ribbon for thermal transfer printer | |
| JPS6360794A (en) | Thermal transfer recording medium | |
| JP3096691B2 (en) | Thermal transfer cover film | |
| JPS62108090A (en) | Thermal transfer ribbon | |
| JP4467853B2 (en) | Thermal transfer film, image forming method and image formed product using the same | |
| JP4478361B2 (en) | Thermal transfer film, image forming method and image formed product using the same | |
| JPS6237191A (en) | Thermal transfer material | |
| JPH06102392B2 (en) | Thermal transfer ink ribbon for dry transfer material manufacturing | |
| JP2762444B2 (en) | Ink ribbon for dry transfer material production | |
| WO1993001058A1 (en) | Thermal transfer ink sheet for forming color image | |
| JPS61295080A (en) | Heat sensitive transfer material | |
| JPH08112969A (en) | Thermal transfer recording material | |
| JPS63128991A (en) | Ink ribbon for production of dry transfer material | |
| JP3384377B2 (en) | Thermal transfer recording medium and image forming method | |
| JPH03219989A (en) | Ink ribbon for dry transfer material | |
| JPH0316776A (en) | Ink ribbon for dry transfer material manufacture | |
| JPS63128990A (en) | Ink ribbon for production of dry transfer material | |
| JP2003211856A (en) | Thermal transfer recording medium, image receiving sheet and method for forming image using them | |
| JPS62201290A (en) | Sublimation type thermal transfer image receiving member | |
| JP2001347761A (en) | Heat sensitive transfer medium | |
| JPH0780357B2 (en) | Thermal transfer ribbon | |
| JPH04173378A (en) | Thermal transfer ink ribbon | |
| JPH0316775A (en) | Ink ribbon for manufacture of dry transfer material | |
| JPH0289689A (en) | Thermal transfer recording medium |