JPS60210675A - Production of water paint having a deodorizing effect - Google Patents
Production of water paint having a deodorizing effectInfo
- Publication number
- JPS60210675A JPS60210675A JP6815184A JP6815184A JPS60210675A JP S60210675 A JPS60210675 A JP S60210675A JP 6815184 A JP6815184 A JP 6815184A JP 6815184 A JP6815184 A JP 6815184A JP S60210675 A JPS60210675 A JP S60210675A
- Authority
- JP
- Japan
- Prior art keywords
- paint
- compds
- water
- deodorizing
- water paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、壁面或いは天井などに使用する水性塗料に関
するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a water-based paint used for walls, ceilings, etc.
凡そ人間の生活する環境において、様々な匂にとり囲ま
れている現状である。そして、良い匂が人間社会の文化
であると考えられ、悪臭は非文化と考えられている。悪
臭を除去する方法として、活性炭等の吸着物質を一定の
容器に封入して、住居の一部に取り付ける方法で吸着を
行う方法を用いているのが一般的である。しかし、この
方法では広い住居空間に於ける悪臭を除去する事は困難
で、住居空間の空気を換気しなければならなかった。と
ころで、住居に於て最も広い面積をもつものが壁面と天
井の様に周りの部分である。本願の目的としては、この
周りの面に悪臭を除去する消臭剤入りの塗料を塗布する
ことにより、住居空間に於て発生する悪臭を除く事を目
的とした水性塗料の製造法にある。In the environment in which humans live, they are currently surrounded by various scents. Good smells are considered to be part of the culture of human society, while bad smells are considered uncultured. A common method for removing bad odors is to enclose an adsorbent such as activated carbon in a certain container and attach it to a part of the house to perform adsorption. However, with this method, it is difficult to remove bad odors from large living spaces, and the air in the living spaces must be ventilated. By the way, the things with the largest area in a house are the surrounding areas, such as the walls and ceiling. The purpose of this application is to provide a method for producing a water-based paint for the purpose of removing bad odors generated in a residential space by applying a paint containing a deodorizing agent to the surrounding surfaces.
本願の製造法の対象としては水性の合成樹脂エマルンヨ
ノ塗料、或いは水溶性樹脂塗料である。一般に水性塗料
の塗料組成としては、結合材である合成樹脂エマルシぢ
ンまたは水溶性樹脂、水、着色顔料、体質顔料、分散剤
、湿潤剤、増粘剤、可塑剤、成膜助剤、防腐剤、防黴剤
と骨材、充填材からなっている。また、一般に水性塗料
はアルカリ性を呈するものが多く、一方で、消臭剤は強
アルカリ性域に於てはその効果が著しく劣るか、又は分
解するものが多い。水性塗料に消臭剤を添加しようとす
る場合、Ｐｉ（を弱アルカリから酸性域にする必要があ
り、また、Ｐ Ｈが５．０以下の中張酸性域では塗料中
の樹脂成分が安定性を失い、ゲル化し、塗料としての機
能が失なわれる。従って塗料のＰＨを６．０〜８．０の
弱アルカリ〜弱酸性域に調整する必要がある。The manufacturing method of the present application is applied to water-based synthetic resin emulsion coatings or water-soluble resin coatings. In general, the composition of water-based paints includes a synthetic resin emulsion or water-soluble resin as a binder, water, coloring pigments, extender pigments, dispersants, wetting agents, thickeners, plasticizers, film-forming aids, and preservatives. It consists of an anti-mold agent, an aggregate, and a filler. Furthermore, in general, many water-based paints exhibit alkalinity, while deodorants are often significantly less effective or decompose in strongly alkaline areas. When adding a deodorizing agent to a water-based paint, it is necessary to change Pi from a weak alkaline to an acidic range, and the resin components in the paint are unstable in a neutral acidic range with a pH of 5.0 or less. The paint loses its properties, gels, and loses its function as a paint.Therefore, it is necessary to adjust the pH of the paint to a weakly alkaline to weakly acidic range of 6.0 to 8.0.
更に、塗面がフラットの場合、消臭剤の接触面が少なく
、悪臭除去効果を大きくする為には塗面に凹凸を設けた
り、塗面表面に通気性を与えたり、使用骨材に気泡性を
持ったものを使用するのがよい。Furthermore, if the painted surface is flat, there is less contact surface for the deodorizer, so in order to increase the odor removal effect, it is necessary to create unevenness on the painted surface, provide air permeability to the painted surface, or add air bubbles to the aggregate used. It is better to use something with gender.
以上の事柄から導き出された本願の構成としては、水性
塗料中に悪臭を化合、中和、抱接等の作用により除去す
る消臭物質を添加し、骨材。The structure of the present application derived from the above points is that a deodorizing substance that removes bad odors by combination, neutralization, inclusion, etc. is added to the water-based paint, and aggregate is added.
充填材として気泡性に富んだバーミキュライト。Vermiculite is highly foamy and can be used as a filler.
パーライト、発泡ポリスチレン、珪藻土などを使用した
上で、ＰＨを６．０〜８．０に調整することを特徴とし
ている。It is characterized by using perlite, expanded polystyrene, diatomaceous earth, etc., and adjusting the pH to 6.0 to 8.0.
以下に本願の構成内容を実施例を含みながら詳述する。The contents of the present application will be explained in detail below, including examples.
まず第１に本願に使用される消臭物質について述べると
、消臭効果のある化合物としては、フラバノノール類、
フラボノール類等の植物性化合物、グリオキサール、ア
ビエチン酸等の有機系化合物、トリポリリン酸２−アル
ミニウム。First of all, regarding the deodorizing substances used in this application, compounds with deodorizing effects include flavanonols,
Plant compounds such as flavonols, organic compounds such as glyoxal and abietic acid, and 2-aluminum tripolyphosphate.
還元鉄等の無機化合物がある。更に、活性炭。There are inorganic compounds such as reduced iron. Additionally, activated carbon.
ゼオライトの様に多孔質の無機化合物もまた悪臭を吸着
する性質があるが、トリポリリン酸２−アルミニウムの
様にＰＩ（が５．０以下のものは、塗料の塗膜形成物質
（例えば、エチレン酢酸ビニル共重合物またはアクリル
酸エステル共重合物等の合成樹脂エマルション）がゲル
状となる為使用できない。また、活性炭は黒色で水分を
吸収すると他の物質の吸着能力がなくなる為に、色と吸
着能力の問題から単独では使用できない。Porous inorganic compounds such as zeolite also have the property of adsorbing bad odors, but those with a PI (PI) of 5.0 or less, such as 2-aluminum tripolyphosphate, are used as paint film-forming substances (e.g., ethylene acetate). Synthetic resin emulsions (such as vinyl copolymers or acrylic ester copolymers) cannot be used because they become gel-like.Also, activated carbon is black and loses its adsorption ability for other substances when it absorbs water, so its color and adsorption It cannot be used alone due to capacity issues.
従って、本願に係る水性塗料に使用する消臭剤としては
フラバノノール類化合物、フラボノール類化合物、アビ
エチン酸、グリオキサール等の有機化合物の他、無機化
合物である還元鉄などが使用できる。フラバノノール類
としては、ピノバンクジノ、アロマプントリン、エンゲ
リチン、フスチン、クシキホリン、アスチルビン。Therefore, as a deodorizing agent used in the water-based paint according to the present application, in addition to organic compounds such as flavanonol compounds, flavonol compounds, abietic acid, and glyoxal, inorganic compounds such as reduced iron can be used. Flavanonols include pinobancino, aromapuntolin, engelitin, fuscin, xiquiphorin, and astilbin.
アンペロブチンなどがあり、フラボノール類としては、
ケンフェロール、トリホリン、アストラガリン、ロビニ
ン、クエルセチン、クエルシトリン、イックエルシトリ
ン、ルチン、ミリセチン、ミリシトジノなどがある。Flavonols include ampelbutin, etc.
These include kaempferol, triforin, astragaline, robinin, quercetin, quercitrin, quercitrin, rutin, myricetin, and myricitodino.
尚、本願の実施例ではフラボノール類化合物、アビエチ
ン酸化合物、グリオキサールを使用したが、その中でも
フラボノール類化合物が弱酸性を呈し塗料に対する適性
もあり、広い悪臭物質に対しても効果的であった。In the examples of the present application, flavonol compounds, abietic acid compounds, and glyoxal were used, and among them, flavonol compounds exhibit weak acidity, are suitable for paints, and are effective against a wide range of malodorous substances.
本願で消臭対象とする悪臭について述べると、人間の生
活環境の中で悪臭と感するものには、動植物の腐敗臭と
しての窒素化合物であるアノモニア類、アミン類、硫黄
化合物である硫化水素の他、ニコチン、油脂の酸臭なと
である。フラボノール系の植物性化合物は、自然界の自
浄作用を行うもので悪臭を選択的に吸着する事ができる
。Regarding the bad odors that are targeted for deodorization in this application, the things that humans perceive as bad odors in the living environment include anomonias, which are nitrogen compounds, amines, and hydrogen sulfide, which is a sulfur compound. Others include nicotine and the sour odor of fats and oils. Flavonol-based plant compounds have a natural self-purifying effect and can selectively absorb bad odors.
次に、本願に使用する気泡性に富んだ骨材。Next, the highly cellular aggregate used in this application.
充填材としては、バーミキュライト、パーライト、ゼオ
ライト、シリカゲル、アルミナ、アルミナシリケート、
シリカアルミネート、アロフェン、軽石、珪藻土、白土
、シラスバルーン、アスベスト、ベントナイト、発泡ガ
ラス砕粒、発泡ポリスチレン砕粒等があげられ、これら
の１種または２種以上を塗料中に混合する事に依り、塗
面に凹凸を設け、通気性を与え、悪臭と消臭剤の接触面
積を大きくするものである。Filling materials include vermiculite, pearlite, zeolite, silica gel, alumina, alumina silicate,
Examples include silica aluminate, allophane, pumice, diatomaceous earth, white clay, shirasu balloons, asbestos, bentonite, crushed foamed glass granules, crushed granulated foamed polystyrene, etc. By mixing one or more of these into the paint, coating The surface is textured to provide breathability and increase the contact area between the odor and the deodorizer.
本願の構成要素として三つめに、塗料のＰＨ調整がある
が、調整は通常の水性塗料を製造する要領で水、分散剤
、湿潤剤、着−色顔料、体質顔料、増粘剤、成膜助剤を
混合し分散させた後、結合材である合成樹脂エマルショ
ンまたは水溶性樹脂を混合した以降にＰ ｌ−１調整を
行う。この中に消臭剤、骨材、充填材が入っていないの
はＰＨ調整前に消臭剤を添加して、消臭剤の効果をなく
さない為と、本願に使用する骨材、充填材が長時間の混
合９分散により粒の破壊を避ける為である。そして、Ｐ
）Ｉ調整にはクエン酸。The third component of this application is the PH adjustment of the paint, which is adjusted in the same way as in the production of ordinary water-based paints: water, dispersant, wetting agent, coloring pigment, extender pigment, thickener, film forming agent, etc. After mixing and dispersing the auxiliary agent and mixing the synthetic resin emulsion or water-soluble resin as a binder, P l-1 adjustment is performed. The reason why deodorant, aggregate, and filler are not included is because the deodorant is added before pH adjustment so that the effect of the deodorant is not lost, and because the aggregate and filler used in this application are not included. This is to avoid the destruction of grains due to long-time mixing and dispersion of the material. And P
) Citric acid for I adjustment.
コハク酸、リンゴ酸等の有機酸、リン酸、希塩酸等の酸
水溶液或いは水酸化ナトリウム、水酸化カルシウム等の
アルカリが使用される。Organic acids such as succinic acid and malic acid, acid aqueous solutions such as phosphoric acid and dilute hydrochloric acid, or alkalis such as sodium hydroxide and calcium hydroxide are used.
実施例 １．２及び比較例 １．２
実施例としては消臭剤入り水性塗料に於て、骨材、充填
材としてバーミキュライト、珪藻土を使用したものと、
比較例１としてはそれらの骨材、充填材を使用せず塗面
として平滑に仕上がるものと、比較例２としては消臭剤
の添加がなく上記の骨材、充填材の使用もない塗料を製
造し、アンモニアガスの吸着能力を比較した。Example 1.2 and Comparative Example 1.2 As an example, vermiculite and diatomaceous earth were used as aggregate and filler in a water-based paint containing deodorizer,
Comparative Example 1 is a paint that does not use these aggregates and fillers and has a smooth painted surface, and Comparative Example 2 is a paint that does not contain any deodorizing agent and does not use the above aggregates and fillers. were manufactured and compared in their adsorption capacity for ammonia gas.
Ｐ Ｈは消臭剤を添加する前に０．１％塩酸の水溶液を
もって調整し７．５とした。また、消臭剤としてはフラ
ボノール類植物性化合物を使用した〔塗料の配合組成〕
数値は重量部を示す。The pH was adjusted to 7.5 using a 0.1% aqueous solution of hydrochloric acid before adding the deodorant. In addition, a flavonol plant compound was used as a deodorant. [Blend composition of paint] Values indicate parts by weight.
明細書の浄１！Ｊ（内容に変更なし）
第 １ 表
〔試験方法〕
塗料の配合組成に従って製造した実施例１゜２比較例１
，２の各塗料を約１ ｓｎ平方のアクリル仮にＲ当り０
．９〜１．０ ｋｇ塗布し、乾燥後一部に検知すべきガ
ス導入管を取り付けた発泡ポリウレタン板で作成した１
ばの立方体中に密封して外気との遮断をする。Clean statement 1! J (No change in content) Table 1 [Test method] Example 1゜2 Comparative example 1 manufactured according to the paint composition
, 2 each paint is about 1 sn square acrylic. If R is 0
．． 1 made from a foamed polyurethane plate with 9 to 1.0 kg applied and, after drying, a gas introduction pipe to be detected is attached to a part.
It is sealed in a cube and isolated from the outside air.
ガス導入管より検知すべきアンモニアを内部に置いたＰ
紙の上に一定量（２８％アンモニア水、１０ｍ１りを注
入し、Ｐ紙の表面において蒸発する様に作成して、内部
に拡散されるアンモニアガスを測定することとした。P with ammonia to be detected from the gas introduction pipe placed inside.
A fixed amount (10 ml of 28% ammonia water) was injected onto the paper so that it evaporated on the surface of the P paper, and the ammonia gas diffused inside was measured.
アンモニアガスの測定方法は導入管を通して内部のガス
１００ｔＲ１を吸引し、アンモニア検知管で測定した。Ammonia gas was measured by sucking 100 tR1 of internal gas through an inlet tube and measuring it with an ammonia detection tube.
検知管は５０〇−迄の測定は可能であるが、ゲージをオ
ーバーするものにつ（１）では注入ガス量より算出した
。The detection tube can measure up to 500 -, but in case of exceeding the gauge, (1) was calculated from the amount of injected gas.
試験結果を示す数値の単位は−である。The unit of the numerical value indicating the test result is -.
−以下余白−
明細書の浄書（内容に変更なし）
〔試験結果〕
第 ２ 表
第２表は第１表の実施例１．２、比較例１゜２のアンモ
ニアガス吸収値を残存アンモニアガスの測定により測定
し１こ。即ち、実施例１の塗料を用いて試験しｔことこ
ろ、アンモニア注入後、５時間経過時に於てはアンモニ
アガスの存在は１０ｐＰｎで消臭能力は９９．３％とい
う事になる。- Margins below - Reprint of specification (no changes to content) [Test results] Table 2 Table 2 shows the ammonia gas absorption values of Example 1.2 and Comparative Example 1.2 in Table 1, compared to the residual ammonia gas. Measured by measurement. That is, in a test using the paint of Example 1, the presence of ammonia gas was 10 pPn and the deodorizing ability was 99.3% after 5 hours had passed after ammonia injection.
実施例２に於ては９３．１％、比較例１は６１，３、％
、比較例２は１２％となり、表面の状態により、吸収能
力のない事が判明し１こ。93.1% in Example 2, 61.3% in Comparative Example 1
In Comparative Example 2, it was 12%, indicating that it had no absorption capacity due to the surface condition.
明細書の浄書（内容に変更なし）
比較例 ３〜５
実施例１に示した試料について、Ｐ Ｒを変化した場合
の消臭能力が変化するかどうかについて試験した。内容
としてはＰＨ調整を行わないものを比較例３とし、過剰
に酸を加えたものを比較例４、逆にアルカリを加えてＰ
ｉ−Ｉをより高くしたものを比１絞例５とした。Ｐ
Ｉ−Ｉ調整の方法としては、Ｐ Ｈを下げる場合につい
ては０．１％塩酸の水溶液、Ｉ’ Ｈを」二げる場合に
ついては１％の水酸化す） ｌ）ラム水溶液を用いて調
整した。Reprint of specification (no change in content) Comparative Examples 3 to 5 The samples shown in Example 1 were tested to see if their deodorizing ability changed when PR was changed. Regarding the contents, Comparative Example 3 is without pH adjustment, Comparative Example 4 is with excess acid added, and P is conversely with addition of alkali.
The sample with higher i-I was designated as Ratio 1 Reduction Example 5. P
The method for I-I adjustment is to use a 0.1% aqueous solution of hydrochloric acid to lower the pH, and 1% hydroxide to increase the I'H) l) Adjustment using a rum aqueous solution did.
Ｐ ｉ（調整後、各々に実施例１と同様に消臭剤、バー
ミキーライトを添加、混合した。混合後のＩＦ ＨはＰ
Ｈ調整後の値と殆んど変化がなかった。P i (After adjustment, deodorant and vermikey light were added and mixed in the same manner as in Example 1. IF H after mixing was P
There was almost no change from the value after H adjustment.
第 ３ 表
〔試験方法〕
消臭能ノＪの測定方法は、前述の実施例１，２、比１咬
例１，２を試験した方法に準じて行った。Table 3 [Test Method] The deodorizing ability J was measured in accordance with the method used to test Examples 1 and 2 and Ratio 1 Bite Examples 1 and 2 described above.
明細書の浄書く内容に変更なし）
比較例４は塗料が一部ゲル化現象を呈した為に、塗面が
良く仕上がらなかった。(There is no change in the contents of the specification.) In Comparative Example 4, the paint surface partially showed a gelation phenomenon, so the painted surface was not well finished.
第 ４ 表
第４表は実施例１，２の塗料を用いてアンモニアガスの
吸収能力を測定した時と同様にして、試験した測定値を
示すものであり、例えば比１絞例４では吸収能力として
７２％と高い値を示すのは、塗料が酸性の為にアンモニ
アを中和する作用がある為と考えられる。しかし、塗料
がゲル化する事は塗膜の形成を防げる為、塗料としては
使用できない。また、比較例５では吸収能力５２％、比
較例３では同６６％と両者とも吸収能力が低い値を示し
ている。Table 4 Table 4 shows the measured values tested in the same way as when measuring the absorption capacity of ammonia gas using the paints of Examples 1 and 2. For example, in Example 4 with a ratio of 1, the absorption capacity The high value of 72% is thought to be due to the acidic nature of the paint, which has the effect of neutralizing ammonia. However, gelling the paint prevents the formation of a paint film, so it cannot be used as a paint. Moreover, the absorption capacity of Comparative Example 5 was 52%, and that of Comparative Example 3 was 66%, both of which had low absorption capacities.
実施例１と比較例３〜５の比較により明らかにＰＨが消
臭能力に大きく影響することが判る。A comparison between Example 1 and Comparative Examples 3 to 5 clearly shows that pH greatly affects the deodorizing ability.
実施例３〜５．比較例６
実施例１〜２．比較例１．３〜５では、消臭剤としてフ
ラボノール類植物性化合物を使用し、消臭対象の悪臭と
してアンモニアガスを選んだが、しかし、悪臭物質とし
て他にもあるので、トリメチルアミノ、硫化水素につい
てその試験を行い、消臭剤としても他にグリオキサール
、アビエチン酸を使用し比較試験を行った。Examples 3-5. Comparative Example 6 Examples 1-2. In Comparative Examples 1.3 to 5, flavonol plant compounds were used as deodorants, and ammonia gas was selected as the malodor to be deodorized, but since there are other malodorous substances, trimethylamino, hydrogen sulfide, etc. A comparative test was also conducted using glyoxal and abietic acid as deodorants.
実施例１の配合組成中の消臭剤を変化させて製造した。 It was manufactured by changing the deodorant in the formulation of Example 1.
消臭剤と試料隘の対象表を第５表に示す。Table 5 shows the list of deodorants and sample volumes.
消臭能力の測定方法は実施例１，２、比較例１〜５を試
験した方法に準じて行った。但し、悪臭物質としてトリ
メチルアミン、硫化水素を一定量封入してかす定した。The deodorizing ability was measured in accordance with the method used in Examples 1 and 2 and Comparative Examples 1 to 5. However, a certain amount of trimethylamine and hydrogen sulfide were sealed as malodorous substances to eliminate the odor.
（１）ｌ−ＩＪメチルアミンの吸収試験筒 ６ 表 試験結果を示す数値の単位はｐｌＺｎである。 (1) L-IJ methylamine absorption test tube 6 table The unit of the numerical value indicating the test result is plZn.
明細書の浄書（内容に変更なし）
第６表はトリメチルアミンの吸収試験結果を示す表であ
るが、比較例２に於ても３１％の吸収能力があるのは骨
材として使用したバーミキュライトのもつ吸収性による
ものと考える。Revision of the specification (no changes to the contents) Table 6 shows the results of the absorption test for trimethylamine. Even in Comparative Example 2, the absorption capacity of 31% is due to the fact that the vermiculite used as the aggregate has an absorption capacity of 31%. I think this is due to absorbency.
（２）硫化水素の吸収試験
第 ７ 表
試験結果から、消臭剤によるトリメチルアミン、硫化水
素の吸収能力はほぼ同様の傾向を示し、王者の中ではフ
ラボノーｌＶ類化合物が良い吸収能力を示すことが判る
。(2) Hydrogen sulfide absorption test From the test results in Table 7, the absorption abilities of trimethylamine and hydrogen sulfide by deodorants show almost the same tendency, and among the champions, flavonol IV compounds show good absorption ability. I understand.
特許出願人 菊水化学工業株式会社
代表者 遠 山 昌 夫
手続補正書（方式）
％式％
２、発明の名称
消臭効果をもった水性塗料の製造法
３、補正をする者
事件との関係 特許出願人
居所 愛知県名古屋市中村区名駅四丁目４番１２号昭和
５９年７月１１日（発送日 同年７月３１日）第１表の
ある第８頁、第２表のある第４０頁、第３表のある第１
１頁、第４表のある第１２頁、第５表、第６表のある第
１４頁、第７表のある第１５頁（内容に変更なし）。Patent Applicant Kikusui Chemical Co., Ltd. Representative Masao Toyama Procedural Amendment (Method) % Formula % 2. Name of the invention Method for manufacturing water-based paint with deodorizing effect 3. Relationship with the person making the amendment Patent Applicant's residence: 4-4-12 Meieki, Nakamura-ku, Nagoya, Aichi Prefecture, July 11, 1980 (Shipping date: July 31, 1981) Page 8 with Table 1, page 40 with Table 2 , the first with Table 3
Page 1, page 12 with Table 4, page 14 with Tables 5 and 6, page 15 with Table 7 (no change in content).
Claims (1)
去する消臭物質を添加し、骨材、充填材として気泡性に
富んだバーミキュライト、パーライト、発泡ポリスチレ
ン、珪藻土などを使用した上で、Ｐ ｌ（を６．θ〜８
．０に調整することを特徴とする、消臭効果をもつ水性
塗料の製造法。A deodorizing substance that removes bad odors by combining, neutralizing, and inclusion is added to the water-based paint, and highly cellular vermiculite, perlite, expanded polystyrene, diatomaceous earth, etc. are used as aggregates and fillers. Then, P l( is 6.θ~8
．． A method for producing a water-based paint having a deodorizing effect, which is characterized by adjusting the odor to zero.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6815184A JPS60210675A (en) | 1984-04-05 | 1984-04-05 | Production of water paint having a deodorizing effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6815184A JPS60210675A (en) | 1984-04-05 | 1984-04-05 | Production of water paint having a deodorizing effect |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60210675A true JPS60210675A (en) | 1985-10-23 |
| JPS6314022B2 JPS6314022B2 (en) | 1988-03-29 |
Family
ID=13365450
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6815184A Granted JPS60210675A (en) | 1984-04-05 | 1984-04-05 | Production of water paint having a deodorizing effect |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60210675A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62195029A (en) * | 1986-02-22 | 1987-08-27 | Shiraishi Chuo Kenkyusho:Kk | Aqueous antiblocking coating material composition |
| JPS62209179A (en) * | 1986-03-11 | 1987-09-14 | Toraya Uule Kk | Deodorizing adhesive |
| JPS63108083A (en) * | 1986-05-31 | 1988-05-12 | Toyota Central Res & Dev Lab Inc | Coating material composition |
| JPS63254034A (en) * | 1987-03-11 | 1988-10-20 | インペリアル・ケミカル・インダストリーズ・ピーエルシー | Refractory composite material and manufacture thereof |
| JPH01225676A (en) * | 1988-03-04 | 1989-09-08 | Misawa Homes Co Ltd | Coating composition and coating method |
| JPH0343465A (en) * | 1989-07-11 | 1991-02-25 | Nippon Tokushu Toryo Co Ltd | Coating compound for interior of building structure |
| KR20010108854A (en) * | 2000-05-31 | 2001-12-08 | 임기태 | Functional mixture mixture for interior and exterior paint of building |
| JP2002138252A (en) * | 2000-11-02 | 2002-05-14 | Takatoshi Fujino | Diatomaceous earth-containing coating material composition |
| KR100484405B1 (en) * | 2002-09-02 | 2005-04-22 | 조남일 | A composite of paint having multi-function |
| JP2006241413A (en) * | 2005-03-07 | 2006-09-14 | Zixsys:Kk | Binder for diatomaceous earth, method for producing the same, coating material containing diatomaceous earth and method for producing the same |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002021214A (en) * | 2000-07-10 | 2002-01-23 | Fujita Corp | Building material capable of deodorization paint and building using these material and paint and deodorizing method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55141244A (en) * | 1979-04-20 | 1980-11-05 | Chisso Corp | Deodorant |
| JPS5633103A (en) * | 1979-08-23 | 1981-04-03 | Nippon Steel Corp | Feeding method for cast slab to hot rolling pass |
| JPS56100060A (en) * | 1980-01-14 | 1981-08-11 | Shiraimatsu Shinyaku Co | Deodorant composition |
| JPS57192557A (en) * | 1981-05-22 | 1982-11-26 | Hitachi Ltd | Deodrant treatment agent |
-
1984
- 1984-04-05 JP JP6815184A patent/JPS60210675A/en active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55141244A (en) * | 1979-04-20 | 1980-11-05 | Chisso Corp | Deodorant |
| JPS5633103A (en) * | 1979-08-23 | 1981-04-03 | Nippon Steel Corp | Feeding method for cast slab to hot rolling pass |
| JPS56100060A (en) * | 1980-01-14 | 1981-08-11 | Shiraimatsu Shinyaku Co | Deodorant composition |
| JPS57192557A (en) * | 1981-05-22 | 1982-11-26 | Hitachi Ltd | Deodrant treatment agent |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62195029A (en) * | 1986-02-22 | 1987-08-27 | Shiraishi Chuo Kenkyusho:Kk | Aqueous antiblocking coating material composition |
| JPS62209179A (en) * | 1986-03-11 | 1987-09-14 | Toraya Uule Kk | Deodorizing adhesive |
| JPS63108083A (en) * | 1986-05-31 | 1988-05-12 | Toyota Central Res & Dev Lab Inc | Coating material composition |
| JPS63254034A (en) * | 1987-03-11 | 1988-10-20 | インペリアル・ケミカル・インダストリーズ・ピーエルシー | Refractory composite material and manufacture thereof |
| JPH01225676A (en) * | 1988-03-04 | 1989-09-08 | Misawa Homes Co Ltd | Coating composition and coating method |
| JPH0343465A (en) * | 1989-07-11 | 1991-02-25 | Nippon Tokushu Toryo Co Ltd | Coating compound for interior of building structure |
| KR20010108854A (en) * | 2000-05-31 | 2001-12-08 | 임기태 | Functional mixture mixture for interior and exterior paint of building |
| JP2002138252A (en) * | 2000-11-02 | 2002-05-14 | Takatoshi Fujino | Diatomaceous earth-containing coating material composition |
| KR100484405B1 (en) * | 2002-09-02 | 2005-04-22 | 조남일 | A composite of paint having multi-function |
| JP2006241413A (en) * | 2005-03-07 | 2006-09-14 | Zixsys:Kk | Binder for diatomaceous earth, method for producing the same, coating material containing diatomaceous earth and method for producing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6314022B2 (en) | 1988-03-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |