JPS622073B2 - - Google Patents

Info

Publication number: JPS622073B2
Authority: JP; Japan
Prior art keywords: polyester; hollow; hollow fiber; water absorption; spinning
Prior art date: 1986-01-17
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP639386A

Other languages

English (en)

Japanese (ja)

Other versions

JPS61167080A (ja

Inventor

Motoyoshi Suzuki

Kyokazu Tsunawaki

Osamu Wada

Akio Kimura

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Teijin Ltd

Original Assignee

Teijin Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-01-17

Filing date

1986-01-17

Publication date

1987-01-17

1986-01-17 Application filed by Teijin Ltd filed Critical Teijin Ltd

1986-01-17 Priority to JP639386A priority Critical patent/JPS61167080A/ja

1986-07-28 Publication of JPS61167080A publication Critical patent/JPS61167080A/ja

1987-01-17 Publication of JPS622073B2 publication Critical patent/JPS622073B2/ja

Status Granted legal-status Critical Current

Links

-1 terephthalic acid Chemical class 0.000 claims description 46
239000012510 hollow fiber Substances 0.000 claims description 41
229920000728 polyester Polymers 0.000 claims description 41
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 37
239000000835 fiber Substances 0.000 claims description 27
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 18
229910052751 metal Inorganic materials 0.000 claims description 18
239000002184 metal Substances 0.000 claims description 18
239000003513 alkali Substances 0.000 claims description 17
150000001875 compounds Chemical class 0.000 claims description 13
239000007864 aqueous solution Substances 0.000 claims description 11
125000000962 organic group Chemical group 0.000 claims description 10
238000002074 melt spinning Methods 0.000 claims description 9
239000011574 phosphorus Substances 0.000 claims description 9
229910052698 phosphorus Inorganic materials 0.000 claims description 9
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 8
150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 4
238000004519 manufacturing process Methods 0.000 claims description 4
230000001588 bifunctional effect Effects 0.000 claims description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 33
238000010521 absorption reaction Methods 0.000 description 28
239000004744 fabric Substances 0.000 description 21
WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 14
238000000034 method Methods 0.000 description 13
239000001488 sodium phosphate Substances 0.000 description 10
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
229920000642 polymer Polymers 0.000 description 9
150000003839 salts Chemical class 0.000 description 9
238000009987 spinning Methods 0.000 description 8
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 7
238000007796 conventional method Methods 0.000 description 7
229910000397 disodium phosphate Inorganic materials 0.000 description 7
235000019800 disodium phosphate Nutrition 0.000 description 7
229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 6
238000006243 chemical reaction Methods 0.000 description 6
230000007423 decrease Effects 0.000 description 6
238000006068 polycondensation reaction Methods 0.000 description 6
239000002253 acid Substances 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
206010061592 cardiac fibrillation Diseases 0.000 description 4
239000007795 chemical reaction product Substances 0.000 description 4
230000002600 fibrillogenic effect Effects 0.000 description 4
229920001515 polyalkylene glycol Polymers 0.000 description 4
238000003786 synthesis reaction Methods 0.000 description 4
238000005406 washing Methods 0.000 description 4
235000010290 biphenyl Nutrition 0.000 description 3
239000004305 biphenyl Substances 0.000 description 3
XQKKWWCELHKGKB-UHFFFAOYSA-L calcium acetate monohydrate Chemical compound O.[Ca+2].CC([O-])=O.CC([O-])=O XQKKWWCELHKGKB-UHFFFAOYSA-L 0.000 description 3
229940067460 calcium acetate monohydrate Drugs 0.000 description 3
239000003054 catalyst Substances 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
239000011521 glass Substances 0.000 description 3
238000002844 melting Methods 0.000 description 3
230000008018 melting Effects 0.000 description 3
238000002156 mixing Methods 0.000 description 3
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 3
238000012545 processing Methods 0.000 description 3
239000011734 sodium Substances 0.000 description 3
235000011121 sodium hydroxide Nutrition 0.000 description 3
238000005809 transesterification reaction Methods 0.000 description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
GYSRYFZMSPUCLA-UHFFFAOYSA-H [Mg+2].P(=O)([O-])([O-])[O-].C(CCCCCCCCCCC)OCCCCCCCCCCCC.P(=O)([O-])([O-])[O-].[Mg+2].[Mg+2] Chemical compound [Mg+2].P(=O)([O-])([O-])[O-].C(CCCCCCCCCCC)OCCCCCCCCCCCC.P(=O)([O-])([O-])[O-].[Mg+2].[Mg+2] GYSRYFZMSPUCLA-UHFFFAOYSA-H 0.000 description 2
238000005299 abrasion Methods 0.000 description 2
125000002723 alicyclic group Chemical group 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
239000012670 alkaline solution Substances 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
239000002131 composite material Substances 0.000 description 2
230000018044 dehydration Effects 0.000 description 2
238000006297 dehydration reaction Methods 0.000 description 2
238000001035 drying Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000003112 inhibitor Substances 0.000 description 2
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
239000004137 magnesium phosphate Substances 0.000 description 2
229910001463 metal phosphate Inorganic materials 0.000 description 2
229910000401 monomagnesium phosphate Inorganic materials 0.000 description 2
235000019785 monomagnesium phosphate Nutrition 0.000 description 2
229920000139 polyethylene terephthalate Polymers 0.000 description 2
239000005020 polyethylene terephthalate Substances 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
229910052700 potassium Inorganic materials 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
229910000162 sodium phosphate Inorganic materials 0.000 description 2
235000011008 sodium phosphates Nutrition 0.000 description 2
238000012360 testing method Methods 0.000 description 2
WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 2
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
UUWJHAWPCRFDHZ-UHFFFAOYSA-N 1-dodecoxydodecane;phosphoric acid Chemical compound OP(O)(O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC UUWJHAWPCRFDHZ-UHFFFAOYSA-N 0.000 description 1
VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
NQSMEZJWJJVYOI-UHFFFAOYSA-N Methyl 2-benzoylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C(=O)C1=CC=CC=C1 NQSMEZJWJJVYOI-UHFFFAOYSA-N 0.000 description 1
CVUIZWFQMUFZSL-UHFFFAOYSA-K P(=O)([O-])([O-])[O-].C[Mn+3] Chemical compound P(=O)([O-])([O-])[O-].C[Mn+3] CVUIZWFQMUFZSL-UHFFFAOYSA-K 0.000 description 1
RECMVHGLUHDCTK-UHFFFAOYSA-K P(=O)([O-])([O-])[O-].[Na+].COC.[Na+].[Na+] Chemical compound P(=O)([O-])([O-])[O-].[Na+].COC.[Na+].[Na+] RECMVHGLUHDCTK-UHFFFAOYSA-K 0.000 description 1
SIHFZSASJWRZQM-UHFFFAOYSA-N P(O)(O)O.COC Chemical compound P(O)(O)O.COC SIHFZSASJWRZQM-UHFFFAOYSA-N 0.000 description 1
ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000001361 adipic acid Substances 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
125000005907 alkyl ester group Chemical group 0.000 description 1
229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
238000009835 boiling Methods 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000003086 colorant Substances 0.000 description 1
239000013078 crystal Substances 0.000 description 1
239000003599 detergent Substances 0.000 description 1
150000002009 diols Chemical group 0.000 description 1
ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
235000019797 dipotassium phosphate Nutrition 0.000 description 1
229910000396 dipotassium phosphate Inorganic materials 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
239000006081 fluorescent whitening agent Substances 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical class [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
150000002433 hydrophilic molecules Chemical class 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
239000006224 matting agent Substances 0.000 description 1
238000000691 measurement method Methods 0.000 description 1
239000000203 mixture Substances 0.000 description 1
229910000403 monosodium phosphate Inorganic materials 0.000 description 1
235000019799 monosodium phosphate Nutrition 0.000 description 1
KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
150000003018 phosphorus compounds Chemical class 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
239000002994 raw material Substances 0.000 description 1
238000009991 scouring Methods 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
150000003460 sulfonic acids Chemical class 0.000 description 1
239000012209 synthetic fiber Substances 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
238000010998 test method Methods 0.000 description 1
USTXUJIHHVNDFR-UHFFFAOYSA-K tripotassium 1-dodecoxydodecane phosphate Chemical compound P(=O)([O-])([O-])[O-].[K+].C(CCCCCCCCCCC)OCCCCCCCCCCCC.[K+].[K+] USTXUJIHHVNDFR-UHFFFAOYSA-K 0.000 description 1
230000004580 weight loss Effects 0.000 description 1

Landscapes

Chemical Or Physical Treatment Of Fibers (AREA)
Artificial Filaments (AREA)

JP639386A 1986-01-17 1986-01-17 中空繊維の製造法 Granted JPS61167080A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP639386A JPS61167080A (ja)	1986-01-17	1986-01-17	中空繊維の製造法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP639386A JPS61167080A (ja)	1986-01-17	1986-01-17	中空繊維の製造法

Publications (2)

Publication Number	Publication Date
JPS61167080A JPS61167080A (ja)	1986-07-28
JPS622073B2 true JPS622073B2 (de)	1987-01-17

Family

ID=11637120

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP639386A Granted JPS61167080A (ja)	1986-01-17	1986-01-17	中空繊維の製造法

Country Status (1)

Country	Link
JP (1)	JPS61167080A (de)

1986
- 1986-01-17 JP JP639386A patent/JPS61167080A/ja active Granted

Also Published As

Publication number	Publication date
JPS61167080A (ja)	1986-07-28

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