JPS62201803A - Herbicide composition - Google Patents
Herbicide compositionInfo
- Publication number
- JPS62201803A JPS62201803A JP4198586A JP4198586A JPS62201803A JP S62201803 A JPS62201803 A JP S62201803A JP 4198586 A JP4198586 A JP 4198586A JP 4198586 A JP4198586 A JP 4198586A JP S62201803 A JPS62201803 A JP S62201803A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- present
- gel
- weight
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 34
- 239000004009 herbicide Substances 0.000 title claims abstract description 15
- 239000000945 filler Substances 0.000 claims abstract description 9
- 229920000620 organic polymer Polymers 0.000 claims abstract description 9
- 239000007787 solid Substances 0.000 claims description 13
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- 239000006259 organic additive Substances 0.000 claims description 4
- 239000003349 gelling agent Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 16
- 150000002500 ions Chemical group 0.000 abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 6
- 239000002895 emetic Substances 0.000 abstract description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract description 3
- 229910021538 borax Inorganic materials 0.000 abstract description 3
- 239000003086 colorant Substances 0.000 abstract description 3
- 239000000377 silicon dioxide Substances 0.000 abstract description 3
- 239000004328 sodium tetraborate Substances 0.000 abstract description 3
- 235000010339 sodium tetraborate Nutrition 0.000 abstract description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract description 2
- 150000004676 glycans Chemical class 0.000 abstract description 2
- 229920001282 polysaccharide Polymers 0.000 abstract description 2
- 239000005017 polysaccharide Substances 0.000 abstract description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract description 2
- ODPOAESBSUKMHD-UHFFFAOYSA-L 6,7-dihydrodipyrido[1,2-b:1',2'-e]pyrazine-5,8-diium;dibromide Chemical compound [Br-].[Br-].C1=CC=[N+]2CC[N+]3=CC=CC=C3C2=C1 ODPOAESBSUKMHD-UHFFFAOYSA-L 0.000 abstract 1
- 230000035622 drinking Effects 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 239000007788 liquid Substances 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 9
- -1 benzene sulfone Chemical class 0.000 description 7
- 150000003839 salts Chemical group 0.000 description 7
- 208000032484 Accidental exposure to product Diseases 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000004026 adhesive bonding Methods 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 235000013336 milk Nutrition 0.000 description 3
- 239000008267 milk Substances 0.000 description 3
- 210000004080 milk Anatomy 0.000 description 3
- 235000014214 soft drink Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000005630 Diquat Substances 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 240000000249 Morus alba Species 0.000 description 2
- 235000008708 Morus alba Nutrition 0.000 description 2
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
- 229940006460 bromide ion Drugs 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 238000003776 cleavage reaction Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229910003480 inorganic solid Inorganic materials 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 2
- 239000001630 malic acid Substances 0.000 description 2
- 235000011090 malic acid Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- ZMESHQOXZMOOQQ-UHFFFAOYSA-N 1-(naphthalen-1-ylmethyl)naphthalene Chemical compound C1=CC=C2C(CC=3C4=CC=CC=C4C=CC=3)=CC=CC2=C1 ZMESHQOXZMOOQQ-UHFFFAOYSA-N 0.000 description 1
- SKYNPRKUXHXZFJ-UHFFFAOYSA-L 6,7-dihydrodipyrido[1,2-b:1',2'-e]pyrazine-5,8-diium;dichloride Chemical compound [Cl-].[Cl-].C1=CC=[N+]2CC[N+]3=CC=CC=C3C2=C1 SKYNPRKUXHXZFJ-UHFFFAOYSA-L 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 235000014036 Castanea Nutrition 0.000 description 1
- 241001070941 Castanea Species 0.000 description 1
- 235000011511 Diospyros Nutrition 0.000 description 1
- 241000723267 Diospyros Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-L L-tartrate(2-) Chemical compound [O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O FEWJPZIEWOKRBE-JCYAYHJZSA-L 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229910000564 Raney nickel Inorganic materials 0.000 description 1
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 1
- 244000028419 Styrax benzoin Species 0.000 description 1
- 235000000126 Styrax benzoin Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 235000008411 Sumatra benzointree Nutrition 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 229960002130 benzoin Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 150000001638 boron Chemical class 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- MXZACTZQSGYANA-UHFFFAOYSA-N chembl545463 Chemical compound Cl.C1=CC(OC)=CC=C1C(N=C1)=CN2C1=NC(C)=C2O MXZACTZQSGYANA-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 235000015872 dietary supplement Nutrition 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- SYJFEGQWDCRVNX-UHFFFAOYSA-N diquat Chemical compound C1=CC=[N+]2CC[N+]3=CC=CC=C3C2=C1 SYJFEGQWDCRVNX-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- BVBRZOLXXOIMQG-UHFFFAOYSA-N fluoroborane Chemical compound FB BVBRZOLXXOIMQG-UHFFFAOYSA-N 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 235000019382 gum benzoic Nutrition 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 229940006461 iodide ion Drugs 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000005527 methyl sulfate group Chemical group 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- FIKAKWIAUPDISJ-UHFFFAOYSA-L paraquat dichloride Chemical compound [Cl-].[Cl-].C1=C[N+](C)=CC=C1C1=CC=[N+](C)C=C1 FIKAKWIAUPDISJ-UHFFFAOYSA-L 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- JVUYWILPYBCNNG-UHFFFAOYSA-N potassium;oxido(oxo)borane Chemical compound [K+].[O-]B=O JVUYWILPYBCNNG-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 description 1
- 230000009747 swallowing Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は固体状除草剤組成物に関するものである、更に
詳しくは、除草活性成分としてビピリジウム第４級イオ
ンを含む固体状除草剤組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a solid herbicidal composition, and more particularly to a solid herbicidal composition containing bipyridium quaternary ion as a herbicidal active ingredient.
今日、農薬【工除草剤、殺菌剤、殺虫剤又は成長調制剤
として中広（使用され、現代社会に大きな貢献としてい
るものの一つである。Today, pesticides are used as herbicides, fungicides, insecticides, and growth regulators, and are one of the major contributions to modern society.
この様な農薬は、医薬同様充分な注意をムい、且つ、政
令に従い、適切な使用方法で使用すれば何等人命に害を
及ぼすものではない。These agricultural chemicals, like medicines, do not pose any harm to human life if they are used with sufficient caution, in accordance with government ordinances, and in an appropriate manner.
しかし、ｇｋ桑そ安全に使用すべく、幾多の努力がなさ
れているにも拘わらず、誤飲される場合が実際に起こり
、農薬のより安全な剤型が一方で求められている。However, despite numerous efforts to use gk mulberry safely, cases of accidental ingestion still occur, and safer formulations of agricultural chemicals are being sought.
例えば、子供や老人が、Ｉ′ＩＩ涼飲料水とまちがって
、液体状のａ桑を誤飲するとか、不注意にも大人がｄ％
飲するとか、錠剤の場合であっても栗とか、食用とか、
栄養剤として誤用したり、その他の目的に使用すること
がある。この様な誤用によりａ桑を口にした場合、１大
な事態となり５ることがある。For example, a child or elderly person may accidentally drink liquid a-mulberry instead of I'II soft drink, or an adult may inadvertently drink d%
Chestnuts, edibles, etc.
It may be misused as a nutritional supplement or used for other purposes. If a mulberry is ingested due to such misuse, a serious situation may occur.
農薬の誤飲を防ぐことな目的として、特公昭５６−３４
５６１号公報には、除草性ビピリジウム第４級塩をＩＵ
ｍｆｉ％以上含むグル状の除草剤組成物が記載されてい
る。この発明は、上記ビピリジウム第４級塩の水溶液を
ゲルの状態にして、比較的飲み雉くした点に特徴がある
が、それでもなおビピリジウム第４級塩の濃度は高濃度
であり、誤まって口の中へ入れた場合、充分に安全とは
言えない。To prevent the accidental ingestion of agricultural chemicals,
Publication No. 561 discloses that herbicidal bipyridium quaternary salt is
Glue-like herbicide compositions containing at least mfi% are described. This invention is characterized in that the aqueous solution of the bipyridium quaternary salt is made into a gel state and is relatively drinkable, but the concentration of the bipyridium quaternary salt is still high, so It is not completely safe if you put it in your mouth.
そこで、本発明の目的は、ゲル状の形態よりも一層飲み
込み雉い固体状の除草剤組成物を提供することにある。Therefore, an object of the present invention is to provide a solid herbicide composition that is easier to swallow than a gel-like herbicide composition.
また、本発明の他の目的は、仮に誤まって口の中に入れ
た場合であって、人体に対する悪影響がないか或いは比
較的Ｍ歇である固体状の除草剤組成物を提供することに
ある。Another object of the present invention is to provide a solid herbicidal composition that has no adverse effects on the human body or is relatively safe even if accidentally put into the mouth. be.
本発明の更に他の目的は、固体状の除草剤組成物を別の
目的のために清涼飲料や牛乳などの液体に混入した場合
、グル化を起し、かかる液体が誤って飲用されるのを防
止し得るような固体状の除草剤組成物を提供することに
ある。Still another object of the present invention is that when a solid herbicide composition is mixed into a liquid such as a soft drink or milk for another purpose, gluing occurs and the liquid is ingested by mistake. The object of the present invention is to provide a solid herbicidal composition that can prevent the above.
本発明の更に他の目的は、固体状の除草剤組成物が本来
の除草剤として使用のために、比較的大量の水に加えら
れた場合、使用のための散布に支障がない程度に溶液を
形成し、且つ、適当な除草活性を損なわない溶液を与え
る固体状の除草剤組成物を提供することにある。Still another object of the present invention is that when the solid herbicide composition is added to a relatively large amount of water for use as a proper herbicide, the composition can be dissolved to the extent that it does not interfere with the application of the herbicide composition for use. The object of the present invention is to provide a solid herbicidal composition which forms a solution which does not impair proper herbicidal activity.
本発明の更に他の目的は、以下の説明から明らかとなる
であろう。Further objects of the invention will become apparent from the description below.
本発明者の研究によれば、前記本発明の目的は、（ｉ）
除草性ビピリジウム第４級イオンの含有量が１０重虚チ
以下、（Ｉ）ゲル形成性を模型合体の含有量が０．１〜
７５ｉ盪チ、ＯＭ）グル化剤の含有量が０〜５０重量％
、（ｔｖ）汀機添加助剤の含有量がＯ〜ｌ０ｊｌ瓜チ反
び（Ｖ）充填剤の含ｉｔが０〜６０Ｊｉ麓チよりなる固
体状除草剤組成物によって達成されることがわかった。According to the research of the present inventor, the object of the present invention is (i)
The content of the herbicidal bipyridium quaternary ion is 10% or less, and (I) the content of the gel-forming model is 0.1 to 10%.
75i, OM) Gluing agent content is 0 to 50% by weight
(TV) It was found that the content of the strainer addition aid was 0 to 10jl and the content of the filler (V) was 0 to 60Ji. .
本発明の除草剤組成物は次の如き特ａを有する。その一
つは、液状ではなく、自己流動性の少い粉末、ペレット
状あるいは塊状などの固体状であり、まず、大皿の誤飲
がさけられること又、液体とは異なり一度に多量の摂取
が虐かしいことがまず、あげられる。The herbicidal composition of the present invention has the following characteristics a. One is that it is not a liquid, but a solid such as a powder, pellet, or lump that has low self-flowing properties. First, it prevents accidental swallowing from a large plate, and unlike liquid, it cannot be ingested in large quantities at once. The cruel things are mentioned first.
その第２点として、水あるいは清涼飲料水、牛乳あるい
はその他の液状物に誤って添加された場合、少量の場合
、液体自体が粘度を増し、本来の液状の常態でないこと
を認識させると共に、それ自体を誤飲しても乍大な事態
にはいたり雌いこと、又、ｆ大事態の予想されるごとき
多量誤飲する危険がある量率組成物が液体に添加された
場合、本発明の組成物は水などと作用し、流動性の奢る
しく低いか或いはある場合は実質的危険を予想されるよ
うな流動性を有しないペーストを形成し、不測の事態に
も対拠できないようになっている。すなわち、本発明の
組成物昏工誤用による安全性の極めて高い。Second, if it is accidentally added to water, soft drinks, milk, or other liquids, in small amounts, the liquid itself will increase in viscosity, making you aware that it is not in its original liquid state. If a composition of the present invention is added to a liquid, there is a danger that even if it is accidentally ingested, it will cause a serious situation, and there is a risk of accidental ingestion of a large amount, which is expected to cause a serious situation. When the composition interacts with water etc., it forms a paste with extremely low fluidity or, in some cases, no fluidity that can be expected to pose a substantial danger and cannot be used against unforeseen circumstances. ing. That is, the composition of the present invention has extremely high safety against misuse.
第３の特徴は、以上の如き、誤用に対する安全性が極め
て高いにも拘わらず、除草剤の効果は非常に高く、かつ
、除草剤本来の目的とする使用においてきわめて簡単に
液剤として単に希釈し、施用できろ点である。すなわち
、従来の液状体ビピリジウム第４級イオンとほとんど全
（同様に施用できる利点を有している。The third characteristic is that although the herbicide is extremely safe against misuse, it is extremely effective and can be used for its intended purpose by simply diluting it as a liquid. , this is the point where it can be applied. That is, it has the advantage that it can be applied almost entirely in the same manner as the conventional liquid bipyridium quaternary ion.
従って、本発明の組成物の特徴は、誤用による危険を著
しく低減でき、ビピリジウム第４級塩の本来の使用にお
いてはその除草活性を十分に生かすことができるという
優れた点を有している。Therefore, the composition of the present invention has the advantage of being able to significantly reduce the risk of misuse and making full use of its herbicidal activity when the bipyridium quaternary salt is originally used.
本発明において用いられるビピリジウム第４級塩として
は、下記一般式（ｉ）
％式％
および／または下記一般式（ＩＩ）
で表わされるものが有利である。As the bipyridium quaternary salt used in the present invention, those represented by the following general formula (i) % formula % and/or the following general formula (II) are advantageous.
前記式（ｉ）または〔「〕において７ニオンの選択は、
例えば、価格など１ｃ２ｉｉｉｉづいて適宜に行われる
。アニオンとしては、適当な水溶性を有する塩を生ずる
ものが好ましい。１価または多価であり得るアニオンの
例としては、酢改根、ベンゼンスルホンａｆｆｉ根、安
息香１！！根、臭素ｔ！ｌ根、臭素イオン、酪ｃｌｊｔ
根、塩素酸根、塩素イオン、クエンば根、ギ戚根、フル
オーケイ酸根、７マル酸根、フルオルホウ素ｌ！２根、
沃素イオン、乳１１に根、リンゴ酸根、マレインｆ！！
根、メチル硫酸根、硝酸根、プロピオン酸根、リン酸根
、サリチル酸根、スルファミン酸根、フハク酸根、硫酸
根、チオシアン酸根、酒石酸根および、−トルエンスル
ホン酸根を挙げることができる。The selection of the 7-ion in the above formula (i) or [''] is,
For example, this is done as appropriate based on price, etc. The anion is preferably one that yields a salt with appropriate water solubility. Examples of anions that can be monovalent or polyvalent are vinegar cleavage, benzene sulfone affi root, benzoin 1! ! Root, bromine t! l root, bromide ion, butycljt
Root, chlorate root, chloride ion, citric acid root, citric acid root, fluorosilicic acid root, 7 malic acid root, fluoroboron l! 2 roots,
Iodine ion, milk 11 root, malic acid root, malein f! !
Mention may be made of the radicals methylsulfate, nitrate, propionate, phosphate, salicylate, sulfamate, succinate, sulfate, thiocyanate, tartrate and -toluenesulfonate.
好ましいのは臭素イオン、塩素イオン、沃素イオンｌた
はメチル硫酸根である。Preferred are bromide ion, chloride ion, iodide ion or methyl sulfate group.
上記一般式（ｉ）の化合物の例としては、仔１１，１’
−エチレン−２，２′−ビビリジクムジズｐマイト（ジ
クアト・ジクロライド）
（ｄｉｑｕａｔ ｄｉｂｒｏｍｉｄｅ ）（ロ）１，１
′−エチレン２，２′−ビビリジニウムジクロライド
←→１，１′−エチレンー２．２′−ビビリジニウムジ
アイオダイド
等を挙げることができる＠
かかる化合物をＳ造する方法は符に限定されるものでは
ない。例えば、この化合物として、ジクワット・ジクロ
ライドを用いた場合、この化合物が原料としてピリジン
をラネーニッケル触媒により二念化した２２′ビピリジ
ルとエチレングルマイトを用いて４級化することにより
製造したものなどには好適に本発明は適用される。Examples of compounds of the above general formula (i) include 11,1'
-Ethylene-2,2'-biviridicum dibromide (diquat dibromide) (b) 1,1
'-ethylene 2,2'-biviridinium dichloride←→1,1'-ethylene-2,2'-biviridinium diiodide, etc.@ The method for producing such a compound is limited to the following. It's not something you can do. For example, when diquat dichloride is used as this compound, this compound is produced by quaternizing pyridine as a raw material using 22' bipyridyl and ethylene glumite, which are divalently converted using a Raney nickel catalyst. The present invention is preferably applied.
かかる一般式〔１〕の化合物の例として、に）１．１′
−ジメチル−４，４′−ビピリジニウム・ジクロライド
（バラクアト・ジクロライド）（ホ）１．１′−ジー２
−ヒト−キシエチル−４，４’−ビピリジニウム・ジク
ロライド
（へ）１−（２−ヒドロキシエチル） −ｉ’−メチル
−４，４’−ビピリジニウム・ジクロライド（ト）Ｌ、
１’−ジー（カルバモイルメチル）−４，４’−ビピリ
ジニウム・ジクロライド
（ト）１．１’−ビスーＮ、Ｎ−ジメチルカルバモイル
メチル−４，４′−ビピリジニウム・ジクロライド（す
）１，１’−ビスーＮ、Ｎ’−ジエチルカルバモイルメ
チル−４，４′−ビピリジニウム・ジクロライド（スｌ
１１ ｔ’−ジアセトニル−４，４′−ビピリジニウ
ム°ジクロライド
に）１，１′−ジェトキシカルボニルメチル−４，４’
−ビピリジニウム・ジクロライド
ｅＦ）１，１’−ジアリル−４，４′−ビピリジニウム
・ジクロライド
（ワＮ、１’−ジメチルチ士−４，４′−ビピリジニウ
ム・ジクロライド
ｔどが挙げられる。As an example of the compound of general formula [1], 1.1'
-dimethyl-4,4'-bipyridinium dichloride (baraquat dichloride) (e) 1.1'-di2
-human-xyethyl-4,4'-bipyridinium dichloride (h)1-(2-hydroxyethyl) -i'-methyl-4,4'-bipyridinium dichloride (h)L,
1'-di(carbamoylmethyl)-4,4'-bipyridinium dichloride (su)1,1'-bis-N,N-dimethylcarbamoylmethyl-4,4'-bipyridinium dichloride (su)1,1'- Bis-N,N'-diethylcarbamoylmethyl-4,4'-bipyridinium dichloride (sl
11 t'-Diacetonyl-4,4'-bipyridinium° dichloride) 1,1'-jethoxycarbonylmethyl-4,4'
-Bipyridinium dichloride eF) 1,1'-diallyl-4,4'-bipyridinium dichloride (1'-dimethyldichloride-4,4'-bipyridinium dichloride).
かかる一般式（Ｉｌ）の化合物は、例えば、欠配反応式
で示される方法、つまりジピリジンとアルキルハライド
とを反応させる方法によって製造することができる。Such a compound of general formula (Il) can be produced, for example, by a method represented by a defective reaction scheme, that is, a method in which dipyridine and an alkyl halide are reacted.
本発明の除草性組成物における活性成分は、前記一般式
（［、ｌまたは〔厘〕、或いは（ｉ）と（ｆｆ）の混合
物を含んでいればよい。The active ingredient in the herbicidal composition of the present invention may contain the general formula ([, l or [厘]), or a mixture of (i) and (ff).
殊に（ｉ）と（ＩＩ）を混合して使用する場合、好んで
用いられる岨合せとしては、例えば（イ）−（に）、仲
）−に）、（イ）−一、←）−一、げ）−（）＞ ｉた
け（ロ）−（ト）などが挙げられる。In particular, when (i) and (II) are used in combination, preferred combinations include (a)-(ni), naka)-ni), (b)-1, ←)- Examples include 1, ge)-()> itake(b)-(g), etc.
本発明の組成物中のビピリジウム第４級イオンの含有量
は、安全的見地から、一般の誤飲における摂取量が人体
に重大な事態を生起させない量であり、高々１０１Ｌ量
チであり、好ましくは９重量％以下である。From a safety standpoint, the content of bipyridium quaternary ions in the composition of the present invention is such that the amount ingested by accidental ingestion will not cause any serious harm to the human body, and is preferably at most 101 L. is 9% by weight or less.
一方、ビピリジウム第４級イオンの濃度の下限は、特に
制限を受げないが、運搬、取り仮いの容易さ、保有など
の点から、２重量％以上、好ましくは３重量％以上が推
奨される。On the other hand, the lower limit of the concentration of bipyridium quaternary ions is not particularly limited, but from the viewpoint of transportation, ease of storage, storage, etc., a concentration of 2% by weight or more, preferably 3% by weight or more is recommended. Ru.
本発明の組成物におけるグル形成性有機重合体は、水と
混合した時にグルを形成し５るものであれば種々のもの
が使用可能であり、多量の水に０Ｔ溶るものが好適であ
る。好適な列としては、多嘘類、カルボキシメチルセル
ツース類、ヒドジキシエチルセルー−ス類が挙げられる
。Various types of glue-forming organic polymers can be used in the composition of the present invention as long as they form a glue when mixed with water, and those that are 0T soluble in a large amount of water are preferred. . Suitable series include polyesters, carboxymethyl celluloses, and hydroxyethyl celluloses.
この多糖類としては、−粉或いは化学的に変性されたｗ
粉が含まれる。また肩当な構造を持ち一般に増粘剤とし
て用いる前々の化合物を本発明の組成物に悪影響を及ぼ
さない限り使用することができる。その例としては、ポ
リビニルアルコール、ポリエチレングリコールを示すこ
とができる。This polysaccharide includes - powder or chemically modified w
Contains powder. In addition, the aforementioned compounds which have a similar structure and are generally used as thickeners can be used as long as they do not adversely affect the composition of the present invention. Examples include polyvinyl alcohol and polyethylene glycol.
かかるゲル形成性有機重合体は、！ＬＨ，物当り０．１
〜７５Ｍ’ａ％の範囲で使用される。殊に０．５〜６０
重ｔチ使用するのが望ましい結果な与える。特にゲル形
成性有機重合体は、組成物当り、前記の割合とする外に
、組成物中のビピリジウムｍ４ＲイオンＩＭ量部に対し
、０．０１〜２０重重部、好ましくは０．０５〜１５重
量部、特に０．１〜１．０重大部使用されるのが好まし
い。Such gel-forming organic polymers are! LH, hit 0.1
It is used in the range of ~75M'a%. Especially 0.5-60
Using more weight gives the desired result. In particular, the gel-forming organic polymer should be used in the above-mentioned proportions per composition, and in addition, 0.01 to 20 parts by weight, preferably 0.05 to 15 parts by weight, based on the amount of bipyridium m4R ion IM in the composition. It is preferred to use 0.1 to 1.0 parts, especially 0.1 to 1.0 parts.
以上の如く、グル形成性ｆ機重合体の割合を制御するこ
とによって、本発明の組成物を誤って、水を含有する液
体に加え、それを飲むという二重の誤りをおかしたとき
でも重大な事態を招くことが予想されろ場合でも、液体
中で組成物はグル状体を形成し、誤飲の機会を少なくし
、爽にかかるものを気付かずに口の中へ入れたときでも
その流動性の欠如から事大な事態を招く量、ゲル状物を
飲むこともできない。すなわち極めて安全な除草性紙成
剤が、除草性ビリジクム第４級イオンの量と、ゲル形成
性有機重合体の址との双方を規定することにより形成さ
れるのである。かくして、前記の如く、ビピリジウム第
４級イオンとグル形成性有機重合体の濃度と割合をｉＪ
！４！Ｊ１することにより安全性の高い組成物が得られ
る。As described above, by controlling the proportion of the glue-forming f-functional polymer, even if the composition of the present invention is mistakenly added to a water-containing liquid and the liquid is drunk, the double error can be avoided. Even if it is expected that a dangerous situation will occur, the composition forms a glue-like body in the liquid, reducing the chance of accidental ingestion, and even if something that splashes on something is put into the mouth without realizing it. I can't even drink gel-like substances in such quantities that the lack of fluidity would cause a serious situation. That is, an extremely safe herbicidal paper forming agent can be formed by specifying both the amount of herbicidal viridicum quaternary ion and the content of the gel-forming organic polymer. Thus, as described above, the concentration and ratio of bipyridium quaternary ion and glue-forming organic polymer can be adjusted to iJ
! 4! By carrying out J1, a highly safe composition can be obtained.
本発明の組成物においては、グル化を促進し或いはグル
化物の安定化のためにゲル化剤を使用しな（でもよいが
、時として使用するのが有利である。妹にグル化剤の使
用によってグル形成性９機重合体の使用側合を５０％以
上少くすることが不可能となることがある。In the compositions of the present invention, gelling agents may not be used (although it is sometimes advantageous to use them) to promote glulation or stabilize the gludide. Depending on the usage, it may become impossible to reduce the usage side combination of the glu-forming nine-unit polymer by more than 50%.
かかるグル化剤としては微細構造を有するシリカ、アル
ミナ、シリカマグネシアなどの無機固体の水不溶性のも
のを使用することができるしまた、例えば、硼砂、メタ
硼酸ナトリウムまたはカリウム、４硼醒ナトリウム、硼
酸アンモニウムなどの硼＋１１塩の如き水溶性の無機固
体も使用することができる〇
上記グル剤は、本発明の組成物当り５０重量％以下使用
されるが、好ましくは０．１〜４０重ｔｑｂである。殊
に上記水不溶性のものを使用するときは５〜４ｏＸｆｒ
ｋ’４が有利であり、水溶性のものの場合は０．１〜１
０重量％使用するのが適当である。As such gluing agents, water-insoluble inorganic solids such as finely structured silica, alumina, silica magnesia, etc. can be used, and also, for example, borax, sodium or potassium metaborate, sodium borax, boric acid, etc. Water-soluble inorganic solids such as boron+11 salts such as ammonium can also be used. The above glue is used in an amount of up to 50% by weight based on the composition of the present invention, but preferably in an amount of 0.1 to 40 tqb. be. Especially when using the above water-insoluble ones, 5 to 4 oXfr.
k'4 is advantageous, and for water-soluble ones 0.1-1
It is appropriate to use 0% by weight.
本発明組成物が水と作用しグルを形成する際のＰＨはあ
まりアルカリすぎたり、酸性すぎるとそのグル形成能は
減退する。しかし弱酸性、微アルカリ性であるならばそ
のゲル形成には特に大きな支障はない。If the pH of the composition of the present invention when it interacts with water to form a glue is too alkaline or too acidic, its glue-forming ability will be reduced. However, if it is weakly acidic or slightly alkaline, there is no particular problem in gel formation.
本発明の除草剤組成物は、形状なをする固体乃至実質的
に流動性を有しない固体の形態であるが、上記ビピリジ
ウム第４級イオン、ゲル形成性有機重合体、また必要に
よりグル化剤の他に水と作用して固化剤として、または
単に混合される充填剤を含んでいてもよい。この充填剤
としては水ｇ性のものが好ましい。かかる充填剤として
は、無水および水不飽和の結晶水を育する無機および有
機の化合物が示される。例としては、無水硫酸ソーダ、
芒硝、タルク、食塩などがある。The herbicide composition of the present invention is in the form of a shaped solid or a solid having substantially no fluidity, and contains the bipyridium quaternary ion, a gel-forming organic polymer, and, if necessary, a gluing agent. In addition, fillers that act with water as solidifying agents or are simply mixed may also be included. This filler is preferably water-based. Such fillers include anhydrous and water-unsaturated inorganic and organic compounds that grow water of crystallization. Examples include anhydrous sodium sulfate,
Examples include mirabilite, talc, and salt.
上記充填剤の使用櫨は、組成物に対し６０重量％以下、
好ましくはｓｏｉｍチ以下であればよい。The amount of filler used in the above filler is 60% by weight or less based on the composition;
Preferably, it is less than soim.
本発明では更に櫨々の有機添加助剤を加えることも可能
である。かかる有機添加助剤としては、慣用、特に誤飲
などの災害からのがれるために催吐剤、あるいは着臭剤
、あるいは苦味剤などの添加剤を加えて、より安全な除
草性組成物をつくることも町血であり、その方が一般に
好ましい場合もある。本発明においても、催吐剤、着臭
剤、苦味剤などは本発明における条件を満足すれば特に
限定されるものではない。In the present invention, it is also possible to further add an organic additive auxiliary agent. As such organic additives, additives such as emetics, odorants, and bittering agents are commonly used, especially to avoid accidents such as accidental ingestion, to create safer herbicidal compositions. It is also a town blood, which is generally preferable in some cases. In the present invention, emetics, odorants, bittering agents, and the like are not particularly limited as long as they satisfy the conditions of the present invention.
しかし催吐剤、ｊＡ剤、苦味剤などが有機系で、アルキ
ル芳香族系または複素凌系化合物のときに好ましい使用
態様となることがある。However, when the emetic, jA agent, bittering agent, etc. are organic, alkyl aromatic or complex compounds, preferred usage may occur.
また、これらの警告物質の他に一般に除草性組成物に利
用される添加物を加えることもできる。すなわち、アル
キル硫酸エステル、アルキルスルホン酸塩類、リグニン
スルホン酸塩類、ポリオキシエチレングリコールエーテ
ル類、ポリオキシエチレンアルキルアリールエーテル、
ポリオキシエチレンソルビタンモノアルキレート、ジナ
フチルメタンジスルホン酸塩等の界面活性剤、乳化剤又
は分散剤又は尿素剤：カルボキシメチルセルロース、ア
ラビアゴム等の各種補助剤等の１４４又は２柿以上を用
いて調製される。In addition to these warning substances, additives commonly used in herbicidal compositions can also be added. That is, alkyl sulfates, alkyl sulfonates, lignin sulfonates, polyoxyethylene glycol ethers, polyoxyethylene alkylaryl ethers,
Polyoxyethylene sorbitan monoalkylate, surfactant such as dinaphthylmethane disulfonate, emulsifier or dispersant, or urea agent: Prepared using 144 or 2 persimmons or more, various auxiliary agents such as carboxymethyl cellulose, gum arabic, etc. Ru.
前記有機添加助剤は、本発明の＃Ｊｌ我物当り、１０１
鳳チ以下、好ましくは０．５〜８重筺多使用するのが望
ましい。The organic additive auxiliary agent is #Jl of the present invention, 101
It is desirable to use as many as 0.5 to 8 layers, preferably 0.5 to 8 layers.
本発明の組成物は、固体の状態で用いられろ。The composition of the invention may be used in solid form.
このような剤としては、粉剤、粒剤、ベレット状剤、シ
リンドリカル状剤など各種の形態で使用される。その際
、強度、すべり、あるいは水溶性向上のため種々の薬剤
も加えろことができるＯ
本発明の除螺剤徂成柳は、除草の目的に使用する。この
濠、この＠成物をペースト状から完全な溶解状態又は分
散状態で使用される。かくすることにより、従来の水浴
性剤と同様に用いることができる。Such agents are used in various forms such as powders, granules, pellets, and cylindrical agents. At that time, various chemicals may be added to improve strength, slipperiness, or water solubility.The screw remover of the present invention is used for the purpose of weeding. This compound is used in a paste state to a completely dissolved state or a dispersed state. By doing so, it can be used in the same way as conventional water bathing agents.
以下実施例を挙げて本発明を詳述する。The present invention will be described in detail below with reference to Examples.
実７Ｉ！１例１ （パラコート製剤のＦＡ製）３５．０
．ｌ［ｌ１％の１．１−ジメチル−４，４−ビピリジウ
ム・ジクロライド（以下”ＰＱＯＩ２’と略記する）の
Ａノ１水醪液７８１ｇと非イオン界面活！４１（アルキ
ルフェニルニーｆ ＃ 系） ２（ｉ，Ｏ！ｉトポリオ
キシエチレンアルキルアミン系界面活性剤８０．（ｉ＆
をｔム加し、さらに安息香酸ナトリウム１８．０９とメ
タ硼酸ナトリウムｓ、ｕ ｇと水ｉｏ。Real 7I! Example 1 (paraquat formulation made by FA) 35.0
．． 1% of 1.1-dimethyl-4,4-bipyridium dichloride (hereinafter abbreviated as "PQOI2') in A-no. 2(i,O!i topolyoxyethylenealkylamine surfactant 80.(i&
and then add 18.09 g of sodium benzoate, 18.0 g of sodium metaborate, and 1 g of water.
屑〕を加え、濃塩酸でＰＨを６．９に調節した。] and the pH was adjusted to 6.9 with concentrated hydrochloric acid.
これに複素、！ｊ！催吐剤Ｕ、３０．９と着色剤（アシ
ッドブルー１）の２０チ水浴液を６．５０ｇ添加してさ
らに着臭剤（アミン系）をｓ、ｕ ｙ添加した後水を加
えて全体を１．０リツトルとした。This is complex! j! Add 6.50g of emetic U, 30.9 and a 20% water bath solution of a coloring agent (Acid Blue 1), then add an odorant (amine type) s, uy, and then add water to bring the whole to 1. .0 liter.
この除草性組成物の主たる組成は次の通りであった。The main composition of this herbicidal composition was as follows.
実施例２（バラコートとジクワットの鹿合裂剤の調製）
３５．０！１ｆｆｉチの１．１′−ジメチル−４，４′
−ビピリジウム・ジクロライド（以下ＰＱＯｊ２と略記
する）の濃厚水溶液３５５．１ 、＠と３０．０重量％
の１．五′−エチレンー２．２′−ビピリジウム・ジク
ロライド（以下′″１）ＱＢｒ２’と略記する）の貞厚
水醪液５６５．０ ｇを混合して、非イオン界面活性剤
（アルチルフェニルエーテル系） ２０．０！！とポリ
オキシエチレンアルキルアミン系界面活性剤４Ｕ、Ｏｇ
を添加して水均１００ｊｌ〆を加え、濃塩酸でＰ Ｈを
３．１に調節した。Example 2 (Preparation of Balaquat and Diquat cleavage agent) 35.0!1ffi of 1.1'-dimethyl-4,4'
- Concentrated aqueous solution of bipyridium dichloride (hereinafter abbreviated as PQOj2) 355.1 @30.0% by weight
1. A nonionic surfactant (altylphenyl ether type ) 20.0!! and polyoxyethylene alkylamine surfactant 4U, Og
100 liters of water was added thereto, and the pH was adjusted to 3.1 with concentrated hydrochloric acid.
これに？！！素ｉｊＩ倦吐剤０ 、３０．９と着色剤（
アシッドブルー１）の２０チ水溶液を６．５０ｇ添加し
、さらに着臭剤（アミン系）をｓ、ｏ Ｉｉ添加後、水
を加えて全体を１．０リツトルとした。to this? ! ! Prime ijI emetic agent 0, 30.9 and colorant (
After adding 6.50 g of a 20-liter aqueous solution of Acid Blue 1) and adding an odorant (amine type), water was added to bring the total volume to 1.0 liter.
この除草性組成物の主たる組成は次の通りであった。The main composition of this herbicidal composition was as follows.
Claims (1)
重量％以下、（ｉｉ）ゲル形成性有機重合体の含有量が
０．１〜７５重量％、（ｉｉｉ）ゲル化剤の含有量が０
〜５０重量％、（ｉｖ）有機添加助剤の含有量が０〜１
０重量％及び（ｖ）充填剤の含有量が０〜６０重量％よ
りなる固体状除草剤組成物。(i) Content of herbicidal bipyridium quaternary ion is 10
% by weight or less, (ii) the content of the gel-forming organic polymer is 0.1 to 75% by weight, (iii) the content of the gelling agent is 0
~50% by weight, (iv) content of organic additive auxiliary agent is 0-1
A solid herbicide composition comprising 0% by weight and (v) a filler content of 0 to 60% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4198586A JPS62201803A (en) | 1986-02-28 | 1986-02-28 | Herbicide composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4198586A JPS62201803A (en) | 1986-02-28 | 1986-02-28 | Herbicide composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62201803A true JPS62201803A (en) | 1987-09-05 |
Family
ID=12623490
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4198586A Pending JPS62201803A (en) | 1986-02-28 | 1986-02-28 | Herbicide composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62201803A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996003871A1 (en) * | 1994-08-03 | 1996-02-15 | Zeneca Limited | Gel formulation |
| CN1062710C (en) * | 1990-07-10 | 2001-03-07 | 曾尼卡有限公司 | Herbicidal compositions |
| US6649190B1 (en) | 1994-07-28 | 2003-11-18 | Syngenta Limited | Gel formulation |
| US11419329B2 (en) | 2010-03-12 | 2022-08-23 | Monsanto Technology Llc | Agrochemical gel compositions |
-
1986
- 1986-02-28 JP JP4198586A patent/JPS62201803A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1062710C (en) * | 1990-07-10 | 2001-03-07 | 曾尼卡有限公司 | Herbicidal compositions |
| US6649190B1 (en) | 1994-07-28 | 2003-11-18 | Syngenta Limited | Gel formulation |
| WO1996003871A1 (en) * | 1994-08-03 | 1996-02-15 | Zeneca Limited | Gel formulation |
| JPH10503765A (en) * | 1994-08-03 | 1998-04-07 | ゼネカ・リミテッド | Gel preparation |
| US6436439B1 (en) | 1994-08-03 | 2002-08-20 | Syngenta Limited | Gel formulation |
| CN1108098C (en) * | 1994-08-03 | 2003-05-14 | 曾尼卡有限公司 | Gel formulation |
| US11419329B2 (en) | 2010-03-12 | 2022-08-23 | Monsanto Technology Llc | Agrochemical gel compositions |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101410327B (en) | Thickened fluid composition comprising chlorine dioxide | |
| CN102088860B (en) | Concentrate for preparing disinfectant and preparation and use method thereof | |
| CN110150315B (en) | Solid high-purity chlorine dioxide releasing agent | |
| EP2292096A2 (en) | Active bromine containing biocidal compositions and their preparation | |
| US6602442B1 (en) | Composition for generating chlorine dioxide | |
| PL90345B1 (en) | ||
| AU781655B2 (en) | Stable, high available halogen 1,3,5-triazine-2,4,6-trione compositions having rapid dissolution rates | |
| EP1154690B1 (en) | Composition for generating chlorine dioxide | |
| JPS62201803A (en) | Herbicide composition | |
| CN113598191A (en) | Formula and use scheme of binary-packaged low-temperature disinfectant | |
| BG108194A (en) | Composition containing paraquat and/or diquat, an alginate and an emetic and/or purgative | |
| US7309503B2 (en) | Methods for the preparation of concentrated aqueous bromine solutions and high activity bromine-containing solids | |
| CA1097096A (en) | Herbicidal compositions | |
| KR0180547B1 (en) | Herbicidal compositions | |
| JP2001520173A (en) | Improved iodine antimicrobial solution containing nonionic surfactant and halogen anions | |
| EP2359694B1 (en) | Preparation of concentrated bromine solutions and high activity bromine solids | |
| JPH0153843B2 (en) | ||
| GB1577317A (en) | Herbicidal compositions | |
| JP2780846B2 (en) | Herbicide composition | |
| KR810000277B1 (en) | Herbicidal compositions | |
| JPH11157805A (en) | Production kit for aqueous chlorine dioxide, aqueous chlorine dioxide precursor composition and production of aqueous chlorine dioxide | |
| JPS6135964B2 (en) | ||
| KR790001657B1 (en) | Concentrated herbicidal compositions | |
| JP2703973B2 (en) | Herbicide composition | |
| WO2022192147A1 (en) | Liquid antimicrobial compositions and methods |