JPH0455600B2 - - Google Patents
Info
- Publication number
- JPH0455600B2 JPH0455600B2 JP61205549A JP20554986A JPH0455600B2 JP H0455600 B2 JPH0455600 B2 JP H0455600B2 JP 61205549 A JP61205549 A JP 61205549A JP 20554986 A JP20554986 A JP 20554986A JP H0455600 B2 JPH0455600 B2 JP H0455600B2
- Authority
- JP
- Japan
- Prior art keywords
- resins
- layer
- thermal transfer
- anchor layer
- recording material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 claims description 24
- 229920005989 resin Polymers 0.000 claims description 11
- 239000011347 resin Substances 0.000 claims description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- -1 and fluororesins Polymers 0.000 claims description 4
- 239000000020 Nitrocellulose Substances 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive effect Effects 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 claims description 3
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 3
- 229920001220 nitrocellulos Polymers 0.000 claims description 3
- 239000002985 plastic film Substances 0.000 claims description 3
- 229920006255 plastic film Polymers 0.000 claims description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 3
- 229920006122 polyamide resin Polymers 0.000 claims description 3
- 239000005060 rubber Substances 0.000 claims description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000877 Melamine resin Polymers 0.000 claims description 2
- 239000004695 Polyether sulfone Substances 0.000 claims description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 2
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 229920001568 phenolic resin Polymers 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- 229920002492 poly(sulfone) Polymers 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 229920005906 polyester polyol Polymers 0.000 claims description 2
- 229920001225 polyester resin Polymers 0.000 claims description 2
- 239000004645 polyester resin Substances 0.000 claims description 2
- 229920006393 polyether sulfone Polymers 0.000 claims description 2
- 229920001721 polyimide Polymers 0.000 claims description 2
- 239000009719 polyimide resin Substances 0.000 claims description 2
- 229920005862 polyol Polymers 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 229920002050 silicone resin Polymers 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 2
- 239000010410 layer Substances 0.000 claims 6
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 239000011241 protective layer Substances 0.000 claims 1
- 238000000034 method Methods 0.000 description 20
- 230000000694 effects Effects 0.000 description 7
- 239000006224 matting agent Substances 0.000 description 6
- 238000007788 roughening Methods 0.000 description 6
- 239000001993 wax Substances 0.000 description 5
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、サーマルヘツドやサーマルペンを用
いて転写方式により文字や画像を記録する熱転写
記録法に用いる感熱転写記録体に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a thermal transfer recording medium used in a thermal transfer recording method in which characters and images are recorded by a transfer method using a thermal head or a thermal pen.
（従来の技術）
近年、サーマルヘツドを用いた感熱転写記録方
式は、記録装置が比較的低価格であること、印字
時の騒音が少ないこと、記録装置の保守が容易な
こと、カラー記録が容易なこと、などの利点によ
り急速に普及が進んでいる。(Prior art) In recent years, thermal transfer recording methods using thermal heads have been developed because the recording device is relatively inexpensive, there is little noise during printing, the recording device is easy to maintain, and color recording is easy. It is rapidly becoming popular due to its advantages such as:
この記録方式に用いられる記録媒体、すなわち
感熱転写記録材においては、基材の一方の面に少
なくとも熱溶融性の組成物からなる感熱転写層を
設けたものが用いられるが、従来の感熱転写記録
材では、印字物の表面光沢が他の方式に比べて大
きく、印字物の表面の艶消しの可能な記録材が求
められていた。 The recording medium used in this recording method, that is, the heat-sensitive transfer recording material, is one in which a heat-sensitive transfer layer made of a heat-melting composition is provided on one side of the base material. The surface gloss of printed matter is higher than that of other methods, and there has been a demand for a recording material that can make the surface of printed matter matte.
感熱転写記録材の構成上、印字物の表面の艶消
しを行なう方法としては、たとえば特開昭60−
101084号に開示されているように、基材の表面を
粗面化する方法、特開昭60−101083号及び特開昭
60−101085号に開示されているように、転写イン
キ中にマツト材を混入する方法、特開昭60−
101086号に開示されているように、基材表面に粗
面化層を設ける方法などが提案されている。 Due to the structure of the thermal transfer recording material, methods for matting the surface of printed matter include, for example,
101084, a method for roughening the surface of a base material, JP-A-60-101083 and JP-A-Sho.
60-101085, a method of mixing pine wood into transfer ink, JP-A-60-
As disclosed in No. 101086, a method of providing a roughened layer on the surface of a base material has been proposed.
しかしながら、これらの方法、すなわち基材の
表面を粗面化し、その粗面を転写された転写層の
表面に形成しようとする方法と、転写層自体にマ
ツト剤を混入し、その表面での粗面化効果に期待
する方法はいずれも充分かつ安定した粗面化効果
を上げる上で難点があつた。前者の方法は一般的
に転写により表面形状をも同時に転写する技術の
転用であるが、この技術は、熱転写時に用いる場
合には、転写層が基材との剥離時に表面形状が以
後変化しない程度に固化していることが必要であ
り、サーマルヘツドによる転写の如く、高温転
写、高速剥離の場合に、この条件を安定した満た
すのはきわめて困難である。後者の方法は一般に
塗装の艶消しに用いられる方法の転用であるが、
上と同じ理由でサーマルヘツドによる転写の場合
には、マツト剤が表面に分布する時間的間隔が小
さく、マツト剤表面への熱溶融成分のぬれもあ
り、粗面化効果を上げるためのマツト剤の添加量
が多く必要である割には安定した粗面を形成るの
が困難である。 However, these methods, namely the method of roughening the surface of the base material and forming the rough surface on the surface of the transferred transfer layer, and the method of mixing a matting agent into the transfer layer itself and creating a rough surface on the surface. All of the methods that are expected to achieve a surface roughening effect have had difficulties in achieving a sufficient and stable surface roughening effect. The former method is generally a reuse of the technology that also transfers the surface shape at the same time, but when used during thermal transfer, this technique is used to ensure that the surface shape does not change after the transfer layer is peeled from the base material. It is extremely difficult to stably satisfy this condition in the case of high-temperature transfer and high-speed peeling, such as transfer using a thermal head. The latter method is a repurposing of the method generally used for matting paint;
For the same reason as above, in the case of transfer using a thermal head, the time interval during which the matting agent is distributed on the surface is short, and the matting agent surface is wetted by the hot melt component, so that the matting agent is used to increase the roughening effect. It is difficult to form a stable rough surface even though a large amount of is required.
（発明の目的）
本発明は以上のような事情に鑑みなされたもの
であり、印字物の表面艶消しの可能な熱転写リボ
ン、感熱転写シート等の感熱転写記録体の提供を
目的とする。(Objective of the Invention) The present invention was made in view of the above-mentioned circumstances, and an object of the present invention is to provide a thermal transfer recording medium such as a thermal transfer ribbon or a thermal transfer sheet, which can make the surface of printed matter matte.
（目的を達成するための手段）
上記の目的を達成するために、本発明者等は、
サーマルヘツドによる転写時の熱的状況の観察に
基づき、印刷物表面の粗面化方法を鋭意検討した
結果、従来の方法とは全く異なる原理に基き、転
写剥離時にアンカー層を凝集破壊することによつ
て、印字物表面の艶消しを行なうことが可能であ
ることを見出し、本発明を完成するに至つた。(Means for achieving the purpose) In order to achieve the above purpose, the inventors
Based on the observation of the thermal conditions during transfer using a thermal head, we conducted a thorough study on a method for roughening the printed surface. Based on a completely different principle from conventional methods, we developed a method that causes cohesive failure of the anchor layer during transfer peeling. Therefore, the inventors discovered that it is possible to make the surface of printed matter matte, and completed the present invention.
本発明の感熱転写記録材５の構成としては、基
本的には、第１図に示すようにプラスチツクフイ
ルム等の基材１、アンカー層２、感熱転写層３と
からなる。アンカー層が凝集破壊を起こし、その
結果、被転写物の表面に転移した感熱転写層の表
面が粗面化されるようにアンカー層の材料が設定
されている。 The thermal transfer recording material 5 of the present invention basically comprises a base material 1 such as a plastic film, an anchor layer 2, and a thermal transfer layer 3, as shown in FIG. The material of the anchor layer is set so that the anchor layer causes cohesive failure, and as a result, the surface of the heat-sensitive transfer layer transferred to the surface of the transfer object is roughened.
基材１としては、ポリエステルフイルム等の耐
熱性プラスチツクフイルム、コンデンサー紙等の
紙のいずれでもよく、また、ステイツキング防止
のための背面処理、後述するアンカー層２との接
着を強化するための表面処理があつてもよい。 The base material 1 may be a heat-resistant plastic film such as a polyester film or a paper such as a condenser paper, and may also be treated with a back surface to prevent staking and a surface to strengthen adhesion with the anchor layer 2 described later. There may be some processing.
感熱転写層３としては、ワツクス、熱可塑性樹
脂等のバインダーに着色剤を混入したものを基礎
とし、必要な添加剤を入れたものにより形成した
ものが使用できる。 The heat-sensitive transfer layer 3 may be formed from a binder such as wax or thermoplastic resin mixed with a coloring agent, and the necessary additives added thereto.
アンカー層２としては、まず基材１との接着性
が強く、かつ全体として転写時の熱変形に耐える
程度の耐熱性を有することが必要である。 First, the anchor layer 2 needs to have strong adhesion to the base material 1 and to have heat resistance as a whole to withstand thermal deformation during transfer.
また、このアンカー層２は、前記構成の感熱転
写層３と基材１との間に、アンカー層２の凝集力
が基材１とアンカー層２の結合力とアンカー層２
と感熱転写層３の結合力並びに感熱転写時におけ
る感熱転写層３と受像体の結合力より小さくなる
ように設ける。アンカー層２をこのようにする
と、感熱転写時にアンカー層２で凝集破壊を起こ
し、受像体（被転写体）上の印字物の表面が粗面
化することにより、十分な艶消し効果が得られる
ことになる。 In addition, this anchor layer 2 has a structure in which the cohesive force of the anchor layer 2 is equal to the bonding force between the base material 1 and the anchor layer 2 and the anchor layer 2 between the thermal transfer layer 3 having the above structure and the base material 1.
and the thermal transfer layer 3 and the bonding force between the thermal transfer layer 3 and the image receptor during thermal transfer. When the anchor layer 2 is formed in this way, cohesive failure occurs in the anchor layer 2 during thermal transfer, and the surface of the printed matter on the image receptor (transferred object) becomes rough, thereby obtaining a sufficient matting effect. It turns out.
この条件を満たすアンカー層２の組成としては
耐熱性成分と接着性成分の以下の様な組合せがあ
げられる。 The composition of the anchor layer 2 that satisfies this condition includes the following combinations of heat-resistant components and adhesive components.
耐熱性成分としては、ニトロセルロース等のセ
ルロース誘導体、ポリイミド樹脂、ポリサルホン
樹脂、ポリエーテルサルホン樹脂、シリコーン樹
脂、エポキシ樹脂、メラミン樹脂、フエノール樹
脂、弗素樹脂等の熱可塑性及び熱硬化性樹脂、接
着性成分としては、ポリアミド樹脂、ポリエステ
ル樹脂、アクリル樹脂、エチレン−酢酸ビニル共
重合体、環化ゴム、塩化ゴム、スチレン−ブタジ
エン共重合体、スチレン−ブタジエ−スチレン共
重合体、ロジン誘導体、ケトン樹脂、スチレン樹
脂、ポリエステルポリオール、アクリルポリオー
ル、天然ワツクス、合成ワツクス、ポリオレフイ
ンワツクス等のポリマーをそれぞれ挙げることが
できる。 Heat-resistant components include cellulose derivatives such as nitrocellulose, thermoplastic and thermosetting resins such as polyimide resins, polysulfone resins, polyethersulfone resins, silicone resins, epoxy resins, melamine resins, phenolic resins, and fluororesins, and adhesives. Polyamide resin, polyester resin, acrylic resin, ethylene-vinyl acetate copolymer, cyclized rubber, chlorinated rubber, styrene-butadiene copolymer, styrene-butadiene-styrene copolymer, rosin derivative, ketone resin. , styrene resins, polyester polyols, acrylic polyols, natural waxes, synthetic waxes, and polyolefin waxes.
以上の成分の組合せ方法及び比率は先に述べた
条件を満たすように基材、感熱転写層およびプリ
ンターの印字条件を考慮して決定されるが、代表
的な構成例を実施例に示す。 The combination method and ratio of the above components are determined in consideration of the substrate, the heat-sensitive transfer layer, and the printing conditions of the printer so as to satisfy the above-mentioned conditions, and typical configuration examples are shown in Examples.
（発明の効果）
本発明の感熱転写記録体を用いることにより、
サーマルヘツドを用いた熱転写記録の印字表面の
艶を消すことができるが、さらに次のような諸効
果を奏する。(Effects of the invention) By using the thermal transfer recording material of the invention,
It is possible to eliminate the gloss on the printed surface of thermal transfer recording using a thermal head, but it also has the following effects.
(1) マツト剤を用いる従来の方法に比べて、表面
形状がより微細に粗面化されるので自然でかつ
艶消しの程度の高い印字面が得られる。(1) Compared to the conventional method using a matting agent, the surface shape is more finely roughened, so a natural and highly matte printed surface can be obtained.
(2) 印字条件、エネルギーの広い範囲での艶消効
果が得られる。(2) A matte effect can be obtained under a wide range of printing conditions and energies.
(3) マツト剤を使用しないので、アンカー層の塗
工が容易であり、かつ薄膜化ができるため、低
エネルギーでの印字性を阻害しない。(3) Since no matting agent is used, the anchor layer can be easily applied and can be made into a thin film, so it does not impede printing performance at low energy.
（実施例）
厚さ5.7μのポリエステル延伸フイルムに、表１
に示すアンカー剤を塗布し、溶剤を揮散させて厚
み1.0μのアンカー層を形成した。次に表２に示す
熱転写性インキをアンカー層上に3.5μ厚に塗布し
て感熱転写層を設け、転写リボンを作成した。(Example) Table 1 was applied to a polyester stretched film with a thickness of 5.7μ.
The anchor agent shown in Figure 1 was applied, and the solvent was evaporated to form an anchor layer with a thickness of 1.0 μm. Next, a thermal transfer ink shown in Table 2 was applied to a thickness of 3.5 μm on the anchor layer to provide a thermal transfer layer, and a transfer ribbon was prepared.
別に比較例として、厚さ5.7μのポリエステル延
伸フイルムに表２に示す熱転写性インキを3.5μ厚
に塗布して感熱転写層を設け、転写リボンを作成
した。 Separately, as a comparative example, a heat-sensitive transfer layer was provided by applying the thermal transferable ink shown in Table 2 to a thickness of 3.5 μm on a stretched polyester film having a thickness of 5.7 μm to prepare a transfer ribbon.
上記２種類の熱転写リボンを使用して、ライン
タイプのサーマルヘツドを備えたプリンターでベ
ツク平滑度500秒坪量50ｇ／m2の被転写紙に印字
を行なつた。 Using the above two types of thermal transfer ribbons, printing was carried out on transfer paper having a base smoothness of 50 seconds and a basis weight of 50 g/m 2 using a printer equipped with a line-type thermal head.
〔表１〕
アンカー剤組成
ニトロセルロース樹脂 17重量部
ポリアミド樹脂 ６ 〃
トルエン 50重量部
イソプロピルアルコール 20 〃
酢酸エチル ７ 〃
〔表２〕
インキ組成
カルナバワツクス 50重量部
ライスワツクス 30 〃
エチレン酢酸ビニル共重合体 ６ 〃
ノニオン界面活性剤 ２ 〃
カーボンブラツク 12 〃
この印字物の印字表面を目視及び60°光沢計で
光沢度を測定した。[Table 1] Anchor agent composition Nitrocellulose resin 17 parts by weight Polyamide resin 6 Toluene 50 parts by weight Isopropyl alcohol 20 Ethyl acetate 7 [Table 2] Ink composition Carnauba wax 50 parts by weight Rice wax 30 Ethylene vinyl acetate copolymer 6 〃 Nonionic surfactant 2 〃 Carbon black 12 〃 The glossiness of the printed surface of this printed article was measured visually and with a 60° gloss meter.
目視による比較では、本発明の実施例の熱転写
リボンを用いた印字物はほとんど完全に艶が消え
ており、比較例の熱転写リボンを用いた印字物の
表面が著しく光沢があるのと対照的であつた。 Visual comparison shows that the printed matter using the thermal transfer ribbon of the example of the present invention has almost completely lost its luster, which is in contrast to the extremely glossy surface of the printed matter using the thermal transfer ribbon of the comparative example. It was hot.
光沢度を比較したところ、本発明の熱転写リボ
ンを用いた印字物の印字表面は10％±3.2％であ
り、比較例の熱転写リボンを用いた印字物の印字
表面は75％±5.6％であつた。 A comparison of the glossiness showed that the printed surface of the printed matter using the thermal transfer ribbon of the present invention was 10% ± 3.2%, and that of the printed matter using the thermal transfer ribbon of the comparative example was 75% ± 5.6%. Ta.
第１図は本発明の概略構成説明図である。
１……基材、２……アンカー層、３……感熱転
写層、５……感熱転写記録材。
FIG. 1 is a schematic structural explanatory diagram of the present invention. 1...Base material, 2...Anchor layer, 3...Thermal transfer layer, 5...Thermal transfer recording material.
Claims (1)
てなり、かつ転写時に該アンカー層内で凝集破壊
を起こす感熱転写記録材であつて、該アンカー層
がニトロセルロース誘導体、ポリイミド樹脂、ポ
リサルホン樹脂、ポリエーテルサルホン樹脂、シ
リコーン樹脂、エポキシ樹脂、メラミン樹脂、フ
エノール樹脂、弗素樹脂から選ばれる耐熱性成分
と、ポリアミド樹脂、ポリエステル樹脂、アクリ
ル樹脂、エチレン−酢酸ビニル共重合体、環化ゴ
ム、スチレン−ブタジエン共重合体、スチレン−
ブタジエン−スチレン共重合体、ロジン誘導体、
ケトン樹脂、スチレン樹脂、ポリエステルポリオ
ール、アクリルポリオール、天然ワツクス、合成
ワツクス、ポリオレフインワツクスから選ばれる
接着成分からなることを特徴とする感熱転写記録
材。 ２ アンカー層にさらに着色剤を含むことを特徴
とする請求項１記載の感熱転写記録材。 ３ 基材がプラスチツクフイルムからなり、感熱
転写層が形成されていない面にステイツキング防
止のための保護層が設けられていることを特徴と
する請求項１記載の感熱転写記録材。[Scope of Claims] 1. A thermal transfer recording material comprising an anchor layer and a transfer layer on one side of a base material, and which causes cohesive failure within the anchor layer during transfer, wherein the anchor layer is made of nitrocellulose. Heat-resistant components selected from derivatives, polyimide resins, polysulfone resins, polyethersulfone resins, silicone resins, epoxy resins, melamine resins, phenolic resins, and fluororesins, as well as polyamide resins, polyester resins, acrylic resins, and ethylene-vinyl acetate resins. Polymer, cyclized rubber, styrene-butadiene copolymer, styrene-
butadiene-styrene copolymer, rosin derivative,
A thermal transfer recording material comprising an adhesive component selected from ketone resin, styrene resin, polyester polyol, acrylic polyol, natural wax, synthetic wax, and polyolefin wax. 2. The thermal transfer recording material according to claim 1, wherein the anchor layer further contains a colorant. 3. The heat-sensitive transfer recording material according to claim 1, wherein the base material is made of a plastic film, and a protective layer for preventing sticking is provided on the surface on which the heat-sensitive transfer layer is not formed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61205549A JPS6360794A (en) | 1986-09-01 | 1986-09-01 | Thermal transfer recording medium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61205549A JPS6360794A (en) | 1986-09-01 | 1986-09-01 | Thermal transfer recording medium |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6360794A JPS6360794A (en) | 1988-03-16 |
| JPH0455600B2 true JPH0455600B2 (en) | 1992-09-03 |
Family
ID=16508729
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61205549A Granted JPS6360794A (en) | 1986-09-01 | 1986-09-01 | Thermal transfer recording medium |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6360794A (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3808462C2 (en) * | 1987-03-17 | 1996-04-25 | Toyo Ink Mfg Co | Heat-sensitive transfer material |
| DE3738934A1 (en) * | 1987-11-17 | 1989-05-24 | Pelikan Ag | THERMAL RIBBON |
| JP2539883B2 (en) * | 1988-04-13 | 1996-10-02 | 三菱製紙株式会社 | Thermal transfer recording sheet |
| JP2532566B2 (en) * | 1988-04-15 | 1996-09-11 | 三菱製紙株式会社 | Thermal transfer recording sheet |
| JPH01290493A (en) * | 1988-05-18 | 1989-11-22 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
| JPH0281681A (en) * | 1988-09-20 | 1990-03-22 | Toyo Ink Mfg Co Ltd | Thermal transfer material |
| JP2579685B2 (en) * | 1989-06-30 | 1997-02-05 | 東洋インキ製造株式会社 | Thermal transfer material |
| JP2571851B2 (en) * | 1989-06-30 | 1997-01-16 | 東洋インキ製造株式会社 | Thermal transfer material |
| JP2619290B2 (en) * | 1989-07-05 | 1997-06-11 | 大日精化工業株式会社 | Heat-sensitive transfer recording sheet |
| JPH0372352A (en) * | 1989-08-11 | 1991-03-27 | Toyo Ink Mfg Co Ltd | Opaque material |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58114987A (en) * | 1981-12-28 | 1983-07-08 | Toppan Printing Co Ltd | Transfer sheet |
| JPS58208088A (en) * | 1982-05-28 | 1983-12-03 | Oike Kogyo Kk | Transfer foil for hot stamping |
| JPS6040294A (en) * | 1983-08-12 | 1985-03-02 | Hitachi Chem Co Ltd | Thermal transfer film |
| JPS6049998A (en) * | 1983-08-30 | 1985-03-19 | Fujitsu Ltd | Ink sheet for thermal transfer recording |
| JPS60101083A (en) * | 1983-11-08 | 1985-06-05 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS60109897A (en) * | 1983-11-18 | 1985-06-15 | Toshiba Corp | Ink carrier for thermal transfer recording |
| JPS60127191A (en) * | 1983-12-14 | 1985-07-06 | Konishiroku Photo Ind Co Ltd | Thermal transfer recording medium |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6033031Y2 (en) * | 1979-05-23 | 1985-10-02 | 日本写真印刷株式会社 | Heat-resistant vapor deposition transfer material |
-
1986
- 1986-09-01 JP JP61205549A patent/JPS6360794A/en active Granted
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58114987A (en) * | 1981-12-28 | 1983-07-08 | Toppan Printing Co Ltd | Transfer sheet |
| JPS58208088A (en) * | 1982-05-28 | 1983-12-03 | Oike Kogyo Kk | Transfer foil for hot stamping |
| JPS6040294A (en) * | 1983-08-12 | 1985-03-02 | Hitachi Chem Co Ltd | Thermal transfer film |
| JPS6049998A (en) * | 1983-08-30 | 1985-03-19 | Fujitsu Ltd | Ink sheet for thermal transfer recording |
| JPS60101083A (en) * | 1983-11-08 | 1985-06-05 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS60109897A (en) * | 1983-11-18 | 1985-06-15 | Toshiba Corp | Ink carrier for thermal transfer recording |
| JPS60127191A (en) * | 1983-12-14 | 1985-07-06 | Konishiroku Photo Ind Co Ltd | Thermal transfer recording medium |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6360794A (en) | 1988-03-16 |
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