JPS6351460B2 - - Google Patents

Info

Publication number: JPS6351460B2
Authority: JP; Japan
Prior art keywords: rubber; resin composition; polymerization; impact resistance; weight
Prior art date: 1981-05-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP56070139A

Other languages

English (en)

Japanese (ja)

Other versions

JPS57187345A (en

Inventor

Keiji Iio

So Iwamoto

Mitsuyoshi Nakamura

Ichiro Ootsuka

Hisashi Aihara

Haruo Inoe

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mitsui Toatsu Chemicals Inc

Original Assignee

Mitsui Toatsu Chemicals Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-05-12

Filing date

1981-05-12

Publication date

1988-10-14

1981-05-12 Application filed by Mitsui Toatsu Chemicals Inc filed Critical Mitsui Toatsu Chemicals Inc

1981-05-12 Priority to JP7013981A priority Critical patent/JPS57187345A/ja

1982-11-18 Publication of JPS57187345A publication Critical patent/JPS57187345A/ja

1988-10-14 Publication of JPS6351460B2 publication Critical patent/JPS6351460B2/ja

Status Granted legal-status Critical Current

Links

239000002245 particle Substances 0.000 claims description 35
238000000034 method Methods 0.000 claims description 30
229920001971 elastomer Polymers 0.000 claims description 26
239000011342 resin composition Substances 0.000 claims description 25
238000006116 polymerization reaction Methods 0.000 claims description 20
229920001296 polysiloxane Polymers 0.000 claims description 20
-1 polysiloxane Polymers 0.000 claims description 19
229920002554 vinyl polymer Polymers 0.000 claims description 15
229920001890 Novodur Polymers 0.000 claims description 12
229920000642 polymer Polymers 0.000 claims description 11
239000000178 monomer Substances 0.000 claims description 8
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
238000012662 bulk polymerization Methods 0.000 claims description 7
239000000203 mixture Substances 0.000 claims description 7
229910052710 silicon Inorganic materials 0.000 claims description 7
239000010703 silicon Substances 0.000 claims description 7
239000005062 Polybutadiene Substances 0.000 claims description 6
229920002857 polybutadiene Polymers 0.000 claims description 6
229920001577 copolymer Polymers 0.000 claims description 5
229920001519 homopolymer Polymers 0.000 claims description 5
239000005060 rubber Substances 0.000 claims description 4
239000000725 suspension Substances 0.000 claims description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 32
230000000694 effects Effects 0.000 description 10
239000000243 solution Substances 0.000 description 9
238000001125 extrusion Methods 0.000 description 8
239000008188 pellet Substances 0.000 description 7
239000000047 product Substances 0.000 description 7
229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 6
230000000052 comparative effect Effects 0.000 description 6
150000003961 organosilicon compounds Chemical class 0.000 description 6
239000000654 additive Substances 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
229920005989 resin Polymers 0.000 description 5
239000011347 resin Substances 0.000 description 5
238000003756 stirring Methods 0.000 description 5
229920005992 thermoplastic resin Polymers 0.000 description 5
239000004205 dimethyl polysiloxane Substances 0.000 description 4
235000013870 dimethyl polysiloxane Nutrition 0.000 description 4
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
238000010557 suspension polymerization reaction Methods 0.000 description 4
239000004793 Polystyrene Substances 0.000 description 3
239000000470 constituent Substances 0.000 description 3
238000000465 moulding Methods 0.000 description 3
229920002223 polystyrene Polymers 0.000 description 3
KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 3
CYLVUSZHVURAOY-UHFFFAOYSA-N 2,2-dibromoethenylbenzene Chemical compound BrC(Br)=CC1=CC=CC=C1 CYLVUSZHVURAOY-UHFFFAOYSA-N 0.000 description 2
239000008346 aqueous phase Substances 0.000 description 2
238000004132 cross linking Methods 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
238000002156 mixing Methods 0.000 description 2
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
229920003048 styrene butadiene rubber Polymers 0.000 description 2
238000012360 testing method Methods 0.000 description 2
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 2
CISIJYCKDJSTMX-UHFFFAOYSA-N 2,2-dichloroethenylbenzene Chemical class ClC(Cl)=CC1=CC=CC=C1 CISIJYCKDJSTMX-UHFFFAOYSA-N 0.000 description 1
YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical class ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
229920000459 Nitrile rubber Polymers 0.000 description 1
239000002174 Styrene-butadiene Substances 0.000 description 1
238000003917 TEM image Methods 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000001506 calcium phosphate Substances 0.000 description 1
229910000389 calcium phosphate Inorganic materials 0.000 description 1
235000011010 calcium phosphates Nutrition 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000003086 colorant Substances 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000000635 electron micrograph Methods 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000012456 homogeneous solution Substances 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
125000002768 hydroxyalkyl group Chemical group 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
229940057995 liquid paraffin Drugs 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
239000003607 modifier Substances 0.000 description 1
125000000962 organic group Chemical group 0.000 description 1
150000002900 organolithium compounds Chemical class 0.000 description 1
239000012071 phase Substances 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
239000003505 polymerization initiator Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000000746 purification Methods 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000011160 research Methods 0.000 description 1
150000003377 silicon compounds Chemical class 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
239000000375 suspending agent Substances 0.000 description 1
238000012546 transfer Methods 0.000 description 1
235000019731 tricalcium phosphate Nutrition 0.000 description 1
238000005406 washing Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

JP7013981A 1981-05-12 1981-05-12 Rubber-modified styrene resin composition Granted JPS57187345A (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP7013981A JPS57187345A (en)	1981-05-12	1981-05-12	Rubber-modified styrene resin composition

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP7013981A JPS57187345A (en)	1981-05-12	1981-05-12	Rubber-modified styrene resin composition

Publications (2)

Publication Number	Publication Date
JPS57187345A JPS57187345A (en)	1982-11-18
JPS6351460B2 true JPS6351460B2 (fr)	1988-10-14

Family

ID=13422935

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP7013981A Granted JPS57187345A (en)	1981-05-12	1981-05-12	Rubber-modified styrene resin composition

Country Status (1)

Country	Link
JP (1)	JPS57187345A (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0611828B2 (ja) *	1985-03-29	1994-02-16	出光石油化学株式会社	熱可塑性樹脂組成物
NL193458C (nl) *	1985-10-22	1999-11-02	Asahi Chemical Ind	Werkwijze voor de continue bereiding van een rubberversterkte polystyreensamenstelling met een hoge slagvastheid.
JPH01275649A (ja) *	1988-04-27	1989-11-06	Asahi Chem Ind Co Ltd	光沢と耐衝撃性に優れたゴム変性ポリスチレン樹脂組成物
JPS63112646A (ja) *	1986-10-29	1988-05-17	Asahi Chem Ind Co Ltd	高光沢耐衝撃性ポリスチレン樹脂組成物
CA1335524C (fr) *	1988-04-11	1995-05-09	Hideo Kasahara	Composition de resine de polystyrene modifiee au caoutchouc
JPH02145637A (ja) *	1988-11-29	1990-06-05	Asahi Chem Ind Co Ltd	改良されたゴム変性スチレン系樹脂組成物よりなる摺動性物品
ES2930761T3 (es)	2017-07-26	2022-12-21	Ineos Styrolution Group Gmbh	Composición de copolímero de estireno modificado al impacto que comprende un aditivo de polisiloxano que tiene características de abrasión mejoradas
EP3658623A1 (fr)	2017-07-26	2020-06-03	INEOS Styrolution Group GmbH	Composition de copolymère de styrène à résistance aux chocs modifiée comprenant un additif de polysiloxane ayant des caractéristiques d'abrasion améliorées
KR102034670B1 (ko) *	2017-11-21	2019-11-08	금호석유화학 주식회사	전도성 수지 조성물 및 그 제조방법

Citations (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS49109438A (fr) *	1973-02-21	1974-10-17
JPS5058189A (fr) *	1973-09-19	1975-05-20
JPS50122589A (fr) *	1974-03-07	1975-09-26
JPS51100145A (ja) *	1975-03-01	1976-09-03	Japan Synthetic Rubber Co Ltd	Netsukasoseijushisoseibutsu
JPS5286444A (en) *	1976-01-14	1977-07-18	Mitsui Toatsu Chem Inc	Rubber-modified styrene resin compositions
JPS52152491A (en) *	1976-06-15	1977-12-17	Asahi Chem Ind Co Ltd	Styrene resin composition and its preparation
JPS535293A (en) *	1976-07-01	1978-01-18	Monsanto Co	Bulk polymerization method
JPS5330525A (en) *	1976-09-01	1978-03-22	Mitsubishi Motors Corp	Method of manufacturing double noise protecting wall of vehicle
JPS5344188A (en) *	1976-08-20	1978-04-20	Texas Instruments Inc	Ic and method of producing same
JPS53124561A (en) *	1977-04-06	1978-10-31	Japan Synthetic Rubber Co Ltd	Preparation of rubber-modified thermoplastic resin composition
JPS53130793A (en) *	1977-04-20	1978-11-15	Asahi Chem Ind Co Ltd	Preparation of high impact polystyrene composition
JPS53130791A (en) *	1977-04-20	1978-11-15	Asahi Chem Ind Co Ltd	Preparation of high impact polystyrene
JPS5556114A (en) *	1978-10-20	1980-04-24	Asahi Chem Ind Co Ltd	Preparation of high-impact polystyrene resin
JPS57172948A (en) *	1981-04-17	1982-10-25	Mitsui Toatsu Chem Inc	Rubber-modified styrene resin composition
JPS6326774A (ja) *	1986-07-21	1988-02-04	Mitsubishi Electric Corp	信号処理装置
JPS6351459A (ja) *	1986-08-22	1988-03-04	Toshiba Chem Corp	導電性成形材料

1981
- 1981-05-12 JP JP7013981A patent/JPS57187345A/ja active Granted

Patent Citations (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS49109438A (fr) *	1973-02-21	1974-10-17
JPS5058189A (fr) *	1973-09-19	1975-05-20
JPS50122589A (fr) *	1974-03-07	1975-09-26
JPS51100145A (ja) *	1975-03-01	1976-09-03	Japan Synthetic Rubber Co Ltd	Netsukasoseijushisoseibutsu
JPS5286444A (en) *	1976-01-14	1977-07-18	Mitsui Toatsu Chem Inc	Rubber-modified styrene resin compositions
JPS52152491A (en) *	1976-06-15	1977-12-17	Asahi Chem Ind Co Ltd	Styrene resin composition and its preparation
JPS535293A (en) *	1976-07-01	1978-01-18	Monsanto Co	Bulk polymerization method
JPS5344188A (en) *	1976-08-20	1978-04-20	Texas Instruments Inc	Ic and method of producing same
JPS5330525A (en) *	1976-09-01	1978-03-22	Mitsubishi Motors Corp	Method of manufacturing double noise protecting wall of vehicle
JPS53124561A (en) *	1977-04-06	1978-10-31	Japan Synthetic Rubber Co Ltd	Preparation of rubber-modified thermoplastic resin composition
JPS53130793A (en) *	1977-04-20	1978-11-15	Asahi Chem Ind Co Ltd	Preparation of high impact polystyrene composition
JPS53130791A (en) *	1977-04-20	1978-11-15	Asahi Chem Ind Co Ltd	Preparation of high impact polystyrene
JPS5556114A (en) *	1978-10-20	1980-04-24	Asahi Chem Ind Co Ltd	Preparation of high-impact polystyrene resin
JPS57172948A (en) *	1981-04-17	1982-10-25	Mitsui Toatsu Chem Inc	Rubber-modified styrene resin composition
JPS6326774A (ja) *	1986-07-21	1988-02-04	Mitsubishi Electric Corp	信号処理装置
JPS6351459A (ja) *	1986-08-22	1988-03-04	Toshiba Chem Corp	導電性成形材料

Also Published As

Publication number	Publication date
JPS57187345A (en)	1982-11-18

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US10941289B2 (en)	2021-03-09	Graft copolymer, thermoplastic resin composition including graft copolymer, and method of preparing thermoplastic resin composition
WO2009084897A2 (fr)	2009-07-09	Composition de résine thermoplastique à faible brillant et à surface lisse et pièce moulée fabriquée avec cette composition de résine
TW201829496A (zh)	2018-08-16	熱塑性樹脂及熱塑性樹脂組成物
JPH0468326B2 (fr)	1992-11-02
JPS6351459B2 (fr)	1988-10-14
JP6978412B2 (ja)	2021-12-08	ゴム変性ビニル系グラフト共重合体及びそれを含む熱可塑性樹脂組成物
JPS6351460B2 (fr)	1988-10-14
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WO2019190298A1 (fr)	2019-10-03	Composition de résine thermoplastique et produit moulé l'utilisant
JPH0463099B2 (fr)	1992-10-08
JPH0786165B2 (ja)	1995-09-20	耐衝撃性熱可塑性樹脂組成物
JP3201206B2 (ja)	2001-08-20	ゴム変性スチレン系樹脂組成物およびその成形品
KR101827613B1 (ko)	2018-02-08	고무변성 비닐계 그라프트 공중합체 및 이를 포함하는 열가소성 수지 조성물
JPS6326774B2 (fr)	1988-05-31
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EP3533830B1 (fr)	2022-03-09	Composition de résine thermoplastique, procédé de production associé, et produit moulé formé à partir de celle-ci
CN107973878B (zh)	2020-06-09	一种共聚物及其制备方法和应用以及共混材料
JP6916275B2 (ja)	2021-08-11	乳化性開始剤、コア−シェル共重合体、およびそれを含む熱可塑性樹脂組成物
JPH0660273B2 (ja)	1994-08-10	ゴム変性ポリスチレン樹脂組成物
JP3978272B2 (ja)	2007-09-19	制振性熱可塑性樹脂組成物
KR920001046B1 (ko)	1992-02-01	고무-변성된 폴리스티렌 수지 조성물
JPH0376338B2 (fr)	1991-12-05
JP2835531B2 (ja)	1998-12-14	耐衝撃性熱可塑性樹脂組成物
JPS5842216B2 (ja)	1983-09-17	耐衝撃性樹脂の製造法