JPS61111543A - Etching method - Google Patents

Etching method

Info

Publication number
JPS61111543A
JPS61111543A JP23389284A JP23389284A JPS61111543A JP S61111543 A JPS61111543 A JP S61111543A JP 23389284 A JP23389284 A JP 23389284A JP 23389284 A JP23389284 A JP 23389284A JP S61111543 A JPS61111543 A JP S61111543A
Authority
JP
Japan
Prior art keywords
oxide film
etching
etched
photo resist
photoresist
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP23389284A
Other languages
Japanese (ja)
Inventor
Tsutomu Otogawa
音川 努
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm Co Ltd
Original Assignee
Rohm Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm Co Ltd filed Critical Rohm Co Ltd
Priority to JP23389284A priority Critical patent/JPS61111543A/en
Publication of JPS61111543A publication Critical patent/JPS61111543A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/306Chemical or electrical treatment, e.g. electrolytic etching

Landscapes

  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Weting (AREA)

Abstract

PURPOSE:To enable fine patterning by markedly reducing the amount of side etching by a method wherein the etching process is divided into many times of step, and the baking process is made present during them. CONSTITUTION:The Si oxide film 20 of a semiconductor wafer 10 is coated with a photo resist 30, and about 50% of film thickness of the oxide film 20 is etched by dipping in the etchant. The wafer 10 is washed with pure water and dried. The dried wafer 10 is mounted on e.g. a hot plate, and the adhesion of the photo resist 30 with the Si oxide film 20 is enhanced again by baking at a heating temperature and for a heating time which are suitable for the kind of photo resist. In other words, the photo resist 30 deforms and comes to cover the side etching part 21 of the oxide film 20. The remnant portion of Si oxide film 20 is completely etched by dipping this baked wafer 10 again in the etchant.

Description

【発明の詳細な説明】 (イ)産業上の利用分野 この発明は、半導体ウェハに所定のデバイスを形成する
場合に必要なエツチング方法に係り、特に、ウェットタ
イプのエツチング方法に関する。
DETAILED DESCRIPTION OF THE INVENTION (a) Field of Industrial Application The present invention relates to an etching method necessary for forming a predetermined device on a semiconductor wafer, and particularly to a wet type etching method.

(ロ)従来技術 一般にこの種のエツチング方法は、例えば半導体ウェハ
の表面に形成させたシリコン酸化膜或いは電極等をパタ
ーンニングする場合に利用されている。ここでは、前記
シリコン酸化膜をパターンニングする場合を例として説
明する。
(b) Prior Art Generally, this type of etching method is used for patterning, for example, a silicon oxide film or electrodes formed on the surface of a semiconductor wafer. Here, the case of patterning the silicon oxide film will be explained as an example.

まず前記半導体ウェハの表面にシリコン酸化膜を成長さ
せ、ホトレジストの塗布・露光・現像工程を経て前記シ
リコン酸化膜のエツチングすべき部分以外をホトレジス
トで被覆した後、前記半導体ウェハを例えば弗化水素等
のエツチング液中に所定時間浸漬させることにより前記
シリコン酸化膜をパターンニングしている。即ち、従来
では一度のエツチングでもって完了させている。このと
き、前記シリコン酸化膜とホトレジストとの界面にエツ
チング液が回り込み、この部分からエツチング深さと比
例してサイドエツチングしてしまうという問題がある。
First, a silicon oxide film is grown on the surface of the semiconductor wafer, and after a photoresist application, exposure, and development process, the silicon oxide film is coated with photoresist except for the portion to be etched. The silicon oxide film is patterned by immersing it in an etching solution for a predetermined period of time. That is, conventionally, etching is completed in one go. At this time, there is a problem in that the etching solution flows around the interface between the silicon oxide film and the photoresist, and side etching occurs from this part in proportion to the etching depth.

即ち、上記方法においては微細なパターンニングを行う
のは非常に困難であり、  ′製品として歩留りの低減
を招くこととなる。
In other words, it is very difficult to perform fine patterning using the above method, which results in a reduction in the yield of the product.

(ハ)目的 この発明は、サイドエツチング量を減少せしめて微細な
パターンニングを可能とし、かつ、製品の歩留りを向上
しうるエツチング方法を提供することを目的としている
(C) Objective The object of the present invention is to provide an etching method that enables fine patterning by reducing the amount of side etching and improves the yield of products.

(ニ)構成 この発明に係るエツチング方法の特徴とする処は、半導
体ウェハの表面の被エツチング部以外を覆ったホトレジ
ストをマスクとして前記被エツチング部を所定の深さま
でエツチングする第1のエツチング工程と、該被エツチ
ング部とホトレジストとを再密着せしめるように該半導
体ウェハを加熱するベーキング工程と、前記ベーキング
されたホトレジストをマスクとして前記残余の被エツチ
ング部を再度エツチングする第2のエツチング工程とを
具備したことにある。
(d) Structure The etching method according to the present invention is characterized by a first etching step in which the etching target area is etched to a predetermined depth using a photoresist covering the surface of the semiconductor wafer other than the etching target area as a mask. , a baking step of heating the semiconductor wafer so as to bring the etched portion and photoresist into close contact again; and a second etching step of etching the remaining etched portion again using the baked photoresist as a mask. It's what I did.

(ポ)実施例 第1図はこの発明に係るエツチング方法の一実施例を示
す説明図であり、被エツチング層とじて本実施例ではシ
リコン酸化膜とする。同図を参考として以下説明する。
(P) Embodiment FIG. 1 is an explanatory view showing an embodiment of the etching method according to the present invention, and the layer to be etched is a silicon oxide film in this embodiment. This will be explained below with reference to the same figure.

■ 半導体ウェハ10の表面11にシリコン酸化膜20
を成長させる。このシリコン酸化膜20のエツチングす
べき部分以外に通常の露光・現像工程を経てホトレジス
ト30を被着させる(第1図(al参照)。
■ Silicon oxide film 20 on the surface 11 of the semiconductor wafer 10
grow. A photoresist 30 is deposited on the silicon oxide film 20 other than the portion to be etched through a normal exposure and development process (see FIG. 1 (al)).

■ 例えば弗化水素等のエツチング液中に前記ホトレジ
スI・30をマスクとした半導体ウェハ10を浸漬させ
ることにより、シリコン酸化膜20の膜厚の約50%を
エツチングする(第1図(b)参照)(第1のエツチン
グ工程)。
(2) Etching approximately 50% of the thickness of the silicon oxide film 20 by immersing the semiconductor wafer 10 using the photoresist I-30 as a mask in an etching solution such as hydrogen fluoride (see FIG. 1(b)). Reference) (first etching step).

■ 前記半導体ウェハ10を大量の純水にて洗浄し、乾
燥させる。
(2) The semiconductor wafer 10 is washed with a large amount of pure water and dried.

■ 前記洗浄した半導体ウェハ10を例えばホットプレ
ートの上に装着し、前記被着したホトレジストの種類に
応じて加熱温度および時間を設定するが22本実施例で
は140℃程度で5分間位行うことにより、ホトレジス
ト30とシリコン酸化膜20との密着性を再度高める(
ベーキング工程)。なお、前記■の工程にて所定厚エツ
チングしたシリコン酸化膜20上端に発生したサイドエ
ツチング部21には、その上部に位置するホトレジスト
30が変形して前記シリコン酸化膜20のサイドエツチ
ング部21を覆うようになる(第1図(C1参照)。
(2) The cleaned semiconductor wafer 10 is mounted on, for example, a hot plate, and the heating temperature and time are set depending on the type of photoresist deposited.22 In this embodiment, the heating is performed at about 140° C. for about 5 minutes. , the adhesion between the photoresist 30 and the silicon oxide film 20 is increased again (
baking process). Incidentally, in the side-etched part 21 generated at the upper end of the silicon oxide film 20 etched to a predetermined thickness in the step (2) above, the photoresist 30 located above is deformed and covers the side-etched part 21 of the silicon oxide film 20. (see Figure 1 (C1)).

■ 前記ベーキングした半導体ウェハ10を再度弗化水
素等のエツチング液中に浸漬させることにより、前記残
余のシリコン酸化膜20を完全にエツチングさせる(第
1図(dl参照)(第2のエツチング工程)。
(2) By immersing the baked semiconductor wafer 10 again in an etching solution such as hydrogen fluoride, the remaining silicon oxide film 20 is completely etched (see FIG. 1 (dl) (second etching step). .

上記の如くパターンニングされた半導体ウェハ10は、
順次拡散および成長工程へと進む。
The semiconductor wafer 10 patterned as described above is
Proceed sequentially to diffusion and growth steps.

なお、この発明は被エツチング部として上記実施例のも
のに限定されず、例えばアルミニウム等の電極および窒
化膜などをパターンニングさせる場合にも有効であるこ
とは言うまでもない。
It goes without saying that the present invention is not limited to the portions to be etched that are described in the above-mentioned embodiments, but is also effective in patterning electrodes such as aluminum, nitride films, and the like.

また、上記実施例ではエツチング工程を2分割した場合
を示したが、これに限定されるものでなく、分割数を3
以上にしそれぞれのエツチング工程の間にベーキング工
程を介在させればサイドエツチング量を更に少な(する
ことができる。
Furthermore, although the above embodiment shows the case where the etching process is divided into two, the etching process is not limited to this, and the number of divisions may be three.
By interposing a baking process between each etching process, the amount of side etching can be further reduced.

(へ)効果 この発明は、上記詳説したように、工・ノチング工程を
複数回に分けると共にその途中に、サイドエツチング部
をホトレジストで覆いかつホトレジストの密着性を良好
にするベーキング工程を介在させたので、全体のサイド
エツチング量を大幅に減少させることができ、よって微
細なパターンニングが可能となる。
(f) Effects As detailed above, this invention divides the etching/notching process into multiple steps, and interposes a baking process in the middle to cover the side etched portion with photoresist and improve the adhesion of the photoresist. Therefore, the total amount of side etching can be significantly reduced, and fine patterning becomes possible.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図はこの発明に係るエツチング方法の一実施例を示
す説明図である。 10・・・半導体ウェハ、11・・・表面、20・・・
シリコン酸化膜、21・・・サイドエ・ノチング部、3
0・・・ホトレジスト。
FIG. 1 is an explanatory diagram showing an embodiment of the etching method according to the present invention. 10... Semiconductor wafer, 11... Surface, 20...
Silicon oxide film, 21... side etching part, 3
0...Photoresist.

Claims (1)

【特許請求の範囲】[Claims] (1)半導体ウェハの表面の被エッチング部以外を覆っ
たホトレジストをマスクとして前記被エッチング部を所
定の深さまでエッチングする第1のエッチング工程と、 該被エッチング部とホトレジストとを再密着せしめるよ
うに該半導体ウェハを加熱するベーキング工程と、 前記ベーキングされたホトレジストをマスクとして前記
残余の被エッチング部を再度エッチングする第2のエッ
チング工程とを具備したことを特徴とするエッチング方
法。
(1) A first etching step of etching the etched part to a predetermined depth using a photoresist covering the surface of the semiconductor wafer other than the etched part as a mask, and bringing the etched part and the photoresist into close contact again. An etching method comprising: a baking step of heating the semiconductor wafer; and a second etching step of etching the remaining etched portion again using the baked photoresist as a mask.
JP23389284A 1984-11-05 1984-11-05 Etching method Pending JPS61111543A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP23389284A JPS61111543A (en) 1984-11-05 1984-11-05 Etching method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP23389284A JPS61111543A (en) 1984-11-05 1984-11-05 Etching method

Publications (1)

Publication Number Publication Date
JPS61111543A true JPS61111543A (en) 1986-05-29

Family

ID=16962197

Family Applications (1)

Application Number Title Priority Date Filing Date
JP23389284A Pending JPS61111543A (en) 1984-11-05 1984-11-05 Etching method

Country Status (1)

Country Link
JP (1) JPS61111543A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05148339A (en) * 1991-02-27 1993-06-15 Bayer Ag Hydrophilic olefinically unsaturated polyurethane and use of same as reactive emulsifier

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05148339A (en) * 1991-02-27 1993-06-15 Bayer Ag Hydrophilic olefinically unsaturated polyurethane and use of same as reactive emulsifier

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