JPH07179323A - Eye makeup cosmetic - Google Patents
Eye makeup cosmeticInfo
- Publication number
- JPH07179323A JPH07179323A JP30730693A JP30730693A JPH07179323A JP H07179323 A JPH07179323 A JP H07179323A JP 30730693 A JP30730693 A JP 30730693A JP 30730693 A JP30730693 A JP 30730693A JP H07179323 A JPH07179323 A JP H07179323A
- Authority
- JP
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- Prior art keywords
- fibers
- fluorine compound
- eye makeup
- makeup cosmetic
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
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Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、製品中での繊維の分散
性に優れ、睫及び眉毛へ繊維が束付きしたり枝分かれ状
に付着することのない、均一な付着性を有する睫用及び
／又は眉毛用のアイメークアップ化粧料に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is for eyelashes having excellent dispersibility of fibers in a product and having a uniform adherence to the eyelashes and eyebrows without causing the fibers to be bundled or branching. And / or eye makeup cosmetics for eyebrows.
【０００２】[0002]
【従来の技術】従来、睫用、眉毛用のアイメークアップ
化粧料は睫や眉毛の形を整えてより美しくみせるために
用いられており、求められる機能としては、睫のカール
力、睫及び眉毛のロングラッシュ感、ボリューム感のア
ップ等が挙げられる。これらの機能を満たすために種々
の原料が配合され、カール感やボリューム感を出すため
にワックス成分や皮膜形成剤が多く配合されたり、ボリ
ューム感やロングラッシュ感を出すために繊維が配合さ
れることがある。2. Description of the Related Art Conventionally, eye make-up cosmetics for eyelashes and eyebrows have been used to improve the shape of eyelashes and eyebrows to make them look more beautiful. The required functions are the curling power of eyelashes, eyelashes and eyebrows. The long rush feeling and volume feeling are improved. Various raw materials are blended to satisfy these functions, a large amount of a wax component and a film forming agent are blended to give a curl feeling and a volume feeling, and fibers are blended to give a volume feeling and a long rush feeling. Sometimes.
【０００３】[0003]
【発明が解決しようとする課題】しかしながら、用いら
れる繊維は製品系での分散性が悪く、睫や眉毛につけた
とき繊維が不均一でなおかつ睫や眉毛に沿って付着せ
ず、枝分かれ状に付着したり睫や眉毛の上で束付きする
など、外観上の美しさが損なわれてきた。そのため、繊
維の分散性を向上させる目的で界面活性剤等を配合し、
その改善が試みられてきたが、その効果は充分とは言え
なかった。However, the fibers used have poor dispersibility in the product system, and when applied to the eyelashes and eyebrows, the fibers are non-uniform and they do not adhere along the eyelashes or eyebrows, but in a branched manner. The beauty of the appearance has been impaired, for example, by putting it on the eyelashes or eyelashes. Therefore, for the purpose of improving the dispersibility of the fibers, a surfactant or the like is added,
The improvement has been tried, but the effect was not sufficient.
【０００４】[0004]
【課題を解決するための手段】かかる事情に鑑み、本発
明者らは上記課題を解決するために鋭意研究を行った結
果、フッ素化合物で繊維の表面を処理し繊維の分散性を
向上させ、その繊維を配合することによって、繊維が睫
や眉毛に均一かつ毛の方向に沿って付着し、束付きや枝
分かれ状の付着などを抑えるという優れた性質が得られ
ることを見いだし本発明を完成させた。In view of such circumstances, the present inventors have conducted diligent research to solve the above problems, and as a result, the surface of the fiber is treated with a fluorine compound to improve the dispersibility of the fiber, It has been found that, by blending the fibers, the fibers are uniformly attached to the eyelashes and eyebrows along the direction of the hair, and excellent properties of suppressing adhesion with bundles or branches are obtained, and the present invention is completed. It was
【０００５】即ち、本発明は、フッ素化合物により表面
を処理した繊維を含有することを特徴とするアイメーク
アップ化粧料を提供するものである。That is, the present invention provides an eye make-up cosmetic composition containing fibers whose surface is treated with a fluorine compound.
【０００６】本発明で用いられるフッ素化合物は、例え
ば次の一般式（１）The fluorine compound used in the present invention has, for example, the following general formula (1):
【化３】 （式中、ｎは６〜１８の整数を示し、ｍは１又は２を示
す。）で表されるパーフルオロアルキルリン酸エステル
ジエタノールアミン塩（旭硝子（株）製、アサヒガード
ＡＧ５３０等）、一般式（２）[Chemical 3] (In the formula, n represents an integer of 6 to 18 and m represents 1 or 2.) A perfluoroalkyl phosphate ester diethanolamine salt (Asahi Guard AG530 manufactured by Asahi Glass Co., Ltd.), a general formula. (2)
【化４】 （式中、ａは１〜１２の整数を示し、ｂは１〜５の整数
を示し、Ｘは同一又は異なって、アルコキシ基、ハロゲ
ン原子又はアルキル基を示す。ただし、すべてのＸがア
ルキル基の場合を除く。）で表されるパーフルオロアル
キルシラン（ＬＳ−１６０、ＬＳ−３６０，ＬＳ−９１
２，ＬＳ−１０８０、ＬＳ−１０９０、ＬＳ−１４６５
（以上、信越化学工業（株）製）、ＸＣ９５−４１８，
ＸＣ９５−４６６，ＸＣ９５−４６７，ＸＣ９５−４６
８，ＸＣ９５−４６９，ＸＣ９５−４７０，ＸＣ９５−
４７１，ＸＣ９５−４７２（以上、東芝シリコーン
（株）製）等が挙げられる。[Chemical 4] (In formula, a shows the integer of 1-12, b shows the integer of 1-5, X is the same or different and shows an alkoxy group, a halogen atom, or an alkyl group. However, all X is an alkyl group. Of the perfluoroalkylsilane (LS-160, LS-360, LS-91).
2, LS-1080, LS-1090, LS-1465
(Above, manufactured by Shin-Etsu Chemical Co., Ltd.), XC95-418,
XC95-466, XC95-467, XC95-46
8, XC95-469, XC95-470, XC95-
471, XC95-472 (above, manufactured by Toshiba Silicone Co., Ltd.) and the like.
【０００７】処理される繊維としては、ナイロン、ポリ
エステル等の合成繊維、レーヨン等の人造繊維、セルロ
ース等の天然繊維、アセテート人絹等の半合成繊維、等
が挙げられるが、通常化粧品に用いられるものならば、
何等これらに限定されるものではない。The fibers to be treated include synthetic fibers such as nylon and polyester, artificial fibers such as rayon, natural fibers such as cellulose, semi-synthetic fibers such as acetate human silk, etc., but they are usually used in cosmetics. If something
It is not limited to these.
【０００８】繊維の太さについては１〜７デニール（以
下Ｄと記す）が好ましい。繊維の長さについては０．５
〜５ｍｍが好ましく、１〜３ｍｍがより好ましい。これ
らの繊維は材質、太さ又は長さにおいて１種又は２種以
上を組み合わせて用いることができる。The fiber thickness is preferably 1 to 7 denier (hereinafter referred to as D). 0.5 for fiber length
-5 mm is preferable, and 1-3 mm is more preferable. These fibers may be used alone or in combination of two or more in terms of material, thickness or length.
【０００９】これらの繊維をフッ素化合物で処理する方
法は、特に限定されないが、例えばフッ素化合物をアセ
トン、トルエン等の有機溶媒に加熱溶解せしめ、その中
に繊維の１種又は２種以上の混合物を加え、撹拌後溶媒
を留去して繊維上にフッ素化合物を被覆又は付着させ、
場合によっては更に焼き付け処理をする方法がある。The method for treating these fibers with a fluorine compound is not particularly limited. For example, the fluorine compound is heated and dissolved in an organic solvent such as acetone or toluene, and one or a mixture of two or more of the fibers is added thereto. In addition, the solvent is distilled off after stirring to coat or adhere the fluorine compound on the fiber,
Depending on the case, there is a method of further baking.
【００１０】又、フッ素化合物にアルキルリン酸ジエタ
ノールアミン塩を用いる場合には、同様の繊維に水を加
えてスラリー状とし、一方アルキルリン酸エステルジエ
タノールアミン塩を水に加え攪拌して０．１〜５重量％
（以下％と記す）のエマルジョン状態としたものを、前
記スラリーに徐々に注加、混合した後酸性とし、常温又
は高温静置などによってエマルジョンを破壊して洗浄、
ろ過、乾燥すれば良い。尚、フッ素化合物の処理量は、
その種類によっても異なるが繊維の０．１〜５０％、特
に０．５〜２０％が好ましい。When an alkylphosphoric acid diethanolamine salt is used as the fluorine compound, water is added to the same fiber to make a slurry, while the alkylphosphoric acid ester diethanolamine salt is added to water and stirred for 0.1-5. weight%
What was made into an emulsion state (hereinafter referred to as%) is gradually poured into the above slurry, mixed and then acidified, and the emulsion is broken by washing at room temperature or high temperature and washed,
It may be filtered and dried. The processing amount of the fluorine compound is
Although it varies depending on the type, it is preferably 0.1 to 50%, particularly 0.5 to 20% of the fiber.
【００１１】本発明においてフッ素化合物により処理さ
れた繊維の配合量は、繊維の種類によっても異なるが、
好ましくは０．０１〜１０％、より好ましくは０．１〜
５％配合される。The blending amount of the fiber treated with the fluorine compound in the present invention varies depending on the kind of the fiber,
Preferably 0.01 to 10%, more preferably 0.1 to 10.
5% is blended.
【００１２】又、本発明の効果を損なわない範囲で、通
常アイメークアップ化粧料に用いられる粉体や、固形、
液状又はペースト状の油剤、ゲル化剤、エマルションポ
リマー、界面活性剤、多価アルコール、紫外線吸収剤、
美容成分、グリコール類、水溶性成分、樹脂、防腐剤、
香料等を配合することができる。[0012] Further, within a range that does not impair the effects of the present invention, powders or solids usually used in eye makeup cosmetics, solid,
Liquid or paste oil, gelling agent, emulsion polymer, surfactant, polyhydric alcohol, UV absorber,
Beauty ingredients, glycols, water-soluble ingredients, resins, preservatives,
Fragrances and the like can be added.
【００１３】[0013]
【実施例】以下に実施例を挙げて、更に説明する。な
お、これらは本発明を何ら限定するものではない。EXAMPLES The present invention will be further described below with reference to examples. These do not limit the present invention in any way.
【００１４】実施例１〜３及び比較例１〜３ 表１に示す処方の皮膜タイプマスカラを調製し、繊維の
分散性、繊維の付着均一性、使用時の使用感、効果の持
続性等について評価した。その結果を表２に示す。Examples 1 to 3 and Comparative Examples 1 to 3 Film type mascaras having the formulations shown in Table 1 were prepared, and the dispersibility of the fibers, the uniformity of the adhesion of the fibers, the feeling during use, the durability of the effect, etc. evaluated. The results are shown in Table 2.
【００１５】[0015]
【表１】 [Table 1]
【００１６】（製法） Ａ． （２）〜（６）及び（１２）を混合し加熱溶解す
る。 Ｂ． Ａに（７）（８）及び（１０）（１１）を加え、
均一に分散する。 Ｃ． Ｂに（１）（９）を加え、混合し、均質にする。 Ｄ． Ｃを容器に充填して、製品とする。(Production Method) A. (2) to (6) and (12) are mixed and dissolved by heating. B. Add (7) (8) and (10) (11) to A,
Disperse evenly. C. Add (1) and (9) to B, mix and homogenize. D. Fill C into a container to obtain a product.
【００１７】（分散性の評価） ガラス板にドクターブレードを用いて皮膜タイプマスカ
ラの薄膜を引き、乾燥後、凝集物の有無により判断し
た。 判定 全くなし ◎ ややある ○ ある △ 非常にある ×(Evaluation of Dispersibility) A thin film of film type mascara was drawn on a glass plate using a doctor blade, dried, and then judged by the presence or absence of aggregates. Judgment None ◎ Somewhat ○ Yes △ Very much ×
【００１８】（睫へのなじみやすさ、繊維の付着均一
性、使用時の使用感、耐水耐油性、効果の持続性の評
価）実施例２及び比較例２のマスカラについて、女性パ
ネル２０名による使用テストを行い、下記基準により評
価した。 評価点 非常によい ３点 良い〜普通 ２点 悪い １点 判定 平均点 ２．５点以上 ◎ ２．０点以上２．５点未満 ○ １．５点以上２．０点未満 △ １．５点未満 ×(Ease of conforming to eyelashes, uniformity of adhesion of fibers, feeling of use during use, water and oil resistance, and evaluation of effect persistence) The mascara of Example 2 and Comparative Example 2 was evaluated by 20 female panels. A usage test was conducted and evaluated according to the following criteria. Evaluation points Very good 3 points Good to normal 2 points Poor 1 point Judgment average point 2.5 points or more ◎ 2.0 points or more and less than 2.5 points ○ 1.5 points or more and less than 2.0 points △ 1.5 points Less than ×
【００１９】[0019]
【表２】 [Table 2]
【００２０】表２から明らかなように、アサヒガード５
％処理ナイロン繊維を配合した本発明のマスカラは比較
例と比べ、繊維の分散性、使用時の使用感、繊維の付着
均一性において特に優れたものであり、製品の品質とし
て比較例より優れていることが実証された。As is clear from Table 2, Asahi Guard 5
Compared with the comparative example, the mascara of the present invention containing the% treated nylon fiber is particularly excellent in the dispersibility of the fiber, the feeling of use during use, and the uniformity of the adhesion of the fiber, and is superior to the comparative example in terms of product quality. It was proved that
【００２１】 実施例４ 乳化皮膜タイプマスカラ （処方） （重量％） （１）ステアリン酸 ２ （２）ミツロウ ８ （３）セタノール １ （４）モノオレイン酸ポリオキシエチレンソルビタン（２０Ｅ.Ｏ.） ０．８ （５）セスキオレイン酸ソルビタン ０．４ （６）顔料 １５ （７）トリエタノールアミン １ （８）防腐剤 適量 （９）アサヒガード５％処理ナイロン繊維（２Ｄ、１．５ｍｍ） ３ （注１） （１０）ポリアクリル酸エステルエマルジョン ４０ （１１）香料 適量 （１２）精製水 残量 （注１）：前記と同じExample 4 Emulsion film type mascara (formulation) (% by weight) (1) stearic acid 2 (2) beeswax 8 (3) cetanol 1 (4) polyoxyethylene sorbitan monooleate (20E.O.) 0 .8 (5) Sorbitan sesquioleate 0.4 (6) Pigment 15 (7) Triethanolamine 1 (8) Preservative Appropriate amount (9) Asahi Guard 5% treated nylon fiber (2D, 1.5 mm) 3 (Note) 1) (10) Polyacrylate emulsion 40 (11) Perfume proper amount (12) Purified water Remaining amount (Note 1): Same as above
【００２２】（製法） Ａ． （１）〜（５）を加熱溶解後、（６）を加えて均
一分散する。 Ｂ． （７）〜（１０）及び（１２）を加熱混合する。 Ｃ． ＡにＢを加え、乳化し、冷却後、（１１）を加え
る。 Ｄ． Ｃを容器に充填して、製品とする。(Production Method) A. After heating and dissolving (1) to (5), (6) is added and uniformly dispersed. B. (7) to (10) and (12) are heated and mixed. C. Add B to A, emulsify, and after cooling, add (11). D. Fill C into a container to obtain a product.
【００２３】 実施例５ 溶剤タイプマスカラ （処方） （重量％） （１）デンプン脂肪酸エステル ８ （２）パラフィンワックス ８ （３）イソパラフィン 残量 （４）顔料 １０ （５）アサヒガード５％処理ナイロン繊維（３Ｄ、１ｍｍ）（注１） ３ （６）香料 適量 （注１）：前記と同じExample 5 Solvent type mascara (formulation) (% by weight) (1) Starch fatty acid ester 8 (2) Paraffin wax 8 (3) Isoparaffin remaining (4) Pigment 10 (5) Asahi guard 5% treated nylon fiber (3D, 1 mm) (Note 1) 3 (6) Perfume Suitable amount (Note 1): Same as above
【００２４】（製法） Ａ． （３）の一部で（４）（５）を均一分散させる。 Ｂ． （３）の残部と（１）（２）（６）を加熱混合す
る。 Ｃ． ＡとＢを均一に混合する。 Ｄ． Ｃを容器に充填して、製品とする。(Production Method) A. (4) and (5) are uniformly dispersed in a part of (3). B. The rest of (3) and (1), (2) and (6) are heated and mixed. C. Mix A and B uniformly. D. Fill C into a container to obtain a product.
【００２５】 実施例６ リキッドアイブロウ （処方） （重量％） （１）ポリメタクリル酸 ２ （２）トリエタノールアミン ２．５ （３）ブチレングリコール ３ （４）塩化ナトリウム ０．５ （５）防腐剤 適量 （６）シリカ ２ （７）顔料 ８ （８）アサヒガード５％処理レーヨン繊維（１Ｄ、０．５ｍｍ） ２ （注１） （９）香料 適量 （１０）ポリアクリル酸エステルエマルジョン ４０ （１１）精製水 残量 （注１）：前記と同じExample 6 Liquid Eyebrow (Formulation) (wt%) (1) Polymethacrylic acid 2 (2) Triethanolamine 2.5 (3) Butylene glycol 3 (4) Sodium Chloride 0.5 (5) Preservative Proper amount (6) Silica 2 (7) Pigment 8 (8) Asahi Guard 5% treated rayon fiber (1D, 0.5 mm) 2 (Note 1) (9) Perfume Proper amount (10) Polyacrylic ester emulsion 40 (11) Purified water balance (Note 1): Same as above
【００２６】（製法） Ａ． （１）〜（５）（１１）を混合し、加熱溶解す
る。 Ｂ． Ａに（６）〜（８）を加え、均一分散する。 Ｃ． Ｂに（９）（１０）を加え、均一に混合する。 Ｄ． Ｃを容器に充填して、製品とする。(Production Method) A. (1) to (5) and (11) are mixed and dissolved by heating. B. (6) to (8) are added to A and uniformly dispersed. C. Add (9) and (10) to B and mix uniformly. D. Fill C into a container to obtain a product.
【００２７】[0027]
【発明の効果】以上詳述した如く、繊維をフッ素化合物
で処理することにより繊維の分散性が向上し、その繊維
を配合したアイメークアップ化粧料は睫及び眉毛への繊
維の付着均一性が向上し、従来問題とされてきた睫及び
眉毛への繊維の束付きや枝分かれ状の付着などの現象が
改善される。このように、本発明のアイメークアップ化
粧料は使用時の使用感、繊維の付着均一性等に優れた品
質を有し、非常に有用である。As described in detail above, the dispersibility of fibers is improved by treating the fibers with a fluorine compound, and the eye makeup cosmetics containing the fibers have improved uniformity of the adhesion of the fibers to the eyelashes and eyebrows. However, the phenomenon such as the attachment of fibers to the eyelashes and the eyebrows and the branch-like attachment, which have been conventionally problematic, are improved. As described above, the eye makeup cosmetic of the present invention is very useful because it has excellent qualities in use, uniformity of fiber attachment and the like.
Claims (5)
を含有することを特徴とするアイメークアップ化粧料。1. An eye make-up cosmetic, comprising fibers whose surface is treated with a fluorine compound.
０．５〜５ｍｍの範囲である請求項１記載のアイメーク
アップ化粧料。2. The eye makeup cosmetic according to claim 1, wherein the fiber has a thickness of 1 to 7 denier and a length of 0.5 to 5 mm.
〜３ｍｍの範囲である請求項１記載のアイメークアップ
化粧料。3. The fiber has a thickness of 1 to 7 denier and a length of 1
The eye makeup cosmetic according to claim 1, which is in the range of 3 mm.
す。）で表されるパーフルオロアルキルリン酸エステル
ジエタノールアミン塩から選ばれる化合物の１種又は２
種以上である、請求項１から３の何れか１項に記載のア
イメークアップ化粧料。4. A fluorine compound is represented by the following general formula (1): (In the formula, n represents an integer of 6 to 18, and m represents 1 or 2.) One or two compounds selected from perfluoroalkyl phosphate ester diethanolamine salts.
The eye makeup cosmetic according to any one of claims 1 to 3, which is one or more kinds.
を示し、Ｘは同一又は異なって、アルコキシ基、ハロゲ
ン原子又はアルキル基を示す。ただし、すべてのＸがア
ルキル基の場合を除く。）で表されるパーフルオロアル
キルシランから選ばれる化合物の１種又は２種以上であ
る、請求項１から３の何れか１項に記載のアイメークア
ップ化粧料。5. A fluorine compound is represented by the following general formula (2): (In formula, a shows the integer of 1-12, b shows the integer of 1-5, X is the same or different and shows an alkoxy group, a halogen atom, or an alkyl group. However, all X is an alkyl group. The eye makeup cosmetics according to any one of claims 1 to 3, which is one or more compounds selected from the perfluoroalkylsilanes represented by the formula (1) or (2) or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30730693A JP3409192B2 (en) | 1993-11-12 | 1993-11-12 | Eye makeup cosmetics for eyelashes or eyebrows |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30730693A JP3409192B2 (en) | 1993-11-12 | 1993-11-12 | Eye makeup cosmetics for eyelashes or eyebrows |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH07179323A true JPH07179323A (en) | 1995-07-18 |
| JP3409192B2 JP3409192B2 (en) | 2003-05-26 |
Family
ID=17967566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30730693A Expired - Lifetime JP3409192B2 (en) | 1993-11-12 | 1993-11-12 | Eye makeup cosmetics for eyelashes or eyebrows |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3409192B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6306407B1 (en) | 1998-07-30 | 2001-10-23 | Color Access, Inc. | Topical moisture regulating compositions |
| US6342237B1 (en) | 1999-07-08 | 2002-01-29 | L'oréal | Make-up composition comprising fibers |
| US6905696B2 (en) | 2003-01-06 | 2005-06-14 | Color Access, Inc. | Alignment of enhancers in cosmetic compositions |
| US6955805B2 (en) | 1999-06-02 | 2005-10-18 | Color Access, Inc. | Non-tacky mascara composition |
| JP2022018606A (en) * | 2020-07-16 | 2022-01-27 | 株式会社伊勢半 | Eye makeup cosmetic |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4866564B2 (en) * | 2004-03-30 | 2012-02-01 | 株式会社コーセー | Cosmetic for salmon |
-
1993
- 1993-11-12 JP JP30730693A patent/JP3409192B2/en not_active Expired - Lifetime
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6306407B1 (en) | 1998-07-30 | 2001-10-23 | Color Access, Inc. | Topical moisture regulating compositions |
| US6596286B2 (en) * | 1998-07-30 | 2003-07-22 | Color Access, Inc. | Topical moisture regulating compositions |
| US6955805B2 (en) | 1999-06-02 | 2005-10-18 | Color Access, Inc. | Non-tacky mascara composition |
| US6342237B1 (en) | 1999-07-08 | 2002-01-29 | L'oréal | Make-up composition comprising fibers |
| US6905696B2 (en) | 2003-01-06 | 2005-06-14 | Color Access, Inc. | Alignment of enhancers in cosmetic compositions |
| JP2022018606A (en) * | 2020-07-16 | 2022-01-27 | 株式会社伊勢半 | Eye makeup cosmetic |
| KR20230040985A (en) | 2020-07-16 | 2023-03-23 | 가부시키가이샤 이세항 | eye makeup cosmetics |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3409192B2 (en) | 2003-05-26 |
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