JPH0488041A - Stabilized chlorine-containing resin composition - Google Patents
Stabilized chlorine-containing resin compositionInfo
- Publication number
- JPH0488041A JPH0488041A JP20292190A JP20292190A JPH0488041A JP H0488041 A JPH0488041 A JP H0488041A JP 20292190 A JP20292190 A JP 20292190A JP 20292190 A JP20292190 A JP 20292190A JP H0488041 A JPH0488041 A JP H0488041A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- bis
- containing resin
- chlorine
- lead
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 239000000460 chlorine Substances 0.000 title claims abstract description 21
- 229910052801 chlorine Inorganic materials 0.000 title claims abstract description 21
- 239000011342 resin composition Substances 0.000 title claims description 9
- -1 hydrotalcite compound Chemical class 0.000 claims abstract description 28
- 229960001545 hydrotalcite Drugs 0.000 claims abstract description 14
- 229910001701 hydrotalcite Inorganic materials 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 9
- 239000003513 alkali Substances 0.000 claims abstract description 9
- 239000005749 Copper compound Substances 0.000 claims abstract description 8
- 150000001880 copper compounds Chemical class 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 abstract description 15
- 239000007864 aqueous solution Substances 0.000 abstract description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract description 7
- 230000000704 physical effect Effects 0.000 abstract description 4
- 229910021591 Copper(I) chloride Inorganic materials 0.000 abstract description 3
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 abstract description 3
- 229940045803 cuprous chloride Drugs 0.000 abstract description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract description 3
- KRGNPJFAKZHQPS-UHFFFAOYSA-N chloroethene;ethene Chemical group C=C.ClC=C KRGNPJFAKZHQPS-UHFFFAOYSA-N 0.000 abstract description 2
- 229920001038 ethylene copolymer Polymers 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 description 25
- 239000002253 acid Substances 0.000 description 17
- 229920001577 copolymer Polymers 0.000 description 10
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 8
- PWZFXELTLAQOKC-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide;tetrahydrate Chemical class O.O.O.O.[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O PWZFXELTLAQOKC-UHFFFAOYSA-A 0.000 description 8
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 239000007983 Tris buffer Substances 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 4
- 229960003280 cupric chloride Drugs 0.000 description 4
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229940049920 malate Drugs 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 239000004800 polyvinyl chloride Substances 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 3
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 3
- 229910000365 copper sulfate Inorganic materials 0.000 description 3
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 3
- PWEVMPIIOJUPRI-UHFFFAOYSA-N dimethyltin Chemical compound C[Sn]C PWEVMPIIOJUPRI-UHFFFAOYSA-N 0.000 description 3
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 description 3
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- 230000002087 whitening effect Effects 0.000 description 3
- UKVYVZLTGQVOPX-IHWYPQMZSA-N (z)-3-aminobut-2-enoic acid Chemical class C\C(N)=C\C(O)=O UKVYVZLTGQVOPX-IHWYPQMZSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- RZBBHEJLECUBJT-UHFFFAOYSA-N 6-methylheptyl 2-sulfanylacetate Chemical compound CC(C)CCCCCOC(=O)CS RZBBHEJLECUBJT-UHFFFAOYSA-N 0.000 description 2
- OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 241001483078 Phyto Species 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 125000006267 biphenyl group Chemical group 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- NPAIMXWXWPJRES-UHFFFAOYSA-N butyltin(3+) Chemical compound CCCC[Sn+3] NPAIMXWXWPJRES-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 229940116318 copper carbonate Drugs 0.000 description 2
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Chemical compound CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 150000004677 hydrates Chemical class 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 229940070765 laurate Drugs 0.000 description 2
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 2
- OCWMFVJKFWXKNZ-UHFFFAOYSA-L lead(2+);oxygen(2-);sulfate Chemical compound [O-2].[O-2].[O-2].[Pb+2].[Pb+2].[Pb+2].[Pb+2].[O-]S([O-])(=O)=O OCWMFVJKFWXKNZ-UHFFFAOYSA-L 0.000 description 2
- 239000004611 light stabiliser Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- SJOCPYUKFOTDAN-ZSOIEALJSA-N methyl (4z)-4-hydroxyimino-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophene-1-carboxylate Chemical compound C1C(C)(C)C\C(=N\O)C=2C1=C(C(=O)OC)SC=2SC SJOCPYUKFOTDAN-ZSOIEALJSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 2
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 235000011181 potassium carbonates Nutrition 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000013112 stability test Methods 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- GKOTWPKLOWTGAG-NRFIWDAESA-L (z)-4-butoxy-4-oxobut-2-enoate;dioctyltin(2+) Chemical compound CCCCOC(=O)\C=C/C(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)\C=C/C(=O)OCCCC GKOTWPKLOWTGAG-NRFIWDAESA-L 0.000 description 1
- BLZFAQQFNDAXEY-KWZUVTIDSA-L (z)-but-2-enedioate;dicyclohexyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.C1CCCCC1[Sn+2]C1CCCCC1 BLZFAQQFNDAXEY-KWZUVTIDSA-L 0.000 description 1
- APQIUTYORBAGEZ-UHFFFAOYSA-N 1,1-dibromoethane Chemical compound CC(Br)Br APQIUTYORBAGEZ-UHFFFAOYSA-N 0.000 description 1
- AFPIWWDEGJLLCL-UHFFFAOYSA-N 1,3,2,4$l^{2}-dioxasilaplumbetane 2-oxide Chemical compound [Pb+2].[O-][Si]([O-])=O AFPIWWDEGJLLCL-UHFFFAOYSA-N 0.000 description 1
- GWEHVDNNLFDJLR-UHFFFAOYSA-N 1,3-diphenylurea Chemical compound C=1C=CC=CC=1NC(=O)NC1=CC=CC=C1 GWEHVDNNLFDJLR-UHFFFAOYSA-N 0.000 description 1
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 1
- 229940114069 12-hydroxystearate Drugs 0.000 description 1
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 1
- OFOWUDSDZLONKT-UHFFFAOYSA-N 12-oxo-octadecanoic acid Chemical compound CCCCCCC(=O)CCCCCCCCCCC(O)=O OFOWUDSDZLONKT-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- WCTWRMIVIIOQPX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dibutyl(oxo)tin Chemical compound OCC(CO)(CO)CO.CCCC[Sn](=O)CCCC WCTWRMIVIIOQPX-UHFFFAOYSA-N 0.000 description 1
- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 description 1
- OLOQHZSCBTUIGQ-UHFFFAOYSA-L 2,2-dibutyl-1,3,2-oxathiastannolan-5-one Chemical compound CCCC[Sn]1(CCCC)OC(=O)CS1 OLOQHZSCBTUIGQ-UHFFFAOYSA-L 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- PQMSAAPLQZNBHK-UHFFFAOYSA-N 2-(benzotriazol-1-yl)phenol Chemical class OC1=CC=CC=C1N1C2=CC=CC=C2N=N1 PQMSAAPLQZNBHK-UHFFFAOYSA-N 0.000 description 1
- KRZTYSCUOUIFHR-BDAKNGLRSA-N 2-[(1r,3s)-2,2-dimethyl-3-(2-oxopropyl)cyclopropyl]acetonitrile Chemical compound CC(=O)C[C@H]1[C@@H](CC#N)C1(C)C KRZTYSCUOUIFHR-BDAKNGLRSA-N 0.000 description 1
- XRXMNWGCKISMOH-UHFFFAOYSA-N 2-bromobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1Br XRXMNWGCKISMOH-UHFFFAOYSA-N 0.000 description 1
- IKCLCGXPQILATA-UHFFFAOYSA-N 2-chlorobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1Cl IKCLCGXPQILATA-UHFFFAOYSA-N 0.000 description 1
- CGMMPMYKMDITEA-UHFFFAOYSA-N 2-ethylbenzoic acid Chemical compound CCC1=CC=CC=C1C(O)=O CGMMPMYKMDITEA-UHFFFAOYSA-N 0.000 description 1
- VHKGIWUCVBAITR-UHFFFAOYSA-K 2-ethylhexyl 2-[bis[[2-(2-ethylhexoxy)-2-oxoethyl]sulfanyl]-octylstannyl]sulfanylacetate Chemical compound CCCCC(CC)COC(=O)CS[Sn](CCCCCCCC)(SCC(=O)OCC(CC)CCCC)SCC(=O)OCC(CC)CCCC VHKGIWUCVBAITR-UHFFFAOYSA-K 0.000 description 1
- XKZGIJICHCVXFV-UHFFFAOYSA-N 2-ethylhexyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCC(CC)CCCC)OC1=CC=CC=C1 XKZGIJICHCVXFV-UHFFFAOYSA-N 0.000 description 1
- QWUAEFUHELCUHK-UHFFFAOYSA-N 2-hydroxy-2-methylicosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCC(C)(O)C(O)=O QWUAEFUHELCUHK-UHFFFAOYSA-N 0.000 description 1
- IKRKINIKITZMKG-UHFFFAOYSA-N 2-hydroxy-5-octylbenzoic acid Chemical compound CCCCCCCCC1=CC=C(O)C(C(O)=O)=C1 IKRKINIKITZMKG-UHFFFAOYSA-N 0.000 description 1
- KLLLJCACIRKBDT-UHFFFAOYSA-N 2-phenyl-1H-indole Chemical compound N1C2=CC=CC=C2C=C1C1=CC=CC=C1 KLLLJCACIRKBDT-UHFFFAOYSA-N 0.000 description 1
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- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
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- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical compound [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 description 1
- UMKARVFXJJITLN-UHFFFAOYSA-N lead;phosphorous acid Chemical compound [Pb].OP(O)O UMKARVFXJJITLN-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- CSHCPECZJIEGJF-UHFFFAOYSA-N methyltin Chemical compound [Sn]C CSHCPECZJIEGJF-UHFFFAOYSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 229940098695 palmitic acid Drugs 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000002989 phenols Chemical group 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920005671 poly(vinyl chloride-propylene) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 229940079889 pyrrolidonecarboxylic acid Drugs 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000011182 sodium carbonates Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 125000005402 stannate group Chemical group 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 1
- 229950006389 thiodiglycol Drugs 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- XTTGYFREQJCEML-UHFFFAOYSA-N tributyl phosphite Chemical compound CCCCOP(OCCCC)OCCCC XTTGYFREQJCEML-UHFFFAOYSA-N 0.000 description 1
- RITMCSKITUMWCK-UHFFFAOYSA-N tris(2,5-ditert-butyl-4-hydroxyphenyl) phosphite Chemical compound C1=C(O)C(C(C)(C)C)=CC(OP(OC=2C(=CC(O)=C(C=2)C(C)(C)C)C(C)(C)C)OC=2C(=CC(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1C(C)(C)C RITMCSKITUMWCK-UHFFFAOYSA-N 0.000 description 1
- ILLOBGFGKYTZRO-UHFFFAOYSA-N tris(2-ethylhexyl) phosphite Chemical compound CCCCC(CC)COP(OCC(CC)CCCC)OCC(CC)CCCC ILLOBGFGKYTZRO-UHFFFAOYSA-N 0.000 description 1
- LUUMBHMWFNNZPH-UHFFFAOYSA-N tris(3,5-ditert-butyl-4-hydroxyphenyl) phosphite Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(OP(OC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)OC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 LUUMBHMWFNNZPH-UHFFFAOYSA-N 0.000 description 1
- JZNDMMGBXUYFNQ-UHFFFAOYSA-N tris(dodecylsulfanyl)phosphane Chemical compound CCCCCCCCCCCCSP(SCCCCCCCCCCCC)SCCCCCCCCCCCC JZNDMMGBXUYFNQ-UHFFFAOYSA-N 0.000 description 1
- QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 description 1
- WRSPWQHUHVRNFV-UHFFFAOYSA-N tris[3,5-di(nonyl)phenyl] phosphite Chemical compound CCCCCCCCCC1=CC(CCCCCCCCC)=CC(OP(OC=2C=C(CCCCCCCCC)C=C(CCCCCCCCC)C=2)OC=2C=C(CCCCCCCCC)C=C(CCCCCCCCC)C=2)=C1 WRSPWQHUHVRNFV-UHFFFAOYSA-N 0.000 description 1
- XKMIVULWBGSCQE-UHFFFAOYSA-J tris[[8-methyl-2-(6-methylheptyl)-2-sulfanylnonanoyl]oxy]stannyl 8-methyl-2-(6-methylheptyl)-2-sulfanylnonanoate Chemical compound C(CCCCC(C)C)C(C(=O)[O-])(S)CCCCCC(C)C.[Sn+4].C(CCCCC(C)C)C(C(=O)[O-])(S)CCCCCC(C)C.C(CCCCC(C)C)C(C(=O)[O-])(S)CCCCCC(C)C.C(CCCCC(C)C)C(C(=O)[O-])(S)CCCCCC(C)C XKMIVULWBGSCQE-UHFFFAOYSA-J 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、安定化された塩素含有樹脂組成物に関し、詳
しくは、塩素含有樹脂に対して、無機銅化合物水溶液で
処理後、炭酸アルカリ水溶液で再処理したハイドロタル
サイト化合物を添加することによって耐熱性、耐候性の
向上、チョーキングの防止および物性の改善された硬質
塩素含有樹脂組成物に関する。Detailed Description of the Invention [Industrial Application Field] The present invention relates to a stabilized chlorine-containing resin composition, and more specifically, the chlorine-containing resin is treated with an aqueous inorganic copper compound solution and then treated with an aqueous alkali carbonate solution. The present invention relates to a hard chlorine-containing resin composition that has improved heat resistance, weather resistance, prevention of chalking, and improved physical properties by adding a hydrotalcite compound that has been reprocessed.
一般に、塩素含有樹脂は、熱および光に対する安定性に
劣り、加熱成型加工時に主として脱塩化水素に起因する
熱分解を起こし易く、このため、加工品の機械的性質の
低下や色調の悪化を生じ、著しい不利益をまねく。In general, chlorine-containing resins have poor stability against heat and light, and are prone to thermal decomposition mainly due to dehydrochlorination during hot molding, resulting in decreased mechanical properties and color tone of processed products. , resulting in significant disadvantage.
そこで従来より、かかる欠点をさけるために、一種また
は数種の安定剤を添加し安定化することが行われていた
。In order to avoid such drawbacks, it has been conventional practice to add one or more kinds of stabilizers for stabilization.
これらの安定剤の中でも鉛系の安定剤は熱安定化効果が
比較的大きいので広く使用されている。Among these stabilizers, lead-based stabilizers are widely used because they have a relatively large thermal stabilizing effect.
しかしながら、鉛系安定剤を添加した塩素含有樹脂は加
工時に着色が生しること、耐候性が不十分であり特に屋
外での使用時にチョーキングという白化現象を生しるな
どの欠点があり、これらを改善することが要望されてい
た。However, chlorine-containing resins with lead-based stabilizers have disadvantages such as discoloration during processing, insufficient weather resistance, and a whitening phenomenon called chalking, especially when used outdoors. It was requested that this be improved.
また、最近では過酷な温度条件下におけるさらに高度な
熱安定性も要求されている。Furthermore, in recent years, even higher thermal stability under severe temperature conditions has been required.
これらの要求を満たすために、鉛系安定剤と有機錫化合
物を併用する（特開昭５７−１５０号公報）ことが提案
されているが、チョーキングの防止にはほとんど効果が
なく、熱安定化効果も不充分であった。またチョーキン
グを防止するために、鉛系安定剤に２．６−シメチルー
１，４−ジヒドロピリジン系の化合物（特開昭５６−１
６３１３８号公報）あるいは２，２，６．６−チトラメ
チルピベリジン基を有する化合物を併用する（特開昭５
９〜１９６３５１号公報）などが提案されたが、その効
果はまだ不充分であり、さらにこれらの改善が強く望ま
れていた。In order to meet these requirements, it has been proposed to use a lead-based stabilizer and an organic tin compound in combination (Japanese Unexamined Patent Application Publication No. 57-150), but this has little effect on preventing chalking, and thermal stabilization The effect was also insufficient. In addition, in order to prevent chalking, a 2,6-dimethyl-1,4-dihydropyridine compound (Japanese Unexamined Patent Publication No. 56-118) was added to the lead stabilizer.
63138) or in combination with a compound having a 2,2,6,6-titramethylpiveridine group (Japanese Unexamined Patent Publication No. 5
9-196351) have been proposed, but their effects are still insufficient, and further improvements have been strongly desired.
また、ステアリン酸金属塩を併用する配合はチョーキン
グが発現し、特に非鉛系の配合を用いた成型品において
は安定剤および滑剤として多種の金属石けんを用いるた
めチョーキングが著しく、これらのチョーキングを防止
するためポリオール部分エステルなどの使用（特開昭５
６−５７８４４号公報）が提案されているが、まだ不充
分であった。In addition, formulations that use stearate metal salts in combination can cause chalking, and especially in molded products using non-lead formulations, chalking is significant as various metal soaps are used as stabilizers and lubricants. The use of polyol partial esters, etc. to
6-57844) has been proposed, but it was still insufficient.
また、塩化第一銅、塩化第二銅、硫酸銅、塩基性炭酸銅
および炭酸銅などの無機銅化合物を使用する方法（特開
昭５９−１０２９４２号公報）あるいは銅を含有するハ
イドロタルサイト類化合物およびグリシン銅より選ばれ
る一種または二種を使用する方法（特開平２−１８７４
４２号公報）などが提案されているが、この方法では耐
チヨーキング性はある程度改善されるものの、塩素含有
樹脂の熱安定性１．熱着色性および耐候性を悪化させて
しまう。In addition, methods using inorganic copper compounds such as cuprous chloride, cupric chloride, copper sulfate, basic copper carbonate, and copper carbonate (Japanese Unexamined Patent Publication No. 102942/1982) or hydrotalcites containing copper are also available. A method using one or two selected from compounds and copper glycine (Japanese Patent Application Laid-Open No. 2-1874
42), but although this method improves the yoking resistance to some extent, the thermal stability of the chlorine-containing resin is 1. This will deteriorate heat colorability and weather resistance.
さらにまた、有機錫化合物はチョーキング現象は比較的
少ないが、特に有機錫メルカプタイド化合物は耐候性が
劣り、その使用範囲が限定され、その改善が要望されて
いた。Furthermore, although organotin compounds are relatively less likely to cause a chalking phenomenon, organotin mercaptide compounds in particular have poor weather resistance, which limits their range of use, and there has been a demand for improvement.
本発明者等は、上記の欠点を改良すべく鋭意検討を重ね
た結果、硬質塩素含有樹脂に対して、無機銅化合物水溶
液で処理後、炭酸アルカリ水溶液で再処理したハイドロ
タルサイト化合物を添加することによって耐熱性、耐候
性の向上、チョーキングの防止および物性の改善された
硬質塩素含有樹脂組成物が得られることを知見した。As a result of intensive studies to improve the above-mentioned drawbacks, the present inventors added a hydrotalcite compound that was treated with an aqueous inorganic copper compound solution and then re-treated with an aqueous alkali carbonate solution to a hard chlorine-containing resin. It has been found that by doing this, a hard chlorine-containing resin composition with improved heat resistance, weather resistance, prevention of chalking, and improved physical properties can be obtained.
本発明は、上記知見に基づきなされたもので、塩素含有
樹脂１００重量部に対して、無機銅化合物水溶液で処理
後、炭酸アルカリ水溶液で再処理したハイドロタルサイ
ト化合物０．００１〜５重量部を添加してなる安定化さ
れた硬質塩素含有樹脂組成物を提供するものである。The present invention has been made based on the above findings, and includes 0.001 to 5 parts by weight of a hydrotalcite compound treated with an aqueous inorganic copper compound solution and then re-treated with an aqueous alkali carbonate solution to 100 parts by weight of a chlorine-containing resin. The object of the present invention is to provide a stabilized hard chlorine-containing resin composition.
以下、本発明の塩素含有樹脂組成物について詳細に説明
する。Hereinafter, the chlorine-containing resin composition of the present invention will be explained in detail.
本発明において使用される塩素含有樹脂としては、例え
ば、ポリ塩化ビニル、塩素化ポリ塩化ビニル、ポリ塩化
ビニリチン、塩素化ポリエチレン、塩化ビニル−酢酸ビ
ニル共重合体、塩化ビニルエチレン共重合体、塩化ビニ
ル−プロピレン共重合体、塩化ビニル−スチレン共重合
体、塩化ビニル−イソブチレン共重合体、塩化ビニル−
塩化ビニリデン共重合体、塩化ビニル−スチレン−無水
マレイン酸三元共重合体、塩化ビニル、スチレンアクリ
ロニリトル共重合体、塩化ビニル−ブタジェン共重合体
、塩化ビニル−イソプレン共重合体、塩化ビニル−塩素
化プロピレン共重合体、塩化ビニル−塩化ビニリデン−
酢酸ビニル三元共重合体、塩化ビニル−マレイン酸エス
テル共重合体、塩化ビニルーメククリル酸エステル共重
合体、塩化ビニル−アクリロニトリル共重合体、塩化ビ
ニル−各種ビニルエーテル共重合体などの塩素含有樹脂
、およびそれら相互のあるいは他の塩素を含まない合成
樹脂とのブレンド品、ブロック共重合体、グラフト共重
合体などをあげることができる。Examples of the chlorine-containing resin used in the present invention include polyvinyl chloride, chlorinated polyvinyl chloride, polyvinyritine chloride, chlorinated polyethylene, vinyl chloride-vinyl acetate copolymer, vinyl chloride ethylene copolymer, vinyl chloride -Propylene copolymer, vinyl chloride-styrene copolymer, vinyl chloride-isobutylene copolymer, vinyl chloride-
Vinylidene chloride copolymer, vinyl chloride-styrene-maleic anhydride terpolymer, vinyl chloride, styrene acrylonitrile copolymer, vinyl chloride-butadiene copolymer, vinyl chloride-isoprene copolymer, vinyl chloride- Chlorinated propylene copolymer, vinyl chloride-vinylidene chloride-
Chlorine-containing resins such as vinyl acetate terpolymer, vinyl chloride-maleic acid ester copolymer, vinyl chloride-meccrylic acid ester copolymer, vinyl chloride-acrylonitrile copolymer, vinyl chloride-various vinyl ether copolymers, etc. , and blends of these with each other or with other chlorine-free synthetic resins, block copolymers, graft copolymers, and the like.
また、本発明で処理されるために用いられるハイドロタ
ルサイト化合物は、次の一般式ＣＩ）で示されるマグネ
シウムとアルミニウムから成る含水複塩化合物である。Further, the hydrotalcite compound used for the treatment in the present invention is a hydrous double salt compound consisting of magnesium and aluminum and represented by the following general formula CI).
Ｍｇ＋−ｘＡＩｘ（ＯＨ）ｚＡ ｘ／ｚ・ｍＨｚＯ（１
）（上式中、ＸはＯ＜ ｘ≦０．５の範囲の実数であり
、ＡはＣＯ３またはＳＯ４を示し、ｍは実数をしめす。Mg+-xAIx(OH)zA x/z・mHzO(1
) (In the above formula, X is a real number in the range of O<x≦0.5, A represents CO3 or SO4, and m represents a real number.
）
上記ハイドロタルサイト化合物は天然物であってもよく
、また合成品であってもよい。合成方法としては、特公
昭４６−２２８０号公報、特公昭５０−３００３９号公
報、特公昭５１−２９１２９号公報などに記載の公知の
方法を例示することができる。また、本発明においては
、その結晶構造、結晶粒子径などに制限されることなく
使用することが可能である。) The hydrotalcite compound may be a natural product or a synthetic product. Examples of the synthesis method include known methods described in Japanese Patent Publication No. 46-2280, Japanese Patent Publication No. 50-30039, Japanese Patent Publication No. 51-29129, and the like. Further, in the present invention, it can be used without being restricted by its crystal structure, crystal particle size, etc.
これらの無機銅水溶液および炭酸アルカリ水溶液により
処理されたハイドロタルサイト化合物の使用量は塩素含
有樹脂１００重量部に対して、０９００１〜５重量部、
特に０．０１〜３重量部とするのが好ましい。The amount of the hydrotalcite compound treated with these inorganic copper aqueous solutions and alkali carbonate aqueous solutions is 09001 to 5 parts by weight, based on 100 parts by weight of the chlorine-containing resin.
In particular, it is preferably 0.01 to 3 parts by weight.
本発明でハイドロタルサイト化合物を処理するために用
いられる無機銅化合物としては、例えば塩化第一銅、塩
化第二銅、塩化第二銅水和物、塩化銅アンモニウム、塩
化銅カリウム、臭化銅水和物、硫酸銅、硫酸銅水和物な
どの水溶性無機酸の第一および第二銅塩およびこれらの
水和物などがあげられる。Examples of inorganic copper compounds used to treat hydrotalcite compounds in the present invention include cuprous chloride, cupric chloride, cupric chloride hydrate, cupric ammonium chloride, cupric potassium chloride, and copper bromide. Examples include cuprous and cupric salts of water-soluble inorganic acids such as hydrates, copper sulfate, and copper sulfate hydrates, and hydrates thereof.
これらの無機銅水溶液の使用量はハイドロタルサイトの
炭酸イオンの当量までである。The amount of these inorganic copper aqueous solutions used is up to the equivalent of carbonate ions of hydrotalcite.
無機銅水溶液に続いてハイドロタルサイトを処理する炭
酸アルカリとしては、リチウム、ナトリウムおよびカリ
ウムの炭酸塩であり、また重炭酸塩でもよい。The alkali carbonates used to treat the hydrotalcite subsequent to the aqueous inorganic copper solution include lithium, sodium and potassium carbonates, and may also be bicarbonates.
これらの炭酸アルカリ水溶液の使用量は、はじめにハイ
ドロタルサイトを処理した無機銅水溶液の無機酸イオン
を交換するために十分必要な量である。The amount of the alkali carbonate aqueous solution used is an amount sufficient to exchange the inorganic acid ions in the inorganic copper aqueous solution in which the hydrotalcite was first treated.
合成例１
アルカマイザ−１（ｔａ和化学工業製合成ハイドロタル
サイト）１０ｇ、水３５０ｇおよびエチルエルコール５
０ｇを撹拌、均一に分散させ、ここに硫酸銅・五本塩４
．９７ｇを加えて６０’Ｃまで加温し、１時間撹拌する
。次いで炭酸ナトリウム２．０９ｇを加え、室温で２時
間撹拌する。ろ過、水洗、乾燥して安定化剤−１を合成
した。Synthesis Example 1 Alkamizer-1 (synthetic hydrotalcite manufactured by Tawa Kagaku Kogyo) 10 g, water 350 g and ethyl ercole 5
Stir 0g to uniformly disperse, add copper sulfate/five salts 4
．． Add 97g, warm to 60'C and stir for 1 hour. Next, 2.09 g of sodium carbonate is added and stirred at room temperature for 2 hours. Stabilizer-1 was synthesized by filtering, washing with water, and drying.
合成例２
ＤＨＴ−４Ａ （協和化学工業製合成ハイドロタルサイ
））Ｌｏｇ：水４００ｇおよびエチルエルコールＬｏｇ
をビーカーに入れ、撹拌しながら均一に分散させる。こ
こに塩化第二銅２．３６ｇを加え、５０°Ｃで２時間保
持する。室温まで冷却後、さらに炭酸カリウム２．７３
ｇを加え、５０°Ｃで２時間保持する。ろ過、水洗後乾
燥して安定剤■を合成した。Synthesis Example 2 DHT-4A (Synthetic Hydrotalcyan manufactured by Kyowa Chemical Industry)) Log: 400 g of water and ethyl ercol Log
Place in a beaker and stir to evenly disperse. Add 2.36 g of cupric chloride to this and hold at 50°C for 2 hours. After cooling to room temperature, add 2.73 g of potassium carbonate.
g and kept at 50°C for 2 hours. After filtration, washing with water, and drying, stabilizer (2) was synthesized.
合成例３〜４
合成例１と同様の操作により、下記のハイドロタルサイ
ト化合物を硫酸銅および炭酸ナトリウムで熱処理してそ
れぞれ安定化剤−■〜■を合成した。Synthesis Examples 3 to 4 In the same manner as in Synthesis Example 1, the following hydrotalcite compounds were heat-treated with copper sulfate and sodium carbonate to synthesize stabilizers -■ to ■, respectively.
ハイドロタルサイト８
安定化剤−■：アルカマイザー■
安定化剤−■：アルカマイザー■
（＊いずれも協和化学工業製合成ハイドロタルサイト化
合物）
本発明には通常用いられる金属系安定剤を添加すること
ができ、たとえば、鉛系安定剤、カルシウム系安定剤、
亜鉛系安定剤、マグネシウム系安定剤、バリウム系安定
剤、有機錫系安定剤およびこれらの複塩などがあげられ
る。Hydrotalcite 8 Stabilizer - ■: Alcamizer ■ Stabilizer - ■: Alcamizer ■ (*Both are synthetic hydrotalcite compounds manufactured by Kyowa Chemical Industry) A commonly used metal stabilizer is added to the present invention. For example, lead-based stabilizers, calcium-based stabilizers,
Examples include zinc-based stabilizers, magnesium-based stabilizers, barium-based stabilizers, organotin-based stabilizers, and double salts thereof.
上記鉛系安定剤としては、たとえば、鉛白、塩基性珪酸
鉛、塩基性硫酸鉛、二塩基性硫酸鉛、三塩基性硫酸鉛、
塩基性亜硫酸鉛、二塩基性亜リン酸鉛、シリカゲル共沈
珪酸鉛、二塩基性フクル酸鉛：三塩基性マレイン酸鉛、
サリチル酸鉛、ステアリン酸鉛、塩基性ステアリン酸鉛
、二塩基性ステアリン酸鉛、ラウリン酸鉛、オクチル酸
鉛、１２−ヒドロキシステアリン酸鉛、ヘヘニン酸鉛、
ナフテン酸鉛などがあげられる。Examples of the lead-based stabilizers include white lead, basic lead silicate, basic lead sulfate, dibasic lead sulfate, tribasic lead sulfate,
Basic lead sulfite, dibasic lead phosphite, silica gel co-precipitated lead silicate, dibasic lead fuculate: tribasic lead maleate,
Lead salicylate, lead stearate, basic lead stearate, dibasic lead stearate, lead laurate, lead octylate, lead 12-hydroxystearate, lead hehenate,
Examples include lead naphthenate.
亜鉛系、カルシウム系、マグネシウム系およびバリウム
系安定剤などの例としては、これらの酸化物、水酸化物
、炭酸塩、塩基性炭酸塩、（メタ）硼酸塩、（メタ）珪
酸塩、（亜）リン酸塩、塩基性リン酸塩、アルミン酸塩
、チタン酸塩、スズ酸塩、ロダン酸塩などの無機化合物
および有機カルボン酸との金属石けんがあげられる。か
かる有機カルボン酸の例としては、酢酸、乳酸、ステア
リル乳酸、カプロン酸、ベテルゴン酸、ラウリン酸、２
−エチルヘキシル酸、ミリスチン酸、パルチミン酸、ウ
ンデシレン酸、リシノール酸、リノール酸、リルイン酸
、ネオデカン酸、オレイン酸、ステアリン酸、イソデカ
ン酸、イソステアリン酸、１２−ヒドロキシステアリン
酸、１２−ケトステアリン酸、クロロステアリン酸、フ
ｌニルステアリン酸、アラキン酸、ベヘン酸、エルカ酸
、ブラシジン酸および類似酸ならびに獣脂脂肪酸、やし
油脂肪酸、キリ油脂肪酸、大豆油脂肪酸および綿実油脂
肪酸のような天然に産出する上記の酸の混合物、安息香
酸、クロル安息香酸、トルイル酸、サリチル酸、ｐ−第
三ブチル安息香酸、５−第：オクチルサリチル酸、リフ
テン酸、キシリル酸、エチル安息香酸、イソプロピル安
息香酸、ジ第三ブチル安息香酸、ブロモ安息香酸、マレ
イン酸、アジピン酸、フクル酸、モノブチルマレート、
モノデシルツクレート、シクロヘキサンジカルボン酸な
どがあげられる。Examples of zinc-based, calcium-based, magnesium-based and barium-based stabilizers include their oxides, hydroxides, carbonates, basic carbonates, (meta)borates, (meta)silicates, and (meta)silicates. ) Metal soaps with inorganic compounds and organic carboxylic acids such as phosphates, basic phosphates, aluminates, titanates, stannates, and rhodanates. Examples of such organic carboxylic acids include acetic acid, lactic acid, stearyl lactic acid, caproic acid, betergonic acid, lauric acid,
-Ethylhexylic acid, myristic acid, palmitic acid, undecylenic acid, ricinoleic acid, linoleic acid, liluic acid, neodecanoic acid, oleic acid, stearic acid, isodecanoic acid, isostearic acid, 12-hydroxystearic acid, 12-ketostearic acid, chloro Naturally occurring above such as stearic acid, furinylstearic acid, arachidic acid, behenic acid, erucic acid, brassic acid and similar acids and tallow fatty acids, coconut oil fatty acids, tung oil fatty acids, soybean oil fatty acids and cottonseed oil fatty acids mixture of acids, benzoic acid, chlorobenzoic acid, toluic acid, salicylic acid, p-tert-butylbenzoic acid, 5-octylsalicylic acid, rifthenic acid, xylylic acid, ethylbenzoic acid, isopropylbenzoic acid, di-tert-butylbenzoic acid Benzoic acid, bromobenzoic acid, maleic acid, adipic acid, fucuric acid, monobutyl maleate,
Examples include monodecyl tucrate and cyclohexanedicarboxylic acid.
また、上記有機錫系安定剤としては、たとえば、メチル
スタノイソク酸、プチルスタノインク酸、オクチルスタ
ノインク酸、ジメチル錫オキサイド、ジブチル錫オキサ
イド、ジオクチル錫オキサイド、ジメチル錫サルファイ
ド、ジブチル錫サルファイド、ジオクチル錫サルファイ
ド、ジシクロへキシル錫サルファイド、モノブチル錫オ
キサイド・サルファイド、メチルチオスタノイソク酸、
プチルチオスタノイソク酸、オクチルチオスタノイソク
酸、ジブチル錫ジラウレ−１・、ジブチル錫ジステアレ
ート、ジオクチル錫ジオレート、ジブチル錫塩基性ラウ
レート、ジブチル錫ジクロトネ＝１〜、ジブチル錫ビス
（ブトキシジエチレングリコールマレート）、ジブチル
錫メチル・オクチル・ネオペンチルグリコールマレート
、ジブチル錫イソオクチル・１４−ブタンジオールマレ
−Ｉ・、ジブチル錫ジメタクリレート、ジブチル錫ジシ
ンナト、ジオクチル錫ビス（オレイルマレート）、ジブ
チル錫ビス（ステアリルマレート）、ジブチル錫イタコ
ネート、ジオクチル錫マレート、シアミル錫ビス（シク
ロへキシルマレート）、ジメチル錫ジクロトネート、ジ
エチル錫ビス（イソオクチルシトロネート）、ジプロピ
ル錫ビス（ヘンシルマレート）、ジイソブチル錫ビス（
プロピルマレト）、ジシクロヘキシル錫マレート、ジオ
クチル錫ビス（ブチルマレート）、ジブチル錫ジメトキ
シド、ジブチル錫ジラウロキシド、ジオクチル錫エチレ
ングリコキシド、ペンタエリスリトール・ジブチル錫オ
キシド縮金物、ジブチル錫ビス（ラウリルメルカプタイ
ド）、ジメチル錫ビス（ステアリルメルカプタイド）、
モノブチル錫トリス（ラウリルメルカプタイド）、ジブ
チル錫−βメルカプトプロピオネート、ジオクチル錫−
βメルカプトプロピオネ−１−、ジブチル錫メルカプト
アセテート、モノブチル錫１〜リス（イソオクチルメル
カプトアセテート）、モノオクチル錫トリス（２−エチ
ルへキシルメルカプトアセテート）、ジブチル錫ビス（
イソオクチルメルカプトアセテト）、ジオクチル錫ビス
（イソオクチルメルカプトアセテート
ルへキシルメルカプトアセテート）、ジメチル錫ビス（
イソオクチルメルカプトアセテートメチル錫ビス（イソ
オクチルメルカプトプロピオネート）、モノブチル錫ト
リス（イソオクチルメルカプトプロピオネート）、ビス
（モノブチルジ（イソオクトキシカルボニルメチレンチ
オ）錫〕サルファイド、ビス（ジブチルモノ（イソオク
トキシカルボニルメチレンチオ）錫〕ザルファイド、モ
ノブチルモノクロル錫ビス（イソオクチルメルカプトプ
ロピオネート）、モノブチルモノクロロ錫ビス（イソオ
クチルメルカプトアセテート）、モノブチルモノクロロ
錫ビス（ラウリルメルカプタイド）、ブチル錫ビス（エ
チルセルソロブマレート）、ビス（ジオクチル錫ブチル
マレート）マレート、ビス（メチル錫ジイソオクチルチ
ルグリコレート）ジサルファイド、ビス（メチル／ジメ
チル錫モノ／ジイソオクチルチオグリコレート）ジサル
ファイド、ビス（メチル錫ジイソオクチルチオグリコレ
ート）トリサルファイド、ビス（ブチル錫ジイソオクチ
ルチオグリコレート）トリサルファイド、２−ブトキシ
カルボニルエチル錫トリス（ブチルチオグリコレート）
などがあげられる。Examples of the organotin-based stabilizers include methyl stanoisocyanic acid, butyl stanoic acid, octyl stanoic acid, dimethyltin oxide, dibutyltin oxide, dioctyltin oxide, dimethyltin sulfide, and dibutyltin sulfide. , dioctyltin sulfide, dicyclohexyltin sulfide, monobutyltin oxide sulfide, methylthiostanoisocyanate,
butylthiostanoisocyanate, octylthiostanoisocyanate, dibutyltin dilaure-1, dibutyltin distearate, dioctyltin dioleate, dibutyltin basic laurate, dibutyltin dicrotone=1~, dibutyltin bis(butoxydiethylene glycol malate) ), dibutyltin methyl octyl neopentyl glycol maleate, dibutyltin isooctyl 14-butanediol male-I, dibutyltin dimethacrylate, dibutyltin disinnato, dioctyltin bis(oleyl maleate), dibutyltin bis(stearyl) dibutyltin itaconate, dioctyltin malate, cyamyltin bis(cyclohexylmalate), dimethyltin dicrotonate, diethyltin bis(isooctylcitronate), dipropyltin bis(hensylmalate), diisobutyltin bis(
propyl maleate), dicyclohexyltin maleate, dioctyltin bis(butyl maleate), dibutyltin dimethoxide, dibutyltin dilauroxide, dioctyltin ethylene glycoxide, pentaerythritol dibutyltin oxide condensate, dibutyltin bis(lauryl mercaptide), dimethyltin Bis (stearyl mercaptide),
Monobutyltin tris (lauryl mercaptide), dibutyltin-β-mercaptopropionate, dioctyltin-
β-mercaptopropione-1-, dibutyltin mercaptoacetate, monobutyltin 1-lis(isooctylmercaptoacetate), monooctyltin tris(2-ethylhexylmercaptoacetate), dibutyltin bis(
isooctylmercaptoacetate), dioctyltin bis(isooctylmercaptoacetate hexylmercaptoacetate), dimethyltin bis(
isooctylmercaptoacetate methyltin bis(isooctylmercaptopropionate), monobutyltin tris(isooctylmercaptopropionate), bis(monobutyldi(isooctoxycarbonylmethylenethio)tin) sulfide, bis(dibutylmono(isooctoxy) carbonylmethylenethio)tin] sulfide, monobutylmonochlorotinbis(isooctylmercaptopropionate), monobutylmonochlorotinbis(isooctylmercaptoacetate), monobutylmonochlorotinbis(laurylmercaptide), butyltinbis( Bis(dioctyltinbutylmalate) malate, Bis(methyltin diisooctylthioglycolate) disulfide, Bis(methyl/dimethyltin mono/diisooctylthioglycolate) disulfide, Bis(methyltin diisooctyl glycolate) disulfide Tin diisooctylthioglycolate) trisulfide, bis(butyltin diisooctylthioglycolate) trisulfide, 2-butoxycarbonylethyltin tris(butylthioglycolate)
etc.
これらの金属系安定剤の使用量は塩素含有樹脂１００重
量部に対して、０６ ０１〜１０重量部、特に０．０５
〜５重量部とするのが好ましい。The amount of these metal stabilizers used is 0.06 to 10 parts by weight, especially 0.05 parts by weight, per 100 parts by weight of the chlorine-containing resin.
It is preferable to set it as 5 parts by weight.
本発明の組成物には、有機ホスファイト系抗酸他剤を併
用することができる。かかる有機ホスファイト系抗酸化
剤としては、ジフェニルデシルホスファイト、ｌ・リフ
ェニルボスファイＩ・、トリスノニルフェニルホスファ
イト、トリデシルホスファイト、トリス（２〜エチルヘ
キシル）ホスファイト、トリブチルホスファイト、ジラ
ウリルアシドホスファイト、ジブチルアシドホスファイ
ト、トリス（ジノニルフェニル）ホスファイト、トリラ
ウリルトリチオホスファイト、ｌ・リラウリルホスファ
イト、ビス（ネオペンチルグリコール）１．４−シクロ
ヘキサンジメチルジホスファイト、ジステアリルペンタ
エリスリトールジホスファイト、ジイソデシルペンタエ
リスリトールジホスファイト、ジフェニルアシドボスフ
ァイト、トリス（ラウリル−２−チオエチル）ホスファ
イト、テトラトリデシル−１，，１，ｌ−トリス（２゛
−メチル−５゛−第三ブチル−４”−ヒドロキシフェ
ニル）ブタンジホスファイト、テＩ・う（Ｃ＋□〜１５
混合アルキル）−４４“−イソプロピリデンジフェニル
ジホスファイト、トリス（４−ヒドロキシ−２，５−ジ
第三ブチルフェニル）ホスファイト、トリス（４−ヒド
ロキシ−３，５−ジ第三ブチルフェニル）ホスファイト
、２−エチルヘキシルジフェニルホスファイＩ・、トリ
ス（モノ、ジ混合ノニルフェニル）ホスファイト、水素
化−４４−イソプロピリデンジフェノールポリホスファ
イト、ジフェニル・ビス〔４，４”−ｎ−ブチリデンビ
ス（２−第三ブチル−５−メチルフェノール）］チオジ
ェタノールジホスファイト、ビス（オクチルフェニル）
・ビス（４，４″−ｎ−フチリデンビス（２−第三ブチ
ル−５−メチルフェノール））−１，６−ヘキサンジオ
ールジホスファイト、フェニル−４，４−イソプロピリ
デンジフェノール・ペンタエリスリトールジホスファイ
ト、フエニルジイソデシルホスファイト、テトラトリデ
シル−４４’ −ｎ−ブチリデンビス（２−第三ブチル
−５−メチルフェノール）ジホスファイト、トリス（２
，４−ジ第三ブチルフェニル）ホスファイトなどがあげ
られる。Organic phosphite anti-acid agents and other agents can be used in combination with the composition of the present invention. Such organic phosphite-based antioxidants include diphenyldecyl phosphite, l-riphenylbosphite I, trisnonylphenyl phosphite, tridecyl phosphite, tris(2-ethylhexyl) phosphite, tributyl phosphite, di- Lauryl acid phosphite, dibutyl acid phosphite, tris(dinonylphenyl) phosphite, trilauryl trithiophosphite, l-lilauryl phosphite, bis(neopentyl glycol) 1,4-cyclohexane dimethyl diphosphite, distearyl Pentaerythritol diphosphite, diisodecyl pentaerythritol diphosphite, diphenyl acid bosphite, tris(lauryl-2-thioethyl) phosphite, tetratridecyl-1,,1,l-tris(2゛-methyl-5゛- Tertiary-butyl-4”-hydroxyphenyl)butane diphosphite, TeI・U(C+□~15
mixed alkyl)-44"-isopropylidene diphenyl diphosphite, tris(4-hydroxy-2,5-di-tert-butylphenyl) phosphite, tris(4-hydroxy-3,5-di-tert-butylphenyl) phosphite phyto, 2-ethylhexyldiphenylphosphite I, tris(mono-, di-mixed nonylphenyl)phosphite, hydrogenated-44-isopropylidenediphenol polyphosphite, diphenyl bis[4,4”-n-butylidenebis(2 -tert-butyl-5-methylphenol)] Thiogetanol diphosphite, bis(octylphenyl)
・Bis(4,4″-n-phthylidene bis(2-tert-butyl-5-methylphenol))-1,6-hexanediol diphosphite, phenyl-4,4-isopropylidene diphenol ・pentaerythritol diphosphite phyto, phenyl diisodecyl phosphite, tetratridecyl-44'-n-butylidene bis(2-tert-butyl-5-methylphenol) diphosphite, tris(2
, 4-di-tert-butylphenyl) phosphite.
本発明の組成物に、紫外線吸収剤、ヒンダードアミン化
合物などの光安定剤を添加することによってその耐光性
を一層改善することができる。By adding a light stabilizer such as an ultraviolet absorber or a hindered amine compound to the composition of the present invention, its light resistance can be further improved.
この光安定剤としてはたとえば、２．４−ジヒドロキシ
ベンゾフェノン、２−ヒドロキシ−４メトキシヘンシフ
エノン、２−ヒドロキシ−４オクトキシヘンヅフエノン
、５．５° −メチレンヒス（２−ヒドロキシ−４−メ
トキシヘンシフエノン）などの２−ヒドロキシベンゾフ
ェノン類；２−（２° −ヒドロキシ−５″−メチルフ
ェニル）ベンゾトリアゾール、２− （２’ −ヒドロ
キシ５′−第三オクチルフェニル）ヘンシトリアゾール
、ｌ−（２’−ヒドロキシ−３’、５’ −ジクミル
フェニル）ヘンシトリアゾール、２−（２−ヒドロキシ
−３′、５” −ジ第三ブチルフェニル）−５−クロロ
ベンツトリアソー）Ｌ／、２（２″−ヒドロキシ−３′
−第三ブチル−５′メチルフエニル）−５−クロロヘン
シトリアゾール、ｌ−（２’ −ヒドロキシ−３°
５” −ジクミルフェニル）ヘンシトリアゾール、２２
メチレンビス（４−第三オクチルー６−ベンゾトリアゾ
リル）フェノールなどの１− （２’ −ヒドロキシフ
ェニル）ベンゾトリアゾール類；フェニルサリシレート
、レゾルシノールモノヘンゾエート、２．４−ジ第三ブ
チルフェニル−３° ５゛ジ第三ブチル−４”−ヒド
ロキシヘンゾエート：ヘキサデシル−３，５−ジ第三ブ
チルー４−ヒドロキシベンゾニー１・などのヘンゾエー
ｌ−Ｍ；２エチル−２′−エトキシオキザニリド、２−
エトキシ−４−ドデシルオキザニリドなどの置換オキザ
ニリド類；エチルーα−シアノ−β、βジフェニルアク
リレート、メチル−２−シアノ３−メチル−３−（ｐ−
メトキシフェニル）アクリレートなどのシアノアクリレ
−１・類；２，２６．６−テトラメチル−４−ピペリジ
ルステアレート、１．２，２．６．６−パンクメチル−
４ピペリジルステアレート、２．２．６ローテトラメチ
ルー４−ピペリジルヘンゾエート、ビス（２，２，６，
６−テトラメチル−４−ピペリジル）セバケート、ビス
（１２２６６−ベンタメチルー４−ピペリジル）セバケ
ート、テトラキス（２，２，６，６−テトラメチル−４
−ピペリジルｌ−１，２，３，４−ブタンテトラカルボ
キシレート、テトラキス（］、］２，２，６．６−ベン
タメチルー４ピペリジル）−１２３４ブタンテトラカル
ポキシレ−１〜、ビス（１２２，６，６−−ペンタメチ
ルー４−ピペリジル）ジ（トリデシル）−１，２，３４
−ブタンテトラカルボキシレート、ビス（１２，２６６
ペンタメチルー４−ピペリジル）−１−ブチル２−（３
，５−ジ第三ブチルー４−ヒドロキシヘンシル）マロネ
ート、１−（２−ヒドロキシエチル）−２，２，６，６
−テトラメチル−４−ピペリジツール／コハク酸ジエチ
ル重縮合物、１６−ビス（２，２，６，６−チトラメチ
ルー４ピペリジルアミノ）ヘキサン／ジブロモエタン重
縮合物、１，６−ビス（２，２，６，６−チトラメチル
ー４−ピペリジルアミノ）ヘキサン／２４−ジクロロ−
６−第三オクチルアミノ−３−トリアジン重縮合物、１
．６−ビス（２，２，６ローテトラメチルー４−ピペリ
ジルアミノ）ヘキサン／２．４−ジクロロ−６−モルホ
リノ−Ｓトリアジン重縮合物などのヒンダードアミン化
合物があげられる。Examples of the light stabilizer include 2.4-dihydroxybenzophenone, 2-hydroxy-4methoxyhenduphenone, 2-hydroxy-4octoxyhenduphenone, and 5.5°-methylenehis(2-hydroxy-4- 2-hydroxybenzophenones such as methoxyhensiphenone); 2-(2°-hydroxy-5″-methylphenyl)benzotriazole, 2-(2′-hydroxy5′-tert-octylphenyl)hensitriazole, l- (2'-hydroxy-3',5'-dicumylphenyl)hencytriazole, 2-(2-hydroxy-3',5"-di-tert-butylphenyl)-5-chlorobenztriazo) L/, 2 (2″-hydroxy-3′
-tert-butyl-5'-methylphenyl)-5-chlorohencitriazole, l-(2'-hydroxy-3°
5”-dicumylphenyl)hencytriazole, 22
1-(2'-Hydroxyphenyl)benzotriazoles such as methylenebis(4-tert-octyl-6-benzotriazolyl)phenol; phenyl salicylate, resorcinol monohenzoate, 2,4-di-tert-butylphenyl-3° 5゛di-tert-butyl-4''-hydroxyhenzoate: hexadecyl-3,5-di-tert-butyl-4-hydroxybenzony 1-M; 2-ethyl-2'-ethoxyoxanilide, 2 −
Substituted oxanilides such as ethoxy-4-dodecyloxanilide; ethyl-α-cyano-β, β-diphenyl acrylate, methyl-2-cyano-3-methyl-3-(p-
Cyanoacrylates such as methoxyphenyl) acrylate; 2,26.6-tetramethyl-4-piperidyl stearate, 1.2,2.6.6-pankmethyl-
4-piperidyl stearate, 2.2.6-rotetramethyl-4-piperidylhenzoate, bis(2,2,6,
6-tetramethyl-4-piperidyl) sebacate, bis(12266-bentamethyl-4-piperidyl) sebacate, tetrakis(2,2,6,6-tetramethyl-4
-piperidyl l-1,2,3,4-butanetetracarboxylate, tetrakis(], ]2,2,6.6-bentamethyl-4piperidyl)-1234butanetetracarpoxylate-1~,bis(122,6 ,6--pentamethyl-4-piperidyl)di(tridecyl)-1,2,34
-butanetetracarboxylate, bis(12,266
Pentamethyl-4-piperidyl)-1-butyl 2-(3
, 5-ditert-butyl-4-hydroxyhensyl) malonate, 1-(2-hydroxyethyl)-2,2,6,6
-tetramethyl-4-piperiditul/diethyl succinate polycondensate, 16-bis(2,2,6,6-titramethyl-4piperidylamino)hexane/dibromoethane polycondensate, 1,6-bis(2,2, 6,6-titramethyl-4-piperidylamino)hexane/24-dichloro-
6-tertiary octylamino-3-triazine polycondensate, 1
．． Examples include hindered amine compounds such as 6-bis(2,2,6-rotetramethyl-4-piperidylamino)hexane/2,4-dichloro-6-morpholino-S triazine polycondensate.
また、本発明の組成物に、１．４−ブタンジオールビス
（β−アミノクロトネート）、チオジグリコールビス（
β−アミノクロトネート）などのβ−アミノクロトネー
ト類；ジフェニル尿素、ジフェニルチオ尿素などの尿素
類；α−フェニルインドール、α−（オクチルフェニル
）インドールなどのインドール頻：２，６−シメチルー
３．５ジカルボオクトキシ−１，４−ジヒドロピリジン
、２６−シメチルー３．５−ジカルボラウリルオキシ−
１４−ジヒドロピリジンなどのジヒドロピリジン類；ジ
ヘンゾイルメタン、ヘンジイルアセトン、ステアロイル
ヘンヅイルメタン、カブロイルヘンジイルメタン、デヒ
ドロ酢酸などのβ−ジケトン化合物；トリメチロールプ
ロパン、グリセリン、トリス（ヒドロキシエチル）イソ
シアヌレート、ヘンタエリスリトール、ジペンタエリス
リトール、マンニント、ツルピント、ペンタエリスリト
ール・ステアリン酸エステル、ジペンタエリスリトール
・アジピン酸エステル、ジペンタエリスリトール・ピロ
リドンカルボン酸エステルなどの多価アルコール類；ジ
ラウリルチオジプロピオネート、ジステアリルチオジプ
ロピオネート、ペンタエリスリトール・テトう（ラウリ
ルメルカプトプロピオネート）などの有機硫黄系化合物
；ビスフェノールＡ、２．６−ジ第三ブチルｐ−クレゾ
ール、ステアリル−３，５−ジ第三フチルー４−ヒドロ
キシフェニルプロピオネートなどのフェノール類あるい
はメラミン類を併用することができる。In addition, 1,4-butanediol bis(β-aminocrotonate), thiodiglycol bis(
β-aminocrotonates such as β-aminocrotonate); ureas such as diphenylurea and diphenylthiourea; indoles such as α-phenylindole and α-(octylphenyl)indole; 2,6-dimethyl-3. 5-dicarbooctoxy-1,4-dihydropyridine, 26-dimethyl-3,5-dicarbolauryloxy-
Dihydropyridines such as 14-dihydropyridine; β-diketone compounds such as dihenzoylmethane, hendiylacetone, stearoylhendiylmethane, cabroylhendiylmethane, and dehydroacetic acid; trimethylolpropane, glycerin, tris(hydroxyethyl) isocyanate Polyhydric alcohols such as nurate, hentaerythritol, dipentaerythritol, manninto, tulpinto, pentaerythritol stearate, dipentaerythritol adipate, dipentaerythritol pyrrolidone carboxylic acid ester; dilauryl thiodipropionate, Organic sulfur compounds such as distearyl thiodipropionate, pentaerythritol tetra(lauryl mercaptopropionate); bisphenol A, 2,6-di-tert-butyl p-cresol, stearyl-3,5-di-tertiary Phenols such as phthyl-4-hydroxyphenylpropionate or melamines can be used in combination.
その他必要に応じて、本発明の組成物には例えば架橋剤
、顔料、充填剤、発泡剤、帯電防止剤、防雪剤、プレー
トアウト防止剤、表面処理剤、滑剤、難燃剤、蛍光剤、
防黴剤、殺菌雑、金属不活性剤、光劣化剤、加工助剤、
離型剤、補強剤などを包含させることができる。If necessary, the composition of the present invention may include, for example, a crosslinking agent, a pigment, a filler, a foaming agent, an antistatic agent, a snow protection agent, a plate-out prevention agent, a surface treatment agent, a lubricant, a flame retardant, a fluorescent agent,
Antifungal agents, sterilizers, metal deactivators, photodegradants, processing aids,
A mold release agent, reinforcing agent, etc. can be included.
次に示す実施例は本発明の塩素含有樹脂組成物の効果を
示すものであるが、本発明はこれらの実施例によって限
定されるものではない。The following examples show the effects of the chlorine-containing resin composition of the present invention, but the present invention is not limited to these examples.
実施例１
次の配合により、１９０°Ｃで５分間混練した後に、１
７０°Ｃ１２００ｋｇ／ｃｍ２の条件下で５分間プレス
して１ ｍｍの試験片を作成した。この試験片を１９０
°Ｃのオーブン中に入れ、熱安定性試験を行い、黒化す
るまでの時間を測定した。Example 1 With the following formulation, after kneading at 190°C for 5 minutes, 1
A 1 mm test piece was prepared by pressing for 5 minutes at 70°C and 1200 kg/cm2. This test piece was
A thermal stability test was performed by placing the sample in an oven at 0.degree. C., and the time until blackening was measured.
また、屋外暴露試験を行い、白化（チョーキング）する
までの時間を測定した。In addition, an outdoor exposure test was conducted to measure the time required for whitening (chalking).
その結果を表−１に示す。The results are shown in Table-1.
（配 合）
ＰＶＣ（Ｐ ＝ １０００） １００重
量部重量部性塩基鉛 １．０ステア
リン酸鉛 ２．〇二塩基性ステアリ
ン酸鉛 ０．３ステアリン酸バリウム
０． １炭酸カルシウム
３．０酸化チタン ０． ２カ
ーボンブラツク ０．０１安定化剤
実施例２
次の配合により、実施例１と同様にして試験片を作成し
、この試験片を用い１９０°Ｃでの熱安定性試験および
初期着色性の試験を行った。また、ウエザオメーターに
より１６８時間照射後のアイゾツト衝撃強度（ｋｇ−ｃ
ｍ／ｃｍ２）および５０４時間照射後の伸びを測定した
。(Composition) PVC (P = 1000) 100 parts by weight Basic lead 1.0 Lead stearate 2. 〇Dibasic lead stearate 0.3 barium stearate
0. 1 calcium carbonate
3.0 Titanium oxide 0. 2 Carbon Black 0.01 Stabilizer Example 2 A test piece was prepared in the same manner as in Example 1 with the following formulation, and this test piece was used for a thermal stability test at 190°C and an initial coloring test. I did it. In addition, the Izot impact strength (kg-c) after 168 hours of irradiation was measured using a weatherometer.
m/cm2) and elongation after 504 hours of irradiation were measured.
なお、伸びはオリジナルとの比、すなわち伸び残率で示
した。Note that the elongation is expressed as a ratio to the original, that is, as a percentage of remaining elongation.
その結果を表−２に示す。The results are shown in Table-2.
（配合）
ＰＶＣ（Ｐ ＝ １０５０） １００重
量部ステアリン酸 ０．５三塩基
性硫酸鉛 ０．５二塩基性ステアリ
ン酸鉛 ０． ５安定化剤（表−２）
０．１
実施例３
次の配合により、混練ロールで厚さ１ ｍｍのシートを
作成し、このシートについて、１年問屋外曝露後のチョ
ーキングの発生状態を測定した。その結果を次の表−３
に示す。(Composition) PVC (P = 1050) 100 parts by weight Stearic acid 0.5 Tribasic lead sulfate 0.5 Dibasic lead stearate 0. 5 Stabilizer (Table 2) 0.1 Example 3 A sheet with a thickness of 1 mm was prepared using a kneading roll using the following formulation, and the occurrence of chalking on this sheet after one year of outdoor exposure was measured. did. The results are shown in Table 3 below.
Shown below.
なお、チョーキングの発生状態は１０段階で評価した。The occurrence of chalking was evaluated on a scale of 10.
■
変化なしく無色）
（配 合）
ＰＶＣ（Ｐ ＝ ８００）
ステアリン酸カルシウム
ステアリン酸亜鉛
炭酸カルシウム
ジブチル錫マレートポリマー
著しく白化
１００重量部
０、 ７
０．３
３．０
０．１
安定化剤（表−３）
０．１
（発明の効果〕
本発明になる塩素含有樹脂組成物は、耐熱性および耐候
性の向上、チョーキングの防止及び物性の改善されたも
のである。■ Colorless with no change) (Formulation) PVC (P = 800) Calcium stearate Zinc stearate Calcium dibutyltin malate Polymer Significant whitening 100 parts by weight 0, 7 0.3 3.0 0.1 Stabilizer (Table -3) 0.1 (Effects of the Invention) The chlorine-containing resin composition of the present invention has improved heat resistance and weather resistance, prevention of chalking, and improved physical properties.
Claims (1)
水溶液で処理後、炭酸アルカリ水溶液で再処理したハイ
ドロタルサイト化合物０．００１〜５重量部を添加して
なる安定化された塩素含有樹脂組成物。A stabilized chlorine-containing resin composition obtained by adding 0.001 to 5 parts by weight of a hydrotalcite compound treated with an aqueous inorganic copper compound solution and then re-treated with an aqueous alkali carbonate solution to 100 parts by weight of a hard chlorine-containing resin. thing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2202921A JP2981761B2 (en) | 1990-07-31 | 1990-07-31 | Stabilized chlorine-containing resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2202921A JP2981761B2 (en) | 1990-07-31 | 1990-07-31 | Stabilized chlorine-containing resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0488041A true JPH0488041A (en) | 1992-03-19 |
| JP2981761B2 JP2981761B2 (en) | 1999-11-22 |
Family
ID=16465370
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2202921A Expired - Fee Related JP2981761B2 (en) | 1990-07-31 | 1990-07-31 | Stabilized chlorine-containing resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2981761B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0709427A1 (en) | 1994-10-27 | 1996-05-01 | Kyowa Chemical Industry Co., Ltd. | Resin composition and molded article |
| WO2004024825A1 (en) * | 2002-09-13 | 2004-03-25 | Kaneka Corporation | Polymer composition containing double salt whose metal components are magnesium and aluminum |
-
1990
- 1990-07-31 JP JP2202921A patent/JP2981761B2/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0709427A1 (en) | 1994-10-27 | 1996-05-01 | Kyowa Chemical Industry Co., Ltd. | Resin composition and molded article |
| US5696226A (en) * | 1994-10-27 | 1997-12-09 | Kyowa Chemical Industry Co., Ltd. | Resin composition and molded article thereof |
| WO2004024825A1 (en) * | 2002-09-13 | 2004-03-25 | Kaneka Corporation | Polymer composition containing double salt whose metal components are magnesium and aluminum |
| CN1301301C (en) * | 2002-09-13 | 2007-02-21 | 株式会社钟化 | Polymer composition containing double salt whose metal components are magnesium and aluminum |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2981761B2 (en) | 1999-11-22 |
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