JPH07291835A - Makeup cosmetic - Google Patents
Makeup cosmeticInfo
- Publication number
- JPH07291835A JPH07291835A JP10766094A JP10766094A JPH07291835A JP H07291835 A JPH07291835 A JP H07291835A JP 10766094 A JP10766094 A JP 10766094A JP 10766094 A JP10766094 A JP 10766094A JP H07291835 A JPH07291835 A JP H07291835A
- Authority
- JP
- Japan
- Prior art keywords
- iron
- color
- titanium dioxide
- pigment
- extender pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
Description
【０００１】[0001]
【産業上の利用分野】この発明は、鉄処理体質顔料と鉄
含有二酸化チタンを併用して配合することにより、白く
浮き上がったような塗布色が改善され、外観色と塗布色
の差が小さく自然な肌色を再現でき、さらにはフラッシ
ュ撮影により顔が白く浮かび上がることを防ぐメイクア
ップ化粧料に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention This invention improves the coating color which appears white and improves the appearance color by reducing the difference between the appearance color and the coating color by blending the iron-treated extender pigment and iron-containing titanium dioxide in combination. The present invention relates to makeup cosmetics that can reproduce different skin tones and prevent the face from appearing white due to flash photography.
【０００２】[0002]
【従来の技術】従来のメイクアップ化粧料、例えばパウ
ダーファンデーションは、主にタルク、セリサイト、マ
イカなどの体質顔料、二酸化チタン、酸化亜鉛などの白
色顔料、ベンガラ、黄酸化鉄、黒酸化鉄、有機色素など
の着色顔料、その他金属石ケン、油性成分などから構成
された混合物である。そのため外観に現れる色調は、そ
れぞれの反射光が等分化されて現れるものであり、それ
ぞれの粉体が持つ特徴は失われていない。よって、フラ
ッシュ光や蛍光灯のような短波長の青みの強い光源下で
は、処方中に占める割合の大きい体質顔料や白色顔料の
散乱光が増幅され、白く浮いたような色調が際だってし
まう白浮きという現象が生ずる。2. Description of the Related Art Conventional makeup cosmetics such as powder foundations are mainly composed of extrinsic pigments such as talc, sericite and mica, white pigments such as titanium dioxide and zinc oxide, red iron oxide, yellow iron oxide and black iron oxide. It is a mixture composed of a coloring pigment such as an organic dye, other metallic soap, an oily component and the like. Therefore, the color tone that appears in the appearance is that the reflected light is equally divided and appears, and the characteristics of each powder are not lost. Therefore, under a short-wavelength blue light source such as a flashlight or a fluorescent lamp, the scattered light of an extender pigment or a white pigment, which accounts for a large proportion of the prescription, is amplified, and the white tone that floats in white is conspicuous. The phenomenon of floating occurs.
【０００３】特に白色顔料として汎用されている二酸化
チタンは、白浮きの最も大きな原因であると考えられて
いる。またパウダーファンデーションのような油性成分
の含量が１０％前後で、濡れの低い粉体を多く含有する
メイクアップ化粧料では、白浮きが顕著にみられること
が知られている。In particular, titanium dioxide, which is widely used as a white pigment, is considered to be the largest cause of whitening. Further, it is known that whitening is remarkably observed in makeup cosmetics containing an oily component such as a powder foundation around 10% and containing a large amount of powder having low wetness.
【０００４】そこで、白浮き現象を抑えるためにフォト
クロミック性を有する酸化チタンを配合する試みがなさ
れている。しかしながら白色顔料がメイクアップ化粧料
中に占める割合は通常２０重量％以下であり、白色顔料
にフォトクロミック性顔料を使用するだけでは、白浮き
を完全に抑えることは困難であった。Therefore, attempts have been made to blend titanium oxide having photochromic properties in order to suppress the whitening phenomenon. However, the proportion of the white pigment in the makeup cosmetics is usually 20% by weight or less, and it has been difficult to completely suppress whitening only by using a photochromic pigment as the white pigment.
【０００５】また、消費者が通常メイクアップ化粧料を
購入する際は、実際に使用しないで外観色だけを見て購
入することが多い。しかし、通常メイクアップ化粧料中
に使用される体質顔料のタルク、セリサイト類は、板状
結晶のため平行方向に配向し、反射光が散乱光となり白
くなるが、未使用の外観は、顔料の配向がなく、塗布時
よりも暗く、濃い色に見えてしまう。そのため、購入時
に見た色と実際使用したときの色調が異なる結果とな
る。When consumers usually purchase makeup cosmetics, they often do not actually use them but only look at the appearance color. However, the extrinsic pigments talc and sericite, which are usually used in makeup cosmetics, are oriented parallel to each other because of plate crystals, and the reflected light becomes scattered light and becomes white, but the unused appearance is pigment. There is no orientation, and it looks darker and darker than when applied. Therefore, the color seen at the time of purchase and the color tone when actually used are different.
【０００６】[0006]
【発明が解決しようとする課題】この発明の目的は、白
く浮き上がったような塗布色が改善され、外観色と塗布
色の差が小さく自然な肌色を再現でき、さらにはフラッ
シュ撮影により顔が白く浮かび上がることのないメイク
アップ化粧料を提供することにある。SUMMARY OF THE INVENTION The object of the present invention is to improve the coating color that appears to be white, to reproduce a natural skin color with a small difference between the appearance color and the coating color, and to make the face white by flash photography. It is to provide makeup cosmetics that do not emerge.
【０００７】体質顔料として一般に用られているタル
ク、セリサイト、マイカなどは偏平な結晶形態をとって
おりその表面は反射率が高く、光源の反射光によって光
を散乱し白浮きや外観色と塗布色の差が大きくなる原因
となりうる。しかも体質顔料は、一般的なメイクアップ
化粧料の中でも固型粉体化粧料に多用されており、多い
ものでは９０％以上を占める。Talc, sericite, mica and the like, which are generally used as extender pigments, have a flat crystal form, and the surface thereof has a high reflectance, and the light reflected by the light source scatters light to cause whitening and appearance color. This may cause a large difference in coating color. In addition, extender pigments are often used in solid powder cosmetics among general makeup cosmetics, and most of them account for 90% or more.
【０００８】[0008]
【課題を解決するための手段】この発明におけるメイク
アップ化粧料は、鉄含有二酸化チタン及び鉄処理体質顔
料を必須成分として含有することを特徴とするものであ
る。つまり屈折率が大きく、白色度に影響する白色顔料
である二酸化チタンと、メイクアップ化粧料中で二酸化
チタンよりも配合割合の大きい体質顔料を鉄処理するこ
とにより散乱光の発生を抑えることができるため、外観
色と塗布色の差が小さく自然な肌色を再現でき、白浮き
がなくなる。The makeup cosmetics of the present invention are characterized by containing iron-containing titanium dioxide and an iron-treated extender pigment as essential components. In other words, the generation of scattered light can be suppressed by ironing titanium dioxide, which is a white pigment that has a large refractive index and affects the whiteness, and an extender pigment that has a larger blending ratio than titanium dioxide in makeup cosmetics. Therefore, the difference between the appearance color and the applied color is small, and a natural skin color can be reproduced, and whitening does not occur.
【０００９】従来のフォトクロミック性を有する二酸化
チタンを使用する場合と比べて、鉄処理体質顔料及び鉄
含有二酸化チタンを併用することにより、散乱光の発生
が飛躍的に少なくなり、外観色と塗布色の差が小さく自
然な肌色を再現でき、白浮き現象が抑制された。Compared with the case of using titanium dioxide having a conventional photochromic property, the combined use of the iron-treated extender pigment and the iron-containing titanium dioxide dramatically reduces the generation of scattered light, resulting in an appearance color and a coating color. Difference was small and natural skin color could be reproduced, and whitening phenomenon was suppressed.
【００１０】この発明で用いる鉄処理体質顔料で使用す
る体質顔料は、化粧料で使用される体質顔料であれば特
に限定されず、タルク、カオリン、マイカ、セリサイ
ト、軽質炭酸マグネシウム、軽質炭酸カルシウム等の無
機顔料、ナイロン末、ポリメチルメタアクリレート、ポ
リエチレン末、絹粉末、アミノ酸系粉末、オルガノシロ
キサン系粉末等の有機顔料、ステアリン酸マグネシウ
ム、ステアリン酸アルミニウム等の金属石ケンなど種
類、粒子形状、粒径を問わない。The extender pigment used in the iron-treated extender pigment used in the present invention is not particularly limited as long as it is an extender pigment used in cosmetics, and talc, kaolin, mica, sericite, light magnesium carbonate, light calcium carbonate. Inorganic pigments such as, nylon powder, polymethylmethacrylate, polyethylene powder, silk powder, amino acid powder, organic pigments such as organosiloxane powder, magnesium stearate, metal soap such as aluminum stearate, type, particle shape, etc. Regardless of particle size.
【００１１】体質顔料の鉄処理方法は、乾式方法、湿式
方法など処理方法は問わない。The iron treatment method for the extender pigment may be a dry method, a wet method or the like.
【００１２】鉄処理体質顔料は、オルガノゾルを用いて
調製することもできる。塩化第二鉄を低級アルコールな
どの溶媒を用いてオルガノゾルとした後、体質顔料を浸
漬させる。これを乾燥し、３００〜１０００℃好ましく
は、３００〜８００℃で焼成後、粉砕することにより鉄
処理体質顔料が得られる。確実には、オルガノゾルに体
質顔料を浸漬し、これにナトリウムエチラートのような
金属アルコキシドを加え還流し反応させる。この操作に
より塩化第二鉄からトリエトキシ鉄と塩化ナトリウムが
得られる。これはナトリウム法と呼ばれる方法である。
次に水を加えて、加水分解し、表面のトリエトキシ鉄は
酸化鉄へと変化する。これを水洗、乾燥後３００〜１０
００℃好ましくは３５０〜８５０℃で焼成し、粉砕する
ことにより鉄処理体質顔料が得られる。The iron-treated extender pigment can also be prepared using an organosol. Ferric chloride is made into an organosol using a solvent such as a lower alcohol, and then an extender pigment is dipped. The iron-treated extender pigment is obtained by drying, firing at 300 to 1000 ° C., preferably 300 to 800 ° C., and then pulverizing. To be sure, the extender pigment is dipped in the organosol, and a metal alkoxide such as sodium ethylate is added thereto and refluxed for reaction. By this operation, triethoxy iron and sodium chloride can be obtained from ferric chloride. This is a method called the sodium method.
Next, water is added and hydrolyzed, and the triethoxy iron on the surface changes to iron oxide. This is washed with water and dried, then 300 to 10
An iron-treated extender pigment is obtained by firing at 00 ° C., preferably 350 to 850 ° C., and pulverizing.
【００１３】鉄処理体質顔料は、塩化第二鉄の酸性水溶
液に体質顔料を浸漬させ、中和した後乾燥し、３００〜
１０００℃好ましくは３５０〜８５０℃で焼成後、粉砕
することによっても調製できる。The iron-treated extender pigment is prepared by immersing the extender pigment in an acidic aqueous solution of ferric chloride, neutralizing it, and then drying it.
It can also be prepared by firing at 1000 ° C., preferably 350 to 850 ° C., and then pulverizing.
【００１４】鉄処理体質顔料は、メカノケミカル的手法
を用いて、例えば、ホソカワミクロン社製オングミルで
体質顔料と酸化鉄又は水酸化鉄を処理することによって
得られる。The iron-treated extender pigment can be obtained, for example, by treating the extender pigment and iron oxide or iron hydroxide with an Ong Mill manufactured by Hosokawa Micron Co. using a mechanochemical technique.
【００１５】この発明において使用される二酸化チタン
は、ルチル型、アナターゼ型いずれの結晶タイプでもよ
く、また粒子径も特に限定されず、微粒子でも通常の酸
化チタンでもよい。また二酸化チタンの調製方法は種類
を問わず、硫酸法、塩素法どちらの方法を用いて調製し
てもよい。The titanium dioxide used in the present invention may be either rutile type or anatase type crystal type, and the particle size is not particularly limited, and may be fine particles or ordinary titanium oxide. The titanium dioxide may be prepared by any of the sulfuric acid method and the chlorine method regardless of the type.
【００１６】また、二酸化チタンの鉄処理方法は種類を
問わず、乾式、湿式いずれの方法でもよい。また、鉄処
理は、二酸化チタン粉体に直接行っても、二酸化チタン
合成過程において行ってもよい。The method for treating titanium dioxide with iron may be either dry or wet regardless of the type. Further, the iron treatment may be performed directly on the titanium dioxide powder or in the titanium dioxide synthesis process.
【００１７】鉄含有二酸化チタンは、メカノケミカル的
手法を用いて、例えば、ホソカワミクロン社製オングミ
ルで二酸化チタンと酸化鉄又は水酸化鉄を処理すること
によって得られる。The iron-containing titanium dioxide can be obtained by using a mechanochemical method, for example, by treating titanium dioxide and iron oxide or iron hydroxide with an Ong Mill manufactured by Hosokawa Micron.
【００１８】鉄含有二酸化チタンは四塩化チタンを加水
分解する際塩化第二鉄を添加し、チタニア表面に含水酸
化鉄又は酸化鉄を沈殿させた後、３００〜８５０℃で焼
成、粉砕して得ることができる。Iron-containing titanium dioxide is obtained by adding ferric chloride when hydrolyzing titanium tetrachloride to precipitate iron oxide hydroxide or iron oxide on the surface of titania, and then calcining at 300 to 850 ° C. and crushing. be able to.
【００１９】鉄含有二酸化チタンは、特開平５−３３０
８２５に記載されるように、ルチル核を有するチタニア
ゾルの存在下に鉄の水溶性塩好ましくは塩化第二鉄を中
和して、該チタニア表面に含水酸化鉄又は酸化鉄をＦｅ
換算で二酸化チタンに対して１〜１５重量％に成るよう
沈殿させ、分別し、３００〜８５０℃で焼成、粉砕後、
必要に応じて表面改質処理を行い製造する。Iron-containing titanium dioxide is disclosed in JP-A-5-330.
825, a water-soluble salt of iron, preferably ferric chloride, is neutralized in the presence of a titania sol having a rutile nucleus, and iron oxide hydroxide or iron oxide is added to the surface of the titania.
Precipitated to be 1 to 15% by weight with respect to titanium dioxide, fractionated, calcined at 300 to 850 ° C., pulverized,
If necessary, surface modification treatment is carried out to manufacture.
【００２０】この発明においては鉄処理体質顔料及び／
又は鉄含有二酸化チタン顔料を更にシリコーン処理、界
面活性剤処理、表面アルコキシル化、金属石ケン処理、
脂肪酸処理、フッ素樹脂処理、ワックス処理などの表面
処理、或いはこれらの二種類以上を用いた複合処理を行
ったものを用いてもよい。In the present invention, an iron-treated extender pigment and /
Alternatively, iron-containing titanium dioxide pigment is further treated with silicone, surfactant, surface alkoxylation, metal soap treatment,
A surface treatment such as a fatty acid treatment, a fluororesin treatment, or a wax treatment, or a composite treatment using two or more of these may be used.
【００２１】なおこの発明におけるメイクアップ化粧料
とは、白色顔料及び体質顔料を含有するメイクアップ化
粧料であれば特に限定されず、ファンデーション、頬
紅、アイシャドウ、アイライナー、マスカラ、口紅、ア
イブロウ等特に種類を問わない。更にメイクアップ化粧
料の形態も限定されず、粉末状、ケーキ状、ペンシル
状、スティック状、軟膏状、液状、乳液状、クリーム
状，ゲル状などとすることができる。The makeup cosmetic in the present invention is not particularly limited as long as it is a makeup cosmetic containing a white pigment and an extender pigment, such as foundation, blusher, eye shadow, eyeliner, mascara, lipstick, and eyebrow. It does not matter what kind. Further, the form of the makeup cosmetic is not limited, and may be powder, cake, pencil, stick, ointment, liquid, emulsion, cream, gel or the like.
【００２２】本発明におけるメイクアップ化粧料には、
鉄処理体質顔料及び鉄含有二酸化チタンに加えて、通常
化粧料組成物に用いられる他の成分を必要に応じて適宜
配合することができる。The makeup cosmetics of the present invention include:
In addition to the iron-treated extender pigment and the iron-containing titanium dioxide, other components usually used in cosmetic compositions can be appropriately blended as necessary.
【００２３】[0023]
【作用】メイクアップ化粧料において、従来のフォトク
ロミック性を有する二酸化チタンを使用する場合と比べ
て、鉄処理体質顔料及び鉄含有二酸化チタンを併用する
ことにより、散乱光の発生が飛躍的に少なくなり、外観
色と塗布色の差が小さく自然な肌色を再現でき、白浮き
現象を抑制することができる。[Function] Compared to the case of using conventional titanium dioxide having photochromic properties in makeup cosmetics, the combined use of iron-treated extender pigment and iron-containing titanium dioxide dramatically reduces the generation of scattered light. In addition, it is possible to reproduce a natural skin color with a small difference between the appearance color and the coating color, and suppress the phenomenon of whitening.
【００２４】[0024]
【実施例】以下、実施例に基づきこの発明を更に詳細に
説明する。なお、この発明はこれにより限定されるもの
ではない。また、以下の説明において、配合量は、重量
％で示してある。The present invention will be described in more detail based on the following examples. The present invention is not limited to this. Further, in the following description, the blending amount is shown by weight%.
【００２５】実施例１：パウダーファンデーションExample 1: Powder foundation
【表１】 表１に示した処方でプレス成型形態のパウダーファンデ
ーションを調製した。Ａ相をヘンシェルミキサーに投入
し、混合均一化する。これにＢ相を加え更に混練均一化
しＣ相を加える。アトマイザーにて整粒処理後プレス成
型を行いパウダーファンデーションを調製した。体質顔
料及び白色顔料を全て鉄処理体質顔料及び鉄含有二酸化
チタンとして配合したものを実施例１とした。比較例１
は、鉄処理体質顔料及び鉄含有二酸化チタンを通常の体
質顔料及び二酸化チタンに代替したものである。比較例
２は、実施例１において鉄含有二酸化チタンを通常の二
酸化チタンに代替したものである。比較例３は、実施例
１において鉄処理体質顔料を通常の体質顔料に代替した
ものである。比較例１，２，３と実施例１は、予めプレ
ス時の外観色がほぼ一致するよう調製した。[Table 1] A powder foundation in the form of press molding was prepared according to the formulation shown in Table 1. Pour phase A into a Henschel mixer and mix to homogenize. Phase B is added to this, and the mixture is further kneaded and homogenized, and phase C is added. After sizing with an atomizer, press molding was performed to prepare a powder foundation. Example 1 was a mixture of all extender pigments and white pigments as iron-treated extender pigments and iron-containing titanium dioxide. Comparative Example 1
Is an iron-treated extender pigment and iron-containing titanium dioxide that are replaced with a normal extender pigment and titanium dioxide. Comparative Example 2 is the one in which the iron-containing titanium dioxide in Example 1 was replaced with ordinary titanium dioxide. In Comparative Example 3, the iron-treated extender pigment in Example 1 was replaced with a normal extender pigment. Comparative Examples 1, 2 and 3 and Example 1 were prepared in advance so that the appearance colors at the time of pressing were almost the same.
【００２６】外観色の比較 パフでほぐされた面の状態は、肌に塗布された面の状態
に近く、未使用、使用後の外観色の差が小さいほど外観
色と塗布色の差が小さく、自然な肌色が再現できるメイ
クアップ化粧料といえる。また、Ｌ値は、明度を示し、
未使用、使用後の明度差が小さいほど白く浮き上がった
ような塗布色が改善されているといえる。実施例１及び
比較例１，２，３の、未使用のプレス面と、パフでほぐ
した使用後の面の外観色を比較して表２に示した。Comparison of appearance color The state of the puffed surface is similar to the state of the surface applied to the skin, and the difference in appearance color between unused and used is smaller, the difference between appearance color and application color is smaller. , Make-up cosmetics that can reproduce natural skin tones. Also, the L value indicates the lightness,
It can be said that the smaller the difference in lightness between unused and used, the better the coating color that appears white. Table 2 shows a comparison of the appearance colors of the unused press surface and the surface after use after puffing in Example 1 and Comparative Examples 1, 2, and 3.
【表２】 [Table 2]
【００２７】未使用のプレス面と、パフでほぐした使用
後の面との色差は、比較例の方が大きく特に明度が高め
にあらわれた。実施例１では、明度差が０．８４であっ
たのに対し、鉄処理体質顔料及び鉄含有二酸化チタンを
全く配合していない比較例１では、２．１５と明度の差
が大きくなっている。鉄処理顔料又は鉄含有二酸化チタ
ンのいずれか一方を含有する比較例２，３では、明度差
が１．８０，１．７１と比較例１よりは小さな値で、白
浮きが改善されてはいるが、実施例１ほどの飛躍的な改
善には至っていない。よって、鉄処理体質顔料、鉄含有
二酸化チタンを併用することにより白浮きが著しく改善
されているといえよう。The color difference between the unused press surface and the surface after use after puffing was large in the comparative example, and the brightness was particularly high. In Example 1, the difference in lightness was 0.84, whereas in Comparative Example 1 in which the iron-treated extender pigment and iron-containing titanium dioxide were not mixed at all, the difference in lightness was 2.15, which was a large difference. . In Comparative Examples 2 and 3 containing either the iron-treated pigment or the iron-containing titanium dioxide, the difference in lightness was 1.80 and 1.71, which was smaller than that in Comparative Example 1, and whitening was improved. However, it has not reached the dramatic improvement of Example 1. Therefore, it can be said that the whitening is remarkably improved by using the iron-treated extender pigment and the iron-containing titanium dioxide in combination.
【００２８】赤みの度合いをを示すａ値の未使用、使用
後の差をみると、実施例では−０．２７で誤差の範囲で
あるのに対し、比較例１，２，３は、−１．０６，−
０．７３，−０．９２と、ａ値が減少し赤みが減少し
た。鉄処理体質顔料又は鉄含有二酸化チタンのいずれか
一方を配合した比較例２，３は、鉄処理体質顔料及び鉄
含有二酸化チタンを全く配合しない比較例１より若干赤
みの減少が抑えられているが、大幅な改善には至ってい
ない。鉄処理体質顔料、鉄含有二酸化チタンを併用する
ことにより、外観色と塗布色の赤みの差が小さくなり、
自然な肌色が再現できる。Looking at the difference in the value a indicating the degree of redness before and after use, the error range is -0.27 in the examples, whereas the difference is -0.27 in the examples. 1.06,-
From 0.73 to -0.92, the a value decreased and the redness decreased. In Comparative Examples 2 and 3 in which either the iron-treated extender pigment or the iron-containing titanium dioxide was added, the reduction in redness was slightly suppressed as compared with Comparative Example 1 in which the iron-treated extender pigment and the iron-containing titanium dioxide were not added at all. , Has not reached a significant improvement. The combined use of iron-treated extender pigment and iron-containing titanium dioxide reduces the difference in redness between the appearance color and the coating color,
Can reproduce natural skin tones.
【００２９】総合的な色調の差を示す色差を見てみる
と、実施例と比較例の相違が顕著である。実施例１で
は、色差が０．８８であるのに対し、比較例では、１．
９６から２．４５と色差が２倍以上大きな値となってい
る。鉄処理体質顔料又は鉄含有二酸化チタンのいずれか
一方を配合した比較例２，３は、色差が１．９７，１．
９６で、鉄処理体質顔料及び鉄含有二酸化チタンを全く
配合しない比較例１の色差２．４５より改善が認められ
るが、顕著な改善ではない。この傾向は、各試料につい
て色差を図示した図１においてより明確に認められる。
以上のように、鉄処理体質顔料と鉄含有二酸化チタンを
併用することにより、白く浮き上がったような塗布色が
大幅に改善され、外観色と塗布色の差が小さく、自然な
肌色を良好に再現できることが明らかに認められた。Looking at the color difference showing the overall difference in color tone, the difference between the example and the comparative example is remarkable. In Example 1, the color difference is 0.88, whereas in Comparative Example, 1.
From 96 to 2.45, the color difference is more than twice as large. In Comparative Examples 2 and 3 in which either the iron-treated extender pigment or the iron-containing titanium dioxide was blended, the color difference was 1.97, 1.
96, an improvement was recognized from the color difference of 2.45 of Comparative Example 1 in which the iron-treated extender pigment and the iron-containing titanium dioxide were not blended at all, but it was not a significant improvement. This tendency is more clearly seen in FIG. 1, which illustrates the color difference for each sample.
As described above, by using the iron-treated extender pigment and iron-containing titanium dioxide in combination, the coating color that appears white is greatly improved, the difference between the appearance color and the coating color is small, and the natural skin color is reproduced well. It was clearly recognized that it was possible.
【００３０】光沢の比較 粘着テープの粘着面に実施例１及び比較例１，２，３を
塗布し、その面の光沢をグロスメーターを用いて測定し
た。測定時の入射角、反射角はともに７５度である。結
果を表３に示した。Comparison of Gloss Example 1 and Comparative Examples 1, 2 and 3 were applied to the adhesive surface of the adhesive tape, and the gloss of the surface was measured using a gloss meter. The incident angle and the reflection angle at the time of measurement are both 75 degrees. The results are shown in Table 3.
【表３】 実施例の方が、光沢が低くなっており、反射光が少ない
ことが明らかである。反射光が少ないと、不自然な光沢
がなくなり、自然な肌色が再現できる。更にフラッシュ
光での反射が少なくなり、写真に写った際に白く浮き上
がったような顔色になるのを抑制できる。[Table 3] It is clear that the example has lower gloss and less reflected light. When the amount of reflected light is low, the unnatural gloss disappears and natural skin tones can be reproduced. Furthermore, the reflection of the flash light is reduced, and it is possible to suppress the appearance of a white complexion in the photograph.
【００３１】実施例２：油性ファンデーションExample 2: Oily foundation
【表４】 表４に示す処方により油性ファンデーションを調製し
た。Ａ相を７５〜８０℃にて溶解均一化した後、予め混
合均一化したＢ相を加え攪拌しながら室温まで冷却す
る。Ｃ相を添加後３本ローラーにて均一化し、容器に充
填する。鉄含有二酸化チタンを二酸化チタンに、鉄処理
タルク，鉄処理マイカをそれぞれタルク，マイカに代替
し、未使用面の外観色が実施例２と同様になるよう調色
した比較例４を同時に調製した。[Table 4] Oily foundations were prepared according to the formulations shown in Table 4. After the phase A is dissolved and homogenized at 75 to 80 ° C., the phase B mixed and homogenized in advance is added and cooled to room temperature with stirring. After phase C is added, it is homogenized with three rollers and filled in a container. Comparative Example 4 was prepared in which iron-containing titanium dioxide was replaced with titanium dioxide, and iron-treated talc and iron-treated mica were replaced with talc and mica, respectively, and the unused surface was toned to have the same appearance color as that of Example 2. .
【００３２】実施例３：乳化型ファンデーションExample 3: Emulsion type foundation
【表５】 表５に示す処方により乳化型ファンデーションを調製し
た。Ａ相を８０〜８５℃にて均一混合化し、予め混合均
一化したＢ相を加えホモミキサーにて均一に分散させ
る。これに８０〜８５℃で溶解均一化したＣ相を添加
し、ホモミキサーにて乳化する。室温付近まで冷却し、
Ｄ相を加え均一化して調製した。鉄含有二酸化チタンを
二酸化チタンに、鉄処理タルクをタルクに代替し、外観
色が実施例３と同様になるよう調色した比較例５を同時
に調製した。[Table 5] An emulsion type foundation was prepared according to the formulation shown in Table 5. The phase A is uniformly mixed at 80 to 85 ° C., and the phase B, which has been mixed and homogenized in advance, is added and uniformly dispersed by a homomixer. Phase C dissolved and homogenized at 80 to 85 ° C. is added thereto, and the mixture is emulsified with a homomixer. Cool to around room temperature,
Phase D was added and homogenized. Comparative Example 5 was prepared at the same time, in which the iron-containing titanium dioxide was replaced with titanium dioxide and the iron-treated talc was replaced with talc, and the appearance color was adjusted to be the same as in Example 3.
【００３３】塗布色の官能評価 上記で得られた実施例１〜３，比較例１〜５のファンデ
ーションを実際に塗布して外観色と塗布色の差に関する
官能評価を行った。女性２０名に各ファンデーションを
塗布してもらい、外観色と塗布色の差が気にならない、
少し気になる、気になる、かなり気になるの４段階で評
価し、各評価を行ったパネラーの人数を集計した。結果
を表６に示す。Sensory Evaluation of Coating Colors The foundations of Examples 1 to 3 and Comparative Examples 1 to 5 obtained above were actually coated to perform sensory evaluations regarding the difference between the appearance color and the coating color. I asked 20 women to apply each foundation, so I do not mind the difference between the appearance color and the application color,
The evaluation was made in four grades of slightly worrisome, worrisome, and worrisome, and the number of panelists who performed each evaluation was totaled. The results are shown in Table 6.
【表６】 この結果から、実際例のファンデーションは、比較例の
ものよりも外観色と塗布色の差が気にならないことが明
らかであり、自然な肌色が再現できることがわかる。鉄
処理体質顔料又は鉄含有二酸化チタンのいずれか一方を
配合した比較例２，３は、鉄処理体質顔料及び鉄含有二
酸化チタンを全く配合しない比較例１より外観色と塗布
色の差が気にならなくなっているが、大幅な改善には至
っていない。鉄処理体質顔料、鉄含有二酸化チタンを併
用することにより、外観色と塗布色の差が小さく、自然
な肌色を再現できるメイクアップ化粧料が得られた。[Table 6] From these results, it is clear that the difference between the appearance color and the applied color is less noticeable in the foundation of the actual example than in the comparative example, and it is clear that a natural skin color can be reproduced. In Comparative Examples 2 and 3 in which either the iron-treated extender pigment or the iron-containing titanium dioxide was added, the difference between the appearance color and the coating color was more noticeable than in Comparative Example 1 in which the iron-treated extender pigment and the iron-containing titanium dioxide were not added at all. It has disappeared, but it has not improved significantly. By using the iron-treated extender pigment and the iron-containing titanium dioxide in combination, a makeup cosmetic having a small difference between the appearance color and the coating color and capable of reproducing a natural skin color was obtained.
【００３４】フラッシュ光による撮影 上記で得られた実施例１〜３，比較例１〜５のファンデ
ーションを実際に塗布し、太陽光の入らない室内にてフ
ラッシュ撮影を行った。一名の女性に実施例，比較例あ
わせて８種類のファンデーションを塗布し、ファンデー
ション毎にフラッシュ光による写真撮影を行った。これ
で得られた写真を用いてファンデーションの白浮きが気
になるかどうか、２０名に聞き取り調査を行った。白浮
きが顕著である、ややある、ないの３段階で聞き取りを
行い、各評価を行った人数を集計した。結果を表７に示
す。Photographing with Flash Light The foundations of Examples 1 to 3 and Comparative Examples 1 to 5 obtained above were actually applied, and flash photographing was carried out in a room where sunlight did not enter. Eight types of foundations, including the examples and comparative examples, were applied to one woman, and a photograph was taken with a flash light for each foundation. Using the photograph thus obtained, an interview survey was conducted with 20 people as to whether or not whitening of the foundation was a concern. Interviews were conducted on three levels: whitening was noticeable, moderate, and nonexistent, and the number of people who performed each evaluation was totaled. The results are shown in Table 7.
【表７】 この結果から、実施例のファンデーションは、比較例の
ものよりもフラッシュ撮影による白浮きが抑制されてい
ることは明らかである。鉄処理体質顔料又は鉄含有二酸
化チタンのいずれか一方を配合した比較例２，３は、鉄
処理体質顔料及び鉄含有二酸化チタンを全く配合しない
比較例１よりフラッシュ撮影による白浮きが若干抑えら
れているが、大幅な改善には至っていない。鉄処理体質
顔料、鉄含有二酸化チタンを併用することにより、フラ
ッシュ撮影による白浮きが大幅に抑制された。[Table 7] From this result, it is clear that the foundation of the example has more suppressed whitening due to flash photography than the comparative example. In Comparative Examples 2 and 3 containing either the iron-treated extender pigment or the iron-containing titanium dioxide, whitening caused by flash photography was slightly suppressed as compared with Comparative Example 1 in which the iron-treated extender pigment and the iron-containing titanium dioxide were not added at all. However, there is no significant improvement. By using an iron-treated extender pigment and iron-containing titanium dioxide in combination, whitening caused by flash photography was significantly suppressed.
【００３５】[0035]
【発明の効果】鉄処理体質顔料と鉄含有二酸化チタンを
併用して配合することにより、白く浮き上がったような
塗布色が改善され、外観色と塗布色の差が小さく自然な
肌色を再現でき、さらにはフラッシュ撮影により顔が白
く浮かび上がることを防ぐメイクアップ化粧料が得られ
た。[Effects of the Invention] By using the iron-treated extender pigment and iron-containing titanium dioxide in combination, the coating color that appears to be white is improved, and the difference between the appearance color and the coating color is small and a natural skin color can be reproduced. Furthermore, a makeup cosmetic that prevents the face from appearing white by flash photography was obtained.
【図１】本発明の実施例１及び比較例１，２，３に係る
パウダーファンデーションの未使用のプレス面と、パフ
でほぐした使用後の面との色差を示す図であるFIG. 1 is a diagram showing a color difference between an unused pressed surface of a powder foundation according to Example 1 of the present invention and Comparative Examples 1, 2, and 3 and a surface after use which is loosened with a puff.
Claims (3)
用して配合することを特徴とするメイクアップ化粧料。1. A makeup cosmetic comprising an iron-treated body pigment and iron-containing titanium dioxide in combination.
ル中若しくは塩化第二鉄の酸性水溶液中に、体質顔料を
浸漬した後乾燥、焼成、粉砕して得られる請求項１に記
載のメイクアップ化粧料。2. The makeup according to claim 1, wherein the iron-treated extender pigment is obtained by immersing the extender pigment in a ferric chloride organosol or an acidic aqueous solution of ferric chloride, followed by drying, firing, and crushing. Up cosmetics.
水分解する際塩化第二鉄を添加し、チタニア表面に含水
酸化鉄を沈殿させた後、焼成、粉砕して得られる請求項
１又は請求項２に記載のメイクアップ化粧料。3. The iron-containing titanium dioxide is obtained by adding ferric chloride when hydrolyzing titanium tetrachloride, precipitating hydrous iron oxide on the surface of titania, followed by calcination and pulverization. The makeup cosmetic composition according to claim 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10766094A JPH07291835A (en) | 1994-04-21 | 1994-04-21 | Makeup cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10766094A JPH07291835A (en) | 1994-04-21 | 1994-04-21 | Makeup cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH07291835A true JPH07291835A (en) | 1995-11-07 |
Family
ID=14464797
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10766094A Pending JPH07291835A (en) | 1994-04-21 | 1994-04-21 | Makeup cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07291835A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100348821B1 (en) * | 1999-01-25 | 2002-08-17 | 주식회사 태평양 | A Method for preparing black titanium oxide powder |
| JP2007291090A (en) * | 2006-03-31 | 2007-11-08 | Kose Corp | Powdery cosmetic |
| JP2011526908A (en) * | 2008-07-01 | 2011-10-20 | ザ プロクター アンド ギャンブル カンパニー | The process of reducing skin powderiness or pasty appearance |
-
1994
- 1994-04-21 JP JP10766094A patent/JPH07291835A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100348821B1 (en) * | 1999-01-25 | 2002-08-17 | 주식회사 태평양 | A Method for preparing black titanium oxide powder |
| JP2007291090A (en) * | 2006-03-31 | 2007-11-08 | Kose Corp | Powdery cosmetic |
| JP2011526908A (en) * | 2008-07-01 | 2011-10-20 | ザ プロクター アンド ギャンブル カンパニー | The process of reducing skin powderiness or pasty appearance |
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