JPS6234069B2 - - Google Patents

Info

Publication number: JPS6234069B2
Authority: JP; Japan
Prior art keywords: weight; parts; graft; graft polymer; latex
Prior art date: 1979-06-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP54073086A

Other languages

English (en)

Japanese (ja)

Other versions

JPS55165942A (en

Inventor

Mitsuo Abe

Hideyuki Hatsutori

Akira Kamya

Hiroshi Kinomura

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

JSR Corp

Original Assignee

Japan Synthetic Rubber Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-06-12

Filing date

1979-06-12

Publication date

1987-07-24

1979-06-12 Application filed by Japan Synthetic Rubber Co Ltd filed Critical Japan Synthetic Rubber Co Ltd

1979-06-12 Priority to JP7308679A priority Critical patent/JPS55165942A/ja

1980-12-24 Publication of JPS55165942A publication Critical patent/JPS55165942A/ja

1987-07-24 Publication of JPS6234069B2 publication Critical patent/JPS6234069B2/ja

Status Granted legal-status Critical Current

Links

229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 33
229920000578 graft copolymer Polymers 0.000 claims description 23
239000000178 monomer Substances 0.000 claims description 22
229920002554 vinyl polymer Polymers 0.000 claims description 17
239000000203 mixture Substances 0.000 claims description 15
229920005989 resin Polymers 0.000 claims description 15
239000011347 resin Substances 0.000 claims description 15
150000001875 compounds Chemical class 0.000 claims description 14
-1 alcohol ester Chemical class 0.000 claims description 11
229920005992 thermoplastic resin Polymers 0.000 claims description 10
239000002245 particle Substances 0.000 claims description 8
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 8
125000004432 carbon atom Chemical group C* 0.000 claims description 7
239000011342 resin composition Substances 0.000 claims description 7
229920001577 copolymer Polymers 0.000 claims description 6
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 6
XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 3
239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 3
230000000379 polymerizing effect Effects 0.000 claims description 3
229920001296 polysiloxane Polymers 0.000 claims description 3
150000004671 saturated fatty acids Chemical class 0.000 claims description 3
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
229920003244 diene elastomer Polymers 0.000 claims description 2
239000004816 latex Substances 0.000 description 25
229920000126 latex Polymers 0.000 description 25
238000000034 method Methods 0.000 description 18
229920001971 elastomer Polymers 0.000 description 14
238000000465 moulding Methods 0.000 description 11
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 10
238000006116 polymerization reaction Methods 0.000 description 10
239000005060 rubber Substances 0.000 description 9
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 8
230000000052 comparative effect Effects 0.000 description 8
239000005062 Polybutadiene Substances 0.000 description 7
239000011324 bead Substances 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 7
229920002857 polybutadiene Polymers 0.000 description 7
229920000642 polymer Polymers 0.000 description 7
239000000843 powder Substances 0.000 description 7
238000003756 stirring Methods 0.000 description 7
YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 6
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
230000000694 effects Effects 0.000 description 6
238000010559 graft polymerization reaction Methods 0.000 description 6
235000014113 dietary fatty acids Nutrition 0.000 description 5
238000002474 experimental method Methods 0.000 description 5
239000000194 fatty acid Substances 0.000 description 5
229930195729 fatty acid Natural products 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
150000001298 alcohols Chemical class 0.000 description 4
230000007423 decrease Effects 0.000 description 4
150000004665 fatty acids Chemical class 0.000 description 4
238000002347 injection Methods 0.000 description 4
239000007924 injection Substances 0.000 description 4
239000000725 suspension Substances 0.000 description 4
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
239000000654 additive Substances 0.000 description 3
LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 3
PFBWBEXCUGKYKO-UHFFFAOYSA-N ethene;n-octadecyloctadecan-1-amine Chemical compound C=C.CCCCCCCCCCCCCCCCCCNCCCCCCCCCCCCCCCCCC PFBWBEXCUGKYKO-UHFFFAOYSA-N 0.000 description 3
238000002156 mixing Methods 0.000 description 3
239000012966 redox initiator Substances 0.000 description 3
238000010557 suspension polymerization reaction Methods 0.000 description 3
QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 2
IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 2
FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 2
239000004359 castor oil Substances 0.000 description 2
235000019438 castor oil Nutrition 0.000 description 2
230000006378 damage Effects 0.000 description 2
230000007547 defect Effects 0.000 description 2
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
229910001873 dinitrogen Inorganic materials 0.000 description 2
238000011156 evaluation Methods 0.000 description 2
239000011790 ferrous sulphate Substances 0.000 description 2
235000003891 ferrous sulphate Nutrition 0.000 description 2
ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
238000001746 injection moulding Methods 0.000 description 2
BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
239000000314 lubricant Substances 0.000 description 2
GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
235000003441 saturated fatty acids Nutrition 0.000 description 2
235000010413 sodium alginate Nutrition 0.000 description 2
239000000661 sodium alginate Substances 0.000 description 2
229940005550 sodium alginate Drugs 0.000 description 2
KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 1
ZGHZSTWONPNWHV-UHFFFAOYSA-N 2-(oxiran-2-yl)ethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCC1CO1 ZGHZSTWONPNWHV-UHFFFAOYSA-N 0.000 description 1
239000004803 Di-2ethylhexylphthalate Substances 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
KRADHMIOFJQKEZ-UHFFFAOYSA-N Tri-2-ethylhexyl trimellitate Chemical compound CCCCC(CC)COC(=O)C1=CC=C(C(=O)OCC(CC)CCCC)C(C(=O)OCC(CC)CCCC)=C1 KRADHMIOFJQKEZ-UHFFFAOYSA-N 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
230000003712 anti-aging effect Effects 0.000 description 1
238000005452 bending Methods 0.000 description 1
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
239000008116 calcium stearate Substances 0.000 description 1
235000013539 calcium stearate Nutrition 0.000 description 1
150000001733 carboxylic acid esters Chemical class 0.000 description 1
239000012986 chain transfer agent Substances 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000001066 destructive effect Effects 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
239000004205 dimethyl polysiloxane Substances 0.000 description 1
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
229940017705 formaldehyde sulfoxylate Drugs 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
239000008103 glucose Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
SBGKURINHGJRFN-UHFFFAOYSA-N hydroxymethanesulfinic acid Chemical compound OCS(O)=O SBGKURINHGJRFN-UHFFFAOYSA-N 0.000 description 1
239000003999 initiator Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
239000011812 mixed powder Substances 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
FIBARIGPBPUBHC-UHFFFAOYSA-N octyl 8-(3-octyloxiran-2-yl)octanoate Chemical compound CCCCCCCCOC(=O)CCCCCCCC1OC1CCCCCCCC FIBARIGPBPUBHC-UHFFFAOYSA-N 0.000 description 1
238000010422 painting Methods 0.000 description 1
238000005453 pelletization Methods 0.000 description 1
238000007747 plating Methods 0.000 description 1
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
239000003505 polymerization initiator Substances 0.000 description 1
230000002265 prevention Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
239000000344 soap Substances 0.000 description 1
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
229940048086 sodium pyrophosphate Drugs 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
229920003048 styrene butadiene rubber Polymers 0.000 description 1
238000010998 test method Methods 0.000 description 1
238000012360 testing method Methods 0.000 description 1
235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

JP7308679A 1979-06-12 1979-06-12 Thermoplastic resin composition Granted JPS55165942A (en)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP7308679A JPS55165942A (en)	1979-06-12	1979-06-12	Thermoplastic resin composition

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP7308679A JPS55165942A (en)	1979-06-12	1979-06-12	Thermoplastic resin composition

Publications (2)

Publication Number	Publication Date
JPS55165942A JPS55165942A (en)	1980-12-24
JPS6234069B2 true JPS6234069B2 (zh)	1987-07-24

Family

ID=13508164

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP7308679A Granted JPS55165942A (en)	1979-06-12	1979-06-12	Thermoplastic resin composition

Country Status (1)

Country	Link
JP (1)	JPS55165942A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5654366A (en) *	1995-02-27	1997-08-05	Dow Corning Toray Silicone Co., Ltd.	Thermoplastic resin composition

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS59219362A (ja) *	1983-05-27	1984-12-10	Sumitomo Naugatuck Co Ltd	熱可塑性樹脂組成物
JPS60171117A (ja) *	1984-02-15	1985-09-04	Denki Kagaku Kogyo Kk	樹脂キ−トツプ製品
JPS60231751A (ja) *	1984-05-02	1985-11-18	Japan Synthetic Rubber Co Ltd	熱可塑性樹脂組成物
JPS60252650A (ja) *	1984-05-30	1985-12-13	Sumitomo Naugatuck Co Ltd	耐熱性樹脂組成物
JPH0643539B2 (ja) *	1986-11-27	1994-06-08	出光石油化学株式会社	熱可塑性樹脂組成物
JPH0623291B2 (ja) *	1988-11-28	1994-03-30	旭化成工業株式会社	熱安定性に優れたゴム変性スチレン系樹脂摺動物品
KR100546783B1 (ko) *	1999-09-21	2006-01-25	제일모직주식회사	내열성이 우수한 열가소성 수지 조성물
US8053159B2 (en)	2003-11-18	2011-11-08	Honeywell International Inc.	Antireflective coatings for via fill and photolithography applications and methods of preparation thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS4929947A (zh) *	1972-07-17	1974-03-16
JPS50140553A (zh) *	1974-04-30	1975-11-11
JPS51100145A (ja) *	1975-03-01	1976-09-03	Japan Synthetic Rubber Co Ltd	Netsukasoseijushisoseibutsu

1979
- 1979-06-12 JP JP7308679A patent/JPS55165942A/ja active Granted

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS4929947A (zh) *	1972-07-17	1974-03-16
JPS50140553A (zh) *	1974-04-30	1975-11-11
JPS51100145A (ja) *	1975-03-01	1976-09-03	Japan Synthetic Rubber Co Ltd	Netsukasoseijushisoseibutsu

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5654366A (en) *	1995-02-27	1997-08-05	Dow Corning Toray Silicone Co., Ltd.	Thermoplastic resin composition

Also Published As

Publication number	Publication date
JPS55165942A (en)	1980-12-24

Publication	Publication Date	Title
EP0277687B1 (en)	1994-05-18	Rubber-reinforced monovinylidene aromatic polymer resins and a method for their preparation
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EP0208382B1 (en)	1991-09-18	Rubber-reinforced styrenic polymer resins having improved flow and gloss characteristics
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JP3978272B2 (ja)	2007-09-19	制振性熱可塑性樹脂組成物
KR100775737B1 (ko)	2007-11-09	전사성이 우수한 열가소성 수지 조성물
KR102586515B1 (ko)	2023-10-06	공중합체 조성물, 이의 제조방법 및 이를 포함하는 열가소성 수지 조성물
KR100208576B1 (ko)	1999-07-15	스티렌계 수지 조성물
KR100567387B1 (ko)	2006-04-04	내충격성 및 광택성이 향상된 열가소성 수지조성물 및 그 제조방법
JP3222751B2 (ja)	2001-10-29	成形外観に優れた熱可塑性樹脂組成物
JP2006526682A (ja)	2006-11-24	スチレン系熱可塑性樹脂組成物
KR0184704B1 (ko)	1999-05-15	광택 및 내약품성이 우수한 고니트릴계 수지의 제조방법
KR20170055647A (ko)	2017-05-22	그라프트 공중합체, 이의 제조방법 및 이를 포함하는 열가소성 수지 조성물
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JPH0794593B2 (ja)	1995-10-11	熱可塑性樹脂組成物

JPS6234069B2 - - Google Patents

Info

Links

Landscapes

Priority Applications (1)

Applications Claiming Priority (1)

Publications (2)

Family

ID=13508164

Family Applications (1)

Country Status (1)

Cited By (1)

Families Citing this family (8)

Citations (3)

Patent Citations (3)

Cited By (1)

Also Published As

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